CN109454202A - A kind of casting penetration enhancer, wear-resisting steel casting and preparation method thereof - Google Patents

A kind of casting penetration enhancer, wear-resisting steel casting and preparation method thereof Download PDF

Info

Publication number
CN109454202A
CN109454202A CN201811518352.0A CN201811518352A CN109454202A CN 109454202 A CN109454202 A CN 109454202A CN 201811518352 A CN201811518352 A CN 201811518352A CN 109454202 A CN109454202 A CN 109454202A
Authority
CN
China
Prior art keywords
casting
wear
penetration enhancer
iron
vanadium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201811518352.0A
Other languages
Chinese (zh)
Other versions
CN109454202B (en
Inventor
魏世忠
陈冲
柳文良
张程
毛丰
潘昆明
王晓东
汪宙
徐流杰
李秀青
张倩倩
周玉成
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Beijing Institute of light quantitative science and Research Co., Ltd.
YUNNAN KUNGANG WEAR RESISTANT MATERIAL SCIENCE CO., LTD.
Original Assignee
Henan University of Science and Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henan University of Science and Technology filed Critical Henan University of Science and Technology
Priority to CN201811518352.0A priority Critical patent/CN109454202B/en
Publication of CN109454202A publication Critical patent/CN109454202A/en
Application granted granted Critical
Publication of CN109454202B publication Critical patent/CN109454202B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22CFOUNDRY MOULDING
    • B22C3/00Selection of compositions for coating the surfaces of moulds, cores, or patterns
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D19/00Casting in, on, or around objects which form part of the product
    • B22D19/08Casting in, on, or around objects which form part of the product for building-up linings or coverings, e.g. of anti-frictional metal
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C27/00Alloys based on rhenium or a refractory metal not mentioned in groups C22C14/00 or C22C16/00
    • C22C27/06Alloys based on chromium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/48Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/54Ferrous alloys, e.g. steel alloys containing chromium with nickel with boron
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/58Ferrous alloys, e.g. steel alloys containing chromium with nickel with more than 1.5% by weight of manganese

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Mold Materials And Core Materials (AREA)

Abstract

The present invention relates to a kind of casting penetration enhancers, wear-resisting steel casting and preparation method thereof, belong to wear-resistant material technical field.Casting penetration enhancer of the invention consists of the following mass percentage components: chromium 50~70%, carbon 3~5%, molybdenum 1~2%, manganese 1~1.5%, vanadium 1~2%, surplus are iron.Carbon in casting penetration enhancer of the invention can be respectively formed carbide with a large amount of chromium and a small amount of vanadium, to improve the hardness and wear-resisting property of casting infiltration layer, meanwhile, manganese, molybdenum and vanadium can refine the crystal grain of casting infiltration layer, the toughness of casting infiltration layer is improved, to improve the impact resistance of casting infiltration layer.

Description

A kind of casting penetration enhancer, wear-resisting steel casting and preparation method thereof
Technical field
The present invention relates to a kind of casting penetration enhancers, wear-resisting steel casting and preparation method thereof, belong to wear-resistant material technical field.
Background technique
Infiltration technology is that by alloy powder, hard particles brushing or the particular surface that prefabricated component is embedded in casting mold is made, Solidification waste heat when using casting forms one layer of surface alloying layer with specific organization and performance in matrix surface.Infiltration technology It is partially formed composite casting infiltration layer in casting easy to wear, can both guarantee casting on the basis of not changing the original ingredient of casting, tissue With enough intensity, toughnesses, and the wear-resisting property of casting easy-wearing surface is increased substantially, to improve the use of entire casting Service life.And Infiltration technology is with short production cycle, low energy consumption, simple process, is not required to special equipment, is compound thickness, low in cost, It is widely used in the industries such as metallurgy, mine, machinery.
Currently, Infiltration technology uses chromium and other strong elements as reinforced phase mostly, but ingredient is single, and casting is caused to seep Layer hardness and toughness matching relationship are bad, and casting infiltration layer is easy to fall off, and crack.
In the prior art, the Chinese invention patent application that application publication number is CN101195156A discloses one kind in guide and guard The method that plate surface forms casting infiltration layer.Foreplate is combined by wear-resistant alloy layer and parent.This method comprises: by high carbon chromium Iron, vanadium iron, ferrotianium, rare earth ferrosilicon are ground into 200~300 mesh, stir evenly, and the nickel coated aluminium oxide powder of 250~300 mesh is added, Then resin is added, stirs, is coated in mo(U)ld face, solidifies 30min or more, the low conjunction of middle carbon for being 1600~1650 DEG C by temperature Golden steel molten steel pours into casting mold, cooling.The combination that this method is made between the matrix of foreplate and casting infiltration layer works well, and has There are high rigidity and excellent wearability.But vanadium iron powder used and nickel package alumina are more, expensive, other nickel package alumina Although can improve the wetability of alumina particle and matrix, under the conditions of wear working condition, aluminium oxide is still easy to peel off, resistance to Mill property is poor.
Summary of the invention
The object of the present invention is to provide a kind of at low cost, good casting penetration enhancers of wearability.
The present invention also provides a kind of at low cost, good wear-resisting steel castings of wearability.
The present invention also provides a kind of preparation methods of above-mentioned wear-resisting steel casting, can further increase wear-resisting steel casting Wearability.
In order to achieve the goal above, technical solution used by casting penetration enhancer of the invention are as follows:
A kind of casting penetration enhancer, it is characterised in that: consist of the following components in percentage by mass: chromium 50~70%, carbon 3~5%, Molybdenum 1~2%, manganese 1~1.5%, vanadium 1~2%, surplus are iron.
Carbon in casting penetration enhancer of the invention can be respectively formed carbide with a large amount of chromium and a small amount of vanadium, seep to improve casting The hardness and wear-resisting property of layer, meanwhile, manganese, molybdenum and vanadium can refine the crystal grain of casting infiltration layer, the toughness of casting infiltration layer be improved, to mention The impact resistance of height casting infiltration layer.
The casting penetration enhancer is mixed to get by high-carbon chromium iron, molybdenum-iron powder, ferromanganese powder, vanadium iron powder, iron powder.With high carbon ferro-chrome Powder, molybdenum-iron powder, ferromanganese powder, vanadium iron powder, iron powder are mixed and made into casting penetration enhancer, can be improved the uniformity coefficient of each component in casting penetration enhancer.
In order to reduce the fusing difficulty of casting penetration enhancer, the average grain diameter of the casting penetration enhancer is 80~200 μm.
Technical solution used by wear-resisting steel casting of the invention is:
Including steel casting matrix and the casting infiltration layer of steel casting matrix surface, the casting is arranged in a kind of wear-resisting steel casting Infiltration layer consists of the following components in percentage by mass: chromium 50~70%, carbon 3~5%, molybdenum 1~2%, manganese 1~1.5%, vanadium 1~ 2%, surplus is iron.
It is the multicomponent alloy abrasion-resistant composite layer using chromium as essential element that infiltration layer is cast in wear-resisting steel casting of the invention, casts infiltration layer It is capable of forming good metallurgical bonding with steel casting matrix, and cast the carbon in infiltration layer to distinguish with a large amount of chromium and a small amount of vanadium Carbide is formed, so that the hardness and wear-resisting property of casting infiltration layer are improved, while manganese, molybdenum and vanadium can refine the crystal grain of casting infiltration layer, The toughness of casting infiltration layer is improved, to improve the impact resistance of casting infiltration layer.
Preferably, the steel casting matrix is low-alloy steel.Using low-alloy steel as steel casting matrix, with the casting infiltration layer There is preferable matching, the bond strength of casting infiltration layer and steel casting matrix, and the hardness of low-alloy steel can be further increased It is good with toughness matching relationship, it can be improved the impact resistance polishing machine of casting entirety.
Preferably, the steel casting matrix consists of the following components in percentage by mass: C 0.35~0.40%, Si 0.30~0.50%, Mn 1.8~2.4%, Cr 0.9~1.4%, Ni 0.3~0.5%, Mo 0.2~0.3%, Nb 0.01 ~0.02%, B 0.03~0.05%, S≤0.005%, P≤0.005%, surplus are iron.Control P's and S in steel casting matrix Content reduces diffusion of the P and S to casting infiltration layer, casting infiltration layer and matrix is avoided to become fragile, and whole impact resistance abrasion is turned up.
In order to further increase the wear-resistant impact property of casting infiltration layer and reduce cost, it is preferred that the thickness of the casting infiltration layer Degree is 6~10mm.
Technical solution used by the preparation method of wear-resisting steel casting of the invention are as follows:
A kind of preparation method of above-mentioned wear-resisting steel casting, includes the following steps:
It provides and forms consistent casting penetration enhancer with the casting infiltration layer;
It provides and coating is mainly seeped by the casting that the casting penetration enhancer, organic binder and organic solvent form;
Coating is seeped into the casting and is coated in mold cavity surface, then lights the casting coated in mold cavity and seeps coating, to After paint solidification, molten steel is injected into mold cavity, it is cooling.
The preparation method of wear-resisting steel casting of the invention, simple process can be completed with current routine casting production line, and And it is with short production cycle, at low cost, thicker casting infiltration layer can be made;In addition, between casting infiltration layer obtained and steel casting matrix at Divide distribution gradient, substantially increases the bond strength of casting infiltration layer and matrix.
In order to improve the uniformity coefficient of each component in casting penetration enhancer and improve the efficiency of mixing, it is preferred that the casting penetration enhancer by High-carbon chromium iron, molybdenum-iron powder, ferromanganese powder, vanadium iron powder, iron powder composition;The average grain diameter of the casting penetration enhancer is 80~200 μm.Selection The reason of particle size range, is the flowing of the fusing that can guarantee to cast penetration enhancer simultaneously and molten steel into casting penetration enhancer.
In order to further increase the performance of casting infiltration layer and reduce cost, it is preferred that casting seeps coating on mold cavity surface Coating thickness is 5~9mm.
Specific embodiment
Casting penetration enhancer provided by the invention, it is characterised in that: consist of the following components in percentage by mass: chromium 50~70%, Carbon 3~5%, molybdenum 1~2%, manganese 1~1.5%, vanadium 1~2%, surplus are iron.
The casting penetration enhancer is mixed to get by high-carbon chromium iron, molybdenum-iron powder, ferromanganese powder, vanadium iron powder, iron powder.The casting penetration enhancer Average grain diameter is 80~200 μm, preferably 120~150 μm.
Wear-resisting steel casting provided by the invention is seeped including steel casting matrix and the casting that steel casting matrix surface is arranged in Layer, the casting infiltration layer consist of the following components in percentage by mass: chromium 50~70%, carbon 3~5%, molybdenum 1~2%, manganese 1~ 1.5%, vanadium 1~2%, surplus are iron.The casting infiltration layer includes the lath martensite tissue of high-wearing feature and the chromium of Dispersed precipitate Carbide and vanadium carbide.
The preparation method of above-mentioned wear-resisting steel casting provided by the invention, comprising the following steps:
It provides and forms consistent casting penetration enhancer with the casting infiltration layer;
It provides and coating is mainly seeped by the casting that the casting penetration enhancer, organic binder and organic solvent form;
Coating is seeped into the casting and is coated in mold cavity surface, then lights the casting coated in mold cavity and seeps coating, to After paint solidification, molten steel is injected into mold cavity, it is cooling.
The casting infiltration layer of abrasion-resistant stee made from preparation method using wear-resisting steel casting of the invention, which is formed, has high-wearing feature Lath martensite tissue, Dispersed precipitate chromium carbide and vanadium carbide.
Preferably, the average grain diameter of the casting penetration enhancer is 80~200 μm.It is further preferred that the casting penetration enhancer is averaged Partial size is 120~150 μm.
When mold cavity surface coats casting and seeps coating, it can according to need and casting infiltration coating is only coated in mold cavity table The partial region in face.
Coating is seeped in the adhesion strength on mold cavity surface in order to improve casting, while being reduced casting and being seeped coating in mold cavity table The flowing in face improves the surface quality of wear-resisting steel casting, it is preferred that the organic binder is polyvinyl butyral or phenolic aldehyde Resin.The organic solvent is ethyl alcohol.The mass ratio of the organic binder and organic solvent is 1:(14~20).It is described organic The gross mass of binder and organic solvent and the mass ratio of casting penetration enhancer are 1:(7~11.5).
It is further preferred that the mass ratio of the organic binder and organic solvent is 1:(15~20).It is described organic viscous The mass ratio of the gross mass and casting penetration enhancer of tying agent and organic solvent is 1:(7~10).
Preferably, the molten steel is low-alloy steel molten steel.It is further preferred that the low-alloy steel molten steel is by following quality The group of percentage is grouped as: C 0.35~0.40%, Si 0.30~0.50%, Mn 1.8~2.4%, Cr 0.9~1.4%, Ni 0.3~0.5%, Mo 0.2~0.3%, Nb 0.01~0.02%, B 0.03~0.05%, S≤0.005%, P≤ 0.005%, surplus is iron.Both Cr, Ni cooperate with the degree of supercooling for being capable of increasing austenitic steel, and thinning microstructure improves intensity and changes Kind impact flexibility and reduction Cold Brittleness Transition Temperature.Suitable Mo, Cr, Ni can refine crystal grain, improve intensity.
Preferably, the temperature of the molten steel is 1580~1680 DEG C.Casting is carried out at a higher temperature is capable of providing foot Diffusion of enough heat melts casting penetration enhancers and guarantee casting infiltration layer alloying element into matrix, ultimate guarantee are cast between infiltration layer and matrix Metallurgical bonding makes casting infiltration layer be not easy to peel off in work process.
Below in conjunction with specific embodiment, further description of the technical solution of the present invention.
Cast the embodiment of penetration enhancer
Embodiment 1
The casting penetration enhancer of the present embodiment, consists of the following mass percentage components: chromium 70%, carbon 5%, molybdenum 2%, manganese 1.5%, vanadium 2%, surplus are iron;Casting penetration enhancer to be by average grain diameter be 150 μm of high-carbon chromium iron, molybdenum-iron powder, ferromanganese powder, vanadium What iron powder and iron powder obtained after mixing.
Embodiment 2
The casting penetration enhancer of the present embodiment, consists of the following mass percentage components: chromium 50%, carbon 3%, molybdenum 1%, manganese 1%, Vanadium 1%, surplus are iron;Casting penetration enhancer to be by average grain diameter be 120 μm high-carbon chromium iron, molybdenum-iron powder, ferromanganese powder, vanadium iron powder and What iron powder obtained after mixing.
Embodiment 3
The casting penetration enhancer of the present embodiment, consists of the following mass percentage components: chromium 60%, carbon 4%, molybdenum 1.5%, manganese 1.2%, vanadium 1.5%, surplus are iron;Casting penetration enhancer to be by average grain diameter be 130 μm high-carbon chromium iron, molybdenum-iron powder, ferromanganese powder, What vanadium iron powder and iron powder obtained after mixing.
Embodiment 4
The casting penetration enhancer of the present embodiment, the difference with the casting penetration enhancer of embodiment 1 are: the casting penetration enhancer of the present embodiment is will to be averaged Partial size is to obtain after 80 μm of high-carbon chromium iron, molybdenum-iron powder, ferromanganese powder, vanadium iron powder and iron powder mixes.
Embodiment 5
The casting penetration enhancer of the present embodiment, the difference with the casting penetration enhancer of embodiment 2 are only that: the casting penetration enhancer of the present embodiment is will to put down Equal partial size is to obtain after 200 μm of high-carbon chromium iron, molybdenum-iron powder, ferromanganese powder, vanadium iron powder and iron powder mixes.
The embodiment of wear-resisting steel casting
Embodiment 1
Including steel casting matrix and the casting infiltration layer of steel casting matrix surface is arranged in the wear-resisting steel casting of the present embodiment, Casting infiltration layer consists of the following components in percentage by mass: chromium 70%, carbon 5%, molybdenum 2%, manganese 1.5%, vanadium 2%, surplus are iron;Casting Infiltration layer with a thickness of 10mm;Steel casting matrix consists of the following mass percentage components: C:0.40%, Si:0.50%, Mn: 2.4%, Cr:1.4%, Ni:0.5%, Mo:0.3%, Nb:0.02%, B:0.05%, S:0.004%, P:0.003%, surplus For Fe.Casting infiltration layer includes the carbide of the lath martensite tissue of high-wearing feature and the chromium of Dispersed precipitate and the carbide of vanadium.
Embodiment 2
Including steel casting matrix and the casting infiltration layer of steel casting matrix surface is arranged in the wear-resisting steel casting of the present embodiment, Casting infiltration layer consists of the following components in percentage by mass: chromium 50%, carbon 3%, molybdenum 1%, manganese 1%, vanadium 1%, surplus are iron;Casting is seeped Layer with a thickness of 6mm;Steel casting matrix consists of the following mass percentage components: C:0.35%, Si:0.30%, Mn: 1.8%, Cr:0.9%, Ni:0.3%, Mo:0.2%, Nb:0.01%, B:0.03%, S:0.003%, P:0.004%, surplus For iron.Casting infiltration layer includes the carbide of the lath martensite tissue of high-wearing feature and the chromium of Dispersed precipitate and the carbide of vanadium.
Embodiment 3
Including steel casting matrix and the casting infiltration layer of steel casting matrix surface is arranged in the wear-resisting steel casting of the present embodiment, Casting infiltration layer consists of the following components in percentage by mass: chromium 60%, carbon 4%, molybdenum 1.5%, manganese 1.2%, vanadium 1.5%, surplus are Iron;Cast infiltration layer with a thickness of 8mm;Steel casting matrix consists of the following mass percentage components: C:0.4%, Si:0.4%, Mn:2.0%, Cr:1.2%, Ni:0.4%, Mo:0.25%, Nb:0.02%, B:0.04%, S:0.003%, P:0.004%, Surplus is iron.Casting infiltration layer includes the carbonization of the carbide and vanadium of the lath martensite tissue of high-wearing feature and the chromium of Dispersed precipitate Object.
The embodiment of the preparation method of wear-resisting steel casting
Embodiment 1
The preparation method of the wear-resisting steel casting of the present embodiment, comprising the following steps:
1) it is iron according to chromium 70g, carbon 5g, molybdenum 2g, manganese 1.5g, vanadium 2g, surplus in every 100g alloyed powder, weighs respectively average Partial size is that 150 μm of high-carbon chromium iron, molybdenum-iron powder, ferromanganese powder, vanadium iron powder and iron powder is configured to alloy powder, mixed with ball mill Casting penetration enhancer is obtained after closing uniformly, it is spare;
2) 0.5g polyvinyl butyral and 8.5g dehydrated alcohol are added into every 100g that step 1) prepares casting penetration enhancer Mixed solution stirs evenly, and obtains casting and seeps coating;Then it is corresponding coated in the wear-resisting position of castings desire coating to be seeped into obtained casting Mold cavity surface, coating thickness 9mm, light casting seep coating, it is spare after paint solidification;
3) molten steel that temperature is 1680 DEG C is poured into the mold in step 2), after natural cooling, takes out casting, cast Alloying layer thickness is 10mm.
Wherein, the molten steel poured into is low-alloy steel molten steel, is consisted of the following mass percentage components: C:0.40%, Si: 0.50%, Mn:2.4%, Cr:1.4%, Ni:0.5%, Mo:0.3%, Nb:0.02%, B:0.05%, S:0.004%, P: 0.003%, surplus Fe.
Embodiment 2
The preparation method of the wear-resisting steel casting of the present embodiment, comprising the following steps:
1) it is iron according to chromium 50g, carbon 3g, molybdenum 1g, manganese 1g, vanadium 1g, surplus in every 100g alloyed powder, weighs average grain respectively Diameter is that 120 μm of high-carbon chromium iron, molybdenum-iron powder, ferromanganese powder, vanadium iron powder and iron powder is configured to alloy powder, is mixed with ball mill Casting penetration enhancer is obtained after uniformly, it is spare;
2) 0.8g polyvinyl butyral and 11.7g dehydrated alcohol are added into every 100g that step 1) prepares casting penetration enhancer Mixed solution stirs evenly, and obtains casting and seeps coating;Then it is corresponding coated in the wear-resisting position of castings desire coating to be seeped into obtained casting Mold cavity surface, coating thickness 5mm, light casting seep coating, it is spare after paint solidification;
3) molten steel that temperature is 1580 DEG C is poured into the mold in step 2), after natural cooling, takes out casting, cast Alloying layer thickness is 6mm.
Wherein, the molten steel poured into is low-alloy steel molten steel, is consisted of the following mass percentage components: C:0.35%, Si: 0.30%, Mn:1.8%, Cr:0.9%, Ni:0.3%, Mo:0.2%, Nb:0.01%, B:0.03%, S:0.003%, P: 0.004%, surplus is iron.
Embodiment 3
The preparation method of the wear-resisting steel casting of the present embodiment, comprising the following steps:
1) it is iron according to chromium 60g, carbon 4g, molybdenum 1.5g, manganese 1.2g, vanadium 1.5g, surplus in every 100g alloyed powder, weighs respectively Granularity is that 130 μm of high-carbon chromium iron, molybdenum-iron powder, ferromanganese powder, vanadium iron powder and iron powder is configured to alloy powder, mixed with ball mill Casting penetration enhancer is obtained after closing uniformly, it is spare;
2) 0.6g polyvinyl butyral and 9.4g dehydrated alcohol are added into every 100g that step 1) prepares casting penetration enhancer Mixed solution stirs evenly, and obtains casting and seeps coating;Then it is corresponding coated in the wear-resisting position of castings desire coating to be seeped into obtained casting Mold cavity surface, coating thickness 7mm, light casting seep coating, it is spare after paint solidification;
3) molten steel that temperature is 1630 DEG C is poured into the mold in step 2), after natural cooling, takes out casting, cast Alloying layer thickness is 8mm.
Wherein, the molten steel poured into is low-alloy steel molten steel, is consisted of the following mass percentage components: C:0.4%, Si: 0.4%, Mn:2.0%%, Cr:1.2%, Ni:0.4%, Mo:0.25%, Nb:0.02%, B:0.04%, S:0.003%, P: 0.004%, surplus is iron.
Embodiment 4
The preparation method of the wear-resisting steel casting of the present embodiment, the area with the preparation method of the wear-resisting steel casting in embodiment 1 Be not only that: high-carbon chromium iron employed in step 1), molybdenum-iron powder, ferromanganese powder, vanadium iron powder and iron powder average grain diameter be 80μm。
Embodiment 5
The preparation method of the wear-resisting steel casting of the present embodiment, the area with the preparation method of the wear-resisting steel casting in embodiment 2 Be not only that: high-carbon chromium iron employed in step 1), molybdenum-iron powder, ferromanganese powder, vanadium iron powder and iron powder average grain diameter be 200μm。
Experimental example
According to standard GB/T/T 230.1-2018 " metal material Rockwell hardness test part 1: test method ", divide The casting infiltration layer that wear-resisting steel casting is made in the other Examples 1 to 5 to above-mentioned preparation method carries out the test of Rockwell hardness, test knot Fruit is shown in Table 1.
The performance test results of the wear-resisting steel casting of table 1 casting infiltration layer
Project Rockwell hardness (HRC)
Embodiment 1 61.5
Embodiment 2 57.0
Embodiment 3 60.5
Embodiment 4 60.4
Embodiment 5 61.2
As shown in Table 1, the casting infiltration layer of wear-resisting steel casting of the invention has the advantages that hardness is high, wearability is good.

Claims (10)

1. a kind of casting penetration enhancer, it is characterised in that: consist of the following components in percentage by mass: chromium 50~70%, carbon 3~5%, molybdenum 1~2%, manganese 1~1.5%, vanadium 1~2%, surplus are iron.
2. casting penetration enhancer according to claim 1, it is characterised in that: the casting penetration enhancer is by high-carbon chromium iron, molybdenum-iron powder, manganese iron Powder, vanadium iron powder, iron powder are mixed to get.
3. casting penetration enhancer according to claim 2, it is characterised in that: the average grain diameter of the casting penetration enhancer is 80~200 μm.
4. a kind of wear-resisting steel casting, it is characterised in that: seeped including steel casting matrix and the casting that steel casting matrix surface is arranged in Layer, the casting infiltration layer consist of the following components in percentage by mass: chromium 50~70%, carbon 3~5%, molybdenum 1~2%, manganese 1~ 1.5%, vanadium 1~2%, surplus are iron.
5. wear-resisting steel casting according to claim 4, it is characterised in that: the steel casting matrix is low-alloy steel.
6. wear-resisting steel casting according to claim 4 or 5, it is characterised in that: the steel casting matrix is by following quality hundred The group of ratio is divided to be grouped as: C 0.35~0.40%, Si 0.30~0.50%, Mn 1.8~2.4%, Cr 0.9~1.4%, Ni 0.3~0.5%, Mo 0.2~0.3%, Nb 0.01~0.02%, B 0.03~0.05%, S≤0.005%, P≤ 0.005%, surplus is iron.
7. wear-resisting steel casting according to claim 4, it is characterised in that: it is described casting infiltration layer with a thickness of 6~10mm.
8. a kind of preparation method of wear-resisting steel casting as claimed in claim 4, characterized by the following steps:
It provides and forms consistent casting penetration enhancer with the casting infiltration layer;
It provides and coating is mainly seeped by the casting that the casting penetration enhancer, organic binder and organic solvent form;
Coating is seeped into the casting and is coated in mold cavity surface, then lights the casting coated in mold cavity and seeps coating, to coating After solidification, molten steel is injected into mold cavity, it is cooling.
9. the preparation method of wear-resisting steel casting according to claim 8, it is characterised in that: the casting penetration enhancer is by high carbon ferro-chrome Powder, molybdenum-iron powder, ferromanganese powder, vanadium iron powder, iron powder composition;The average grain diameter of the casting penetration enhancer is 80~200 μm.
10. the preparation method of wear-resisting steel casting according to claim 8, it is characterised in that: casting seeps coating in mold cavity The coating thickness on surface is 5~9mm.
CN201811518352.0A 2018-12-12 2018-12-12 Casting infiltration agent, wear-resistant steel casting and preparation method thereof Active CN109454202B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811518352.0A CN109454202B (en) 2018-12-12 2018-12-12 Casting infiltration agent, wear-resistant steel casting and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811518352.0A CN109454202B (en) 2018-12-12 2018-12-12 Casting infiltration agent, wear-resistant steel casting and preparation method thereof

Publications (2)

Publication Number Publication Date
CN109454202A true CN109454202A (en) 2019-03-12
CN109454202B CN109454202B (en) 2020-07-10

Family

ID=65613197

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201811518352.0A Active CN109454202B (en) 2018-12-12 2018-12-12 Casting infiltration agent, wear-resistant steel casting and preparation method thereof

Country Status (1)

Country Link
CN (1) CN109454202B (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110090917A (en) * 2019-04-15 2019-08-06 河北科技大学 A kind of iron base composite material method for casting and seeping coating, preparation method and casting impregnation coating using its preparation
CN112570687A (en) * 2019-09-29 2021-03-30 洛阳钢丰机械制造有限公司 Special alloy composite casting process
CN112962019A (en) * 2021-02-03 2021-06-15 河南科技大学 High-wear-resistance steel-based composite material and preparation method thereof
CN113145829A (en) * 2021-01-29 2021-07-23 自贡长城硬面材料有限公司 Preparation method of composite wear-resistant element
CN114011887A (en) * 2021-10-18 2022-02-08 马鞍山市方圆材料工程股份有限公司 Outlet guide for lost foam composite casting and production process

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5187128A (en) * 1975-01-28 1976-07-30 Nippon Tungsten SEIMITSUFUKUGOZ AIRYOBUHINSEIZOHO
CN2752122Y (en) * 2004-08-11 2006-01-18 河南科技大学 Surface composite reinforced train coupling hook cavity fitting
CN101182624A (en) * 2006-11-13 2008-05-21 河南科技大学 Tisco manganese steel casting surface alloying process method
CN101195156A (en) * 2007-12-04 2008-06-11 北京工业大学 Process for producing casting and seeping foreplate of rolling mill
CN102321848A (en) * 2011-09-03 2012-01-18 许斌 Surface particle reinforced composite material layer of iron cast member and preparation method thereof
CN103406519A (en) * 2013-07-25 2013-11-27 北京工业大学 Coated alloy powder used for casting surface alloying and alloying method
CN104858397A (en) * 2015-05-29 2015-08-26 山东鑫茂奥奈特复合固体润滑工程技术有限公司 Preparation method for erosion-resistant slurry pump overflowing piece surface composite material
CN105108055A (en) * 2015-09-29 2015-12-02 河南科技大学 Preparation method of cast-infiltration high-carbon high-chromium manganese-containing wear-resistant composite material
CN103361597B (en) * 2012-04-06 2016-08-03 武安市文祥合金制造有限公司 A kind of high-phosphorous iron top layer method for carburizing
CN106378519A (en) * 2016-11-16 2017-02-08 武汉理工大学 Alloy powder material for high heat-resisting strength iron-based cladding layer and cladding layer preparation method
CN108817310A (en) * 2018-06-27 2018-11-16 山西中条山机电设备有限公司 Coating and preparation method are seeped in a kind of casting

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5187128A (en) * 1975-01-28 1976-07-30 Nippon Tungsten SEIMITSUFUKUGOZ AIRYOBUHINSEIZOHO
CN2752122Y (en) * 2004-08-11 2006-01-18 河南科技大学 Surface composite reinforced train coupling hook cavity fitting
CN101182624A (en) * 2006-11-13 2008-05-21 河南科技大学 Tisco manganese steel casting surface alloying process method
CN101195156A (en) * 2007-12-04 2008-06-11 北京工业大学 Process for producing casting and seeping foreplate of rolling mill
CN102321848A (en) * 2011-09-03 2012-01-18 许斌 Surface particle reinforced composite material layer of iron cast member and preparation method thereof
CN103361597B (en) * 2012-04-06 2016-08-03 武安市文祥合金制造有限公司 A kind of high-phosphorous iron top layer method for carburizing
CN103406519A (en) * 2013-07-25 2013-11-27 北京工业大学 Coated alloy powder used for casting surface alloying and alloying method
CN104858397A (en) * 2015-05-29 2015-08-26 山东鑫茂奥奈特复合固体润滑工程技术有限公司 Preparation method for erosion-resistant slurry pump overflowing piece surface composite material
CN105108055A (en) * 2015-09-29 2015-12-02 河南科技大学 Preparation method of cast-infiltration high-carbon high-chromium manganese-containing wear-resistant composite material
CN106378519A (en) * 2016-11-16 2017-02-08 武汉理工大学 Alloy powder material for high heat-resisting strength iron-based cladding layer and cladding layer preparation method
CN108817310A (en) * 2018-06-27 2018-11-16 山西中条山机电设备有限公司 Coating and preparation method are seeped in a kind of casting

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110090917A (en) * 2019-04-15 2019-08-06 河北科技大学 A kind of iron base composite material method for casting and seeping coating, preparation method and casting impregnation coating using its preparation
CN112570687A (en) * 2019-09-29 2021-03-30 洛阳钢丰机械制造有限公司 Special alloy composite casting process
CN113145829A (en) * 2021-01-29 2021-07-23 自贡长城硬面材料有限公司 Preparation method of composite wear-resistant element
CN112962019A (en) * 2021-02-03 2021-06-15 河南科技大学 High-wear-resistance steel-based composite material and preparation method thereof
CN112962019B (en) * 2021-02-03 2022-03-04 河南科技大学 High-wear-resistance steel-based composite material and preparation method thereof
CN114011887A (en) * 2021-10-18 2022-02-08 马鞍山市方圆材料工程股份有限公司 Outlet guide for lost foam composite casting and production process
CN114011887B (en) * 2021-10-18 2023-01-17 马鞍山市方圆材料工程股份有限公司 Outlet guide for lost foam composite casting and production process

Also Published As

Publication number Publication date
CN109454202B (en) 2020-07-10

Similar Documents

Publication Publication Date Title
CN109454202A (en) A kind of casting penetration enhancer, wear-resisting steel casting and preparation method thereof
CN103418923B (en) Overlaying repair method for worn roller
CN100519003C (en) Process for producing casting and seeping foreplate of rolling mill
CN102330014B (en) Abrasion-resistant cast iron material
CN101870027B (en) Method for manufacturing high-chromium alloy overlaying composite abrasion resistant plate
CN105081612B (en) A kind of plasma arc surfacing alloy powder for hot-work die
CN100526495C (en) Boron-containing casting die steel and preparation method thereof
CN101092674A (en) Nitrogen contained austenitic cast iron in use for beset ring of piston
CN110172693A (en) A kind of crystal boundary toughening high rigidity ferrio wear-resistant material and preparation method thereof
CN106480380A (en) A kind of laser manufactures the iron(-)base powder of low-speed heave-load marine diesel engine piston annular groove
CN101412097A (en) Method for preparing cyclone separator steel bushing inner lining wear-resistant composite bed
CN103406519A (en) Coated alloy powder used for casting surface alloying and alloying method
CN102691028A (en) Composite material coated with precoated SiC-Fe based alloy layer and preparation method thereof
CN108747083A (en) A kind of high boron flux-cored wire and its application process of the wear-resisting phase of two-phase complex intensifying master
CN112958774B (en) Surface composite ceramic iron-based material and preparation method thereof
CN105886881A (en) Multi-component microalloying chrome-manganese wear-resisting alloy steel sand-suction tube and preparation method thereof
CN106282835B (en) The secondary alloyed method for preparing high rigidity high-strength tenacity ferrio wear-resistant material
CN101412098A (en) Method for preparing primary column shaped horniness phase composite wear-resistant block
CN101412102A (en) Method for preparing primary column/ribbon shaped horniness phase composite wear-resistant steel rolling guide roller
CN102785003B (en) Method for overlaying iron-based surface composite material
CN103192162A (en) Corrosion-resistant and wear-resistant composite metal plate
CN1327028C (en) Surface or local gradient reinforced wear resistant manganese steel composite material and preparing process
JP4491758B2 (en) Cylinder for molding machine
CN106521294B (en) A kind of preparation method of Si-Mn alloyings abrasion resistant cast steel
JPS6326295A (en) Corrision-and wear-resistant alloy and composite cylinder thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
TA01 Transfer of patent application right
TA01 Transfer of patent application right

Effective date of registration: 20191211

Address after: 471003 Xiyuan Road, Jianxi District, Henan, No. 48, No.

Applicant after: Henan University of Science and Technology

Applicant after: YUNNAN KUNGANG WEAR RESISTANT MATERIAL SCIENCE CO., LTD.

Applicant after: Beijing Institute of light quantitative science and Research Co., Ltd.

Address before: 471003 Xiyuan Road, Jianxi District, Henan, No. 48, No.

Applicant before: Henan University of Science and Technology

GR01 Patent grant
GR01 Patent grant