CN109385917A - Black composite dye mill base of a kind of high staining power dispersion and preparation method thereof - Google Patents

Black composite dye mill base of a kind of high staining power dispersion and preparation method thereof Download PDF

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Publication number
CN109385917A
CN109385917A CN201811283793.7A CN201811283793A CN109385917A CN 109385917 A CN109385917 A CN 109385917A CN 201811283793 A CN201811283793 A CN 201811283793A CN 109385917 A CN109385917 A CN 109385917A
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added
agent
mill base
chitosan
composite dye
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刘玉梅
蒋佗贤
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
    • C08B37/00—Preparation of polysaccharides not provided for in groups C08B1/00 - C08B35/00; Derivatives thereof
    • C08B37/0006—Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid
    • C08B37/0024—Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid beta-D-Glucans; (beta-1,3)-D-Glucans, e.g. paramylon, coriolan, sclerotan, pachyman, callose, scleroglucan, schizophyllan, laminaran, lentinan or curdlan; (beta-1,6)-D-Glucans, e.g. pustulan; (beta-1,4)-D-Glucans; (beta-1,3)(beta-1,4)-D-Glucans, e.g. lichenan; Derivatives thereof
    • C08B37/0027—2-Acetamido-2-deoxy-beta-glucans; Derivatives thereof
    • C08B37/003—Chitin, i.e. 2-acetamido-2-deoxy-(beta-1,4)-D-glucan or N-acetyl-beta-1,4-D-glucosamine; Chitosan, i.e. deacetylated product of chitin or (beta-1,4)-D-glucosamine; Derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/653—Nitrogen-free carboxylic acids or their salts
    • D06P1/6533—Aliphatic, araliphatic or cycloaliphatic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673—Inorganic compounds
    • D06P1/67333—Salts or hydroxides
    • D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673—Inorganic compounds
    • D06P1/67383—Inorganic compounds containing silicon

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • Molecular Biology (AREA)
  • General Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Cosmetics (AREA)
  • Coloring (AREA)

Abstract

The application provides black composite dye mill base of a kind of high staining power dispersion and preparation method thereof, belongs to the preparation technical field of disperse dyes.It also include bleeding agent, levelling agent and migration inhibitor comprising dispersed black dye, reserve salt, water-soluble nonionic surfactant, nonionic thickener, oil-soluble nonionic surface active agent, ethyl alcohol, starch, vinyl acetate, acrylic acid, emulsifier, urea, preservative, dispersing agent, glacial acetic acid, chitosan.The application is dispersed into the black dye paste that meets and is applied to dyeing, has many advantages, such as that good stability, modest viscosity, transferring rate are high, washing fastness is good, power part is high.

Description

Black composite dye mill base of a kind of high staining power dispersion and preparation method thereof
Technical field
This application involves a kind of high staining powers to disperse black composite dye mill base and preparation method thereof, belongs to disperse dyes Preparation technical field.
Background technique
Disperse dyes have the characteristics that complete, bright in colour, the every fastness of chromatography is higher and is not easily decomposed, thus extensive Dyeing and stamp for synthetic fibers such as terylene, polyamide fibre, acetate fibers.At present in country's dyeing, for washing and chemical fibre Stamp to colour general be water dyeing method, and traditional disperse dyes be it is granular, partial size exists many more than micron Drawback: 1. need high temperature to steam Hua Fase, waste a large amount of steam energies；2. dye utilization rate is in 65%-70%, there are dyestuff utilizations The defect that rate is low, loose colour is big；3. since partial size is larger, although can be dispersed in water the short time, the time, which has been grown, to be precipitated, and And traditional disperse dyes need repeatedly washing, waste water resource to be easy to produce sewage, need to handle in dispersion process, waste money Source.
Especially since the major way of printed polyester is direct printing, pigment printing, thermal transfer printing, and directly print Flower is the most important mode of current stamp, and which is that commercial dyes, thickener and additive are prepared into certain viscosity Print paste, then carry out stamp, drying, decatize and multiple tracks washing conventional machining techniques；With high viscosity, low solid content The development of synthetic thickening agent, although can be reduced the dosage of synthetic thickening agent in print paste in dyeing, because of existing disperse dyes It is poor with the compatibility of synthetic thickening agent, for obtain certain viscosity print paste, it is still necessary to configure high solids content (such as 5~ 6%) synthetic thickening agent print paste, to prevent the decline of stamp dielectric viscosity.And synthetic thickening agent dosage in print paste Increase, cause direct printing dye utilization rate low, PRINTED FABRIC could remove fabric table there is still a need for road washing after a large amount of The loose colour in face, to meet the purpose for improving terylene printing product color fastness, obtaining soft feel.
Therefore how to realize that environmentally friendly Non-water washing and the dyestuff evaporated are very promising.Meanwhile some applications of dyestuff Performance has been to be concerned by more and more people, such as: vividness, crock fastness, light fastness, washing fastness, fastness to sublimation etc., The disperse dyes for how preparing to obtain fine processing are crucial.
Summary of the invention
In view of this, the application provides a kind of high staining power dispersion black composite dye mill base first, composite dye tool There is very high staining power, and without washing, it can be achieved that the purpose of energy conservation and environmental protection emission reduction.
Specifically, the application is achieved through the following technical solutions above-mentioned purpose:
A kind of black composite dye mill base of high staining power dispersion, dispersed black dye 10~40%, sepiolite powder 10~ 15%, dispersing agent 8~10%, ethyl alcohol 7~9%, oil-soluble nonionic surface active agent 5~8%, guar gum 5~8%, Water-soluble nonionic surfactant 4~7%, aluminum aluminum sulfate 4~6%, acrylic acid 4~6%, glacial acetic acid 2.6~4.5%, Nonionic thickener 2~3%, chitosan 2~3%, emulsifier 1.5~2.2%, preservative 0.3~0.8%, reserve salt 0.8 ~1%；Dyeing capacity part of composite dye mill base is 200-500%.
In the above scheme, using dispersed black dye as principal component, water-soluble nonionic surfactant and oil is added Dissolubility nonionic surface active agent, gained composite dye stability of pigment paste is good, modest viscosity, can be dispersed in water for a long time, It will not precipitate, be not required to by washing, and transferring rate is high, washing fastness is good, and (also referred to as dye strength refers to sample to dyeing capacity part Opposite tinctorial strength of the dyestuff compared with standard dyes dye level) it can reach 200~500%.
To realize that more using effects, above scheme can also add as follows:
It further include having bleeding agent, levelling agent and migration inhibitor, and bleeding agent content in composite dye mill base is 1~3g/ L, 2~4g/L of levelling agent, 4~5g/L of migration inhibitor.
The water-soluble nonionic surfactant is selected from fatty alcohol polyoxyethylene ether, alkyl phenol polyoxyethylene ether, rouge One of fat acid polyoxyethylene ester is a variety of.
The nonionic thickener be selected from polyethylene glycol, polyether nonionic surfactant, polyvinylpyrrolidone, One of polyvinyl alcohol is a variety of.
The oil-soluble nonionic surface active agent is selected from fatty alcohol polyoxyethylene ether, alkyl phenol polyoxyethylene ether, rouge It is fat acid polyoxyethylene ester, sorbitan fatty acid ester, one or more in fatty glyceride.
The dispersing agent is lignosulfonate, naphthalenesulfonic acid-formaldehyde condensate, one in benzyl naphthalene sulfonic acid-formaldehyde condensation product Kind is a variety of.It is furthermore preferred that the average molecular weight of the lignosulfonate dispersing agent is 10000~15000, sulfonation degree is 0.8 ~1.5；Alternatively, the dispersing agent is the mixture of lignosulfonate and naphthalenesulfonic acid-formaldehyde condensate, and the two mass ratio is 3 ~5:1.
The emulsifier is the compound emulsifying agent of lauryl sodium sulfate and triethanolamine, and the two mass ratio is 2:2~3.
Present invention also provides the preparation methods of the black composite dye mill base of above-mentioned dispersion simultaneously comprising the steps of:
(1) reaction vessel is added water to, is added guar gum while stirring, under stirring condition, keeps guar gum sufficiently molten Sepiolite powder is added in Xie Hou, and stirring is added dropwise emulsifier, is creamy white to entire reaction system, adds acrylic acid, heats up 30~45min is kept the temperature after to 76 DEG C -85 DEG C, then cools to 42~46 DEG C, glacial acetic acid is added, and adjusting pH value is 6-7, room to be down to Temperature obtains material A；
(2) nonionic thickener, aluminum aluminum sulfate and ethyl alcohol are mixed, stirs evenly to obtain material B；
(3) dispersing agent and dispersed black dye are uniformly mixed, water-soluble nonionic surfactant and oil is then added After being ground to 50-700nm, material A and chitosan is added (when containing bleeding agent in component in dissolubility nonionic surface active agent When, bleeding agent is added at this time), material C is obtained after mixing evenly；
(4) material B is added in material C, then is ground to 50-700nm, reserve salt is added and preservative (contains in such as ingredient Have levelling agent, migration inhibitor, then levelling agent, migration inhibitor are added at this time), then it is ground to 50-700nm to obtain the final product.
Wherein, in above-mentioned operation, the chitosan is processed through following methods: it adds chitosan into acetic acid solution, Stirring extremely forms homogeneous phase solution；Maleic anhydride is dissolved in acetone, is then added in the homogeneous phase solution, wherein maleic anhydride matter Amount is the 2.5~4% of chitosan mass；It is purified after 9~10h of reaction is stirred at room temperature to obtain the final product.
The dispersing agent and the black composite dye mill base of dispersion of the application is uniformly mixed, and water-soluble nonionic surface-active is added Agent and oil-soluble nonionic surface active agent be ground to 50-700nm, and gained composite dye stability of pigment paste is good, viscosity It is moderate, it can be dispersed in water, will not precipitate for a long time, be not required to that there is the transmitting of good dyestuff by washing, energy conservation and environmental protection emission reduction Property and permeability, and transferring rate is high, and washing fastness is good.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, with reference to embodiments, to the present invention It is further elaborated.Additional aspect and advantage of the invention will be set forth in part in the description, partially will be under Become obvious in the description in face, or practice through the invention is recognized.It is only used to explain this hair it should be appreciated that being described below It is bright, it is not intended to limit the present invention.
Term "comprising" used herein, " comprising ", " having ", " containing " or its any other deformation, it is intended that covering Non-exclusionism includes.For example, composition, step, method, product or device comprising listed elements are not necessarily limited to those and want Element, but may include not expressly listed other elements or such composition, step, method, product or device it is intrinsic Element.
Conjunction " Consists of " excludes any element that do not point out, step or component.If in claim, this Phrase will make claim closed, so that it is not included the material in addition to the material of those descriptions, but relative normal Except rule impurity.When being rather than immediately following after theme in the clause that phrase " Consists of " appears in claim main body, It is only limited to element described in the clause；Other elements are not excluded except the claim as a whole.
Equivalent, concentration or other values or parameter are excellent with range, preferred scope or a series of upper limit preferred values and lower limit When the Range Representation that choosing value limits, this should be understood as specifically disclosing by any range limit or preferred value and any range Any pairing of lower limit or preferred value is formed by all ranges, regardless of whether the range separately discloses.For example, when open When range " 1 to 5 ", described range should be interpreted as including range " 1 to 4 ", " 1 to 3 ", " 1 to 2 ", " 1 to 2 and 4 to 5 ", " 1 to 3 and 5 " etc..When numberical range is described herein, unless otherwise stated, otherwise the range is intended to include its end Value and all integers and score in the range.
Singular includes that plural number discusses object, unless the context clearly dictates otherwise." optional " or it is " any It is a kind of " refer to that the item described thereafter or event may or may not occur, and the description include situation that event occurs and The situation that event does not occur.
Indefinite article "an" before element or component of the present invention (goes out the quantitative requirement of element or component with "one" Occurrence number) unrestriction.Therefore "one" or "an" should be read as including one or at least one, and singular Element or component also include plural form, unless the quantity obviously only refers to singular.
Unless otherwise noted, water-soluble nonionic surfactant described herein is selected from aliphatic alcohol polyethenoxy One of ether, alkyl phenol polyoxyethylene ether, polyoxyethylene carboxylate are a variety of；The nonionic thickener is selected from poly- second One of glycol, polyether nonionic surfactant, polyvinylpyrrolidone, polyvinyl alcohol are a variety of；The oil-soluble Nonionic surface active agent is selected from fatty alcohol polyoxyethylene ether, alkyl phenol polyoxyethylene ether, polyoxyethylene carboxylate, dehydration It is one or more in Span, fatty glyceride；The dispersing agent is lignosulfonate, naphthalene sulfonate formaldehyde contracting One of object, benzyl naphthalene sulfonic acid-formaldehyde condensation product or a variety of are closed, and the average molecular weight of lignosulfonate dispersing agent is 10000 ~15000, for sulfonation degree 0.8~1.5, the dispersing agent is the mixture of lignosulfonate and naphthalenesulfonic acid-formaldehyde condensate, And the two mass ratio is 3~5:1；The emulsifier is the compound emulsifying agent of lauryl sodium sulfate and triethanolamine, the two matter Amount is than being 2:2~3.The preparation method for dispersing black composite dye mill base comprises the steps of:
(1) reaction vessel is added water to, is added guar gum while stirring, under stirring condition, keeps guar gum sufficiently molten Sepiolite powder is added in Xie Hou, and stirring is added dropwise emulsifier, is creamy white to entire reaction system, adds acrylic acid, heats up 30~45min is kept the temperature after to 76 DEG C -85 DEG C, then cools to 42~46 DEG C, glacial acetic acid is added, and adjusting pH value is 6-7, room to be down to Temperature obtains material A；
(2) nonionic thickener, aluminum aluminum sulfate and ethyl alcohol are mixed, stirs evenly to obtain material B；
(3) dispersing agent and dispersed black dye are uniformly mixed, water-soluble nonionic surfactant and oil is then added After being ground to 50-700nm, material A and chitosan is added (when containing bleeding agent in component in dissolubility nonionic surface active agent When, bleeding agent is added at this time), material C is obtained after mixing evenly；
(4) material B is added in material C, then is ground to 50-700nm, reserve salt is added and preservative (contains in such as ingredient Have levelling agent, migration inhibitor, then levelling agent, migration inhibitor are added at this time), then it is ground to 50-700nm to obtain the final product.
The chitosan is processed through following methods: adding chitosan into acetic acid solution, stirring to formation mixes Liquid；Maleic anhydride is dissolved in acetone, is then added in the homogeneous phase solution, wherein maleic anhydride quality is chitosan mass 2.5~4%；It is purified after 9~10h of reaction is stirred at room temperature to obtain the final product.
Moreover, technical characteristic involved in each embodiment of the application as long as they do not conflict with each other can To be combined with each other.
Embodiment 1
Take following raw material for standby: dispersed black dye 20%, sepiolite powder 12%, dispersing agent 10%, ethyl alcohol 9%, oil are molten Property nonionic surface active agent 8%, guar gum 8%, water-soluble nonionic surfactant 7%, aluminum aluminum sulfate 6%, Acrylic acid 6%, nonionic thickener 3%, chitosan 3%, emulsifier 2.2%, preservative 0.5%, is prevented glacial acetic acid 4.5% Salt 0.8% is contaminated, the dispersed black dye mill base of said components is high-intensitive disperse dyes, and power part is 200~500%.
As needed, bleeding agent, levelling agent and migration inhibitor can also be added in the black composite dye mill base of above-mentioned dispersion, And bleeding agent content in mill base is 2g/L, levelling agent 3g/L, migration inhibitor 4.5g/L, and appropriate adjustment dispersing agent adds Dosage.
It is prepared as follows the black composite dye mill base of dispersion:
(1) reaction vessel is added water to, is added guar gum while stirring, under stirring condition, keeps guar gum sufficiently molten Sepiolite powder is added in Xie Hou, and stirring is added dropwise emulsifier, is creamy white to entire reaction system, adds acrylic acid, heats up 30~45min is kept the temperature after to 76 DEG C -85 DEG C, then cools to 42~46 DEG C, glacial acetic acid is added, and adjusting pH value is 6-7, room to be down to Temperature obtains material A；
(2) nonionic thickener, aluminum aluminum sulfate and ethyl alcohol are mixed, stirs evenly to obtain material B；
(3) dispersing agent and dispersed black dye are uniformly mixed, water-soluble nonionic surfactant and oil is then added After being ground to 50-700nm, material A and chitosan is added (when containing bleeding agent in component in dissolubility nonionic surface active agent When, bleeding agent is added at this time), material C is obtained after mixing evenly；
(4) material B is added in material C, then is ground to 50-700nm, reserve salt is added and preservative (contains in such as ingredient Have levelling agent, migration inhibitor, then levelling agent, migration inhibitor are added at this time), then it is ground to 50-700nm to obtain the final product.
Wherein, the chitosan is processed through following methods: adding chitosan into acetic acid solution, stirring is equal to being formed Phase solution；Maleic anhydride is dissolved in acetone, is then added in the homogeneous phase solution, wherein maleic anhydride quality is chitosan matter The 3% of amount；It is purified after reaction 9h is stirred at room temperature to obtain the final product.
Embodiment 2
Take following raw material for standby: dispersed black dye 25%, sepiolite powder 12%, dispersing agent 8%, ethyl alcohol 7%, oil-soluble Nonionic surface active agent 7%, guar gum 8%, water-soluble nonionic surfactant 7%, aluminum aluminum sulfate 6%, third Olefin(e) acid 6%, glacial acetic acid 4.5%, nonionic thickener 3%, chitosan 3%, emulsifier 2.2%, preservative 0.5%, resist printing Salt 0.8%, the dispersed black dye mill base of said components are high-intensitive disperse dyes, and power part is 200~500%.
As needed, bleeding agent, levelling agent and migration inhibitor can also be added in the black composite dye mill base of above-mentioned dispersion, And bleeding agent content in mill base is 1g/L, levelling agent 2g/L, migration inhibitor 5g/L, and the addition of appropriate adjustment dispersing agent Amount.
It is prepared as follows the black composite dye mill base of dispersion:
(1) reaction vessel is added water to, is added guar gum while stirring, under stirring condition, keeps guar gum sufficiently molten Sepiolite powder is added in Xie Hou, and stirring is added dropwise emulsifier, is creamy white to entire reaction system, adds acrylic acid, heats up 30~45min is kept the temperature after to 76 DEG C -85 DEG C, then cools to 42~46 DEG C, glacial acetic acid is added, and adjusting pH value is 6-7, room to be down to Temperature obtains material A；
(2) nonionic thickener, aluminum aluminum sulfate and ethyl alcohol are mixed, stirs evenly to obtain material B；
(3) dispersing agent and dispersed black dye are uniformly mixed, water-soluble nonionic surfactant and oil is then added After being ground to 50-700nm, material A and chitosan is added (when containing bleeding agent in component in dissolubility nonionic surface active agent When, bleeding agent is added at this time), material C is obtained after mixing evenly；
(4) material B is added in material C, then is ground to 50-700nm, reserve salt is added and preservative (contains in such as ingredient Have levelling agent, migration inhibitor, then levelling agent, migration inhibitor are added at this time), then it is ground to 50-700nm to obtain the final product.
Wherein, the chitosan is processed through following methods: adding chitosan into acetic acid solution, stirring is equal to being formed Phase solution；Maleic anhydride is dissolved in acetone, is then added in the homogeneous phase solution, wherein maleic anhydride quality is chitosan matter The 3% of amount；It is purified after reaction 9h is stirred at room temperature to obtain the final product.
Embodiment 3
Take following raw material for standby: dispersed black dye 28%, sepiolite powder 10%, dispersing agent 8%, ethyl alcohol 7%, oil-soluble Nonionic surface active agent 6%, guar gum 8%, water-soluble nonionic surfactant 7%, aluminum aluminum sulfate 6%, third Olefin(e) acid 6%, glacial acetic acid 4.5%, nonionic thickener 3%, chitosan 3%, emulsifier 2.2%, preservative 0.5%, resist printing Salt 0.8%, the dispersed black dye mill base of said components are high-intensitive disperse dyes, and power part is 200~500%.
As needed, bleeding agent, levelling agent and migration inhibitor can also be added in the black composite dye mill base of above-mentioned dispersion, And bleeding agent content in mill base is 2g/L, levelling agent 3g/L, migration inhibitor 4.5g/L, and appropriate adjustment dispersing agent adds Dosage.
It is prepared as follows the black composite dye mill base of dispersion:
(1) reaction vessel is added water to, is added guar gum while stirring, under stirring condition, keeps guar gum sufficiently molten Sepiolite powder is added in Xie Hou, and stirring is added dropwise emulsifier, is creamy white to entire reaction system, adds acrylic acid, heats up 30~45min is kept the temperature after to 76 DEG C -85 DEG C, then cools to 42~46 DEG C, glacial acetic acid is added, and adjusting pH value is 6-7, room to be down to Temperature obtains material A；
(2) nonionic thickener, aluminum aluminum sulfate and ethyl alcohol are mixed, stirs evenly to obtain material B；
(3) dispersing agent and dispersed black dye are uniformly mixed, water-soluble nonionic surfactant and oil is then added After being ground to 50-700nm, material A and chitosan is added (when containing bleeding agent in component in dissolubility nonionic surface active agent When, bleeding agent is added at this time), material C is obtained after mixing evenly；
(4) material B is added in material C, then is ground to 50-700nm, reserve salt is added and preservative (contains in such as ingredient Have levelling agent, migration inhibitor, then levelling agent, migration inhibitor are added at this time), then it is ground to 50-700nm to obtain the final product.
Wherein, the chitosan is processed through following methods: adding chitosan into acetic acid solution, stirring is equal to being formed Phase solution；Maleic anhydride is dissolved in acetone, is then added in the homogeneous phase solution, wherein maleic anhydride quality is chitosan matter The 3% of amount；It is purified after reaction 9h is stirred at room temperature to obtain the final product.
Embodiment 4
Take following raw material for standby: dispersed black dye 30%, sepiolite powder 12%, dispersing agent 8%, ethyl alcohol 7%, oil-soluble Nonionic surface active agent 5%, guar gum 5%, water-soluble nonionic surfactant 7%, aluminum aluminum sulfate 6%, third Olefin(e) acid 6%, glacial acetic acid 4.5%, nonionic thickener 3%, chitosan 3%, emulsifier 2.2%, preservative 0.5%, resist printing Salt 0.8%, the dispersed black dye mill base of said components are high-intensitive disperse dyes, and power part is 200~500%.
As needed, bleeding agent, levelling agent and migration inhibitor can also be added in the black composite dye mill base of above-mentioned dispersion, And bleeding agent content in mill base is 3g/L, levelling agent 4g/L, migration inhibitor 4g/L, and the addition of appropriate adjustment dispersing agent Amount.
It is prepared as follows the black composite dye mill base of dispersion:
(1) reaction vessel is added water to, is added guar gum while stirring, under stirring condition, keeps guar gum sufficiently molten Sepiolite powder is added in Xie Hou, and stirring is added dropwise emulsifier, is creamy white to entire reaction system, adds acrylic acid, heats up 30~45min is kept the temperature after to 76 DEG C -85 DEG C, then cools to 42~46 DEG C, glacial acetic acid is added, and adjusting pH value is 6-7, room to be down to Temperature obtains material A；
(2) nonionic thickener, aluminum aluminum sulfate and ethyl alcohol are mixed, stirs evenly to obtain material B；
(3) dispersing agent and dispersed black dye are uniformly mixed, water-soluble nonionic surfactant and oil is then added After being ground to 50-700nm, material A and chitosan is added (when containing bleeding agent in component in dissolubility nonionic surface active agent When, bleeding agent is added at this time), material C is obtained after mixing evenly；
(4) material B is added in material C, then is ground to 50-700nm, reserve salt is added and preservative (contains in such as ingredient Have levelling agent, migration inhibitor, then levelling agent, migration inhibitor are added at this time), then it is ground to 50-700nm to obtain the final product.
Wherein, the chitosan is processed through following methods: adding chitosan into acetic acid solution, stirring is equal to being formed Phase solution；Maleic anhydride is dissolved in acetone, is then added in the homogeneous phase solution, wherein maleic anhydride quality is chitosan matter The 3% of amount；It is purified after reaction 9h is stirred at room temperature to obtain the final product.
Embodiment 5
Take following raw material for standby: dispersed black dye 33%, sepiolite powder 10%, dispersing agent 8%, ethyl alcohol 8%, oil-soluble Nonionic surface active agent 6%, guar gum 5%, water-soluble nonionic surfactant 4%, aluminum aluminum sulfate 6%, third Olefin(e) acid 6%, glacial acetic acid 4.5%, nonionic thickener 3%, chitosan 3%, emulsifier 2.2%, preservative 0.5%, resist printing Salt 0.8%, the dispersed black dye mill base of said components are high-intensitive disperse dyes, and power part is 200~500%.
As needed, bleeding agent, levelling agent and migration inhibitor can also be added in the black composite dye mill base of above-mentioned dispersion, And bleeding agent content in mill base is 2g/L, levelling agent 3g/L, migration inhibitor 4.5g/L, and appropriate adjustment dispersing agent adds Dosage.
It is prepared as follows the black composite dye mill base of dispersion:
(1) reaction vessel is added water to, is added guar gum while stirring, under stirring condition, keeps guar gum sufficiently molten Sepiolite powder is added in Xie Hou, and stirring is added dropwise emulsifier, is creamy white to entire reaction system, adds acrylic acid, heats up 30~45min is kept the temperature after to 76 DEG C -85 DEG C, then cools to 42~46 DEG C, glacial acetic acid is added, and adjusting pH value is 6-7, room to be down to Temperature obtains material A；
(2) nonionic thickener, aluminum aluminum sulfate and ethyl alcohol are mixed, stirs evenly to obtain material B；
(3) dispersing agent and dispersed black dye are uniformly mixed, water-soluble nonionic surfactant and oil is then added After being ground to 50-700nm, material A and chitosan is added (when containing bleeding agent in component in dissolubility nonionic surface active agent When, bleeding agent is added at this time), material C is obtained after mixing evenly；
(4) material B is added in material C, then is ground to 50-700nm, reserve salt is added and preservative (contains in such as ingredient Have levelling agent, migration inhibitor, then levelling agent, migration inhibitor are added at this time), then it is ground to 50-700nm to obtain the final product.
Wherein, the chitosan is processed through following methods: adding chitosan into acetic acid solution, stirring is equal to being formed Phase solution；Maleic anhydride is dissolved in acetone, is then added in the homogeneous phase solution, wherein maleic anhydride quality is chitosan matter The 3% of amount；It is purified after reaction 9h is stirred at room temperature to obtain the final product.
Embodiment 6
Take following raw material for standby: dispersed black dye 35%, sepiolite powder 12%, dispersing agent 8%, ethyl alcohol 7%, oil-soluble Nonionic surface active agent 5%, guar gum 5%, water-soluble nonionic surfactant 4%, aluminum aluminum sulfate 4%, third Olefin(e) acid 6%, glacial acetic acid 4.5%, nonionic thickener 3%, chitosan 3%, emulsifier 2.2%, preservative 0.5%, resist printing Salt 0.8%, the dispersed black dye mill base of said components are high-intensitive disperse dyes, and power part is 200~500%.
As needed, bleeding agent, levelling agent and migration inhibitor can also be added in the black composite dye mill base of above-mentioned dispersion, And bleeding agent content in mill base is 2g/L, levelling agent 3g/L, migration inhibitor 4.5g/L, and appropriate adjustment dispersing agent adds Dosage.
It is prepared as follows the black composite dye mill base of dispersion:
(1) reaction vessel is added water to, is added guar gum while stirring, under stirring condition, keeps guar gum sufficiently molten Sepiolite powder is added in Xie Hou, and stirring is added dropwise emulsifier, is creamy white to entire reaction system, adds acrylic acid, heats up 30~45min is kept the temperature after to 76 DEG C -85 DEG C, then cools to 42~46 DEG C, glacial acetic acid is added, and adjusting pH value is 6-7, room to be down to Temperature obtains material A；
(2) nonionic thickener, aluminum aluminum sulfate and ethyl alcohol are mixed, stirs evenly to obtain material B；
(3) dispersing agent and dispersed black dye are uniformly mixed, water-soluble nonionic surfactant and oil is then added After being ground to 50-700nm, material A and chitosan is added (when containing bleeding agent in component in dissolubility nonionic surface active agent When, bleeding agent is added at this time), material C is obtained after mixing evenly；
(4) material B is added in material C, then is ground to 50-700nm, reserve salt is added and preservative (contains in such as ingredient Have levelling agent, migration inhibitor, then levelling agent, migration inhibitor are added at this time), then it is ground to 50-700nm to obtain the final product.
Wherein, the chitosan is processed through following methods: adding chitosan into acetic acid solution, stirring is equal to being formed Phase solution；Maleic anhydride is dissolved in acetone, is then added in the homogeneous phase solution, wherein maleic anhydride quality is chitosan matter The 3% of amount；It is purified after reaction 9h is stirred at room temperature to obtain the final product.
Embodiment 7
Take following raw material for standby: dispersed black dye 38%, sepiolite powder 10%, dispersing agent 8%, ethyl alcohol 7%, oil-soluble Nonionic surface active agent 5%, guar gum 5%, water-soluble nonionic surfactant 4%, aluminum aluminum sulfate 4%, third Olefin(e) acid 5%, glacial acetic acid 4.5%, nonionic thickener 3%, chitosan 3%, emulsifier 2.2%, preservative 0.5%, resist printing Salt 0.8%, the dispersed black dye mill base of said components are high-intensitive disperse dyes, and power part is 200~500%.
As needed, bleeding agent, levelling agent and migration inhibitor can also be added in the black composite dye mill base of above-mentioned dispersion, And bleeding agent content in mill base is 2.5g/L, levelling agent 3.5g/L, migration inhibitor 4g/L, and appropriate adjustment dispersing agent Additive amount.
It is prepared as follows the black composite dye mill base of dispersion:
(1) reaction vessel is added water to, is added guar gum while stirring, under stirring condition, keeps guar gum sufficiently molten Sepiolite powder is added in Xie Hou, and stirring is added dropwise emulsifier, is creamy white to entire reaction system, adds acrylic acid, heats up 30~45min is kept the temperature after to 76 DEG C -85 DEG C, then cools to 42~46 DEG C, glacial acetic acid is added, and adjusting pH value is 6-7, room to be down to Temperature obtains material A；
(2) nonionic thickener, aluminum aluminum sulfate and ethyl alcohol are mixed, stirs evenly to obtain material B；
(3) dispersing agent and dispersed black dye are uniformly mixed, water-soluble nonionic surfactant and oil is then added After being ground to 50-700nm, material A and chitosan is added (when containing bleeding agent in component in dissolubility nonionic surface active agent When, bleeding agent is added at this time), material C is obtained after mixing evenly；
(4) material B is added in material C, then is ground to 50-700nm, reserve salt is added and preservative (contains in such as ingredient Have levelling agent, migration inhibitor, then levelling agent, migration inhibitor are added at this time), then it is ground to 50-700nm to obtain the final product.
Wherein, the chitosan is processed through following methods: adding chitosan into acetic acid solution, stirring is equal to being formed Phase solution；Maleic anhydride is dissolved in acetone, is then added in the homogeneous phase solution, wherein maleic anhydride quality is chitosan matter The 3% of amount；It is purified after reaction 9h is stirred at room temperature to obtain the final product.
Embodiment 8
Take following raw material for standby: dispersed black dye 40%, sepiolite powder 10%, dispersing agent 8%, ethyl alcohol 7%, oil-soluble Nonionic surface active agent 5%, guar gum 5%, water-soluble nonionic surfactant 4%, aluminum aluminum sulfate 4%, third Olefin(e) acid 4%, glacial acetic acid 3%, nonionic thickener 3%, chitosan 3%, emulsifier 2.2%, preservative 0.8%, reserve salt 1%, the dispersed black dye mill base of said components is high-intensitive disperse dyes, and power part is 200~500%.
As needed, bleeding agent, levelling agent and migration inhibitor can also be added in the black composite dye mill base of above-mentioned dispersion, And bleeding agent content in mill base is 2g/L, levelling agent 3g/L, migration inhibitor 4.5g/L, and appropriate adjustment dispersing agent adds Dosage.
It is prepared as follows the black composite dye mill base of dispersion:
(1) reaction vessel is added water to, is added guar gum while stirring, under stirring condition, keeps guar gum sufficiently molten Sepiolite powder is added in Xie Hou, and stirring is added dropwise emulsifier, is creamy white to entire reaction system, adds acrylic acid, heats up 30~45min is kept the temperature after to 76 DEG C -85 DEG C, then cools to 42~46 DEG C, glacial acetic acid is added, and adjusting pH value is 6-7, room to be down to Temperature obtains material A；
(2) nonionic thickener, aluminum aluminum sulfate and ethyl alcohol are mixed, stirs evenly to obtain material B；
(3) dispersing agent and dispersed black dye are uniformly mixed, water-soluble nonionic surfactant and oil is then added After being ground to 50-700nm, material A and chitosan is added (when containing bleeding agent in component in dissolubility nonionic surface active agent When, bleeding agent is added at this time), material C is obtained after mixing evenly；
(4) material B is added in material C, then is ground to 50-700nm, reserve salt is added and preservative (contains in such as ingredient Have levelling agent, migration inhibitor, then levelling agent, migration inhibitor are added at this time), then it is ground to 50-700nm to obtain the final product.
Wherein, the chitosan is processed through following methods: adding chitosan into acetic acid solution, stirring is equal to being formed Phase solution；Maleic anhydride is dissolved in acetone, is then added in the homogeneous phase solution, wherein maleic anhydride quality is chitosan matter The 3% of amount；It is purified after reaction 9h is stirred at room temperature to obtain the final product.
Embodiment 9
Take following raw material for standby: dispersed black dye 25%, sepiolite powder 12%, dispersing agent 9%, ethyl alcohol 7%, oil-soluble Nonionic surface active agent 6%, guar gum 8%, water-soluble nonionic surfactant 7%, aluminum aluminum sulfate 6%, third Olefin(e) acid 6%, glacial acetic acid 4.5%, nonionic thickener 3%, chitosan 3%, emulsifier 2.2%, preservative 0.5%, resist printing Salt 0.8%, the dispersed black dye mill base of said components are high-intensitive disperse dyes, and power part is 200~500%.
As needed, bleeding agent, levelling agent and migration inhibitor can also be added in the black composite dye mill base of above-mentioned dispersion, And bleeding agent content in mill base is 2g/L, levelling agent 3g/L, migration inhibitor 4.5g/L, and appropriate adjustment dispersing agent adds Dosage.
It is prepared as follows the black composite dye mill base of dispersion:
(1) reaction vessel is added water to, is added guar gum while stirring, under stirring condition, keeps guar gum sufficiently molten Sepiolite powder is added in Xie Hou, and stirring is added dropwise emulsifier, is creamy white to entire reaction system, adds acrylic acid, heats up 30~45min is kept the temperature after to 76 DEG C -85 DEG C, then cools to 42~46 DEG C, glacial acetic acid is added, and adjusting pH value is 6-7, room to be down to Temperature obtains material A；
(2) nonionic thickener, aluminum aluminum sulfate and ethyl alcohol are mixed, stirs evenly to obtain material B；
(3) dispersing agent and dispersed black dye are uniformly mixed, water-soluble nonionic surfactant and oil is then added After being ground to 50-700nm, material A and chitosan is added (when containing bleeding agent in component in dissolubility nonionic surface active agent When, bleeding agent is added at this time), material C is obtained after mixing evenly；
(4) material B is added in material C, then is ground to 50-700nm, reserve salt is added and preservative (contains in such as ingredient Have levelling agent, migration inhibitor, then levelling agent, migration inhibitor are added at this time), then it is ground to 50-700nm to obtain the final product.
Wherein, the chitosan is processed through following methods: adding chitosan into acetic acid solution, stirring is equal to being formed Phase solution；Maleic anhydride is dissolved in acetone, is then added in the homogeneous phase solution, wherein maleic anhydride quality is chitosan matter The 3% of amount；It is purified after reaction 9h is stirred at room temperature to obtain the final product.
Embodiment 10
Take following raw material for standby: dispersed black dye 28%, sepiolite powder 13%, dispersing agent 8%, ethyl alcohol 9%, oil-soluble Nonionic surface active agent 5%, guar gum 5%, water-soluble nonionic surfactant 6%, aluminum aluminum sulfate 6%, third Olefin(e) acid 6%, glacial acetic acid 4.5%, nonionic thickener 3%, chitosan 3%, emulsifier 2.2%, preservative 0.5%, resist printing Salt 0.8%, the dispersed black dye mill base of said components are high-intensitive disperse dyes, and power part is 200~500%.
As needed, bleeding agent, levelling agent and migration inhibitor can also be added in the black composite dye mill base of above-mentioned dispersion, And bleeding agent content in mill base is 2g/L, levelling agent 3g/L, migration inhibitor 4.5g/L, and appropriate adjustment dispersing agent adds Dosage.
It is prepared as follows the black composite dye mill base of dispersion:
(1) reaction vessel is added water to, is added guar gum while stirring, under stirring condition, keeps guar gum sufficiently molten Sepiolite powder is added in Xie Hou, and stirring is added dropwise emulsifier, is creamy white to entire reaction system, adds acrylic acid, heats up 30~45min is kept the temperature after to 76 DEG C -85 DEG C, then cools to 42~46 DEG C, glacial acetic acid is added, and adjusting pH value is 6-7, room to be down to Temperature obtains material A；
(2) nonionic thickener, aluminum aluminum sulfate and ethyl alcohol are mixed, stirs evenly to obtain material B；
(3) dispersing agent and dispersed black dye are uniformly mixed, water-soluble nonionic surfactant and oil is then added After being ground to 50-700nm, material A and chitosan is added (when containing bleeding agent in component in dissolubility nonionic surface active agent When, bleeding agent is added at this time), material C is obtained after mixing evenly；
(4) material B is added in material C, then is ground to 50-700nm, reserve salt is added and preservative (contains in such as ingredient Have levelling agent, migration inhibitor, then levelling agent, migration inhibitor are added at this time), then it is ground to 50-700nm to obtain the final product.
Wherein, the chitosan is processed through following methods: adding chitosan into acetic acid solution, stirring is equal to being formed Phase solution；Maleic anhydride is dissolved in acetone, is then added in the homogeneous phase solution, wherein maleic anhydride quality is chitosan matter The 3% of amount；It is purified after reaction 9h is stirred at room temperature to obtain the final product.
Embodiment 11
Take following raw material for standby: dispersed black dye 28%, sepiolite powder 15%, dispersing agent 8%, ethyl alcohol 7%, oil-soluble Nonionic surface active agent 5%, guar gum 5%, water-soluble nonionic surfactant 6%, aluminum aluminum sulfate 6%, third Olefin(e) acid 6%, glacial acetic acid 4.5%, nonionic thickener 3%, chitosan 2%, emulsifier 2.2%, preservative 0.5%, resist printing Salt 0.8%, the dispersed black dye mill base of said components are high-intensitive disperse dyes, and power part is 200~500%.
As needed, bleeding agent, levelling agent and migration inhibitor can also be added in the black composite dye mill base of above-mentioned dispersion, And bleeding agent content in mill base is 3g/L, levelling agent 4g/L, migration inhibitor 5g/L, and the addition of appropriate adjustment dispersing agent Amount.
It is prepared as follows the black composite dye mill base of dispersion:
(1) reaction vessel is added water to, is added guar gum while stirring, under stirring condition, keeps guar gum sufficiently molten Sepiolite powder is added in Xie Hou, and stirring is added dropwise emulsifier, is creamy white to entire reaction system, adds acrylic acid, heats up 30~45min is kept the temperature after to 76 DEG C -85 DEG C, then cools to 42~46 DEG C, glacial acetic acid is added, and adjusting pH value is 6-7, room to be down to Temperature obtains material A；
(2) nonionic thickener, aluminum aluminum sulfate and ethyl alcohol are mixed, stirs evenly to obtain material B；
(3) dispersing agent and dispersed black dye are uniformly mixed, water-soluble nonionic surfactant and oil is then added After being ground to 50-700nm, material A and chitosan is added (when containing bleeding agent in component in dissolubility nonionic surface active agent When, bleeding agent is added at this time), material C is obtained after mixing evenly；
(4) material B is added in material C, then is ground to 50-700nm, reserve salt is added and preservative (contains in such as ingredient Have levelling agent, migration inhibitor, then levelling agent, migration inhibitor are added at this time), then it is ground to 50-700nm to obtain the final product.
Wherein, the chitosan is processed through following methods: adding chitosan into acetic acid solution, stirring is equal to being formed Phase solution；Maleic anhydride is dissolved in acetone, is then added in the homogeneous phase solution, wherein maleic anhydride quality is chitosan matter The 3% of amount；It is purified after reaction 9h is stirred at room temperature to obtain the final product.
Embodiment 12
Take following raw material for standby: dispersed black dye 30%, sepiolite powder 15%, dispersing agent 8%, ethyl alcohol 7%, oil-soluble Nonionic surface active agent 5%, guar gum 5%, water-soluble nonionic surfactant 4%, aluminum aluminum sulfate 6%, third Olefin(e) acid 6%, glacial acetic acid 4.5%, nonionic thickener 3%, chitosan 3%, emulsifier 2.2%, preservative 0.5%, resist printing Salt 0.8%, the dispersed black dye mill base of said components are high-intensitive disperse dyes, and power part is 200~500%.
As needed, bleeding agent, levelling agent and migration inhibitor can also be added in the black composite dye mill base of above-mentioned dispersion, And bleeding agent content in mill base is 2g/L, levelling agent 3g/L, migration inhibitor 4.5g/L, and appropriate adjustment dispersing agent adds Dosage.
It is prepared as follows the black composite dye mill base of dispersion:
(1) reaction vessel is added water to, is added guar gum while stirring, under stirring condition, keeps guar gum sufficiently molten Sepiolite powder is added in Xie Hou, and stirring is added dropwise emulsifier, is creamy white to entire reaction system, adds acrylic acid, heats up 30~45min is kept the temperature after to 76 DEG C -85 DEG C, then cools to 42~46 DEG C, glacial acetic acid is added, and adjusting pH value is 6-7, room to be down to Temperature obtains material A；
(2) nonionic thickener, aluminum aluminum sulfate and ethyl alcohol are mixed, stirs evenly to obtain material B；
(3) dispersing agent and dispersed black dye are uniformly mixed, water-soluble nonionic surfactant and oil is then added After being ground to 50-700nm, material A and chitosan is added (when containing bleeding agent in component in dissolubility nonionic surface active agent When, bleeding agent is added at this time), material C is obtained after mixing evenly；
(4) material B is added in material C, then is ground to 50-700nm, reserve salt is added and preservative (contains in such as ingredient Have levelling agent, migration inhibitor, then levelling agent, migration inhibitor are added at this time), then it is ground to 50-700nm to obtain the final product.
Wherein, the chitosan is processed through following methods: adding chitosan into acetic acid solution, stirring is equal to being formed Phase solution；Maleic anhydride is dissolved in acetone, is then added in the homogeneous phase solution, wherein maleic anhydride quality is chitosan matter The 3% of amount；It is purified after reaction 9h is stirred at room temperature to obtain the final product.
Embodiment 13
Take following raw material for standby: dispersed black dye 30%, sepiolite powder 15%, dispersing agent 8%, ethyl alcohol 7%, oil-soluble Nonionic surface active agent 6%, guar gum 8%, water-soluble nonionic surfactant 7%, aluminum aluminum sulfate 5%, third Olefin(e) acid 4%, glacial acetic acid 2.6%, nonionic thickener 2%, chitosan 2%, emulsifier 2.1%, preservative 0.5%, resist printing Salt 0.8%, the dispersed black dye mill base of said components are high-intensitive disperse dyes, and power part is 200~500%.
As needed, bleeding agent, levelling agent and migration inhibitor can also be added in the black composite dye mill base of above-mentioned dispersion, And bleeding agent content in mill base is 2g/L, levelling agent 3g/L, migration inhibitor 4.5g/L, and appropriate adjustment dispersing agent adds Dosage.
It is prepared as follows the black composite dye mill base of dispersion:
(1) reaction vessel is added water to, is added guar gum while stirring, under stirring condition, keeps guar gum sufficiently molten Sepiolite powder is added in Xie Hou, and stirring is added dropwise emulsifier, is creamy white to entire reaction system, adds acrylic acid, heats up 30~45min is kept the temperature after to 76 DEG C -85 DEG C, then cools to 42~46 DEG C, glacial acetic acid is added, and adjusting pH value is 6-7, room to be down to Temperature obtains material A；
(2) nonionic thickener, aluminum aluminum sulfate and ethyl alcohol are mixed, stirs evenly to obtain material B；
(3) dispersing agent and dispersed black dye are uniformly mixed, water-soluble nonionic surfactant and oil is then added After being ground to 50-700nm, material A and chitosan is added (when containing bleeding agent in component in dissolubility nonionic surface active agent When, bleeding agent is added at this time), material C is obtained after mixing evenly；
(4) material B is added in material C, then is ground to 50-700nm, reserve salt is added and preservative (contains in such as ingredient Have levelling agent, migration inhibitor, then levelling agent, migration inhibitor are added at this time), then it is ground to 50-700nm to obtain the final product.
Wherein, the chitosan is processed through following methods: adding chitosan into acetic acid solution, stirring is equal to being formed Phase solution；Maleic anhydride is dissolved in acetone, is then added in the homogeneous phase solution, wherein maleic anhydride quality is chitosan matter The 3% of amount；It is purified after reaction 9h is stirred at room temperature to obtain the final product.
Embodiment 14
Take following raw material for standby: dispersed black dye 28%, sepiolite powder 15%, dispersing agent 8%, ethyl alcohol 7%, oil-soluble Nonionic surface active agent 6%, guar gum 8%, water-soluble nonionic surfactant 7%, aluminum aluminum sulfate 5%, third Olefin(e) acid 4%, nonionic thickener 2%, chitosan 2.5%, emulsifier 2.2%, preservative 0.8%, is prevented glacial acetic acid 3.5% Salt 1% is contaminated, the dispersed black dye mill base of said components is high-intensitive disperse dyes, and power part is 200~500%.
As needed, bleeding agent, levelling agent and migration inhibitor can also be added in the black composite dye mill base of above-mentioned dispersion, And bleeding agent content in mill base is 2g/L, levelling agent 3g/L, migration inhibitor 4.5g/L, and appropriate adjustment dispersing agent adds Dosage.
It is prepared as follows the black composite dye mill base of dispersion:
(1) reaction vessel is added water to, is added guar gum while stirring, under stirring condition, keeps guar gum sufficiently molten Sepiolite powder is added in Xie Hou, and stirring is added dropwise emulsifier, is creamy white to entire reaction system, adds acrylic acid, heats up 30~45min is kept the temperature after to 76 DEG C -85 DEG C, then cools to 42~46 DEG C, glacial acetic acid is added, and adjusting pH value is 6-7, room to be down to Temperature obtains material A；
(2) nonionic thickener, aluminum aluminum sulfate and ethyl alcohol are mixed, stirs evenly to obtain material B；
(3) dispersing agent and dispersed black dye are uniformly mixed, water-soluble nonionic surfactant and oil is then added After being ground to 50-700nm, material A and chitosan is added (when containing bleeding agent in component in dissolubility nonionic surface active agent When, bleeding agent is added at this time), material C is obtained after mixing evenly；
(4) material B is added in material C, then is ground to 50-700nm, reserve salt is added and preservative (contains in such as ingredient Have levelling agent, migration inhibitor, then levelling agent, migration inhibitor are added at this time), then it is ground to 50-700nm to obtain the final product.
Wherein, the chitosan is processed through following methods: adding chitosan into acetic acid solution, stirring is equal to being formed Phase solution；Maleic anhydride is dissolved in acetone, is then added in the homogeneous phase solution, wherein maleic anhydride quality is chitosan matter The 3% of amount；It is purified after reaction 9h is stirred at room temperature to obtain the final product.
Embodiment 15
Take following raw material for standby: dispersed black dye 28%, sepiolite powder 12%, dispersing agent 10%, ethyl alcohol 7%, oil are molten Property nonionic surface active agent 5%, guar gum 5%, water-soluble nonionic surfactant 7%, aluminum aluminum sulfate 6%, Acrylic acid 6%, glacial acetic acid 4%, nonionic thickener 3%, chitosan 3%, emulsifier 2.2%, preservative 0.8%, resist printing Salt 1%, the dispersed black dye mill base of said components are high-intensitive disperse dyes, and power part is 200~500%.
As needed, bleeding agent, levelling agent and migration inhibitor can also be added in the black composite dye mill base of above-mentioned dispersion, And bleeding agent content in mill base is 1.5g/L, levelling agent 2g/L, migration inhibitor 5g/L, and appropriate adjustment dispersing agent adds Dosage.
It is prepared as follows the black composite dye mill base of dispersion:
(1) reaction vessel is added water to, is added guar gum while stirring, under stirring condition, keeps guar gum sufficiently molten Sepiolite powder is added in Xie Hou, and stirring is added dropwise emulsifier, is creamy white to entire reaction system, adds acrylic acid, heats up 30~45min is kept the temperature after to 76 DEG C -85 DEG C, then cools to 42~46 DEG C, glacial acetic acid is added, and adjusting pH value is 6-7, room to be down to Temperature obtains material A；
(2) nonionic thickener, aluminum aluminum sulfate and ethyl alcohol are mixed, stirs evenly to obtain material B；
(3) dispersing agent and dispersed black dye are uniformly mixed, water-soluble nonionic surfactant and oil is then added After being ground to 50-700nm, material A and chitosan is added (when containing bleeding agent in component in dissolubility nonionic surface active agent When, bleeding agent is added at this time), material C is obtained after mixing evenly；
(4) material B is added in material C, then is ground to 50-700nm, reserve salt is added and preservative (contains in such as ingredient Have levelling agent, migration inhibitor, then levelling agent, migration inhibitor are added at this time), then it is ground to 50-700nm to obtain the final product.
Wherein, the chitosan is processed through following methods: adding chitosan into acetic acid solution, stirring is equal to being formed Phase solution；Maleic anhydride is dissolved in acetone, is then added in the homogeneous phase solution, wherein maleic anhydride quality is chitosan matter The 3% of amount；It is purified after reaction 9h is stirred at room temperature to obtain the final product.
Embodiment 16
Take following raw material for standby: dispersed black dye 35%, sepiolite powder 12%, dispersing agent 8%, ethyl alcohol 7%, oil-soluble Nonionic surface active agent 5%, guar gum 5%, water-soluble nonionic surfactant 4%, aluminum aluminum sulfate 4%, third Olefin(e) acid 6%, glacial acetic acid 4.5%, nonionic thickener 3%, chitosan 3%, emulsifier 2.2%, preservative 0.5%, resist printing Salt 0.8%, the dispersed black dye mill base of said components are high-intensitive disperse dyes, and power part is 200~500%.
As needed, bleeding agent, levelling agent and migration inhibitor can also be added in the black composite dye mill base of above-mentioned dispersion, And bleeding agent content in mill base is 2g/L, levelling agent 3g/L, migration inhibitor 4.5g/L, and appropriate adjustment dispersing agent adds Dosage.
It is prepared as follows the black composite dye mill base of dispersion:
(1) reaction vessel is added water to, is added guar gum while stirring, under stirring condition, keeps guar gum sufficiently molten Sepiolite powder is added in Xie Hou, and stirring is added dropwise emulsifier, is creamy white to entire reaction system, adds acrylic acid, heats up 30~45min is kept the temperature after to 76 DEG C -85 DEG C, then cools to 42~46 DEG C, glacial acetic acid is added, and adjusting pH value is 6-7, room to be down to Temperature obtains material A；
(2) nonionic thickener, aluminum aluminum sulfate and ethyl alcohol are mixed, stirs evenly to obtain material B；
(3) dispersing agent and dispersed black dye are uniformly mixed, water-soluble nonionic surfactant and oil is then added After being ground to 50-700nm, material A and chitosan is added (when containing bleeding agent in component in dissolubility nonionic surface active agent When, bleeding agent is added at this time), material C is obtained after mixing evenly；
(4) material B is added in material C, then is ground to 50-700nm, reserve salt is added and preservative (contains in such as ingredient Have levelling agent, migration inhibitor, then levelling agent, migration inhibitor are added at this time), then it is ground to 50-700nm to obtain the final product.
Wherein, the chitosan is processed through following methods: adding chitosan into acetic acid solution, stirring is equal to being formed Phase solution；Maleic anhydride is dissolved in acetone, is then added in the homogeneous phase solution, wherein maleic anhydride quality is chitosan matter The 3% of amount；It is purified after reaction 9h is stirred at room temperature to obtain the final product.
Embodiment 17
Take following raw material for standby: dispersed black dye 35%, sepiolite powder 15%, dispersing agent 8%, ethyl alcohol 7%, oil-soluble Nonionic surface active agent 6%, guar gum 8%, water-soluble nonionic surfactant 4%, aluminum aluminum sulfate 4%, third Olefin(e) acid 4%, glacial acetic acid 2.6%, nonionic thickener 2%, chitosan 2%, emulsifier 1.5%, preservative 0.3%, resist printing Salt 0.8%, the dispersed black dye mill base of said components are high-intensitive disperse dyes, and power part is 200~500%.
As needed, bleeding agent, levelling agent and migration inhibitor can also be added in the black composite dye mill base of above-mentioned dispersion, And bleeding agent content in mill base is 2g/L, levelling agent 4g/L, migration inhibitor 5g/L, and the addition of appropriate adjustment dispersing agent Amount.
It is prepared as follows the black composite dye mill base of dispersion:
(1) reaction vessel is added water to, is added guar gum while stirring, under stirring condition, keeps guar gum sufficiently molten Sepiolite powder is added in Xie Hou, and stirring is added dropwise emulsifier, is creamy white to entire reaction system, adds acrylic acid, heats up 30~45min is kept the temperature after to 76 DEG C -85 DEG C, then cools to 42~46 DEG C, glacial acetic acid is added, and adjusting pH value is 6-7, room to be down to Temperature obtains material A；
(2) nonionic thickener, aluminum aluminum sulfate and ethyl alcohol are mixed, stirs evenly to obtain material B；
(3) dispersing agent and dispersed black dye are uniformly mixed, water-soluble nonionic surfactant and oil is then added After being ground to 50-700nm, material A and chitosan is added (when containing bleeding agent in component in dissolubility nonionic surface active agent When, bleeding agent is added at this time), material C is obtained after mixing evenly；
(4) material B is added in material C, then is ground to 50-700nm, reserve salt is added and preservative (contains in such as ingredient Have levelling agent, migration inhibitor, then levelling agent, migration inhibitor are added at this time), then it is ground to 50-700nm to obtain the final product.
Wherein, the chitosan is processed through following methods: adding chitosan into acetic acid solution, stirring is equal to being formed Phase solution；Maleic anhydride is dissolved in acetone, is then added in the homogeneous phase solution, wherein maleic anhydride quality is chitosan matter The 3% of amount；It is purified after reaction 9h is stirred at room temperature to obtain the final product.
Embodiment 18
Take following raw material for standby: dispersed black dye 35%, sepiolite powder 10%, dispersing agent 8%, ethyl alcohol 7%, oil-soluble Nonionic surface active agent 6%, guar gum 8%, water-soluble nonionic surfactant 5%, aluminum aluminum sulfate 4%, third Olefin(e) acid 4%, glacial acetic acid 4.5%, nonionic thickener 3%, chitosan 2%, emulsifier 2.2%, preservative 0.5%, resist printing Salt 0.8%, the dispersed black dye mill base of said components are high-intensitive disperse dyes, and power part is 200~500%.
As needed, bleeding agent, levelling agent and migration inhibitor can also be added in the black composite dye mill base of above-mentioned dispersion, And bleeding agent content in mill base is 2g/L, levelling agent 3g/L, migration inhibitor 4.5g/L, and appropriate adjustment dispersing agent adds Dosage.
It is prepared as follows the black composite dye mill base of dispersion:
(1) reaction vessel is added water to, is added guar gum while stirring, under stirring condition, keeps guar gum sufficiently molten Sepiolite powder is added in Xie Hou, and stirring is added dropwise emulsifier, is creamy white to entire reaction system, adds acrylic acid, heats up 30~45min is kept the temperature after to 76 DEG C -85 DEG C, then cools to 42~46 DEG C, glacial acetic acid is added, and adjusting pH value is 6-7, room to be down to Temperature obtains material A；
(2) nonionic thickener, aluminum aluminum sulfate and ethyl alcohol are mixed, stirs evenly to obtain material B；
(3) dispersing agent and dispersed black dye are uniformly mixed, water-soluble nonionic surfactant and oil is then added After being ground to 50-700nm, material A and chitosan is added (when containing bleeding agent in component in dissolubility nonionic surface active agent When, bleeding agent is added at this time), material C is obtained after mixing evenly；
(4) material B is added in material C, then is ground to 50-700nm, reserve salt is added and preservative (contains in such as ingredient Have levelling agent, migration inhibitor, then levelling agent, migration inhibitor are added at this time), then it is ground to 50-700nm to obtain the final product.
Wherein, the chitosan is processed through following methods: adding chitosan into acetic acid solution, stirring is equal to being formed Phase solution；Maleic anhydride is dissolved in acetone, is then added in the homogeneous phase solution, wherein maleic anhydride quality is chitosan matter The 3% of amount；It is purified after reaction 9h is stirred at room temperature to obtain the final product.
Measure of merit example
The black composite dye mill base of dispersion resulting to above-described embodiment 1-18 is tested for the property, and is tested as follows: respectively being taken Disperse black composite dye mill base in 0.5g above-described embodiment, add water to 15g, make its ultrasonic dissolution, it is abundant that 35g thickener is then added Carry out stamp is stirred evenly, after being put into 100 DEG C of baking ovens progress prebakes, until 210 DEG C of * 1min carry out thermal transfer on transfer interpreter, i.e., Sample cloth after being transferred.It observes cloth specimen coloured light and uses AATCC 16-2004, AATCC 16-2014, GB/T 3920-2008 Its light fastness, washing fastness and fastness to rubbing are measured, measurement result is as shown in table 1.
1 different component of table disperses the effect comparison table of black composite dye mill base
As can be seen from Table 1: present case provide the black composite dye stability of pigment paste of dispersion is good, modest viscosity, Neng Gouchang It is dispersed in water, will not precipitate long, there is good dyestuff transitivity and permeability, and transferring rate is high, washing fastness and resistance to Crock fastness is good.

Claims (10)

1. a kind of high staining power disperses black composite dye mill base, it is characterised in that: the composite dye includes following quality point Number meter each components: dispersed black dye 10~40%, sepiolite powder 10~15%, dispersing agent 8~10%, ethyl alcohol 7~9%, Oil-soluble nonionic surface active agent 5~8%, guar gum 5~8%, water-soluble nonionic surfactant 4~7%, Aluminum aluminum sulfate 4~6%, acrylic acid 4~6%, glacial acetic acid 2.6~4.5%, nonionic thickener 2~3%, chitosan 2~ 3%, emulsifier 1.5~2.2%, preservative 0.3~0.8%, reserve salt 0.8~1%；Disperse the dyestuff of black composite dye mill base Power part is 200-500%.
2. a kind of high staining power as described in claim 1 disperses black composite dye mill base, it is characterised in that: also include to seep Saturating agent, levelling agent and migration inhibitor, bleeding agent content in composite dye mill base are 1~3g/L, levelling agent in composite dye color Content is 2~4g/L in slurry, migration inhibitor content in composite dye mill base is 4~5g/L.
3. a kind of high staining power as claimed in claim 1 or 2 disperses black composite dye mill base, it is characterised in that: the oil Dissolubility nonionic surface active agent be selected from fatty alcohol polyoxyethylene ether, alkyl phenol polyoxyethylene ether, polyoxyethylene carboxylate, It is one or more in sorbitan fatty acid ester, fatty glyceride.
4. a kind of high staining power as claimed in claim 1 or 2 disperses black composite dye mill base, it is characterised in that: the water Dissolubility nonionic surface active agent is selected from fatty alcohol polyoxyethylene ether, alkyl phenol polyoxyethylene ether, polyoxyethylene carboxylate One of or it is a variety of.
5. a kind of high staining power as claimed in claim 1 or 2 disperses black composite dye mill base, it is characterised in that: described non- Ionic thickener in polyethylene glycol, polyether nonionic surfactant, polyvinylpyrrolidone, polyvinyl alcohol one Kind is a variety of.
6. a kind of high staining power as claimed in claim 1 or 2 disperses black composite dye mill base, it is characterised in that: described point Powder is one of lignosulfonate, naphthalenesulfonic acid-formaldehyde condensate, benzyl naphthalene sulfonic acid-formaldehyde condensation product or a variety of；Alternatively, The dispersing agent is lignosulfonate, and average molecular weight is 10000~15000, and sulfonation degree is 0.8~1.5；Or, described point Powder is the mixture of lignosulfonate and naphthalenesulfonic acid-formaldehyde condensate, and the two mass ratio is 3~5:1.
7. a kind of high staining power as claimed in claim 1 or 2 disperses black composite dye mill base, it is characterised in that: the cream Agent is the compound emulsifying agent of lauryl sodium sulfate and triethanolamine, and the two mass ratio is 2:2~3.
8. the preparation method that high staining power as described in claim 1 disperses black composite dye mill base, which is characterized in that comprising with Lower step:
(1) guar gum is added in Xiang Shuizhong while stirring, after completely dissolution to guar gum, sepiolite powder is added, stirs, drop Add emulsifier, be creamy white to entire reaction system, add acrylic acid, 30~45min is kept the temperature after being warming up to 76 DEG C -85 DEG C, 42~46 DEG C are cooled to again, glacial acetic acid is added, and adjusting pH value is 6-7, and room temperature to be down to obtains material A；
(2) nonionic thickener, aluminum aluminum sulfate and ethyl alcohol are mixed, stirs evenly to obtain material B；
(3) dispersing agent and dispersed black dye are uniformly mixed, be added water-soluble nonionic surfactant and oil-soluble it is non-from Subtype surfactant is ground to 50-700nm, and material A and chitosan is added, and obtains material C after mixing evenly；
(4) material B is added in material C, then is ground to 50-700nm, reserve salt and preservative is added, then be ground to 50- 700nm to obtain the final product.
9. the preparation method that high staining power as claimed in claim 2 disperses black composite dye mill base, which is characterized in that comprising with Lower step:
(1) guar gum is added in Xiang Shuizhong while stirring, after completely dissolution to guar gum, sepiolite powder is added, stirs, drop Add emulsifier, be creamy white to entire reaction system, add acrylic acid, 30~45min is kept the temperature after being warming up to 76 DEG C -85 DEG C, 42~46 DEG C are cooled to again, glacial acetic acid is added, and adjusting pH value is 6-7, and room temperature to be down to obtains material A；
(2) nonionic thickener, aluminum aluminum sulfate and ethyl alcohol are mixed, stirs evenly to obtain material B；
(3) dispersing agent and dispersed black dye are uniformly mixed, be added water-soluble nonionic surfactant and oil-soluble it is non-from Subtype surfactant is ground to 50-700nm, and material A and chitosan and bleeding agent is added, and obtains material C after mixing evenly；
(4) material B is added in material C, then is ground to 50-700nm, levelling agent, migration inhibitor, reserve salt and anti-corrosion is added Agent, then it is ground to 50-700nm to obtain the final product.
10. the preparation method that the high staining power as described in claim 8 or 9 disperses black composite dye mill base, which is characterized in that institute It states chitosan to be pre-processed using preceding using following methods: add chitosan into acetic acid solution, stirring is homogeneous to being formed Solution；Maleic anhydride is dissolved in acetone, is then added in the homogeneous phase solution, wherein maleic anhydride quality is chitosan mass 2.5~4%；It is purified after 9~10h of reaction is stirred at room temperature to obtain the final product.
CN201811283793.7A 2018-10-31 2018-10-31 Black composite dye mill base of a kind of high staining power dispersion and preparation method thereof Pending CN109385917A (en)

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CN110230212A (en) * 2019-05-21 2019-09-13 武汉纺织大学 A kind of Polyester Textiles colouring method
CN111673941A (en) * 2020-06-10 2020-09-18 江西富上美科技有限公司 Plastic master batch preparation process
CN112391855A (en) * 2020-11-09 2021-02-23 菲诺染料化工(无锡)有限公司 Aqueous high-solubility low-hydrochloric acid dye color paste for textile printing

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Application publication date: 20190226