CN109440443B - Preparation method of super-hydrophobic fabric - Google Patents
Preparation method of super-hydrophobic fabric Download PDFInfo
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- CN109440443B CN109440443B CN201811039646.5A CN201811039646A CN109440443B CN 109440443 B CN109440443 B CN 109440443B CN 201811039646 A CN201811039646 A CN 201811039646A CN 109440443 B CN109440443 B CN 109440443B
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
- D06L1/12—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using aqueous solvents
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
- D06M13/148—Polyalcohols, e.g. glycerol or glucose
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
- D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
- D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/26—Polymers or copolymers of unsaturated carboxylic acids or derivatives thereof
- D06M2101/28—Acrylonitrile; Methacrylonitrile
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/12—Hydrophobic properties
Abstract
The invention discloses a preparation method of a super-hydrophobic fabric, which comprises the steps of firstly cleaning to remove various impurities on the surface of a fabric substrate; then, soaking the cleaned cloth into a polyhydroxy compound aqueous solution to enable the polyhydroxy compound to be attached to the surface of the cloth; and finally, placing the treated cloth and a silanization reagent under a vacuum condition for reaction to obtain the super-hydrophobic surface. The cloth prepared by the method has good hydrophobic property, strong coating binding capacity and good temperature resistance effect; meanwhile, the method has simple production equipment and preparation process, is easy to operate and has good industrial production prospect; the gas phase reaction method is adopted to graft the fluorocarbon chains, no fluorine-containing wastewater is generated, and the production process is more environment-friendly.
Description
Technical Field
The invention belongs to the technical field of material surface modification, and particularly relates to a preparation method of a super-hydrophobic fabric.
Background
The cloth is a material commonly used in decorative materials. Comprises various fabrics such as chemical fiber carpets, non-woven wallcoverings, linen, nylon fabrics, colored rubberized fabrics, flannel and the like. These cloths play a considerable role in decorative displays, often a major non-negligible effort in the overall sales space. A large amount of cloth is used for wall surface decoration, partition and background treatment, and a good commercial space display style can be formed.
However, since the decorative cloth is often in a high humidity environment in the process of using the decorative cloth, such as the south return south or the plum rain season, the decorative cloth will be in a state of being wetted for a long time, which not only affects the decorative effect, but also seriously affects the service life of the decorative cloth. In addition, when the decorative cloth is used in various exhibition and display processes, the situation that water is mistakenly scattered on the cloth inevitably occurs, and the cloth is inconvenient to replace immediately at the moment, so that the exhibition effect can be seriously influenced.
At present, the super-hydrophobic material has been widely applied to a plurality of fields of self-cleaning of building material surfaces, water proofing of circuit board surfaces, water proofing and corrosion resistance of metal device surfaces and the like due to the properties of self-cleaning, wetting resistance, water proofing and water blocking and the like. And all obtain good waterproof and anti-wetting effects. Therefore, if a super-hydrophobic coating suitable for various decorative fabrics can be developed, the problems faced by the decorative fabrics can be effectively alleviated.
Patent CN106436302A discloses an outer hydrophilic cotton cloth with a hydrophobic inner layer, which is composed of an outer cloth and an inner cloth, wherein the outer cloth of the cloth has hydrophilicity after hydrophilic treatment, and the inner cloth is provided with a hydrophobic film with a nano hierarchical structure of a grid structure on the surface of the cloth through zinc oxide particles with a net structure, dopamine hydrochloride and folic acid. Therefore, the fabric can quickly drain the water in the inner layer to the fabric in the outer layer, the inner layer keeps dry and comfortable, and the fabric is suitable for manufacturing materials of clothes. However, the outer cloth is not hydrophobic, and the moisture can still wet the surface of the cloth, so that the requirement of the decorative cloth cannot be met.
Patent CN105949499A discloses a method for preparing a super-hydrophobic material, comprising: firstly, finishing a three-dimensional structure on a substrate material by a nanotechnology to improve the roughness of the three-dimensional structure finished by the material; then, coating the material by a low-surface-energy substance through a surface modification technology to finally obtain the super-hydrophobic material. Although the preparation process is simple and the reaction conditions are mild, the nano TiO is used in the first step2The surface roughness of the base material is changed by the materials, and the color of the cloth can be changed for the cloth for decoration, so that the decoration display effect is influenced; in addition, the method adopts a soaking mode to coat the low surface energy, and the fluorine-containing silane wastewater is easy to generate.
Therefore, there is a need to develop a simple, efficient and generally applicable method for modifying the superhydrophobicity of the surface of various textile products.
Disclosure of Invention
The invention aims to overcome the defects and shortcomings of the existing cloth modification method and provide a preparation method of a super-hydrophobic cloth. The cloth treated by the method forms a super-hydrophobic coating on the surface of the cloth on the premise of keeping the original color of the decorative cloth, so that the cloth obtains good performances of self-cleaning, wetting resistance, water resistance and the like, and further can meet the requirements of various complex decorative environments; and the fluorocarbon chain is grafted to the surface of the cloth by adopting a gas phase reaction method, and no fluorine-containing wastewater is generated.
The invention aims to provide a preparation method of a super-hydrophobic fabric.
The above object of the present invention is achieved by the following technical solutions:
a preparation method of super-hydrophobic cloth comprises the following steps:
s1, placing the cloth in a cleaning agent, washing the cloth with ultra-pure water after ultrasonic cleaning, then placing the base material in ethanol at 15-40 ℃, washing the base material with the ultra-pure water after ultrasonic cleaning, and drying the base material for later use;
s2, soaking the cloth processed in the step S1 in a polyhydroxy compound aqueous solution, and drying the cloth for later use after soaking;
s3, carrying out silanization reaction on the cloth processed in the step S2 and a silanization reagent in vacuum, washing the cloth with an ethanol solution after the reaction is finished, and drying to obtain the super-hydrophobic cloth;
the S1 cleaning agent consists of the following components: 5-10 w/percent of sodium fatty alcohol-polyoxyethylene ether sulfate, 5-10 w/percent of sodium dodecyl benzene sulfonate, 0.5-0.8 w/percent of coconut diethanolamide, 10-20 w/percent of isopropanol and the balance of water.
The method comprises the steps of firstly cleaning various impurities on the surface of a cloth substrate, ensuring the color of the cloth by the selected cleaning agent, then immersing the cleaned cloth into a polyhydroxy compound aqueous solution to enable a large amount of polyhydroxy compounds to be attached to the surface of the cloth, and finally placing the treated cloth and a silanization reagent under a vacuum condition to react by adopting a gas phase reaction method to obtain the surface of the substrate modified by low surface energy substances, wherein the surface of the cloth has a micro rough structure, so that the super-hydrophobic surface is obtained.
Preferably, the cloth is cotton cloth, chemical fiber cloth, linen, wool fabric, silk or blended fabric.
Preferably, the polyhydroxy compound aqueous solution of S2 is a mixed aqueous solution of polyhydroxy compound and glyoxal, wherein the concentration of the polyhydroxy compound is 20-100 mg/mL, the concentration of the glyoxal is 1-5 mg/mL, and the balance is water.
Preferably, the polyol is sucrose or polyacrylic acid.
More preferably, the polyacrylic acid has a mass average molecular weight of 3000.
Preferably, the silylation agent in S3 is 1H,1H,2H, 2H-perfluorooctyltriethoxysilane or 1H,1H,2H, 2H-perfluorooctyltrimethoxysilane.
Preferably, the ultrasonic cleaning with the S1 cleaning agent is carried out for 15-20 min at 20-40 ℃; and the ethanol cleaning is carried out for 15-20 min by ultrasonic treatment at 15-40 ℃.
Preferably, the soaking time of S2 is 5-10 min.
Preferably, the vacuum condition of S3 is a pressure of less than 200 Pa.
Preferably, the silylation reaction of S3 is carried out at room temperature for 24-70 h.
Compared with the prior art, the invention has the following beneficial effects:
according to the invention, the hydroxyl is attached to the surface of the cloth by only adopting sucrose or polyacrylic acid on the premise of not changing the color of the surface of the cloth; and then connecting the low-surface-energy fluorocarbon chains to the surface of the substrate through a silane coupling agent to form the super-hydrophobic coating. The water contact angles of the cloth forming the super-hydrophobic coating are all more than 150 degrees, and the cloth has excellent performances of wetting resistance, water resistance and water resistance. Meanwhile, the coating has good temperature resistance, can still maintain super-hydrophobic performance under the condition of being at 85 ℃ for a long time, and can meet the daily use requirement. Meanwhile, the method has simple production equipment and preparation process, is easy to operate, is suitable for various cloth base materials, and has good industrial production prospect; the gas phase reaction method is adopted to graft the fluorocarbon chains, no fluorine-containing wastewater is generated, and the production process is more environment-friendly.
Detailed Description
The present invention is further illustrated by the following specific examples, which are not intended to limit the invention in any way. Reagents, methods and apparatus used in the present invention are conventional in the art unless otherwise indicated.
Unless otherwise indicated, reagents and materials used in the following examples are commercially available.
Example 1
A preparation method of super-hydrophobic cotton cloth takes 2.5 multiplied by 7.5cm cotton cloth as a base material and is prepared by the following method:
1. placing the cloth in a cleaning agent, performing ultrasonic treatment at 25 ℃ for 20min, then rinsing with ultrapure water for 10min, then placing the substrate in ethanol at 25 ℃ for ultrasonic treatment for 20min, finally taking out, rinsing with ultrapure water, and placing at 65 ℃ for drying for later use; wherein the proportion of the cleaning agent is as follows: sodium fatty alcohol polyoxyethylene ether sulfate (5 w/%), sodium dodecyl benzene sulfonate (5 w/%), coco diethanol amide (0.5 w/%), isopropanol (20 w/%), deionized water (69.5 w/%);
2. after pretreatment, immersing the base material in a polyhydroxy compound aqueous solution for 10min, taking out and drying at 65 ℃ for later use; wherein the polyhydroxy compound aqueous solution is a mixed aqueous solution of sucrose and glyoxal, the concentration of the sucrose is 30mg/mL, and the concentration of the glyoxal is 1.5 mg/mL;
3. placing the substrate treated by the polyhydroxy compound aqueous solution and 200 mu L of 1H,1H,2H, 2H-perfluorooctyltriethoxysilane in a vacuum environment with the pressure of less than 200Pa to complete the silanization reaction, wherein the reaction is carried out for 48 hours at room temperature; and taking out the substrate, washing with an ethanol solution, and drying to obtain the super-hydrophobic fabric.
Example 2
A preparation method of super-hydrophobic polyester cloth takes 2.5 multiplied by 7.5cm polyester cloth as a base material and is prepared by the following method:
1. firstly, placing the cloth in a cleaning agent, performing ultrasonic treatment at 30 ℃ for 20min, then rinsing with ultrapure water for 10min, then placing the substrate in ethanol at 25 ℃, performing ultrasonic treatment for 20min, finally taking out, rinsing with ultrapure water, and placing at 65 ℃ for drying for later use; wherein the proportion of the cleaning agent is as follows: sodium fatty alcohol polyoxyethylene ether sulfate (7.5 w/%), sodium dodecylbenzenesulfonate (5 w/%), cocodiethanolamide (0.5 w/%), isopropanol (20 w/%), deionized water (67 w/%);
2. after pretreatment, immersing the base material in a polyhydroxy compound aqueous solution, soaking for 7.5 min, taking out and drying at 65 ℃ for later use; wherein the polyhydroxy compound aqueous solution is a mixed aqueous solution of sucrose and glyoxal, the concentration of the sucrose is 40 mg/mL, and the concentration of the glyoxal is 2 mg/mL;
3. placing the substrate treated by the polyhydroxy compound aqueous solution and 100 microliter of 1H,1H,2H, 2H-perfluorooctyltriethoxysilane and 100 microliter of 1H,1H,2H, 2H-perfluorooctyltrimethoxysilane in a vacuum environment with the pressure of less than 200Pa to complete a silanization reaction, wherein the reaction is carried out for 36 hours at room temperature; and taking out the substrate, washing with an ethanol solution, and drying to obtain the super-hydrophobic fabric.
Example 3
A preparation method of super-hydrophobic cotton fiber cloth takes 2.5 multiplied by 7.5cm cotton fiber cloth as a base material and is prepared by the following method:
1. firstly, placing the cloth in a cleaning agent, performing ultrasonic treatment at 35 ℃ for 20min, then rinsing with ultrapure water for 10min, then placing the substrate in ethanol at 20 ℃ for ultrasonic treatment for 20min, finally taking out, rinsing with ultrapure water, and placing at 65 ℃ for drying for later use; wherein the proportion of the cleaning agent is as follows: sodium fatty alcohol polyoxyethylene ether sulfate (10 w/%), sodium dodecyl benzene sulfonate (10 w/%), coco diethanol amide (0.5 w/%), isopropanol (20 w/%), deionized water (59.5 w/%);
2. after pretreatment, immersing the base material in a polyhydroxy compound aqueous solution for 10min, taking out and drying at 65 ℃ for later use; wherein the polyhydroxy compound aqueous solution is a mixed aqueous solution of sucrose and glyoxal, the concentration of the sucrose is 20mg/mL, and the concentration of the glyoxal is 1 mg/mL;
3. placing the substrate treated by the polyhydroxy compound aqueous solution and 200 mu L of 1H,1H,2H, 2H-perfluorooctyltriethoxysilane in a vacuum environment with the pressure of less than 200Pa to complete the silanization reaction, wherein the reaction is carried out for 48 hours at room temperature; and taking out the substrate, washing with an ethanol solution, and drying to obtain the super-hydrophobic fabric.
Example 4
A preparation method of acrylic fabric takes 2.5 multiplied by 7.5cm acrylic fabric as a base material and is prepared by the following method:
1. firstly, placing the cloth in a cleaning agent, performing ultrasonic treatment at 35 ℃ for 20min, then rinsing with ultrapure water for 10min, then placing the substrate in ethanol at 35 ℃ for 20min, performing ultrasonic treatment, finally taking out, rinsing with ultrapure water, and placing at 65 ℃ for drying for later use; wherein the proportion of the cleaning agent is as follows: sodium fatty alcohol polyoxyethylene ether sulfate (5 w/%), sodium dodecyl benzene sulfonate (5 w/%), coco diethanol amide (0.5 w/%), isopropanol (20 w/%), deionized water (69.5 w/%);
2. after pretreatment, immersing the base material in a polyhydroxy compound aqueous solution, soaking for 8min, taking out and drying at 65 ℃ for later use; wherein the water solution of the polyhydroxy compound is a mixed water solution of polyacrylic acid and glyoxal, the concentration of the polyacrylic acid is 50 mg/mL, the concentration of the glyoxal is 2.5 mg/mL, and the average molecular weight of the polyacrylic acid is 3000;
3. placing the substrate treated by the polyhydroxy compound aqueous solution and 200 microliter of 1H,1H,2H, 2H-perfluorooctyltrimethoxysilane in a vacuum environment with the pressure less than 200Pa to complete the silanization reaction, wherein the reaction is carried out for 48 hours at room temperature; and taking out the substrate, washing with an ethanol solution, and drying to obtain the super-hydrophobic fabric.
Example 5
A preparation method of silk cloth takes 2.5 multiplied by 7.5cm silk cloth as a base material and is prepared by the following steps:
1. firstly, placing the cloth in a cleaning agent, performing ultrasonic treatment at 20 ℃ for 20min, then rinsing with ultrapure water for 10min, then placing the substrate in ethanol at 20 ℃ for ultrasonic treatment for 20min, finally taking out, rinsing with ultrapure water, and placing at 65 ℃ for drying for later use; wherein the proportion of the cleaning agent is as follows: sodium fatty alcohol polyoxyethylene ether sulfate (10 w/%), sodium dodecyl benzene sulfonate (5 w/%), coco diethanol amide (0.5 w/%), isopropanol (10 w/%), deionized water (74.5 w/%);
2. after pretreatment, immersing the base material in a polyhydroxy compound aqueous solution for 10min, taking out and drying at 65 ℃ for later use; wherein the polyhydroxy compound aqueous solution is a mixed aqueous solution of polyacrylic acid and glyoxal, the concentration of the polyacrylic acid is 70 mg/mL, the concentration of the glyoxal is 3.5 mg/mL, and the average molecular weight of the polyacrylic acid is 3000;
3. placing the substrate treated by the polyhydroxy compound aqueous solution and 200 mu L of 1H,1H,2H, 2H-perfluorooctyltriethoxysilane in a vacuum environment with the pressure of less than 200Pa to complete the silanization reaction, wherein the reaction is carried out for 60 hours at room temperature; and taking out the substrate, washing with an ethanol solution, and drying to obtain the super-hydrophobic fabric.
The cloth which is not treated as above is set as a comparative example, and water contact angle and rolling angle test tests are performed on examples 1 to 5 and comparative examples 1 to 3.
The results of the contact angle and the rolling angle are shown in table 1:
TABLE 1
The results of the water contact angle and the rolling angle test after heating at 75 ℃ for 12h are shown in the following table 2:
TABLE 2
The comparison tests show that after the cloth substrate is treated by the method, the water contact angles of the cloth substrate exceed 150 degrees, the rolling angles of the cloth substrate are lower than 10 degrees, good super-hydrophobic performance is shown, and the waterproof and water-blocking performance of the cloth substrate is effectively improved. Meanwhile, after 6 hours of continuous heating at 85 ℃, the treated cloth still keeps better super-hydrophobic performance and can meet daily requirements.
Claims (7)
1. The preparation method of the super-hydrophobic cloth is characterized by comprising the following steps:
s1, placing the cloth in a cleaning agent, washing the cloth with ultra-pure water after ultrasonic cleaning, then placing the base material in ethanol at 15-40 ℃, washing the base material with the ultra-pure water after ultrasonic cleaning, and drying the base material for later use;
s2, soaking the cloth processed in the step S1 in a polyhydroxy compound aqueous solution, and drying the cloth for later use after soaking;
s3, placing the cloth processed in the step S2 and a silanization reagent in a vacuum environment with the pressure intensity of less than 200Pa to complete silanization reaction, after the reaction is finished, washing the cloth with an ethanol solution, and drying to obtain super-hydrophobic cloth;
the S1 cleaning agent consists of the following components: 5-10 w/percent of sodium fatty alcohol-polyoxyethylene ether sulfate, 5-10 w/percent of sodium dodecyl benzene sulfonate, 0.5-0.8 w/percent of coconut diethanolamide, 10-20 w/percent of isopropanol and the balance of water;
s2, the polyhydroxy compound aqueous solution is a mixed aqueous solution of polyhydroxy compound and glyoxal, wherein the concentration of the polyhydroxy compound is 20-100 mg/mL, the concentration of the glyoxal is 1-5 mg/mL, and the balance is water;
the polyhydroxy compound is sucrose or polyacrylic acid.
2. The method of claim 1, wherein the fabric is cotton cloth, chemical fiber cloth, hemp cloth, wool cloth, silk, or blended fabric.
3. The method of claim 1, wherein the polyacrylic acid has a mass average molecular weight of 3000.
4. The method of claim 1, wherein the silylation agent S3 is 1H,1H,2H, 2H-perfluorooctyltriethoxysilane or 1H,1H,2H, 2H-perfluorooctyltrimethoxysilane.
5. The preparation method of the superhydrophobic fabric according to claim 1, wherein the ultrasonic cleaning with the S1 cleaning agent is carried out at 20-40 ℃ for 15-20 min; and the ethanol cleaning is carried out for 15-20 min by ultrasonic treatment at 15-40 ℃.
6. The preparation method of the superhydrophobic fabric according to claim 1, wherein the soaking time of S2 is 5-10 min.
7. The preparation method of the superhydrophobic fabric according to claim 1, wherein the silanization reaction of S3 is carried out at room temperature for 24-70 h.
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| CN110132668B (en) * | 2019-04-28 | 2022-02-15 | 西安培华学院 | Conventional glass slide super-hydrophobic treatment method |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101544476A (en) * | 2008-03-28 | 2009-09-30 | 皮尔金顿集团有限公司 | Super-hydrophobic transparent coating and preparation method thereof |
| CN102010515A (en) * | 2010-10-21 | 2011-04-13 | 浙江大学 | Method for preparing natural hydrophobic and oleophobic cellulose material |
| CN102641830A (en) * | 2012-05-08 | 2012-08-22 | 吉林大学 | Method for preparing self-healing super-hydrophobic coating by means of spraying technology |
| CN105507061A (en) * | 2015-11-27 | 2016-04-20 | 湖北大学 | Superhydrophobic coating and preparation method thereof |
| CN105696306A (en) * | 2015-11-11 | 2016-06-22 | 陕西科技大学 | Method for preparing super-hydrophobic textile from thiol-ene click chemistry-modified fiber |
-
2018
- 2018-09-06 CN CN201811039646.5A patent/CN109440443B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101544476A (en) * | 2008-03-28 | 2009-09-30 | 皮尔金顿集团有限公司 | Super-hydrophobic transparent coating and preparation method thereof |
| CN102010515A (en) * | 2010-10-21 | 2011-04-13 | 浙江大学 | Method for preparing natural hydrophobic and oleophobic cellulose material |
| CN102641830A (en) * | 2012-05-08 | 2012-08-22 | 吉林大学 | Method for preparing self-healing super-hydrophobic coating by means of spraying technology |
| CN105696306A (en) * | 2015-11-11 | 2016-06-22 | 陕西科技大学 | Method for preparing super-hydrophobic textile from thiol-ene click chemistry-modified fiber |
| CN105507061A (en) * | 2015-11-27 | 2016-04-20 | 湖北大学 | Superhydrophobic coating and preparation method thereof |
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| CN109440443A (en) | 2019-03-08 |
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