CN109401473A - A kind of glass and ceramic surface thermal spray coloured silk membrane technology - Google Patents

A kind of glass and ceramic surface thermal spray coloured silk membrane technology Download PDF

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Publication number
CN109401473A
CN109401473A CN201811290094.5A CN201811290094A CN109401473A CN 109401473 A CN109401473 A CN 109401473A CN 201811290094 A CN201811290094 A CN 201811290094A CN 109401473 A CN109401473 A CN 109401473A
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parts
agent
spray
color film
coloured silk
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郭洪坤
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Huoshan Weitao New Material Technology Co Ltd
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Huoshan Weitao New Material Technology Co Ltd
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Priority to CN201811290094.5A priority Critical patent/CN109401473A/en
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/001—General methods for coating; Devices therefor
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
    • C03C17/007—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character containing a dispersed phase, e.g. particles, fibres or flakes, in a continuous phase
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
    • C03C17/008—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character comprising a mixture of materials covered by two or more of the groups C03C17/02, C03C17/06, C03C17/22 and C03C17/28
    • C03C17/009—Mixtures of organic and inorganic materials, e.g. ormosils and ormocers
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5025—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with ceramic materials
    • C04B41/5045—Rare-earth oxides
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81—Coating or impregnation
    • C04B41/85—Coating or impregnation with inorganic materials
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    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
    • C03C2217/40—Coatings comprising at least one inhomogeneous layer
    • C03C2217/43—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
    • C03C2217/70—Properties of coatings
    • C03C2217/72—Decorative coatings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/221—Oxides; Hydroxides of metals of rare earth metal
    • C08K2003/2213—Oxides; Hydroxides of metals of rare earth metal of cerium
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
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    • C08K2003/2227—Oxides; Hydroxides of metals of aluminium
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2265—Oxides; Hydroxides of metals of iron
    • C08K2003/2272—Ferric oxide (Fe2O3)
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2289—Oxides; Hydroxides of metals of cobalt
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
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Abstract

The invention discloses a kind of glass and ceramic surface thermal spray coloured silk membrane technologies, it includes 18-22 parts of EDTA ethylenediamine tetra-acetic acid that it, which plates color film its component by weight, 18-22 parts of glycerol alcohol ester, 13-17 parts of ethyl acetate, 9-10 parts of polyacrylic resin, aobvious (12-18 parts of iron oxide red of agent of coloured silk, 6-10 parts of cobalt oxide, aoxidize bait -8-10, 1-2 parts of aluminium oxide, 12-17 parts of titanium oxide, 7-12 parts of cerium oxide), 5-10 parts of film forming agent, 1-3 parts of dispersing agent, 2-4 parts of curing agent, 10-14 parts of metal-chelator, 1-2 parts of silicone couplet, preparation method is first by EDTA ethylenediamine tetra-acetic acid, ethyl acetate, polyacrylic resin is added in glycerol alcohol ester and stirs and evenly mixs, obtain mixed material A；Aobvious color agent is added in mixed material A again and is stirred evenly, mixed material B is obtained, finally film forming agent, dispersing agent, curing agent, metal-chelator, silicone couplet are added in mixed material B and stirred and evenly mixed to get the color film of plating is arrived.

Description

A kind of glass and ceramic surface thermal spray coloured silk membrane technology
[technical field]
The invention belongs to glass, ceramic spraying plating processing technique field, and in particular to a kind of glass and ceramic surface heat Spraying plating coloured silk membrane technology.
[background technique]
For the glass or ceramic of finished product or semi-finished product, vacuum ion plating coloured silk film is carried out due to various needs Secondary operation.It since plating metal aoxidizes color film tradition is processed using vaccum ion coater, equipment investment is big, is lost It is high, difficult maintenance, stringent to operation art technique and be unable to streamline production operation, and cause time-consuming, finished product efficiency is low, and And vacuum ion membrane plating carries out in low temperature, low with the binding force of glass or ceramic, color film is easy to oxidize and falls off.
[summary of the invention]
Problem in view of the shortcomings of the prior art, the present invention is intended to provide a kind of glass and the thermal spray of ceramic surface Color membrane technology.
In order to achieve the above objectives, a kind of glass of the present invention and ceramic surface thermal spray coloured silk membrane technology, it is special Sign is by preparation is plated four color film, adjustment spray dedicated unit, spray oxidation filming and baking and curing steps and completed.
In order to achieve the above objectives, a kind of glass of the present invention and ceramic surface thermal spray coloured silk membrane technology, it is special Sign is that color film is plated in the preparation, and plating color film its component by weight includes EDTA ethylenediamine tetra-acetic acid 18-22 Part, 18-22 part of glycerol alcohol ester, 13-17 part of ethyl acetate, 9-10 parts of polyacrylic resin, aobvious color agent (12-18 parts of iron oxide red, 6-10 parts of cobalt oxide, aoxidize bait -8-10,1-2 parts of aluminium oxide, 12-17 parts of titanium oxide, 7-12 parts of cerium oxide), film forming agent 5-10 Part, 1-3 parts of dispersing agent, 2-4 parts of curing agent, 10-14 parts of metal-chelator, 1-2 parts of silicone couplet, preparation method is first will EDTA ethylenediamine tetra-acetic acid, ethyl acetate, polyacrylic resin are added in glycerol alcohol ester and stir and evenly mix, and obtain mixed material A；Again Aobvious color agent is added in mixed material A and is stirred evenly, mixed material B is obtained, finally by film forming agent, dispersing agent, curing agent, metal chelating Mixture, silicone couplet, which are added in mixed material B, to be stirred and evenly mixed to get the color film of plating is arrived.
In order to achieve the above objectives, a kind of glass of the present invention and ceramic surface thermal spray coloured silk membrane technology, it is special Sign is that the adjustment spray dedicated unit is to be adjusted to the dedicated unit of the color film of spray plating, and will plate color film Constant pressure normal temperature storage is carried out, spray dedicated unit is placed in security context, and heat dissipation is installed on the spray head of spray dedicated unit Cooling device, compressed air used require dry, cleaning, constant pressure.
In order to achieve the above objectives, a kind of glass of the present invention and ceramic surface thermal spray coloured silk membrane technology, it is special Sign is that the spray oxidation filming is that the temperature of glass and ceramic is controlled at 450-800 DEG C, clean closed Unlatching spray dedicated unit, sprays glass and ceramic under environment, after plating color film spray, according to the color film of plating Reaction temperature adjust color film thickness.
In order to achieve the above objectives, a kind of glass of the present invention and ceramic surface thermal spray coloured silk membrane technology, it is special Sign is that the baking and curing is to carry out baking and curing after glass and ceramic high temperature spray plate color film, keeps plating color Film has the rearrangement of more fully time progress molecule.
In order to achieve the above objectives, a kind of glass of the present invention and ceramic surface thermal spray coloured silk membrane technology, it is special Sign is that the film forming agent is rosin ester, and the dispersing agent is AK-1000, and the curing agent is povidone, described Metal-chelator is nitrilotriacetic acid trisodium salt, and the silicone couplet is amino silicane coupling agent KH-550.
A kind of glass and ceramic surface thermal spray coloured silk membrane technology of the invention have the beneficial effect that:
The first, it solves the drawbacks of traditional vacuum ion plating coloured silk membrane technology, improves production efficiency, it is energy saving, improve finished product Rate；The second, plating color film is to enable color film securely color film spray is plated to the surface of glass or ceramics under conditions of high temperature In conjunction with the surface of glass or ceramics, asked caused by solving in traditional vacuum ion-plating technique due to color film is insecure Topic；Third, the cost for substantially reducing equipment investment more have advantage for the popularization in market.
[Detailed description of the invention]
Fig. 1 is the process flow chart of a kind of described glass and ceramic surface thermal spray coloured silk membrane technology.
[specific embodiment]
With reference to the accompanying drawing 1 and specific embodiment invention is further described in detail.
It is special in a kind of glass of the present invention and ceramic surface thermal spray coloured silk membrane technology preferred embodiment Sign be by: preparation is plated four color film, adjustment spray dedicated unit, spray oxidation filming and baking and curing steps and is completed.
In a kind of glass of the present invention and ceramic surface thermal spray coloured silk membrane technology preferred embodiment, institute Color film is plated in the preparation stated, and plating color film its component by weight includes 18-22 parts of EDTA ethylenediamine tetra-acetic acid, glyceryl alcohol 18-22 parts of ester, 13-17 parts of ethyl acetate, 9-10 parts of polyacrylic resin, show coloured silk agent (12-18 parts of iron oxide red, cobalt oxide 6- 10 parts, aoxidize bait -8-10,1-2 parts of aluminium oxide, 12-17 parts of titanium oxide, 7-12 parts of cerium oxide), 5-10 parts of film forming agent, dispersing agent 1-3 parts, 2-4 parts of curing agent, 10-14 parts of metal-chelator, 1-2 parts of silicone couplet, preparation method is first by EDTA ethylenediamine Tetraacethyl, ethyl acetate, polyacrylic resin are added in glycerol alcohol ester and stir and evenly mix, and obtain mixed material A；Aobvious color agent is added again Enter into mixed material A and stir evenly, obtains mixed material B, it is finally that film forming agent, dispersing agent, curing agent, metal-chelator, silicon is even Connection agent, which is added in mixed material B, to be stirred and evenly mixed to get the color film of plating is arrived.
In a kind of glass of the present invention and ceramic surface thermal spray coloured silk membrane technology preferred embodiment, institute The adjustment spray dedicated unit stated is to be adjusted to the dedicated unit of the color film of spray plating, and it is normal to plate color film progress constant pressure Temperature storage, spray dedicated unit are placed in security context, install heat radiation cooling device on the spray head of spray dedicated unit, institute Dry, cleaning, constant pressure are required with compressed air.
In a kind of glass of the present invention and ceramic surface thermal spray coloured silk membrane technology preferred embodiment, institute The spray oxidation filming stated is that the temperature of glass and ceramic is controlled at 450-800 DEG C, is opened under clean closed environment Spray dedicated unit is opened, glass and ceramic are sprayed, after plating color film spray, according to the reaction temperature for plating color film Degree adjusts color film thickness.
In a kind of glass of the present invention and ceramic surface thermal spray coloured silk membrane technology side preferred embodiment, The baking and curing is to carry out baking and curing after glass and ceramic high temperature spray plate color film, and making to plate color film has more The sufficient time carries out the rearrangement of molecule.
In a kind of glass of the present invention and ceramic surface thermal spray coloured silk membrane technology preferred embodiment, institute The film forming agent stated is rosin ester, and the dispersing agent is AK-1000, and the curing agent is povidone, the metal-chelating Agent is nitrilotriacetic acid trisodium salt, and the silicone couplet is amino silicane coupling agent KH-550.
In a kind of glass of the present invention and ceramic surface thermal spray coloured silk membrane technology preferred embodiment, institute Plating coloured silk film its component by weight stated includes 22 parts of EDTA ethylenediamine tetra-acetic acid, and 18 parts of glycerol alcohol ester, ethyl acetate 14 Part, 9 parts of polyacrylic resin, aobvious 17 parts of titanium oxide of agent of coloured silk, 6 parts of film forming agent, 1 part of dispersing agent, 2 parts of curing agent, metal-chelator 10 parts, 1 part of silicone couplet；Preparation method is first to be added to EDTA ethylenediamine tetra-acetic acid, ethyl acetate, polyacrylic resin It is stirred and evenly mixed in glycerol alcohol ester, obtains mixed material A；Aobvious color agent is added in mixed material A again and is stirred evenly, mixed material B is obtained； Finally film forming agent, dispersing agent, curing agent, metal-chelator, silicone couplet are added in mixed material B stir and evenly mix to get To color film is plated, wherein film forming agent is rosin ester, and dispersing agent AK-1000, curing agent is povidone, and metal-chelator is ammonia three Acetic acid trisodium, silicone couplet are amino silicane coupling agent KH-550.
In a kind of glass of the present invention and ceramic surface thermal spray coloured silk membrane technology preferred embodiment, institute Plating coloured silk film its component by weight stated includes 18 parts of EDTA ethylenediamine tetra-acetic acid, and 22 parts of glycerol alcohol ester, ethyl acetate 13 Part, 10 parts of polyacrylic resin, 8 parts of bait of oxidation of aobvious coloured silk agent, 9 parts of film forming agent, 3 parts of dispersing agent, 4 parts of curing agent, metal-chelator 14 parts, 2 parts of silicone couplet；Preparation method is first to be added to EDTA ethylenediamine tetra-acetic acid, ethyl acetate, polyacrylic resin It is stirred and evenly mixed in glycerol alcohol ester, obtains mixed material A；Aobvious color agent is added in mixed material A again and is stirred evenly, mixed material B is obtained； Finally film forming agent, dispersing agent, curing agent, metal-chelator, silicone couplet are added in mixed material B stir and evenly mix to get To color film is plated, wherein film forming agent is rosin ester, and dispersing agent AK-1000, curing agent is povidone, and metal-chelator is ammonia three Acetic acid trisodium, silicone couplet are amino silicane coupling agent KH-550.
In a kind of glass of the present invention and ceramic surface thermal spray coloured silk membrane technology preferred embodiment, institute Plating coloured silk film its component by weight stated includes 20 parts of EDTA (ethylenediamine tetra-acetic acid), and 20 parts of glycerol alcohol ester, ethyl acetate 16 parts, 10 parts of polyacrylic resin, aobvious coloured silk agent (7 parts of cerium oxide), 8 parts of film forming agent, 2 parts of dispersing agent, 3 parts of curing agent, metal chelating 13 parts of mixture, 1 part of silicone couplet；Preparation method is first by EDTA (ethylenediamine tetra-acetic acid), ethyl acetate, polyacrylic resin It is added in glycerol alcohol ester and stirs and evenly mixs, obtain mixed material A；Aobvious color agent is added in mixed material A again and is stirred evenly, must be mixed Material B；Finally film forming agent, dispersing agent, curing agent, metal-chelator, silicone couplet are added to stir in mixed material B and be mixed It is even to get to color film is plated, wherein film forming agent is rosin ester, and dispersing agent AK-1000, curing agent is povidone, metal-chelating Agent is nitrilotriacetic acid trisodium salt, and silicone couplet is amino silicane coupling agent KH-550.
Problem in view of the shortcomings of the prior art, the present invention is intended to provide a kind of glass and the thermal spray of ceramic surface Color membrane technology, which, which has, solves the drawbacks of traditional vacuum ion plating coloured silk membrane technology, improves production efficiency, saves energy Yield rate is improved in source, and plating color film is to enable color film color film spray is plated to the surface of glass or ceramics under conditions of high temperature Securely in conjunction with the surface of glass or ceramics, solves and caused in traditional vacuum ion-plating technique because color film is insecure The problem of；The cost for substantially reducing equipment investment more has the characteristics that advantage for the popularization in market.
According to the disclosure and teachings of the above specification, those skilled in the art in the invention can also be to above-mentioned embodiment party Formula carries out change and modification appropriate.Therefore, the invention is not limited to the specific embodiments disclosed and described above, to this Some modifications and changes of invention should also be as falling into the scope of the claims of the present invention.In addition, although this specification In use some specific terms, these terms are merely for convenience of description, does not limit the present invention in any way.

Claims (6)

1. a kind of glass and ceramic surface thermal spray coloured silk membrane technology, it is characterized in that by: it is special that color film, adjustment spray are plated in preparation It is completed with four device, spray oxidation filming and baking and curing steps.
2. a kind of glass according to claim 1 and ceramic surface thermal spray coloured silk membrane technology, which is characterized in that described Preparation plate color film, plating color film its component by weight includes 18-22 parts of EDTA ethylenediamine tetra-acetic acid, glycerol alcohol ester 18-22 parts, 13-17 parts of ethyl acetate, 9-10 parts of polyacrylic resin, show coloured silk agent (12-18 parts of iron oxide red, cobalt oxide 6-10 Part, aoxidize bait -8-10,1-2 parts of aluminium oxide, 12-17 parts of titanium oxide, 7-12 parts of cerium oxide), 5-10 parts of film forming agent, dispersing agent 1-3 Part, 2-4 parts of curing agent, 10-14 parts of metal-chelator, 1-2 parts of silicone couplet, preparation method is first by EDTA ethylenediamine tetrem Acid, ethyl acetate, polyacrylic resin are added in glycerol alcohol ester and stir and evenly mix, and obtain mixed material A；Aobvious color agent is added to again It is stirred evenly in mixed material A, obtains mixed material B, finally by film forming agent, dispersing agent, curing agent, metal-chelator, silicone couplet It is added in mixed material B and stirs and evenly mixs to get the color film of plating is arrived.
3. a kind of glass according to claim 1 and ceramic surface thermal spray coloured silk membrane technology, which is characterized in that described Adjustment spray dedicated unit be that the dedicated unit for plating color film to spray is adjusted, and will be plated color film and be carried out constant pressure room temperature Storage, spray dedicated unit are placed in security context, install heat radiation cooling device on the spray head of spray dedicated unit, used Compressed air requires dry, cleaning, constant pressure.
4. a kind of glass according to claim 1 and ceramic surface thermal spray coloured silk membrane technology, which is characterized in that described Spray oxidation filming be that the temperature of glass and ceramic is controlled at 450-800 DEG C, opened under clean closed environment Dedicated unit is sprayed, glass and ceramic are sprayed, after plating color film spray, according to the reaction temperature for plating color film Adjust color film thickness.
5. a kind of glass according to claim 1 and ceramic surface thermal spray coloured silk membrane technology, which is characterized in that described Baking and curing be to carry out baking and curing after glass and ceramic high temperature spray plate color film, making to plate color film has more sufficiently Time carry out molecule rearrangement.
6. a kind of glass according to claim 2 and ceramic surface thermal spray coloured silk membrane technology, which is characterized in that described Film forming agent be rosin ester, the dispersing agent be AK-1000, the curing agent be povidone, the metal-chelator For nitrilotriacetic acid trisodium salt, the silicone couplet is amino silicane coupling agent KH-550.
CN201811290094.5A 2018-10-31 2018-10-31 A kind of glass and ceramic surface thermal spray coloured silk membrane technology Pending CN109401473A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101823842A (en) * 2010-03-23 2010-09-08 杭州捷菱机械设备有限公司 Method and equipment for producing coated glass
CN102406290A (en) * 2011-10-20 2012-04-11 牟小燕 Fantastic artificial jewelry and preparation method thereof
CN107904560A (en) * 2018-01-15 2018-04-13 浦江金砂工艺有限公司 The technique that a kind of crystal glass decoration plates colour film in two times
CN108218245A (en) * 2018-03-12 2018-06-29 珠海里田文化有限公司 A kind of novel process for changing Glass Craft color

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101823842A (en) * 2010-03-23 2010-09-08 杭州捷菱机械设备有限公司 Method and equipment for producing coated glass
CN102406290A (en) * 2011-10-20 2012-04-11 牟小燕 Fantastic artificial jewelry and preparation method thereof
CN107904560A (en) * 2018-01-15 2018-04-13 浦江金砂工艺有限公司 The technique that a kind of crystal glass decoration plates colour film in two times
CN108218245A (en) * 2018-03-12 2018-06-29 珠海里田文化有限公司 A kind of novel process for changing Glass Craft color

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