CN109401431A - A kind of aluminum-pinch silk-screen water-based ink - Google Patents

A kind of aluminum-pinch silk-screen water-based ink Download PDF

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Publication number
CN109401431A
CN109401431A CN201811272737.3A CN201811272737A CN109401431A CN 109401431 A CN109401431 A CN 109401431A CN 201811272737 A CN201811272737 A CN 201811272737A CN 109401431 A CN109401431 A CN 109401431A
Authority
CN
China
Prior art keywords
water
parts
aluminum
based ink
aqueous
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811272737.3A
Other languages
Chinese (zh)
Inventor
胡燕捷
宋国麟
赵少铃
胡德勇
胡德平
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HUIZHOU KAKI PAINT CO Ltd
Original Assignee
HUIZHOU KAKI PAINT CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by HUIZHOU KAKI PAINT CO Ltd filed Critical HUIZHOU KAKI PAINT CO Ltd
Priority to CN201811272737.3A priority Critical patent/CN109401431A/en
Publication of CN109401431A publication Critical patent/CN109401431A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/106Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D11/107Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/037Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/102Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • C09D11/103Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds of aldehydes, e.g. phenol-formaldehyde resins

Abstract

The present invention discloses a kind of aluminum-pinch silk-screen water-based ink, comprises the following components in parts by weight: 15~35 parts of water-based acrylic resin, modified 30~50 parts of the organosilicon acrylic resin of waterborne polyester, and 20~30 parts of high etherified amino resins, 8~10 parts of pigment, 6~10 parts of auxiliary agent.After the present invention is printed on aluminum-pinch surface and is solidified; can be obtained a kind of high richness of bloom, hardness is high, impact resistance can well and the decoration protective layer of anti-pollution oil resistant; for decorating aluminium profiles plate surface stamp and protection, it is that one kind is both artistic and practical, has excellent performance, is low in cost, environment-friendlyink ink easy for construction.

Description

A kind of aluminum-pinch silk-screen water-based ink
Technical field
The invention belongs to technical field of coatings, and in particular to a kind of aluminum-pinch silk-screen water-based ink.
Background technique
Aluminum-pinch is generally single silver color, is unable to satisfy growing demand as ornament materials, and printing technique Application enrich the kind of aluminum-pinch, improve the quality of aluminum-pinch, the decorative effect for improving aluminum-pinch, expanded aluminium button Plate decoration space, is widely used.Most of aluminum-pinch manufacturing enterprises use oiliness ink for screen printing currently on the market Printing material, it is various in style too plenty for the eye to take it all in, in recent years since water-base resin and the relevant technologies achieve breakthrough, aqueous painting The advantage of material highlights, instead of many usual solvent based coatings, as people are to volatile organic matter and toxic The limitation of substance is further stringent, and in fields such as metallic paint, wood tool coating, building coatings, just gradually substitution oiliness is applying water paint Material.Water-based ink is that organic solvent is substituted using water as the solvent and diluent of ink, adjusts ink viscosity to adapt to printer A kind of environment-friendly ink that skill requires plays the role of update, enters aluminium exactly with well-known reason Buckle Printing Industry, meaning enable us wait and see.
Summary of the invention
In order to solve the above technical problems, the present invention provides a kind of aluminum-pinch silk-screen water-based ink, printing operation is simple, cost It is cheap, film hardness is higher for printing, creasing resistance is preferable, surface-brightening, lovely luster, decorative effect is excellent, is able to satisfy pair Decorate the different demands of aluminium.
The technical scheme adopted by the invention to achieve the purpose is as follows:
A kind of aluminum-pinch silk-screen water-based ink, comprises the following components in parts by weight: 15~35 parts of water-based acrylic resin, water 30~50 parts of organosilicon acrylic resin of polyester modification of property, 20~30 parts of high etherified amino resins, 8~10 parts of pigment, 6~10 parts of auxiliary agent.
It further illustrates, the water-based acrylic resin is raw for Guangzhou Chan Xie macromolecule Co., Ltd (southern resin) The WA-320 water soluble acrylic acid rouge of production or the WX-2302 water soluble acrylic acid rouge of Foshan City gulf material Science and Technology Ltd., Amoisonic production One or both of.
It further illustrates, the modified organosilicon acrylic resin of the waterborne polyester is raw for Qingyuan City Ke Linda new material Co., Ltd The modified organosilicon acrylic resin of the TG1602 water-soluble polyester of production.
It further illustrates, the high etherified amino resins are the methyl etherified of U.S. CYTEC (cyanogen is special) company production One or both of high imino group melamine resin CYMEL325 and HMMM resin CYMEL303.
It further illustrates, the pigment is macromolecular pigment, inorganic pigment, pearlescent pigment and metal resistant to high temperature One of pigment or compound.
It further illustrates, the auxiliary agent includes acid-base modifier, aqueous dispersion, aqueous wetting agent, aqueous defoaming Agent, aqueous thixotropic agent, aqueous microbiocidal, salt fog resistance auxiliary agent, deionized water and other adjusting auxiliary agents.
It further illustrates, the acid-base modifier, aqueous dispersion, aqueous wetting agent, aqueous defoamer, aqueous touching Become weight accounting in auxiliary agent of agent, aqueous microbiocidal and salt fog resistance auxiliary agent be respectively (2%~10%), (6%~10%), (5%~10%), (5%~10%), (5%~10%), (5%~10%), the remainder in auxiliary agent be deionized water and Other adjusting auxiliary agents.
Compared with prior art, the beneficial effects of the present invention are:
After the present invention is printed on aluminum-pinch surface and is solidified, it is high, resistance to that a kind of high richness of bloom, hardness can be obtained Punching performance is good and the decoration protective layer of anti-pollution oil resistant, for decorating aluminium profiles plate surface stamp and protection, be it is a kind of it is both artistic and practical, It has excellent performance, is low in cost, environment-friendlyink ink easy for construction.
Specific embodiment
In order to further understand the content, features and effects of the present invention, hereby enumerating following embodiment explanation.
Embodiment 1
A kind of aluminum-pinch silk-screen water-based ink, comprises the following components in parts by weight: 20 parts of WA-320 resin, TG1602 resin 40 parts, 20 parts of CYMEL325 resin, 10 parts of pigment, 10 parts of auxiliary agent.
Manufacturing process: it will be formulated raw material precise by weight percentage, sequentially add in mixer, sufficiently stir It mixes uniform (about needing 2 hours), it is filling after detection is qualified.
Construction technology: water-based ink is imposed on screen printing device after adjusting the viscosity that ink is needed to printing with deionized water Printing, printed document toast 15~25 minutes through 150~180 DEG C and obtain required printing.Water-based ink printing performance is shown in Table 1.
Embodiment 2
A kind of aluminum-pinch silk-screen water-based ink, comprises the following components in parts by weight: WA-320 resin 10, WX-2302 resin 15, TG1602 resins 35, CYMEL325 resin 22, pigment 8, auxiliary agent 10.
Manufacturing process: it will be formulated raw material precise by weight percentage, sequentially add in mixer, sufficiently stir It mixes uniform (about needing 2 hours), it is filling after detection is qualified.
Construction technology: water-based ink is imposed on screen printing device after adjusting the viscosity that ink is needed to printing with deionized water Printing, printed document toast 15~25 minutes through 150~180 DEG C and obtain required printing.Water-based ink printing performance is shown in Table 1.
Embodiment 3
A kind of aluminum-pinch silk-screen water-based ink, comprises the following components in parts by weight: WX-2302 resin 15, TG1602 resin 40, CYMEL303 resins 25, pigment 10, auxiliary agent 10.
Manufacturing process: it will be formulated raw material precise by weight percentage, sequentially add in mixer, sufficiently stir It mixes uniform (about needing 2 hours), it is filling after detection is qualified.
Construction technology: water-based ink is imposed on screen printing device after adjusting the viscosity that ink is needed to printing with deionized water Printing, printed document toast 15~25 minutes through 150~180 DEG C and obtain required printing.Water-based ink printing performance is shown in Table 1.
Embodiment 4
A kind of aluminum-pinch silk-screen water-based ink, comprises the following components in parts by weight: WA-320 resin 8, WX-2302 resin 12, TG1602 resins 38, CYMEL303 resin 24, pigment 8, auxiliary agent 10.
Manufacturing process: it will be formulated raw material precise by weight percentage, sequentially add in mixer, sufficiently stir It mixes uniform (about needing 2 hours), it is filling after detection is qualified.
Construction technology: water-based ink is imposed on screen printing device after adjusting the viscosity that ink is needed to printing with deionized water Printing, printed document toast 15~25 minutes through 150~180 DEG C and obtain required printing.Water-based ink printing performance is shown in Table 1
Embodiment 5
A kind of aluminum-pinch silk-screen water-based ink, comprises the following components in parts by weight: WA-320 resin 18, TG1602 resin 42, CYMEL303 resins 10, CYMEL325 resin, 10, pigment 10, auxiliary agent 10.
Manufacturing process: it will be formulated raw material precise by weight percentage, sequentially add in mixer, sufficiently stir It mixes uniform (about needing 2 hours), it is filling after detection is qualified.
Construction technology: water-based ink is imposed on screen printing device after adjusting the viscosity that ink is needed to printing with deionized water Printing, printed document toast 15~25 minutes through 150~180 DEG C and obtain required printing.Water-based ink printing performance is shown in Table 1.
1 aluminum-pinch water-based ink printing performance test table of table
Test item Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5
Hardness ≥2H ≥2H ≥2H ≥2H ≥2H
Resistant to collapsing (90 degree) It is unchanged It is unchanged It is unchanged It is unchanged It is unchanged
Adhesive force (hundred lattice 3M glue) 0 grade 0 grade 0 grade 0 grade 0 grade
Acid resistance (5%HCl 48h) It is unchanged It is unchanged It is unchanged It is unchanged It is unchanged
Alkali resistance (5%NaOH 48h) It is unchanged It is unchanged It is unchanged It is unchanged It is unchanged
Resistance to butanone wiping ≥100 ≥100 ≥100 ≥100 ≥100
Note:
Hardness test: with Chinese pencil test;
Resistant to collapsing test: measured workpiece is bent to 90 degree, and observation film layer has flawless;
Adhesive force test: hundred lattice are drawn on measured workpiece surface, is pasted, is vertically pullled 5 times with 3M adhesive tape.Observation has inkless Film obscission.It is 0 grade without falling off;
Acid and alkali resistance test: will be put into 5%HCl or 5%NaOH liquid by workpiece and impregnate 48h, take out and clean room temperature 4 Phenomena such as whether there is or not discoloration, dissolution or hardening is observed after hour;
Resistance to butanone rubbing test: the cotton balls for speckling with butanone is wiped into measured workpiece surface 100 times back and forth, surface is unchanged.
The above is only the preferred embodiments of the present invention, and is not intended to limit the present invention in any form, Any simple modification made to the above embodiment according to the technical essence of the invention, equivalent variations and modification, belong to The range of technical solution of the present invention.

Claims (7)

1. a kind of aluminum-pinch silk-screen water-based ink, which is characterized in that comprise the following components in parts by weight: water-based acrylic resin 15 ~35 parts, modified 30~50 parts of the organosilicon acrylic resin of waterborne polyester, 20~30 parts of high etherified amino resins, 8~10 parts of pigment, auxiliary agent 6 ~10 parts.
2. a kind of aluminum-pinch silk-screen water-based ink according to claim 1, it is characterised in that: the water-based acrylic resin For the WA-320 water soluble acrylic acid rouge or Foshan City gulf Amoisonic material of Guangzhou Chan Xie macromolecule Co., Ltd (southern resin) production One or both of the WX-2302 water soluble acrylic acid rouge of Science and Technology Ltd.'s production.
3. a kind of aluminum-pinch silk-screen water-based ink according to claim 1, it is characterised in that: the waterborne polyester modified silicon Third resin is the modified organosilicon acrylic resin of TG1602 water-soluble polyester of Qingyuan City Ke Linda new material Co., Ltd production.
4. a kind of aluminum-pinch silk-screen water-based ink according to claim 1, it is characterised in that: the high etherified amino resins For the methyl etherified high imino group melamine resin CYMEL325 and hexamethoxy methyl of the production of U.S. CYTEC (cyanogen is special) company One or both of melamine resin CYMEL303.
5. a kind of aluminum-pinch silk-screen water-based ink according to claim 1, it is characterised in that: the pigment is high temperature resistant One of macromolecular pigment, inorganic pigment, pearlescent pigment and metallic pigments or compound.
6. a kind of aluminum-pinch silk-screen water-based ink according to claim 1, it is characterised in that: the auxiliary agent includes soda acid tune Save agent, aqueous dispersion, aqueous wetting agent, aqueous defoamer, aqueous thixotropic agent, aqueous microbiocidal, salt fog resistance auxiliary agent, deionization Water and other adjusting auxiliary agents.
7. a kind of aluminum-pinch silk-screen water-based ink according to claim 6, it is characterised in that: the acid-base modifier, water The weight of property dispersing agent, aqueous wetting agent, aqueous defoamer, aqueous thixotropic agent, aqueous microbiocidal and salt fog resistance auxiliary agent in auxiliary agent Measure accounting be respectively (2%~10%), (6%~10%), (5%~10%), (5%~10%),
(5%~10%), (5%~10%), the remainder in auxiliary agent are deionized water and other adjusting auxiliary agents.
CN201811272737.3A 2018-10-30 2018-10-30 A kind of aluminum-pinch silk-screen water-based ink Pending CN109401431A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811272737.3A CN109401431A (en) 2018-10-30 2018-10-30 A kind of aluminum-pinch silk-screen water-based ink

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Application Number Priority Date Filing Date Title
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109929325A (en) * 2019-04-11 2019-06-25 惠州市嘉淇涂料有限公司 A kind of aluminum-pinch silk-screen water-based ink
CN116515358A (en) * 2023-04-28 2023-08-01 深圳市深赛尔股份有限公司 Preparation method of modified aqueous aluminum rolling paint and aqueous aluminum rolling-aqueous printing paint

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104559463A (en) * 2013-10-16 2015-04-29 深圳市顾康力化工有限公司 Water-based silkscreen printing ink and preparation process thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104559463A (en) * 2013-10-16 2015-04-29 深圳市顾康力化工有限公司 Water-based silkscreen printing ink and preparation process thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
清远市柯林达新材料有限公司: "TG1602水溶性聚酯改性硅丙树脂", 《HTTP://39.104.157.44/PRODUCT/392548318.HTML》 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109929325A (en) * 2019-04-11 2019-06-25 惠州市嘉淇涂料有限公司 A kind of aluminum-pinch silk-screen water-based ink
CN116515358A (en) * 2023-04-28 2023-08-01 深圳市深赛尔股份有限公司 Preparation method of modified aqueous aluminum rolling paint and aqueous aluminum rolling-aqueous printing paint

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Application publication date: 20190301