CN109395994A - A kind of nylon-coating process for splined hub - Google Patents

A kind of nylon-coating process for splined hub Download PDF

Info

Publication number
CN109395994A
CN109395994A CN201811583807.7A CN201811583807A CN109395994A CN 109395994 A CN109395994 A CN 109395994A CN 201811583807 A CN201811583807 A CN 201811583807A CN 109395994 A CN109395994 A CN 109395994A
Authority
CN
China
Prior art keywords
workpiece
nylon
coating
splined hub
priming paint
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811583807.7A
Other languages
Chinese (zh)
Inventor
穆俊豪
赵贺
柴二帅
周岩
雷务然
陈云升
马喜岭
周建喜
张鹏超
李建勋
齐瑞晓
刘金檑
李磊
侯光辉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Xuchang Yuandong Drive Shaft Co Ltd
Original Assignee
Xuchang Yuandong Drive Shaft Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Xuchang Yuandong Drive Shaft Co Ltd filed Critical Xuchang Yuandong Drive Shaft Co Ltd
Priority to CN201811583807.7A priority Critical patent/CN109395994A/en
Publication of CN109395994A publication Critical patent/CN109395994A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00Processes for applying liquids or other fluent materials
    • B05D1/36Successively applying liquids or other fluent materials, e.g. without intermediate treatment
    • B05D1/38Successively applying liquids or other fluent materials, e.g. without intermediate treatment with intermediate treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00Processes for applying liquids or other fluent materials
    • B05D1/18Processes for applying liquids or other fluent materials performed by dipping
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/02Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/12Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by mechanical means
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50Multilayers
    • B05D7/52Two layers
    • B05D7/54No clear coat specified
    • B05D7/544No clear coat specified the first layer is let to dry at least partially before applying the second layer

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

The present invention relates to the production and processing method technical fields of splined hub workpiece, more particularly to a kind of nylon-coating process for splined hub, including Work inspection device, workpiece Shot Blasting, labor cost primer dipping and coating, workpiece heating, workpiece apply nylon and finished workpart detection and etc., the huge workload for avoiding worker from using gasoline to clean machine workpieces one by one, substantially reduce process time, simplify manufacturing procedure, and the mode of gasoline cleaning is eliminated, substantially improve the environment of processing workshop, reduce production cost, the qualification rate of the nylon adhesive force detection of finished work-piece is substantially increased simultaneously.

Description

A kind of nylon-coating process for splined hub
Technical field
The present invention relates to the production and processing method technical fields of splined hub workpiece, and in particular to a kind of Buddhist nun for splined hub Imperial coated technique.
Background technique
Splined hub nylon-coating is widely used in truck drive shaft field, applies Buddhist nun on the splined hub surface of transmission shaft On the one hand dragon avoids directly contacting between steel part when splined shaft cooperates with splined hub, plays the wear-resisting effect of damping, another Coating nylon can improve the cooperation precision with oil sealing on the outside of aspect splined hub, while play antirust function, and before nylon-coating Manage extremely critical, the success or failure of pre-treatment are related to nylon adhesion effect.
Splined hub is transported to nylon-coating workshop and applies one layer to its internal spline and outer surface after machine shop processing Nylon coating inevitably attaches a large amount of greasy dirts and a little iron is cut in splined hub machining process, in transport process, The pollutants such as dust are unavoidably attached again, and traditional approach uses gasoline cleaning method, and worker scrubs part with brush one by one Completely, it then will accelerate to dry up under placing part fan, take time and effort, gasoline needs to carry out whole pond update daily, and part yet needs It cleans, dry or dries, very complicated and efficiency is very low.In actual production, using gasoline cleaning, there are many deficiencies Place, on the one hand, this method is not effective to the biggish part of greasy residues, and after especially putty mixing attaches, scrub is not only There is no effect, the more can wash the more dirty instead, hidden danger of quality is very big, part uneven color after coating, after individual part applies nylon Adhesive force is very poor, and nylon is easy to remove from sliding sleeve;On the other hand, which needs worker to have extremely strong responsibility The heart, every part are intended to scrub one by one, dry, cumbersome, large labor intensity, and in attachment force inspecting or following process It in assembling process, or often will appear nylon obscission, returned by the gross to guarantee that quality can only apply nylon part to the batch Work causes greatly to produce waste, and also often occurs individual part nylon in Market Feedback and fall off the quality accident of failure;Vapour Oil volatilization also causes very big influence to worker and processing environment, finds that the nylon poor adhesive force overwhelming majority is former by multi-party analysis It is because being that splined hub is handled before applying nylon unqualified, so the nylon-coating process for needing one kind new solves the problems, such as this.
Summary of the invention
To solve the above-mentioned problems, the present invention provides a kind of techniques of splined hub nylon-coating, including Work inspection device, throwing Ball processing, primer dipping and coating, coating nylon, reach expected results and substantially increase workpiece adhesive force detection it is qualified Rate has eliminated the mode of gasoline cleaning, has improved processing environment and the labor intensity of worker.
The present invention provides a kind of nylon-coating process for splined hub, including following step in order to solve the above problem It is rapid:
Step 1: inside and outside integrity checking is carried out to mach workpiece, workpiece is packed into material frame, in batches falls a material frame workpiece Enter in shot-blast cleaning machine and carry out Shot Blasting 5-8 minutes, the steel sand granularity in shot-blast cleaning machine is 1.5-1.8 millimeters;
Step 2: the workpiece surface after Shot Blasting is removed using air gun and remains steel sand;
Step 3: the part that workpiece is needed to apply is immersed in priming paint 1-2 seconds, is placed on workbench and is dried, until priming paint does not drip It falls;
Step 4: falling the priming paint of workpiece bottom in cotton supernatant, and workpiece is sent into heating furnace and is heated, and heating in-furnace temperature is 290-320 DEG C, until workpiece surface temperature is 270-300 DEG C, and workpiece surface is in dark-brown;
Step 5: take out workpiece, with fixture clamp workpiece do not need coating one end and keep workpiece vertical, workpiece is needed to apply The 1/3-1/2 of nylon section immerses in nylon coating fluidized bed 3-5 seconds, then needs to apply nylon section for workpiece and is totally immersed into Nylon coating fluidized bed 15-17 seconds;
Step 6: being upside down in naturally dry in the movements and postures of actors for the workpiece after dip-coating, checks and applies when workpiece surface temperature is lower than 60 DEG C Whether layer part has impurity, protrusion or collides with, and then measures nylon thickness.
Further, check that underproof workpiece uses high pressure water after 420-460 DEG C of high-temperature heating in the step 6 Rifle removes priming paint and nylon coating, then carries out step 1 and processes to step 6.
Further, the steel sand in the shot-blast cleaning machine of the step 1 is diamond shape.
Further, Number of Jobs is 100-150 part in the step 1 material frame.
Further, the priming paint is 7P-0200 priming paint.
Further, the shot-blast cleaning machine is apron type airless shot blasting machine.
Beneficial effect
1, the solution of the present invention is used for the surface nylon-coating of splined hub, and the workpiece after machining is detected no inside and outside defect Afterwards, it is framed up and puts into apron type airless shot blasting machine progress Shot Blasting, the steel sand in shot-blast cleaning machine is diamond shape, and granularity is 1.5-1.8 millimeters, Shot Blasting can effectively remove the burs such as greasy dirt, iron filings and dust of workpiece surface adherency, and 5-8 minutes Cleaning while multiple workpiece, relatively previous artificial and effect high using cleaning efficiency for gasoline cleaning can be completed in batches It is good, while reducing a large amount of gasoline and expending, save very big expense, improve workshop processing environment, and it is opposite with Toward the artificial mode for clearing up workpiece one by one, greatly reduce the labor intensity of worker, need to only be used after impeller blasting air gun or Other toolings remove the possible remaining steel sand of workpiece surface, and two steps replace previous multiple steps, when reducing mass production Between;
2, being heated to workpiece surface temperature in heating furnace after workpiece leaching priming paint dries is 270-300 DEG C, and workpiece surface is deep at this time Brown can be judged by color board, first need the part 1/3-1/2 of the part applied to be submerged initially in nylon workpiece when applying nylon Coating fluidized bed 3-5 seconds, then coated portion is needed integrally to immerse nylon coating fluidized bed workpiece, entire coating process exists 10-20 seconds, since nylon material takes difference, shake 3-4 times up and down is needed when applying German nylon powder, when coating A Kema nylon powder When need shake 5-7 time up and down so that nylon-coating is uniform, guarantee to apply effect;Product warp underproof for coating effect Primer surface and nylon coating are removed with giant after 420-460 DEG C of high-temperature heating, re-starts processing, secondary operation is still not It is done over again when qualified to machining processes before.
Specific embodiment
Embodiment 1
A kind of nylon-coating process for splined hub, comprising the following steps:
Step 1: inside and outside integrity checking is carried out to mach workpiece, 100 workpiece are packed into material frame, by a material frame workpiece It pours into apron type airless shot blasting machine and carries out Shot Blasting 5 minutes, the steel sand in shot-blast cleaning machine is diamond shape and steel sand granularity is 1.8 millimeter;
Step 2: the workpiece surface after Shot Blasting is removed using air gun and remains steel sand;
Step 3: the part that workpiece is needed to apply is immersed in priming paint 1-2 seconds, is placed on workbench and is dried, until priming paint does not drip It falls, priming paint is 7P-0200 priming paint;
Step 4: falling the priming paint of workpiece bottom in cotton supernatant, and workpiece is sent into heating furnace and is heated, and heating in-furnace temperature is 320 DEG C, until workpiece surface temperature is 300 DEG C, and workpiece surface is in dark-brown at this time, can compare and judge with color board;
Step 5: take out workpiece, with fixture clamp workpiece do not need coating one end and keep workpiece vertical, workpiece is needed to apply The 1/3-1/2 of nylon section immerses in nylon coating fluidized bed 3 seconds, then needs to apply nylon section for workpiece and is totally immersed into Buddhist nun Imperial coating fluidized bed 17 seconds;
Step 6: being upside down in naturally dry in the movements and postures of actors for the workpiece after dip-coating, and one end of workpiece uncoated nylon is made to be located at bottom, It checks whether coating part has impurity, protrusion or collide with when workpiece surface temperature is lower than 60 DEG C, then measures nylon thickness.
Product in step 6 is through detection nylon-coating effect free from admixture, protrusion, bubble or scratch, through inspecting adhesive force by random samples Test also no problem, is sent to next processing stations, checks underproof workpiece after 460 DEG C of high-temperature heatings after drying in the air to room temperature Priming paint and nylon coating are removed using giant, then the process of progress step 1 to step 6, after secondary operation Workpiece is still not qualified to do over again to machining processes;Splined hub is processed using this programme, production and processing efficiency can not only be improved, changed Kind workshop condition reduces labor intensity of workers, moreover it is possible to which the processing effect for stablizing splined hub improves the nylon adhesive force on its surface.
Embodiment 2
A kind of nylon-coating process for splined hub, comprising the following steps:
Step 1: inside and outside integrity checking is carried out to mach workpiece, 130 workpiece are packed into material frame, by a material frame workpiece It pours into apron type airless shot blasting machine and carries out Shot Blasting 7 minutes, the steel sand in shot-blast cleaning machine is diamond shape and steel sand granularity is 1.4 millimeter;
Step 2: the workpiece surface after Shot Blasting is removed using air gun and remains steel sand;
Step 3: the part that workpiece is needed to apply is immersed in priming paint 1-2 seconds, is placed on workbench and is dried, until priming paint does not drip It falls, priming paint is 7P-0200 priming paint;
Step 4: falling the priming paint of workpiece bottom in cotton supernatant, and workpiece is sent into heating furnace and is heated, and heating in-furnace temperature is 300 DEG C, until workpiece surface temperature is 290 DEG C, and slightly dim dark-brown is presented in workpiece surface at this time;
Step 5: take out workpiece, with fixture clamp workpiece do not need coating one end and keep workpiece vertical, workpiece is needed to apply The 1/3-1/2 of nylon section immerses in nylon coating fluidized bed 4 seconds, then needs to apply nylon section for workpiece and is totally immersed into Buddhist nun Imperial coating fluidized bed 16 seconds;
Step 6: being upside down in naturally dry in the movements and postures of actors for the workpiece after dip-coating, and one end of workpiece uncoated nylon is made to be located at bottom, It checks whether coating part has impurity, protrusion or collide with when workpiece surface temperature is lower than 60 DEG C, then measures nylon thickness.
Product in step 6 is through detection nylon-coating effect free from admixture, protrusion, bubble or scratch, through inspecting adhesive force by random samples Test also no problem, is sent to next processing stations, checks underproof workpiece after 445 DEG C of high-temperature heatings after drying in the air to room temperature Priming paint and nylon coating are removed using giant, then the process of progress step 1 to step 6, after secondary operation Workpiece is still not qualified to do over again to machining processes;Splined hub is processed using this programme, production and processing efficiency can not only be improved, changed Kind workshop condition reduces labor intensity of workers, moreover it is possible to which the processing effect for stablizing splined hub improves the nylon adhesive force on its surface.
Embodiment 3
A kind of nylon-coating process for splined hub, comprising the following steps:
Step 1: inside and outside integrity checking is carried out to mach workpiece, 150 workpiece are packed into material frame, by a material frame workpiece It pours into apron type airless shot blasting machine and carries out Shot Blasting 8 minutes, the steel sand in shot-blast cleaning machine is diamond shape and steel sand granularity is 1.5 millimeter;
Step 2: the workpiece surface after Shot Blasting is removed using air gun and remains steel sand;
Step 3: the part that workpiece is needed to apply is immersed in priming paint 1 to 2 seconds, is placed on workbench and is dried, until priming paint does not drip It falls, priming paint is 7P-0200 priming paint;
Step 4: falling the priming paint of workpiece bottom in cotton supernatant, and workpiece is sent into heating furnace and is heated, and heating in-furnace temperature is It 290 DEG C, until workpiece surface temperature is 270 DEG C, and the brown that workpiece surface is presented at this time, is compared and is judged by color board;
Step 5: take out workpiece, with fixture clamp workpiece do not need coating one end and keep workpiece vertical, workpiece is needed to apply The 1/3-1/2 of nylon section immerses in nylon coating fluidized bed 5 seconds, then needs to apply nylon section for workpiece and is totally immersed into Buddhist nun Imperial coating fluidized bed 15 seconds;
Step 6: being upside down in naturally dry in the movements and postures of actors for the workpiece after dip-coating, and one end of workpiece uncoated nylon is made to be located at bottom, It checks whether coating part has impurity, protrusion or collide with when workpiece surface temperature is lower than 60 DEG C, then measures nylon thickness.
Product in step 6 is through detection nylon-coating effect free from admixture, protrusion, bubble or scratch, through inspecting adhesive force by random samples Test also no problem, is sent to next processing stations, checks underproof workpiece after 420 DEG C of high-temperature heatings after drying in the air to room temperature Priming paint and nylon coating are removed using giant, then the process of progress step 1 to step 6, after secondary operation Workpiece is still not qualified to do over again to machining processes;Splined hub is processed using this programme, production and processing efficiency can not only be improved, changed Kind workshop condition reduces labor intensity of workers, moreover it is possible to which the processing effect for stablizing splined hub improves the nylon adhesive force on its surface.
The above described is only a preferred embodiment of the present invention, be not intended to limit the present invention in any form, though So the present invention has been disclosed as a preferred embodiment, and however, it is not intended to limit the invention, any technology people for being familiar with this profession Member, without departing from the scope of the present invention, when the technology contents using the disclosure above make a little change or modification It is right according to the technical essence of the invention for the equivalent embodiment of equivalent variations, but without departing from the technical solutions of the present invention Any simple modification, equivalent change and modification made by above embodiments, all of which are still within the scope of the technical scheme of the invention.

Claims (6)

1. a kind of nylon-coating process for splined hub, it is characterised in that: the following steps are included:
Step 1: inside and outside integrity checking is carried out to mach workpiece, workpiece is packed into material frame, in batches falls a material frame workpiece Enter in shot-blast cleaning machine and carry out Shot Blasting 5-8 minutes, the steel sand granularity in shot-blast cleaning machine is 1.5-1.8 millimeters;
Step 2: the workpiece surface after Shot Blasting is removed using air gun and remains steel sand;
Step 3: the part that workpiece is needed to apply is immersed in priming paint 1-2 seconds, is placed on workbench and is dried, until priming paint does not drip It falls;
Step 4: falling the priming paint of workpiece bottom in cotton supernatant, and workpiece is sent into heating furnace and is heated, and heating in-furnace temperature is 290-320 DEG C, until workpiece surface temperature is 270-300 DEG C, and workpiece surface is in dark-brown;
Step 5: take out workpiece, with fixture clamp workpiece do not need coating one end and keep workpiece vertical, workpiece is needed to apply The 1/3-1/2 of nylon section immerses in nylon coating fluidized bed 3-5 seconds, then needs to apply nylon section for workpiece and is totally immersed into Nylon coating fluidized bed 15-17 seconds;
Step 6: being upside down in naturally dry in the movements and postures of actors for the workpiece after dip-coating, checks and applies when workpiece surface temperature is lower than 60 DEG C Whether layer part has impurity, protrusion or collides with, and then measures nylon thickness.
2. a kind of nylon-coating process for splined hub as described in claim 1, it is characterised in that: examined in the step 6 Underproof workpiece is looked into after 420-460 DEG C of high-temperature heating using giant removal priming paint and nylon coating, is then walked Rapid one processes to step 6.
3. a kind of nylon-coating process for splined hub as described in claim 1, it is characterised in that: the throwing of the step 1 Steel sand in ball descaling machine is diamond shape.
4. a kind of nylon-coating process for splined hub as described in claim 1, it is characterised in that: the step 1 material frame Middle Number of Jobs is 100-150 part.
5. a kind of nylon-coating process for splined hub as described in claim 1, it is characterised in that: the priming paint is 7P- No. 0200 priming paint.
6. a kind of nylon-coating process for splined hub as described in claim 1, it is characterised in that: the shot-blast cleaning machine For apron type airless shot blasting machine.
CN201811583807.7A 2018-12-24 2018-12-24 A kind of nylon-coating process for splined hub Pending CN109395994A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811583807.7A CN109395994A (en) 2018-12-24 2018-12-24 A kind of nylon-coating process for splined hub

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811583807.7A CN109395994A (en) 2018-12-24 2018-12-24 A kind of nylon-coating process for splined hub

Publications (1)

Publication Number Publication Date
CN109395994A true CN109395994A (en) 2019-03-01

Family

ID=65460670

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201811583807.7A Pending CN109395994A (en) 2018-12-24 2018-12-24 A kind of nylon-coating process for splined hub

Country Status (1)

Country Link
CN (1) CN109395994A (en)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5546966A (en) * 1978-09-30 1980-04-02 Toyoda Gosei Kk Reinforced plastic product
CN101077495A (en) * 2007-05-18 2007-11-28 许昌远东传动轴有限公司 Transmission shaft sliding spline shaft polyundecanamide coating process

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5546966A (en) * 1978-09-30 1980-04-02 Toyoda Gosei Kk Reinforced plastic product
CN101077495A (en) * 2007-05-18 2007-11-28 许昌远东传动轴有限公司 Transmission shaft sliding spline shaft polyundecanamide coating process

Similar Documents

Publication Publication Date Title
CN105964510A (en) Varnish-baking surface coating technology
CN105013685A (en) Automobile bumper spraying process
CN107199168A (en) A kind of handware baking finish process method
CN103041973A (en) Plastic spraying technological process of metal workpiece
CN110201859A (en) A kind of auto parts and components lacquer spraying technique
CN111570236A (en) Paint spraying method for surface of carbon steel box body
CN110538783A (en) sheet metal part coating process
CN109500744A (en) Large-size stainless steel work piece surface blasting craft
CN103586185A (en) Wharf vehicle coating process
CN106031970A (en) Manufacturing method of container
CN109395994A (en) A kind of nylon-coating process for splined hub
CN113430511A (en) Surface treatment process for metal workpiece
CN111822286A (en) Spraying process for gasoline generator set
CN103586187A (en) Coating process for exported oil truck
CN110180726B (en) Novel double-track spraying production line
CN112221911A (en) Powder spraying process for automobile parts
US20160175870A1 (en) Nozzle Adjustment Aid, and Method
CN109374515B (en) Method for detecting chemical resistance of paint film in baking process
CN105903656A (en) Impurity removal process of color steel plate
AU2011257886B2 (en) Method of treating rolled steel article
CN110433999A (en) Automatic coating production line system for magnetic suspension track panel
CN110331359A (en) A kind of surface treatment method for thermal spraying inorganic coating
CN112893041A (en) Spraying method of sensor coating
CN106964528A (en) A kind of method of surface treatment before composite material blade coating iron at the leading edge spray painting
CN107486381A (en) Valve paint application technique

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20190301

RJ01 Rejection of invention patent application after publication