CN109468877A - A kind of temperature change anti-counterfeit paint and warm change anti-counterfeiting paper - Google Patents
A kind of temperature change anti-counterfeit paint and warm change anti-counterfeiting paper Download PDFInfo
- Publication number
- CN109468877A CN109468877A CN201811190175.8A CN201811190175A CN109468877A CN 109468877 A CN109468877 A CN 109468877A CN 201811190175 A CN201811190175 A CN 201811190175A CN 109468877 A CN109468877 A CN 109468877A
- Authority
- CN
- China
- Prior art keywords
- temperature
- parts
- color
- mark
- weight ratio
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/40—Coatings with pigments characterised by the pigments siliceous, e.g. clays
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/42—Coatings with pigments characterised by the pigments at least partly organic
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/54—Starch
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/58—Polymers or oligomers of diolefins, aromatic vinyl monomers or unsaturated acids or derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/66—Coatings characterised by a special visual effect, e.g. patterned, textured
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/40—Agents facilitating proof of genuineness or preventing fraudulent alteration, e.g. for security paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Paper (AREA)
Abstract
The present invention relates to anti-counterfeiting paper technical fields, become anti-counterfeit paint more particularly to a kind of temperature and temperature becomes anti-counterfeiting paper, be made of the following raw material: amylan, styrene-butadiene latex, wheaten starch, kaolin, resin color-developing agent, dispersing agent, defoaming agent, piece alkali, warm variable pigments and water.Temperature of the invention becomes anti-counterfeiting paper and has the advantages that 1, tool is personalized, the mark such as unique text, pattern.2, when temperature is higher than 50 DEG C and is lower than 150 DEG C, personalized mark can change color, and when temperature is fallen after rise to 50 degree or less, the mark for changing color restores native color again, repeatable to verify.3, it is identified with scrapings such as nail, coins or when temperature is more than 150 DEG C, mark can change color and even if temperature falls the mark to have changed colour to room temperature after rise and can not become native color again again.4, compared with existing temperature becomes anti-counterfeiting paper, there is better anti-aging property, the holding time, remote super existing temperature became anti-counterfeiting paper.
Description
Technical field
The present invention relates to anti-counterfeiting paper technical fields, and in particular to a kind of temperature change anti-counterfeit paint and warm change anti-counterfeiting paper.
Background technique
False proof bill is mainly completed by body paper manufacture, coating waste water, printing three phases.If the above three stage all
There is preferable anti-counterfeiting technology and form composite anti-fake, antifalse effect will be best, because fake producer will crack composite anti-fake skill
Art must just get together many-sided talent simultaneously, grasp multiple technologies, possess a variety of equipments.So, the movement of fraud adds
Greatly, it is easy exposure, fraud cost substantial increase, or even is schemed without benefit, and then reduce the generation of imitation behavior.
In the prior art, only watermark, safe line technology in the paper making process, the very high vacation of fidelity had occurred in the former
Ticket, the latter's cost are very high, it is difficult to practical；In printing stage, it is commercially available everywhere that various smooth alternating temperatures become fluorescent inks, printing house it is extremely more and
Keep printing antifalse effect poor；Currently, temporarily without the anti-counterfeit paint of high technology content.
Due to the counterfeit raising with the relevant technologies, the paper products such as bill, marketable securities, certificate certificate, mark identify
Anti-counterfeiting technology requires also higher and higher, in order to meet this requirement, increases before paper articles print and is coated with a kind of the anti-fake of high-tech
Coating becomes current urgent problem to be solved.
Application No. is 201210115356.0 Chinese invention patents to disclose a kind of coloured hidden change pattern anti-fake painting of paper
Material and its manufacturing method, prepare the component that raw material includes quality proportioning as described below: 2~6 parts of precipitated calcium carbonate；Atlapulgite
3.5~8.5 parts；15~25 parts of PD amylan；1.7~7.5 parts of defoaming agent；7.5~12.5 parts of wheaten starch；Resin color-developing agent 2
~6 parts；7.5~12.5 parts of styrene-butadiene latex；2~6 parts of microcapsules colour former；0.02~0.06 part of fluorescer；Temperature becomes material 4~8
Part；26~36 parts of water.Above-mentioned configured coating is applied on paper, and forms coloured hidden change pattern anti-fake paper, is had at this time
The hidden color for becoming pattern and becoming material in temperature of color, it is heated reach certain temperature when, pattern becomes colorless, and restores original again after cooling
Colored pattern, color change are obvious and rapid；If applying certain pressure at coloured hidden change pattern, which can show hidden change color
Pattern, but at pattern herein will not variation with temperature and change colour, and do not apply stressed place and then restore original colored pattern.
Although the patent can achieve preferable antifalse effect, but the anti-counterfeit paint is there are still discoloring temperature range is relatively narrow,
The defects of anti-aging property is poor, and the holding time is shorter needs further to be improved.
Summary of the invention
In order to overcome shortcoming and defect existing in the prior art, the purpose of the present invention is to provide a kind of temperature to become anti-fake painting
Material and temperature become anti-counterfeiting paper.
The purpose of the invention is achieved by the following technical solution: a kind of temperature change anti-counterfeit paint, by following weight percent
Raw material is made:
Preferably, it is made of the raw material of following weight percent:
Preferably, the mixture that the temperature variable pigments are made of red pigment and blue pigment with weight ratio 1:2-3.
Preferably, the color change interval of the temperature variable pigments is 50-150 DEG C.
Preferably, the styrene-butadiene latex is carboxylic styrene butadiene latex.More preferably, the carboxylic styrene butadiene latex by weighing as follows
The raw material of amount part is made: 30-50 parts of butadiene, 40-60 parts of styrene, 1-5 parts of unsaturated carboxylic acid function monomer, vinyl insatiable hunger
With 1-5 parts of amide, 1-2 parts of vinyl unsaturation cross-linking monomer, 1-3 parts of maleic acid glycol ester, nano chitin 1-5
Part, 1-3 parts of amino resins, 0.5-2.5 parts of composite emulsifier, 0.5-2.5 parts of polymer protection glue, 0.5-2.5 parts of initiator, chela
0.5-1.5 parts of mixture, 0.5-1.5 parts of pH buffer, 0.5-1.5 parts of molecular weight regulator, 0.5-1.5 parts of terminator and deionization
100-200 parts of water.
Carboxylic styrene butadiene latex of the invention is by using above-mentioned raw materials, and the weight proportion of each raw material of strict control, is made
Carboxylic styrene butadiene latex there is preferable ageing resistance, cohesive force and conjunctiva intensity also with higher, mechanical and chemistry is surely
Qualitative good, mobility, storage stability are good.
The unsaturated carboxylic acid function monomer is by methacrylic acid, itaconic acid and maleic anhydride with weight ratio 1.5-2.5:
The mixture of 0.5-1.5:1 composition.The present invention passes through type, compounding and the proportion of strict control unsaturated carboxylic acid function monomer,
It is obtained that there is preferable ageing resistance, cohesive force and conjunctiva intensity also with higher.
The vinyl unsaturated amides are by Methacrylamide, N, N- dimethylacrylamide and N- methylol propylene
The mixture that amide is formed with weight ratio 1-2:0.8-1.2:1.The present invention passes through the kind of strict control vinyl unsaturated amides
The adhesion strength of monomer can be improved in class, compounding and proportion, improves the stability and ageing resistance of carboxylic styrene butadiene latex.
The vinyl unsaturation cross-linking monomer is isobornyl methacrylate, hydroxyethyl methacrylate and methyl
The mixture that glycidyl acrylate is formed with weight ratio 1:0.4-0.8:0.2-0.6.The present invention passes through strict control ethylene
Type, compounding and the proportion of base unsaturation cross-linking monomer, can be improved the adhesion strength of monomer, improve the steady of carboxylic styrene butadiene latex
Qualitative and ageing resistance.
The mixing that the composite emulsifier is made of anion emulsifier and nonionic emulsifier with weight ratio 1:1-2
Object.The present invention passes through type, compounding and the proportion of strict control composite emulsifier, and emulsifying effectiveness is good, and carboxyl fourth can be improved
The stability of benzene latex.
The anion emulsifier is by neopelex, lauryl sodium sulfate and dodecyl succinate sodium
The mixture formed with weight ratio 2-4:1-2:1.The present invention passes through the type of strict control anion emulsifier, compounds and match
Than emulsifying effectiveness is good, and the stability of carboxylic styrene butadiene latex can be improved.
The nonionic emulsifier is to be added by ethoxymer distribution for the nonylphenol polyoxyethylene ether of 5-20, ethylene oxide
At the Brij-721 that number is 5-20 and with sorbitan fatty acid ester or with weight ratio 1:0.8-1.2:1.4-
The mixture of 2.2 compositions.The present invention passes through type, compounding and the proportion of strict control nonionic emulsifier, and emulsifying effectiveness is good,
The stability of carboxylic styrene butadiene latex can be improved.
The polymer protection glue is by carrageenan, guar gum and locust bean gum with weight ratio 1:0.4-0.8:0.8-1.2
The mixture of composition.The present invention passes through type, compounding and the proportion of strict control polymer protection glue, and Carboxy can be improved
The cohesive force and conjunctiva intensity of latex.
The initiator is by sodium peroxydisulfate, cumyl peroxide and azodiisobutyronitrile with weight ratio 1-2:0.8-
1.2:1 the mixture of composition.The present invention passes through type, compounding and the proportion of strict control initiator, and initiation effect is good, solidification
Speed is fast.
The chelating agent is made of disodium ethylene diamine tetraacetate and tetrasodium ethylenediamine tetraacetate with weight ratio 0.5-1.5:1
Mixture.The present invention passes through type, compounding and the proportion of strict control chelating agent, can improve the dispersion of carboxylic styrene butadiene latex
Performance.
The mixture that the pH buffer is made of methyl silanol potassium and methyl silicon sodium alcoholate with weight ratio 1-2:1.This hair
Bright type, compounding and proportion by strict control pH buffer, the pH-value of adjustable reaction system.
The molecular weight regulator be tert-dodecylmercaotan, 3- mercaptopropionic acid ethyl hexyl alcohol ester and dimethyl -2 4,4-,
The mixture that 4- diphenyl -1- butylene is formed with weight ratio 1.4-2.2:0.5-1.5:1.The present invention passes through strict control molecular weight
Type, compounding and the proportion of regulator, can control the molecular weight of carboxylic styrene butadiene latex, have carboxylic styrene butadiene latex obtained
Preferable ageing resistance, cohesive force and conjunctiva intensity also with higher.
The terminator be by N- isopropylhydroxyla, monoalkyl dithiocarbamate salt and Sodium Sulphate Nine Hydroxide with weight
Measure the mixture formed than 0.8-1.2:0.5-1.5:1.The present invention passes through type, compounding and the proportion of strict control terminator,
Carboxylic styrene butadiene latex has preferable ageing resistance, and cohesive force and conjunctiva intensity also with higher can control carboxyl fourth
The molecular weight of benzene latex makes carboxylic styrene butadiene latex obtained have a preferable ageing resistance, cohesive force also with higher with
Conjunctiva intensity.
Preferably, the resin color-developing agent is benzyl zinc salicylate.
Preferably, the dispersing agent is polyacrylamide.
Preferably, the defoaming agent is organic silicon defoamer.More preferably, the organic silicon defoamer is by following weight
The raw material of part is made: 20-40 parts of containing hydrogen silicone oil, 10-30 parts of polymethylphenyl siloxane fluid, 5-15 parts of heptamethyltrisiloxane, polyoxypropylene
It is 10-20 parts of polyethers, 5-15 parts of graphene oxide modification organic silicon oil, 4-8 parts of hydrophobic silicic aerogels, 3-7 parts of polyethyl acrylate, complete
2-6 parts of fluorine octanol, 5-15 parts of emulsifier, 0.5-1.5 parts of coupling agent, 0.5-1.5 parts of thickener and 100-200 parts of deionized water.
Organic silicon defoamer of the invention is by using above-mentioned raw materials, and the weight proportion of each raw material of strict control, is made
Organic silicon defoamer defoaming power it is strong, can not only effectively abolish the foam generated, and foam can be inhibited significantly,
The generation of foam is prevented, also has many advantages, such as that antifoaming speed is fast, the inhibition bubble time is long, dosage is few, stability is good, non-toxic and tasteless.
The emulsifier is by fatty alcohol polyoxyethylene ether, neopelex and poly- naphthalene formaldehyde sulfonate salt with weight
Measure the mixture formed than 2-4:0.5-1.5:1.The present invention passes through type, compounding and the proportion of strict control emulsifier, cream
It is good to change effect, the stability of organic silicon defoamer can be improved.
The coupling agent is by γ-glycidyl ether oxygen propyl trimethoxy silicane, γ-methacryloxypropyl three
Methoxy silane and three isopropoxy silane of γ-methacryloxypropyl are formed with weight ratio 0.4-0.8:1:0.5-1.5
Mixture.The present invention passes through type, compounding and the proportion of strict control coupling agent, and the weather-proof of organic silicon defoamer can be improved
Property, improve dispersibility.
The thickener is by methylcellulose, hydroxyethyl cellulose and hydroxypropyl methyl cellulose with weight ratio 1-2:
The mixture of 0.5-1.5:1 composition.The present invention passes through type, compounding and the proportion of strict control thickener, and thickening effect is good,
The stability of machine silicon defoaming agent can be improved.
A kind of temperature change anti-counterfeiting paper, it is obtained using temperature change anti-counterfeit paint described above that the temperature becomes anti-counterfeiting paper.
Preferably, when temperature is higher than 50 DEG C and is lower than 150 DEG C, anti-counterfeiting mark can change color；When temperature is fallen after rise to 50
When below degree, the anti-counterfeiting mark for changing color restores native color, and repeatable verifying again；Scrape anti-counterfeiting mark or when temperature is more than
At 150 DEG C, anti-counterfeiting mark can change color, and even if temperature falls the mark to have changed colour to room temperature after rise and can not become former face again again
Color.
The beneficial effects of the present invention are: temperature of the invention becomes anti-counterfeiting paper and has the advantages that 1, tool is personalized, unique
The mark such as text, pattern.2, when temperature is higher than 50 DEG C and is lower than 150 DEG C, personalized mark can change color (such as by peach
Red becomes hyacinthine or red by blue purpling), and when temperature is fallen after rise to 50 degree or less, the mark for changing color is restored again
Native color repeats verifying.3, with the scrapings such as nail, coin identify or when temperature is more than 150 DEG C, mark can change color and
Even if temperature falls the mark to have changed colour to room temperature after rise can not become native color again again.4, compared with existing temperature becomes anti-counterfeiting paper, have
Better anti-aging property, the holding time, remote super existing temperature became anti-counterfeiting paper.
Specific embodiment
For the ease of the understanding of those skilled in the art, below with reference to embodiment, the present invention is further illustrated, real
The content that the mode of applying refers to not is limitation of the invention.
Embodiment 1
A kind of temperature change anti-counterfeit paint, is made of the raw material of following weight percent:
The mixture that the temperature variable pigments are made of red pigment and blue pigment with weight ratio 1:2.
The color change interval of the temperature variable pigments is 50-150 DEG C.
The styrene-butadiene latex is carboxylic styrene butadiene latex.
The resin color-developing agent is benzyl zinc salicylate.
The dispersing agent is polyacrylamide.
The defoaming agent is organic silicon defoamer.
A kind of temperature change anti-counterfeiting paper, it is obtained using temperature change anti-counterfeit paint described above that the temperature becomes anti-counterfeiting paper.
When temperature is higher than 50 DEG C and is lower than 150 DEG C, anti-counterfeiting mark can change color；When temperature is fallen after rise to 50 degree or less
When, the anti-counterfeiting mark for changing color restores native color, and repeatable verifying again；Scrape anti-counterfeiting mark or when temperature is more than 150 DEG C
When, anti-counterfeiting mark can change color, and even if temperature falls the mark to have changed colour to room temperature after rise and can not become native color again again.
Embodiment 2
The present embodiment and above-described embodiment 1 the difference is that: a kind of temperature change anti-counterfeit paint, by following weight percent
Raw material be made:
The mixture that the temperature variable pigments are made of red pigment and blue pigment with weight ratio 1:2.2.
Embodiment 3
The present embodiment and above-described embodiment 1 the difference is that: a kind of temperature change anti-counterfeit paint, by following weight percent
Raw material be made:
The mixture that the temperature variable pigments are made of red pigment and blue pigment with weight ratio 1:2.4.
Embodiment 4
The present embodiment and above-described embodiment 1 the difference is that: a kind of temperature change anti-counterfeit paint, by following weight percent
Raw material be made:
The mixture that the temperature variable pigments are made of red pigment and blue pigment with weight ratio 1:2.8.
Embodiment 5
The present embodiment and above-described embodiment 1 the difference is that: a kind of temperature change anti-counterfeit paint, by following weight percent
Raw material be made:
The mixture that the temperature variable pigments are made of red pigment and blue pigment with weight ratio 1:3.
Embodiment 6
The present embodiment and above-described embodiment 1 the difference is that: the carboxylic styrene butadiene latex by following parts by weight original
Material is made: 30 parts of butadiene, 40 parts of styrene, 1 part of unsaturated carboxylic acid function monomer, 1 part of vinyl unsaturated amides, vinyl
1 part of unsaturated cross-linking monomer, 1 part of maleic acid glycol ester, 1 part of nano chitin, 1 part of amino resins, composite emulsifier
0.5 part, 0.5 part of polymer protection glue, 0.5 part of initiator, 0.5 part of chelating agent, 0.5 part of pH buffer, molecular weight regulator 0.5
Part, 0.5 part of terminator and 100 parts of deionized water.
The unsaturated carboxylic acid function monomer is by methacrylic acid, itaconic acid and maleic anhydride with weight ratio 1.5:0.5:
The mixture of 1 composition；The vinyl unsaturated amides are by Methacrylamide, N, N- dimethylacrylamide and N- hydroxyl first
The mixture that base acrylamide is formed with weight ratio 1:0.8:1；The vinyl unsaturation cross-linking monomer is methacrylic acid
The mixture that isobornyl thiocyanoacetate, hydroxyethyl methacrylate and glycidyl methacrylate are formed with weight ratio 1:0.4:0.2.
The mixture that the composite emulsifier is made of anion emulsifier and nonionic emulsifier with weight ratio 1:1；
The anion emulsifier is by neopelex, lauryl sodium sulfate and dodecyl succinate sodium with weight ratio
The mixture of 2:1:1 composition；The nonionic emulsifier be by ethoxymer distribution be 5 nonylphenol polyoxyethylene ether, ring
Oxidative ethane adduct number be 5 Brij-721 and with sorbitan fatty acid ester or with weight ratio 1:0.8:1.4
The mixture of composition.
The polymer protection glue is made of carrageenan, guar gum and locust bean gum with weight ratio 1:0.4:0.8 mixed
Close object；The initiator is made of sodium peroxydisulfate, cumyl peroxide and azodiisobutyronitrile with weight ratio 1:0.8:1
Mixture；The chelating agent is made of disodium ethylene diamine tetraacetate and tetrasodium ethylenediamine tetraacetate with weight ratio 0.5:1 mixed
Close object.
The mixture that the pH buffer is made of methyl silanol potassium and methyl silicon sodium alcoholate with weight ratio 1:1；Described point
Son amount regulator is tert-dodecylmercaotan, 3- mercaptopropionic acid ethyl hexyl alcohol ester and 4,4- dimethyl -2,4- diphenyl -1- butylene
The mixture formed with weight ratio 1.4:0.5:1；The terminator is by N- isopropylhydroxyla, monoalkyl dithiocarbamate
The mixture formed in salt and Sodium Sulphate Nine Hydroxide with weight ratio 0.8:0.5:1.
The organic silicon defoamer is made of the raw material of following parts by weight: 20 parts of containing hydrogen silicone oil, 10 parts of polymethylphenyl siloxane fluid, seven
5 parts of methyl trisiloxanes, 10 parts of polyoxypropylene polyether, 5 parts of graphene oxide modification organic silicon oil, 4 parts of hydrophobic silicic aerogels, poly- third
3 parts of olefin(e) acid ethyl ester, 2 parts of perfluorooctanol, 5 parts of emulsifier, 0.5 part of coupling agent, 0.5 part of thickener and 100 parts of deionized water.
The emulsifier is by fatty alcohol polyoxyethylene ether, neopelex and poly- naphthalene formaldehyde sulfonate salt with weight
Measure the mixture formed than 2:0.5:1；The coupling agent is by γ-glycidyl ether oxygen propyl trimethoxy silicane, γ-methyl
Acryloyloxypropyltrimethoxysilane and three isopropoxy silane of γ-methacryloxypropyl are with weight ratio 0.4:1:
The mixture of 0.5 composition；The thickener is by methylcellulose, hydroxyethyl cellulose and hydroxypropyl methyl cellulose with weight
Than the mixture of 1:0.5:1 composition.
Embodiment 7
The present embodiment and above-described embodiment 2 the difference is that: the carboxylic styrene butadiene latex by following parts by weight original
Material is made: 35 parts of butadiene, 45 parts of styrene, 2 parts of unsaturated carboxylic acid function monomer, 2 parts of vinyl unsaturated amides, vinyl
1.2 parts of unsaturated cross-linking monomer, 1.5 parts of maleic acid glycol ester, 2 parts of nano chitin, 1.5 parts of amino resins, compounding
1 part of emulsifier, 1 part of polymer protection glue, 1 part of initiator, 0.8 part of chelating agent, 0.8 part of pH buffer, molecular weight regulator 0.8
Part, 0.8 part of terminator and 120 parts of deionized water.
The unsaturated carboxylic acid function monomer is by methacrylic acid, itaconic acid and maleic anhydride with weight ratio 1.8:0.8:
The mixture of 1 composition；The vinyl unsaturated amides are by Methacrylamide, N, N- dimethylacrylamide and N- hydroxyl first
The mixture that base acrylamide is formed with weight ratio 1.2:0.9:1；The vinyl unsaturation cross-linking monomer is metering system
The mixing that sour isobornyl thiocyanoacetate, hydroxyethyl methacrylate and glycidyl methacrylate are formed with weight ratio 1:0.5:0.3
Object.
The mixing that the composite emulsifier is made of anion emulsifier and nonionic emulsifier with weight ratio 1:1.2
Object；The anion emulsifier is by neopelex, lauryl sodium sulfate and dodecyl succinate sodium with weight
Measure the mixture formed than 2.5:1.2:1；The nonionic emulsifier is the polyoxyethylene nonyl phenyl second for being 8 by ethoxymer distribution
Alkene ether, ethoxymer distribution be 8 Brij-721 and with sorbitan fatty acid ester or with weight ratio 1:
The mixture of 0.9:1.6 composition.
The polymer protection glue is made of carrageenan, guar gum and locust bean gum with weight ratio 1:0.5:0.9 mixed
Close object；The initiator is made of sodium peroxydisulfate, cumyl peroxide and azodiisobutyronitrile with weight ratio 1.2:0.9:1
Mixture；The chelating agent is made of disodium ethylene diamine tetraacetate and tetrasodium ethylenediamine tetraacetate with weight ratio 0.8:1
Mixture.
The mixture that the pH buffer is made of methyl silanol potassium and methyl silicon sodium alcoholate with weight ratio 1.2:1；It is described
Molecular weight regulator is tert-dodecylmercaotan, 3- mercaptopropionic acid ethyl hexyl alcohol ester and 4,4- dimethyl -2,4- diphenyl -1- fourth
The mixture that alkene is formed with weight ratio 1.6:0.8:1；The terminator is by N- isopropylhydroxyla, two thioamido first of monoalkyl
The mixture formed in hydrochlorate and Sodium Sulphate Nine Hydroxide with weight ratio 0.9:0.8:1.
The organic silicon defoamer is made of the raw material of following parts by weight: 25 parts of containing hydrogen silicone oil, 15 parts of polymethylphenyl siloxane fluid, seven
8 parts of methyl trisiloxanes, 12 parts of polyoxypropylene polyether, 8 parts of graphene oxide modification organic silicon oil, 5 parts of hydrophobic silicic aerogels, poly- third
4 parts of olefin(e) acid ethyl ester, 3 parts of perfluorooctanol, 8 parts of emulsifier, 0.8 part of coupling agent, 0.8 part of thickener and 120 parts of deionized water.
The emulsifier is by fatty alcohol polyoxyethylene ether, neopelex and poly- naphthalene formaldehyde sulfonate salt with weight
Measure the mixture formed than 2.5:0.8:1；The coupling agent is by γ-glycidyl ether oxygen propyl trimethoxy silicane, γ-first
Base acryloyloxypropyltrimethoxysilane and three isopropoxy silane of γ-methacryloxypropyl are with weight ratio 0.5:
1:0.8 the mixture of composition；The thickener is by methylcellulose, hydroxyethyl cellulose and hydroxypropyl methyl cellulose with weight
Measure the mixture formed than 1.2:0.8:1.
Embodiment 8
The present embodiment and above-described embodiment 3 the difference is that: the carboxylic styrene butadiene latex by following parts by weight original
Material is made: 40 parts of butadiene, 50 parts of styrene, 3 parts of unsaturated carboxylic acid function monomer, 3 parts of vinyl unsaturated amides, vinyl
1.5 parts of unsaturated cross-linking monomer, 2 parts of maleic acid glycol ester, 3 parts of nano chitin, 2 parts of amino resins, compound emulsion
1.5 parts of agent, 1.5 parts of polymer protection glue, 1.5 parts of initiator, 1 part of chelating agent, 1 part of pH buffer, 1 part of molecular weight regulator,
1 part and 150 parts of deionized water of terminator.
The unsaturated carboxylic acid function monomer is by methacrylic acid, itaconic acid and maleic anhydride with weight ratio 2:1:1 group
At mixture；The vinyl unsaturated amides are by Methacrylamide, N, N- dimethylacrylamide and N- methylol
The mixture that acrylamide is formed with weight ratio 1.5:1:1；The vinyl unsaturation cross-linking monomer is that methacrylic acid is different
The mixture that norbornene ester, hydroxyethyl methacrylate and glycidyl methacrylate are formed with weight ratio 1:0.6:0.4.
The mixing that the composite emulsifier is made of anion emulsifier and nonionic emulsifier with weight ratio 1:1.5
Object；The anion emulsifier is by neopelex, lauryl sodium sulfate and dodecyl succinate sodium with weight
Measure the mixture formed than 3:1.5:1；The nonionic emulsifier is the polyoxyethylene nonyl phenyl second for being 12 by ethoxymer distribution
Alkene ether, ethoxymer distribution be 12 Brij-721 and with sorbitan fatty acid ester or with weight ratio 1:
1:1.8 the mixture of composition.
The mixing that the polymer protection glue is made of carrageenan, guar gum and locust bean gum with weight ratio 1:0.6:1
Object；The initiator is made of sodium peroxydisulfate, cumyl peroxide and azodiisobutyronitrile with weight ratio 1.5:1:1 mixed
Close object；The mixture that the chelating agent is made of disodium ethylene diamine tetraacetate and tetrasodium ethylenediamine tetraacetate with weight ratio 1:1.
The mixture that the pH buffer is made of methyl silanol potassium and methyl silicon sodium alcoholate with weight ratio 1.5:1；It is described
Molecular weight regulator is tert-dodecylmercaotan, 3- mercaptopropionic acid ethyl hexyl alcohol ester and 4,4- dimethyl -2,4- diphenyl -1- fourth
The mixture that alkene is formed with weight ratio 1.8:1:1；The terminator is by N- isopropylhydroxyla, monoalkyl dithiocarbamate
The mixture formed in salt and Sodium Sulphate Nine Hydroxide with weight ratio 1:1:1.
The organic silicon defoamer is made of the raw material of following parts by weight: 30 parts of containing hydrogen silicone oil, 20 parts of polymethylphenyl siloxane fluid, seven
10 parts of methyl trisiloxanes, 10 parts of graphene oxide modification organic silicon oil, 6 parts of hydrophobic silicic aerogels, gathers 15 parts of polyoxypropylene polyether
5 parts of ethyl acrylate, 4 parts of perfluorooctanol, 10 parts of emulsifier, 1 part of coupling agent, 1 part of thickener and 150 parts of deionized water.
The emulsifier is by fatty alcohol polyoxyethylene ether, neopelex and poly- naphthalene formaldehyde sulfonate salt with weight
Measure the mixture formed than 3:1:1；The coupling agent is by γ-glycidyl ether oxygen propyl trimethoxy silicane, γ-methyl-prop
Alkene acryloxypropylethoxysilane trimethoxy silane and three isopropoxy silane of γ-methacryloxypropyl are with weight ratio 0.6:1:1
The mixture of composition；The thickener is by methylcellulose, hydroxyethyl cellulose and hydroxypropyl methyl cellulose with weight ratio
1.5:1:1 the mixture of composition.
Embodiment 9
The present embodiment and above-described embodiment 4 the difference is that: the carboxylic styrene butadiene latex by following parts by weight original
Material is made: 45 parts of butadiene, 55 parts of styrene, 4 parts of unsaturated carboxylic acid function monomer, 4 parts of vinyl unsaturated amides, vinyl
1.8 parts of unsaturated cross-linking monomer, 2.5 parts of maleic acid glycol ester, 4 parts of nano chitin, 2.5 parts of amino resins, compounding
2 parts of emulsifier, 2 parts of polymer protection glue, 2 parts of initiator, 1.2 parts of chelating agent, 1.2 parts of pH buffer, molecular weight regulator 1.2
Part, 1.2 parts of terminator and 180 parts of deionized water.
The unsaturated carboxylic acid function monomer is by methacrylic acid, itaconic acid and maleic anhydride with weight ratio 2.2:1.2:
The mixture of 1 composition；The vinyl unsaturated amides are by Methacrylamide, N, N- dimethylacrylamide and N- hydroxyl first
The mixture that base acrylamide is formed with weight ratio 1.8:1.1:1；The vinyl unsaturation cross-linking monomer is metering system
The mixing that sour isobornyl thiocyanoacetate, hydroxyethyl methacrylate and glycidyl methacrylate are formed with weight ratio 1:0.7:0.5
Object.
The mixing that the composite emulsifier is made of anion emulsifier and nonionic emulsifier with weight ratio 1:1.8
Object；The anion emulsifier is by neopelex, lauryl sodium sulfate and dodecyl succinate sodium with weight
Measure the mixture formed than 3.5:1.8:1；The nonionic emulsifier is the polyoxyethylene nonyl phenyl for being 16 by ethoxymer distribution
Vinethene, ethoxymer distribution be 16 Brij-721 and with sorbitan fatty acid ester or with weight ratio
1:1.1:2 the mixture of composition.
The polymer protection glue is made of carrageenan, guar gum and locust bean gum with weight ratio 1:0.7:1.1 mixed
Close object；The initiator is made of sodium peroxydisulfate, cumyl peroxide and azodiisobutyronitrile with weight ratio 1.8:1.1:1
Mixture；The chelating agent is made of disodium ethylene diamine tetraacetate and tetrasodium ethylenediamine tetraacetate with weight ratio 1.2:1
Mixture.
The mixture that the pH buffer is made of methyl silanol potassium and methyl silicon sodium alcoholate with weight ratio 1.8:1；It is described
Molecular weight regulator is tert-dodecylmercaotan, 3- mercaptopropionic acid ethyl hexyl alcohol ester and 4,4- dimethyl -2,4- diphenyl -1- fourth
The mixture that alkene is formed with weight ratio 2:1.2:1；The terminator is by N- isopropylhydroxyla, monoalkyl dithiocarbamate
The mixture formed in salt and Sodium Sulphate Nine Hydroxide with weight ratio 1.1:1.2:1.
The organic silicon defoamer is made of the raw material of following parts by weight: 35 parts of containing hydrogen silicone oil, 25 parts of polymethylphenyl siloxane fluid, seven
12 parts of methyl trisiloxanes, 12 parts of graphene oxide modification organic silicon oil, 7 parts of hydrophobic silicic aerogels, gathers 18 parts of polyoxypropylene polyether
6 parts of ethyl acrylate, 5 parts of perfluorooctanol, 12 parts of emulsifier, 1.2 parts of coupling agent, 1.2 parts of thickener and 180 parts of deionized water.
The emulsifier is by fatty alcohol polyoxyethylene ether, neopelex and poly- naphthalene formaldehyde sulfonate salt with weight
Measure the mixture formed than 3.5:1.2:1；The coupling agent is by γ-glycidyl ether oxygen propyl trimethoxy silicane, γ-first
Base acryloyloxypropyltrimethoxysilane and three isopropoxy silane of γ-methacryloxypropyl are with weight ratio 0.7:
1:1.2 the mixture of composition；The thickener is by methylcellulose, hydroxyethyl cellulose and hydroxypropyl methyl cellulose with weight
Measure the mixture formed than 1.8:1.2:1.
Embodiment 10
The present embodiment and above-described embodiment 5 the difference is that: the carboxylic styrene butadiene latex by following parts by weight original
Material is made: 50 parts of butadiene, 60 parts of styrene, 5 parts of unsaturated carboxylic acid function monomer, 5 parts of vinyl unsaturated amides, vinyl
2 parts of unsaturated cross-linking monomer, 3 parts of maleic acid glycol ester, 5 parts of nano chitin, 3 parts of amino resins, composite emulsifier
2.5 parts, 2.5 parts of polymer protection glue, 2.5 parts of initiator, 1.5 parts of chelating agent, 1.5 parts of pH buffer, molecular weight regulator 1.5
Part, 1.5 parts of terminator and 200 parts of deionized water.
The unsaturated carboxylic acid function monomer is by methacrylic acid, itaconic acid and maleic anhydride with weight ratio 2.5:1.5:
The mixture of 1 composition；The vinyl unsaturated amides are by Methacrylamide, N, N- dimethylacrylamide and N- hydroxyl first
The mixture that base acrylamide is formed with weight ratio 2:1.2:1；The vinyl unsaturation cross-linking monomer is methacrylic acid
The mixture that isobornyl thiocyanoacetate, hydroxyethyl methacrylate and glycidyl methacrylate are formed with weight ratio 1:0.8:0.6.
The mixture that the composite emulsifier is made of anion emulsifier and nonionic emulsifier with weight ratio 1:2；
The anion emulsifier is by neopelex, lauryl sodium sulfate and dodecyl succinate sodium with weight ratio
The mixture of 4:2:1 composition；The nonionic emulsifier be by ethoxymer distribution be 20 nonylphenol polyoxyethylene ether, ring
Oxidative ethane adduct number be 20 Brij-721 and with sorbitan fatty acid ester or with weight ratio 1:1.2:2.2
The mixture of composition.
The polymer protection glue is made of carrageenan, guar gum and locust bean gum with weight ratio 1:0.8:1.2 mixed
Close object；The initiator is made of sodium peroxydisulfate, cumyl peroxide and azodiisobutyronitrile with weight ratio 2:1.2:1
Mixture；The chelating agent is made of disodium ethylene diamine tetraacetate and tetrasodium ethylenediamine tetraacetate with weight ratio 1.5:1 mixed
Close object.
The mixture that the pH buffer is made of methyl silanol potassium and methyl silicon sodium alcoholate with weight ratio 1-2:1；It is described
Molecular weight regulator is tert-dodecylmercaotan, 3- mercaptopropionic acid ethyl hexyl alcohol ester and 4,4- dimethyl -2,4- diphenyl -1- fourth
The mixture that alkene is formed with weight ratio 2.2:1.5:1；The terminator is by N- isopropylhydroxyla, two thioamido first of monoalkyl
The mixture formed in hydrochlorate and Sodium Sulphate Nine Hydroxide with weight ratio 1.2:1.5:1.
The organic silicon defoamer is made of the raw material of following parts by weight: 40 parts of containing hydrogen silicone oil, 30 parts of polymethylphenyl siloxane fluid, seven
15 parts of methyl trisiloxanes, 15 parts of graphene oxide modification organic silicon oil, 8 parts of hydrophobic silicic aerogels, gathers 20 parts of polyoxypropylene polyether
7 parts of ethyl acrylate, 6 parts of perfluorooctanol, 15 parts of emulsifier, 1.5 parts of coupling agent, 1.5 parts of thickener and 200 parts of deionized water.
The emulsifier is by fatty alcohol polyoxyethylene ether, neopelex and poly- naphthalene formaldehyde sulfonate salt with weight
Measure the mixture formed than 4:1.5:1；The coupling agent is by γ-glycidyl ether oxygen propyl trimethoxy silicane, γ-methyl
Acryloyloxypropyltrimethoxysilane and three isopropoxy silane of γ-methacryloxypropyl are with weight ratio 0.8:1:
The mixture of 1.5 compositions；The thickener is by methylcellulose, hydroxyethyl cellulose and hydroxypropyl methyl cellulose with weight
Than the mixture of 2:1.5:1 composition.
Temperature of the invention becomes anti-counterfeiting paper when temperature is higher than 50 DEG C and is lower than 150 DEG C, and personalized mark can change color
(such as from pink become hyacinthine or by blue purpling it is red), and when temperature is fallen after rise to 50 degree or less, change the mark of color
Know and restore native color again, repeats verifying.It is identified with scrapings such as nail, coins or when temperature is more than 150 DEG C, mark can change
Color and even if temperature falls the mark to have changed colour to room temperature after rise and can not become native color again again.Compared with existing temperature becomes anti-counterfeiting paper,
With better anti-aging property, the holding time can be improved one times or more compared with existing temperature becomes anti-counterfeiting paper.
Above-described embodiment is the preferable implementation of the present invention, and in addition to this, the present invention can be realized with other way,
Do not depart under the premise of present inventive concept it is any obviously replace it is within the scope of the present invention.
Claims (10)
1. a kind of temperature becomes anti-counterfeit paint, it is characterised in that: be made of the raw material of following weight percent:
2. a kind of temperature according to claim 1 becomes anti-counterfeit paint, it is characterised in that: by the raw material system of following weight percent
At:
3. a kind of temperature according to claim 1 becomes anti-counterfeit paint, it is characterised in that: the temperature variable pigments are by red pigment
The mixture formed with blue pigment with weight ratio 1:2-3.
4. a kind of temperature according to claim 1 becomes anti-counterfeit paint, it is characterised in that: the color change interval of the temperature variable pigments is
50-150℃。
5. a kind of temperature according to claim 1 becomes anti-counterfeit paint, it is characterised in that: the styrene-butadiene latex is carboxy styrene-butadiene rubber
Cream.
6. a kind of temperature according to claim 1 becomes anti-counterfeit paint, it is characterised in that: the resin color-developing agent is benzyl bigcatkin willow
Sour zinc.
7. a kind of temperature according to claim 1 becomes anti-counterfeit paint, it is characterised in that: the dispersing agent is polyacrylamide.
8. a kind of temperature according to claim 1 becomes anti-counterfeit paint, it is characterised in that: the defoaming agent is organosilicon defoaming
Agent.
9. a kind of temperature becomes anti-counterfeiting paper, it is characterised in that: the temperature is become anti-counterfeiting paper and become using the described in any item temperature of claim 1-8
Anti-counterfeit paint is made.
10. a kind of temperature according to claim 9 becomes anti-counterfeiting paper, it is characterised in that: when temperature is higher than 50 DEG C and is lower than 150 DEG C
When, anti-counterfeiting mark can change color；When temperature is fallen after rise to 50 degree or less, the anti-counterfeiting mark for changing color restores native color again,
And repeatable verifying；It scrapes anti-counterfeiting mark or when temperature is more than 150 DEG C, anti-counterfeiting mark can change color, and even if temperature is returned
Room temperature is dropped down onto, the mark to have changed colour can not become native color again again.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811190175.8A CN109468877A (en) | 2018-10-12 | 2018-10-12 | A kind of temperature change anti-counterfeit paint and warm change anti-counterfeiting paper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811190175.8A CN109468877A (en) | 2018-10-12 | 2018-10-12 | A kind of temperature change anti-counterfeit paint and warm change anti-counterfeiting paper |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109468877A true CN109468877A (en) | 2019-03-15 |
Family
ID=65663833
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811190175.8A Pending CN109468877A (en) | 2018-10-12 | 2018-10-12 | A kind of temperature change anti-counterfeit paint and warm change anti-counterfeiting paper |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109468877A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116102923A (en) * | 2022-12-29 | 2023-05-12 | 广东邦固化学科技有限公司 | Temperature-changing anti-counterfeiting coating and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101373183A (en) * | 2008-08-01 | 2009-02-25 | 东莞市天盛特种纸制品有限公司 | Method for detecting non-carbon carbon paper CB surface and CF surface colour development by reference paper |
| CN102677537A (en) * | 2012-04-19 | 2012-09-19 | 东莞市侨盛纸业有限公司 | Anti-counterfeiting coating with colored concealed variable patterns for paper and method for preparing colored anti-counterfeiting coating |
| CN102767116A (en) * | 2012-07-03 | 2012-11-07 | 东莞市侨盛纸业有限公司 | Paint used for three-color watermark security paper and preparation method thereof |
| CN104910714A (en) * | 2015-06-23 | 2015-09-16 | 南昌添丽特实业有限责任公司 | Temperature-changeable microcapsule coating and preparation method thereof |
-
2018
- 2018-10-12 CN CN201811190175.8A patent/CN109468877A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101373183A (en) * | 2008-08-01 | 2009-02-25 | 东莞市天盛特种纸制品有限公司 | Method for detecting non-carbon carbon paper CB surface and CF surface colour development by reference paper |
| CN102677537A (en) * | 2012-04-19 | 2012-09-19 | 东莞市侨盛纸业有限公司 | Anti-counterfeiting coating with colored concealed variable patterns for paper and method for preparing colored anti-counterfeiting coating |
| CN102767116A (en) * | 2012-07-03 | 2012-11-07 | 东莞市侨盛纸业有限公司 | Paint used for three-color watermark security paper and preparation method thereof |
| CN104910714A (en) * | 2015-06-23 | 2015-09-16 | 南昌添丽特实业有限责任公司 | Temperature-changeable microcapsule coating and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116102923A (en) * | 2022-12-29 | 2023-05-12 | 广东邦固化学科技有限公司 | Temperature-changing anti-counterfeiting coating and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR100197341B1 (en) | Redispersible silicon-modified dispersion powder composition, method of manufacturing it and its use | |
| TWI241324B (en) | Composite co-structured or co-adsorbed, mineral or organic filler or pigment compounds and the use thereof | |
| CN101376682B (en) | Modified butyl benzene emulsion and preparation thereof | |
| CN107200807B (en) | A kind of paper nano color paste dispersing agent and preparation method and application | |
| CN104311739B (en) | Organic-silicon-modified styrene-butadiene latex and preparation method thereof | |
| CN103554348B (en) | A kind of polymkeric substance, its preparation method and application | |
| CN101768895A (en) | Styrene-acrylate emulsion type high effective surface sizing agent and preparation method thereof | |
| CN103756601B (en) | Metal(lic)powder tackiness agent and preparation method thereof and wallpaper, textiles | |
| CN104254545B (en) | The aqueous polymer dispersion that can be obtained by the emulsion polymerization that free radical in the presence of lignosulphonates causes | |
| CN1989181B (en) | Novel hydrodispersible waterproofing agent, the preparation thereof, and the use of the same in the field of construction especially in mineral binding agent compositions | |
| CN104693889A (en) | Low-odor water-based ink and preparation method thereof | |
| CN104805732A (en) | Styrene-acrylate emulsion type efficient surface sizing agent and preparing method thereof | |
| CN101806013A (en) | Top coating for coating layer of double-sided coating white board as well as preparation method and application thereof | |
| CN101983268B (en) | Paper coating or binding formulations and methods of making and using same | |
| CN108589343B (en) | Preparation method and application of pigment/organic silicon/polyacrylate nanocapsule coating with multilayer core-shell structure | |
| CN109293814A (en) | A kind of preparation method of the styrene-butadiene latex for papermaking paint | |
| CN109468877A (en) | A kind of temperature change anti-counterfeit paint and warm change anti-counterfeiting paper | |
| CN103321095B (en) | Fluorescent falsification-preventing carbonless copy paper coating and application thereof | |
| CN105315728B (en) | A kind of inorganic water-proof aging resistant coating and preparation method thereof | |
| CN102224174A (en) | Polymer composition | |
| CN103215825B (en) | Printing adhesive of stone paper wallpaper and preparation method of printing adhesive | |
| CN108329416A (en) | A kind of paper mill base dispersant with high efficiency and its preparation method and application | |
| CN107690461B (en) | Polymer for antifouling paint | |
| CN102203193A (en) | Use of aqueous composite-particle dispersions as binders in elastic coatings | |
| CN109293834A (en) | A kind of preparation method of styrene-butadiene latex and products thereof and application |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190315 |