CN109440217A - A kind of ultra-fine, penetrating polyester fiber and its manufacturing method - Google Patents
A kind of ultra-fine, penetrating polyester fiber and its manufacturing method Download PDFInfo
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- CN109440217A CN109440217A CN201811249247.1A CN201811249247A CN109440217A CN 109440217 A CN109440217 A CN 109440217A CN 201811249247 A CN201811249247 A CN 201811249247A CN 109440217 A CN109440217 A CN 109440217A
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- 239000000835 fiber Substances 0.000 title claims abstract description 135
- 229920000728 polyester Polymers 0.000 title claims abstract description 105
- 230000000149 penetrating effect Effects 0.000 title claims abstract description 43
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 28
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims abstract description 39
- 239000000314 lubricant Substances 0.000 claims abstract description 37
- 239000007788 liquid Substances 0.000 claims abstract description 29
- 239000012744 reinforcing agent Substances 0.000 claims abstract description 26
- 230000000845 anti-microbial effect Effects 0.000 claims abstract description 25
- 239000011248 coating agent Substances 0.000 claims abstract description 25
- 238000000576 coating method Methods 0.000 claims abstract description 25
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 13
- 235000019439 ethyl acetate Nutrition 0.000 claims abstract description 13
- 239000000203 mixture Substances 0.000 claims abstract description 13
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 13
- 239000000463 material Substances 0.000 claims description 41
- 239000000126 substance Substances 0.000 claims description 33
- 238000001125 extrusion Methods 0.000 claims description 30
- 238000006243 chemical reaction Methods 0.000 claims description 29
- 238000002156 mixing Methods 0.000 claims description 22
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 18
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 18
- 238000001035 drying Methods 0.000 claims description 18
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 12
- 230000018044 dehydration Effects 0.000 claims description 12
- 238000006297 dehydration reaction Methods 0.000 claims description 12
- 238000005469 granulation Methods 0.000 claims description 12
- 230000003179 granulation Effects 0.000 claims description 12
- 229920001903 high density polyethylene Polymers 0.000 claims description 12
- 239000004700 high-density polyethylene Substances 0.000 claims description 12
- 229920001684 low density polyethylene Polymers 0.000 claims description 12
- 239000004702 low-density polyethylene Substances 0.000 claims description 12
- JMANVNJQNLATNU-UHFFFAOYSA-N oxalonitrile Chemical compound N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 claims description 12
- 239000002245 particle Substances 0.000 claims description 12
- SZHOJFHSIKHZHA-UHFFFAOYSA-N tridecanoic acid Chemical compound CCCCCCCCCCCCC(O)=O SZHOJFHSIKHZHA-UHFFFAOYSA-N 0.000 claims description 12
- -1 polysiloxanes Polymers 0.000 claims description 8
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 7
- 239000004332 silver Substances 0.000 claims description 7
- 229910052709 silver Inorganic materials 0.000 claims description 7
- FPIPGXGPPPQFEQ-UHFFFAOYSA-N 13-cis retinol Natural products OCC=C(C)C=CC=C(C)C=CC1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-UHFFFAOYSA-N 0.000 claims description 6
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 6
- 235000021355 Stearic acid Nutrition 0.000 claims description 6
- FPIPGXGPPPQFEQ-BOOMUCAASA-N Vitamin A Natural products OC/C=C(/C)\C=C\C=C(\C)/C=C/C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-BOOMUCAASA-N 0.000 claims description 6
- FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 claims description 6
- 239000010425 asbestos Substances 0.000 claims description 6
- 235000013871 bee wax Nutrition 0.000 claims description 6
- 239000012166 beeswax Substances 0.000 claims description 6
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 6
- 239000003822 epoxy resin Substances 0.000 claims description 6
- 229910052731 fluorine Inorganic materials 0.000 claims description 6
- 239000011737 fluorine Substances 0.000 claims description 6
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 6
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 6
- 229920000058 polyacrylate Polymers 0.000 claims description 6
- 229920002239 polyacrylonitrile Polymers 0.000 claims description 6
- 229920000647 polyepoxide Polymers 0.000 claims description 6
- 229920001296 polysiloxane Polymers 0.000 claims description 6
- 229910052895 riebeckite Inorganic materials 0.000 claims description 6
- 238000009987 spinning Methods 0.000 claims description 6
- 239000008117 stearic acid Substances 0.000 claims description 6
- 235000019155 vitamin A Nutrition 0.000 claims description 6
- 239000011719 vitamin A Substances 0.000 claims description 6
- 229940045997 vitamin a Drugs 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 238000005491 wire drawing Methods 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 229920002994 synthetic fiber Polymers 0.000 claims description 5
- 229920004933 Terylene® Polymers 0.000 claims description 3
- 229920006306 polyurethane fiber Polymers 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 239000012943 hotmelt Substances 0.000 claims description 2
- 239000006210 lotion Substances 0.000 claims description 2
- 229920005906 polyester polyol Polymers 0.000 claims description 2
- 238000009738 saturating Methods 0.000 claims description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims 1
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 claims 1
- 235000019270 ammonium chloride Nutrition 0.000 claims 1
- 230000035699 permeability Effects 0.000 abstract description 5
- 230000002745 absorbent Effects 0.000 abstract description 2
- 239000002250 absorbent Substances 0.000 abstract description 2
- 230000004048 modification Effects 0.000 abstract description 2
- 238000012986 modification Methods 0.000 abstract description 2
- 238000007500 overflow downdraw method Methods 0.000 abstract description 2
- 210000004243 sweat Anatomy 0.000 abstract description 2
- 235000013339 cereals Nutrition 0.000 description 15
- 238000000034 method Methods 0.000 description 7
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 6
- 230000000844 anti-bacterial effect Effects 0.000 description 5
- 239000004744 fabric Substances 0.000 description 5
- OHCYZUDVCRJREC-UHFFFAOYSA-M trimethyl(pentadecyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCC[N+](C)(C)C OHCYZUDVCRJREC-UHFFFAOYSA-M 0.000 description 5
- 229920004934 Dacron® Polymers 0.000 description 4
- 239000006071 cream Substances 0.000 description 4
- 239000012782 phase change material Substances 0.000 description 4
- 150000005846 sugar alcohols Polymers 0.000 description 4
- 238000001816 cooling Methods 0.000 description 3
- VDGJOQCBCPGFFD-UHFFFAOYSA-N oxygen(2-) silicon(4+) titanium(4+) Chemical compound [Si+4].[O-2].[O-2].[Ti+4] VDGJOQCBCPGFFD-UHFFFAOYSA-N 0.000 description 3
- 239000004814 polyurethane Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 229920006307 urethane fiber Polymers 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 229910003978 SiClx Inorganic materials 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000007259 addition reaction Methods 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
- D06M15/277—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof containing fluorine
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- Microbiology (AREA)
- Manufacturing & Machinery (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention relates to polyester fiber technical fields, and in particular to a kind of ultra-fine, penetrating polyester fiber and its manufacturing method；The composition of ultra-fine, the penetrating polyester fiber are as follows: the modified polyester fibre of 100-120 part of mass fraction meter, 10-15 parts of poly- acetic ester fiber, 6-8 parts of parts polyvinyl alcohol, 5-8 parts of reinforcing agent, 3-5 parts of lubricant, 3-10 parts of antimicrobial coating, 200-300 parts of housekeeping liquid；Ultra-fine, penetrating polyester fiber prepared by the present invention is prepared using fusion method, its transparency for effectively raising polyester fiber, it ensure that its permeability, furthermore pass through the modification to polyester fiber, make it have certain absorbent properties, rush can effectively absorb sweat, guarantee its comforts of use.
Description
Technical field
The invention belongs to polyester fiber technical fields, and in particular to a kind of ultra-fine, penetrating polyester fiber and its manufacturer
Method.
Background technique
In recent years, with the development of science and technology, the development of chemical fiber industry, various types Functional Chemical Fibers product are pushed
Exploitation be provided with the breakthrough development of Materiality.Polyester fiber is as one of three big main force's fibers in synthetic fibers, Yin Qiyi
Wash, the advantages that quick-drying, intensity are high, flexibility is good, conformality is good and by the raw material as all kinds of textiles, but simultaneously, terylene is one
Kind typical hydrophobic fibre, that there are sucting wet air permeabilities is poor, wears the problems such as sultry, seriously limits its answering in garment industry
With there is an urgent need to one kind to breathe freely by people, absorbent function polyester fiber.
Chinese patent application CN107761385A discloses that the invention discloses a kind of temperature adjustable intelligent fibers.One kind can
Temperature-adjusting type intelligent fiber, phase transformation intelligent temperature adjusting fiber include polyester fiber and phase-change material；Phase is wrapped in the outer rim of polyester fiber
Become material；The polyester fiber is ultra-fine polyester fiber, and the diameter of polyester fiber is 300~600nm；The phase-change material
For phase transformation viscose glue composite fibre.Compared with the existing technology, a kind of temperature adjustable intelligent fiber is provided, phase-change material and terylene are changed
The technique and structure of fiber, the good progress of phase-change material and polyester fiber is blended, in this way, the blend fibre produced was both
There are crease-resistant, effect that conformality is good fleecy fluffy, soft, warming, and that keep polyester fiber intrinsic, after substantially increasing
The overall quality of continuous fabric, its permeability of the fiber of this method preparation are poor.
Chinese patent application CN107780038A discloses that the invention discloses a kind of antibacterial cooling function fabric and its systems
Preparation Method is raw material by antibacterial, nice and cool ultra-fine polyester filament, is made into weft-knitted double-faced jacquard fabric through circular knitting machine；Described is super
Thin polyester fiber is made of the raw material of following weight percents: 1~20% silver system antibacterial matrices, 5~20% heat conduction master batch,
60~91% polyester slice, fibre section are odd-shaped cross section, fibre fineness 0.45D.Antibacterial provided by the invention is felt nice and cool function
For energy fabric since its cooling effect and antibacterial functions pass through fiber itself and realize, the fabric is by extreme friction and repeatedly washes
Still there is after washing excellent absorbing fast-drying, fast cooling and antibiotic and sterilizing performance, its permeability of fiber of this method preparation compared with
Difference.
Above-mentioned patent there are aiming at the problem that, the present invention, which has developed ultra-fine, penetrating polyester fiber, can be good at meeting
Demand of the market to polyester fiber.
Summary of the invention
In order to achieve the purpose that in background technique, one kind proposed by the present invention ultra-fine, penetrating polyester fiber and its manufacture
Method；
What the present invention realized by the following technical solutions:
A kind of ultra-fine, penetrating polyester fiber and its manufacturing method, the following steps are included:
A kind of ultra-fine, penetrating polyester fiber and its manufacturing method, which is characterized in that ultra-fine, the penetrating polyester fiber
Composition are as follows: the modified polyester fibre of 100-120 part of mass fraction meter, 10-15 parts of poly- acetic ester fiber, 6-8 parts of parts
Polyvinyl alcohol, 5-8 parts of reinforcing agent, 3-5 parts of lubricant, 3-10 parts of antimicrobial coating, 200-300 parts of housekeeping liquid；
Described one kind ultra-fine, penetrating polyester fiber and its manufacturing method are as follows: the Modified Polyester for being 100-120 parts by mass fraction
Synthetic fibre fiber, 10-15 parts of poly- acetic ester fiber, 6-8 parts of parts polyvinyl alcohol, 5-8 parts of reinforcing agent, 3-5 parts of lubricant add
Enter in batch mixer and mixed, after mixing, material is added in dryer and is dried, drying temperature is dried at 50-60 DEG C
Material is added in parallel single screw extrusion machine after dry and carries out granulation extrusion, the identical particle of particle size is obtained, then should
Expect that grain is added in hot melt extruder, the stretched type spinning machine of the crin of extrusion carries out ultra-fine wire drawing, obtains super fine polyester
Then this thread is placed into 3-10 parts of antimicrobial coating and impregnates 50-60 minutes by fiber, temperature is room temperature, then be will heat up
105-110 DEG C, 200-300 parts of housekeeping liquid is added, after impregnating 30-50min in a manner of disseminating, is drawn off, then into
Row centrifugal dehydration is dried, the substance obtained after drying is exactly, ultra-fine, logical after dehydration completely under conditions of 80-100 DEG C
Saturating polyester fiber.
Wherein, the modified polyester fibre are as follows: by 100-120 parts of polyester fiber, 10-15 parts of polyacrylonitrile, 4-6
Part polyester polyol, 1-2 part to two fourth cyanogen of benzene, 4-5 parts of polysiloxanes, 2-3 parts lubricant addition batch mixer in into
Material is added in twin-screw granulating extruder after mixing and is modified and is granulated extrusion, obtain modified materials by row mixing
Grain, which is exactly modified polyester fibre.
Wherein, the reinforcing agent are as follows: receive 20-30 parts of DH-1 reinforcing agent, 5-10 parts of epoxy resin, 6-10 parts
Rice silica, 4-8 part of asbestos fibre, 10-15 parts of high density polyethylene (HDPE), 2-4 parts lubricant addition batch mixer in into
Material is added in twin-screw granulating extruder after mixing and carries out granulation extrusion, obtain material of uniform size by row mixing
Grain, which is exactly reinforcing agent.
Wherein, the antimicrobial coating are as follows: by the organic silver of 2-3 part of mass fraction meter, 4-5 parts of citric acid, 10-15
The polyurethane fiber, 10-20 parts of acetone, 1-2 parts of vitamin A of part are added in reaction kettle and are mixed, and are completely dissolved to it
The substance obtained afterwards, the substance are exactly antimicrobial coating.
Wherein, the lubricant are as follows: by temperature of reaction kettle control at 50-60 DEG C, revolving speed control, will in 200-300rpm
Mass fraction is 2-4 parts of beeswax, 5-10 parts of stearic acid, 1-2 parts of tridecanoic acid, the addition of 5-10 parts of low density polyethylene (LDPE)
In reaction kettle, the substance obtained after carrying out hybrid reaction 1-2 hours, which is exactly lubricant.
Wherein, the housekeeping liquid are as follows: by the fluorine-containing butyl polyacrylate class ionic of 20-30 part of mass fraction meter
Lotion, 2-5 parts of pentadecyl trimethyl ammonium chloride, 100-200 parts of water are added in reaction kettle and are obtained after mixing
Substance, which is exactly housekeeping liquid.
Wherein, the ultra-fine polyester fiber are as follows: filament of the diameter at 400-600 nanometers.
Detailed description of the invention
Fig. 1 is ultra-fine, penetrating polyester fiber and its manufacturing process flow diagram proposed by the present invention.
Beneficial to benefit
Ultra-fine, penetrating polyester fiber prepared by the present invention is prepared using fusion method, is effectively raised and is washed
The transparency of synthetic fibre fiber ensure that its permeability, furthermore by the modification to polyester fiber, make it have certain absorption
Performance, rush can effectively absorb sweat, guarantee its comforts of use.
Specific embodiment
In order to keep the purpose of the present invention, technical scheme and beneficial effects clearer, below in conjunction with experimental data, to this
The preferred embodiment of invention is described in detail, to facilitate the technical staff to understand.
Embodiment 1
A kind of ultra-fine, penetrating polyester fiber and its manufacturing method, the following steps are included:
A kind of ultra-fine, penetrating polyester fiber and its manufacturing method, which is characterized in that ultra-fine, the penetrating polyester fiber
Composition are as follows: 120 parts of modified polyester fibre of mass fraction meter, 14 parts of poly- acetic ester fiber, the polyvinyl alcohol of 8 parts of parts, 6
Reinforcing agent, 5 parts of the lubricant, 9 parts of antimicrobial coating, 280 parts of housekeeping liquid of part；
Described one kind ultra-fine, penetrating polyester fiber and its manufacturing method are as follows: the modified dacron for being 120 parts by mass fraction is fine
Dimension, 14 parts of poly- acetic ester fiber, the polyvinyl alcohol of 8 parts of parts, 6 parts of reinforcing agent, 5 parts of lubricant are added in batch mixer and carry out
Material is added in dryer and dries, material is added after 50-60 DEG C, drying for drying temperature after mixing by mixing
Granulation extrusion is carried out in parallel single screw extrusion machine, obtains the identical particle of particle size, heat fusing then is added in the material grain
In extruder, the stretched type spinning machine of the crin of extrusion carries out ultra-fine wire drawing, ultra-fine polyester fiber is obtained, then by the silk
It is placed into 9 parts of antimicrobial coating and impregnates 50-60 minutes, temperature is room temperature, then will heat up 105-110 DEG C, is added 280 parts
Housekeeping liquid, after impregnating 30-50min in a manner of disseminating, be drawn off, then carry out centrifugal dehydration, after dehydration completely,
It is dried under conditions of 80-100 DEG C, the substance obtained after drying is exactly ultra-fine, penetrating polyester fiber.
Wherein, the modified polyester fibre are as follows: by 120 parts of polyester fiber, 13 parts of polyacrylonitrile, 5 parts of polyester
Polyalcohol, 1 part to two fourth cyanogen of benzene, 4 parts of polysiloxanes, 3 parts lubricant be added batch mixer in mix, be uniformly mixed
Afterwards, material is added in twin-screw granulating extruder and is modified and is granulated extrusion, obtain modified materials grain, which is exactly to be modified
Polyester fiber.
Wherein, the reinforcing agent are as follows: by 28 parts of DH-1 reinforcing agent, 9 parts of epoxy resin, 8 parts of nanometer titanium dioxide
Silicon, 8 parts of asbestos fibre, 14 parts of high density polyethylene (HDPE), 4 parts of lubricant are added in batch mixer and are mixed, and are uniformly mixed
Afterwards, material is added in twin-screw granulating extruder and carries out granulation extrusion, obtain material grain of uniform size, which is exactly to enhance
Agent.
Wherein, the antimicrobial coating are as follows: by 2.5 parts of organic silver of mass fraction meter, 4.5 parts of citric acid, 13 parts
Polyurethane fiber, 20 parts of acetone, 1 part vitamin A be added reaction kettle in mixed, obtained after it is completely dissolved
Substance, the substance are exactly antimicrobial coating.
Wherein, the lubricant are as follows: by temperature of reaction kettle control at 50-60 DEG C, revolving speed control, will in 200-300rpm
Mass fraction be 3 parts of beeswax, 8 parts of stearic acid, 2 parts of tridecanoic acid, 8 parts low density polyethylene (LDPE) be added reaction kettle in,
The substance obtained after carrying out hybrid reaction 1-2 hours, which is exactly lubricant.
Wherein, the housekeeping liquid are as follows: by 28 parts of mass fraction meter fluorine-containing butyl polyacrylate class ionic creams
The substance obtained after mixing in reaction kettle is added in liquid, 4 parts of pentadecyl trimethyl ammonium chloride, 160 parts of water, should
Substance is exactly housekeeping liquid.
Wherein, the ultra-fine polyester fiber are as follows: filament of the diameter at 500 nanometers.
Embodiment 2
A kind of ultra-fine, penetrating polyester fiber and its manufacturing method, the following steps are included:
A kind of ultra-fine, penetrating polyester fiber and its manufacturing method, which is characterized in that ultra-fine, the penetrating polyester fiber
Composition are as follows: 120 parts of modified polyester fibre of mass fraction meter, 12 parts of poly- acetic ester fiber, the polyvinyl alcohol of 8 parts of parts, 6
Reinforcing agent, 4 parts of the lubricant, 6 parts of antimicrobial coating, 250 parts of housekeeping liquid of part；
Described one kind ultra-fine, penetrating polyester fiber and its manufacturing method are as follows: the modified dacron for being 120 parts by mass fraction is fine
Dimension, 12 parts of poly- acetic ester fiber, the polyvinyl alcohol of 8 parts of parts, 6 parts of reinforcing agent, 4 parts of lubricant are added in batch mixer and carry out
Material is added in dryer and dries, material is added after 50-60 DEG C, drying for drying temperature after mixing by mixing
Granulation extrusion is carried out in parallel single screw extrusion machine, obtains the identical particle of particle size, heat fusing then is added in the material grain
In extruder, the stretched type spinning machine of the crin of extrusion carries out ultra-fine wire drawing, ultra-fine polyester fiber is obtained, then by the silk
It is placed into 6 parts of antimicrobial coating and impregnates 50-60 minutes, temperature is room temperature, then will heat up 105-110 DEG C, is added 250 parts
Housekeeping liquid, after impregnating 30-50min in a manner of disseminating, be drawn off, then carry out centrifugal dehydration, after dehydration completely,
It is dried under conditions of 80-100 DEG C, the substance obtained after drying is exactly ultra-fine, penetrating polyester fiber.
Wherein, the modified polyester fibre are as follows: by 110 parts of polyester fiber, 15 parts of polyacrylonitrile, 5 parts of polyester
Polyalcohol, 1 part to two fourth cyanogen of benzene, 5 parts of polysiloxanes, 3 parts lubricant be added batch mixer in mix, be uniformly mixed
Afterwards, material is added in twin-screw granulating extruder and is modified and is granulated extrusion, obtain modified materials grain, which is exactly to be modified
Polyester fiber.
Wherein, the reinforcing agent are as follows: by 25 parts of DH-1 reinforcing agent, 6 parts of epoxy resin, 7 parts of nanometer titanium dioxide
Silicon, 6 parts of asbestos fibre, 13 parts of high density polyethylene (HDPE), 3 parts of lubricant are added in batch mixer and are mixed, and are uniformly mixed
Afterwards, material is added in twin-screw granulating extruder and carries out granulation extrusion, obtain material grain of uniform size, which is exactly to enhance
Agent.
Wherein, the antimicrobial coating are as follows: by 3 parts of organic silver of mass fraction meter, 5 parts of citric acid, 12 parts poly-
Urethane fiber, 15 parts of acetone, 1 part of vitamin A are added in reaction kettle and are mixed, the object obtained after it is completely dissolved
Matter, the substance are exactly antimicrobial coating.
Wherein, the lubricant are as follows: by temperature of reaction kettle control at 50-60 DEG C, revolving speed control, will in 200-300rpm
Mass fraction be 3 parts of beeswax, 6 parts of stearic acid, 1 part of tridecanoic acid, 6 parts low density polyethylene (LDPE) be added reaction kettle in,
The substance obtained after carrying out hybrid reaction 1-2 hours, which is exactly lubricant.
Wherein, the housekeeping liquid are as follows: by 25 parts of mass fraction meter fluorine-containing butyl polyacrylate class ionic creams
The substance obtained after mixing in reaction kettle is added in liquid, 3 parts of pentadecyl trimethyl ammonium chloride, 150 parts of water, should
Substance is exactly housekeeping liquid.
Wherein, the ultra-fine polyester fiber are as follows: filament of the diameter at 600 nanometers.
Embodiment 3
A kind of ultra-fine, penetrating polyester fiber and its manufacturing method, the following steps are included:
A kind of ultra-fine, penetrating polyester fiber and its manufacturing method, which is characterized in that ultra-fine, the penetrating polyester fiber
Composition are as follows: 120 parts of modified polyester fibre of mass fraction meter, 15 parts of poly- acetic ester fiber, the polyvinyl alcohol of 8 parts of parts, 8
Reinforcing agent, 5 parts of the lubricant, 10 parts of antimicrobial coating, 300 parts of housekeeping liquid of part；
Described one kind ultra-fine, penetrating polyester fiber and its manufacturing method are as follows: the modified dacron for being 120 parts by mass fraction is fine
Dimension, 15 parts of poly- acetic ester fiber, the polyvinyl alcohol of 8 parts of parts, 8 parts of reinforcing agent, 5 parts of lubricant are added in batch mixer and carry out
Material is added in dryer and dries, material is added after 50-60 DEG C, drying for drying temperature after mixing by mixing
Granulation extrusion is carried out in parallel single screw extrusion machine, obtains the identical particle of particle size, heat fusing then is added in the material grain
In extruder, the stretched type spinning machine of the crin of extrusion carries out ultra-fine wire drawing, ultra-fine polyester fiber is obtained, then by the silk
It is placed into 10 parts of antimicrobial coating and impregnates 50-60 minutes, temperature is room temperature, then will heat up 105-110 DEG C, is added 300
The housekeeping liquid of part, after impregnating 30-50min in a manner of disseminating, is drawn off, and then carries out centrifugal dehydration, after dehydration completely,
It is dried under conditions of 80-100 DEG C, the substance obtained after drying is exactly ultra-fine, penetrating polyester fiber.
Wherein, the modified polyester fibre are as follows: by 120 parts of polyester fiber, 15 parts of polyacrylonitrile, 6 parts of polyester
Polyalcohol, 2 parts to two fourth cyanogen of benzene, 5 parts of polysiloxanes, 3 parts lubricant be added batch mixer in mix, be uniformly mixed
Afterwards, material is added in twin-screw granulating extruder and is modified and is granulated extrusion, obtain modified materials grain, which is exactly to be modified
Polyester fiber.
Wherein, the reinforcing agent are as follows: by 30 parts of DH-1 reinforcing agent, 10 parts of epoxy resin, 10 parts of nano-silica
SiClx, 8 parts of asbestos fibre, 15 parts of high density polyethylene (HDPE), 4 parts of lubricant are added in batch mixer and are mixed, and mixing is equal
After even, material is added in twin-screw granulating extruder and carries out granulation extrusion, obtains material grain of uniform size, which is exactly to increase
Strong agent.
Wherein, the antimicrobial coating are as follows: by 3 parts of organic silver of mass fraction meter, 5 parts of citric acid, 15 parts poly-
Urethane fiber, 20 parts of acetone, 2 parts of vitamin A are added in reaction kettle and are mixed, the object obtained after it is completely dissolved
Matter, the substance are exactly antimicrobial coating.
Wherein, the lubricant are as follows: by temperature of reaction kettle control at 50-60 DEG C, revolving speed control, will in 200-300rpm
Mass fraction is 4 parts of beeswax, 10 parts of stearic acid, 2 parts of tridecanoic acid, 10 parts of low density polyethylene (LDPE) addition reaction kettle
In, the substance obtained after carrying out hybrid reaction 1-2 hours, which is exactly lubricant.
Wherein, the housekeeping liquid are as follows: by 30 parts of mass fraction meter fluorine-containing butyl polyacrylate class ionic creams
The substance obtained after mixing in reaction kettle is added in liquid, 5 parts of pentadecyl trimethyl ammonium chloride, 200 parts of water, should
Substance is exactly housekeeping liquid.
Wherein, the ultra-fine polyester fiber are as follows: filament of the diameter at 400 nanometers.
Embodiment 4
A kind of ultra-fine, penetrating polyester fiber and its manufacturing method, the following steps are included:
A kind of ultra-fine, penetrating polyester fiber and its manufacturing method, which is characterized in that ultra-fine, the penetrating polyester fiber
Composition are as follows: 100 parts of modified polyester fibre of mass fraction meter, 10 parts of poly- acetic ester fiber, the polyvinyl alcohol of 6 parts of parts, 5
Reinforcing agent, 3 parts of the lubricant, 3 parts of antimicrobial coating, 200 parts of housekeeping liquid of part；
Described one kind ultra-fine, penetrating polyester fiber and its manufacturing method are as follows: the modified dacron for being 100 parts by mass fraction is fine
Dimension, 10 parts of poly- acetic ester fiber, the polyvinyl alcohol of 6 parts of parts, 5 parts of reinforcing agent, 3 parts of lubricant are added in batch mixer and carry out
Material is added in dryer and dries, material is added after 50-60 DEG C, drying for drying temperature after mixing by mixing
Granulation extrusion is carried out in parallel single screw extrusion machine, obtains the identical particle of particle size, heat fusing then is added in the material grain
In extruder, the stretched type spinning machine of the crin of extrusion carries out ultra-fine wire drawing, ultra-fine polyester fiber is obtained, then by the silk
It is placed into 3 parts of antimicrobial coating and impregnates 50-60 minutes, temperature is room temperature, then will heat up 105-110 DEG C, is added 200 parts
Housekeeping liquid, after impregnating 30-50min in a manner of disseminating, be drawn off, then carry out centrifugal dehydration, after dehydration completely,
It is dried under conditions of 80-100 DEG C, the substance obtained after drying is exactly ultra-fine, penetrating polyester fiber.
Wherein, the modified polyester fibre are as follows: by 100 parts of polyester fiber, 10 parts of polyacrylonitrile, 4 parts of polyester
Polyalcohol, 1 part to two fourth cyanogen of benzene, 4 parts of polysiloxanes, 2 parts lubricant be added batch mixer in mix, be uniformly mixed
Afterwards, material is added in twin-screw granulating extruder and is modified and is granulated extrusion, obtain modified materials grain, which is exactly to be modified
Polyester fiber.
Wherein, the reinforcing agent are as follows: by 20 parts of DH-1 reinforcing agent, 5 parts of epoxy resin, 6 parts of nanometer titanium dioxide
Silicon, 4 parts of asbestos fibre, 10 parts of high density polyethylene (HDPE), 2 parts of lubricant are added in batch mixer and are mixed, and are uniformly mixed
Afterwards, material is added in twin-screw granulating extruder and carries out granulation extrusion, obtain material grain of uniform size, which is exactly to enhance
Agent.
Wherein, the antimicrobial coating are as follows: by 2 parts of organic silver of mass fraction meter, 4 parts of citric acid, 10 parts poly-
Urethane fiber, 10 parts of acetone, 1 part of vitamin A are added in reaction kettle and are mixed, the object obtained after it is completely dissolved
Matter, the substance are exactly antimicrobial coating.
Wherein, the lubricant are as follows: by temperature of reaction kettle control at 50-60 DEG C, revolving speed control, will in 200-300rpm
Mass fraction be 2 parts of beeswax, 5 parts of stearic acid, 1 part of tridecanoic acid, 5 parts low density polyethylene (LDPE) be added reaction kettle in,
The substance obtained after carrying out hybrid reaction 1-2 hours, which is exactly lubricant.
Wherein, the housekeeping liquid are as follows: by 20 parts of mass fraction meter fluorine-containing butyl polyacrylate class ionic creams
The substance obtained after mixing in reaction kettle is added in liquid, 2 parts of pentadecyl trimethyl ammonium chloride, 100 parts of water, should
Substance is exactly housekeeping liquid.
Wherein, the ultra-fine polyester fiber are as follows: filament of the diameter at 450 nanometers.
Finally, it is stated that preferred embodiment above is only used to illustrate the technical scheme of the present invention rather than limits, although logical
It crosses above preferred embodiment the present invention is described in detail, however, those skilled in the art should understand that, can be
Various changes are made to it in form and in details, without departing from defined by claims of the present invention.
Claims (7)
1. a kind of ultra-fine, penetrating polyester fiber and its manufacturing method, which is characterized in that ultra-fine, the penetrating terylene is fine
The composition of dimension are as follows: the modified polyester fibre of 100-120 part of mass fraction meter, 10-15 parts of poly- acetic ester fiber, 6-8 parts of parts
Polyvinyl alcohol, 5-8 parts of reinforcing agent, 3-5 parts of lubricant, 3-10 parts of antimicrobial coating, 200-300 parts of housekeeping
Liquid；
Described one kind ultra-fine, penetrating polyester fiber and its manufacturing method are as follows: the Modified Polyester for being 100-120 parts by mass fraction
Synthetic fibre fiber, 10-15 parts of poly- acetic ester fiber, 6-8 parts of parts polyvinyl alcohol, 5-8 parts of reinforcing agent, 3-5 parts of lubricant add
Enter in batch mixer and mixed, after mixing, material is added in dryer and is dried, drying temperature is dried at 50-60 DEG C
Material is added in parallel single screw extrusion machine after dry and carries out granulation extrusion, the identical particle of particle size is obtained, then should
Expect that grain is added in hot melt extruder, the stretched type spinning machine of the crin of extrusion carries out ultra-fine wire drawing, obtains super fine polyester
Then this thread is placed into 3-10 parts of antimicrobial coating and impregnates 50-60 minutes by fiber, temperature is room temperature, then be will heat up
105-110 DEG C, 200-300 parts of housekeeping liquid is added, after impregnating 30-50min in a manner of disseminating, is drawn off, then into
Row centrifugal dehydration is dried, the substance obtained after drying is exactly, ultra-fine, logical after dehydration completely under conditions of 80-100 DEG C
Saturating polyester fiber.
2. one kind according to claim 1 ultra-fine, penetrating polyester fiber and its manufacturing method, which is characterized in that described
Modified polyester fibre are as follows: by 100-120 parts of polyester fiber, 10-15 parts of polyacrylonitrile, 4-6 parts of polyester polyol, 1-
2 parts to two fourth cyanogen of benzene, 4-5 parts of polysiloxanes, 2-3 parts lubricant be added batch mixer in mix, after mixing,
Material is added in twin-screw granulating extruder and is modified and is granulated extrusion, obtains modified materials grain, which is exactly Modified Polyester
Synthetic fibre fiber.
3. one kind according to claim 1 ultra-fine, penetrating polyester fiber and its manufacturing method, which is characterized in that described
Reinforcing agent are as follows: by 20-30 parts of DH-1 reinforcing agent, 5-10 parts of epoxy resin, 6-10 parts of nano silica, 4-8 parts
Asbestos fibre, 10-15 parts of high density polyethylene (HDPE), 2-4 parts lubricant be added batch mixer in mixed, be uniformly mixed
Afterwards, material is added in twin-screw granulating extruder and carries out granulation extrusion, obtain material grain of uniform size, which is exactly to enhance
Agent.
4. one kind according to claim 1 ultra-fine, penetrating polyester fiber and its manufacturing method, which is characterized in that described
Antimicrobial coating are as follows: by the organic silver of 2-3 part of mass fraction meter, 4-5 parts of citric acid, 10-15 parts of polyurethane fiber,
10-20 parts of acetone, 1-2 parts of vitamin A are added in reaction kettle and are mixed, and the substance obtained after it is completely dissolved should
Substance is exactly antimicrobial coating.
5. one kind according to claim 1 ultra-fine, penetrating polyester fiber and its manufacturing method, which is characterized in that described
Lubricant are as follows: by temperature of reaction kettle control at 50-60 DEG C, mass fraction is 2-4 parts in 200-300rpm by revolving speed control
Beeswax, 5-10 parts of stearic acid, 1-2 parts of tridecanoic acid, 5-10 parts of low density polyethylene (LDPE) are added in reaction kettle, are mixed
The substance that reaction obtains after 1-2 hours, which is exactly lubricant.
6. one kind according to claim 1 ultra-fine, penetrating polyester fiber and its manufacturing method, which is characterized in that described
Housekeeping liquid are as follows: by the fluorine-containing butyl polyacrylate class ionic lotion of 20-30 part of mass fraction meter, the 15 of 2-5 parts
The substance obtained after mixing in reaction kettle is added in alkyl trimethyl ammonium chloride, 100-200 parts of water, which is exactly
Housekeeping liquid.
7. one kind according to claim 1 ultra-fine, penetrating polyester fiber and its manufacturing method, which is characterized in that described
Ultra-fine polyester fiber are as follows: filament of the diameter at 400-600 nanometers.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110317438A (en) * | 2019-05-29 | 2019-10-11 | 泰兴市艾珀耐特复合材料有限公司 | A kind of high-strength PET force-bearing plate and preparation method thereof |
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| CN1986952A (en) * | 2005-12-22 | 2007-06-27 | 青岛通力达科技开发有限公司 | Process for preparing poly modified chitosan anti-bacteria wet keeping finishing agent |
| CN101177801A (en) * | 2007-11-30 | 2008-05-14 | 东华大学 | Lustrous polyester fiber and method for manufacturing the same |
| CN107780038A (en) * | 2017-09-19 | 2018-03-09 | 江南大学 | A kind of antibacterial cooling function fabric and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1986952A (en) * | 2005-12-22 | 2007-06-27 | 青岛通力达科技开发有限公司 | Process for preparing poly modified chitosan anti-bacteria wet keeping finishing agent |
| CN101177801A (en) * | 2007-11-30 | 2008-05-14 | 东华大学 | Lustrous polyester fiber and method for manufacturing the same |
| CN107780038A (en) * | 2017-09-19 | 2018-03-09 | 江南大学 | A kind of antibacterial cooling function fabric and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110317438A (en) * | 2019-05-29 | 2019-10-11 | 泰兴市艾珀耐特复合材料有限公司 | A kind of high-strength PET force-bearing plate and preparation method thereof |
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Application publication date: 20190308 |