CN109423252A - A kind of insulating tape and preparation method thereof - Google Patents

A kind of insulating tape and preparation method thereof Download PDF

Info

Publication number
CN109423252A
CN109423252A CN201710500211.5A CN201710500211A CN109423252A CN 109423252 A CN109423252 A CN 109423252A CN 201710500211 A CN201710500211 A CN 201710500211A CN 109423252 A CN109423252 A CN 109423252A
Authority
CN
China
Prior art keywords
resin compound
parts
preparation
curing agent
fire retardant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710500211.5A
Other languages
Chinese (zh)
Inventor
不公告发明人
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kuang Chi Institute of Advanced Technology
Original Assignee
Kuang Chi Institute of Advanced Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kuang Chi Institute of Advanced Technology filed Critical Kuang Chi Institute of Advanced Technology
Priority to CN201710500211.5A priority Critical patent/CN109423252A/en
Priority to PCT/CN2018/079823 priority patent/WO2019001034A1/en
Publication of CN109423252A publication Critical patent/CN109423252A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J183/00—Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Adhesives based on derivatives of such polymers
    • C09J183/04—Polysiloxanes
    • C09J183/06—Polysiloxanes containing silicon bound to oxygen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00—Compositions of natural rubber
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/04—Non-macromolecular additives inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/06—Non-macromolecular additives organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J167/00—Adhesives based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Adhesives based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J167/00—Adhesives based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Adhesives based on derivatives of such polymers
    • C09J167/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J171/00—Adhesives based on polyethers obtained by reactions forming an ether link in the main chain; Adhesives based on derivatives of such polymers
    • C09J171/02—Polyalkylene oxides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes
    • C09J175/06—Polyurethanes from polyesters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes
    • C09J175/08—Polyurethanes from polyethers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J183/00—Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Adhesives based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2217—Oxides; Hydroxides of metals of magnesium
    • C08K2003/2224—Magnesium hydroxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K3/2279—Oxides; Hydroxides of metals of antimony
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/32—Phosphorus-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/13—Phenols; Phenolates
    • C08K5/136—Phenols containing halogens
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/29—Compounds containing one or more carbon-to-nitrogen double bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
    • C09J2301/408—Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the adhesive layer
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2467/00—Presence of polyester
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2467/00—Presence of polyester
    • C09J2467/006—Presence of polyester in the substrate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2471/00—Presence of polyether
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2475/00—Presence of polyurethane
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2483/00—Presence of polysiloxane

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The embodiment of the invention provides a kind of preparation methods of insulating tape, comprising: mixes polyester polyol oxygen, fire retardant, talcum powder and carbon black, obtains resin compound；Curing agent is added in the resin compound, the resin compound after being solidified；Resin compound after the solidification is rolled into coiled material；And PET film is pasted in the coiled material upper and lower surface, it is sliced, obtains the insulating tape.Waterproof, insulation and the proof voltage breakdown protection of electric appliance may be implemented in the insulating protection that can be used for high-tension electricity, appliance field by the insulating tape that returning method is prepared, and construction is simple is, it can be achieved that long-effective protection.

Description

A kind of insulating tape and preparation method thereof
Technical field
The present invention relates to field of material technology, more particularly, to a kind of insulating tape.
Background technique
Insulating tape is a kind of for preventing from leaking electricity, and plays the adhesive tape of insulating effect, it is made of base band and pressure-sensitive adhesive layer.Base For band generally using cotton, synthetic fabrics and plastic film etc., glue-line adds the compounding agents such as solvent misture to be made by rubber.Preparation Method mostly uses the mode of coating, applies man-hour requirement field mix, and needs to be brushed process for several times, complicated for operation, performance It is big to construction technology dependence.
Summary of the invention
In order to solve the problems in the existing technology, according to an aspect of the invention, there is provided a kind of insulating tape Preparation method, comprising: polyester polyol oxygen, fire retardant, talcum powder and carbon black are mixed, resin compound is obtained；? Curing agent is added in the resin compound, the resin compound after being solidified；By the resin compound pressure after the solidification Prolong into coiled material；And PET film is pasted in the coiled material upper and lower surface, it is sliced, obtains the insulating tape.
In the above preparation method, the polyester polyol oxygen is C4-C30Polyester polyol oxygen.
In the above preparation method, the fire retardant is selected from antimony oxide, magnesium hydroxide, aluminium hydroxide, decabrominated dipheny The double S ethers of ether, tetrabromobisphenol A, eight bromo ether, eight bromines, three (dialkyl phosphinic acid) aluminium, hydrogen phosphite aluminium, methylene-diphenyl phosphine oxygen The substituted polyarylether of compound -, xyxylene bis- (diphenyl phosphine oxides), 1,2- be bis--(9,10- dihydro-9-oxy -10- phospho hetero phenanthrene - 10- oxide) ethane, bis- (diphenyl phosphine oxide the ylmethyl) -1,1'- biphenyl of 4,4'-, one of double melamine pyrophosphoric zinc Or a variety of combination.
In the above preparation method, the curing agent is selected from phenolsulfonic acid, maleic anhydride, phthalic anhydride, ten The combination of one or more of dialkylene succinic anhydride, hexahydrophthalic acid anhydride, m-phenylene diamine (MPD), isocyanates.
In the above preparation method, polyester polyol oxygen, fire retardant, talcum powder and carbon black are mixed, obtains resin In the step of mixture, further comprise: according to mass fraction meter, by 80-120 parts of polyester polyol oxygen, 5-20 parts of resistance Combustion agent, 10-50 parts of talcum powder and 10-200 parts of carbon black are added separately in kneader, are mediated 10-30 minutes, are obtained described Resin compound.
In the above preparation method, polyester polyol oxygen, fire retardant, talcum powder and carbon black are mixed, obtains resin In the step of mixture, further comprise: according to mass fraction meter, by 100 parts of polyester polyol oxygen, 10 parts of fire retardant, 30 parts of talcum powder and 100 parts of carbon black are added separately in kneader, are mediated 20 minutes, are obtained the resin compound.
In the above preparation method, curing agent is added in the resin compound, the resin compound after being solidified The step of in, further comprise: according to mass fraction meter, curing agent 5-50 parts added in 80-120 parts of resin compound.
In the above preparation method, curing agent is added in the resin compound, the resin compound after being solidified The step of in, further comprise: according to mass fraction meter, 25 parts of curing agent added in 100 parts of resin compound.
In the above preparation method, the preparation method further include: packaging of aluminizing is carried out to the insulating tape being prepared, Vacuum sealing.
According to another aspect of the present invention, insulating tape prepared by the preparation method is additionally provided.
The flame retardant property of resin compound can be improved by the way that fire retardant is added in the present invention, by the way that talcum powder is added, Talcum powder can increase the mobility of resin compound and reduce thixotropic property as modifying agent can be adjusted by the way that carbon black is added It saves the thixotropy of material and reduces cost, the curing rate of resin compound can be accelerated by the way that curing agent is added, shorten solidification Time, and after obtaining coiled material, PET film is pasted by two sides, it can be more suitable to avoid contaminated materials surface when using Answer live use environment.
Method rapid construction provided by the invention and easy to use, the present invention by by bulk material with curing agent is compound makes With, rapid construction is realized by quick-setting method in air, and product belongs to web form, it is easily operated.From admittedly Change in conjunction with coiled material, live mixing is avoided to operate, can greatly simplify using difficulty, reduce the time consumed by use process.
Preparation method through the invention can prepare flame retardant property and waterproof performance are good, non-aging, breakdown voltage is high, Long durable insulating layer, construction is simple, conveniently, can solve high-tension apparatus to ambient enviroment and personnel's bring dangerous problem with And itself is because of plant issue caused by voltage.
And the insulating tape that preparation method provided by the present invention is prepared can be used for high-tension electricity, appliance field Insulating protection, waterproof, insulation and the proof voltage breakdown protection of electric appliance may be implemented, and construction is simple is, it can be achieved that long-acting guarantor Shield.
Detailed description of the invention
It in order to more clearly explain the embodiment of the invention or the technical proposal in the existing technology, below will be to institute in embodiment Attached drawing to be used is needed to be briefly described, it should be apparent that, the accompanying drawings in the following description is only some implementations of the invention Example, for those of ordinary skill in the art, without creative efforts, can also obtain according to these attached drawings Obtain other attached drawings.
Fig. 1 is the process flow chart according to the preparation method of the insulating tape of some embodiments of the present invention.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, those of ordinary skill in the art's every other embodiment obtained belong to what the present invention protected Range.
The preparation method of insulating tape provided by the invention, comprising the following steps:
The preparation of insulating tape:
Shown in step S101 as shown in figure 1, polyester polyol oxygen, fire retardant, talcum powder and carbon black are mixed, obtained Resin compound, specifically, according to mass fraction meter, by 80-120 parts of polyester polyol oxygen, 5-20 parts of fire retardant, 10- The carbon black of 50 parts of talcum powder and 10-200 part is added separately in kneader, is mediated 10-30 minute, is obtained the resin and mix Object；Preferably, according to mass fraction meter, by 100 parts of polyester polyol oxygen, 10 parts of fire retardant, 30 parts of talcum powder and 100 The carbon black of part is added separately in kneader, is mediated 20 minutes, is obtained the resin compound；Wherein, polyester polyol oxygen C4- C30Polyester polyol oxygen.The fire retardant is selected from antimony oxide, magnesium hydroxide, aluminium hydroxide, deca-BDE, tetrabromobisphenol A, the double S ethers of eight bromo ether, eight bromines, three (dialkyl phosphinic acid) aluminium, hydrogen phosphite aluminium, methylene-diphenyl phosphine oxide-substituted Polyarylether, xyxylene bis- (diphenyl phosphine oxides), 1,2- be bis--(9,10- dihydro-9-oxy -10- phospho hetero phenanthrene -10- oxide) second The group of one or more of bis- (diphenyl phosphine oxide the ylmethyl) -1,1'- biphenyl of alkane, 4,4'-, double melamine pyrophosphoric zinc It closes.
Shown in step S102 as shown in figure 1, curing agent is added in the resin compound, the resin after being solidified is mixed Object is closed, specifically, according to mass fraction meter, curing agent 5-50 parts is added in 80-120 parts of resin compound, it is preferable that press According to mass fraction meter, 25 parts of curing agent are added in 100 parts of resin compound, wherein curing agent is selected from phenolsulfonic acid, along fourth Enedioic acid acid anhydride, phthalic anhydride, dodecenylsuccinic anhydride, hexahydrophthalic acid anhydride, m-phenylene diamine (MPD), one in isocyanates Kind or a variety of combinations.
Shown in step S103 as shown in figure 1, the resin compound after the solidification is rolled into coiled material.
Shown in step S104 as shown in figure 1, PET film is pasted in the coiled material upper and lower surface, is sliced, obtains the insulation Adhesive tape.
Embodiment 1
1) commercially available silicone acrylates, flame retardant of magnesium hydroxide, talcum powder and carbon black etc. are added to kneader, Wherein mass ratio: silicone acrylates are 100 parts, and 5 parts of flame retardant of magnesium hydroxide, talcum powder is 10 parts, and carbon black is 10 parts, It mediates 15 minutes, obtains resin compound.
2) it is added isocyanate curing agent in the resin mixture, 100 parts of resin compound, 5 parts of isocyanate curing agent, Obtain final product.
3) final product is rolled into the coiled material of respective thickness using calender, PET film is covered on two sides, is sliced, using plating Aluminium packs Vacuum Package, obtains final products.
4) hardness, breakdown voltage, UV accelerated ageing performance, flame retardant property and waterproof performance after test solidification.
Embodiment 2
1) commercially available adipate polyester glycol, antimony oxide fire retardant, talcum powder and carbon black etc. are added to kneader, Wherein mass ratio: adipate polyester glycol is 120 parts, and 20 parts of antimony oxide fire retardant, talcum powder is 50 parts, carbon black 150 Part, it mediates 30 minutes, obtains resin compound.
2) in the resin mixture be added phenolsulfonic acid curing agent, 100 parts of resin compound, isocyanate curing agent 50 Part, obtain final product.
3) final product is rolled into the coiled material of respective thickness using calender, PET film is covered on two sides, is sliced, using plating Aluminium packs Vacuum Package, obtains final products.
4) hardness, breakdown voltage, UV accelerated ageing performance, flame retardant property and waterproof performance after test solidification.
Embodiment 3
1) commercially available silicone acrylates, hydrogen phosphite aluminium fire retardant, talcum powder and carbon black etc. are added to kneading Machine, wherein mass ratio: silicone acrylates are 80 parts, and 10 parts of hydrogen phosphite aluminium fire retardant, talcum powder is 25 parts, and carbon black is It 200 parts, mediates 10 minutes, obtains resin compound.
2) in the resin mixture be added maleic acid anhydride curing agents, 100 parts of resin compound, isocyanate curing agent 25 parts, obtain final product.
3) final product is rolled into the coiled material of respective thickness using calender, PET film is covered on two sides, is sliced, using plating Aluminium packs Vacuum Package, obtains final products.
4) hardness, breakdown voltage, UV accelerated ageing performance, flame retardant property and waterproof performance after test solidification.
Embodiment 4
1) by bis- (diphenyl phosphine oxide) fire retardants of commercially available polytetrahydrofuran diol, xyxylene, talcum powder and carbon black Etc. being added to kneader, wherein mass ratio: polytetrahydrofuran diol is 100 parts, and xyxylene bis- (diphenyl phosphine oxides) is fire-retardant 10 parts of agent, talcum powder is 30 parts, and carbon black is 100 parts, mediates 20 minutes, obtains resin compound.
2) it is added isocyanate curing agent in the resin mixture, 100 parts of resin compound, isocyanate curing agent 25 Part, obtain final product.
3) final product is rolled into the coiled material of respective thickness using calender, PET film is covered on two sides, is sliced, using plating Aluminium packs Vacuum Package, obtains final products.
4) hardness, breakdown voltage, UV accelerated ageing performance, flame retardant property and waterproof performance after test solidification.
Embodiment 5
1) commercially available silicone acrylates, aluminium hydroxide fire retardant, talcum powder and carbon black etc. are added to kneader, Wherein mass ratio: silicone acrylates are 110 parts, and 18 parts of aluminium hydroxide fire retardant, talcum powder is 15 parts, carbon black 80 Part, it mediates 20 minutes, obtains resin compound.
2) it is added isocyanate curing agent in the resin mixture, 100 parts of resin compound, isocyanate curing agent 50 Part, obtain final product.
3) final product is rolled into the coiled material of respective thickness using calender, PET film is covered on two sides, is sliced, using plating Aluminium packs Vacuum Package, obtains final products.
4) hardness, breakdown voltage, UV accelerated ageing performance, flame retardant property and waterproof performance after test solidification.
Embodiment 6
1) commercially available silicone acrylates, tetrabromobisphenol A fire retardant, talcum powder and carbon black etc. are added to kneading Machine, wherein mass ratio: silicone acrylates are 90 parts, and 20 parts of tetrabromobisphenol A fire retardant, talcum powder is 40 parts, and carbon black is It 120 parts, mediates 30 minutes, obtains resin compound.
2) it is added isocyanate curing agent in the resin mixture, 100 parts of resin compound, isocyanate curing agent 40 Part, obtain final product.
3) final product is rolled into the coiled material of respective thickness using calender, PET film is covered on two sides, is sliced, using plating Aluminium packs Vacuum Package, obtains final products.
4) hardness, breakdown voltage, UV accelerated ageing performance, flame retardant property and waterproof performance after test solidification.
Hardness is tested by shore hardness test method to the insulating tape that embodiment 1 is prepared into embodiment 6, By the way that 1.8mm sheet material to be coated on bare conductor, to test breakdown voltage, tested by UV accelerated ageing case to test UV and accelerate Ageing properties test flame retardant property and 4 small in water by impregnating insulating tape by horizontal, testing vertical flammability method When after test whether tolerance 12KV voltage carry out testing water-proof performance, test result is as follows:
1 test result of table
As the result is shown: the technical solution of above-described embodiment can prepare flame retardant property and waterproof performance it is good, it is non-aging, hit Wear that voltage is high, long durable insulating layer, construction is simple, conveniently can solve high-tension apparatus to ambient enviroment and personnel's bring Dangerous problem and itself because of plant issue caused by voltage.
The above is merely preferred embodiments of the present invention, be not intended to limit the invention, it is all in spirit of the invention and Within principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.

Claims (10)

1. a kind of preparation method of insulating tape characterized by comprising
Polyester polyol oxygen, fire retardant, talcum powder and carbon black are mixed, resin compound is obtained；
Curing agent is added in the resin compound, the resin compound after being solidified；
Resin compound after the solidification is rolled into coiled material；And
PET film is pasted in the coiled material upper and lower surface, is sliced, obtains the insulating tape.
2. preparation method according to claim 1, which is characterized in that the polyester polyol oxygen is C4-C30Polyester polyols Alcohol oxygen.
3. preparation method according to claim 1, which is characterized in that the fire retardant is selected from antimony oxide, hydroxide The double S ethers of magnesium, aluminium hydroxide, deca-BDE, tetrabromobisphenol A, eight bromo ether, eight bromines, three (dialkyl phosphinic acid) aluminium, hydrogen phosphite The substituted polyarylether of aluminium, methylene-diphenyl phosphine oxide-, xyxylene bis- (diphenyl phosphine oxides), 1,2- be bis--(9,10- Dihydro-9-oxy -10- phospho hetero phenanthrene -10- oxide) ethane, bis- (diphenyl phosphine oxide the ylmethyl) -1,1'- biphenyl of 4,4'-, double trimerizations The combination of one or more of cyanamide zinc pyrophosphate.
4. preparation method according to claim 1, which is characterized in that the curing agent is selected from phenolsulfonic acid, maleic two One of acid anhydrides, phthalic anhydride, dodecenylsuccinic anhydride, hexahydrophthalic acid anhydride, m-phenylene diamine (MPD), isocyanates or The a variety of combination of person.
5. preparation method according to claim 1, which is characterized in that described by polyester polyol oxygen, fire retardant, talcum powder In the step of being mixed with carbon black, obtaining resin compound, further comprise: according to mass fraction meter, by 80-120 parts Polyester polyol oxygen, 5-20 parts of fire retardant, 10-50 parts of talcum powder and 10-200 parts of carbon black is added separately to kneader In, it mediates 10-30 minutes, obtains the resin compound.
6. preparation method according to claim 1, which is characterized in that described by polyester polyol oxygen, fire retardant, talcum powder In the step of being mixed with carbon black, obtaining resin compound, further comprise: according to mass fraction meter, by 100 parts of polyester Polyalcohol oxygen, 10 parts of fire retardant, 30 parts of talcum powder and 100 parts of carbon black are added separately in kneader, are mediated 20 minutes, Obtain the resin compound.
7. preparation method according to claim 1, which is characterized in that curing agent is added in the resin compound, obtains In the step of resin compound after to solidification, further comprise: according to mass fraction meter, in 80-120 parts of resin compound 5-50 parts of middle addition curing agent.
8. preparation method according to claim 1, which is characterized in that curing agent is added in the resin compound, obtains In the step of resin compound after to solidification, further comprise: according to mass fraction meter, in 100 parts of resin compound 25 parts of curing agent of addition.
9. preparation method according to claim 1, which is characterized in that the preparation method further include: to what is be prepared Insulating tape carries out packaging of aluminizing, vacuum sealing.
10. a kind of insulating tape that preparation method according to claim 1 to 9 is prepared.
CN201710500211.5A 2017-06-27 2017-06-27 A kind of insulating tape and preparation method thereof Pending CN109423252A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201710500211.5A CN109423252A (en) 2017-06-27 2017-06-27 A kind of insulating tape and preparation method thereof
PCT/CN2018/079823 WO2019001034A1 (en) 2017-06-27 2018-03-21 Insulating tape and method for preparing same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710500211.5A CN109423252A (en) 2017-06-27 2017-06-27 A kind of insulating tape and preparation method thereof

Publications (1)

Publication Number Publication Date
CN109423252A true CN109423252A (en) 2019-03-05

Family

ID=64741921

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710500211.5A Pending CN109423252A (en) 2017-06-27 2017-06-27 A kind of insulating tape and preparation method thereof

Country Status (2)

Country Link
CN (1) CN109423252A (en)
WO (1) WO2019001034A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111825887A (en) * 2020-06-19 2020-10-27 上海太朔材料技术有限公司 Composite material containing coffee grounds and preparation method thereof

Citations (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01223187A (en) * 1988-03-02 1989-09-06 Hayakawa Rubber Co Ltd Self-adhesive flame-retardant sound-insulation sheet
JPH05202340A (en) * 1991-11-27 1993-08-10 Sekisui Chem Co Ltd Flame-retardant tacky adhesive tape and fixing of sheet for construction
CN1145937A (en) * 1995-09-21 1997-03-26 石家庄市第六橡胶厂 Fireproof self-sticking insulating rubber tape
CN1182769A (en) * 1996-09-06 1998-05-27 气体产品与化学公司 Hot melt adhesives comprising low free mnomer, low oligomer isocyanate prepolymers
CN1222554A (en) * 1998-11-05 1999-07-14 河北省徐水县胜利特种密封材料厂 Flame-retardant sealing adhesive tape and manufacturing process thereof
CN1464996A (en) * 2001-07-04 2003-12-31 昭和电工株式会社 Resist curable resin composition and cured article thereof
CN1464017A (en) * 2002-06-19 2003-12-31 广州宏昌胶粘带厂 Process for preparing organosilicon modified acrylic ester high-temperature insulation pressure-sensitive adhesive and adhesive tape
JP2006232985A (en) * 2005-02-24 2006-09-07 Shin Etsu Chem Co Ltd Non-halogen adhesive composition, and coverlay film and adhesive sheet obtained using the same
EP1719808A2 (en) * 2005-05-06 2006-11-08 Eastman Chemical Company Pressure sensitive adhesive laminates
JP2007051211A (en) * 2005-08-17 2007-03-01 Shin Etsu Chem Co Ltd Adhesive composition and coverlay film and adhesive sheet using the same
JP2007320976A (en) * 2006-05-30 2007-12-13 Nitto Denko Corp Flame-retardant adhesive sheet
CN101338167A (en) * 2007-08-13 2009-01-07 张一平 Curable adhesive tape for blocking Leakage, and repairing and protecting cable
CN101903446A (en) * 2007-12-21 2010-12-01 路博润高级材料公司 Halogen-free flame retardant thermoplastic polyurethanes
CN102020943A (en) * 2009-09-18 2011-04-20 日东电工株式会社 Insulating tape
CN102533161A (en) * 2011-12-19 2012-07-04 庄晓曦 Flame-retarding pressure-sensitive adhesive and preparation method thereof
CN102867600A (en) * 2011-07-07 2013-01-09 日东电工株式会社 Covering material, covered rectangular rlectric wire and electrical device
CN104725833A (en) * 2015-03-23 2015-06-24 深圳市沃尔核材股份有限公司 Yellowing-resistant halogen-free flame retardant thermoplastic polyurethane elastomer cable rubber material and preparation method thereof
CN106170526A (en) * 2014-04-03 2016-11-30 日东电工株式会社 Polyester adhesive composition and bonding sheet
CN106433147A (en) * 2016-09-21 2017-02-22 武汉中开维电气有限公司 Self-curing insulating material, preparation method and construction method
CN106835732A (en) * 2017-02-21 2017-06-13 东莞市雄林新材料科技股份有限公司 A kind of vehicle slit preventing PUR TPU leathers and preparation method thereof

Patent Citations (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01223187A (en) * 1988-03-02 1989-09-06 Hayakawa Rubber Co Ltd Self-adhesive flame-retardant sound-insulation sheet
JPH05202340A (en) * 1991-11-27 1993-08-10 Sekisui Chem Co Ltd Flame-retardant tacky adhesive tape and fixing of sheet for construction
CN1145937A (en) * 1995-09-21 1997-03-26 石家庄市第六橡胶厂 Fireproof self-sticking insulating rubber tape
CN1182769A (en) * 1996-09-06 1998-05-27 气体产品与化学公司 Hot melt adhesives comprising low free mnomer, low oligomer isocyanate prepolymers
CN1222554A (en) * 1998-11-05 1999-07-14 河北省徐水县胜利特种密封材料厂 Flame-retardant sealing adhesive tape and manufacturing process thereof
CN1464996A (en) * 2001-07-04 2003-12-31 昭和电工株式会社 Resist curable resin composition and cured article thereof
CN1464017A (en) * 2002-06-19 2003-12-31 广州宏昌胶粘带厂 Process for preparing organosilicon modified acrylic ester high-temperature insulation pressure-sensitive adhesive and adhesive tape
JP2006232985A (en) * 2005-02-24 2006-09-07 Shin Etsu Chem Co Ltd Non-halogen adhesive composition, and coverlay film and adhesive sheet obtained using the same
EP1719808A2 (en) * 2005-05-06 2006-11-08 Eastman Chemical Company Pressure sensitive adhesive laminates
JP2007051211A (en) * 2005-08-17 2007-03-01 Shin Etsu Chem Co Ltd Adhesive composition and coverlay film and adhesive sheet using the same
JP2007320976A (en) * 2006-05-30 2007-12-13 Nitto Denko Corp Flame-retardant adhesive sheet
CN101338167A (en) * 2007-08-13 2009-01-07 张一平 Curable adhesive tape for blocking Leakage, and repairing and protecting cable
CN101903446A (en) * 2007-12-21 2010-12-01 路博润高级材料公司 Halogen-free flame retardant thermoplastic polyurethanes
CN102020943A (en) * 2009-09-18 2011-04-20 日东电工株式会社 Insulating tape
CN102867600A (en) * 2011-07-07 2013-01-09 日东电工株式会社 Covering material, covered rectangular rlectric wire and electrical device
CN102533161A (en) * 2011-12-19 2012-07-04 庄晓曦 Flame-retarding pressure-sensitive adhesive and preparation method thereof
CN106170526A (en) * 2014-04-03 2016-11-30 日东电工株式会社 Polyester adhesive composition and bonding sheet
CN104725833A (en) * 2015-03-23 2015-06-24 深圳市沃尔核材股份有限公司 Yellowing-resistant halogen-free flame retardant thermoplastic polyurethane elastomer cable rubber material and preparation method thereof
CN106433147A (en) * 2016-09-21 2017-02-22 武汉中开维电气有限公司 Self-curing insulating material, preparation method and construction method
CN106835732A (en) * 2017-02-21 2017-06-13 东莞市雄林新材料科技股份有限公司 A kind of vehicle slit preventing PUR TPU leathers and preparation method thereof

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
吴涛 等: "电线电缆用阻燃热塑性弹性体的研究应用进展", 《弹性体》 *
山西省化工研究所 编: "《聚氨酯弹性体手册》", 31 January 2001, 化学工业出版社 *
赵世荣 等: "《液体聚合物密封材料》", 31 March 1980, 北京化工出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111825887A (en) * 2020-06-19 2020-10-27 上海太朔材料技术有限公司 Composite material containing coffee grounds and preparation method thereof

Also Published As

Publication number Publication date
WO2019001034A1 (en) 2019-01-03

Similar Documents

Publication Publication Date Title
US10626308B2 (en) Adhesive composition and an article manufactured therefrom
US20220033694A1 (en) Soft solvent-free flame-retardant polyurethane synthetic leather and preparation method therefor
CN105492534B (en) Polyurethane resin composition and the adhesive composite, laminated body, printed wiring board for using it
CN102134376B (en) Halogen-free flame-retardant resin composition and preparation method of prepreg and laminated plate
KR101817814B1 (en) Flat cable covering and flat cable using same
CN101851480A (en) Halogen-free and phosphorous-free flame-retardant synthetic resin adhesive used for flexible copper clad laminate
TW201004804A (en) Flame-retardant adhesive composition and laminated film
CN103304962B (en) Epoxy resin composition with excellent flexibility and flame retardance, and preparation method thereof
US10392540B2 (en) Adhesive composition and an article manufactured therefrom
KR102287124B1 (en) Use of an adhesive composition based on silylated polymers for cryogenic applications
JP5257125B2 (en) Curable flame retardant electromagnetic shielding film
CN109423252A (en) A kind of insulating tape and preparation method thereof
CN101906280A (en) Halogen-free epoxy adhesive for polyethylene terephthalate (PET) protective film or insulation layer and preparation method thereof
CN103694639A (en) Halogen-free anti-aging epoxy resin composition and method for preparing cover film by using same
CN103289319B (en) A kind of phosphorus nitrogen synergistic flame-retardant flexible epoxy resin composition and method of making the same
CN106478926A (en) A kind of compositionss and preparation method thereof and the application in fire proofing field
WO2021128250A1 (en) High temperature resistant b-stageable epoxy adhesive and article manufactured therefrom
CN106008902A (en) Environment-friendly anti-yellowing polyurethane composition
CN103421465B (en) Silicon rubber used for organic silicon self-adhesive tape and synthesis process of silicon rubber
JP2004161805A (en) Flame-retardant epoxy resin composition, and prepreg, laminate, copper-clad laminate and printed circuit board containing the same
JP2005187810A (en) Flame retardant resin composition and metal-clad laminated sheet for flexible printed wiring board, cover lay, adhesive sheet and flexible printed wiring board using this composition
CN110349717B (en) High-temperature stable flame-retardant insulating composite material for generator
CN105733485A (en) Resin composition and application thereof
JP5909693B2 (en) High heat resistant epoxy resin composition, prepreg, metal-clad laminate and printed wiring board
CN102321357A (en) Environment-friendly heat-resistant antistatic insulating material

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20190305

RJ01 Rejection of invention patent application after publication