CN109392948A - A kind of fosthiazate granule and preparation method thereof - Google Patents
A kind of fosthiazate granule and preparation method thereof Download PDFInfo
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- CN109392948A CN109392948A CN201811599491.0A CN201811599491A CN109392948A CN 109392948 A CN109392948 A CN 109392948A CN 201811599491 A CN201811599491 A CN 201811599491A CN 109392948 A CN109392948 A CN 109392948A
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- Prior art keywords
- fosthiazate
- granule
- fertilizer
- effective component
- carrier
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/26—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-nitrogen bonds
- A01N57/32—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-nitrogen bonds containing heterocyclic radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/12—Powders or granules
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/22—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients stabilising the active ingredients
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention provides a kind of fosthiazate granule and preparation method thereof.Be made of the raw material of following mass percentage contents: effective component 0.1-20%, stable elements C 0.1-10%, surplus are carrier and auxiliary material.Effective component is fosthiazate.The stable elements C are as follows: the mixture of magnesia citrate and one or more of paraffin, alditol, sulphur ammonium.In addition to effective component fosthiazate, other pesticide activity components can also be added, mix preparation is made.In the present invention without limitation to addible pesticide activity component, but preferred nicotinoids.The present invention is studied for environmental problem caused by target drug resistance, stability to degradation and fosthiazate, provide a kind of more stable granule, nicotinic insecticide is added in concurrent fosthiazate now and not only shows good insecticidal effect, it is substantially improved in the soil regime stability inferior of different condition, effective component amount of application is reduced simultaneously, it is safer to crop and environment.
Description
Technical field
The invention belongs to pesticide fields, and in particular to a kind of fosthiazate granule and preparation method thereof.
Background technique
Fosthiazate is a kind of efficient, wide spectrum organic phosphorus nematicide of non-fumigation type of Japanese Ishihara Sangyo Kaisha Ltd.'s exploitation.
Its mechanism of action is the acetylcholinesterase for inhibiting pest, not only has very strong action of contace poison, but also be also easy in plant
Middle Uptake and translocation especially has apparent control efficiency to root-knot nematode and pratylenchus etc..But there is easily decomposition in fosthiazate
The problem of, cause the lasting period of fosthiazate shorter.
As a kind of more satisfactory nematicidal medicament, fosthiazate half-life period in soil of the pH less than 6 is 53.3-57.7
It, half-life period is only 14.1-20.7 days in soil of the pH greater than 7.Physio-biochemical characteristics based on fosthiazate, the quotient of fosthiazate
Product preparation is mostly to be prepared into granule under the working condition of pH4.5.
However in practical applications, due to various regions soil acidity or alkalinity difference, the degradation of fosthiazate granule is shown greatly
Difference, the influence generated in face of Different climate to the nematode growth period are existing due to degradation quickening and the postponement in nematode growth period
Having fosthiazate granule field rotating medicine, even there are entirely ineffective risks, also result in serious threat to environment.
Organic phosphates chemical pesticide has long usage history, and protecting to produce to world food played an important role, but
Application for a long time causes serious environmental problem and target resistance.As international community is to the pass of ball ecological environment
Note, organic phosphates chemical pesticide product is by limiting the use of on a large scale, disable.
The problem of based on chemical pesticide use process and policy pressure, research and development are efficient, the pesticide of controlled release is new
Dosage form improves applications of pesticide mode and has important practical significance.
Summary of the invention
The object of the present invention is to provide a kind of fosthiazate granules and preparation method thereof.
Fosthiazate granule provided by the present invention is made: effective component, stable elements of the raw material for including following components
C, carrier and auxiliary material.
In the fosthiazate granule, the mass percentage content of each component can are as follows: effective component 0.1-20%, stablize at
Dividing C 0.1-10%, surplus is carrier and auxiliary material.
The stable elements C can are as follows: magnesia citrate and one or more of paraffin, alditol, sulphur ammonium (ammonium sulfate)
Mixture.
Wherein, magnesia citrate is the complex that magnesia and citric acid are formed with mass ratio 3:7-4:6.
The mass ratio of magnesia citrate and one or more of paraffin, alditol, sulphur ammonium (ammonium sulfate) can are as follows: 5:1-
2.5, concretely 3.5:1.5,5:1 or 5:1.3.
In the present invention, the dosage of the stability ingredient C is not particularly limited, but according to the change for having fosthiazate dosage
Change, on the basis of the total amount of granule, usually in 0.1-10%.
The carrier can are as follows: one or more of silica, mica, talcum, clay, kaolinite, calcium carbonate, carclazyte.
Particularly, in the present invention it is possible to be used for fertilizer as carrier in the preparation of granule.
The fertilizer can are as follows: one of nitrogenous fertilizer, potash fertilizer, phosphate fertilizer, compound fertilizer, compound fertilizer, organic fertilizer, microorganism fertilizer are several
Kind.
In the present invention, according to the difference of manufacturing process, often need to be added various auxiliary material raw materials.The auxiliary material at
Divide and be not particularly limited, but generally include: adhesive helps disintegrating agent, dispersing agent, adsorbent, lubricant, diluent, coloring
One or more of agent.
The adhesive can be starch, gum arabic, soybean protein, casein, gelatine, polyvinyl acetate, poly- second
One or more of enol, rosin, shellac, pitch, ethene-vinyl acetate copolymer resins.
It is described that disintegrating agent is helped to can be one of sulphur ammonium, calcium chloride, salt, magnesium chloride, aluminium chloride, bentonite, urea
Or it is several.
The dispersing agent can be sodium lignin sulfonate, tea seed cake, Chinese honey locust, soapberry, double naphthalenesulfonate formaldehyde condensation compounds,
One or more of pull open powder AC, castor oil ethylene oxide and its derivative.
The adsorbent can be white carbon black, diatomite, concavo-convex rod soil, thenardite, non-avicel cellulose, plastics, second
One or more of olefine resin.
The lubricant can be lubricating oil or alkylphenol-polyethenoxy phosphate, amino acid, poly- alkyl glycol are advanced
Aliphatic ester, polyoxyalkyl ether, polyoxy alkhyl ethers, polyoxy alkyl alcohol phenyl ether, polyoxyalkyl ether sulfate, polyoxy alkyl
One of phenyl ether sulfate, polyoxy alkyl phenyl ether phosphate are appointed several.
The diluent can be one or more of heavy oil, kerosene, naphtha.
The colorant can be pigment scarlet powder, iron powder, chrome green, dark green, peacock green, carbon black, nigrosine, in crystal violet
One or more.
In practical applications, rule is actually occurred according to pest and disease damage, in addition to effective component fosthiazate, other can also be added
Mix preparation is made in pesticide activity component.In the present invention without limitation to addible pesticide activity component, but in prevention and treatment nematode
On, preferred nicotinoids pesticide.
The nicotinoids can are as follows: imidacloprid, thiacloprid, Acetamiprid, Nitenpyram, clothianidin, Diacloden, dinotefuran, furan
Pyridine amine, fluorine pyrrole furanone etc..
In the fosthiazate granule, the mass ratio of fosthiazate and other pesticide activity components can be 1:1-1:50.
In the present invention, the method for preparing fosthiazate granule is not particularly limited, by taking typical comminution granulation as an example,
After carrier crushes, fosthiazate sterling or industrial substance, stability ingredient C and adhesive are infiltrated into carrier surface, then pass through absorption
Agent is coated, this fosthiazate granule is obtained;Or preheat smashed carrier, it is added the adhesive of molten condition, then plus
Enter fosthiazate raw medicine and stability ingredient C, adds powdered adsorbent and fosthiazate granule of the present invention is made.
Application of the above-mentioned fosthiazate granule in prevention and treatment root-knot nematode, pratylenchus also belongs to protection model of the invention
It encloses.
The present invention is studied for environmental problem caused by target drug resistance, stability to degradation and fosthiazate, is provided
A kind of more stable process for producing granula is added nicotinic insecticide in concurrent fosthiazate now and not only shows well
Insecticidal effect, be substantially improved in the soil regime stability inferior of different condition, while reducing effective component amount of application, to work
Object and environment are safer.
Specific embodiment
The present invention will be described below by way of specific embodiments, but the present invention is not limited thereto.
Experimental method used in following embodiments is conventional method unless otherwise specified;Institute in following embodiments
Reagent, material etc., are commercially available unless otherwise specified.
Magnesia citrate can be by the way that commercially available magnesium oxide powder to be mixed to get with citric acid powder.
Following embodiments unless otherwise specified, each mean in Anyang vegetables institute greenhouse, soil pH 6.2-8.7 it
Between, cell is set as 1 × 1 meter, and using 1500 grams/acre of dosages, fosthiazate granule is spread fertilizer over the fields soil surface.It is adopted after fortnight
Cell soil acidity or alkalinity is measured with LTS-PHW type soil multi-parameter tacheometer (Hangzhou Lv Bo Instrument Ltd.).
Magnesia citrate as used in the following examples is that magnesia and citric acid are matched with what mass ratio 32:68 was formed
Close object.
Embodiment 1,
Fosthiazate 10%, magnesia citrate 3.5%, alditol 0.5%, silica 1 .6%, polyvinyl acetate 1%,
Sulphur ammonium 1%, pull open powder AC 2%, carclazyte 80.4% use the conventional method for preparing granule that active constituent content is made as 10%
Fosthiazate granule.For magnesia citrate under the conditions of soil moisture content is 85%, it is 6.3 that soil pH is measured after fortnight.
Embodiment 2,
Fosthiazate 15%, gum arabic 0.1%, polyvinyl acetate 1%, sulphur ammonium 1%, is drawn magnesia citrate 5%
Opening powder AC2%, carclazyte 75.9% uses the conventional method for preparing granule that active constituent content is made as 15% fosthiazate
Granula, under the conditions of soil moisture content is 85%, it is 5.9 that soil pH is measured after fortnight.
Embodiment 3,
Fosthiazate 10%, magnesia citrate 5%, alditol 0.3%, silica 1 .6%, polyvinyl acetate 1%, sulphur
Active constituent content is made using the conventional method for preparing granule in ammonium 1%, pull open powder AC2%, carclazyte 29.1%, nitrogenous fertilizer 50%
For 10% fosthiazate granule, under the conditions of soil moisture content is 85%, it is 6.2 that soil pH is measured after fortnight.
Comparative example 1,
According to the embodiment 3 announced in CN103039513A " a kind of fosthiazate granular formulation for killing nematode and preparation method thereof "
Mode:
A kind of fosthiazate granular formulation for killing nematode, with granule total weight, in which: fosthiazate 10%, carrier 50%, dispersion
Auxiliary agent 2%, sustained release agent 1%, bonding agent 3%, remaining is filler.The carrier is fertilizer.Fertilizer be ammonium chloride, ammonium sulfate,
Urea, potassium chloride, potassium sulfate, monoammonium phosphate mixture, N element content be granule total weight 15%, P element content
It is the 5% of granule total weight, K element content is the 5% of granule total weight.Dispersing aid is cornstarch, and sustained release agent is
Polyvinyl alcohol, binder are polyethylene glycol, and filler is the mixture of calcium bicarbonate and white kaolinic;
10% fosthiazate granule (number A) is made.
Commercially available 15% fosthiazate granule (Shanggezhilu Biosciences Co., Ltd., Shaanxi) (number B).
10% fosthiazate granule (number C) is made by (embodiment 2) of the invention.Soil is carried out to granule in above-mentioned 3
Earth spreads fertilizer over the fields test.It is as follows that P in soil H result is measured after fortnight:
Medicament | Dosage | Soil pH before testing | Soil pH after fortnight |
A | 2.25g/m2 | 7.1 | 7.4 |
B | 2.25g/m2 | 6.8 | 6.6 |
C | 2.25g/m2 | 7.8 | 5.8 |
Fosthiazate is mixed with nitrogenous fertilizer can be due to NH4 +Presence cause soil pH to rise, using thiazole prepared by the present invention
The effect that phosphine granule improves soil acidity or alkalinity is obvious.
Claims (10)
1. a kind of fosthiazate granule is made: effective component, stable elements C, carrier and auxiliary of the raw material for including following components
Raw material,
Wherein, the effective component is fosthiazate;
The stable elements C are as follows: the mixture of magnesia citrate and one or more of paraffin, alditol, sulphur ammonium.
2. fosthiazate granule according to claim 1, it is characterised in that: in the fosthiazate granule, each component
Mass percentage content are as follows: effective component 0.1-20%, stable elements C 0.1-10%, surplus are carrier and auxiliary material;
In the stable elements C, the mass ratio of magnesia citrate and one or more of paraffin, alditol, sulphur ammonium are as follows: 5:1-
2.5;
Magnesia citrate is the complex that magnesia and citric acid are formed with mass ratio 3:7-4:6.
3. fosthiazate granule according to claim 1 or 2, it is characterised in that: the carrier are as follows: silica, mica, cunning
One or more of stone, clay, kaolinite, calcium carbonate, carclazyte.
4. fosthiazate granule according to claim 1 or 2, it is characterised in that: the carrier is fertilizer;
The fertilizer are as follows: one or more of nitrogenous fertilizer, potash fertilizer, phosphate fertilizer, compound fertilizer, compound fertilizer, organic fertilizer, microorganism fertilizer.
5. fosthiazate granule according to claim 1, it is characterised in that: in the fosthiazate granule, effective component
In addition to fosthiazate, other pesticide activity components are also added.
6. fosthiazate granule according to claim 5, it is characterised in that: in the fosthiazate granule, effective component
In addition to fosthiazate, nicotinoids are also added.
7. fosthiazate granule according to claim 6, it is characterised in that: the nicotinoids are as follows: imidacloprid, thiacloprid,
One of Acetamiprid, Nitenpyram, clothianidin, Diacloden, dinotefuran, furan pyridine amine, fluorine pyrrole furanone are a variety of.
8. fosthiazate granule according to claim 5, it is characterised in that: in the fosthiazate granule, fosthiazate with
The mass ratio of other pesticide activity components is 1:1-1:50.
9. the method for preparing fosthiazate granule of any of claims 1-8, comprising: after crushing carrier, by thiophene
Azoles phosphine sterling or industrial substance and/or other pesticide activity components, stability ingredient C and adhesive infiltrate carrier surface, then lead to
It crosses adsorbent to be coated, obtains the fosthiazate granule;
Or preheat smashed carrier, the adhesive of molten condition is added, adds fosthiazate raw medicine and/or other pesticides is living
Property ingredient and stability ingredient C, add powdered adsorbent and the fosthiazate granule be made.
10. fosthiazate granule according to claim 1 to 8 answering in prevention and treatment root-knot nematode, pratylenchus
With.
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Citations (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1231117A (en) * | 1998-04-03 | 1999-10-13 | 日本拜耳农药株式会社 | Granular pesticide |
CN101591234A (en) * | 2008-05-26 | 2009-12-02 | 南通市飞宇精细化学品有限公司 | A kind of method of producing magnesium citrate |
CN102511495A (en) * | 2011-12-20 | 2012-06-27 | 海利尔药业集团股份有限公司 | Insecticidal composition for controlling underground insect |
CN102613173A (en) * | 2012-02-24 | 2012-08-01 | 石家庄市龙汇精细化工有限责任公司 | Granule agent for control of soil insects and preparation method thereof |
CN102771510A (en) * | 2012-07-31 | 2012-11-14 | 陕西上格之路生物科学有限公司 | Insecticidal composition containing fosthiazate |
CN102875246A (en) * | 2012-10-25 | 2013-01-16 | 联保作物科技有限公司 | Lythidathion-coated controlled release granule |
CN103039513A (en) * | 2012-12-27 | 2013-04-17 | 广东中迅农科股份有限公司 | Fosthiazate nematicide granules and preparation method thereof |
CN103875705A (en) * | 2014-03-20 | 2014-06-25 | 黄业新 | Pesticide granules containing pymetrozine and lythidathion |
CN104145988A (en) * | 2014-06-16 | 2014-11-19 | 山东华阳农药化工集团有限公司 | Lythidathion-containing insecticidal composition |
CN104672029A (en) * | 2015-01-14 | 2015-06-03 | 广西欧维生物技术有限公司 | Pesticide fertilizer containing lythidathion |
CN105557750A (en) * | 2015-12-20 | 2016-05-11 | 广东中迅农科股份有限公司 | Sustained-release granules for prevention and control of nematodes |
CN106187413A (en) * | 2016-06-30 | 2016-12-07 | 佛山市盈辉作物科学有限公司 | Medicine containing fosthiazate and clothianidin is fertile and preparation method thereof |
CN106259428A (en) * | 2016-08-23 | 2017-01-04 | 佛山市盈辉作物科学有限公司 | A kind of nematicidal composition containing fosthiazate |
-
2018
- 2018-12-26 CN CN201811599491.0A patent/CN109392948A/en active Pending
Patent Citations (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1231117A (en) * | 1998-04-03 | 1999-10-13 | 日本拜耳农药株式会社 | Granular pesticide |
CN101591234A (en) * | 2008-05-26 | 2009-12-02 | 南通市飞宇精细化学品有限公司 | A kind of method of producing magnesium citrate |
CN102511495A (en) * | 2011-12-20 | 2012-06-27 | 海利尔药业集团股份有限公司 | Insecticidal composition for controlling underground insect |
CN102613173A (en) * | 2012-02-24 | 2012-08-01 | 石家庄市龙汇精细化工有限责任公司 | Granule agent for control of soil insects and preparation method thereof |
CN102771510A (en) * | 2012-07-31 | 2012-11-14 | 陕西上格之路生物科学有限公司 | Insecticidal composition containing fosthiazate |
CN102875246A (en) * | 2012-10-25 | 2013-01-16 | 联保作物科技有限公司 | Lythidathion-coated controlled release granule |
CN103039513A (en) * | 2012-12-27 | 2013-04-17 | 广东中迅农科股份有限公司 | Fosthiazate nematicide granules and preparation method thereof |
CN103875705A (en) * | 2014-03-20 | 2014-06-25 | 黄业新 | Pesticide granules containing pymetrozine and lythidathion |
CN104145988A (en) * | 2014-06-16 | 2014-11-19 | 山东华阳农药化工集团有限公司 | Lythidathion-containing insecticidal composition |
CN104672029A (en) * | 2015-01-14 | 2015-06-03 | 广西欧维生物技术有限公司 | Pesticide fertilizer containing lythidathion |
CN105557750A (en) * | 2015-12-20 | 2016-05-11 | 广东中迅农科股份有限公司 | Sustained-release granules for prevention and control of nematodes |
CN106187413A (en) * | 2016-06-30 | 2016-12-07 | 佛山市盈辉作物科学有限公司 | Medicine containing fosthiazate and clothianidin is fertile and preparation method thereof |
CN106259428A (en) * | 2016-08-23 | 2017-01-04 | 佛山市盈辉作物科学有限公司 | A kind of nematicidal composition containing fosthiazate |
Non-Patent Citations (1)
Title |
---|
王建玲等: "《普通化学》", 31 August 2018, 中国农业大学出版社 * |
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