CN109233402A - A kind of water-fast fire-proof dilatation with microcellular structure - Google Patents
A kind of water-fast fire-proof dilatation with microcellular structure Download PDFInfo
- Publication number
- CN109233402A CN109233402A CN201811056941.1A CN201811056941A CN109233402A CN 109233402 A CN109233402 A CN 109233402A CN 201811056941 A CN201811056941 A CN 201811056941A CN 109233402 A CN109233402 A CN 109233402A
- Authority
- CN
- China
- Prior art keywords
- water
- parts
- coating
- microcellular structure
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
- C09D5/185—Intumescent paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/04—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C09D127/08—Homopolymers or copolymers of vinylidene chloride
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/322—Ammonium phosphate
- C08K2003/323—Ammonium polyphosphate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
A kind of water-fast fire-proof dilatation with microcellular structure, it is related to a kind of coating, the fireproof coating is using aqueous high molecular lotion as film forming agent, there is high migration in film forming agent, after low-volatile oil-based liquid pore former migrates, a large amount of hole-closing structures, the catalyst in this structure and film forming agent are formed in film forming agent, the component proportions such as foaming agent and carbon forming agent, which reach, most preferably makes fireproof coating have splendid flame retardant effect.Height migration, after low-volatile oil-based liquid pore former moves to coating surface layer, will form excellent water-resistant layer, and the coating after making drying has fabulous water resistance.In the present invention, the micropore thermal conductivity in coating is extremely low, and the oiliness water-resistant layer on surface, which avoids coating and impregnates in water for a long time, blisters, obscission.The features such as coating storage is stablized, good decorative property, easy for construction, non smoke or few smog generate when burning, particularly suitable for making ultrathin structure fire coating, finishing fire retardant paint and cable fire-refractory coating.
Description
Technical field
The present invention relates to a kind of coating, more particularly to a kind of water-fast fire-proof dilatation with microcellular structure.
Background technique
The development of China's cable fire-refractory coating product starts from the early 1980s, being in finishing fire retardant paint base
Grow up on plinth, occur that the inorganic fireproof coating using sodium silicate as film forming agent in early days, its own does not burn, and meets fiery energy
A small amount of hollow alveolar layer is formed, has certain flameproof protection to act on cable, but its heat insulation fire retardant, weatherability, flexibility are all
It is very poor, it is easy cracking, chance water is fallen off.Due to the defect of inorganic fireproof coating, so that people transfer primary study organic bentonite
Swollen type fireproof coating.Currently, organic expander type fireproof coating is made with modified amido or superchlorinated polyvinyl chloride resin and chlorinated rubber
Base-material, add a variety of fire-proof flame-retarded agents, plasticizer, solvent etc. composition, this kind of solvent based coating there are the toxicity of solvent, price,
The problems such as transportation safety, construction safety and environmental pollution；In addition the application effects such as oil resistant are not ideal enough.Recently, aqueous electricity
Cable fireproof coating also occurs on the market, is mostly the plasticizer being added with aqueous high molecular lotion, is equipped with a variety of fire-proof flame-retarded agents
And it is manufactured, flexibility is preferable, is the developing direction of fireproof coating.
Divide by its fire prevention form and composition, fireproof coating (also referred to as anti-flaming dope) can be divided into Non-expansive fireproof paint and
Expanding fire-proof paint two major classes.Generally the most commonly used is Water-borne inflation type refractory coatings on the market, mainly by film forming matter (one
As be lotion), pigment, filler, solvent, flame-retardant system (generally comprising carbon forming agent, catalyst, foaming agent etc.), the composition such as auxiliary agent.
Main fire retardation is played in Water-borne inflation type refractory coating is expansion type flame retardant, its mechanism of action is mainly passed through
It can foam to form layer of charcoal after burning, play starvation and other fuel gas in gas phase and condensed phase, it is fire-retardant to reach physics
Effect, this layer of charcoal are that experience the following steps are formed: (1) at a certain temperature, serving as the substance of acid source (such as ammonium polyphosphate)
Sour (usually inorganic acid) can be decomposited at a certain temperature；Temperature increase after, decomposite acid can in coating system
Esterification occurs for carbon forming agent (alcohols material), and the gas source in coating system can release gas, expand coating further,
It may act as the catalyst of carbon forming agent；(3) and in combustion coating sample can further melt, and be allowed in molten
State；(4) the vapor and other gases further generated in combustion can release, and the layer of charcoal to be formed is allowed further to send out
Bubble, at the same time, polyalcohol and ester dehydration carbonization form inorganic matter and charcoal residue, and system is further expanded foamed；⑸
When reaction terminates fastly, the layer of charcoal temperature of formation is gradually decreased, solidification slowly, forms fine and close layer of charcoal.
But mainly there are two defects for expanding fire-proof paint common at present.First, poor water resistance, according to facing type
The examination criteria GB12441-2005 of fireproof coating, it is desirable that this kind of coating is to impregnate 24 hours not occur in 25 DEG C of tap water
It falls off, foaming phenomena, as shown in Figure 1.But it is limited in actual application environment, such as the condition that fireproof electric wire and cable sometimes impregnates
It is much higher than this standard with the time, inevitably makes fire prevention material failure in such a case.This is because fire prevention applies at present
Film forming agent aqueous high molecular lotion used in material is essentially all styrene-acrylic emulsion, acetate emulsion, silicone acrylic emulsion and acrylate
Lotion etc., these lotions are commonly used hydrophilic polar monomer in the synthesis process, therefore greatly reduce fireproof coating
Water-resistant capacity, for a long time in water impregnate will appear bubble, obscission.Second, the fire resistance property of expanding fire-proof paint
Carbon is mainly dehydrated under the action of catalyst by carbon forming agent, and what foaming agent was formed after being expanded by thermal decomposition a large amount of closes containing air
Hole is heat-insulated to work, and still, completes the above process and needs the time, while also producing a large amount of heat, to reduce coating
Flameproof effect.
Summary of the invention
The purpose of the present invention is to provide a kind of water-fast fire-proof dilatation with microcellular structure, the coating pass through addition
Pore former forms a large amount of closed porosities in film forming matter, improves the fire insulation performance of fireproof coating, pore former is by moving
It moves to coating surface and forms oiliness waterproof layer, greatly improve the water-resistant capacity of fireproof coating.
The purpose of the present invention is what is be achieved through the following technical solutions:
A kind of water-fast fire-proof dilatation with microcellular structure, in the coating composition containing can be formed closed porosity at
Hole agent, the pore former are migrated to coating surface, and coating is made to have water resistance, and coating composition proportion is as follows by weight:
Aqueous high molecular lotion: 40 ~ 80 parts；Catalyst: 5 ~ 30 parts；Carbon forming agent: 5~30 parts；Foaming agent: 5~30 parts；At
Hole agent: 3~10 parts；Dispersing agent: 0.1-5 parts；Defoaming agent: 0.01-0.5 parts；Deionized water: 10-40 parts；Other auxiliary agents: 1-
20 parts.
A kind of water-fast fire-proof dilatation with microcellular structure, the aqueous high molecular lotion include following cream
One or more of liquid: amino resins, acrylic resin, alkyd resin, Vinylidene Chloride, phenolic resin, styrene-acrylic emulsion, pure C
Lotion, chlorine partial emulsion, silicone acrylic emulsion, elastic emulsion, preferably 50 parts of lotion dosage.
A kind of water-fast fire-proof dilatation with microcellular structure, the catalyst include high polymerization polyphosphoric acid
One or more of ammonium, ammonium magnesium phosphate and melamine phosphate, melamine pyrophosphate, phosphoguanidine urea, catalyst amount
It is preferred that 25 parts.
A kind of water-fast fire-proof dilatation with microcellular structure, the carbon forming agent are polyols material, packet
Include one or more of pentaerythrite, dipentaerythritol, starch, preferably 22 parts of carbon forming agent dosage.
A kind of water-fast fire-proof dilatation with microcellular structure, the foaming agent include melamine, double cyanogen
One or more of amine, chlorinated paraffin, ammonium borate, urea, melamine-formaldehyde resin, cyanogen diamides, foaming agent consumption
It is preferred that 20 parts.
A kind of water-fast fire-proof dilatation with microcellular structure, the pore former includes phosphorous lower member ester,
Such as one or more of diphenyl phosphate monooctyl ester, tricresyl phosphate, trioctyl phosphate, preferably 8 parts of pore former dosage.
A kind of water-fast fire-proof dilatation with microcellular structure, the dispersing agent are low-molecular-weight polypropylene acid
Salt, such as ammonium polyacrylate, preferably 0.2 part of dispersant dosage.
A kind of water-fast fire-proof dilatation with microcellular structure, the defoaming agent are polyethers defoaming agent, such as
Polyoxypropylene ethylene oxide glycerin ether, preferably 0.05 part of defoaming agent dosage.
A kind of water-fast fire-proof dilatation with microcellular structure, preferably 10 parts of the deionized water dosage.
A kind of water-fast fire-proof dilatation with microcellular structure, the auxiliary agent includes titanium dioxide, talcum powder, carbon
Sour calcium powder, expanded graphite, vermiculite power, transparent powder filler, preferably 10 parts of other auxiliary dosages.
The advantages and effects of the present invention are:
1. the method that pore former is added in the present invention in film forming agent-aqueous high molecular lotion, forms in film forming agent after the drying
A large amount of closed porosity, the very low air of thermal conductivity has good heat insulation in micropore, reduces protected object temperature
The rate of climb, this is equivalent to be pre-formed a large amount of holes in fireproof coating, these holes will be with catalyst, carbon forming agent
The dense micro-hole layer of charcoal generated with foaming agent plays fireproof effect jointly, as shown in Figure 2.In addition, due to pore former with it is aqueous
Macromolecule emulsion compatibility is bad (pore former is lipophilic, film forming agent hydrophily), leads to outer surface of the pore former to fireproof coating
It is migrated, finally hydrophobic layer is formed in outer surface, to impart the good water resistance of coating, as shown in Figure 3.
2. expanding fire-proof paint of the invention overcomes the shortcomings that existing fireproof coating poor water resistance, the coating has
Fire insulation performance is good, bonding force is good, intensity is high.Water resistance, acid resistance, the Salt corrosion corrosion of coating are good, not easily to fall off, storage
Deposit stabilization, good decorative property, it is easy for construction the features such as.
Detailed description of the invention
Fig. 1 is existing commercially available fireproof coating blistering, and fall off photo；
Fig. 2 fireproof coating of the present invention forms fine and close fire proof heat-insulation layer photo；
Fig. 3 fireproof coating water resistance of the present invention improves photo in kind；
Fig. 4 fireproof coating fire protecting performance survey report photo of the present invention；
Fig. 5 fireproof coating water resistance survey report photo of the present invention.
Specific embodiment
The present invention is described in detail for illustrated embodiment with reference to the accompanying drawing.
In order to better illustrate the present invention, increase the understanding to summary of the invention, below to typical but non-limiting implementation
Mode is illustrated.
Embodiment 1
Silicone acrylic emulsion: 45 parts；
Ammonium polyphosphate: 22 parts；
Dipentaerythritol: 20 parts；
Melamine: 18 parts；
Diphenyl phosphate monooctyl ester: 8 parts；
Sodium Polyacrylate: 0.2 part；
Polyoxypropylene ethylene oxide glycerin ether: 0.05 part；
Deionized water: 10 parts；
Talcum powder: 8 parts.
Embodiment 2
Pure-acrylic emulsion: 55 parts；
Catalyst: 28 parts；
Pentaerythrite: 18 parts；
Melamine-formaldehyde resin: 22 parts；
Tricresyl phosphate: 8 parts；
SN-5040:0.5 parts；
Polyoxypropylene ethylene oxide glycerin ether: 0.05 part；
Deionized water: 15 parts；
Expanded graphite: 15 parts.
Embodiment 3
Chlorine partially-styrene-acrylic emulsion (1:1): 450 parts；
Melamine pyrophosphate: 30 parts；
Insoluble starch: 15 parts；
Cyanogen diamides: 22 parts；
Trioctyl phosphate: 10 parts；
Ammonium polyacrylate: 0.2 part；
Polyoxypropylene ethylene oxide glycerin ether: 0.06 part；
Deionized water: 10 parts；
Transparent powder: 12 parts.
The fire prevention testing result of embodiment 1 is as shown in figure 4, water-fast testing result is as shown in Figure 5.
Applicant's statement: the present invention passes through the embodiment above for example bright composition of the invention, but the present invention is not
It is limited only to above-mentioned detailed composition, that is to say, that be not meant to that the present invention must can be able to reality under above-mentioned composition
It is existing.Therefore, the technical staff of the industry it should be clear that for core of the invention content, i.e., make by the pore-forming that pore former is played
With any modification with water-fast effect, to the present invention relates to the addition of the equivalence replacement of raw material and auxiliary agent, the selection of processing method,
It should all include within protection the open scope of the invention.
Claims (10)
1. a kind of water-fast fire-proof dilatation with microcellular structure, which is characterized in that containing in the coating composition can be with shape
At the pore former of closed porosity, which is migrated to coating surface, and coating is made to have water resistance, and coating composition matches by weight
Part meter is as follows:
Aqueous high molecular lotion: 40 ~ 80 parts；Catalyst: 5 ~ 30 parts；Carbon forming agent: 5~30 parts；Foaming agent: 5~30 parts；At
Hole agent: 3~10 parts；Dispersing agent: 0.1-5 parts；Defoaming agent: 0.01-0.5 parts；Deionized water: 10-40 parts；Other auxiliary agents: 1-
20 parts.
2. a kind of water-fast fire-proof dilatation with microcellular structure according to claim 1, which is characterized in that the water
Property macromolecule emulsion includes one or more of following lotion: amino resins, acrylic resin, alkyd resin, Vinylidene Chloride,
Phenolic resin, styrene-acrylic emulsion, pure-acrylic emulsion, chlorine partial emulsion, silicone acrylic emulsion, elastic emulsion, preferably 50 parts of lotion dosage.
3. a kind of water-fast fire-proof dilatation with microcellular structure according to claim 1, which is characterized in that described to urge
Agent includes high polymerization ammonium polyphosphate, ammonium magnesium phosphate and melamine phosphate, melamine pyrophosphate, one in phosphoguanidine urea
Kind is several, and preferably 25 parts of catalyst amount.
4. a kind of water-fast fire-proof dilatation with microcellular structure according to claim 1, which is characterized in that it is described at
Charcoal agent is one or more of polyols material, including pentaerythrite, dipentaerythritol, starch, and carbon forming agent dosage is preferred
22 parts.
5. a kind of water-fast fire-proof dilatation with microcellular structure according to claim 1, which is characterized in that the hair
Infusion include melamine, dicyandiamide, chlorinated paraffin, ammonium borate, urea, melamine-formaldehyde resin, in cyanogen diamides
One or more, preferably 20 parts of foaming agent consumption.
6. a kind of water-fast fire-proof dilatation with microcellular structure according to claim 1, which is characterized in that it is described at
Hole agent includes phosphorous lower member ester, such as one or more of diphenyl phosphate monooctyl ester, tricresyl phosphate, trioctyl phosphate,
Preferably 8 parts of pore former dosage.
7. a kind of water-fast fire-proof dilatation with microcellular structure according to claim 1, which is characterized in that described point
Powder is low-molecular-weight polyacrylic acid salt, such as ammonium polyacrylate, preferably 0.2 part of dispersant dosage.
8. a kind of water-fast fire-proof dilatation with microcellular structure according to claim 1, which is characterized in that described to disappear
Infusion is polyethers defoaming agent, such as polyoxypropylene ethylene oxide glycerin ether, preferably 0.05 part of defoaming agent dosage.
9. a kind of water-fast fire-proof dilatation with microcellular structure according to claim 1, which is characterized in that described to go
Preferably 10 parts of ion water consumption.
10. a kind of water-fast fire-proof dilatation with microcellular structure according to claim 1, which is characterized in that described
Auxiliary agent includes titanium dioxide, talcum powder, Paris white, expanded graphite, vermiculite power, transparent powder filler, other auxiliary dosages preferably 10
Part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811056941.1A CN109233402A (en) | 2018-09-11 | 2018-09-11 | A kind of water-fast fire-proof dilatation with microcellular structure |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811056941.1A CN109233402A (en) | 2018-09-11 | 2018-09-11 | A kind of water-fast fire-proof dilatation with microcellular structure |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109233402A true CN109233402A (en) | 2019-01-18 |
Family
ID=65067306
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811056941.1A Pending CN109233402A (en) | 2018-09-11 | 2018-09-11 | A kind of water-fast fire-proof dilatation with microcellular structure |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109233402A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020263108A1 (en) | 2019-06-28 | 2020-12-30 | Klingelberg Products As | Polymer flame retardant and method for its manufacture |
| CN113249004A (en) * | 2021-06-25 | 2021-08-13 | 新疆君泰机电工程有限公司 | Water-based intumescent fire retardant coating for galvanized steel sheet and preparation method thereof |
| WO2023095773A1 (en) * | 2021-11-25 | 2023-06-01 | 関西ペイント株式会社 | Aqueous foaming fireproof coating composition |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1953487A1 (en) * | 2007-02-05 | 2008-08-06 | Weerulin GmbH | Fireproof substance for coating a metallurgic container |
| CN101440249A (en) * | 2008-05-23 | 2009-05-27 | 海洋化工研究院 | Ultrathin section steel structure fire-resisting paint and preparation thereof |
| CN104231805A (en) * | 2014-09-18 | 2014-12-24 | 江苏海晟涂料有限公司 | Water-based ultra-thin fire-retardant coating for steel structures and preparation method of fire-retardant coating |
-
2018
- 2018-09-11 CN CN201811056941.1A patent/CN109233402A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1953487A1 (en) * | 2007-02-05 | 2008-08-06 | Weerulin GmbH | Fireproof substance for coating a metallurgic container |
| CN101440249A (en) * | 2008-05-23 | 2009-05-27 | 海洋化工研究院 | Ultrathin section steel structure fire-resisting paint and preparation thereof |
| CN104231805A (en) * | 2014-09-18 | 2014-12-24 | 江苏海晟涂料有限公司 | Water-based ultra-thin fire-retardant coating for steel structures and preparation method of fire-retardant coating |
Non-Patent Citations (2)
| Title |
|---|
| 化学工业部科学技术情报研究所: "《工业化学助剂品种大全.下册》", 28 February 1990, 化学工业部科学技术情报研究所编辑出版 * |
| 洪仲苓: "《化工有机原料深加工》", 30 June 1997, 化学工业出版社 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020263108A1 (en) | 2019-06-28 | 2020-12-30 | Klingelberg Products As | Polymer flame retardant and method for its manufacture |
| CN113249004A (en) * | 2021-06-25 | 2021-08-13 | 新疆君泰机电工程有限公司 | Water-based intumescent fire retardant coating for galvanized steel sheet and preparation method thereof |
| WO2023095773A1 (en) * | 2021-11-25 | 2023-06-01 | 関西ペイント株式会社 | Aqueous foaming fireproof coating composition |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN112961528B (en) | Environment-friendly fireproof coating and preparation method thereof | |
| CN102174223B (en) | Flame-retardant foamed polyethylene material and preparation method thereof | |
| CN109233402A (en) | A kind of water-fast fire-proof dilatation with microcellular structure | |
| CN104774509A (en) | Fireproof paint | |
| CN101914333A (en) | Aqueous nano ultra-thin steel structure fireproof coating and preparation method thereof | |
| TWI477552B (en) | Fire-resistant polyurethane material and fire-resistant structure | |
| KR20090116042A (en) | Fire resistive intumescent coatings and it's use | |
| CN106146029A (en) | A kind of self-heat conserving fire-proof construction material | |
| CN110698926A (en) | Hydrophobic efficient fireproof coating and preparation method thereof | |
| CN105820375A (en) | Composite flame retardant | |
| RU2523818C1 (en) | Fire-resistant thermal-protective coating and method for production thereof | |
| CN103911025B (en) | A kind of aqueous fire-proof coating | |
| CN108424673B (en) | Alkali-activated fly ash-based intumescent fire-retardant coating for steel structure | |
| KR101489583B1 (en) | Non-Flammable composite for expanded polystyrene foam and manufacturing method thereof | |
| CN106145877A (en) | A kind of magnesium oxysulfide anti-fire door core board | |
| CN109762393A (en) | Efficient silicon nitrogen phosphorus fire retardant, water-resistant type transparent fire-resisting paint and its preparation method and application | |
| CN105255394B (en) | A kind of true golden plate flame retardant type adhesive and its preparation method and application | |
| CN106479297A (en) | A kind of aeroge Water-borne inflation type refractory coating and preparation method thereof | |
| CN104693905A (en) | Fireproof paint for evanescent mode | |
| CN113999583A (en) | Ultrathin flame-retardant water-based paint for manufacturing tank and preparation method thereof | |
| RU2545284C2 (en) | Fire-resistant composite material and method for production thereof | |
| CN106833259A (en) | A kind of frosting flame retardant coating and preparation method thereof | |
| CN113061394A (en) | Flame-retardant natural raw lacquer film and preparation method thereof | |
| CN101805163A (en) | Non-ignitable thermal insulation material for quickly solidifying fireproof insulation board | |
| CN111978591A (en) | Non-combustible foam and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information | ||
| CB02 | Change of applicant information |
Address after: 402360 Chongqing Dazu County High-tech Industrial Development Zone Applicant after: Chongqing Ke Yun new materials Co. Ltd. Address before: 401120 Crown Freedom City G Block 2-4, 355 Honghuang Road, Longxi Street, Yubei District, Chongqing Applicant before: Chongqing Ke Yun new materials Co. Ltd. |