CN109437681A - A kind of composite fireproof plate and preparation method thereof - Google Patents
A kind of composite fireproof plate and preparation method thereof Download PDFInfo
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- CN109437681A CN109437681A CN201811451179.7A CN201811451179A CN109437681A CN 109437681 A CN109437681 A CN 109437681A CN 201811451179 A CN201811451179 A CN 201811451179A CN 109437681 A CN109437681 A CN 109437681A
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- fireproof plate
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/30—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Other silicon-containing organic compounds; Boron-organic compounds
- C04B26/32—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Other silicon-containing organic compounds; Boron-organic compounds containing silicon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D7/00—Producing flat articles, e.g. films or sheets
- B29D7/01—Films or sheets
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/27—Water resistance, i.e. waterproof or water-repellent materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/28—Fire resistance, i.e. materials resistant to accidental fires or high temperatures
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/76—Use at unusual temperatures, e.g. sub-zero
Abstract
The invention discloses a kind of composite fireproof plate and preparation method thereof, this method reasonable disposition fire prevention materials, by the way that a kind of fire-proof board of high-quality is made by the fire prevention material of different ratio and the compression moulding of skeleton reinforcing material.Using fire-proof plate obtained by the method for the present invention, fire resistance rating reaches A1 grades, and smoke toxicity reaches AQ1 grades, and has good water resistance, resistance to acid and alkali and freeze-thaw resistance simultaneously.
Description
Technical field
The present invention relates to a kind of composite fireproof plates and preparation method thereof, belong to fire-proof plate technical field.
Background technique
Fire-proof plate also known as refractory slab are widely used in the fields such as interior decoration, furniture, kitchen cabinet, laboratory table top, exterior wall.It is anti-
Fiery performance is to judge the important indicator of fire-proof plate quality, and fire-protection rating is too low, in the application of plate, if encountering the feelings such as open fire
The flameproof effect of condition, plate is poor, is easy to produce fire.The acid-proof alkaline of plate be judge board quality another is important
Index, conventional plate performance in terms of acid and alkali-resistance is poor, constrains the application range of plate.In addition, pursuing green in the whole people
Under the trend of environmental protection, the smoke toxicity etc. of plate is also to influence an important factor for plate promotes and applies.However, current plate on the market
Material is still difficult to meet requirement of the people to the above index simultaneously, and integrated quality still needs to be further increased.
Summary of the invention
In consideration of it, the present invention, which provides a kind of composite fireproof plate and preparation method thereof, solves problem above.
The technical solution adopted by the present invention is as follows:
A kind of preparation method of composite fireproof plate, comprising the following steps:
(1) by weight, take 30~40 parts of hydroxy silicon oils, 20~30 parts of ethyl containing hydrogen silicone oils and 55~80 parts fire-retardant
Agent, 20~30 DEG C stir evenly, and add 20~30 parts of expanded vermiculites and stir evenly, are finally added 5 under the conditions of 35~40 DEG C
~10 parts of methyl tributanoximo silanes, stir evenly, obtain first material；
By weight, 20~30 parts of ethyl containing hydrogen silicone oils and 25~40 parts of fire retardants are taken, 25~35 DEG C stir evenly, then
20~30 parts of floating beads of addition, 10~20 parts of expanded graphites stir evenly, and 5~10 parts of ethylene are finally added under the conditions of 30~40 DEG C
Base tributanoximo silane and 2~3 parts of methyl tributanoximo silanes, stir evenly, obtain second material；
(2) it is first laid with first material, by sequence from bottom to up, fiberglass gridding cloth, the are laid in first material
Two materials, fiberglass gridding cloth, first material and carbon fiber board, then hydro-forming is carried out, it demoulds, solidification is to get compound anti-
Fiery plate；
The fire retardant is melamine, dipentaerythritol, ammonium polyphosphate, aluminium hydroxide, magnesium chloride, aluminium chloride, oxidation
Magnesium, sodium alginate, glycerol and precipitated calcium carbonate mixture.
Preferably, the first material are as follows: by weight, take 35 parts of hydroxy silicon oils, 20 parts of ethyl containing hydrogen silicone oils and 60
Part fire retardant, 20~30 DEG C stir evenly, and add 25 parts of expanded vermiculites and stir evenly, and 6 parts are finally added under the conditions of 40 DEG C
Methyl tributanoximo silane stirs evenly, and obtains first material.
Preferably, the second material are as follows: by weight, take 25 parts of ethyl containing hydrogen silicone oils and 30 parts of fire retardants, 25~
35 DEG C stir evenly, and add 20 parts of floating beads, 15 parts of expanded graphites stir evenly, finally 6 parts of addition under the conditions of 30~40 DEG C
Vinyl tributyl ketoximyl silane and 2 parts of methyl tributanoximo silanes, stir evenly, obtain second material.
Preferably, the fire retardant is melamine, dipentaerythritol, ammonium polyphosphate, aluminium hydroxide, magnesium chloride, chlorination
Aluminium, magnesia, sodium alginate, glycerol and precipitated calcium carbonate 10:(3~5 in mass ratio): (3~5): (1~2): (9~12): (2
~8): (2~8): (0.3~0.5): (1~3): the mixture of (9~10).
Preferably, the fire retardant is melamine, dipentaerythritol, ammonium polyphosphate, aluminium hydroxide, magnesium chloride, chlorination
Aluminium, magnesia, sodium alginate, glycerol and the precipitated calcium carbonate mixture of 10:3:3:1:12:3:3:0.5:2:10 in mass ratio.
Preferably, the laying depth of first material and second material is 6~8mm in step (2).
The present invention also provides the fire-proof plate as made from the method for the present invention, the composite fireproof plate with a thickness of 12~
15mm。
Compared with prior art, the beneficial effects of the present invention are:
Using fire-proof plate obtained by the method for the present invention, fire resistance rating reaches A1 grades, and smoke toxicity reaches AQ1 grades, and simultaneously
It is a kind of fire-proof board of high-quality with good water resistance, resistance to acid and alkali and freeze-thaw resistance.
Preparation process of the present invention is simple, and raw material sources are extensive, cheap and easily-available, is suitable for industrialized production.
Specific embodiment
Below by specific embodiment, invention is further described in detail.
Experimental method used in the embodiment of the present invention is conventional method unless otherwise specified.
Material used in the embodiment of the present invention, reagent etc., are commercially available unless otherwise specified.
Embodiment 1
A kind of preparation method of composite fireproof plate, comprising the following steps:
(1) by weight, 35 parts of hydroxy silicon oils, 20 parts of ethyl containing hydrogen silicone oils and 60 parts of fire retardants are taken, 30 DEG C of stirrings are equal
It is even, it adds 25 parts of expanded vermiculites and stirs evenly, it is equal that 6 parts of methyl tributanoximo silane stirrings are finally added under the conditions of 40 DEG C
It is even, obtain first material；
By weight, 25 parts of ethyl containing hydrogen silicone oils and 30 parts of fire retardants are taken, 25 DEG C stir evenly, and add 20 parts of drifts
Pearl, 15 parts of expanded graphites stir evenly, and 6 parts of vinyl tributyl ketoximyl silanes and 2 parts of methyl are finally added under the conditions of 40 DEG C
Tributanoximo silane stirs evenly, and obtains second material；
(2) it is first laid with first material, by sequence from bottom to up, fiberglass gridding cloth, the are laid in first material
Two materials, fiberglass gridding cloth, first material and carbon fiber board, then hydro-forming is carried out, it demoulds, solidification is to get compound anti-
Fiery plate；The laying depth of first material and second material is 6~8mm；
The fire retardant is melamine, dipentaerythritol, ammonium polyphosphate, aluminium hydroxide, magnesium chloride, aluminium chloride, oxidation
Magnesium, sodium alginate, glycerol and the precipitated calcium carbonate mixture of 10:3:3:1:12:3:3:0.5:2:10 in mass ratio.
The composite fireproof plate with a thickness of 12~15mm.
Embodiment 2
A kind of preparation method of composite fireproof plate, comprising the following steps:
(1) by weight, 30 parts of hydroxy silicon oils, 20 parts of ethyl containing hydrogen silicone oils and 55 parts of fire retardants are taken, 20 DEG C of stirrings are equal
It is even, it adds 20 parts of expanded vermiculites and stirs evenly, 5 parts of methyl tributanoximo silanes, stirring are finally added under the conditions of 35 DEG C
Uniformly, first material is obtained；
By weight, 20 parts of ethyl containing hydrogen silicone oils and 25 parts of fire retardants are taken, 25 DEG C stir evenly, and add 20 parts of drifts
Pearl, 10 parts of expanded graphites stir evenly, and 5 parts of vinyl tributyl ketoximyl silanes and 2 parts of methyl are finally added under the conditions of 30 DEG C
Tributanoximo silane stirs evenly, and obtains second material；
(2) it is first laid with first material, by sequence from bottom to up, fiberglass gridding cloth, the are laid in first material
Two materials, fiberglass gridding cloth, first material and carbon fiber board, then hydro-forming is carried out, it demoulds, solidification is to get compound anti-
Fiery plate；The laying depth of first material and second material is 6~8mm；
The fire retardant is melamine, dipentaerythritol, ammonium polyphosphate, aluminium hydroxide, magnesium chloride, aluminium chloride, oxidation
Magnesium, sodium alginate, glycerol and the precipitated calcium carbonate mixture of 10:3:3:1:9:2:2:0.3:1:9 in mass ratio.
The composite fireproof plate with a thickness of 12~15mm.
Embodiment 3
A kind of preparation method of composite fireproof plate, comprising the following steps:
(1) by weight, 40 parts of hydroxy silicon oils, 30 parts of ethyl containing hydrogen silicone oils and 80 parts of fire retardants are taken, 30 DEG C of stirrings are equal
It is even, it adds 30 parts of expanded vermiculites and stirs evenly, 10 parts of methyl tributanoximo silanes, stirring are finally added under the conditions of 40 DEG C
Uniformly, first material is obtained；
By weight, 30 parts of ethyl containing hydrogen silicone oils and 40 parts of fire retardants are taken, 35 DEG C stir evenly, and add 30 parts of drifts
Pearl, 20 parts of expanded graphites stir evenly, and 10 parts of vinyl tributyl ketoximyl silanes and 3 parts of methyl are finally added under the conditions of 40 DEG C
Tributanoximo silane stirs evenly, and obtains second material；
(2) it is first laid with first material, by sequence from bottom to up, fiberglass gridding cloth, the are laid in first material
Two materials, fiberglass gridding cloth, first material and carbon fiber board, then hydro-forming is carried out, it demoulds, solidification is to get compound anti-
Fiery plate；The laying depth of first material and second material is 6~8mm
The fire retardant is melamine, dipentaerythritol, ammonium polyphosphate, aluminium hydroxide, magnesium chloride, aluminium chloride, oxidation
Magnesium, sodium alginate, glycerol and the precipitated calcium carbonate mixture of 10:5:5:2:12:8:8:0.5:3:10 in mass ratio.
The present invention also provides the fire-proof plate as made from the method for the present invention, the composite fireproof plate with a thickness of 12~
15mm。
Comparative example 1
A kind of preparation method of composite fireproof plate, comprising the following steps:
(1) by weight, 25 parts of hydroxy silicon oils, 20 parts of ethyl containing hydrogen silicone oils and 50 parts of fire retardants are taken, 25 DEG C of stirrings are equal
It is even, it adds 15 parts of expanded vermiculites and stirs evenly, 5 parts of methyl tributanoximo silanes, stirring are finally added under the conditions of 35 DEG C
Uniformly, first material is obtained；
By weight, 20 parts of ethyl containing hydrogen silicone oils and 20 parts of fire retardants are taken, 30 DEG C stir evenly, and add 20 parts of drifts
Pearl, 5 parts of expanded graphites stir evenly, and 3 parts of vinyl tributyl ketoximyl silanes and 1 part of methyl three are finally added under the conditions of 25 DEG C
Butanone oximino silane, stirs evenly, and obtains second material；
(2) it is first laid with first material, by sequence from bottom to up, fiberglass gridding cloth, the are laid in first material
Two materials, fiberglass gridding cloth, first material and carbon fiber board, then hydro-forming is carried out, it demoulds, solidification is to get compound anti-
Fiery plate；
The fire retardant is melamine, dipentaerythritol, ammonium polyphosphate, aluminium hydroxide, magnesium chloride, aluminium chloride, oxidation
Magnesium, sodium alginate, glycerol and the precipitated calcium carbonate mixture of 10:2:2:1:5:3:1:0.2:1:5 in mass ratio.
The laying depth of first material and second material is 6~8mm in step (2).
The composite fireproof plate with a thickness of 20~25mm.
Comparative example 2
A kind of preparation method of composite fireproof plate, comprising the following steps:
(1) by weight, 50 parts of hydroxy silicon oils, 20 parts of ethyl containing hydrogen silicone oils and 90 parts of fire retardants are taken, 25 DEG C of stirrings are equal
It is even, it adds 35 parts of expanded vermiculites and stirs evenly, 5 parts of methyl tributanoximo silanes, stirring are finally added under the conditions of 50 DEG C
Uniformly, first material is obtained；
By weight, 35 parts of ethyl containing hydrogen silicone oils and 40 parts of fire retardants are taken, 50 DEG C stir evenly, and add 30 parts of drifts
Pearl, 25 parts of expanded graphites stir evenly, and 15 parts of vinyl tributyl ketoximyl silanes and 5 parts of methyl are finally added under the conditions of 45 DEG C
Tributanoximo silane stirs evenly, and obtains second material；
(2) it is first laid with first material, by sequence from bottom to up, fiberglass gridding cloth, the are laid in first material
Two materials, fiberglass gridding cloth, first material and carbon fiber board, then hydro-forming is carried out, it demoulds, solidification is to get compound anti-
Fiery plate；
The fire retardant is melamine, dipentaerythritol, ammonium polyphosphate, aluminium hydroxide, magnesium chloride, aluminium chloride, oxidation
Magnesium, sodium alginate, glycerol and the precipitated calcium carbonate mixture of 10:8:6:1:15:8:10:0.3:1:9 in mass ratio.
The laying depth of first material and second material is 6~8mm in step (2).
The composite fireproof plate with a thickness of 8~10mm.
Comparative example 3
Comparative example 3 the difference from embodiment 1 is that, fire retardant be free of sodium alginate and glycerol.
Comparative example 4
Comparative example 4 the difference from embodiment 1 is that, second material use first material formula and method.
Test example:
Meet the performance data part table 1 of fire-proof plate as made from embodiment and comparative example the method.
Reference standard: GB8624-2012 construction material and classification of combustion properties of building materials and products, GB/T 20285-2006 material produce
The smoke toxicity classification of risks, GB23864-2009 fire-proof sealing material.
Table 1
Test result shows that, using fire-proof plate obtained by the method for the present invention, fire resistance rating reaches A1 grades, and smoke toxicity reaches
AQ1 grades, and there is good water resistance, resistance to acid and alkali and freeze-thaw resistance simultaneously, it is a kind of fire-proof board of high-quality.
The above content is specific embodiment is combined, further detailed description of the invention, and it cannot be said that this hair
Bright specific implementation is only limited to these instructions.For those of ordinary skill in the art to which the present invention belongs, it is not taking off
Under the premise of from present inventive concept, a number of simple deductions or replacements can also be made.
Claims (8)
1. a kind of preparation method of composite fireproof plate, which comprises the following steps:
(1) by weight, 30~40 parts of hydroxy silicon oils, 20~30 parts of ethyl containing hydrogen silicone oils and 55~80 parts of fire retardants are taken, 20
~30 DEG C stir evenly, and add 20~30 parts of expanded vermiculites and stir evenly, and 5~10 parts are finally added under the conditions of 35~40 DEG C
Methyl tributanoximo silane stirs evenly, and obtains first material；
By weight, 20~30 parts of ethyl containing hydrogen silicone oils and 25~40 parts of fire retardants are taken, 25~35 DEG C stir evenly, and add
20~30 parts of floating beads, 10~20 parts of expanded graphites stir evenly, and 5~10 parts of vinyl three are finally added under the conditions of 30~40 DEG C
Butanone oximino silane and 2~3 parts of methyl tributanoximo silanes, stir evenly, obtain second material；
(2) it is first laid with first material, by sequence from bottom to up, fiberglass gridding cloth, the second object are laid in first material
Material, fiberglass gridding cloth, first material and carbon fiber board, then hydro-forming is carried out, it demoulds, solidifies to get composite fireproof plate；
The fire retardant is melamine, dipentaerythritol, ammonium polyphosphate, aluminium hydroxide, magnesium chloride, aluminium chloride, magnesia, sea
The mixture of mosanom, glycerol and precipitated calcium carbonate.
2. the preparation method of composite fireproof plate according to claim 1, which is characterized in that the first material are as follows: by weight
Part meter is measured, takes 35 parts of hydroxy silicon oils, 20 parts of ethyl containing hydrogen silicone oils and 60 parts of fire retardants, 20~30 DEG C stir evenly, and add 25
Part expanded vermiculite stirs evenly, and 6 parts of methyl tributanoximo silanes are finally added under the conditions of 40 DEG C and stir evenly, obtain the first object
Material.
3. the preparation method of composite fireproof plate according to claim 1, which is characterized in that the second material are as follows: by weight
Measure part meter, take 25 parts of ethyl containing hydrogen silicone oils and 30 parts of fire retardants, 25~35 DEG C stir evenly, add 20 parts of floating beads, 15 parts it is swollen
Swollen graphite stirs evenly, and 6 parts of vinyl tributyl ketoximyl silanes and 2 parts of three butanone of methyl are finally added under the conditions of 30~40 DEG C
Oximino silane stirs evenly, and obtains second material.
4. the preparation method of composite fireproof plate according to claim 1, which is characterized in that the fire retardant is melamine
Amine, dipentaerythritol, ammonium polyphosphate, aluminium hydroxide, magnesium chloride, aluminium chloride, magnesia, sodium alginate, glycerol and lightweight carbonic acid
Calcium 10:(3~5 in mass ratio): (3~5): (1~2): (9~12): (2~8): (2~8): (0.3~0.5): (1~3): (9
~10) mixture.
5. the preparation method of composite fireproof plate according to claim 1, which is characterized in that the fire retardant is melamine
Amine, dipentaerythritol, ammonium polyphosphate, aluminium hydroxide, magnesium chloride, aluminium chloride, magnesia, sodium alginate, glycerol and lightweight carbonic acid
The calcium mixture of 10:3:3:1:12:3:3:0.5:2:10 in mass ratio.
6. the preparation method of composite fireproof plate according to claim 1, which is characterized in that in step (2) first material and
The laying depth of second material is 6~8mm.
7. a kind of composite fireproof plate, which is characterized in that be made up of the described in any item preparation methods of claim 1~6.
8. composite fireproof plate according to claim 7, which is characterized in that the composite fireproof plate with a thickness of 12~
15mm。
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN113306237A (en) * | 2021-05-26 | 2021-08-27 | 邓州市新艺木业有限责任公司 | Flame-retardant polymer composite board and preparation method thereof |
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| CN103350535A (en) * | 2013-06-25 | 2013-10-16 | 海龙核材科技（江苏）有限公司 | Preparation method of novel composite fireproof plate |
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2018
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103350535A (en) * | 2013-06-25 | 2013-10-16 | 海龙核材科技（江苏）有限公司 | Preparation method of novel composite fireproof plate |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN113306237A (en) * | 2021-05-26 | 2021-08-27 | 邓州市新艺木业有限责任公司 | Flame-retardant polymer composite board and preparation method thereof |
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Application publication date: 20190308 |