CN109385150A - A kind of water-proof climate resisting bi-component exterior wall latex paint - Google Patents
A kind of water-proof climate resisting bi-component exterior wall latex paint Download PDFInfo
- Publication number
- CN109385150A CN109385150A CN201811174698.3A CN201811174698A CN109385150A CN 109385150 A CN109385150 A CN 109385150A CN 201811174698 A CN201811174698 A CN 201811174698A CN 109385150 A CN109385150 A CN 109385150A
- Authority
- CN
- China
- Prior art keywords
- parts
- water
- exterior wall
- agent
- latex paint
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000003973 paint Substances 0.000 title claims abstract description 30
- 239000004816 latex Substances 0.000 title claims abstract description 21
- 229920000126 latex Polymers 0.000 title claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 28
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000011347 resin Substances 0.000 claims abstract description 20
- 229920005989 resin Polymers 0.000 claims abstract description 20
- 239000006185 dispersion Substances 0.000 claims abstract description 17
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 15
- 239000002253 acid Substances 0.000 claims abstract description 14
- 239000002562 thickening agent Substances 0.000 claims abstract description 11
- 239000007822 coupling agent Substances 0.000 claims abstract description 7
- 239000000049 pigment Substances 0.000 claims abstract description 6
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 5
- 239000000945 filler Substances 0.000 claims abstract description 5
- 230000000855 fungicidal effect Effects 0.000 claims abstract description 5
- 239000000417 fungicide Substances 0.000 claims abstract description 5
- 238000009736 wetting Methods 0.000 claims abstract description 5
- 239000002270 dispersing agent Substances 0.000 claims abstract description 4
- 238000006243 chemical reaction Methods 0.000 claims description 12
- -1 dihydroxy n-butyl Chemical group 0.000 claims description 10
- 239000007788 liquid Substances 0.000 claims description 10
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 9
- 239000011737 fluorine Substances 0.000 claims description 9
- 229910052731 fluorine Inorganic materials 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 9
- 239000000178 monomer Substances 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 7
- 150000002148 esters Chemical class 0.000 claims description 7
- 239000000843 powder Substances 0.000 claims description 7
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 6
- 229920002635 polyurethane Polymers 0.000 claims description 6
- 239000004814 polyurethane Substances 0.000 claims description 6
- GHKCSRZBNZQHKW-UHFFFAOYSA-N 1-sulfanylethanol Chemical class CC(O)S GHKCSRZBNZQHKW-UHFFFAOYSA-N 0.000 claims description 5
- QZPSOSOOLFHYRR-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate Chemical class OCCCOC(=O)C=C QZPSOSOOLFHYRR-UHFFFAOYSA-N 0.000 claims description 5
- WCNKHTIPPVQEQW-UHFFFAOYSA-N 4,4,4-trifluorobut-1-ene Chemical compound FC(F)(F)CC=C WCNKHTIPPVQEQW-UHFFFAOYSA-N 0.000 claims description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 5
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical class CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 claims description 5
- 229910001873 dinitrogen Inorganic materials 0.000 claims description 5
- 238000004945 emulsification Methods 0.000 claims description 5
- 239000003999 initiator Substances 0.000 claims description 5
- 238000009413 insulation Methods 0.000 claims description 5
- MGIYRDNGCNKGJU-UHFFFAOYSA-N isothiazolinone Chemical compound O=C1C=CSN1 MGIYRDNGCNKGJU-UHFFFAOYSA-N 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 claims description 5
- 238000005292 vacuum distillation Methods 0.000 claims description 5
- RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 claims description 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 4
- 125000004423 acyloxy group Chemical group 0.000 claims description 4
- 235000019441 ethanol Nutrition 0.000 claims description 4
- 239000012535 impurity Substances 0.000 claims description 4
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 4
- GNEPLYVYORHREW-UHFFFAOYSA-N 1,1,3,3,6-pentamethyl-7-nitro-2h-inden-5-amine Chemical compound CC1=C(N)C=C2C(C)(C)CC(C)(C)C2=C1[N+]([O-])=O GNEPLYVYORHREW-UHFFFAOYSA-N 0.000 claims description 3
- UICXTANXZJJIBC-UHFFFAOYSA-N 1-(1-hydroperoxycyclohexyl)peroxycyclohexan-1-ol Chemical compound C1CCCCC1(O)OOC1(OO)CCCCC1 UICXTANXZJJIBC-UHFFFAOYSA-N 0.000 claims description 3
- LVJZCPNIJXVIAT-UHFFFAOYSA-N 1-ethenyl-2,3,4,5,6-pentafluorobenzene Chemical compound FC1=C(F)C(F)=C(C=C)C(F)=C1F LVJZCPNIJXVIAT-UHFFFAOYSA-N 0.000 claims description 3
- KESQFSZFUCZCEI-UHFFFAOYSA-N 2-(5-nitropyridin-2-yl)oxyethanol Chemical group OCCOC1=CC=C([N+]([O-])=O)C=N1 KESQFSZFUCZCEI-UHFFFAOYSA-N 0.000 claims description 3
- 229940100555 2-methyl-4-isothiazolin-3-one Drugs 0.000 claims description 3
- QYYMDNHUJFIDDQ-UHFFFAOYSA-N 5-chloro-2-methyl-1,2-thiazol-3-one;2-methyl-1,2-thiazol-3-one Chemical group CN1SC=CC1=O.CN1SC(Cl)=CC1=O QYYMDNHUJFIDDQ-UHFFFAOYSA-N 0.000 claims description 3
- ICQIOYRFQFBEOO-UHFFFAOYSA-N C=CCC.[F] Chemical class C=CCC.[F] ICQIOYRFQFBEOO-UHFFFAOYSA-N 0.000 claims description 3
- XVTONWSMKAHXDJ-UHFFFAOYSA-N C=CCCC.[F] Chemical class C=CCCC.[F] XVTONWSMKAHXDJ-UHFFFAOYSA-N 0.000 claims description 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 3
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 claims description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 3
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- 235000012211 aluminium silicate Nutrition 0.000 claims description 3
- 239000010425 asbestos Substances 0.000 claims description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 3
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 3
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 3
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 3
- 125000003253 isopropoxy group Chemical group [H]C([H])([H])C([H])(O*)C([H])([H])[H] 0.000 claims description 3
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 claims description 3
- MCCIMQKMMBVWHO-UHFFFAOYSA-N octadecanoic acid;titanium Chemical compound [Ti].CCCCCCCCCCCCCCCCCC(O)=O.CCCCCCCCCCCCCCCCCC(O)=O.CCCCCCCCCCCCCCCCCC(O)=O.CCCCCCCCCCCCCCCCCC(O)=O MCCIMQKMMBVWHO-UHFFFAOYSA-N 0.000 claims description 3
- ZTFZSHLWORMEHO-UHFFFAOYSA-A pentaaluminum;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O.[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O.[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O ZTFZSHLWORMEHO-UHFFFAOYSA-A 0.000 claims description 3
- 229920000570 polyether Polymers 0.000 claims description 3
- 229910052895 riebeckite Inorganic materials 0.000 claims description 3
- NKJOXAZJBOMXID-UHFFFAOYSA-N 1,1'-Oxybisoctane Chemical compound CCCCCCCCOCCCCCCCC NKJOXAZJBOMXID-UHFFFAOYSA-N 0.000 claims description 2
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 2
- 239000005995 Aluminium silicate Substances 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 2
- UWHCKJMYHZGTIT-UHFFFAOYSA-N Tetraethylene glycol, Natural products OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 claims description 2
- QBLDFAIABQKINO-UHFFFAOYSA-N barium borate Chemical compound [Ba+2].[O-]B=O.[O-]B=O QBLDFAIABQKINO-UHFFFAOYSA-N 0.000 claims description 2
- 229910021538 borax Inorganic materials 0.000 claims description 2
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 claims description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims description 2
- IXQWNVPHFNLUGD-UHFFFAOYSA-N iron titanium Chemical compound [Ti].[Fe] IXQWNVPHFNLUGD-UHFFFAOYSA-N 0.000 claims description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000010445 mica Substances 0.000 claims description 2
- 229910052618 mica group Inorganic materials 0.000 claims description 2
- 125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 claims description 2
- 239000004328 sodium tetraborate Substances 0.000 claims description 2
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 2
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 claims description 2
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 claims description 2
- 229910000165 zinc phosphate Inorganic materials 0.000 claims description 2
- XAEWLETZEZXLHR-UHFFFAOYSA-N zinc;dioxido(dioxo)molybdenum Chemical compound [Zn+2].[O-][Mo]([O-])(=O)=O XAEWLETZEZXLHR-UHFFFAOYSA-N 0.000 claims description 2
- GUUULVAMQJLDSY-UHFFFAOYSA-N 4,5-dihydro-1,2-thiazole Chemical compound C1CC=NS1 GUUULVAMQJLDSY-UHFFFAOYSA-N 0.000 claims 1
- 230000000977 initiatory effect Effects 0.000 claims 1
- 150000002576 ketones Chemical class 0.000 claims 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 1
- 239000002689 soil Substances 0.000 claims 1
- 230000008961 swelling Effects 0.000 claims 1
- 230000002209 hydrophobic effect Effects 0.000 abstract description 4
- 238000010276 construction Methods 0.000 abstract description 3
- 239000011248 coating agent Substances 0.000 description 11
- 238000000576 coating method Methods 0.000 description 11
- 239000004568 cement Substances 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 230000001680 brushing effect Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
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- DTGKSKDOIYIVQL-WEDXCCLWSA-N (+)-borneol Chemical group C1C[C@@]2(C)[C@@H](O)C[C@@H]1C2(C)C DTGKSKDOIYIVQL-WEDXCCLWSA-N 0.000 description 1
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- 239000000853 adhesive Substances 0.000 description 1
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- 239000012752 auxiliary agent Substances 0.000 description 1
- 229910000062 azane Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
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- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
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- 239000004208 shellac Substances 0.000 description 1
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 description 1
- 229940113147 shellac Drugs 0.000 description 1
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- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
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- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
- C08F214/186—Monomers containing fluorine with non-fluorinated comonomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/22—Esters containing halogen
- C08F220/24—Esters containing halogen containing perhaloalkyl radicals
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
- C09D133/16—Homopolymers or copolymers of esters containing halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
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- C08L2205/00—Polymer mixtures characterised by other features
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Abstract
The present invention relates to a kind of water-proof climate resisting bi-component exterior wall latex paints, which is characterized in that is grouped as by two groups of A, B, according to parts by weight, component A is；35-40 parts of water-based fluorocarbon resin dispersion, 1-5 parts of coalescing agent, 0.3-1.0 parts of levelling agent, 0.1-0.3 parts of thickener, 0.5-1 parts of wetting dispersing agent, 0.25-0.30 parts of defoaming agent, 0.20-0.25 parts of fungicide, 25-40 parts of pigments and fillers, 15-20 parts of water；B component are as follows: 2-5 parts of titanate coupling agent, 1-3 parts of Perhydropolysilazane.The present invention has higher hardness, and better acid resistance, hydrophobic waterproof, UV resistant performance and better dirt-removing power are more applicable for using in construction requirement height and the harsher engineering of environment.
Description
Technical field
The invention belongs to building coating technical field, it is related to a kind of water-proof climate resisting bi-component exterior wall latex paint and its preparation side
Method.
Background technique
Exterior wall paint is also exterior coating, is generally used for exterior wall, also can be used in the place of the high humidities such as toilet.Exterior wall
There are many type of coating, and it is outer can be divided into the self-cleaning elasticity of the antiacid alkali exterior coating of strength, elastic pure acrylic acid exterior coating, organosilicon
Wall coating, advanced acrylic wall paint, oiliness fluorocarbon coating etc..Wherein elastic pure acrylic acid exterior coating, advanced acrylic acid
Exterior coating there are waterproof, paint film is easy to aging, change colour the shortcomings that, that there are hardness is low for the self-cleaning elastic exterior coating material of organosilicon
Although disadvantage, oiliness fluorocarbon coating are had excellent performance, but have the shortcomings that environmental-protecting performance is poor, VOC emission is high.
CN201310620991.9 discloses a kind of weather-proof mildew resistant moistureproof exterior wall paint vehicle, by the composition group of following parts by weight
At: 20-30 parts of ethanol amines, 5-10 parts of XG-95,200-250 parts of nano kaolines, 250-300 parts of lithopone, 10-20 parts of starch,
500-600 parts of vinyl acetate homopolymer lotions, 50-80 parts of propylene glycol, 30-50 parts of isopropanols, 250-300 parts of sericites, 150-
200 parts of GR composite titanium dioxide pigments, 20-30 parts of auxiliary agents, 250-300 parts of pure water.The weather-proof mildew resistant moistureproof exterior wall paint vehicle can support
The ultraviolet light of environment resistant circle solves the problems, such as paint vehicle colour fading, loss of gloss, extends the service life of paint vehicle, while having good anti-
Dirt, rub resistance, anti-mealiness, weatherability, anti-mildew denaturation and moisture resistance.But since the invention uses vinyl acetate homopolymerization
Object lotion is film forming matter, and hydrophobic performance, acid-proof alkaline are slightly worse.
Summary of the invention
It is in order to overcome the shortcomings of the prior art and insufficient, the present invention is intended to provide a kind of water-proof climate resisting bi-component exterior wall latex
Paint.
The present invention takes following technical scheme, a kind of water-proof climate resisting bi-component exterior wall latex paint, which is characterized in that by A, B
Two groups are grouped as, according to parts by weight, component A are as follows: 35-40 parts of water-based fluorocarbon resin dispersion, 1-5 parts of coalescing agent, levelling
0.3-1.0 parts of agent, 0.1-0.3 parts of thickener, 0.5-1 parts of wetting dispersing agent, 0.25-0.30 parts of defoaming agent, fungicide 0.20-
0.25 part, 25-40 parts of pigments and fillers, 15-20 parts of water；B component are as follows: 2-5 parts of titanate coupling agent, 1-3 parts of Perhydropolysilazane.
The coalescing agent is 2,2,4- trimethyl -1,3- pentanediol diisobutyrate, the different octyl ether of butanediol, four sweet
At least one of alcohol, dihydroxy n-butyl ether.
The levelling agent is at least one of BYK-381, BYK-333, BYK-306.
The thickener be carboxymethyl cellulose, hydroxyethyl cellulose, polyether system associate type polyurethane rheological thickeners,
At least one of nonionic polyurethane association thickener.
The wetting dispersing agent be TEGO760W, TEGO715W, TEGO750W, TEGO4100, TEGO685 at least
It is a kind of.
The defoaming agent is at least one of BYK-038, BYK-035, BYK-037.
The fungicide is at least one of Kathon CG isothiazolinone, isothiazolinone, methylisothiazolinone.
The pigments and fillers be talcum powder, Cab-O-sil, mica powder, trbasic zinc phosphate, zinc molybdate, iron oxide red, aluminium triphosphate,
At least one of barium metaborate, kaolin, bentonite, titanium-iron powder, ferrophosphorus powder, graphite powder, borax, flake asbestos, aqueous color paste.
The titanate coupling agent is three titanium stearate acid esters of isopropoxy, two (dioctyl pyrophosphoryl oxygroup) glycolic acids
Titanium, tetra isopropyl two (dioctyl phosphito acyloxy) titanate esters, isopropyl three (dioctylphyrophosphoric acid acyloxy) titanate esters, three
At least one of ethyoxyl epoxyisopropyl titanate esters.
According to parts by weight, the water-based fluorocarbon resin dispersion is prepared by following methods:
(1) by 30-50 parts of fluorine-containing soft monomers, 10-15 parts of fluorine-containing hard monomers, 10-15 parts of hydroxypropyl acrylates, 5-10 part 4,
4,4- trifluorobutenes acid, 2-5 parts of initiators, 1-3 parts of mercaptoethanols are added into mixing kettle, are uniformly mixed, as dropping liquid, standby
With；
(2) lead under condition of nitrogen gas, 30-35 parts of amphiprotic solvents be added into reaction kettle, are then heated to 110-125 DEG C,
Dropping liquid is slowly added dropwise into reaction kettle, 4-5h is added dropwise, insulation reaction 2-3h；Then 0.2-0.5 parts are added for 110-125 DEG C
Initiator continues to keep the temperature 1h；
(3) it is cooled to 50-70 DEG C, it is 8 that 10-15 parts of dimethylethanolamines are added dropwise thereto to system pH, and vacuum distillation removes
It goes solvent and impurity to system quality score to be greater than 85%, it is described to get arriving that 60-90 parts of water high-speed stirred emulsifications is then added
Water-based fluorocarbon resin dispersion.
The fluorine-containing soft monomer is at least one of seven fluorine n-pentenes, five fluorine n-butenes, 17 fluorine monooctyl ester of acrylic acid；
The hard monomer is perfluoroethyl isobornyl thiocyanoacetate, methacrylic acid perfluor isobornyl thiocyanoacetate, at least one in pentafluorostyrene
Kind；The initiator is peroxidized t-butyl perbenzoate, new peroxide tert-butyl caprate, at least one in cyclohexanone peroxide
Kind；The amphiprotic solvent is at least one of ethylene glycol monobutyl ether, ethyl alcohol, propylene glycol monobutyl ether.
The material of A, B component is conventionally uniformly mixed by preparation of the invention, present invention is particularly suitable for
Cement wall, ceramic tile wall to be renovated.
Application method of the invention: A, B component are uniformly mixed by 1h before constructing, and are then imposed on by brushing or spraying
Cement wall, ceramic tile surface of wall to be renovated.
Compared with the existing technology, the present invention has the following advantages that or beneficial outcomes:
It is film forming matter that the present invention, which selects aqueous dual-component fluorocarbon resin, is solid with titanate coupling agent and Perhydropolysilazane
Agent is reacted with curing agent by the hydroxyl of fluorocarbon resin dispersion, is cross-linked to form tridimensional network.Titanate coupling agent is handed over
Connection is had excellent performance, Perhydropolysilazane solidification after have silicon nitride characteristic with high hardness, matrix resin fluorocarbon resin have it is hydrophobic,
The advantages of weather-proof, acid and alkali-resistance, salt spray resistance.The present invention selects high boiling coalescing agent, the emulsion paint it is with high hardness simultaneously,
Filming performance is good, toughness is high.
Specific embodiment
A kind of water-proof climate resisting bi-component exterior wall latex paint of the invention is further described below with reference to embodiment.It can
With understanding, specific embodiment described herein is used only for explaining related invention, rather than the restriction to the invention.
Embodiment 1
According to parts by weight, a kind of water-based fluorocarbon resin dispersion M is prepared by following methods:
(1) by 34 part of seven fluorine n-pentene, 12 parts of perfluoroethyl isobornyl thiocyanoacetates, 11 parts of hydroxypropyl acrylates, 7 parts of 4,4,4-
Trifluorobutene acid, 3 parts of new peroxide tert-butyl caprates, 2 parts of mercaptoethanols are added into mixing kettle, are uniformly mixed, are as added dropwise
Liquid, it is spare；
(2) lead under condition of nitrogen gas, 32 parts of propylene glycol monobutyl ethers are added into reaction kettle, are then heated to 115 DEG C, to anti-
It answers and dropping liquid is slowly added dropwise in kettle, 4.5h is added dropwise, insulation reaction 2.5h；Then 0.3 part of peroxidating neodecanoic acid is added for 115 DEG C
The tert-butyl ester continues to keep the temperature 1h；
(3) 60 DEG C are cooled to, it is 8 that 12 parts of dimethylethanolamines are added dropwise thereto to system pH, and vacuum distillation removes solvent
It is greater than 85% with impurity to system quality score, 80 parts of water high-speed stirred emulsifications is added then to get the water-based fluorocarbon is arrived
Resin dispersion M.
Embodiment 2
According to parts by weight, a kind of water-based fluorocarbon resin dispersion N is prepared by following methods:
(1) by 30 part of five fluorine n-butene, 10 parts of methacrylic acid perfluor isobornyl thiocyanoacetates, 10 parts of hydroxypropyl acrylates, 5 part 4,
4,4- trifluorobutenes acid, 2 parts of new peroxide tert-butyl caprates, 1 mercaptoethanol are added into mixing kettle, are uniformly mixed, as drip
Liquid feeding, it is spare；
(2) lead under condition of nitrogen gas, 30 parts of ethyl alcohol are added into reaction kettle, are then heated to 110 DEG C, delay into reaction kettle
Slow that dropping liquid is added dropwise, 4h is added dropwise, insulation reaction 2h；Then it adds 0.2 part of new peroxide tert-butyl caprate for 110 DEG C, continues
Keep the temperature 1h；
50 DEG C are cooled to, it is 8 that 10 parts of dimethylethanolamines are added dropwise thereto to system pH, and vacuum distillation removes solvent and miscellaneous
Matter to system quality score is greater than 85%, 60 parts of water high-speed stirred emulsifications is added then to get the water-based fluorocarbon resin is arrived
Dispersion N.
Embodiment 3
According to parts by weight, a kind of water-based fluorocarbon resin dispersion X is prepared by following methods:
(1) by 50 parts of 17 fluorine monooctyl esters of acrylic acid, 15 parts of pentafluorostyrenes, 15 parts of hydroxypropyl acrylates, 10 parts of 4,4,4-
Trifluorobutene acid, 5 parts of cyclohexanone peroxides, 3 parts of mercaptoethanols are added into mixing kettle, are uniformly mixed, as dropping liquid, standby
With；
(4) lead under condition of nitrogen gas, 35 parts of propylene glycol monobutyl ethers are added into reaction kettle, are then heated to 125 DEG C, to anti-
It answers and dropping liquid is slowly added dropwise in kettle, 5h is added dropwise, insulation reaction 3h；Then 0.5 part of cyclohexanone peroxide is added for 125 DEG C, after
Continue insurance temperature 1h；
(5) 70 DEG C are cooled to, it is 8 that 15 parts of dimethylethanolamines are added dropwise thereto to system pH, and vacuum distillation removes solvent
It is greater than 85% with impurity to system quality score, 90 parts of water high-speed stirred emulsifications is added then to get the water-based fluorocarbon is arrived
Resin dispersion X.
Embodiment 4
A kind of water-proof climate resisting bi-component exterior wall latex paint, which is characterized in that it is grouped as by two groups of A, B, according to parts by weight,
Component A are as follows: M36 parts of water-based fluorocarbon resin dispersion, 3 parts of 2,2,4- trimethyl -1,3- pentanediol diisobutyrate, BYK-
3810.5 parts, 0.18 part of carboxymethyl cellulose, 0.7 part of TEGO 760W, BYK-0380.28 parts, Kathon CG isothiazolinone 0.22
Part, 32 parts of talcum powder, 18 parts of water；B component are as follows: 4 parts of tetra isopropyl two (dioctyl phosphito acyloxy) titanate esters, the poly- silicon of perhydro
1.7 parts of azane.
Embodiment 5
A kind of water-proof climate resisting bi-component exterior wall latex paint, which is characterized in that it is grouped as by two groups of A, B, according to parts by weight,
Component A is；N35 parts of water-based fluorocarbon resin dispersion, 1 part of dihydroxy n-butyl ether, BYK-3331.0 parts, nonionic polyurethane
0.3 part of association thickener, 0.5 part of TEGO 715W, BYK-0350.25 parts, 0.25 part of isothiazolinone, aluminium triphosphate 40
Part, 15 parts of water；B component are as follows: 2 parts, 3 parts of Perhydropolysilazane of three titanium stearate acid esters of isopropoxy.
Embodiment 6
A kind of water-proof climate resisting bi-component exterior wall latex paint, which is characterized in that it is grouped as by two groups of A, B, according to parts by weight,
Component A is；X40 parts of water-based fluorocarbon resin dispersion, 5 parts of tetraethylene glycol, BYK-3060.3 parts, polyether system association type polyurethane rheology
0.1 part of thickener, 6851 parts of TEGO, BYK-0370.30 parts .0.2 parts of methylisothiazolinone, 25 parts of flake asbestos, 20 parts of water；
B component composition are as follows: 5 parts of triethoxy epoxyisopropyl titanate esters, 1 part of Perhydropolysilazane.
The material of A, B component is conventionally uniformly mixed by the preparation of embodiment 4-6；Application method: construction
The A of embodiment 4-6, B component are uniformly mixed by preceding 1h, then impose on cement wall surface by brushing.
Made with commercially available the third exterior wall latex paint of single-component silicon to ratio, under the same terms, by commercially available the third exterior wall of single-component silicon cream
Shellac varnish imposes on cement wall surface by brushing, and is completely dried rear embodiment 4-6 and comparative example performance test data such as the following table 1.
The performance table of 1 emulsion paint of table
Embodiment and comparative example all has preferable flexibility, adhesive force, water resistance, alkali resistance as can be seen from Table 1, but
The embodiment of the present invention has higher hardness, better acid resistance, hydrophobic waterproof, UV resistant performance and better decontamination
Ability, comprehensive performance of the invention is more preferable, is more applicable for using in construction requirement height and the harsher engineering of environment.
Although the present invention has been explained in detail and has referred to embodiment, for those of ordinary skill in the art, show
Various schemes, modification and the change that can so make as specified above, should be construed as being included within the scope of the claims.
Claims (10)
1. a kind of water-proof climate resisting bi-component exterior wall latex paint, which is characterized in that it is grouped as by two groups of A, B, according to parts by weight,
Component A are as follows: 35-40 parts of water-based fluorocarbon resin dispersion, 1-5 parts of coalescing agent, 0.3-1.0 parts of levelling agent, thickener
0.1-0.3 parts, 0.5-1 parts of wetting dispersing agent, 0.25-0.30 parts of defoaming agent, 0.20-0.25 parts of fungicide, pigments and fillers 25-40
Part, 15-20 parts of water；
B component are as follows: 2-5 parts of titanate coupling agent, 1-3 parts of Perhydropolysilazane.
2. a kind of water-proof climate resisting bi-component exterior wall latex paint according to claim 1, which is characterized in that the film forming helps
Agent is 2,2,4- trimethyl -1,3- pentanediol diisobutyrate, in the different octyl ether of butanediol, tetraethylene glycol, dihydroxy n-butyl ether
It is at least one.
3. a kind of water-proof climate resisting bi-component exterior wall latex paint according to claim 1, which is characterized in that the levelling agent
For at least one of BYK-381, BYK-333, BYK-306.
4. a kind of water-proof climate resisting bi-component exterior wall latex paint according to claim 1, which is characterized in that the thickener
For carboxymethyl cellulose, hydroxyethyl cellulose, polyether system association type polyurethane rheological thickeners, nonionic polyurethane association type
At least one of thickener.
5. a kind of water-proof climate resisting bi-component exterior wall latex paint according to claim 1, which is characterized in that the wetting point
Powder is at least one of TEGO 760W, TEGO 715W, TEGO 750W, 4100 TEGO, TEGO 685.
6. a kind of water-proof climate resisting bi-component exterior wall latex paint according to claim 1, which is characterized in that the defoaming agent
For at least one of BYK-038, BYK-035, BYK-037；The fungicide is Kathon CG isothiazolinone, isothiazoline
At least one of ketone, methylisothiazolinone.
7. a kind of water-proof climate resisting bi-component exterior wall latex paint according to claim 1, which is characterized in that the pigments and fillers
For talcum powder, Cab-O-sil, mica powder, trbasic zinc phosphate, zinc molybdate, iron oxide red, aluminium triphosphate, barium metaborate, kaolin, swelling
At least one of soil, titanium-iron powder, ferrophosphorus powder, graphite powder, borax, flake asbestos, aqueous color paste.
8. a kind of water-proof climate resisting bi-component exterior wall latex paint according to claim 1, which is characterized in that the titanate esters
Coupling agent is three titanium stearate acid esters of isopropoxy, two (dioctyl pyrophosphoryl oxygroup) glycolic acid titaniums, two (dioctyl of tetra isopropyl
Phosphorous acid acyloxy) titanate esters, isopropyl three (dioctylphyrophosphoric acid acyloxy) titanate esters, triethoxy epoxyisopropyl metatitanic acid
At least one of ester.
9. a kind of water-proof climate resisting bi-component exterior wall latex paint according to claim 1, which is characterized in that in parts by weight
Meter, the water-based fluorocarbon resin dispersion are prepared by following methods:
(1) by 30-50 parts of fluorine-containing soft monomers, 10-15 parts of fluorine-containing hard monomers, 10-15 parts of hydroxypropyl acrylates, 5-10 parts of 4,4,4-
Trifluorobutene acid, 2-5 parts of initiators, 1-3 parts of mercaptoethanols are added into mixing kettle, are uniformly mixed, as dropping liquid, spare；
(2) lead under condition of nitrogen gas, 30-35 parts of amphiprotic solvents are added into reaction kettle, are then heated to 110-125 DEG C, to anti-
It answers and dropping liquid is slowly added dropwise in kettle, 4-5h is added dropwise, insulation reaction 2-3h；Then 0.2-0.5 parts of initiations are added for 110-125 DEG C
Agent continues to keep the temperature 1h；
(3) it is cooled to 50-70 DEG C, it is 8 that 10-15 parts of dimethylethanolamines are added dropwise thereto to system pH, and vacuum distillation removes molten
Agent and impurity to system quality score are greater than 85%, and it is described aqueous to get arriving that 60-90 part water high-speed stirreds emulsifications are then added
Fluorocarbon resin dispersion.
10. a kind of water-proof climate resisting bi-component exterior wall latex paint according to claim 9, which is characterized in that described is fluorine-containing
Soft monomer is at least one of seven fluorine n-pentenes, five fluorine n-butenes, 17 fluorine monooctyl ester of acrylic acid；The hard monomer is propylene
At least one of sour perfluor isobornyl thiocyanoacetate, methacrylic acid perfluor isobornyl thiocyanoacetate, pentafluorostyrene；The initiator was
Aoxidize at least one of t-butyl perbenzoate, new peroxide tert-butyl caprate, cyclohexanone peroxide；The amphiprotic solvent is
At least one of ethylene glycol monobutyl ether, ethyl alcohol, propylene glycol monobutyl ether.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811174698.3A CN109385150B (en) | 2018-10-09 | 2018-10-09 | Waterproof weather-resistant double-component exterior wall emulsion paint |
| CN202110026611.3A CN112852235B (en) | 2018-10-09 | 2018-10-09 | Aqueous fluorocarbon resin dispersion and application thereof |
| CN202110026603.9A CN112852234B (en) | 2018-10-09 | 2018-10-09 | Preparation method of waterproof weather-resistant bi-component exterior wall latex paint |
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| CN201811174698.3A CN109385150B (en) | 2018-10-09 | 2018-10-09 | Waterproof weather-resistant double-component exterior wall emulsion paint |
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| CN202110026603.9A Division CN112852234B (en) | 2018-10-09 | 2018-10-09 | Preparation method of waterproof weather-resistant bi-component exterior wall latex paint |
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| CN202110026603.9A Active CN112852234B (en) | 2018-10-09 | 2018-10-09 | Preparation method of waterproof weather-resistant bi-component exterior wall latex paint |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109575708A (en) * | 2018-12-01 | 2019-04-05 | 韶关市合众化工有限公司 | A kind of simple water-proof climate resisting two-component exterior wall latex paint of construction technology |
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Also Published As
| Publication number | Publication date |
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| CN112852235A (en) | 2021-05-28 |
| CN109385150B (en) | 2021-04-16 |
| CN112852235B (en) | 2022-08-23 |
| CN112852234B (en) | 2022-04-05 |
| CN112852234A (en) | 2021-05-28 |
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