CN109432685A - Nanometer fire extinguishing capsule preparation method thereof and fire extinguishing patch, fire extinguishing coating, intelligent extinguishing device - Google Patents
Nanometer fire extinguishing capsule preparation method thereof and fire extinguishing patch, fire extinguishing coating, intelligent extinguishing device Download PDFInfo
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- CN109432685A CN109432685A CN201811296877.4A CN201811296877A CN109432685A CN 109432685 A CN109432685 A CN 109432685A CN 201811296877 A CN201811296877 A CN 201811296877A CN 109432685 A CN109432685 A CN 109432685A
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- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/06—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires containing gas-producing, chemically-reactive components
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62C—FIRE-FIGHTING
- A62C3/00—Fire prevention, containment or extinguishing specially adapted for particular objects or places
- A62C3/16—Fire prevention, containment or extinguishing specially adapted for particular objects or places in electrical installations, e.g. cableways
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/0007—Solid extinguishing substances
- A62D1/0021—Microcapsules
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J183/00—Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Adhesives based on derivatives of such polymers
- C09J183/04—Polysiloxanes
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Public Health (AREA)
- Fire-Extinguishing Compositions (AREA)
- Paints Or Removers (AREA)
Abstract
It include preparing recipe ingredient the invention discloses a kind of nanometer of fire extinguishing capsule preparation method thereof and fire extinguishing patch, fire extinguishing coating, intelligent extinguishing device, this method;After fire retardant, catalyst and gas extinguishing agent mixing, fire retardant, catalyst and gas extinguishing agent are fully ground at 20 DEG C or less using the nano-milled equipment of high-precision that precision is 0.5-5nm;Pure silicon or silica are fully ground at 20 DEG C or less using the nano-milled equipment of high-precision that precision is 0.5-5nm;Fire retardant after being fully ground, catalyst, gas extinguishing agent, pure silicon or silica and silicone resin are formed into 20-50nm microcapsule structure dusty material in 20 DEG C or less ground and mixeds;Pigment smell mixture and 20-50nm microcapsule structure dusty material are stirred, it is static to obtain nanometer fire extinguishing capsule material.The polymorphic Nano capsule fire extinguisher including fire extinguishing adhesive sticker, coating of putting out a fire is prepared using this nanometer fire extinguishing capsule material, and forms intelligent extinguishing device.
Description
Technical field
The present invention relates to field of material technology of electrochemically putting out a fire, in particular to a kind of nanometer fire extinguishing capsule preparation method thereof and
Fire extinguishing patch, fire extinguishing coating, intelligent extinguishing device.
Background technique
Electrical fire is still one of the important source of fire generation, these sources be concentrated mainly on distribution box, power distribution cabinet,
Socket, battery pack, electrical appliance, cable testing bridge etc., these sources have a basic characteristics to be exactly that space is relatively small, and close
It closes, the more difficult discovery of initial fire disaster, once discovery, development speed are exceedingly fast.So small space fire extinguishing all the time be one very
The problem of headache.Because space is small, existing fire extinguisher volume on the market is big, fire extinguisher suitably can not be installed at equipment box
Interior, there are certain limitations for above-water method, but small space is the important fire source point that fire occurs again, waits initial fire disaster to be found
Afterwards, the fire suppression measures such as fire extinguisher or water, sand, fire smothering blanket are manually reused, the loss of time is larger, may lead to fire disaster.
It is put out a fire using large-scale network, cost is high, is not suitable for the disposition of initial fire disaster, and than relatively hazardous, the pollution after fire extinguishing is big.
Especially the fields such as family, cable duct, spacecraft, the vehicles, equipment machine room, petrochemical industry, coal mine, metallurgy never compared with
Good disposition method.
In order to cope with fire risk existing for the source of these electrical fires in small space, generally by using use
Fire proofing, still, fire proofing can not substitute all electrical components, therefore can not effectively be avoided using fire proofing
The fire risk in these sources, when fire occurs, traditional fire-fighting mode is difficult to dispose the fire in small spatial dimension in time
Feelings are developed microcapsules fire extinguisher, using gas extinguishing agent and microcapsule coated material as main material, under specific process conditions
Gas extinguishing agent is wrapped to form microcapsule structure by covering material, and when fire behavior occurs, the covering material on microcapsule structure exists
It is ruptured under high temperature action, gas extinguishing agent discharges fire-retardant gas under high temperature action, to control fire behavior.Existing microcapsules knot
Therefore the defects of structure particle is more, and uniformity is poor, and long-term storage capability is poor needs to be optimized for microcapsules fire extinguisher.
Summary of the invention
Goal of the invention of the invention is to provide a kind of nanometer of fire extinguishing capsule preparation method thereof and fire extinguishing patch, fire extinguishing coating, intelligence
Extinguishing device is made using the two in temperature by encapsulating fire retardant, extinguishing chemical into capsule fortreating AIDS pulverulence using nanotechnology
Under, the rapid cleavage after Nano capsule cracks goes out the physical characteristic fire extinguishing of nitrogen, heat absorption, and is based on nanometer fire extinguishing capsule material
Prepare the extinguishment product of variform.
In order to solve the above-mentioned technical problem, the present invention is by common fire retardant, fire extinguishing using the basic ideas of technical solution
After agent forms solid powder after being wrapped up by nanoencapsulation technology, the silica of proper proportion is added, environmentally friendly colloid can
A variety of shapes for being suitble to small space such as adhesive sticker, coating, bean or pea, rope are prepared into, solve small space fire suppression measures difficulty or ease peace
The problem of dress.Adhesive sticker form can be posted in the inside of distribution box, switch socket, all kinds of cabinet bodies, fire suppression measures is facilitated to be transformed,
It installs additional.Coating mode can be pre-processed directly when all kinds of small Space processings manufacture, and by fire-retardant and fire extinguishing while be acted on,
Manufacturing the small Space Facilities come out directly has fire-retardant and fire-extinguishing function concurrently.Bean or pea and rope shape can act on and cable bridge
The fire extinguishing of the larger spaces such as frame, battery storing case, container, while also having the effect of space light filling antidetonation foam, and
And it can recycle repeatedly.
Specifically, the present invention provides a kind of nanometer of fire extinguishing capsule material, it includes each raw materials of following weight percent
Component:
Silicone resin 10%;
Fire retardant 5-10%;
Aeroge 2%;
Catalyst 1-2%;
Gas extinguishing agent 10%;
Pigment smell mixture 0-2%;
Pure silicon or silica polishing are to 100%.
Further, the gas extinguishing agent be difluorodibromomethane, difluorochlobromo-methane, BTM,
One or more of dibromotetrafluoromethane, trifluoro propane, hexafluoropropane, heptafluoro-propane, IG541.The above gas extinguishing agent exists
In fire extinguishing procedure equal noresidue generates, and will not generate any physics and chemically to the electrical and electronic component of scene of fire
Damage.
Further, the fire retardant is fire retardant additive without halogen.Such as magnesia.
Further, the pigment smell mixture includes pigment and aromatic;The ratio of the pigment and the aromatic
Example is 1:1.
Another aspect of the present invention, in order to prepare above-mentioned nanometer fire extinguishing capsule material, the present invention also provides one kind to receive
The preparation method of rice fire extinguishing capsule material, the described method comprises the following steps:
S101, recipe ingredient is prepared: silicone resin 10%;Fire retardant 5-10%;Aeroge 2%;Catalyst 1-2%;Gas
Extinguishing chemical 10%;Pigment smell mixture 0-2%;Pure silicon or silica polishing are to 100%.
It is 0.5-5nm's using precision after S102, the fire retardant, the catalyst and gas extinguishing agent mixing
Nano-milled equipment is fully ground the fire retardant, the catalyst and the gas extinguishing agent at 20 DEG C or less in high precision;
S103, the pure silicon is fully ground at 20 DEG C or less using the nano-milled equipment of high-precision that precision is 0.5-5nm
Or silica;
S104, will be fully ground after the fire retardant, the catalyst, the gas extinguishing agent, the pure silicon or two
Silica and the silicone resin are in 20 DEG C or less ground and mixeds formation 20-50nm microcapsule structure dusty materials;
S105, pigment smell mixture and the 20-50nm microcapsule structure dusty material are stirred, it is static to obtain
The nanometer fire extinguishing capsule material.
Another aspect of the present invention prepares a kind of method of adhesive sticker of putting out a fire such as using above-mentioned nanometer fire extinguishing capsule material
Under:
Nanometer fire extinguishing capsule material is added to and is accounted in the silicone resin that weight ratio is 25-35%, at room temperature
It stirs evenly, so that the powder of nanometer fire extinguishing capsule material is sufficiently diffused into the silicone resin and forms colloid.
Another aspect of the present invention, using above-mentioned nanometer fire extinguishing capsule material, a kind of method for preparing coating of putting out a fire is as follows:
Nanometer fire extinguishing capsule material is added to and is accounted in the silicone resin that weight ratio is 70-85%, at room temperature
It stirs evenly, so that the powder of nanometer fire extinguishing capsule material, which is sufficiently diffused into the silicone resin, forms the fire extinguishing painting
Material.
Another aspect of the present invention provides a kind of intelligent extinguishing device, is prepared using above-mentioned nanometer fire extinguishing capsule material
Polymorphic Nano capsule fire extinguisher including adhesive sticker of putting out a fire, coating of putting out a fire, encapsulates one in the Nano capsule fire extinguisher
RFID passive RF label, corresponding danger source are arranged the Nano capsule fire extinguisher and utilize RFID signal when fire behavior occurs
Base station emits far Distance RFID signal to the RFID passive RF label, obtains the danger on the RFID passive RF label
Source information.
Further, the intelligent extinguishing device further includes an intelligent management server, and the intelligent management server is logical
It crosses the RFID signal base station and obtains the danger sources information, and the danger sources information is pushed to mobile terminal.
For achieve the purpose that it is above solve the problems, such as, inventive formulation is from raw material selection, production technology, technical parameter etc.
It deployed, controlled.
Specifically, the nanometer fire extinguishing capsule material preparation method of the technical program, the high-precision for being 0.5-5nm using precision
Nano-milled equipment is fully ground into after mixing the gas extinguishing agent, fire retardant, catalyst that generate nitrogen and carbon dioxide
Then pure silicon or silica are equally ground into the silicon nanometer of 0.5-5nm by the foamite mixture nano particle of 0.5-5nm
Particle;Grinding mixing will be carried out again after foamite mixture nano particle and nano silicon particles addition silicone fluid, is formed
20-50nm microcapsule structure dusty material.The powder of nanometer fire extinguishing capsule material, is added the silica of proper proportion, environmental protection
Colloid can be prepared into a variety of shapes for being suitble to small space such as adhesive sticker, coating, bean or pea, rope.Solve small space fire suppression measures
The problem of difficulty or ease are installed.Adhesive sticker form can be posted in the inside of distribution box, switch socket, all kinds of cabinet bodies, and fire extinguishing is facilitated to arrange
It applies transformation, install additional.Coating mode can be pre-processed directly when all kinds of small Space processings manufacture, and fire-retardant and fire extinguishing is same
Shi Zuoyong, the small Space Facilities for manufacturing out directly have fire-retardant and fire-extinguishing function concurrently.Bean or pea and rope shape can act on
With the fire extinguishing of the larger spaces such as cable testing bridge, battery storing case, container, while also having space light filling antidetonation foam
Effect, and can recycle repeatedly.
In addition, being made together with RFID passive label using nanotechnology encapsulation fire retardant, extinguishing chemical at capsule fortreating AIDS state
It is standby to adapt to the initial fire disaster fighting of current down space danger source at the miniature fire extinguisher of intelligent self-extinguishing, and there is Internet of Things function
Energy.The finished product of preparation is cracked into fire-suppressant gas automatically at a certain temperature, and the position of cracked gas can be alarmed to center,
The intermediate package Micro RF ID passive RF label of finished product, and both danger sources corresponding informance, through Internet of Things in 60 seconds
Just know the small spatial position of intelligent miniature nanometer fire extinguisher being directed to and time, the validity period of fire extinguishing effect.Using general mobile phone,
Inspection terminal can be managed to the danger source in its space.Information automation is realized to upload, fire extinguishing automation, manage intelligence
Energyization.
Specific embodiment
Specific embodiments of the present invention will be further explained below.It should be noted that for these implementations
The explanation of mode is used to help understand the present invention, but and does not constitute a limitation of the invention.In addition, invention described below
Technical characteristic involved in each embodiment can be combined with each other as long as they do not conflict with each other.
Embodiment 1
The present invention provides a kind of nanometer of fire extinguishing capsule materials, and it includes each raw material components of following weight percent: silicon
Resin 10%;Fire retardant 5-10%;Aeroge 2%;Catalyst 1-2%;Gas extinguishing agent 10%;Pigment smell mixture 0-
2%;Pure silicon or silica polishing are to 100%.
Optionally, the gas extinguishing agent is difluorodibromomethane, difluorochlobromo-methane, BTM, four
One or more of fluorine Bromofume, trifluoro propane, hexafluoropropane, heptafluoro-propane, IG541.The above gas extinguishing agent is
Equal noresidue generates in fire extinguishing procedure, will not generate any physics and damage chemically to the electrical and electronic component of scene of fire
It is bad.
Optionally, silicone resin type mainly include methyl phenyl silicone resin, methyl silicon resin, low phenyl methyl silicones,
Silicone resin emulsion, self-drying type organic siliconresin, high temperature modification organic siliconresin, epoxy modified silicone resin, organosilicon are poly-
Ester modified resin, self-drying type environmental protection organic siliconresin, environment-protecting silicone resin, non-viscous paint organic siliconresin, bloom are organic
Silicone resin, benzyl transparent silicon resin, methyl transparent organic silicon resin, mica are bonded silicone resin, poly- methyl silicon resin, amino silicone
Resin, silicon resin solution, silicone-epoxy resin, organic silicon polyester resin, solvent-resisting organic siliconresin, has fluorine silicon resin
Machine silicone resin adhesive, fluorine silicon resin Silicone Sealants, high-temperature resisting methyl silicone resin, self-drying type organic silicon insulating varnish, methyl
MQ silicone resin, Vinyl MQ silicon resin, organosilicon acrylic resin coating.
Optionally, the fire retardant is fire retardant additive without halogen.Such as magnesia.Halogen-free flame retardants JLH-W666 is a kind of
High-performance P-N type organic fire-retardant is a kind of triazinetrione compound and yuban class compound, have passed through special table
Surface treatment is not precipitated so being easy dispersion in a plastic material, has good flame retardant effect.W666 decomposition temperature about exists
450 DEG C, maximum particle diameter (D50%) is 20/um, and appearance is white powder, is a kind of height resistant to high temperature for not influencing product colour
Performance halogen-free flame retardants is recommended to be widely used in epoxy resin, polyurethane, polystyrene, polyester applied to polyamide (nylon)
Suggest the halogen-free flame retardants W666 of addition 15%-30% in (PET, PBT), polyolefin and non halogen wire and cable, so that it may
94UL reaches V0-V2 standard.
Optionally, the pigment smell mixture includes pigment and aromatic;The ratio of the pigment and the aromatic
For 1:1.
In order to prepare above-mentioned nanometer fire extinguishing capsule material, the present invention also provides the systems of a kind of nanometer of capsule material of putting out a fire
Preparation Method the described method comprises the following steps:
S101, recipe ingredient is prepared: silicone resin 10%;Fire retardant 5-10%;Aeroge 2%;Catalyst 1-2%;Gas
Extinguishing chemical 10%;Pigment smell mixture 0-2%;Pure silicon or silica polishing are to 100%.
It is 0.5-5nm's using precision after S102, the fire retardant, the catalyst and gas extinguishing agent mixing
Nano-milled equipment is fully ground the fire retardant, the catalyst and the gas extinguishing agent at 20 DEG C or less in high precision;
S103, the pure silicon is fully ground at 20 DEG C or less using the nano-milled equipment of high-precision that precision is 0.5-5nm
Or silica;
S104, will be fully ground after the fire retardant, the catalyst, the gas extinguishing agent, the pure silicon or two
Silica and the silicone resin are in 20 DEG C or less ground and mixeds formation 20-50nm microcapsule structure dusty materials;
S105, pigment smell mixture and the 20-50nm microcapsule structure dusty material are stirred, it is static to obtain
The nanometer fire extinguishing capsule material.
After fire retardant, extinguishing chemical are encapsulated by nano thin-film, form and chemical substance are stablized, in subzero 30 DEG C to 70 DEG C rings
Border tolerance, the theoretical service life was up to 15 years or more.It does not need to safeguard and test, stored without using adminicle, directly effect and space
Interior, the temperature of self-extinguishing can be adjusted according to formula, adapt to the operating temperature of different small space danger sources, and can be kept for day
The stability of normal state.
Embodiment 2
Using the nanometer fire extinguishing capsule material of embodiment 1, a kind of method for preparing adhesive sticker of putting out a fire is as follows:
Nanometer fire extinguishing capsule material is added to and is accounted in the silicone resin that weight ratio is 25-35%, at room temperature
It stirs evenly, so that the powder of nanometer fire extinguishing capsule material is sufficiently diffused into the silicone resin and forms colloid.
Adhesive sticker form can be posted in the inside of distribution box, switch socket, all kinds of cabinet bodies, fire suppression measures is facilitated to be transformed,
It installs additional.
Embodiment 3
A kind of fire extinguishing painting is prepared using above-mentioned nanometer fire extinguishing capsule material using the nanometer fire extinguishing capsule material of embodiment 1
The method of material is as follows:
Nanometer fire extinguishing capsule material is added to and is accounted in the silicone resin that weight ratio is 70-85%, at room temperature
It stirs evenly, so that the powder of nanometer fire extinguishing capsule material, which is sufficiently diffused into the silicone resin, forms the fire extinguishing painting
Material.
Coating mode can be pre-processed directly when all kinds of small Space processings manufacture, and by fire-retardant and fire extinguishing while be made
With the small Space Facilities for manufacturing out directly have fire-retardant and fire-extinguishing function concurrently.
Embodiment 4
The present invention provides a kind of intelligent extinguishing devices, include going out using the nanometer fire extinguishing capsule material preparation of embodiment 1
The polymorphic Nano capsule fire extinguisher of fiery adhesive sticker, coating of putting out a fire, it is passive in the Nano capsule fire extinguisher to encapsulate a RFID
RF tag, the Nano capsule fire extinguisher is arranged in corresponding danger source, when fire behavior occurs, using RFID signal base station to institute
RFID passive RF label transmitting far Distance RFID signal is stated, the danger sources information on the RFID passive RF label is obtained.
Wherein, the intelligent extinguishing device further includes an intelligent management server, and the intelligent management server passes through institute
It states RFID signal base station and obtains the danger sources information, and the danger sources information is pushed to mobile terminal.
Using nanotechnology encapsulation fire retardant, extinguishing chemical at capsule fortreating AIDS state, it is prepared into together with RFID passive label
The intelligent miniature fire extinguisher of self-extinguishing, the initial fire disaster for adapting to current down space danger source is saved, and has internet of things functional.System
Standby finished product is cracked into fire-suppressant gas automatically at a certain temperature, and the position of cracked gas can be alarmed to center, in finished product
Intermediate package Micro RF ID passive RF label just known in 60 seconds with both danger sources corresponding informance by Internet of Things
Time, the validity period of the small spatial position of intelligent miniature nanometer fire extinguisher being directed to and fire extinguishing effect.Use general mobile phone, inspection
Terminal can be managed to the danger source in its space.Information automation is realized to upload, fire extinguishing automation, manage intelligence
Change.
Above the embodiments of the present invention are described in detail, but the present invention is not limited to described embodiments.It is right
For those skilled in the art, in the case where not departing from the principle of the invention and spirit, these embodiments are carried out more
Kind change, modification, replacement and modification, still fall in protection scope of the present invention.
Claims (9)
1. a kind of nanometer of fire extinguishing capsule material, which is characterized in that the nanometer fire extinguishing capsule material includes following weight percent
Each raw material component:
Silicone resin 10%;
Fire retardant 5-10%;
Aeroge 2%;
Catalyst 1-2%;
Gas extinguishing agent 10%;
Pigment smell mixture 0-2%;
Pure silicon or silica polishing are to 100%.
The capsule material 2. nanometer according to claim 1 is put out a fire, which is characterized in that the gas extinguishing agent is difluoro dibromo
Methane, difluorochlobromo-methane, BTM, dibromotetrafluoromethane, trifluoro propane, hexafluoropropane, heptafluoro-propane,
One or more of IG541.
The capsule material 3. nanometer according to claim 1 is put out a fire, which is characterized in that the fire retardant is halogen-free flameproof addition
Agent.
The capsule material 4. nanometer according to claim 1 is put out a fire, which is characterized in that the pigment smell mixture includes color
Element and aromatic;The ratio of the pigment and the aromatic is 1:1.
5. the preparation method of a kind of nanometer of fire extinguishing capsule material, is used to prepare the nanometer as described in claim 1-4 any one
Fire extinguishing capsule material, the described method comprises the following steps:
S101, recipe ingredient is prepared: silicone resin 10%;Fire retardant 5-10%;Aeroge 2%;Catalyst 1-2%;Extinction using gas
Agent 10%;Pigment smell mixture 0-2%;Pure silicon or silica polishing are to 100%.
It is the high-precision of 0.5-5nm using precision after S102, the fire retardant, the catalyst and gas extinguishing agent mixing
It spends nano-milled equipment and is fully ground the fire retardant, the catalyst and the gas extinguishing agent at 20 DEG C or less;
S103, the pure silicon or two are fully ground at 20 DEG C or less using the nano-milled equipment of high-precision that precision is 0.5-5nm
Silica;
S104, will be fully ground after the fire retardant, the catalyst, the gas extinguishing agent, the pure silicon or titanium dioxide
Silicon and the silicone resin are in 20 DEG C or less ground and mixeds formation 20-50nm microcapsule structure dusty materials;
S105, pigment smell mixture and the 20-50nm microcapsule structure dusty material are stirred, it is static obtain it is described
Nanometer fire extinguishing capsule material.
6. a kind of preparation method for adhesive sticker of putting out a fire, which is characterized in that the described method includes:
The nanometer fire extinguishing capsule material of claim 5 is added to and is accounted in the silicone resin that weight ratio is 25-35%, in room temperature
Under the conditions of stir evenly so that the powder of nanometer fire extinguishing capsule material be sufficiently diffused into the silicone resin formed it is gluey
Body.
7. a kind of preparation method for coating of putting out a fire, which is characterized in that the described method includes:
The nanometer fire extinguishing capsule material of claim 5 is added to and is accounted in the silicone resin that weight ratio is 70-85%, in room temperature
Under the conditions of stir evenly so that the powder of nanometer fire extinguishing capsule material be sufficiently diffused into the silicone resin formed described in goes out
Fiery coating.
8. a kind of intelligent extinguishing device, which is characterized in that utilize nanometer as claimed in claim 5 fire extinguishing capsule material preparation packet
The polymorphic Nano capsule fire extinguisher for including fire extinguishing adhesive sticker, coating of putting out a fire, encapsulates a RFID in the Nano capsule fire extinguisher
Passive RF label, corresponding danger source are arranged the Nano capsule fire extinguisher and utilize RFID signal base station when fire behavior occurs
Emit far Distance RFID signal to the RFID passive RF label, obtains the danger source letter on the RFID passive RF label
Breath.
9. a kind of intelligent extinguishing device according to claim, which is characterized in that the intelligent extinguishing device further includes one
Intelligent management server, the intelligent management server obtain the danger sources information by the RFID signal base station, and will
The danger sources information is pushed to mobile terminal.
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CN201811296877.4A CN109432685A (en) | 2018-11-01 | 2018-11-01 | Nanometer fire extinguishing capsule preparation method thereof and fire extinguishing patch, fire extinguishing coating, intelligent extinguishing device |
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CN201811296877.4A CN109432685A (en) | 2018-11-01 | 2018-11-01 | Nanometer fire extinguishing capsule preparation method thereof and fire extinguishing patch, fire extinguishing coating, intelligent extinguishing device |
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Cited By (8)
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KR102011627B1 (en) * | 2019-05-28 | 2019-10-14 | 정인섭 | fire-extinguishing paint composition comprising fire-extinguishing capsules |
CN110433419A (en) * | 2019-06-28 | 2019-11-12 | 浙江南都电源动力股份有限公司 | Lithium electric heating uncontrolled fire inhibits capsule and lithium ion battery |
CN111068234A (en) * | 2019-12-26 | 2020-04-28 | 语路科技(深圳)有限公司 | Polymorphic preparation method and fire extinguishing patch of novel bionic nanocapsule fire extinguisher |
CN111265800A (en) * | 2020-04-01 | 2020-06-12 | 上海联捷消防科技有限公司 | Novel fire blanket capable of automatically extinguishing fire |
CN111793451A (en) * | 2020-08-06 | 2020-10-20 | 消之源科技技术有限公司 | Intelligent fire-extinguishing insulating adhesive tape and preparation method thereof |
CN112043994A (en) * | 2020-09-14 | 2020-12-08 | 西安尚泰安全技术有限责任公司 | Temperature-control capsule type nano fire extinguishing tablet and temperature-control nano capsule fire extinguishing method |
CN112206458A (en) * | 2019-07-09 | 2021-01-12 | 上海汇友精密化学品有限公司 | Fluorine-free non-protein foam extinguishing agent |
CN115177904A (en) * | 2022-07-11 | 2022-10-14 | 上海联捷安全科技有限公司 | Preparation method of nano microbubble fire extinguishing capsule and polymorphic fire extinguishing method |
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KR102011627B1 (en) * | 2019-05-28 | 2019-10-14 | 정인섭 | fire-extinguishing paint composition comprising fire-extinguishing capsules |
CN110433419A (en) * | 2019-06-28 | 2019-11-12 | 浙江南都电源动力股份有限公司 | Lithium electric heating uncontrolled fire inhibits capsule and lithium ion battery |
CN110433419B (en) * | 2019-06-28 | 2021-09-07 | 浙江南都电源动力股份有限公司 | Lithium battery thermal runaway fire suppression capsule and lithium ion battery |
CN112206458A (en) * | 2019-07-09 | 2021-01-12 | 上海汇友精密化学品有限公司 | Fluorine-free non-protein foam extinguishing agent |
CN111068234A (en) * | 2019-12-26 | 2020-04-28 | 语路科技(深圳)有限公司 | Polymorphic preparation method and fire extinguishing patch of novel bionic nanocapsule fire extinguisher |
CN111265800A (en) * | 2020-04-01 | 2020-06-12 | 上海联捷消防科技有限公司 | Novel fire blanket capable of automatically extinguishing fire |
CN111793451A (en) * | 2020-08-06 | 2020-10-20 | 消之源科技技术有限公司 | Intelligent fire-extinguishing insulating adhesive tape and preparation method thereof |
CN112043994A (en) * | 2020-09-14 | 2020-12-08 | 西安尚泰安全技术有限责任公司 | Temperature-control capsule type nano fire extinguishing tablet and temperature-control nano capsule fire extinguishing method |
CN112043994B (en) * | 2020-09-14 | 2022-03-22 | 西安尚泰安全技术有限责任公司 | Temperature-control capsule type nano fire extinguishing tablet and temperature-control nano capsule fire extinguishing method |
CN115177904A (en) * | 2022-07-11 | 2022-10-14 | 上海联捷安全科技有限公司 | Preparation method of nano microbubble fire extinguishing capsule and polymorphic fire extinguishing method |
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