CN109439153A - A kind of unsaturated polyester material of the lower 80 minutes gel times of 38 DEG C of high temperature of electrostatic spraying - Google Patents
A kind of unsaturated polyester material of the lower 80 minutes gel times of 38 DEG C of high temperature of electrostatic spraying Download PDFInfo
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- CN109439153A CN109439153A CN201811289650.7A CN201811289650A CN109439153A CN 109439153 A CN109439153 A CN 109439153A CN 201811289650 A CN201811289650 A CN 201811289650A CN 109439153 A CN109439153 A CN 109439153A
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- unsaturated polyester
- electrostatic spraying
- high temperature
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/45—Anti-settling agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Abstract
The present invention discloses a kind of unsaturated polyester material of lower 80 minutes gel times of 38 DEG C of high temperature of electrostatic spraying, the material includes the component of following parts by weight: 38-48 parts of unsaturated polyester resin, 1-3 parts of grinding auxiliary agent, 35-55 parts of inorganic filler, 3-6 parts of solvent, 1-2 parts of anti-settling agent, enhance 1-2 parts of anti-settling property auxiliary rheological agents, 1-3 parts of hardening agent, 0.1-0.5 parts of defoaming agent, 0.2-0.5 parts of levelling agent, 0.1-0.2 parts of conductive auxiliary agent, 0.5-0.7 parts of polymerization inhibitor, 3-5 parts of adhesion promoter, 0.5-0.7 parts of slow curing type anti-greening dispersing agent；80 minutes gel materials of unsaturated polyester (UP) under 38 DEG C of environment of electrostatic spraying of the invention are suitable for rotary cup electrostatic spraying, improve paint utilization rate, gel time reaches 80 minutes under 38 DEG C of environment.Satisfaction while reaching performance and environmental requirement.
Description
Technical field
The invention belongs to paint fields, and in particular to a kind of insatiable hunger of the lower 80 minutes gel times of 38 DEG C of high temperature of electrostatic spraying
And polyester material.
Background technique
With the continuous progress of science and technology, people increasingly pay attention to environmental protection, and traditional hand spray operation is gradually mechanical
Spraying is substituted, and electrostatic spraying gradually becomes mainstream.Because rotary cup electrostatic spraying uses cycle operation, paint utilization rate is improved,
Its to the gel time of unsaturated polyester material require it is very high need to reach under 38 DEG C of environment 80 minutes, common unsaturated polyester (UP)
The gel time of material only has 30 minutes or so.
Therefore, a kind of construction tolerance that can widen unsaturated polyester (UP) priming paint is badly in need of in this field, to improve material use
Rate reduces environmental pollution.
Summary of the invention
The object of the present invention is to provide a kind of lower 80 minutes gel materials of 38 DEG C of high temperature of electrostatic spraying unsaturated polyester (UP), with solution
The problems such as certainly common PE priming paint electrostatic spraying construction swap time is short on the market, levelability is poor, richness is poor, poor adhesive force,
Achieve the purpose that performance and environmental requirement while meeting.
The technical solution of the present invention is as follows:
The present invention provides a kind of lower 80 minutes gel materials of 38 DEG C of high temperature of electrostatic spraying unsaturated polyester (UP), including host agent, presses
Parts by weight meter, the host agent composition are as follows:
38-48 parts of unsaturated polyester resin
1-3 parts of grinding auxiliary agent
35-55 parts of inorganic filler
3-6 parts of solvent
1-2 parts of anti-settling agent
Enhance 1-2 parts of anti-settling property auxiliary rheological agents
1-3 parts of hardening agent
0.1-0.5 parts of defoaming agent
0.2-0.5 parts of levelling agent
0.1-0.2 parts of conductive auxiliary agent
0.5-0.7 parts of polymerization inhibitor
3-5 parts of adhesion promoter
0.5-0.7 parts of slow curing type anti-greening dispersing agent.
As a further optimization solution of the present invention, the unsaturated polyester resin is Pneumoperitoneum pressure resin.
As a further optimization solution of the present invention, the inorganic filler is transparent powder, calcium carbonate, titanium dioxide and talcum
At least one of powder.
As a further optimization solution of the present invention.
As a further optimization solution of the present invention, the solvent is styrene and ethyl alcohol.
As a further optimization solution of the present invention, the styrene and ethyl alcohol 1:1-4 in mass ratio mixing.
As a further optimization solution of the present invention, the anti-settling agent is fumed silica, the fumed silica
For non-process type gas-phase silica.
As a further optimization solution of the present invention, the hardening agent is nano aluminium oxide, and the defoaming agent is acrylic acid
Ester polymer, the levelling agent are polyacrylacid ester compounds, and the polymerization inhibitor is 5% hydroquinone, and the attachment is made every effort to promote
It is carboxylic petchem solution into agent, the anti-greening dispersing agent of slow curing type is the compound mixture of high molecular weight.
As a further optimization solution of the present invention, the grinding auxiliary agent of the reinforcing material grinability is zinc stearate.
As a further optimization solution of the present invention, the auxiliary rheological agents of the anti-settling property of the reinforcing material are polyhydroxycarboxyliacid acid acyl
Amine aqueous solution.
As a further optimization solution of the present invention, the conductive auxiliary agent of the reinforcing material electric conductivity is unsaturated acid
Carboxylate alkylol ammonium salt solution
Invention mechanism of the invention is:
Conventional unsaturated polyester coating is in addition initiator (also known as curing agent, curing agent, popular name plain boiled water) and promotor
After (popular name Lan Shui), it is necessary to be finished in 20-40min.The present invention is using 0.5-0.7 parts of 5% hydroquinone of addition, and phenols is by oxygen
Corresponding quinone is melted into conjunction with the free radical of chain and plays inhibition.In the presence of phenolic inhibitor, make peroxylradicals very
It is fast to terminate, it is ensured that have sufficient amount oxygen in monomer, the effect that the polymerization inhibitor phase inhibits polymerization reaction can be extended, will terminate it is each from
Stop polymerization reaction by base, until their complete depletion of substances are known as polymerization inhibitor or inhibitor；Subtract free radical activity
It is weak, slow down polymerization rate；The compound mixture 0.5-0.7 that the anti-greening dispersing agent of slow curing type is high molecular weight is added simultaneously
Part, further slow down gel time, is allowed to gel time and reaches under 38 DEG C of environment 80 minutes.Since gel time is too long,
Hardness of film rises slower, addition hardening agent nano aluminium oxide floating and film surface layer promotion hardness of film.
The invention has the following advantages over the prior art:
It is quiet can to provide rotation cup to the lower 80 minutes gel materials of 38 DEG C of high temperature of a kind of electrostatic spraying unsaturated polyester (UP) of the invention
Electrospray construction has that gel time is long, levelling is good, high richness, covering power is good, adhesive force is good, the excellent properties such as easy to polish,
Application range is widened significantly, is reduced environmental pollution.With unsaturated polyester resin, active solvent, inorganic filler, functional form auxiliary agent
Proportion can solve constructs that levelability is poor, richness is poor, covering power is poor, poor adhesive force etc. is scarce on ink type transfer film
Point.
Specific embodiment
The present invention is specifically described below by embodiment, it is necessary to which indicated herein is that following embodiment is only used
It is further detailed in the present invention, should not be understood as limiting the scope of the invention, which is skilled in technique
Some nonessential modifications and adaptations that personnel are made according to foregoing invention content, still fall within protection scope of the present invention.
In following embodiments, unsaturated polyester resin selects the 2007A of the 23402 of Changxing chemical company, Chang Runfa company
Compounding, adhesion promoter select the VT-CD-2 of Guangzhou Ming Yue synthetic material Co., Ltd, and hardening agent selects Xuancheng brilliant auspicious new
The nano aluminium oxide of Materials Co., Ltd, zinc stearate select the BT1818 of hundred Li He companies, and styrene selects the new Hong Shi in Chengdu
The styrene of change, ethyl alcohol are selected to Chengdu Xin Yaxin Fine Chemical Co., Ltd, and Foshan City monkey sage's chemical industry is selected in inorganic filler
TM-1500 transparent powder, rutile type titanium white select the CR-510 of Jinzhou Tai Ye limited liability company, the selection of rutile titania titanium dioxide to climb
The TLA-100 of Zhi Hua family happiness Chemical Co., Ltd., fumed silica select Foshan City Nuo Dun Chemical Industry Science Co., Ltd W-20,
The anti-greening dispersing agent of slow curing type selects the W308 of Rui Long company, and defoaming agent selects the EFKA2720 third of the company of Qi Ba auxiliary agent company
Olefine acid ester polymer, levelling agent select the HX3700 polyacrylacid ester compounds of auxiliary agent company, China, and auxiliary rheological agents select BYK
The BYK405 polyhydroxycarboxylicacid amides solution of company, the ES-80 for increasing coating electric conductivity selection of auxiliary BYK company are unsaturated acid
Carboxylate alkylol ammonium salt solution.
Embodiment 1
Formula: 38 parts of Pneumoperitoneum pressure resin, adhesion promoter 5, anti-0.5 part of greening dispersing agent, polymerization inhibitor:
5% hydroquinone 0.5, hardening agent: 2 parts, grinding auxiliary agent: 3 parts of zinc stearate, solvent: 3 parts of styrene, 1 part of ethyl alcohol, it is inorganic to fill out
Material: 7 parts of transparent powder, titanium dioxide 15,18 parts of calcium carbonate, 5 parts of talcum powder, anti-settling agent: 0.8 part of fumed silica, defoaming agent:
0.1 part of acrylate polymer, levelling agent: 0.5 part of polyacrylacid ester compounds, auxiliary rheological agents: 0.3 part, increases coating and lead
0.1 part of electrical auxiliary agent.
Manufacturing process: Pneumoperitoneum pressure resin is put into → is added adhesion promoter → addition styrene, second
Alcohol → stirring at low speed →, which sequentially adds anti-greening dispersing agent, polymerization inhibitor, defoaming agent and levelling agent → middling speed, to be dispersed 10 minutes
→ fumed silica has been sequentially added, titanium dioxide, transparent powder, calcium carbonate, talcum powder and zinc stearate → high speed dispersion 20 are divided
Clock → addition auxiliary rheological agents, increase coating electric conductivity auxiliary agent stir at low speed, and cross sand mill to fineness≤45 micron.
Resulting PE unsaturated polyester (UP) product appearance: white viscous liquid；Surface drying time≤30 of paint film after spraying application
Minute；20 DEG C are done solid work the time for 24 hours；Good leveling property；Hardness >=H；Adhesive force (cross-hatching): level-one；Gelling time: 38 DEG C of environment
80min；Limits of harmful substances (dissoluble lead, cadmium, chromium, mercury): it is not detected；Paint film good leveling property；Paint film covering power is good；Richness
It is good.Grinability (12h): easy to polish.
Embodiment 2
Formula: 40 parts of Pneumoperitoneum pressure resin, adhesion promoter 4, anti-0.5 part of greening dispersing agent, polymerization inhibitor:
5% hydroquinone 0.5, hardening agent: 2 parts, grinding auxiliary agent: 2 parts of zinc stearate, solvent: 3 parts of styrene, 1 part of ethyl alcohol, it is inorganic to fill out
Material: 6 parts of transparent powder, titanium dioxide 14,22 parts of calcium carbonate, 5 parts of talcum powder, anti-settling agent: 0.8 part of fumed silica, defoaming agent:
0.1 part of acrylate polymer, levelling agent: 0.5 part of polyacrylacid ester compounds, auxiliary rheological agents: 0.3 part, increases coating and lead
0.1 part of electrical auxiliary agent.
Manufacturing process: Pneumoperitoneum pressure resin is put into → is added adhesion promoter → addition styrene, second
Alcohol → stirring at low speed →, which sequentially adds anti-greening dispersing agent, polymerization inhibitor, defoaming agent and levelling agent → middling speed, to be dispersed 10 minutes
→ fumed silica has been sequentially added, titanium dioxide, transparent powder, calcium carbonate, talcum powder and zinc stearate → high speed dispersion 20 are divided
Clock → addition auxiliary rheological agents, increase coating electric conductivity auxiliary agent stir at low speed, and cross sand mill to fineness≤45 micron.
Resulting PE unsaturated polyester (UP) product appearance: white viscous liquid；Surface drying time≤30 of paint film after spraying application
Minute；20 DEG C are done solid work the time for 24 hours；Good leveling property；Hardness >=H；Adhesive force (cross-hatching): level-one；Gelling time: 38 DEG C of environment
80min；Limits of harmful substances (dissoluble lead, cadmium, chromium, mercury): it is not detected；Paint film good leveling property；Paint film covering power is good；Richness
It is good.Grinability (12h): easy to polish.
Embodiment 3
Formula: 4,3 parts of Pneumoperitoneum pressure resin, adhesion promoter 3, anti-0.5 part of greening dispersing agent, polymerization inhibitor
Agent: 5% hydroquinone 0.5, hardening agent: 2 parts, grinding auxiliary agent: 2 parts of zinc stearate, solvent: 3 parts of styrene, 1 part of ethyl alcohol, it is inorganic
Filler: 3 parts of transparent powder, titanium dioxide 15,22 parts of calcium carbonate, talcum powder 2, anti-settling agent: 0.8 part of fumed silica, defoaming agent:
0.1 part of acrylate polymer, levelling agent: 0.5 part of polyacrylacid ester compounds, auxiliary rheological agents: 0.3 part, increases coating and lead
0.1 part of electrical auxiliary agent.
Manufacturing process: Pneumoperitoneum pressure resin is put into → is added adhesion promoter → addition styrene, second
Alcohol → stirring at low speed →, which sequentially adds anti-greening dispersing agent, polymerization inhibitor, defoaming agent and levelling agent → middling speed, to be dispersed 10 minutes
→ fumed silica has been sequentially added, titanium dioxide, transparent powder, calcium carbonate, talcum powder and zinc stearate → high speed dispersion 20 are divided
Clock to fineness≤55 micron → addition auxiliary rheological agents, increase coating electric conductivity auxiliary agent stirs at low speed, and crosses sand mill to fineness
≤ 45 microns.
Resulting PE unsaturated polyester (UP) product appearance: white viscous liquid；Surface drying time≤30 of paint film after spraying application
Minute；20 DEG C are done solid work the time for 24 hours；Good leveling property；Hardness >=H；Adhesive force (cross-hatching): level-one；Gelling time: 38 DEG C of environment
80min；Limits of harmful substances (dissoluble lead, cadmium, chromium, mercury): it is not detected；Paint film good leveling property；Paint film covering power is good；Richness
It is good.Grinability (12h): easy to polish.
Claims (9)
1. a kind of lower 80 minutes gel materials of 38 DEG C of high temperature of electrostatic spraying unsaturated polyester (UP), including host agent, which is characterized in that by weight
Part meter is measured, the host agent composition is as follows:
38-48 parts of unsaturated polyester resin
1-3 parts of grinding auxiliary agent
35-55 parts of inorganic filler
3-6 parts of solvent
1-2 parts of anti-settling agent
Enhance 1-2 parts of anti-settling property auxiliary rheological agents
1-3 parts of hardening agent
0.1-0.5 parts of defoaming agent
0.2-0.5 parts of levelling agent
0.1-0.2 parts of conductive auxiliary agent
0.5-0.7 parts of polymerization inhibitor
3-5 parts of adhesion promoter
0.5-0.7 parts of slow curing type anti-greening dispersing agent.
2. the lower 80 minutes gel materials of 38 DEG C of high temperature of a kind of electrostatic spraying unsaturated polyester (UP) according to claim 1, special
Sign is that the unsaturated polyester resin is Pneumoperitoneum pressure resin.
3. the lower 80 minutes gel materials of 38 DEG C of high temperature of a kind of electrostatic spraying unsaturated polyester (UP) according to claim 1, special
Sign is that the inorganic filler is at least one of transparent powder, calcium carbonate, titanium dioxide and talcum powder.
4. the lower 80 minutes gel materials of 38 DEG C of high temperature of a kind of electrostatic spraying unsaturated polyester (UP) according to claim 1, special
Sign is that the solvent is styrene and ethyl alcohol, it is preferred that the styrene and ethyl alcohol 1:1-4 in mass ratio mixing.
5. the lower 80 minutes gel materials of 38 DEG C of high temperature of a kind of electrostatic spraying unsaturated polyester (UP) according to claim 1, special
Sign is that the anti-settling agent is fumed silica, and the fumed silica is non-process type gas-phase silica.
6. the lower 80 minutes gel materials of 38 DEG C of high temperature of a kind of electrostatic spraying unsaturated polyester (UP) according to claim 1, special
Sign is that the hardening agent is nano aluminium oxide, and the defoaming agent is acrylate polymer, and the levelling agent is polyacrylic acid
Ester type compound, the polymerization inhibitor are 5% hydroquinone, and the adhesion promoter is carboxylic petchem solution,
The anti-greening dispersing agent of slow curing type is the compound mixture of high molecular weight.
7. the lower 80 minutes gel materials of 38 DEG C of high temperature of a kind of electrostatic spraying unsaturated polyester (UP) according to claim 1, special
Sign is that the grinding auxiliary agent of the reinforcing material grinability is zinc stearate.
8. the lower 80 minutes gel materials of 38 DEG C of high temperature of a kind of electrostatic spraying unsaturated polyester (UP) according to claim 1, special
Sign is that the auxiliary rheological agents of the anti-settling property of reinforcing material are polyhydroxycarboxylicacid amides solution.
9. the lower 80 minutes gel materials of 38 DEG C of high temperature of a kind of electrostatic spraying unsaturated polyester (UP) according to claim 1, special
Sign is that the conductive auxiliary agent of the reinforcing material electric conductivity is unsaturated acidic carboxy-late's alkylol ammonium salt solution.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811289650.7A CN109439153A (en) | 2018-10-31 | 2018-10-31 | A kind of unsaturated polyester material of the lower 80 minutes gel times of 38 DEG C of high temperature of electrostatic spraying |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811289650.7A CN109439153A (en) | 2018-10-31 | 2018-10-31 | A kind of unsaturated polyester material of the lower 80 minutes gel times of 38 DEG C of high temperature of electrostatic spraying |
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| Publication Number | Publication Date |
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| CN109439153A true CN109439153A (en) | 2019-03-08 |
Family
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| CN201811289650.7A Pending CN109439153A (en) | 2018-10-31 | 2018-10-31 | A kind of unsaturated polyester material of the lower 80 minutes gel times of 38 DEG C of high temperature of electrostatic spraying |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113025169A (en) * | 2019-12-09 | 2021-06-25 | 广东顺德三和化工有限公司 | Polishing-free unsaturated polyester coating and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106065268A (en) * | 2016-07-21 | 2016-11-02 | 成都优品化工有限公司 | A kind of electrostatic spraying unsaturated polyester (UP) white primer and preparation method thereof |
| CN108610915A (en) * | 2018-05-15 | 2018-10-02 | 嘉宝莉化工集团股份有限公司 | A kind of PE varnish of cold cycling non-whitening |
-
2018
- 2018-10-31 CN CN201811289650.7A patent/CN109439153A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106065268A (en) * | 2016-07-21 | 2016-11-02 | 成都优品化工有限公司 | A kind of electrostatic spraying unsaturated polyester (UP) white primer and preparation method thereof |
| CN108610915A (en) * | 2018-05-15 | 2018-10-02 | 嘉宝莉化工集团股份有限公司 | A kind of PE varnish of cold cycling non-whitening |
Non-Patent Citations (1)
| Title |
|---|
| 兰州化学工业公司化工机械研究组织编写: "《合成树脂及玻璃钢》", 31 July 1973, 燃料化学工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113025169A (en) * | 2019-12-09 | 2021-06-25 | 广东顺德三和化工有限公司 | Polishing-free unsaturated polyester coating and preparation method thereof |
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Application publication date: 20190308 |