CN109400798A - Environment-friendly type is super-hydrophobic/oleophobic textile finish, preparation method and application - Google Patents

Environment-friendly type is super-hydrophobic/oleophobic textile finish, preparation method and application Download PDF

Info

Publication number
CN109400798A
CN109400798A CN201710702447.7A CN201710702447A CN109400798A CN 109400798 A CN109400798 A CN 109400798A CN 201710702447 A CN201710702447 A CN 201710702447A CN 109400798 A CN109400798 A CN 109400798A
Authority
CN
China
Prior art keywords
hydrophobic
monomer
super
environment
oleophobic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201710702447.7A
Other languages
Chinese (zh)
Other versions
CN109400798B (en
Inventor
张丹
郑君红
郑磊
黄婵娟
龙柱
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangnan University
Original Assignee
Jiangnan University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangnan University filed Critical Jiangnan University
Priority to CN201710702447.7A priority Critical patent/CN109400798B/en
Publication of CN109400798A publication Critical patent/CN109400798A/en
Application granted granted Critical
Publication of CN109400798B publication Critical patent/CN109400798B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
    • C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
    • C08F2/30—Emulsion polymerisation with the aid of emulsifying agents non-ionic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/36—Polymerisation in solid state
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/22—Esters containing halogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/22—Esters containing halogen
    • C08F220/24—Esters containing halogen containing perhaloalkyl radicals
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D06M15/277—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof containing fluorine
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/347—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated ethers, acetals, hemiacetals, ketones or aldehydes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/356—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • D06M2200/11—Oleophobic properties
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • D06M2200/12—Hydrophobic properties
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50—Modified hand or grip properties; Softening compositions

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

本发明公开了一种环保型超疏水/疏油纺织品整理剂、其制备方法及应用。所述制备方法包括：将复合乳化剂分散在去离子水中，搅拌加热后，再与丙烯酸酯类单体、苯乙烯单体及抗紫外线的可聚合单体等混合进行预乳化反应，然后在氮气中继续升温，并加入含氟单体和引发剂以引发聚合反应，聚合反应完成后加入无机类抗紫外线整理剂。本发明的制备工艺简单易行，便于大规模生产，且安全环保，成本低廉，同时本发明的环保型超疏水/疏油纺织品整理剂使用简单方便，可赋予织物优异的耐磨性、耐洗性、疏水疏油性能，同时还可大幅地提高织物的抗紫外线性能、抗断裂强度，并保持织物柔软的手感及良好的透气性，而完全不会影响织物的服用性能。

The invention discloses an environment-friendly super-hydrophobic/oleophobic textile finishing agent, a preparation method and application thereof. The preparation method includes: dispersing the composite emulsifier in deionized water, stirring and heating it, mixing with acrylate monomers, styrene monomers, and UV-resistant polymerizable monomers for pre-emulsification reaction, and then carrying out a pre-emulsification reaction in nitrogen. Continue to heat up in the middle, and add fluorine-containing monomers and initiators to initiate the polymerization reaction, and add inorganic anti-ultraviolet finishing agents after the polymerization reaction is completed. The preparation process of the invention is simple and feasible, convenient for large-scale production, safe and environmentally friendly, and low in cost. At the same time, the environment-friendly super-hydrophobic/oleophobic textile finishing agent of the invention is simple and convenient to use, and can impart excellent abrasion resistance and washing resistance to fabrics. At the same time, it can also greatly improve the anti-ultraviolet performance and breaking strength of the fabric, and maintain the soft feel and good air permeability of the fabric, without affecting the wearing performance of the fabric at all.

Description

Environment-friendly type is super-hydrophobic/oleophobic textile finish, preparation method and application
Technical field
The present invention relates to a kind of fabric finishing agents, and in particular to a kind of environment-friendly type is super-hydrophobic/oleophobic textile finish, its Preparation method and application belongs to textile finishing technical field.
Background technique
In recent years, super-hydrophobic/oleophobic material not only has important use in daily life, defends in national defense industry, medical treatment The various fields such as raw have extremely wide application prospect.Super-hydrophobic/oleophobic fabric is because it has special wettability, simultaneously also There are the performances such as Water-proof and oil-proof, antifouling, anticorrosive, freezing and automatically cleaning gradually to have been favored by people.Studies have shown that micro-nano Compound coarse structure and low-surface-energy are the key factors that super-hydrophobic/oleophobic surface is formed.
Based on this, there has been proposed many methods for preparing super-hydrophobic/oleophobic surface, as LBL self-assembly method, colloidal sol-are solidifying Glue method, plasma technology, electrochemical deposition method, etching method, phase separation method and template etc..However, the side of wherein most Method complex procedures, technical process control is difficult, needs to use special equipment, and a part of method therein is also only applicable to The flat surfaces of some special substances, it is difficult to be widely applied.
On the other hand, in textile finishing field, traditional fluorinated acrylate finishing agent mostly uses solution polymerization process system , wherein most organic solvent is poisonous and harmful and volatile, although work well it is unhealthy not environmentally, and higher cost. Furthermore it is 8 perfluoro capryl sulfonyl derivative (PFOS) and perfluorooctanoic acid that traditional fluorine-contained finishing agent, which mostly uses carbon atom number, Compound (PFOA), they are considered to have excellent hydrophobic oleophobic characteristic and good surface-active.However PFOS is a kind of Chemical stability is high, and the perfluorocarbon compound with durability, bioaccumulation and toxicity, not degradable in the environment, and There is harmfulness and potential carcinogenicity to organism, PFOS has been that European Union member countries are forbidden to use and import.
Summary of the invention
The main purpose of the present invention is to provide a kind of environment-friendly type it is super-hydrophobic/oleophobic textile finish, preparation method And application, to overcome deficiency in the prior art.
To realize aforementioned invention purpose, the technical solution adopted by the present invention is as follows:
The embodiment of the invention provides a kind of environment-friendly type it is super-hydrophobic/preparation method of oleophobic textile finish comprising:
(1) compound emulsifying agent is evenly dispersed in deionized water, it is persistently stirred and is added with the speed of 100~900r/min Heat adds acrylic ester monomer, styrene monomer and anti-ultraviolet polymerisable monomer to 40~60 DEG C, carries out pre-emulsification React 30~120min；
(2) the obtained pre-emulsification reaction mixture of step (1) is continuously heating to 65~85 DEG C under protective atmosphere, and slowly Fluorochemical monomer is added；
(3) initiator is added into the obtained hybrid reaction system of step (2), and carries out polymerization reaction 8~for 24 hours, Zhi Houjia Enter inorganic uvioresistant finishing agent, be made the environment-friendly type it is super-hydrophobic/oleophobic textile finish.
In some preferred embodiments, step (3) includes: the uniform speed slow into step (2) obtained hybrid reaction system The aqueous solution of initiator is added dropwise to cause polymerization in ground, and time for adding is 30~120min, is further continued for carrying out polymerization reaction 8~for 24 hours, Inorganic uvioresistant finishing agent is added after the completion of polymerization reaction, obtain the environment-friendly type it is super-hydrophobic/oleophobic textile finish.
The embodiment of the invention also provides the environment-friendly type prepared by preceding method it is super-hydrophobic/oleophobic textile finish.
The embodiment of the invention also provides the environment-friendly type it is super-hydrophobic/purposes of oleophobic textile finish.
Compared with the existing technology, the invention has the advantages that
(1) environment-friendly type provided by the invention it is super-hydrophobic/preparation process of oleophobic textile finish uses emulsion polymerization It realizes, and using water as dispersed phase, it is not only simple and easy, convenient for being mass produced, and also it is low in cost, environmental-friendly；It can assign Give super-hydrophobic textile, oleophobic and anti-pollution；,；
(2) environment-friendly type provided by the invention it is super-hydrophobic/oleophobic textile finish safety and environmental protection, be free of perfluoro caprylic acid (PFOA) and perfluorooctane sulfonate (PFOS) class compound, easy to use, the modes such as it is applicable to spraying, dipping and brushes Textile is arranged, applicable fabric includes all kinds of textiles such as cotton, fiber crops, silk, hair, suede, fiber, leather.
(3) environment-friendly type provided by the invention it is super-hydrophobic/oleophobic textile finish can assign fabric excellent wearability And washability, excellent hydrophobic oleophobic performance, while the anti-ultraviolet property of fabric can also be significantly increased, and significantly increase The Resisting fractre intensity of strong fabric, and also there is the soft feel being equal with fibril materials and good through its fabric after arranging Gas permeability, will not influence the wearability of fabric completely.
Detailed description of the invention
Fig. 1 a- Fig. 1 b be water and n-dodecane a kind of typical environment-friendly type of the invention it is super-hydrophobic/oleophobic textile finishing The test chart of the contact angle (respectively 160 ° and 130 °) on textile after agent arrangement.
Fig. 2 be 10 μ of μ L~30 L water droplet a kind of typical environment-friendly type of the invention it is super-hydrophobic/oleophobic textile finish Wellability test chart on textile after arrangement.
Fig. 3 be water, olive oil, hexadecane, n-dodecane a kind of typical environment-friendly type of the invention it is super-hydrophobic/oleophobic spins The wellability test chart on textile after the arrangement of fabric finishing agent.
Specific embodiment
In view of deficiency in the prior art, inventor is studied for a long period of time and is largely practiced, and is able to propose of the invention Technical solution.A kind of environment-friendly type that the one aspect of the embodiment of the present invention provides is super-hydrophobic/preparation of oleophobic textile finish Method includes:
(1) compound emulsifying agent is evenly dispersed in deionized water, it is persistently stirred and is added with the speed of 100~900r/min Heat adds acrylic ester monomer, styrene monomer and anti-ultraviolet polymerisable monomer to 40~60 DEG C, carries out pre-emulsification React 30~120min；
(2) the obtained pre-emulsification reaction mixture of step (1) is continuously heating to 65~85 DEG C under protective atmosphere, and slowly Fluorochemical monomer is added；
(3) initiator is added into the obtained hybrid reaction system of step (2), and carries out polymerization reaction 8~for 24 hours, Zhi Houjia Enter inorganic uvioresistant finishing agent, be made the environment-friendly type it is super-hydrophobic/oleophobic textile finish.
In some preferred embodiments, the step (3) includes: even into the obtained hybrid reaction system of step (2) The aqueous solution of initiator is added dropwise slowly to cause polymerization in speed, and time for adding is 30~120min, is further continued for carrying out polymerization reaction 8 ~for 24 hours, inorganic uvioresistant finishing agent is added after the completion of polymerization reaction, obtain the environment-friendly type it is super-hydrophobic/oleophobic textile Finishing agent.In some more specific embodiments, the environment-friendly type is super-hydrophobic/the preparation side of oleophobic textile finish Method includes:
(1) compound emulsifying agent is evenly dispersed in deionized water, 40~60 DEG C are heated with stirring to, mixing speed 100 ~900r/min, then acrylic ester monomer, styrene monomer and anti-ultraviolet polymerisable monomer are added in reaction system, It carries out pre-emulsification and reacts 30~120min；
(2) protective gas such as nitrogen are then passed to, 65~85 DEG C is continuously heating to, is slowly added to fluorochemical monomer；
(3) aqueous solution of initiator is added dropwise then to uniform speed slow in system with cause polymerization, time for adding be 30~ 120min, continuation polymerization reaction 8~for 24 hours, inorganic uvioresistant finishing agent is added after the completion of polymerization, it is super that environment-friendly type can be obtained Hydrophobic/oleophobic textile finish.
Further, the compound emulsifying agent includes anionic surfactant and nonionic surfactant；Described Anionic surfactant include neopelex, dodecyl sodium sulfate, double dodecylphenyl ether sodium disulfonates, Lauryl sodium sulfate, enuatrol, odium stearate, sodium abietate, any one or two or more combinations in sodium laurate, And it is without being limited thereto.
Further, the nonionic surfactant includes ethoxylated dodecyl alcohol, secondary alcohol polyoxyethylene ether, alkyl Phenol polyethenoxy ether, fatty acid methyl ester APEO, any one or two or more combinations in 13 carbon alcohol ether of isomery Object, but not limited to this.
Further, the acrylic ester monomer include methyl acrylate, ethyl acrylate, methyl methacrylate, Any one in ethyl methacrylate, butyl acrylate or two or more compositions, but not limited to this.
Further, the fluorochemical monomer includes perfluoro hexyl ethyl propylene acid esters, in ten trifluoro monooctyl ester of methacrylic acid Any one or two or more compositions, but not limited to this.
Further, the initiator includes ammonium persulfate, potassium peroxydisulfate, t-butylperbenzoate, azo diisobutyl amidine It is any one or more among bis- (2- methyl propanamide) dihydrochlorides of hydrochloride, dibenzoyl peroxide, 2,2'- azo Composition, but not limited to this.
Further, the anti-ultraviolet polymerisable monomer includes 2- ethyl -2 '-cyano -3- diphenyl acrylate, third Acrylamide, γ-(methacryloxy) propyl trimethoxy silicane, esters of acrylic acid benzophenone cpd, 2- hydroxyl -4- Propenyloxy group benzophenone, acrylic acid -2,2,6,6- tetramethyl piperidine ester, methacrylic acid -2,2,6,6- tetramethyl piperidine ester, Acrylic acid -1,2,2,6,6- pentamethvl ester, methacrylic acid -1,2,2,6,6- pentamethvl ester any one of or Two or more compositions, and it is without being limited thereto.
Further, the inorganic uvioresistant finishing agent includes TiO2、ZnO、Al2O3, kaolin, talcum powder, charcoal Black, iron oxide, lead monoxide, clay, CaCO3Among any one or more compositions, but not limited to this.
It is more preferred, the acrylic ester monomer, styrene monomer, anti-ultraviolet polymerisable monomer, fluorine-containing list The volume ratio of body and deionized water is 1:0.1~5:0.01~0.1:0.1~5:20~200.
More preferred, the quality of the compound emulsifying agent is the acrylic ester monomer, styrene monomer, uvioresistant The polymerisable monomer of line and 1wt%~10wt% of fluorochemical monomer gross mass.
It is more preferred, the compound emulsifying agent include anionic surfactant that mass ratio is 1:0.1~10 with it is non- Ionic surface active agent.
More preferred, the quality of the initiator is the acrylic ester monomer, styrene monomer, anti-ultraviolet 0.05wt%~10wt% of polymerisable monomer and fluorochemical monomer gross mass.
More preferred, the quality of the inorganic uvioresistant finishing agent is the acrylic ester monomer, styrene 0.1wt%~10wt% of monomer, anti-ultraviolet polymerisable monomer and fluorochemical monomer gross mass.
More preferred, the concentration of the initiator solution is 0.1wt%~10wt%.
The other side of the embodiment of the present invention additionally provide by preceding method preparation environment-friendly type it is super-hydrophobic/oleophobic weaving Product finishing agent.Further, the environment-friendly type it is super-hydrophobic/oleophobic textile finish is emulsion system, wherein emulsion droplet Partial size is 5~200nm.
The another aspect of the embodiment of the present invention additionally provide the environment-friendly type it is super-hydrophobic/oleophobic textile finish is in knitting The purposes of object finishing field.Preferably, the fabric includes cotton, fiber crops, silk, hair, suede, fiber or leather-like textile；Preferably, Fabric after collated at least has super-hydrophobic, oleophobic and anti-pollution.
The another aspect of the embodiment of the present invention additionally provides a kind of fabric finishing method comprising: at least to spray, soak Stain or brush mode by the environment-friendly type it is super-hydrophobic/oleophobic textile finish apply on the fabric, then to fabric carry out It preliminary drying and bakes, preferably in 70~90 DEG C of 5~30min of preliminary drying, in 120~150 DEG C of 20~60min of trainings baking.
Further, the fabric includes cotton, fiber crops, silk, hair, suede, fiber or leather-like textile.
Environment-friendly type of the invention is super-hydrophobic/and oleophobic textile finish has the characteristics that waterproof oil-proof result is good and environmentally friendly, Super-hydrophobic textile, oleophobic, antifouling and high-efficient and lasting anti-ultraviolet property can be assigned.
Environment-friendly type of the invention is super-hydrophobic/and the preparation method of oleophobic textile finish has that preparation is simple, The advantages that convenient for being mass produced.
The present invention is described in detail combined with specific embodiments below.Following embodiment will be helpful to the technology of this field Personnel further understand the present invention, but the invention is not limited in any way.It should be pointed out that the ordinary skill of this field For personnel, without departing from the inventive concept of the premise, various modifications and improvements can be made.These belong to the present invention Protection scope.
Embodiment 1: by the compound emulsifying agent (lauryl alcohol polyethylene glycol oxide of neopelex and 0.65g containing 0.35g Ether) it is dispersed in the deionized water of 200mL, it is heated with stirring to 60 DEG C, mixing speed 300r/min, then by the first of 5mL The 2- ethyl -2 ' of base methacrylate monomer, the styrene monomer of 5mL and 0.5mL-cyano -3- diphenyl acrylate is added anti- It answers in system, carries out pre-emulsification and react 60min；Then pass to nitrogen, be continuously heating to 70 DEG C, be slowly added to 15mL perfluor oneself Base ethyl propylene acid esters；The ammonium persulfate of 0.2g is dissolved in the deionized water of 25mL, then to uniform speed slow in system The aqueous solution of ammonium persulfate is added dropwise to cause polymerization, time for adding 60min continues polymerization reaction 10h, is added after the completion of polymerization The TiO of 0.25g2, can be obtained environment-friendly type it is super-hydrophobic/oleophobic textile finish.
Embodiment 2: by compound emulsifying agent (the secondary alcohol polyoxyethylene ether of dodecyl sodium sulfate and 0.35g containing 0.65g) It is dispersed in the deionized water of 300mL, is heated with stirring to 40 DEG C, mixing speed 200r/min, then by the acrylic acid of 5mL The acrylamide of butyl ester monomer, the styrene monomer of 5mL and 0.25mL is added in reaction system, carries out pre-emulsification and reacts 30min； Nitrogen is then passed to, is continuously heating to 65 DEG C, is slowly added to the ten trifluoro monooctyl ester of methacrylic acid of 10mL；By the persulfuric acid of 0.1g Potassium is dissolved in the deionized water of 30mL, and it is poly- to cause that the aqueous solution of potassium peroxydisulfate is added dropwise then to uniform speed slow in system It closes, time for adding 90min, continues polymerization reaction 8h, the ZnO of 0.1g is added after the completion of polymerization, it is super thin that environment-friendly type can be obtained Water/oleophobic textile finish.
Embodiment 3: by compound emulsifying agent, (alkyl phenol of double dodecylphenyl ether sodium disulfonates and 0.5g containing 0.5g is poly- Ethylene oxide ether) it is dispersed in the deionized water of 100mL, 50 DEG C, mixing speed 400r/min are heated with stirring to, then will γ-(methacryloxy) propyl trimethoxy silicon of the methacrylate monomer of 5mL, the styrene monomer of 5mL and 0.2mL Alkane is added in reaction system, carries out pre-emulsification and reacts 90min；Nitrogen is then passed to, 75 DEG C is continuously heating to, is slowly added to 5mL Perfluoro hexyl ethyl propylene acid esters；The t-butylperbenzoate of 0.1g is dissolved in the deionized water of 10mL, then to system The aqueous solution of t-butylperbenzoate is added dropwise middle uniform speed slow to cause polymerization, time for adding 30min continues polymerization reaction The Al of 0.15g is added in 12h after the completion of polymerization2O3, can be obtained environment-friendly type it is super-hydrophobic/oleophobic textile finish.
Embodiment 4: by compound emulsifying agent (the fatty acid methyl ester polyoxyethylene of lauryl sodium sulfate and 0.6g containing 0.2g Ether) it is dispersed in the deionized water of 250mL, it is heated with stirring to 55 DEG C, mixing speed 500r/min, then by the third of 10mL 2- hydroxyl -4- propenyloxy group the benzophenone of olefin(e) acid acetate monomer, the styrene monomer of 5mL and 0.1mL is added in reaction system, It carries out pre-emulsification and reacts 120min；Nitrogen is then passed to, is continuously heating to 80 DEG C, is slowly added to the methacrylic acid 13 of 5mL Fluorine monooctyl ester；By the azo diisobutyl amidine hydrochloride salt of 0.2g in the deionized water of 40mL, then at the uniform velocity slow in system The aqueous solution of azo diisobutyl amidine hydrochloride is added dropwise slowly to cause polymerization, time for adding 120min continues polymerization reaction 15h, polymerization after the completion of be added 1g kaolin, can be obtained environment-friendly type it is super-hydrophobic/oleophobic textile finish.
Embodiment 5: compound emulsifying agent (the 13 carbon alcohol ether of isomery of sodium abietate and 0.2g containing 0.6g) is evenly dispersed In the deionized water of 200mL, it is heated with stirring to 60 DEG C, mixing speed 900r/min, then by the ethyl methacrylate of 5mL Acrylic acid -2,2 of monomer, the styrene monomer of 10mL and 0.5mL, 6,6- tetramethyl piperidine esters are added in reaction system, carry out Pre-emulsification reacts 70min；Nitrogen is then passed to, is continuously heating to 85 DEG C, is slowly added to the perfluoro hexyl ethylacrylic acid of 10mL Ester；The dibenzoyl peroxide of 0.5g is dissolved in the deionized water of 50mL, was added dropwise then to uniform speed slow in system The aqueous solution of dibenzoyl is aoxidized to cause polymerization, time for adding 60min continues polymerization reaction 10h, is added after the completion of polymerization The talcum powder of 0.15g, can be obtained environment-friendly type it is super-hydrophobic/oleophobic textile finish.
Environment-friendly type prepared by Example 1-5 is super-hydrophobic/oleophobic textile finish (following abbreviation product of the present invention) It the modes such as sprayed, impregnated or is brushed to textile, preliminary drying then is carried out to textile and bake a period of time.It is examined through test It surveys, product of the present invention is all larger than 150 ° to the water contact angle after textile finishing, and vegetable oil contact angle is all larger than 130 °, has excellent Hydrophobic, oleophobic, self-cleaning performance, and arrange after fabric by 30 conventional washes or by 1000 times friction after, still With good hydrophobic oleophobic performance, while also there is excellent washability and wearability.Further, product of the present invention is being assigned While giving fabric excellent hydrophobic oleophobic performance, can also be significantly increased fabric anti-ultraviolet property and enhancing fabric it is anti- Breaking strength, and there is the soft feel and good gas permeability being equal with fibril materials through its fabric after arranging, it is complete It will not influence the wearability of fabric entirely.The environment-friendly type is super-hydrophobic/oleophobic textile finish product be suitable for cotton, fiber crops, silk, All kinds of textiles such as hair, suede, fiber, leather.
Please refer to Fig. 1 a- Fig. 1 b show water and n-dodecane a kind of typical environment-friendly type of the invention it is super-hydrophobic/oleophobic The contact angle (respectively 160 ° and 130 °) on textile after textile finish arrangement.Fig. 2 shows 10 μ of μ L~30 L's Water droplet a kind of typical environment-friendly type of the invention it is super-hydrophobic/oleophobic textile finish arrange after textile on wellability. Fig. 3 show water, olive oil, hexadecane, n-dodecane a kind of typical environment-friendly type of the invention it is super-hydrophobic/oleophobic textile The wellability on textile after finishing agent arrangement.
Various reaction partners and process conditions used by previous embodiment are more typical examples, but by this Case invents the National People's Congress and measures verification experimental verification, other different types of reaction partners and other process conditions listed by this specification It is applicable Deng also, and also equal attainable cost invents claimed technical effect, for example, by environment-friendly type provided by the invention Treated that fabric fibre surface can form one layer of uniform and fine and close film, the tunic for super-hydrophobic/oleophobic textile finish It not only assigns fabric excellent ultra-hydrophobicity, also adds significantly the Resisting fractre intensity of fabric.
It should be appreciated that the technical concepts and features of above-described embodiment only to illustrate the invention, its object is to allow be familiar with this The personage of item technology cans understand the content of the present invention and implement it accordingly, and it is not intended to limit the scope of the present invention.It is all Equivalent change or modification made by Spirit Essence according to the present invention, should be covered by the protection scope of the present invention.

Claims (10)

1. a kind of environment-friendly type is super-hydrophobic/preparation method of oleophobic textile finish, characterized by comprising:
(1) compound emulsifying agent is evenly dispersed in deionized water, it is continuously stirred and heated to the speed of 100~900r/min 40~60 DEG C, acrylic ester monomer, styrene monomer and anti-ultraviolet polymerisable monomer are added, carries out pre-emulsification reaction 30~120min；
(2) the obtained pre-emulsification reaction mixture of step (1) is continuously heating under protective atmosphere 65~85 DEG C, and be slowly added to Fluorochemical monomer；
(3) initiator is added into the obtained hybrid reaction system of step (2), and carries out polymerization reaction 8~for 24 hours, nothing is added later Machine class uvioresistant finishing agent, be made the environment-friendly type it is super-hydrophobic/oleophobic textile finish.
2. preparation method according to claim 1, which is characterized in that step (3) includes: to obtain mixing instead to step (2) Answer the aqueous solution of initiator is added dropwise to uniform speed slow in system with cause polymerization, time for adding be 30~120min, be further continued for into Inorganic uvioresistant finishing agent is added after the completion of polymerization reaction in row polymerization reaction 8~for 24 hours, obtain the environment-friendly type it is super-hydrophobic/ Oleophobic textile finish.
3. preparation method according to claim 1 or 2, it is characterised in that: the compound emulsifying agent includes anionic surface Activating agent and/or nonionic surfactant；Preferably, the anionic surfactant include neopelex, Dodecyl sodium sulfate, double dodecylphenyl ether sodium disulfonates, lauryl sodium sulfate, enuatrol, odium stearate, rosin acid Any one in sodium, sodium laurate or two or more combinations；Preferably, the nonionic surfactant includes laruyl alcohol Polyoxyethylene ether, secondary alcohol polyoxyethylene ether, alkyl phenol polyoxyethylene ether, fatty acid methyl ester APEO, 13 carbon alcohol of isomery Any one in ether or two or more compositions；And/or the acrylic ester monomer includes methyl acrylate, propylene Acetoacetic ester, methyl methacrylate, ethyl methacrylate, any one or two or more combinations in butyl acrylate Object；And/or the fluorochemical monomer include perfluoro hexyl ethyl propylene acid esters, it is any one in ten trifluoro monooctyl ester of methacrylic acid Kind or two or more compositions；And/or the initiator includes ammonium persulfate, potassium peroxydisulfate, t-butylperbenzoate, azo Any one of bis- (2- methyl propanamide) dihydrochlorides of diisobutyl amidine hydrochloride, dibenzoyl peroxide, 2,2'- azo Or two or more composition；And/or the anti-ultraviolet polymerisable monomer includes 2- ethyl -2 '-cyano -3- biphenyl third Olefin(e) acid ester, acrylamide, γ-(methacryloxy) propyl trimethoxy silicane, esters of acrylic acid benzophenone cpd, 2- hydroxyl -4- propenyloxy group benzophenone, acrylic acid -2,2,6,6- tetramethyl piperidine ester, methacrylic acid -2,2,6,6- tetramethyl Phenylpiperidines ester, acrylic acid -1,2,2,6,6- pentamethvl ester, among methacrylic acid -1,2,2,6,6- pentamethvl ester Any one or more compositions；And/or the inorganic uvioresistant finishing agent includes TiO2、ZnO、Al2O3, it is high Ridge soil, talcum powder, carbon black, iron oxide, lead monoxide, clay, CaCO3Among any one or more compositions.
4. preparation method according to claim 1, it is characterised in that: the acrylic ester monomer, resists styrene monomer The volume ratio of the polymerisable monomer of ultraviolet light, fluorochemical monomer and deionized water be 1:0.1~5:0.01~0.1:0.1~5:20~ 200；
And/or the quality of the compound emulsifying agent is the acrylic ester monomer, styrene monomer, anti-ultraviolet gathers Close 1wt%~10wt% of monomer and fluorochemical monomer gross mass；
And/or the compound emulsifying agent includes that the anionic surfactant that mass ratio is 1:0.1~10 is lived with non-ionic surface Property agent；
And/or the quality of the initiator is the acrylic ester monomer, styrene monomer, anti-ultraviolet polymerizable list 0.05wt%~10wt% of body and fluorochemical monomer gross mass；
And/or the quality of the inorganic uvioresistant finishing agent is the acrylic ester monomer, styrene monomer, anti-purple The polymerisable monomer of outside line and 0.1wt%~10wt% of fluorochemical monomer gross mass.
5. preparation method according to claim 2, it is characterised in that: the concentration of the initiator solution is 0.1wt% ~10wt%.
6. by any one of claim 1-5 the method prepare environment-friendly type it is super-hydrophobic/oleophobic textile finish.
7. environment-friendly type according to claim 6 is super-hydrophobic/oleophobic textile finish, it is characterised in that: the environment-friendly type Super-hydrophobic/oleophobic textile finish is emulsion system, and wherein the partial size of emulsion droplet is 5~200nm.
8. the environment-friendly type as described in any one of claim 6-7 is super-hydrophobic/oleophobic textile finish is in textile finishing field Purposes；Preferably, the fabric includes cotton, fiber crops, silk, hair, suede, fiber or leather-like textile；Preferably, knitting after collated Object at least has super-hydrophobic, oleophobic and anti-pollution.
9. a kind of fabric finishing method, characterized by comprising: at least by claim 6-7 in a manner of spraying, dipping or brushing Any one of described in environment-friendly type it is super-hydrophobic/oleophobic textile finish apply on the fabric, then by fabric at 70~90 DEG C 20~60min is dried in 5~30min of preliminary drying, 120~150 DEG C of trainings.
10. fabric finishing method according to claim 9, it is characterised in that: the fabric include cotton, fiber crops, silk, hair, Suede, fiber or leather-like textile.
CN201710702447.7A 2017-08-16 2017-08-16 Environmentally friendly superhydrophobic/oleophobic textile finishing agent, preparation method and application thereof Active CN109400798B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710702447.7A CN109400798B (en) 2017-08-16 2017-08-16 Environmentally friendly superhydrophobic/oleophobic textile finishing agent, preparation method and application thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710702447.7A CN109400798B (en) 2017-08-16 2017-08-16 Environmentally friendly superhydrophobic/oleophobic textile finishing agent, preparation method and application thereof

Publications (2)

Publication Number Publication Date
CN109400798A true CN109400798A (en) 2019-03-01
CN109400798B CN109400798B (en) 2021-04-27

Family

ID=65454631

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710702447.7A Active CN109400798B (en) 2017-08-16 2017-08-16 Environmentally friendly superhydrophobic/oleophobic textile finishing agent, preparation method and application thereof

Country Status (1)

Country Link
CN (1) CN109400798B (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110204990A (en) * 2019-06-24 2019-09-06 西安理工大学 A kind of water solubility transparent hydrophobic coating and its preparation method and application
CN111421907A (en) * 2019-04-30 2020-07-17 浙江东进新材料有限公司 Graphene conductive fabric
CN111962302A (en) * 2020-08-26 2020-11-20 广东宏昊化工有限公司 Elastic finishing agent for after-finishing of cotton fiber products and preparation method thereof
WO2021133331A1 (en) * 2019-12-24 2021-07-01 T.C. Erciyes Universitesi High-strength superhydrophobic coatings on napped textile surfaces
CN113249097A (en) * 2021-05-20 2021-08-13 浙江传化功能新材料有限公司 Polyacrylate phase-change microcapsule and preparation method thereof
CN114989695A (en) * 2022-04-21 2022-09-02 宁波宣威彩色世界涂料有限公司 Water-based environment-friendly odor-free quick-drying floor paint
CN115058894A (en) * 2022-08-17 2022-09-16 江苏金呢工程织物股份有限公司 Hydrolysis-resistant textile auxiliary for drying net
CN116695442A (en) * 2023-06-19 2023-09-05 北京中纺化工股份有限公司 Fabric with waterproof and ultraviolet-resistant functions and preparation method thereof

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5247008A (en) * 1992-01-22 1993-09-21 Bayer Aktiengesellschaft Fluorine containing copolymers and aqueous dispersions prepared therefrom
CN1613883A (en) * 2004-09-17 2005-05-11 浙江大学 Preparation of water dispersed fine emulsion of fluorine acrelate copolymer for anti-oil and anti-water agent
CN101016696A (en) * 2007-02-15 2007-08-15 浙江工业大学 Method of preparing fluorine-containing hydrophobic and oil repellent fabric finishing agent
CN101029105A (en) * 2007-03-30 2007-09-05 德谦（上海）化学有限公司 Weathering-resisting acrylic-resin containing aromatic monomer
CN102041681A (en) * 2009-10-14 2011-05-04 江南大学 Method for preparing short-chain branch water and oil repellent finishing agent containing modified nano-oxide and fluorine
CN104088134A (en) * 2014-07-18 2014-10-08 江南大学 Preparation method of ultraviolet ray resistant antibacterial fabric
CN106381709A (en) * 2016-09-05 2017-02-08 南通纺织丝绸产业技术研究院 Super-hydrophobic and anti-ultraviolet finishing agent used for textiles, and preparation method and application thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5247008A (en) * 1992-01-22 1993-09-21 Bayer Aktiengesellschaft Fluorine containing copolymers and aqueous dispersions prepared therefrom
CN1613883A (en) * 2004-09-17 2005-05-11 浙江大学 Preparation of water dispersed fine emulsion of fluorine acrelate copolymer for anti-oil and anti-water agent
CN101016696A (en) * 2007-02-15 2007-08-15 浙江工业大学 Method of preparing fluorine-containing hydrophobic and oil repellent fabric finishing agent
CN101029105A (en) * 2007-03-30 2007-09-05 德谦（上海）化学有限公司 Weathering-resisting acrylic-resin containing aromatic monomer
CN102041681A (en) * 2009-10-14 2011-05-04 江南大学 Method for preparing short-chain branch water and oil repellent finishing agent containing modified nano-oxide and fluorine
CN104088134A (en) * 2014-07-18 2014-10-08 江南大学 Preparation method of ultraviolet ray resistant antibacterial fabric
CN106381709A (en) * 2016-09-05 2017-02-08 南通纺织丝绸产业技术研究院 Super-hydrophobic and anti-ultraviolet finishing agent used for textiles, and preparation method and application thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
王立敏等: "纳米技术在功能纺织品上的应用", 《第六届功能性纺织品及纳米技术应用研讨会论文集》 *

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111421907A (en) * 2019-04-30 2020-07-17 浙江东进新材料有限公司 Graphene conductive fabric
CN111421907B (en) * 2019-04-30 2021-08-27 浙江东进新材料有限公司 Graphene conductive fabric
CN110204990A (en) * 2019-06-24 2019-09-06 西安理工大学 A kind of water solubility transparent hydrophobic coating and its preparation method and application
CN110204990B (en) * 2019-06-24 2021-08-06 西安理工大学 A kind of water-soluble transparent super-hydrophobic coating and preparation method and application thereof
WO2021133331A1 (en) * 2019-12-24 2021-07-01 T.C. Erciyes Universitesi High-strength superhydrophobic coatings on napped textile surfaces
CN111962302A (en) * 2020-08-26 2020-11-20 广东宏昊化工有限公司 Elastic finishing agent for after-finishing of cotton fiber products and preparation method thereof
CN113249097A (en) * 2021-05-20 2021-08-13 浙江传化功能新材料有限公司 Polyacrylate phase-change microcapsule and preparation method thereof
CN114989695A (en) * 2022-04-21 2022-09-02 宁波宣威彩色世界涂料有限公司 Water-based environment-friendly odor-free quick-drying floor paint
CN114989695B (en) * 2022-04-21 2023-02-10 宁波宣威彩色世界涂料有限公司 Water-based environment-friendly odor-free quick-drying floor paint
CN115058894A (en) * 2022-08-17 2022-09-16 江苏金呢工程织物股份有限公司 Hydrolysis-resistant textile auxiliary for drying net
CN116695442A (en) * 2023-06-19 2023-09-05 北京中纺化工股份有限公司 Fabric with waterproof and ultraviolet-resistant functions and preparation method thereof

Also Published As

Publication number Publication date
CN109400798B (en) 2021-04-27

Similar Documents

Publication Publication Date Title
CN109400798A (en) Environment-friendly type is super-hydrophobic/oleophobic textile finish, preparation method and application
JP6481748B2 (en) Water repellent
CN104831540B (en) Water-repellent, oil-repellent, sun-proof, anti-bend torsion and cold-resistant matt-leather-membrane aqueous coating adhesive for textiles and preparation method of matt-leather-membrane aqueous coating adhesive
CN105085793B (en) A kind of fluorine-containing textile finishing agent composition and preparation method thereof
CN101016696A (en) Method of preparing fluorine-containing hydrophobic and oil repellent fabric finishing agent
JP5862745B2 (en) Fluoropolymer and treatment agent
CN104358125B (en) A kind of environment-friendly type self-crosslinking water and oil repellant fabric finishing agent and preparation method thereof
CN105859950B (en) A kind of hud typed fluorine-containing siliceous Long carbon chain acrylate water-repellent oil-repellent agent
JP3433024B2 (en) Water / oil repellent composition
CN113249971B (en) A core-shell type short-chain fluorine-containing acrylate fabric water- and oil-repellent finishing agent and its preparation method and application
CN104179013A (en) Waterproof and oilproof composition and waterproof and oilproof additive composition
CN102493193B (en) Fluorine-containing water and oil repellant agent and preparing method thereof
CN109371679A (en) A kind of preparation method of easy stain release type fabric water-refusing oil-refusing finishing agent
JP5344076B2 (en) Fluorine-containing composition
CN101148825A (en) Organic fluorine water-refusing oil-refusing finishing agent and preparation thereof
JP2015091968A (en) Block polymer production method, block polymer, and surface treatment agent
JP2013136687A (en) Surface treating agent, and method for producing the same
CN102504136A (en) Fluorine-containing polyether acrylate polymer and preparation method thereof
CN102953264A (en) Technology of shell fabric afterfinish process
JP5556179B2 (en) Fluoropolymer and antifouling agent
CN106758232A (en) Bafta special-purpose water-proof oil-proofing agent, preparation method and its bafta processed through full low-temperature dyeing and finishing
JP2014029052A (en) Water vapor permeable and waterproof fabric and production method therefor
CN102898583A (en) Difluoroalkyl ester polymer fabric finishing agent and its preparation method
TW201321418A (en) Fluorine-containing composition and fluorine-containing polymer
CN109468840A (en) A kind of durable fabric waterproofing agent and preparation method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant