CN109483082A - A kind of coating weld-ring and preparation method thereof - Google Patents

A kind of coating weld-ring and preparation method thereof Download PDF

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Publication number
CN109483082A
CN109483082A CN201811187577.2A CN201811187577A CN109483082A CN 109483082 A CN109483082 A CN 109483082A CN 201811187577 A CN201811187577 A CN 201811187577A CN 109483082 A CN109483082 A CN 109483082A
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China
Prior art keywords
ring
solder
coating
binder
weld
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CN201811187577.2A
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CN109483082B (en
Inventor
王晓蓉
陈斐
范仲华
唐卫岗
蒋金金
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Hangzhou Huaguang Advanced Welding Materials Co Ltd
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Hangzhou Huaguang Advanced Welding Materials Co Ltd
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24Selection of soldering or welding materials proper
    • B23K35/30Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
    • B23K35/3006Ag as the principal constituent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/40Making wire or rods for soldering or welding

Abstract

This application involves a kind of coating weld-rings and preparation method thereof, and coating weld-ring includes solder and brazing flux, and solder is annular in shape, and brazing flux is bonded in solder surface by binder and forms one layer of uniform coating.The binder is the mixture of polyurethane and diluent, and diluent is one of butyl acetate, acetone, dimethyl carbonate or a variety of, and wherein polyurethane accounts for the 80-90% of binder gross mass, and diluent accounts for the 10-20% of binder gross mass.The preparation method of the coating weld-ring is the following steps are included: solder surface forms uniform adhesive layer;Brazing flux is bonded in composition coating weld-ring semi-finished product on the solder for speckle with binder;It is fixed-type that heating polishing is carried out to coating weld-ring semi-finished product.The application is simple for structure, and coating cohesive force is strong, and appearance uniform is fine and close after the processing of three-D lapping machine, and thickness stability is good, and coating weld-ring is easily assembled and uses.

Description

A kind of coating weld-ring and preparation method thereof
Technical field
This application involves a kind of coating weld-rings and preparation method thereof that coating adhesiveness is strong.
Background technique
Soldering refers to that solder and weldment lower than weldment fusing point while heated to after brazing filler metal melts temperature, utilize liquid solder The welding method that the gap of filling solid workpieces connects metal.Leading intermediate temperature solder to be used on the market has copper-based pricker at present Material, silver solder etc..Most of silver solder needs to cooperate scaling powder when in use, and scaling powder can play activation table in welding Face avoids the effects of oxidation, using can obtain better welding effect.
Most of phosphorous copper base solder when in use, since P elements have self-fluxing effect, can be mismatched in welding Brazing flux uses completion welding.But in the narrow weldering for have higher requirements to mobility and surface quality using phosphorous copper base solder When seam, often because solder fluidity and wetability are insufficient, leads to problems such as to lack weldering, insufficient (incomplete) penetration, lead to product defect rate mistake It is high.
The use of scaling powder at present mainly passes through is applied to welding position use by hand, and this results in welding sequences Low, the extra brazing flux of utilization rate that is complicated, smearing brazing flux will cause pollution, impact to environment.In addition to these problems, apply The uncertainty for smearing brazing flux personnel operation also results in Welding Problems.
In order to improve welding efficiency and stability, mitigate environmental pressure caused by welding, medicine core, coating etc. are compound at present Solder receives extensive pay attention to and exploitation.But the flux coated brazingrod produced on the market at present, the adhesive ability of surface coating is poor, During transportation, surface coating can lead to client in use, weld-ring surface pricker underdosage, out because collision be lost Now a large amount of defective products.
Summary of the invention
The technical issues of the application solves is to overcome the above deficiencies in the existing technologies, and provide a kind of coating attachment The strong coating weld-ring and preparation method thereof of power.The weld-ring coating adhesive force is strong, and coating loss is small during transportation, and welding is stablized Property it is good, have good mobility, can be improved bead weld soldering qualification rate and welding efficiency.Especially suitable for high-frequency induction Soldering.
The present invention solves technical solution used by above-mentioned technical problem
A kind of coating weld-ring, including solder and brazing flux, it is characterized in that the coating weld-ring is only bonded by solder and brazing flux.
Herein described solder is annular in shape and is located at internal layer, and the surface of solder is formed uniformly (dipping, coating or other sides Formula) binder, brazing flux be covered on binder formed coating weld-ring outer layer (coating).
The present invention solves technical solution used by above-mentioned technical problem further include:
A kind of preparation method of coating weld-ring, it is characterized in that the following steps are included:
Solder ring surface forms uniform adhesive layer;
Brazing flux is attached to formation coating weld-ring semi-finished product on the solder ring for speckle with binder;
Coating weld-ring semi-finished product (the solder ring for speckling with brazing flux and binder) are fixed-type by heating polishing.
Since binder is evenly distributed in solder ring surface, the brazing flux and direct warp that are bonded in by binder on solder ring It crosses surface to compare coated in the brazing flux on solder ring, there is better Adhesion property, can be reduced brazing flux during Product transport It falls off, guarantees that weld-ring surface still has one layer of uniform brazing flux in welding, guarantee the stability of welding.
By to bonding brazing flux solder ring carry out heating polishing it is fixed-type, can guarantee that binder is completely dried, and The stability of coating weld-ring size is further increased, and weld-ring size influences weld-ring assemble welding, dimensionally stable can reduce card Ring, and fit-up gap is reduced, welding effect is improved, failure welding rate is reduced.
Solder ring surface forms uniform adhesive layer step: the binder prepared being covered on solder ring, in pricker Expect that ring surface forms one layer of uniform adhesive layer.
The binder is the mixture of polyurethane and diluent, and diluent is butyl acetate, in acetone, dimethyl carbonate It is one or more, wherein polyurethane accounts for the 80-90% of mixture gross mass, and diluent accounts for the 10-20% of mixture gross mass.
After binder prepares, it could be used by stirring evenly.In order to make binder more evenly, binder can be heated to 80 degrees Celsius are uniformly mixed.
Solder ring can be used spraying or dipping (dipping) mode and be formed uniformly adhesive layer in solder ring surface.The side of spraying Formula can be with are as follows: and the solder ring of clean surface is laid on plate, binder is sprayed on solder ring using atomizing lance, or Solder ring is placed in bobbing machine by person, the spraying adhesive on vibration solder ring.
The concrete mode of dipping are as follows: the solder ring of clean surface is completely immersed in and is prepared in binder, then from binder It takes out, until there is no until binder drippage, it is viscous that solder ring soaking time should be such that the solder ring surface taken out is evenly distributed with Agent is tied, generally 1-10 minutes, this both of which can guarantee that solder ring surface uniformly adheres to binder, carry out for brazing flux attachment Prepare.
Brazing flux is attached on the solder ring for speckling with binder: there is the solder ring of binder to turn in brazing flux powder surface Rolling contact, brazing flux are attached on solder ring, obtain the semi-finished product for being attached with brazing flux.
The brazing flux is the corresponding FB105 brazing flux of silver-base solder.Preferred brazing flux is needed by micronization processes, and refinement can adopt With planetary ball mill ball milling 24 hours, crosses 200 mesh screens and obtain.
The solder ring is contacted with the rolling of brazing flux can put into a centrifuge rotation by mixing solder ring and brazing flux It realizes.Preferably for usable low speed centrifuge to rotating after solder ring and brazing flux mixing, revolving speed is not higher than 500 turns/min. It can make each solder ring surface sufficiently using rolling contact and brazing flux contact, keep surface attachment brazing flux uniform, utilize solder The rolling of ring, which is beaten, makes surface brazing flux layer more consolidation, further improves the adhesiveness of brazing flux.
Coating weld-ring is fixed-type: in order to guarantee the adhesion property of coating weld-ring coating, and producing the medicine of dimensionally stable The assembly of skin weld-ring adaptation client.It needs to polish coating weld-ring surface of semi-finished.It is preferably viscous in order to have brazing flux Attached performance can heat coating weld-ring semi-finished product, 40-100 DEG C of heating temperature.
Polishing can be by being put into the shake of three-D lapping machine by coating weld-ring semi-finished product and with ball milling pearl (polishing pearl) Dynamic grinding realizes that the mass ratio of ball milling pearl and coating weld-ring semi-finished product is 1:2 to 1:1.To keep coating weld-ring surface coating uniform Hot wind can ground while be blown into densification, and hot blast temperature control is 40-100 DEG C.
Preferably, the ball milling pearl is the half that zirconium oxide ball milling pearl diameter is coating weld-ring internal diameter, and ball milling pearl can To pass through coating weld-ring inner ring, polishing effect can be realized to coating weld-ring Internal and external cycle surface synchronization.Ball milling pearl and coating weld-ring During vibration, the coating layer on ball milling pearl and coating weld-ring surface is collided, so that brazing flux is further compacted, improves the adherency of brazing flux Property, reduce loss late.
Coating weld-ring provided by the invention and preparation method thereof, simple for structure, coating cohesive force is strong, shakes by three-D Appearance uniform is fine and close after grinder processing, and adhesiveness and thickness stability are good, and coating weld-ring is easily assembled and uses.
Specific embodiment
Embodiment 1:
1) by polyurethane and butyl acetate 3, acetone 3, dimethyl carbonate is mixed by the mass ratio of 85%:3%:3%:9%, is heated to 80 DEG C stirring be binder;
2) solder ring is impregnated in a binder, immersion is taken out after five minutes;
3) solder ring and FB105 brazing flux are poured into slow-speed of revolution centrifuge, brazing flux quality is 1/10th of solder, and centrifuge exists It is run 3 minutes under 500 revs/min of revolving speed;
4) semi-finished product (coating weld-ring semi-finished product, similarly hereinafter) are put into ternary time lapping machine, zirconium oxide ball milling pearl, ball milling is added The quality of pearl is the half of solder quality, is blown into hot wind, takes out after five minutes.
Embodiment 2:
1) polyurethane and acetone are synthesized into binder by the mass ratio of 90%:10% and stirred evenly;
2) solder ring is placed in bobbing machine, the binder prepared is sprayed into while starting bobbing machine, is taken out after five minutes;
3) solder ring and FB105 brazing flux are poured into slow-speed of revolution centrifuge, brazing flux quality is 1/10th of solder quality, centrifugation Machine is run 3 minutes under 500 revs/min of revolving speed;
4) semi-finished product are put into ternary time lapping machine, zirconium oxide ball milling pearl is added, the quality of ball milling pearl is solder ring quality Half, be blown into hot wind, take out after five minutes.
Embodiment 3:
1) polyurethane and dimethyl carbonate are synthesized into binder by the mass ratio of 85%:15%;
2) solder ring is impregnated in a binder, immersion is taken out after five minutes;
3) solder ring and FB105 brazing flux are poured into slow-speed of revolution centrifuge, brazing flux quality is 1/5th of solder quality, centrifugation Machine is run 3 minutes under 500 revs/min of revolving speed;
4) semi-finished product are put into ternary time lapping machine, zirconium oxide ball milling pearl is added, the quality of ball milling pearl is equal with for solder Quality is blown into hot wind, takes out after five minutes.
The simple deformation or combination of all present techniques features and technical solution, it is considered that fall into the protection model of the application It encloses.

Claims (12)

1. a kind of coating weld-ring, including solder and brazing flux, it is characterized in that: the solder is annular in shape, brazing flux is by the viscous of solder surface Knot agent is bonded on solder, forms one layer of uniform coating on solder surface.
2. coating weld-ring according to claim 1, it is characterized in that: the binder is the mixture of polyurethane and diluent, Diluent is one of butyl acetate, acetone, dimethyl carbonate or a variety of, and wherein polyurethane accounts for the 80- of binder gross mass 90%, diluent accounts for the 10-20% of binder gross mass.
3. coating weld-ring preparation method according to claim 1 or 2, it is characterized in that the following steps are included:
Solder surface forms uniform adhesive layer;
Brazing flux is bonded in composition coating weld-ring semi-finished product on the solder for speckle with binder;
It is fixed-type that heating polishing is carried out to coating weld-ring semi-finished product.
4. the preparation method of coating weld-ring according to claim 3, it is characterized in that: the even adhesion oxidant layer on the solder surface It is to be formed by spraying or dipping.
5. the preparation method of coating weld-ring according to claim 4, it is characterized in that: the spraying method are as follows: use atomization spray Binder is sprayed on the solder ring under static or vibrational state by rifle.
6. the preparation method of coating weld-ring according to claim 4, it is characterized in that: the dipping mode are as follows: by clean surface Solder ring be completely immersed in binder, solder ring soaking time be 1-10 minutes.
7. the preparation method of coating weld-ring according to claim 3, the brazing flux is bonded on the solder for speckle with binder and walks Suddenly include: that the solder that surface speckles with binder is placed in brazing flux powder contact of rolling, be attached to brazing flux on solder.
8. the preparation method of coating weld-ring according to claim 7, it is characterized in that: the solder of the surface treating adhesive is in brazing flux Middle rolling contact procedure is mixed by the solder and brazing flux powder that surface is speckled with to binder, is put into a centrifuge rotation and is realized.
9. the preparation method of coating weld-ring according to claim 3, it is characterized in that: coating weld-ring semi-finished product heating polishing Fixed-type step includes: that coating weld-ring semi-finished product, ball milling pearl are put into lapping machine vibration grinding;In the same of vibration grinding When be blown into hot wind, hot blast temperature control is 40-100 DEG C.
10. the preparation method of coating weld-ring according to claim 9, it is characterized in that: the ball milling pearl and coating weld-ring half The mass ratio of finished product is 1:2 to 1:1.
11. the preparation method of coating weld-ring according to claim 9, it is characterized in that: the ball milling pearl is zirconium oxide ball milling Pearl.
12. the preparation method of coating weld-ring according to claim 9, it is characterized in that: the ball milling pearl diameter is coating weldering The half of ring internal diameter.
CN201811187577.2A 2018-10-12 2018-10-12 Coating welding ring and preparation method thereof Active CN109483082B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111230359A (en) * 2020-03-09 2020-06-05 浙江新锐焊接科技股份有限公司 Bonding system for brazing flux and application thereof
CN114799617A (en) * 2022-05-20 2022-07-29 南京航空航天大学 Smokeless coating brazing filler metal and preparation method thereof

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111230359A (en) * 2020-03-09 2020-06-05 浙江新锐焊接科技股份有限公司 Bonding system for brazing flux and application thereof
CN114799617A (en) * 2022-05-20 2022-07-29 南京航空航天大学 Smokeless coating brazing filler metal and preparation method thereof

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