CN109467320A - A kind of on-line coating and film-removing technology of shield glass - Google Patents

A kind of on-line coating and film-removing technology of shield glass Download PDF

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Publication number
CN109467320A
CN109467320A CN201810393386.5A CN201810393386A CN109467320A CN 109467320 A CN109467320 A CN 109467320A CN 201810393386 A CN201810393386 A CN 201810393386A CN 109467320 A CN109467320 A CN 109467320A
Authority
CN
China
Prior art keywords
layer
barrier layer
silver
layers
shield glass
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810393386.5A
Other languages
Chinese (zh)
Inventor
熊斌
卢斌
王艾清
张学庆
肖正红
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
FUYAO GLASS (HUBEI) Co Ltd
Original Assignee
FUYAO GLASS (HUBEI) Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by FUYAO GLASS (HUBEI) Co Ltd filed Critical FUYAO GLASS (HUBEI) Co Ltd
Priority to CN201810393386.5A priority Critical patent/CN109467320A/en
Publication of CN109467320A publication Critical patent/CN109467320A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3644Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the metal being silver
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B11/00Cleaning flexible or delicate articles by methods or apparatus specially adapted thereto
    • B08B11/04Cleaning flexible or delicate articles by methods or apparatus specially adapted thereto specially adapted for plate glass, e.g. prior to manufacture of windshields
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C23/00Other surface treatment of glass not in the form of fibres or filaments
    • C03C23/0075Cleaning of glass
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00Coatings on glass
    • C03C2217/70Properties of coatings
    • C03C2217/78Coatings specially designed to be durable, e.g. scratch-resistant

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Surface Treatment Of Glass (AREA)
  • Laminated Bodies (AREA)

Abstract

A kind of plated film and film-removing technology of shield glass, comprising: S1, carry out on-line coating to shield glass to form film plating layer, film plating layer is single silver-colored structure sheaf, double silver-colored structure sheafs, any one in three silver medal structure sheafs;Single silver structure sheaf includes bottom, barrier layer, Ag layers, barrier layer, top layer, protective layer; double silver structure sheafs include bottom, barrier layer, Ag layers, barrier layer, dielectric layer, barrier layer, Ag layers, barrier layer, top layer and protective layer, and three silver medal structure sheafs include bottom, barrier layer, Ag layers, barrier layer, dielectric layer, barrier layer, Ag layers, barrier layer, dielectric layer, barrier layer, Ag layers, barrier layer, top layer and protective layer;S2, membrane removal is carried out using laser membrane-removing machine in the peripheral region, the region ETC and access card region of shield glass.Technique of the invention can effectively prevent silver layer and be oxidized, and improves the spectral technique index of shield glass, meets the requirement of vehicle glass product.

Description

A kind of on-line coating and film-removing technology of shield glass
Technical field
The present invention relates to coating film on glass fields, on-line coating and membrane removal work more particularly, to a kind of shield glass Skill.
Background technique
As the promotion of the energy conservation and environmental awareness of people and the requirement to the comfort of vehicles seating are higher and higher, Coated glass is applied on the vehicles more and more widely as transparent glass window, is penetrated this is because coated glass has The advantages of visible light and reflection infrared ray, so as to significantly reduce air conditioning energy consumption and improve the comfortable of driver and passenger Degree.Currently, the transparent glass window used on the vehicles is mostly using silver layer as the Silver-based low emissivity plated film glass of infrared reflecting layer Glass, the core material of Silver-based low emissivity coated glass are silver (Ag) layers of one layer or multilayer, but silver-colored (Ag) layer is easy to be rotten Erosion and oxidation.
Summary of the invention
The purpose of the present invention is to the deficiencies in the prior art, provide a kind of shield glass on-line coating and Film-removing technology can effectively prevent silver layer and be oxidized, and improves the spectral technique index of shield glass, meets vehicle glass The requirement of product.
The method of the present invention includes the following steps:
S1, on-line coating is carried out to shield glass to form film plating layer, the film plating layer is single silver-colored structure sheaf, double silver knots Any one in structure layer, three silver medal structure sheafs;
Single silver-colored structure sheaf includes bottom, barrier layer, the Ag layer set gradually outward on front windshield substrate surface, hinders Interlayer, top layer, protective layer;Double silver-colored structure sheaf include the bottom set gradually outward on front windshield substrate surface, Barrier layer, Ag layers, barrier layer, dielectric layer, barrier layer, Ag layers, barrier layer, top layer and protective layer;The three silver medal structure sheaf packet Include the bottom, barrier layer, Ag that are set gradually outward on front windshield substrate surface layer, barrier layer, dielectric layer, barrier layer, Ag layers, barrier layer, dielectric layer, barrier layer, Ag layers, barrier layer, top layer and protective layer;
Wherein, the bottom, barrier layer, dielectric layer, top layer and protective layer be selected from Zn, Sn, Ti, Nb, Zr, Hf, Mg, At least one of Ni, In, Al, Ga, W, Bi metal oxide and its mixture, or selected from Si, Al, Zr, Ti, Y, Hf, Nb, Ta metal nitride or at least one of nitrogen oxides and its mixture;
S2, membrane removal is carried out using laser membrane-removing machine in the region ETC of shield glass and access card region.
Total thicknesses of layers of single silver structure sheaf is 70-100nm.
Total thicknesses of layers of double silver structure sheafs is 180-200nm.
Total thicknesses of layers of three silver medal structure sheafs is 250-300nm.
Compared with prior art, it is oxidized the beneficial effects of the present invention are: can effectively prevent silver layer, improves automobile front wind screen The spectral technique index of glass, meets the requirement of vehicle glass product.
Specific embodiment
Below in conjunction with the embodiment of the present invention, present invention is further described in detail.
Specific embodiment
A kind of on-line coating and film-removing technology of shield glass, comprising the following steps:
S1, on-line coating is carried out to shield glass to form film plating layer, the film plating layer is single silver-colored structure sheaf, double silver knots Any one in structure layer, three silver medal structure sheafs;
Single silver-colored structure sheaf includes bottom, barrier layer, the Ag layer set gradually outward on front windshield substrate surface, hinders Interlayer, top layer, protective layer;Double silver-colored structure sheaf include the bottom set gradually outward on front windshield substrate surface, Barrier layer, Ag layers, barrier layer, dielectric layer, barrier layer, Ag layers, barrier layer, top layer and protective layer;The three silver medal structure sheaf packet Include the bottom, barrier layer, Ag that are set gradually outward on front windshield substrate surface layer, barrier layer, dielectric layer, barrier layer, Ag layers, barrier layer, dielectric layer, barrier layer, Ag layers, barrier layer, top layer and protective layer;
Wherein, the bottom, barrier layer, dielectric layer, top layer and protective layer be selected from Zn, Sn, Ti, Nb, Zr, Hf, Mg, At least one of Ni, In, Al, Ga, W, Bi metal oxide and its mixture, or selected from Si, Al, Zr, Ti, Y, Hf, Nb, Ta metal nitride or at least one of nitrogen oxides and its mixture;
S2, membrane removal is carried out using laser membrane-removing machine in the region ETC of shield glass and access card region.
Total thicknesses of layers of single silver structure sheaf is 70-100nm.
Total thicknesses of layers of double silver structure sheafs is 180-200nm.
Total thicknesses of layers of three silver medal structure sheafs is 250-300nm.
The process ration of the different silver-colored structure sheaf products of table 1
The above-mentioned only present invention preferably feasible embodiment, the non-therefore limitation scope of the present invention, according to above-described embodiment Made various modifications are applied within this technical solution protection scope.

Claims (4)

1. the on-line coating and film-removing technology of a kind of shield glass, it is characterised in that the following steps are included:
S1, on-line coating is carried out to shield glass to form film plating layer, the film plating layer is single silver-colored structure sheaf, double silver knots Any one in structure layer, three silver medal structure sheafs;
Single silver-colored structure sheaf includes bottom, barrier layer, the Ag layer set gradually outward on front windshield substrate surface, hinders Interlayer, top layer, protective layer;Double silver-colored structure sheaf include the bottom set gradually outward on front windshield substrate surface, Barrier layer, Ag layers, barrier layer, dielectric layer, barrier layer, Ag layers, barrier layer, top layer and protective layer;The three silver medal structure sheaf packet Include the bottom, barrier layer, Ag that are set gradually outward on front windshield substrate surface layer, barrier layer, dielectric layer, barrier layer, Ag layers, barrier layer, dielectric layer, barrier layer, Ag layers, barrier layer, top layer and protective layer;
Wherein, the bottom, barrier layer, dielectric layer, top layer and protective layer be selected from Zn, Sn, Ti, Nb, Zr, Hf, Mg, At least one of Ni, In, Al, Ga, W, Bi metal oxide and its mixture, or selected from Si, Al, Zr, Ti, Y, Hf, Nb, Ta metal nitride or at least one of nitrogen oxides and its mixture;
S2, membrane removal is carried out using laser membrane-removing machine in the peripheral region, the region ETC and access card region of shield glass.
2. the on-line coating and film-removing technology of a kind of shield glass according to claim 1, it is characterised in that single Total thicknesses of layers of silver-colored structure sheaf is 70-100nm.
3. the on-line coating and film-removing technology of a kind of shield glass according to claim 1, it is characterised in that double Total thicknesses of layers of silver-colored structure sheaf is 180-200nm.
4. the on-line coating and film-removing technology of a kind of shield glass according to claim 1, it is characterised in that three Total thicknesses of layers of silver-colored structure sheaf is 250-300nm.
CN201810393386.5A 2018-04-27 2018-04-27 A kind of on-line coating and film-removing technology of shield glass Pending CN109467320A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810393386.5A CN109467320A (en) 2018-04-27 2018-04-27 A kind of on-line coating and film-removing technology of shield glass

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810393386.5A CN109467320A (en) 2018-04-27 2018-04-27 A kind of on-line coating and film-removing technology of shield glass

Publications (1)

Publication Number Publication Date
CN109467320A true CN109467320A (en) 2019-03-15

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Country Link
CN (1) CN109467320A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2021253549A1 (en) * 2020-06-19 2021-12-23 广东旗滨节能玻璃有限公司 Film-coated glass and manufacturing method therefor

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CN103396016A (en) * 2013-08-07 2013-11-20 福建省万达汽车玻璃工业有限公司 Low-emissivity coated glass and laminated skylight glass thereof
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CN202186945U (en) * 2011-07-11 2012-04-11 信义节能玻璃(芜湖)有限公司 LOW-E film coating glass
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CN103396016A (en) * 2013-08-07 2013-11-20 福建省万达汽车玻璃工业有限公司 Low-emissivity coated glass and laminated skylight glass thereof
CN106542745A (en) * 2016-11-07 2017-03-29 福耀玻璃工业集团股份有限公司 Low radiation coated glass containing three layers of infrared reflecting layer and its laminated glass articles

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Publication number Priority date Publication date Assignee Title
WO2021253549A1 (en) * 2020-06-19 2021-12-23 广东旗滨节能玻璃有限公司 Film-coated glass and manufacturing method therefor

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Application publication date: 20190315

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