CN109410739A - Polyester film electronic tag material and preparation method thereof is electroplated in a kind of phosphorus nitrogen system's environmental protection flame retardant - Google Patents

Polyester film electronic tag material and preparation method thereof is electroplated in a kind of phosphorus nitrogen system's environmental protection flame retardant Download PDF

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Publication number
CN109410739A
CN109410739A CN201811168215.9A CN201811168215A CN109410739A CN 109410739 A CN109410739 A CN 109410739A CN 201811168215 A CN201811168215 A CN 201811168215A CN 109410739 A CN109410739 A CN 109410739A
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CN
China
Prior art keywords
polyester film
phosphorus
flame retardant
nitrogen
coating
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811168215.9A
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Chinese (zh)
Inventor
贺凌
周荣杰
王益刚
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Shenzhen Chang Mao Viscose New Material Co Ltd
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Shenzhen Chang Mao Viscose New Material Co Ltd
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Application filed by Shenzhen Chang Mao Viscose New Material Co Ltd filed Critical Shenzhen Chang Mao Viscose New Material Co Ltd
Priority to CN201811168215.9A priority Critical patent/CN109410739A/en
Publication of CN109410739A publication Critical patent/CN109410739A/en
Pending legal-status Critical Current

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    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02Forms or constructions
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04Polyurethanes

Abstract

The present invention provides a kind of phosphorus nitrogen system's environmental protection flame retardant plating polyester film electronic tag material, from top to bottom includes mute finishing coat, phosphorus-nitrogen containing flame retardant coating, plating polyester film, phosphorus-nitrogen containing flame retardant coating, fire retardant pressure sensitive glue layer, polyester film die bed base stock.Electronic tag material of the invention has effects that the label material of VTM-0 grades of flame retardant effects, enhances product structure, has certain elasticity, while accomplishing fire-retardant increase product cost, is mainly used for electronics, and cable product wraps up information labels.

Description

Polyester film electronic tag material and its preparation is electroplated in a kind of phosphorus nitrogen system's environmental protection flame retardant Method
Technical field
The invention belongs to glue material fields, and in particular to polyester film electronic tag is electroplated in a kind of phosphorus nitrogen system's environmental protection flame retardant Material and preparation method thereof.
Background technique
Inside previous electronics industry, common mobile phone, the internal structures label such as computer is usually not fire-retardant, explosion-proof, The functions such as environmental protection.For the generation for preventing explosion item, interior of mobile phone burns to secondary injury caused by human and environment, environmental protection, right Human body is without side-effects, and the advantages such as cost performance height largely can introduce market in the future, becomes mainstream.
Nitrogen system environmental protection flame retardant plating polyester film electronic tag belongs to the novel industrial chain of label industry, large size processing electronics system Enterprise's such as BYD, Xin Wangda are made, needed for Foxconn etc. has, from original common product, increases flame retardant property, reaches one The field of energy high request.
Summary of the invention
The present invention provides a kind of extraordinary fire-retardant plating polyester film adhesive label material of customization, fire-retardant with VTM-0 grades The label material of effect effect enhances product structure, has certain elasticity, while accomplishing fire-retardant increase product cost, main to use In electronics, cable product wraps up information labels.
In order to achieve the above-mentioned object of the invention, The technical solution adopted by the invention is as follows:
Polyester film electronic tag material is electroplated in a kind of phosphorus nitrogen system's environmental protection flame retardant, it is characterised in that: from top to bottom includes mute Finishing coat, phosphorus-nitrogen containing flame retardant coating, plating polyester film, phosphorus-nitrogen containing flame retardant coating, fire retardant pressure sensitive glue layer, polyester film Die bed base stock;The mute finishing coat includes n propyl propionate: silica: auxiliary agent, mass ratio 86-90:8-12:2-2.5;
The phosphorus-nitrogen containing flame retardant coating is phosphorus-nitrogen system simple substance flame-retardant system TODPDM, includes polyphosphoric acid melamine phosphorus Hydrochlorate and melamine isocyanuric acid, mass ratio 2:1-1.5:1, wherein phosphorus content is in polyphosphoric acid melamine phosphate 13-26%, nitrogen content 40-65%;
The fire retardant pressure sensitive glue layer is PSA acrylic resin, ammonium dihydrogen phosphate, meso-tetraphenyl flutter pheno C44H32N4、 Solvent acetic acid ethyl ester C4H8O2With isocyanate hardener mixture, mass ratio 50-90:10-15:13-17:100-150: 1.5-2.5。
Further, the plating polyester film is the transparent PET polyester film that surface is coated with one layer of metallic aluminium.
Further, the mute finishing coat includes n propyl propionate: silica: auxiliary agent, mass ratio 88:10: 2.2。
Further, the phosphorus-nitrogen system simple substance flame-retardant system TODPDM includes polyphosphoric acid melamine phosphate and trimerization Cyanamide isocyanuric acid, wherein phosphorus content is 23% in polyphosphoric acid melamine phosphate, nitrogen content 65%.
The preparation method of a kind of phosphorus nitrogen system's environmental protection flame retardant plating polyester film electronic tag material, it is characterised in that including such as Lower step:
(1) phosphorus nitrogen system is configured to after being first sufficiently mixed polyphosphoric acid melamine phosphate and melamine isocyanuric acid Fire retardant coating solution is applied in the both side surface of plating polyester film, after drying, is coated primary;
(2) PSA acrylic resin, ammonium dihydrogen phosphate, meso-tetraphenyl are flutterred into pheno C44H32N4, solvent acetic acid ethyl ester C4H8O2With isocyanate hardener, stirs 20 minutes, keep its evenly dispersed, fire retardant pressure sensitive glue is made, it is fire-retardant by what is be stirred Pressure-sensitive glue is coated in the above-mentioned plating polyester film electroless coating one side for having been coated with flame retardant coating, and glue coating dry measure is in 15- 30g/ square metres, attach the release base stock with release function, winding molding;
(3) after being sufficiently mixed n propyl propionate, silica, auxiliary agent, it is applied to the other side table of plating polyester film On face, flame retardant coating is covered, keeps appearance unaffected and there can be good printing effect.
In phosphorus-nitrogen containing flame retardant coating solution, conventional polyester film surface will be applied to, and the content of phosphorous system, research institute helps In the increase of flame retardant effect.It combines, stirs 20 minutes with acrylic acid fire retardant pressure sensitive glue with isocyanate hardener, make it uniformly Dispersion, enables strand to be effectively connected, does not influence the characteristic that terminal uses.Coating is covered, keeps appearance unaffected, is being bonded On polyester film, protective effect is generated.Glue keeps flame-retardant glue stronger again.
The beneficial effects of the present invention are: the present invention mainly with nitrogen system environmental protection fire retarding agent, has material by dissolving in for it Good anti-flammability selects Mylar material laminating type, makes have glue between film and film, and glue makes product structure generate change Change, there is a point elasticity, shatter-resistant, shockproof protection effect.
Specific embodiment
Present invention will be further explained below with reference to specific examples.It should be understood that these embodiments are merely to illustrate this hair It is bright, rather than limit the scope of the invention.Under the premise of without departing substantially from technical solution of the invention, the present invention is made Those of ordinary skill in the art's any change easy to accomplish fall within scope of the presently claimed invention.
Embodiment 1
Polyester film electronic tag material is electroplated in a kind of phosphorus nitrogen system's environmental protection flame retardant, it is characterised in that: from top to bottom includes mute Finishing coat, phosphorus-nitrogen containing flame retardant coating, plating polyester film, phosphorus-nitrogen containing flame retardant coating, fire retardant pressure sensitive glue layer, polyester film Die bed base stock;The mute finishing coat includes n propyl propionate: silica: auxiliary agent ethyl acetate, mass ratio 88:10: 2.2;
The phosphorus-nitrogen containing flame retardant coating is phosphorus-nitrogen system simple substance flame-retardant system TODPDM, includes polyphosphoric acid melamine phosphorus Hydrochlorate and melamine isocyanuric acid, mass ratio 1.75:1, wherein phosphorus content is in polyphosphoric acid melamine phosphate 23%, nitrogen content 65%;
The fire retardant pressure sensitive glue layer is PSA acrylic resin, ammonium dihydrogen phosphate, meso-tetraphenyl flutter pheno C44H32N4、 Solvent acetic acid ethyl ester C4H8O2With isocyanate hardener mixture, mass ratio 70:12.5:15:125:2.
The plating polyester film is the transparent PET polyester film that surface is coated with one layer of metallic aluminium.
The preparation method of a kind of phosphorus nitrogen system's environmental protection flame retardant plating polyester film electronic tag material, it is characterised in that including such as Lower step:
(1) phosphorus nitrogen system is configured to after being first sufficiently mixed polyphosphoric acid melamine phosphate and melamine isocyanuric acid Fire retardant coating solution is applied in the both side surface of plating polyester film, after drying, is coated primary;
(2) PSA acrylic resin, ammonium dihydrogen phosphate, meso-tetraphenyl are flutterred into pheno C44H32N4, solvent acetic acid ethyl ester C4H8O2With isocyanate hardener, stirs 20 minutes, keep its evenly dispersed, fire retardant pressure sensitive glue is made, it is fire-retardant by what is be stirred Pressure-sensitive glue is coated in the above-mentioned plating polyester film electroless coating one side for having been coated with flame retardant coating, and glue coating dry measure is in 25g/ Square metre, attach the release base stock with release function, winding molding;
(3) after being sufficiently mixed n propyl propionate, silica, auxiliary agent ethyl acetate, it is applied to plating polyester film On another side surface, flame retardant coating is covered, keeps appearance unaffected and there can be good printing effect.
Embodiment 2
Polyester film electronic tag material is electroplated in a kind of phosphorus nitrogen system's environmental protection flame retardant, it is characterised in that: from top to bottom includes mute Finishing coat, phosphorus-nitrogen containing flame retardant coating, plating polyester film, phosphorus-nitrogen containing flame retardant coating, fire retardant pressure sensitive glue layer, polyester film Die bed base stock;The mute finishing coat includes n propyl propionate: silica: auxiliary agent ethyl acetate, mass ratio 86:12:2;
The phosphorus-nitrogen containing flame retardant coating is phosphorus-nitrogen system simple substance flame-retardant system TODPDM, includes polyphosphoric acid melamine phosphorus Hydrochlorate and melamine isocyanuric acid, mass ratio 2:1, wherein phosphorus content is 26% in polyphosphoric acid melamine phosphate, Nitrogen content is 40%;
The fire retardant pressure sensitive glue layer is PSA acrylic resin, ammonium dihydrogen phosphate, meso-tetraphenyl flutter pheno C44H32N4、 Solvent acetic acid ethyl ester C4H8O2With isocyanate hardener mixture, mass ratio 90:10:17:100:2.5.
The plating polyester film is the transparent PET polyester film that surface is coated with one layer of metallic aluminium.
The preparation method of a kind of phosphorus nitrogen system's environmental protection flame retardant plating polyester film electronic tag material, it is characterised in that including such as Lower step:
(1) phosphorus nitrogen system is configured to after being first sufficiently mixed polyphosphoric acid melamine phosphate and melamine isocyanuric acid Fire retardant coating solution is applied in the both side surface of plating polyester film, after drying, is coated primary;
(2) PSA acrylic resin, ammonium dihydrogen phosphate, meso-tetraphenyl are flutterred into pheno C44H32N4, solvent acetic acid ethyl ester C4H8O2With isocyanate hardener, stirs 20 minutes, keep its evenly dispersed, fire retardant pressure sensitive glue is made, it is fire-retardant by what is be stirred Pressure-sensitive glue is coated in the above-mentioned plating polyester film electroless coating one side for having been coated with flame retardant coating, and glue coating dry measure is in 15g/ Square metre, attach the release base stock with release function, winding molding;
(3) after being sufficiently mixed n propyl propionate, silica, auxiliary agent ethyl acetate, it is applied to plating polyester film On another side surface, flame retardant coating is covered, keeps appearance unaffected and there can be good printing effect.
Embodiment 3
Polyester film electronic tag material is electroplated in a kind of phosphorus nitrogen system's environmental protection flame retardant, it is characterised in that: from top to bottom includes mute Finishing coat, phosphorus-nitrogen containing flame retardant coating, plating polyester film, phosphorus-nitrogen containing flame retardant coating, fire retardant pressure sensitive glue layer, polyester film Die bed base stock;The mute finishing coat includes n propyl propionate: silica: auxiliary agent ethyl acetate, mass ratio 90:8:2.5;
The phosphorus-nitrogen containing flame retardant coating is phosphorus-nitrogen system simple substance flame-retardant system TODPDM, includes polyphosphoric acid melamine phosphorus Hydrochlorate and melamine isocyanuric acid, mass ratio 1.5:1, wherein phosphorus content is in polyphosphoric acid melamine phosphate 13%, nitrogen content 65%;
The fire retardant pressure sensitive glue layer is PSA acrylic resin, ammonium dihydrogen phosphate, meso-tetraphenyl flutter pheno C44H32N4、 Solvent acetic acid ethyl ester C4H8O2With isocyanate hardener mixture, mass ratio 50:15:13:150:1.5.
The plating polyester film is the transparent PET polyester film that surface is coated with one layer of metallic aluminium.
The preparation method of a kind of phosphorus nitrogen system's environmental protection flame retardant plating polyester film electronic tag material, it is characterised in that including such as Lower step:
(1) phosphorus nitrogen system is configured to after being first sufficiently mixed polyphosphoric acid melamine phosphate and melamine isocyanuric acid Fire retardant coating solution is applied in the both side surface of plating polyester film, after drying, is coated primary;
(2) PSA acrylic resin, ammonium dihydrogen phosphate, meso-tetraphenyl are flutterred into pheno C44H32N4, solvent acetic acid ethyl ester C4H8O2With isocyanate hardener, stirs 20 minutes, keep its evenly dispersed, fire retardant pressure sensitive glue is made, it is fire-retardant by what is be stirred Pressure-sensitive glue is coated in the above-mentioned plating polyester film electroless coating one side for having been coated with flame retardant coating, and glue coating dry measure is in 30g/ Square metre, attach the release base stock with release function, winding molding;
(3) after being sufficiently mixed n propyl propionate, silica, auxiliary agent ethyl acetate, it is applied to plating polyester film On another side surface, flame retardant coating is covered, keeps appearance unaffected and there can be good printing effect.
Comparative example 1
It is same as Example 1, in addition to phosphorus content is 10% in polyphosphoric acid melamine phosphate, nitrogen content 70%.
Comparative example 2
It is same as Example 1, in addition to phosphorus content is 30% in polyphosphoric acid melamine phosphate, nitrogen content 30%.
Comparative example 3
It is same as Example 1, in addition to the phosphorus-nitrogen containing flame retardant coating is phosphorus-nitrogen system simple substance flame-retardant system TODPDM, packet Phosphate containing polyphosphoric acid melamine and melamine isocyanuric acid, mass ratio 1:1.
Comparative example 4
It is same as Example 1, in addition to the phosphorus-nitrogen containing flame retardant coating is phosphorus-nitrogen system simple substance flame-retardant system TODPDM, packet Phosphate containing polyphosphoric acid melamine and melamine isocyanuric acid, mass ratio 3:1.
Comparative example 5
It is same as Example 1, in addition to the phosphorus-nitrogen containing flame retardant coating is polyphosphoric acid melamine phosphate.
The test method of 180 degree peeling force:
Test sample is cut into the tested sample strip of 175mm*25.4mm, it is stainless that tested sample strip is affixed on 304# On steel plate, is pressed the reciprocal roll-in of speed 3 times of 30cm/ minutes using 2kg roller, enable adhesive tape closely then stainless in 304# On steel plate, after twenty minutes, 180 degree peel test force instrument sets correlated condition to room temperature, at the uniform velocity with 30cm/ minutes speed Tested sample strip is removed from 304# stainless steel plate, after the automatic read test numerical value of 180 degree peel test force instrument again manually Value simultaneously records (most stable median).
Combustion testing method: flame height 20mm is adjusted, applies flame time 3s for the first time, anneals and record flaming combustion Time t1;Second of application flame time 3s, anneals and records flaming combustion time t2 and glowing time t3;It records simultaneously Whether burning be more than 125mm graticule and whether have dropping ignite lower section be arranged absorbent cotton.
2, at room temperature to the adhesion strength of flat surface, testing standard executes test sample referring to national standard GB/T2792.
Comparison of test results:
Table 1

Claims (5)

1. polyester film electronic tag material is electroplated in a kind of phosphorus nitrogen system's environmental protection flame retardant, it is characterised in that: from top to bottom include mute face Coating, phosphorus-nitrogen containing flame retardant coating, plating polyester film, phosphorus-nitrogen containing flame retardant coating, fire retardant pressure sensitive glue layer, polyester film bottom Type base stock;The mute finishing coat includes n propyl propionate: silica: auxiliary agent, mass ratio 86-90:8-12:2-2.5;
The phosphorus-nitrogen containing flame retardant coating is phosphorus-nitrogen system simple substance flame-retardant system TODPDM, includes polyphosphoric acid melamine phosphate With melamine isocyanuric acid, mass ratio 2:1-1.5:1, wherein polyphosphoric acid melamine phosphate content is 13- 26%, nitrogen content 40-65%;
The fire retardant pressure sensitive glue layer is PSA acrylic resin, ammonium dihydrogen phosphate, meso-tetraphenyl flutter pheno C44H32N4, solvent Ethyl acetate C4H8O2With isocyanate hardener mixture, mass ratio 50-90:10-15:13-17:100-150:1.5- 2.5。
2. polyester film electronic tag material is electroplated in phosphorus nitrogen according to claim 1 system's environmental protection flame retardant, it is characterised in that electricity Plating polyester film is the transparent PET polyester film that surface is coated with one layer of metallic aluminium.
3. polyester film electronic tag material is electroplated in phosphorus nitrogen according to claim 1 system's environmental protection flame retardant, it is characterised in that: institute Stating mute finishing coat includes n propyl propionate: silica: auxiliary agent, mass ratio 88:10:2.2.
4. polyester film electronic tag material is electroplated in phosphorus nitrogen according to claim 1 system's environmental protection flame retardant, it is characterised in that: institute Stating phosphorus-nitrogen system simple substance flame-retardant system TODPDM includes polyphosphoric acid melamine phosphate and melamine isocyanuric acid, wherein gathering Phosphorus content is 23% in melamine phosphate phosphate, nitrogen content 65%.
5. a kind of preparation method of phosphorus nitrogen system's environmental protection flame retardant plating polyester film electronic tag material, it is characterised in that including as follows Step:
(1) it is fire-retardant that phosphorus nitrogen system is configured to after being first sufficiently mixed polyphosphoric acid melamine phosphate with melamine isocyanuric acid Agent coating solution is applied in the both side surface of plating polyester film, after drying, is coated primary;
(2) PSA acrylic resin, ammonium dihydrogen phosphate, meso-tetraphenyl are flutterred into pheno C44H32N4, solvent acetic acid ethyl ester C4H8O2With Isocyanate hardener stirs 20 minutes, keeps its evenly dispersed, fire retardant pressure sensitive glue is made, the fire retardant pressure sensitive glue that will be stirred Water is coated in the above-mentioned plating polyester film electroless coating one side for having been coated with flame retardant coating, and glue coating dry measure is flat in 15-30g/ Square rice attaches the release base stock with release function, winding molding;
(3) it after being sufficiently mixed n propyl propionate, silica, auxiliary agent, is applied on another side surface of plating polyester film, Cover flame retardant coating.
CN201811168215.9A 2018-10-08 2018-10-08 Polyester film electronic tag material and preparation method thereof is electroplated in a kind of phosphorus nitrogen system's environmental protection flame retardant Pending CN109410739A (en)

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Cited By (2)

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CN110317547A (en) * 2019-06-21 2019-10-11 深圳昌茂粘胶新材料有限公司 A kind of PET battery label material and preparation method thereof with flame resistant drippage
CN113045995A (en) * 2020-12-22 2021-06-29 深圳昌茂粘胶新材料有限公司 Substrate double-sided adhesive tape with ultrathin fireproof flame retardance and preparation method thereof

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CN107573866A (en) * 2017-10-24 2018-01-12 深圳昌茂粘胶新材料有限公司 A kind of ultra-thin fire protection flame retarding double faced adhesive tape
CN108510874A (en) * 2018-04-08 2018-09-07 深圳昌茂粘胶新材料有限公司 Fire-retardant label of a kind of self-bleeding battery of environmental protection and preparation method thereof

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CN110317547A (en) * 2019-06-21 2019-10-11 深圳昌茂粘胶新材料有限公司 A kind of PET battery label material and preparation method thereof with flame resistant drippage
CN113045995A (en) * 2020-12-22 2021-06-29 深圳昌茂粘胶新材料有限公司 Substrate double-sided adhesive tape with ultrathin fireproof flame retardance and preparation method thereof

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