CN109439062A - A kind of water-based temperature resistant of aluminium paper can gold stamping printing ink composition - Google Patents
A kind of water-based temperature resistant of aluminium paper can gold stamping printing ink composition Download PDFInfo
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- CN109439062A CN109439062A CN201811117759.2A CN201811117759A CN109439062A CN 109439062 A CN109439062 A CN 109439062A CN 201811117759 A CN201811117759 A CN 201811117759A CN 109439062 A CN109439062 A CN 109439062A
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- water
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- temperature resistant
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/108—Hydrocarbon resins
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The present invention provide a kind of water-based temperature resistant on aluminium paper aluminium paper can gold stamping ink formulations solve the problems, such as this, a kind of water-based temperature resistant of aluminium paper can gold stamping printing ink composition, wherein, the composition of every 100 parts by weight includes aqueous vinyl chloride-vinyl acetate resin 10-20 parts, 20-30 parts of aqueous polyurethane resin, 5-8 parts of aqueous polyacrylamide wax, 3-5 parts of aqueous dispersion, 3-8 parts of PH stabilizer, 10-16 parts of aqueous pigment, 3-5 parts of ethyl alcohol, remaining is water.Such water-based ink is suitable for the printing that print speed printing speed divides aluminium paper on intaglio printing press up to 120~150m/, has the features such as stability is good, and performance indicator of printed matter in terms of heat resistance, gold stamping is obviously improved, and has application value.
Description
Technical field
The invention belongs to ink areas, and in particular to be suitable on high-speed gravure press, print speed printing speed is up to 120~150m/
Point, it is fast compared with common offset machine (speed is 80~100m/ points).
Background technique
Aluminium paper is a kind of top grade packages printing paper as made of common blank sheet of paper deep processing.Its many advantages early the sixth of the twelve Earthly Branches
It is more smooth for known to insider, however since aluminium paper surface is metallic aluminium, and it is not easy blotting, printability and paper
It opens and is very different, main problem is exactly the drying of ink and the attachment fastness of trace and aluminium film.Therefore, aluminium paper gravure palpus
Using high-quality ink.Easily lead to that layer of ink film-formation result is poor, adhesive force is low easy to fall off when first commercially available water-based ink printing simultaneously.
For these reasons, the present invention provide a kind of aluminium paper aluminium paper water-based temperature resistant can gold stamping ink, ink mainly from
Under several point designs its formula: 1, as cry of the people to environmental protection is more more and more intense, especially atmospheric haze the problem of, day
Beneficial severe, country will also be increasingly stringenter enterprise's VOCs emission request, and the prosperity city such as Beijing, Shanghai, Zhejiang or province are first
The requirement about VOCs discharge has been put into effect afterwards.Water-based ink because its almost without volatile organic compounds VOCs discharge due to increasingly
It is valued by people and favors;2, at present because of intaglio printing press fast speed, to the adaptability of ink, more stringent requirements are proposed, separately
On the one hand, the more common alcohol ink evaporation rate of water-based ink is slow at present, when being further aggravated intaglio printing press application water-based ink at
Film property is poor, thus phenomena such as easily leading to printed matter scumming, pattern missing;3 but there are no a kind of water-based inks currently on the market can
Achieve the effect that directly it is gold stamping, temperature tolerance is poor.Printing factory, the general country republishes gloss oil on water-based ink usually to mention
The temperature tolerance of high printing, with realize can be gold stamping effect.4, described in comprehensive, this water-based ink can not only promote printed matter quality,
The cost of product can also be reduced, and reduces energy consumption resource.
Summary of the invention
It can gold stamping oil in view of the above problems, the object of the present invention is to provide the water-based temperature resistants on a kind of aluminium paper aluminium paper
Ink formulations solve the problems, such as this, and a kind of water-based temperature resistant of aluminium paper can gold stamping printing ink composition, wherein every 100 parts by weight
Composition includes aqueous vinyl chloride-vinyl acetate resin 10-20 parts, 20-30 parts of aqueous polyurethane resin, and 5-8 parts of aqueous polyacrylamide wax, aqueous point
3-5 parts of powder, 3-8 parts of PH stabilizer, 10-16 parts of aqueous pigment, 3-5 parts of ethyl alcohol, remaining is water.
Preferably, the aqueous vinyl chloride-vinyl acetate resin is aqueous vinyl chloride-vinyl acetate resin 701.
Preferably, the aqueous dispersion is WinSperse4000.
Preferably, the aqueous PH stabilizer is the mixing of monoethanolamine, glycol amine or monoethanolamine and glycol amine
Object.
Preferably, the aqueous polyurethane resin FW-33-37.
Preferably, the aqueous pigment is PR57:1.
Preferably, the aqueous polyacrylamide wax is aqueous polypropylene wax 2101.
It is a further object to provide the water-based temperature resistant of aluminium paper described above can gold stamping printing ink composition exist
Application in ink.The present invention it is some be preferably carried out in mode, the application method are as follows: by the aqueous of the aluminium paper
Heatproof can gold stamping printing ink composition through emulsifier high-speed stirred, grinder grinding after, obtain oil with ethanol water mixed diluting
Ink.In a specific embodiment of the invention, directly take color kind 500g that the dilution of the 1:1 mixed solution of 200g ethyl alcohol and water is added to make
For ink, the 1:1 of ethyl alcohol and water is then used to dilute 30-40% as upper machine oil ink again.
Compared with prior art, a kind of water-based temperature resistant of aluminium paper of the present invention can gold stamping printing ink composition beneficial effect
Be: (1) the composition formula is simple, promotes to improve ink by using aqueous polyurethane resin and aqueous polypropylene wax
Heatproof requirement, aqueous polyurethane resin improve the gold stamping performance of ink;(2) by organic pigment and composition be scattered in water and
In ethyl alcohol, pigment is allow to be attached to the material surface of aluminium paper, this ink can reach resistance to mild gold stamping effect.(3) such
Water-based ink is suitable for the printing that print speed printing speed divides aluminium paper on intaglio printing press up to 120~150m/, has stability and waits spies well
Point, performance indicator of printed matter in terms of heat resistance, gold stamping are obviously improved, and have application value.
Specific embodiment
The following examples are used to illustrate the present invention, but are not intended to limit the scope of the present invention..
About vinyl chloride-vinyl acetate resin 701 aqueous in being mentioned in Examples 1 to 3 and aqueous polyurethane resin FW-33-37 by new brightness
Chemical Co., Ltd. provides, and WinSperse4000 type dispersing agent is provided by dimension Persian material (Wei Fang) Co., Ltd, PH stabilizer
Monoethanolamine and glycol amine are provided by Aksu Nobel Co., Ltd, and aqueous face section PR57:1 is limited by Lay grace chemical industry
Company provides, and aqueous polypropylene wax 2101 is provided by new chemical materials Co., Ltd, Longhai City.
Embodiment 1
The composition of 2000g includes aqueous 701 300g of vinyl chloride-vinyl acetate resin, aqueous polyurethane resin FW-33-37 500g, water
Property 2101 130g of polypropylene wax, WinSperse4000 80g, monoethanolamine 110g, PR57:1 260g, ethyl alcohol 65g, remaining is
Water.With mulser high-speed stirred (2500-3000 turns stirring 30-40 minutes), then use grinder with 0.2-0.3L per minute again
Speed go to grind, grinding do relevant performance test afterwards three times, directly take color kind 500g that 200g ethyl alcohol is added to mix with the 1:1 of water
Solution dilution is used as ink, then uses the 1:1 of ethyl alcohol and water to dilute 30-40% as upper machine oil ink again, ink is applied to spray
Aluminium paper surface is tested after being put into the drying in 2 seconds of 80 degree of baking ovens, then after doing.
Embodiment 2
The composition of 2000g includes aqueous 701 370g of vinyl chloride-vinyl acetate resin, aqueous polyurethane resin FW-33-37 450g, water
Property 2101 110g of polypropylene wax, WinSperse4000 100g, monoethanolamine 100g, PR57:1 280g, ethyl alcohol 80g, remaining
For water.With mulser high-speed stirred (2500-3000 turns stirring 30-40 minutes), then use grinder with 0.2- per minute again
The speed of 0.3L goes to grind, and relevant performance test is done in grinding afterwards three times, and color kind 500g is directly taken to add the 1:1 of 150g ethyl alcohol and water
Mixed solution dilution is used as ink, then uses the 1:1 of ethyl alcohol and water to dilute 30-40% as upper machine oil ink again, ink is smeared
To aluminium paper surface, tested after being put into the drying in 2 seconds of 80 degree of baking ovens, then after doing.
Embodiment 3
The composition of 2000 parts by weight includes aqueous 701 260g of vinyl chloride-vinyl acetate resin, aqueous polyurethane resin FW-33-37
400g, aqueous 2101 150g of polypropylene wax, WinSperse4000 100g, glycol amine 90g, PR57:1 300g, ethyl alcohol 100g,
Remaining is water.With mulser high-speed stirred (2500-3000 turns stirring 30-40 minutes), then use grinder with per minute again
The speed of 0.2-0.3L goes to grind, and relevant performance test is done in grinding afterwards three times, and color kind 500g is directly taken to add 150g ethyl alcohol and water
The dilution of 1:1 mixed solution be used as ink, then use the 1:1 of ethyl alcohol and water to dilute 30-40% again black as upper machine oil, by ink
It is applied to aluminium paper surface, is tested after being put into the drying in 2 seconds of 80 degree of baking ovens, then after doing.
The test of test example ink performance
Embodiment 1-3 ink is subjected to correlated performance test, and using water-based ink currently on the market as reference examples, specifically
It the results are shown in Table 1.
The test of 1 ink performance of table
Claims (10)
1. a kind of water-based temperature resistant of aluminium paper can gold stamping printing ink composition, wherein the composition of every 100 parts by weight includes aqueous
10-20 parts of vinyl chloride-vinyl acetate resin, 20-30 parts of aqueous polyurethane resin, 5-8 parts of aqueous polyacrylamide wax, 3-5 parts of aqueous dispersion, PH is steady
Determine 3-8 parts of agent, 10-16 parts of aqueous pigment, 3-5 parts of ethyl alcohol, remaining is water.
2. the water-based temperature resistant of aluminium paper according to claim 1 can gold stamping printing ink composition, wherein the aqueous chlorine vinegar
Resin is aqueous vinyl chloride-vinyl acetate resin 701.
3. the water-based temperature resistant of aluminium paper according to claim 1 can gold stamping printing ink composition, wherein the aqueous dispersion
Agent is WinSperse4000.
4. the water-based temperature resistant of aluminium paper according to claim 1 can gold stamping printing ink composition, wherein the aqueous PH is steady
Determine the mixture that agent is monoethanolamine, glycol amine or monoethanolamine and glycol amine.
5. the water-based temperature resistant of aluminium paper can gold stamping printing ink composition according to claim 1, wherein the aqueous polyurethane
Resin FW-33-37.
6. the water-based temperature resistant of aluminium paper according to claim 1 can gold stamping printing ink composition, wherein the aqueous pigment
For PR57:1.
7. the water-based temperature resistant of aluminium paper according to claim 1 can gold stamping printing ink composition, wherein described aqueous poly- third
Alkene wax is aqueous polypropylene wax 2101.
8. the water-based temperature resistant of the aluminium paper as described in claim 1~7 can application of the gold stamping printing ink composition in ink.
9. the water-based temperature resistant of aluminium paper as claimed in claim 8 can application of the gold stamping printing ink composition in ink, wherein
The application method are as follows: by the water-based temperature resistant of the aluminium paper can gold stamping printing ink composition through emulsifier high-speed stirred, grinding
After machine grinding, ink is obtained with ethanol water mixed diluting.
10. the water-based temperature resistant of aluminium paper as claimed in claim 9 can application of the gold stamping printing ink composition in ink,
In, ethyl alcohol and water ratio are 1:1. in the ethanol water.
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CN201811117759.2A CN109439062A (en) | 2018-09-21 | 2018-09-21 | A kind of water-based temperature resistant of aluminium paper can gold stamping printing ink composition |
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CN201811117759.2A CN109439062A (en) | 2018-09-21 | 2018-09-21 | A kind of water-based temperature resistant of aluminium paper can gold stamping printing ink composition |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115466539A (en) * | 2022-09-13 | 2022-12-13 | 茂名阪田油墨有限公司 | Hot-stamping-resistant black ink |
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CN103709839A (en) * | 2013-12-30 | 2014-04-09 | 东莞光群雷射科技有限公司 | Gilding liquid cement and preparation method thereof as well as application of titanium dioxide in gilding liquid cement |
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CN105062346A (en) * | 2015-09-02 | 2015-11-18 | 上海睿途新材料科技有限公司 | Golden water-based paint for vacuum aluminized paper and preparation method thereof |
CN107903708A (en) * | 2018-01-15 | 2018-04-13 | 浙江美浓世纪集团有限公司 | The water-based low VOC ink of special laser cigarette external packaging of aluminizing |
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2018
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Patent Citations (6)
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WO2009024471A1 (en) * | 2007-08-20 | 2009-02-26 | Basf Se | Process for preparing platelet-like pigments comprising a nitrogen doped carbon coating |
CN102719125A (en) * | 2012-06-12 | 2012-10-10 | 天长市巨龙车船涂料有限公司 | Anti-sticking water-based coating |
CN103709839A (en) * | 2013-12-30 | 2014-04-09 | 东莞光群雷射科技有限公司 | Gilding liquid cement and preparation method thereof as well as application of titanium dioxide in gilding liquid cement |
CN104031472A (en) * | 2014-06-05 | 2014-09-10 | 哈尔滨绿科科技有限公司 | Water-based electrochemical aluminum packaging composite film color layer ink |
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CN107903708A (en) * | 2018-01-15 | 2018-04-13 | 浙江美浓世纪集团有限公司 | The water-based low VOC ink of special laser cigarette external packaging of aluminizing |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN115466539A (en) * | 2022-09-13 | 2022-12-13 | 茂名阪田油墨有限公司 | Hot-stamping-resistant black ink |
CN115466539B (en) * | 2022-09-13 | 2023-09-15 | 茂名阪田油墨有限公司 | Thermoprint-resistant black ink |
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Application publication date: 20190308 |