CN109439025A - A kind of black limed rosin enamel-interior - Google Patents

A kind of black limed rosin enamel-interior Download PDF

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Publication number
CN109439025A
CN109439025A CN201710755279.8A CN201710755279A CN109439025A CN 109439025 A CN109439025 A CN 109439025A CN 201710755279 A CN201710755279 A CN 201710755279A CN 109439025 A CN109439025 A CN 109439025A
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China
Prior art keywords
parts
black
enamel
interior
raw material
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CN201710755279.8A
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Chinese (zh)
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陈玉清
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Individual
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Individual
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Priority to CN201710755279.8A priority Critical patent/CN109439025A/en
Publication of CN109439025A publication Critical patent/CN109439025A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/23Magnetisable or magnetic paints or lacquers

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of black limed rosin enamel-interiors, belong to technical field of coatings, the raw material including following parts by weight: 10~40 parts of carbon black, 25~55 parts of precipitated calcium carbonate, 10~20 parts of blanc fixe, 2~3 parts of titanium dioxide and 1~3 part of vinyl unsaturated carboxylic acid.A kind of black limed rosin enamel-interior of the invention, using carbon black as film forming matter, and using vitreum earth silicon material, special ceramic materials, vinyl unsaturated carboxylic acid, fibrous material as filler, insulation antiseptic anticorrosive paint is made, a kind of waterproof heat insulation coating is made using raw materials such as elastic emulsion, hollow glass micropearl, diatomite, infrared reflection agent, asbestos wools, the coating, which only coats 2mm thickness, can reach good waterproof thermal-insulated effect, it can also be used to make the top finishing of interior metal and wooden object.

Description

A kind of black limed rosin enamel-interior
Technical field
The invention belongs to technical field of coatings, and in particular to a kind of black limed rosin enamel-interior.
Background technique
The performance of acrylic rubber is influenced by atomic number of alkyl carbon purpose in its principal monomer alkyl acrylate.With third Rubber based on olefin(e) acid ester, oil resistant, heat resistance are preferable;And the rubber based on butyl acrylate, because of atomic number of alkyl carbon Purpose increases, and increases the screen effect of ester group polar group, therefore water resistance is made to make moderate progress, simultaneously because screen effect, subtracts Power between weak rubber molecule, increases internal plasticity, so that brittleness temperature be made to reduce, cold resistance is preferable.If by above two Monomer is used in combination, then the rubber between the two performance can be obtained.
Anticorrosive paint is generally divided into conventional anticorrosive paint and anticorrosive paint, is essential one kind in paint Coating.Conventional anticorrosive paint is under general condition, to play the role of the longevity etch-proof, protection non-ferrous metal uses to metal etc. Life;It for anticorrosive paint refers to relatively conventional anticorrosive paint, can be applied in relatively harsh corrosive environment, and have and can reach A kind of anticorrosive paint of protection period longer than conventional anticorrosive paint.
Nowadays anticorrosive paint has become the important fresh combatants of paint field, and anticorrosive paint plays increasing work With development prospect is considerable.But traditional product gradually improves perfect, new product and constantly researches and develops appearance, Yao Shiying anticorrosion market and New standard and requirement in environmental regulation development, it is still necessary to proactive, Continuous Innovation.
No matter the acrylic rubber of which seed type, there are two the common features of molecular structure: first is that highly polar;Two It is fully saturated property.To make it have superior resistance to mineral oil and pyro-oxidation resistance.Its oil resistivity is only second to fluorine glue, and To it is general in the nitrile rubber of high acrylonitrile content it is similar.And heat resistance compares butyronitrile between general purpose rubber and silicon, fluorubber Rubber is higher by 30~60 DEG C using temperature, 180 DEG C of maximum operation (service) temperature, discontinuously uses with the short time up to 200 DEG C, at 150 DEG C The hot air aging several years, performance was without significant change.Furthermore, it is most important that it is to the extreme pressure type containing extreme pressure agents such as sulphur, chlorine, phosphorus Lubricating oil is sufficiently stable, and using temperature up to 150 DEG C, interruption can be higher using temperature.And the nitrile rubber with double bond exists In oil containing extreme pressure agent, when temperature is more than 110 DEG C, that is, significant hardening occurs and becomes fragile.Acrylic rubber also has excellent Good ozone resistants, air-tightness, resistance to flexion and resistance to breach growth property and uvioresistant discolouration etc..
Summary of the invention
Goal of the invention: the purpose of the present invention is to provide a kind of black limed rosin enamel-interiors.
Technical solution: for achieving the above object, the present invention adopts the following technical scheme:
A kind of black limed rosin enamel-interior, the raw material including following parts by weight: 10~40 parts of carbon black, precipitated calcium carbonate 25 ~55 parts, 10~20 parts of blanc fixe, 2~3 parts of titanium dioxide and 1~3 part of vinyl unsaturated carboxylic acid.
The raw material further includes the improved silica that parts by weight are 5~10 parts.
The raw material further includes the kaolin that parts by weight are 2~3 parts.
The raw material further includes the silica for the vitreum that parts by weight are 5~10 parts.
The raw material further includes the calcium carbonate that parts by weight are 5~10 parts.
The utility model has the advantages that compared with prior art, a kind of black limed rosin enamel-interior of the invention, using carbon black as film forming matter Matter, and using vitreum earth silicon material, special ceramic materials, vinyl unsaturated carboxylic acid, fibrous material as filler, guarantor is made Warm anti-corrosion anticorrosive paint is made using raw materials such as elastic emulsion, hollow glass micropearl, diatomite, infrared reflection agent, asbestos wools A kind of waterproof heat insulation coating, which, which only coats 2mm thickness, can reach good waterproof thermal-insulated effect.
Specific embodiment
The present invention is described further With reference to embodiment.
Embodiment 1
A kind of black limed rosin enamel-interior, the raw material including following parts by weight: 10 parts of carbon black, 25 parts of precipitated calcium carbonate, 10 parts of blanc fixe, 2 parts of titanium dioxide and 1 part of vinyl unsaturated carboxylic acid.
Raw material further includes the titanium dioxide that parts by weight are 5 parts of improved silica, 2 parts of kaolin, 5 parts of vitreum Silicon.
Embodiment 2
A kind of black limed rosin enamel-interior, the raw material including following parts by weight: 40 parts of carbon black, 55 parts of precipitated calcium carbonate, 20 parts of blanc fixe, 3 parts of titanium dioxide and 3 parts of vinyl unsaturated carboxylic acid.
Raw material further includes the dioxy that parts by weight are 10 parts of improved silica, 3 parts of kaolin, 10 parts of vitreum SiClx.
Embodiment 3
A kind of black limed rosin enamel-interior, the raw material including following parts by weight: 15 parts of carbon black, 30 parts of precipitated calcium carbonate, 12 parts of blanc fixe, 2.2 parts of titanium dioxide and 1.5 parts of vinyl unsaturated carboxylic acid.
Raw material further includes the dioxy that parts by weight are 6 parts of improved silica, 2.5 parts of kaolin, 7 parts of vitreum SiClx.
Embodiment 4
A kind of black limed rosin enamel-interior, the raw material including following parts by weight: 30 parts of carbon black, 25 parts of precipitated calcium carbonate, 20 parts of blanc fixe, 3 parts of titanium dioxide and 1 part of vinyl unsaturated carboxylic acid.
Raw material further includes the dioxy that parts by weight are 10 parts of improved silica, 3 parts of kaolin, 8 parts of vitreum SiClx.
Embodiment 5
A kind of black limed rosin enamel-interior, the raw material including following parts by weight: 40 parts of carbon black, 55 parts of precipitated calcium carbonate, 20 parts of blanc fixe, 3 parts of titanium dioxide and 1 part of vinyl unsaturated carboxylic acid.
Raw material further includes the dioxy that parts by weight are 10 parts of improved silica, 3 parts of kaolin, 8 parts of vitreum SiClx.
To sum up:
Disadvantage
Poor processability, the easy roll banding of sizing material, flow velocity is slow, and cold resistance is poor, not resistant to water, vapor, soda acid, salting liquid and has Machine polar solvent, poor flexibility at room temperature wear no resistance, poor electrical performance.
It is 180 DEG C of manufacture since acrylic rubber is only second to fluorubber in terms of heat-resisting and oil resistant comprehensive performance Rubber oil sea, O-ring, gasket and the sebific duct used under high temperature uses material.Again because of its stabilization to high temperature extreme pressure lublicating oil Property, therefore had comparative advantage in the world with making all kinds of automobile sealed accessories.Additionally using the excellent spy of acrylic rubber Property manufacture adhesive tape, container lining, deep prospecting rubber product, sponge oil resistant gasket and oil resistant asbestos-rubber product Deng.Acrylic rubber is also applied in the hard-core technologies such as aviation, rocket, guided missile department.As being used to prepare solid fuel Adhesive etc..
Effect
Since the solubility parameter of polyacrylate and the solubility parameter of uncured epoxy resin are not much different, the two has Good intersolubility.Again because polyacrylate backbone is free of double bond, it has good thermal oxidation resistance effect.
The determinant of acrylic liquid rubber flexibilizing epoxy has: whether rubber phase forms, the composition and bullet of rubber phase Property, the size distribution of rubber phase particles, the chemical bonding and epoxy resin-base molecule knot of rubber phase and epoxy resin-base The epoxy-functional concentration etc. of l in structure and its molecule.Wherein principal element is the Phase stracture of solidified resin system, rubber phase With the chemical bonding of epoxy matrix and the ductility of epoxy-resin systems itself, acrylic liquid rubber flexibilizing epoxy system | Phase structure to be mainly rubber phase be dispersed in epoxy matrix with the spherical particle of rule, dispersed phase by differ in size two Kind spheroidal particle composition.
The two poles of the earth distribution of particle size is beneficial to toughening.Small particle mainly works to shear-deformable, big Grain can prevent the growth of crackle.In this way, it is to Toughening Epoxy Resin, the good results are evident.

Claims (5)

1. a kind of black limed rosin enamel-interior, it is characterised in that: the raw material including following parts by weight: 10~40 parts of carbon black, light 25~55 parts of matter calcium carbonate, 10~20 parts of blanc fixe, 2~3 parts of titanium dioxide and 1~3 part of vinyl unsaturated carboxylic acid.
2. a kind of black limed rosin enamel-interior according to claim 1, it is characterised in that: the raw material further includes weight The improved silica that number is 5~10 parts.
3. a kind of black limed rosin enamel-interior according to claim 1, it is characterised in that: the raw material further includes weight The kaolin that number is 2~3 parts.
4. a kind of black limed rosin enamel-interior according to claim 1, it is characterised in that: the raw material further includes weight The silica for the vitreum that number is 5~10 parts.
5. a kind of black limed rosin enamel-interior according to claim 1, it is characterised in that: the raw material further includes weight The calcium carbonate that number is 5~10 parts.
CN201710755279.8A 2017-08-29 2017-08-29 A kind of black limed rosin enamel-interior Pending CN109439025A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710755279.8A CN109439025A (en) 2017-08-29 2017-08-29 A kind of black limed rosin enamel-interior

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710755279.8A CN109439025A (en) 2017-08-29 2017-08-29 A kind of black limed rosin enamel-interior

Publications (1)

Publication Number Publication Date
CN109439025A true CN109439025A (en) 2019-03-08

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710755279.8A Pending CN109439025A (en) 2017-08-29 2017-08-29 A kind of black limed rosin enamel-interior

Country Status (1)

Country Link
CN (1) CN109439025A (en)

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Application publication date: 20190308

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