CN109439185A - Multi-functional camouflage paint and preparation method thereof - Google Patents
Multi-functional camouflage paint and preparation method thereof Download PDFInfo
- Publication number
- CN109439185A CN109439185A CN201811317757.8A CN201811317757A CN109439185A CN 109439185 A CN109439185 A CN 109439185A CN 201811317757 A CN201811317757 A CN 201811317757A CN 109439185 A CN109439185 A CN 109439185A
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- China
- Prior art keywords
- resin
- combination
- camouflage paint
- organic
- agent
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/30—Camouflage paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0812—Aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2265—Oxides; Hydroxides of metals of iron
Abstract
The invention discloses a kind of multi-functional camouflage paints and preparation method thereof, belong to technical field of coatings, it is made of the raw material of following mass percents: combination resin 30%-70%, function pulvis 8%-36% and auxiliary agent 1-10%, wherein, the combination resin is the combination of organic siliconresin, organic fluorin modified crylic acid resin, polyurethane resin and methyl hexahydrophthalic anhydride；The function pulvis is graphene, nanoscale aluminium powder, nanometer ferro oxide combination；Full figure effectively can realize that the short distance under visible light conditions is pretended by equal analog environmental background color under any conditions when this camouflage paint is single coating use；Coating of the present invention has good absorption to have very strong counterreconnaissance stealth effect infrared, far infrared, radar wave；This camouflage paint contains high achievable disposable brush admittedly and reduces construction volume in place；The present invention does not add that organic solvent is environment-protecting and non-poisonous, good leveling property, and metastatic is excellent；There are excellent drying property, wear resistance, scratch resistance, attachment fastness good.
Description
Technical field
The present invention relates to technical field of coatings more particularly to a kind of multi-functional camouflage paint and preparation method thereof.
Background technique
Camouflage paint is the surface for military installations, instrument, so that people is beyond recognition coated object with the color of camouflage
Coating.The purpose that camouflage oneself confuses the enemy can be played under the conditions of visible light, infrared light, ultraviolet light, radar wave etc. are scouted.
It mainly realizes camouflage by the selection of pigment and its different combinations.Camouflage paint is chiefly used in military purposes, such as
Battlebus, tank, cannon, radar etc., it is necessary to have good adhesive force, wear resistance, weatherability, cold resistance and good resistance to
Water, resistance to coal, gasoline and corrosivity of other media etc..
Camouflage paint used at present is different according to the occasion that uses, and camouflage paint can be divided into anti-visible light, anti-closely red again
Outside, the different cultivars such as anti-radar wave, antiultraviolet.Using with specific aim one-sidedness.The coating used exists a large amount of organic
Solvent is during making and use finishes after discarding and all pollutes the environment, does harm to huamn body.Urgent need one in the market
The high multifunctional antiforge coating of safety and environmental protection adaptability is planted to replace existing single camouflage paint.
The camouflage paint that the country uses at present mainly has following defect: 1, not environmentally containing a large amount of organic solvents, to people
Body is harmful；2, use condition is harsh, Environmental single, and comprehensive use value is low；3, it is limited to pretend crypticity under visible light conditions；
4, need the coating application of a variety of different colors of coating complicated to adapt to varying environment；5, slow drying speed, multiple coating expend
Time is long.
Summary of the invention
An object of the present invention, in that a kind of multi-functional camouflage paint is provided, to solve the above problems.
To achieve the goals above, the technical solution adopted by the present invention is that it is such: a kind of multi-functional camouflage paint, by following matter
Measure the raw material composition of percentage:
Combination resin 30%-70%
Function pulvis 8%-36%
Auxiliary agent 1-10%；
Wherein, the combination resin is organic siliconresin, organic fluorin modified crylic acid resin, polyurethane resin and first
The combination of base hexahydrophthalic anhydride；The function pulvis is graphene, nanoscale aluminium powder, nanometer ferro oxide combination；
The reasonably combined several high-quality resins of the present invention: where organic siliconresin sufficiently wraps up dispersed graphite alkene as main resin, receives
The functions powder such as meter level aluminium powder, nanometer ferro oxide, have powerful connections image projection and reduction own face wave emissivity effect；It is poly-
Targetedly counter radar realization is painted the hidden of nothing to urethane resin with the strong electromagnetic wave absorption of methyl hexahydrophthalic anhydride energy
Body camouflage effectiveness；Organic fluorin modified crylic acid resin improves weatherability, durability, chemical-resistant and the anti-corrosive properties, resistance to of coating
The performances such as mill property, non-stain resistance.Ratio appropriate is used between resin, mutually collaboration is used as binder；And it is added appropriate
It is mutually coordinated between auxiliary agent, so that the superior performance of camouflage paint obtained, can solve the above problems substantially.
As a preferred technical scheme: the auxiliary agent includes anti-settling agent, levelling agent, defoaming agent, antistatic agent and adhesive force
Promotor.
As further preferred scheme: the anti-settling agent selects Cabot Cabot M-5 H-5 type nanoscale titanium dioxide
Silicon prevents pigment precipitating from playing stability and changing thixotropy, adjust viscosity, improve levelability, prevents its skinning,
In conjunction with other components of the invention, superior performance can be played；
The levelling agent preferably uses BP-902D, and coating can be promoted smooth, smooth, uniform in film forming, effectively increase surface slip
And scratch resistance and adhesion inhibiting properties；
The defoaming agent preferably uses TEGO Foamex 810, in production and work progress, plays prevention and eliminates bubble and make
With；
The antistatic agent preferably uses Basionics LQ1, in production and work progress, plays the role of eliminating electrostatic.
The adhesion promoter preferably uses Adherant1121, so that product is to the pig iron, stainless steel, organic composite plate
The substrates such as material, ceramic material have splendid attachment fastness.
As a preferred technical scheme: in the combination resin, counting in mass ratio, organic siliconresin: organic fluorine richness third
Olefin(e) acid resin: polyurethane resin: methyl hexahydrophthalic anhydride=(35-40): (5-10): (8-15): (5-10).
As a preferred technical scheme: in the combination function pulvis, counting, graphene: nanoscale aluminium powder: receiving in mass ratio
Meter level iron oxide=(10-15): (12-17): (5-10).
As a preferred technical scheme: be made of the raw material of following mass percents: organic siliconresin 38%, Organic fluoride change
Property acrylic resin 8%, polyurethane resin 10%, methyl hexahydrophthalic anhydride 6.4%, graphene 12.5%, nanometer aluminum
Powder 14%, nanoscale iron powder 6%, BP-902D 2%, nanometer grade silica 1.4%, TEGO Foamex 810 0.6%,
Basionics LQ1 0.5%、Adherant1121 0.6%。
The second object of the present invention is to provide a kind of preparation method of above-mentioned multifunctional coating, the technical solutions of use
Are as follows: by the raw material, in addition to defoaming agent, adhesion promoter and antistatic agent, after ratio mixing, it is dispersed with stirring, so
Grinding afterwards obtains fineness and reaches 20 μm hereinafter, the defoaming agent of the ratio, adhesion promoter and antistatic agent is then added, and glues
Degree, which reaches, applies 4# glasss 70-150 seconds, filters and packages to obtain the final product.
It compared with the prior art, the advantages of the present invention are as follows: this camouflage paint is single coating in use, full figure can be
Analog environmental background color, the short distance effectively realized under visible light conditions are pretended under the conditions of any；Coating pair of the present invention
Infrared, far infrared, radar wave have good absorption to have very strong counterreconnaissance stealth effect；This camouflage paint contains Gao Keshi admittedly
Now disposable brush reduces construction volume in place；The present invention does not add that organic solvent is environment-protecting and non-poisonous, good leveling property, and metastatic is excellent.
There are excellent drying property, wear resistance, scratch resistance, attachment fastness good；Camouflage prepared by the present invention is suitable for following substrate:
The pig iron, stainless steel, organic composite plate, ceramic material etc..
Specific embodiment
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1:
A kind of multi-functional camouflage paint, is made of the raw material of following mass percents: organic siliconresin 38%, organic fluorine richness third
Olefin(e) acid resin 8%, polyurethane resin 10%, methyl hexahydrophthalic anhydride 6.4%, graphene 12.5%, nanoscale aluminium powder
14%, nanoscale iron powder 6%, BP-902D 2%, nanometer grade silica 1.4%, TEGO Foamex 810 0.6%,
Basionics LQ1 0.5%、Adherant1121 0.6%。
Preparation method are as follows: by the raw material, in addition to defoaming agent, adhesion promoter and antistatic agent, in the ratio
It after mixing, is dispersed with stirring, then grinding obtains fineness and reaches 20 μm hereinafter, the defoaming agent of the ratio, adhesive force is then added
Promotor and antistatic agent, viscosity, which reaches, applies 4# glasss 70-150 seconds, filters and packages up to " product A ".
Embodiment 2:
A kind of multi-functional camouflage paint, is made of the raw material of following mass percents: organic siliconresin 39%, organic fluorine richness third
Olefin(e) acid resin 8%, polyurethane resin 10%, methyl hexahydrophthalic anhydride 6.4%, graphene 12.5%, nanoscale aluminium powder
13%, nanoscale iron powder 6%BP-902D 2%, nanometer grade silica 1.4%, TEGO Foamex 810 0.6%
Basionics LQ1 0.5%、Adherant1121 0.6%。
Preparation method are as follows: by the raw material, in addition to defoaming agent, adhesion promoter and antistatic agent, in the ratio
It after mixing, is dispersed with stirring, then grinding obtains fineness and reaches 20 μm hereinafter, the defoaming agent of the ratio, adhesive force is then added
Promotor and antistatic agent, viscosity, which reaches, applies 4# glasss 70-150 seconds, filters and packages up to " product B ".
Embodiment 3:
A kind of multi-functional camouflage paint, is made of the raw material of following mass percents: organic siliconresin 36%, organic fluorine richness third
Olefin(e) acid resin 7%, polyurethane resin 10%, methyl hexahydrophthalic anhydride 6.4%, graphene 12.5%, nanoscale aluminium powder
16%, 7% BP-902D 2% of nanoscale iron powder, nanometer grade silica 1.4%, TEGO Foamex 810 0.6%
Basionics LQ1 0.5%、Adherant1121 0.6%。
Preparation method are as follows: by the raw material, in addition to defoaming agent, adhesion promoter and antistatic agent, in the ratio
It after mixing, is dispersed with stirring, then grinding obtains fineness and reaches 20 μm hereinafter, the defoaming agent of the ratio, adhesive force is then added
Promotor and antistatic agent, viscosity, which reaches, applies 4# glasss 70-150 seconds, filters and packages up to " products C ".
Performance test: by product obtained by claim 1-3, carrying out correlated performance test, test method according to
Relevant criterion, test result are shown in Table 1
1 properties of product test result of table
| Index | It is required that | Product A | Product B | Products C |
| Covering power/% | 95~105 | 99.5 | 98 | 97 |
| Viscosity/(s/25 DEG C of painting 4# flow cup) | 70~150 | 95 | 93 | 95 |
| Hardness | ≥HB | 5H | 4H | 4H |
| Resistance to acid and alkali/(impregnating 240h) | It is not blistering, non-discolouring | It is not blistering, non-discolouring | It is not blistering, non-discolouring | It is not blistering, non-discolouring |
| Impact resistance/(cm) | ≥50 | 70 | 70 | 70 |
| Scratch-resistant | It does not fall the effect of ink | It does not fall the effect of ink | It does not fall the effect of ink | It does not fall the effect of ink |
| Thermal infrared emissivity | ≤0.65 | 0.60 | 0.63 | 0.62 |
| Reflection of radar wave rate | ≤-8 | -10 | -10 | -9 |
| Target is averaged visibility | ≤50% | 40% | 50% | 45% |
The foregoing is merely product A preferred embodiments of the invention, are not intended to limit the invention, it is all in spirit of the invention and
Made any modifications, equivalent replacements, and improvements etc., should all be included in the protection scope of the present invention within principle.
Claims (6)
1. a kind of multi-functional camouflage paint, which is characterized in that be made of the raw material of following mass percents:
Combination resin 30%-70%
Function pulvis 8%-36%
Auxiliary agent 1-10%；
Wherein, the combination resin is organic siliconresin, organic fluorin modified crylic acid resin, polyurethane resin and first
The combination of base hexahydrophthalic anhydride；The function pulvis is the combination of graphene, nanoscale aluminium powder, nanometer ferro oxide.
2. multi-functional camouflage paint according to claim 1, it is characterised in that: the auxiliary agent include anti-settling agent, levelling agent,
Defoaming agent, antistatic agent and adhesion promoter.
3. multi-functional camouflage paint according to claim 1, it is characterised in that: in the combination resin, count in mass ratio,
Organic siliconresin: organic fluorin modified crylic acid resin: polyurethane resin: methyl hexahydrophthalic anhydride=(35-40): (5-
10): (8-15): (5-10).
4. multi-functional camouflage paint according to claim 1, it is characterised in that: in the function pulvis, count in mass ratio,
Graphene: nanoscale aluminium powder: nanometer ferro oxide=(10-15): (12-17): (5-10).
5. multi-functional camouflage paint according to claim 1, it is characterised in that: by the raw material group of following mass percents
At: organic siliconresin 38%, organic fluorin modified crylic acid resin 8%, polyurethane resin 10%, methyl hexahydrophthalic anhydride
6.4%, graphene 12.5%, nanoscale aluminium powder 14%, nanoscale iron powder 6%, BP-902D 2%, nanometer grade silica
1.4%、TEGO Foamex 810 0.6%、Basionics LQ1 0.5%、Adherant1121 0.6%。
6. the preparation method of the multi-functional camouflage paint of claim 2, which comprises the following steps: by the raw material,
In addition to defoaming agent, adhesion promoter and antistatic agent, after ratio mixing, it is dispersed with stirring, then grinding obtains fineness
Reach 20 μm hereinafter, adding the defoaming agent of the ratio, antistatic agent and adhesion promoter, viscosity, which reaches, applies 4# glasss of 70-
It 150 seconds, filters and packages to obtain the final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811317757.8A CN109439185B (en) | 2018-11-07 | 2018-11-07 | Multifunctional camouflage paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811317757.8A CN109439185B (en) | 2018-11-07 | 2018-11-07 | Multifunctional camouflage paint and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109439185A true CN109439185A (en) | 2019-03-08 |
| CN109439185B CN109439185B (en) | 2020-09-04 |
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| CN201811317757.8A Active CN109439185B (en) | 2018-11-07 | 2018-11-07 | Multifunctional camouflage paint and preparation method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110489792A (en) * | 2019-07-12 | 2019-11-22 | 中国人民解放军92942部队 | A kind of method, apparatus and server for visual camouflage distance design |
| CN110791138A (en) * | 2019-09-23 | 2020-02-14 | 成都普瑞斯特新材料有限公司 | Electromagnetic wave unidirectional conduction coating and preparation method thereof |
| CN112239621A (en) * | 2019-12-12 | 2021-01-19 | 济宁长缨野营装备有限公司 | Visible light, near infrared and thermal infrared composite multi-spectrum stealth integrated material |
| CN112708339A (en) * | 2021-01-22 | 2021-04-27 | 泰州市华润纺织品有限公司 | Optical infrared multi-band camouflage coating and preparation method thereof |
| CN114276728A (en) * | 2021-12-31 | 2022-04-05 | 广东美涂士建材股份有限公司 | Modified acrylic acid corrosion-resistant water-based paint and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110489792A (en) * | 2019-07-12 | 2019-11-22 | 中国人民解放军92942部队 | A kind of method, apparatus and server for visual camouflage distance design |
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| CN110791138A (en) * | 2019-09-23 | 2020-02-14 | 成都普瑞斯特新材料有限公司 | Electromagnetic wave unidirectional conduction coating and preparation method thereof |
| CN112239621A (en) * | 2019-12-12 | 2021-01-19 | 济宁长缨野营装备有限公司 | Visible light, near infrared and thermal infrared composite multi-spectrum stealth integrated material |
| CN112708339A (en) * | 2021-01-22 | 2021-04-27 | 泰州市华润纺织品有限公司 | Optical infrared multi-band camouflage coating and preparation method thereof |
| CN112708339B (en) * | 2021-01-22 | 2022-08-26 | 泰州市华润纺织品有限公司 | Optical infrared multi-band camouflage coating and preparation method thereof |
| CN114276728A (en) * | 2021-12-31 | 2022-04-05 | 广东美涂士建材股份有限公司 | Modified acrylic acid corrosion-resistant water-based paint and preparation method thereof |
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|---|---|
| CN109439185B (en) | 2020-09-04 |
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