CN109385090A - A kind of formula and its manufacturing process of oiling rolls and gathering roll - Google Patents

A kind of formula and its manufacturing process of oiling rolls and gathering roll Download PDF

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Publication number
CN109385090A
CN109385090A CN201811381529.7A CN201811381529A CN109385090A CN 109385090 A CN109385090 A CN 109385090A CN 201811381529 A CN201811381529 A CN 201811381529A CN 109385090 A CN109385090 A CN 109385090A
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parts
oiling rolls
gathering roll
ether
polyimides
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景亚宾
范文春
朱兴炜
黄美芳
施国良
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ZHEJIANG GREEN NEW MATERIALS CO Ltd
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ZHEJIANG GREEN NEW MATERIALS CO Ltd
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Priority to CN201811381529.7A priority Critical patent/CN109385090A/en
Publication of CN109385090A publication Critical patent/CN109385090A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L79/00Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
    • C08L79/04Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
    • C08L79/08Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/12Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08L27/18Homopolymers or copolymers or tetrafluoroethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/04Condensation polymers of aldehydes or ketones with phenols only
    • C08L61/16Condensation polymers of aldehydes or ketones with phenols only of ketones with phenols

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses the formulas and its manufacturing process of a kind of oiling rolls and gathering roll, a kind of formula of oiling rolls and gathering roll, according to parts by weight, the oiling rolls and gathering roll are composed of the following components: 20-80 parts of 0-30 parts of 0-30 parts of mixture, talcum powder, the fluoropolymer of 20-60 parts of graphite Gr, polyimides PI or polyether-ether-ketone PEEK or polyimides PI and polyether-ether-ketone PEEK.A kind of manufacturing process of oiling rolls and gathering roll, includes the following steps: step (1): raw material drying;Step (2): physical blending;Step (3): compression molding;Step (4): sintering;Step (5): it is machined up to oiling rolls or gathering roll.The oiling rolls of formula and manufacturing process manufacture through the invention and gathering roll have the advantages that wear-resistant, filoplume amount is light, size coating rate is high, spatter property is high, re-workability.

Description

A kind of formula and its manufacturing process of oiling rolls and gathering roll
Technical field
The present invention relates to the formulas and its manufacturing process of a kind of oiling rolls and gathering roll.
Background technique
The production technology of glass fibre mainly has crucible method and tank furnace method, and prevailing technology is tank furnace method drawing process at present, Be otherwise known as one-shot forming technique.It to be used due to glass fibre in different high molecular materials, in process of production Must be coated with different macromolecule emulsion sizes, after having coated must boundling at a branch of glass fibre, therefore in this production Glass fiber lubricator and gathering roll must be used in the process.Glass fiber lubricator is uniformly to coat glass fiber infiltration agent To a kind of equipment on glass fiber surface, it is generally mainly made of oiling rolls and oiling box etc..At present used in fiberglass industry Baster structure be mainly immersion as a result, oiling rolls are immersed in oil inlet area part, by size when oiling rolls rotate clockwise It takes up, size a part flows back into oiling box, and a part is contacted with glass fiber strand, to meet coated glass fiber Requirement.Environment in high temperature and humidity when glass-fiber industry oiling rolls work, glass fibre and size need cleanliness without any pollution, And can be recycled and utilize again, and be easy to solvent cleaning and lathe turning, on the other hand to guarantee certain lubricity to prevent glass The generation of glass fiber lousiness, while must also have certain porosity and certain surface free energy to guarantee that oiling rolls carry leaching Moisten the demand of agent oil film thickness, therefore graphite material becomes preferred material at present.But due to graphite itself can pollution And the disadvantages of not wear-resisting property, occur some leaching alloy graphite and aluminum oxide ceramic oiling roll in the market, these material tables Face is smooth, and hardness is higher, can overcome pollution of the wear particle to glass fibre, but coefficient of friction is larger, and by glass Broken end cannot be repaired after injuring by a crashing object, and wear surface makes product generate lousiness for glass fibre is cut off, while can not be added again by turning It is reused after work, therefore limits the use in fiberglass industry.
Summary of the invention
The purpose of the present invention is overcoming deficiency in the prior art, the formula and its system of a kind of oiling rolls and gathering roll are provided Make technique.
In order to achieve the above object, the present invention is achieved by the following technical solutions:
A kind of formula of oiling rolls and gathering roll, according to parts by weight, the oiling rolls and gathering roll are composed of the following components: The mixture 0-30 of 20-60 parts of graphite Gr, polyimides PI or polyether-ether-ketone PEEK or polyimides PI and polyether-ether-ketone PEEK Part, 0-30 parts of talcum powder, 20-80 parts of fluoropolymer.
Preferably, the fluoropolymer is polytetrafluoroethylene PTFE, fluorinated ethylene propylene copolymer FEP, tetrafluoro second One or more of alkene-perfluorinated alkoxy vinyl ether copolymer PFA.
Preferably, the partial size of the graphite Gr is between 15 to 45 μm.
Preferably, the partial size of polyimides PI is between 5 to 50 μm.
Preferably, the partial size of the talcum powder is between 5 to 50 μm.
Preferably, the partial size of the polyether-ether-ketone PEEK is between 5 to 50 μm.
A kind of manufacturing process of oiling rolls and gathering roll, includes the following steps:
Step (1): according to parts by weight, 20-60 parts of graphite Gr, polyimides PI or polyether-ether-ketone raw material drying: are weighed 0-30 parts of 0-30 parts of mixture, the talcum powder of PEEK or polyimides PI and polyether-ether-ketone PEEK, then exist them respectively 1-5h is dried at 120-180 DEG C, then natural cooling;
Step (2): physical blending: according to parts by weight, 20-80 parts of fluoropolymer are weighed, then by the graphite after drying 0-30 parts of the mixture of 20-60 parts of Gr, polyimides PI or polyether-ether-ketone PEEK or polyimides PI and polyether-ether-ketone PEEK, 0-30 parts of talcum powder carry out physical blending with fluoropolymer 20-80 parts in high-speed mixer, are mixed after mixing Object;
Step (3): mixture compression molding: is placed on the mold on oiling rolls moulding press or on gathering roll moulding press It is inside pressed and molded to obtain blank;
Step (4): blank sintering: is sintered to the blank sintered in sintering furnace or Muffle furnace;
Step (5): machining: the blank sintered is processed with numerically controlled lathe, then with grinding machine polish surface, So that surface roughness control is between Ra 0.2-0.6 to get oiling rolls or gathering roll.
Preferably, the temperature of the sintering is between 180-390 DEG C, the time of the sintering is between 10-36h.
Beneficial effects of the present invention are as follows: the oiling rolls of formula and manufacturing process manufacture through the invention and gathering roll tool Have the advantages of wear-resistant, filoplume amount is light, size coating rate is high, spatter property is high, re-workability, it is wear-resistant refer to oiling rolls or Gathering roll wearability is significantly better than graphite material oiling rolls or gathering roll, and without carrying out cleaning polishing daily, service life is improved 3-5 times, substantially reduce the production line amount of labour;Filoplume amount gently refers under identical working condition, oiling rolls of the invention or collection The filoplume weight of beam wheel only has the half of graphite oiling rolls/or gathering roll, reduces glass fibre fracture of wire risk, improves fiber product Quality;Size coating rate height refers to that the size coating efficiency of oiling rolls or gathering roll of the invention is high, improves size Service efficiency reduces glass fibre production cost to a certain extent;Spatter property height refers to oiling rolls or gathering roll of the invention It is less prone to picking phenomenon in use, picking is to size when thoroughly changing graphite material oiling rolls or gathering roll use Pollution, and then influence glass fiber quality;Re-workability refers to that oiling rolls or gathering roll and conventional graphite of the invention apply Oiling roller or gathering roll are identical, can arbitrarily be machined, polish.
Specific embodiment
Technical solution of the present invention is described further below:
Embodiment 1:
A kind of formula of oiling rolls and gathering roll, according to parts by weight, the oiling rolls and gathering roll are composed of the following components: The mixture 0-30 of 20-60 parts of graphite Gr, polyimides PI or polyether-ether-ketone PEEK or polyimides PI and polyether-ether-ketone PEEK Part, 0-30 parts of talcum powder, 20-80 parts of fluoropolymer.
Fluoropolymer of the invention is polytetrafluoroethylene PTFE, fluorinated ethylene propylene copolymer FEP, tetrafluoroethene-are complete One or more of Fluoroalkyloxy vinyl ether co-polymer PFA, i.e., fluoropolymer of the invention are (1) PTFE, (2) PTFE + FEP, (3) PTFE+FEP+PFA, (4) PTFE+PFA, (5) FEP, (6) FEP+PFA, (7) PFA.
The partial size of graphite Gr is between 15 to 45 μm.
The partial size of the polyimides PI is between 5 to 50 μm.
The partial size of the talcum powder is between 5 to 50 μm.
The partial size of the polyether-ether-ketone PEEK is between 5 to 50 μm.
The manufacturing process of the oiling rolls and gathering roll, includes the following steps:
Step (1): according to parts by weight, 20-60 parts of graphite Gr, polyimides PI or polyether-ether-ketone raw material drying: are weighed 0-30 parts of 0-30 parts of mixture, the talcum powder of PEEK or polyimides PI and polyether-ether-ketone PEEK, then exist them respectively 1-5h is dried at 120-180 DEG C, then natural cooling;
Step (2): physical blending: according to parts by weight, 20-80 parts of fluoropolymer are weighed, then by the graphite after drying 0-30 parts of the mixture of 20-60 parts of Gr, polyimides PI or polyether-ether-ketone PEEK or polyimides PI and polyether-ether-ketone PEEK, 0-30 parts of talcum powder carry out physical blending with fluoropolymer 20-80 parts in high-speed mixer, are mixed after mixing Object;
Step (3): mixture compression molding: is placed on the mold on oiling rolls moulding press or on gathering roll moulding press It is inside pressed and molded to obtain blank;
Step (4): blank sintering: is sintered to the blank sintered in sintering furnace or Muffle furnace;
Step (5): machining: the blank sintered is processed with numerically controlled lathe, then with grinding machine polish surface, So that surface roughness control is between Ra 0.2-0.6 to get oiling rolls or gathering roll.The temperature of sintering be 180-390 DEG C it Between, the time of the sintering is between 10-36h.
The oiling rolls and gathering roll of formula of the invention and manufacturing process manufacture are with wear-resistant, filoplume amount is light, size The advantages of coating rate is high, spatter property is high, re-workability, it is wear-resistant to refer to that oiling rolls or gathering roll wearability are significantly better than graphite Material oiling rolls or gathering roll, without carrying out cleaning polishing daily, service life improves 3-5 times, substantially reduces production line labor Momentum;Filoplume amount gently refers under identical working condition that the filoplume weight of oiling rolls of the invention or gathering roll only has graphite painting The half of oiling roller/or gathering roll reduces glass fibre fracture of wire risk, improves fiber product quality;Size coating rate height refers to It is the size coating efficiency height of oiling rolls or gathering roll of the invention, improves size service efficiency, reduce to a certain extent Glass fibre production cost;Spatter property height refers to that oiling rolls or gathering roll of the invention are less prone to picking in use Phenomenon, pollution of the picking to size when thoroughly changing graphite material oiling rolls or gathering roll use, and then influence glass fibre Quality;Re-workability refers to that oiling rolls or gathering roll of the invention are identical as conventional graphite oiling rolls or gathering roll, can be any Machining, polishing.
Embodiment 2:
A kind of formula of oiling rolls and gathering roll, according to parts by weight, the oiling rolls and gathering roll are composed of the following components: 20 parts of graphite Gr, 20 parts of fluoropolymer.
Fluoropolymer of the invention is polytetrafluoroethylene PTFE, fluorinated ethylene propylene copolymer FEP, tetrafluoroethene-are complete One or more of Fluoroalkyloxy vinyl ether co-polymer PFA, i.e., fluoropolymer of the invention are (1) PTFE, (2) PTFE + FEP, (3) PTFE+FEP+PFA, (4) PTFE+PFA, (5) FEP, (6) FEP+PFA, (7) PFA.
The manufacturing process of the oiling rolls and gathering roll, includes the following steps:
Step (1): raw material drying: according to parts by weight, 20 parts of graphite Gr is weighed, then by them respectively at 120-180 DEG C Lower dry 1-5h, then natural cooling;
Step (2): physical blending: according to parts by weight, weighing 20 parts of fluoropolymer, then by the graphite Gr after drying 20 parts carry out physical blending with 20 parts of fluoropolymer in high-speed mixer, obtain mixture after mixing;
Step (3): mixture compression molding: is placed on the mold on oiling rolls moulding press or on gathering roll moulding press It is inside pressed and molded to obtain blank;
Step (4): blank sintering: is sintered to the blank sintered in sintering furnace or Muffle furnace;
Step (5): machining: the blank sintered is processed with numerically controlled lathe, then with grinding machine polish surface, So that surface roughness control is between Ra 0.2-0.6 to get oiling rolls or gathering roll.The temperature of sintering be 180-390 DEG C it Between, the time of the sintering is between 10-36h.
The oiling rolls and gathering roll of formula of the invention and manufacturing process manufacture are with wear-resistant, filoplume amount is light, size The advantages of coating rate is high, spatter property is high, re-workability, it is wear-resistant to refer to that oiling rolls or gathering roll wearability are significantly better than graphite Material oiling rolls or gathering roll, without carrying out cleaning polishing daily, service life improves 3-5 times, substantially reduces production line labor Momentum;Filoplume amount gently refers under identical working condition that the filoplume weight of oiling rolls of the invention or gathering roll only has graphite painting The half of oiling roller/or gathering roll reduces glass fibre fracture of wire risk, improves fiber product quality;Size coating rate height refers to It is the size coating efficiency height of oiling rolls or gathering roll of the invention, improves size service efficiency, reduce to a certain extent Glass fibre production cost;Spatter property height refers to that oiling rolls or gathering roll of the invention are less prone to picking in use Phenomenon, pollution of the picking to size when thoroughly changing graphite material oiling rolls or gathering roll use, and then influence glass fibre Quality;Re-workability refers to that oiling rolls or gathering roll of the invention are identical as conventional graphite oiling rolls or gathering roll, can be any Machining, polishing.
Embodiment 3:
A kind of formula of oiling rolls and gathering roll, according to parts by weight, the oiling rolls and gathering roll are composed of the following components: 30 parts of the mixture of 60 parts of graphite Gr, polyimides PI or polyether-ether-ketone PEEK or polyimides PI and polyether-ether-ketone PEEK are slided 30 parts of mountain flour, 80 parts of fluoropolymer.
Fluoropolymer of the invention is polytetrafluoroethylene PTFE, fluorinated ethylene propylene copolymer FEP, tetrafluoroethene-are complete One or more of Fluoroalkyloxy vinyl ether co-polymer PFA, i.e., fluoropolymer of the invention are (1) PTFE, (2) PTFE + FEP, (3) PTFE+FEP+PFA, (4) PTFE+PFA, (5) FEP, (6) FEP+PFA, (7) PFA.
The partial size of graphite Gr is between 15 to 45 μm.
The partial size of the polyimides PI is between 5 to 50 μm.
The partial size of the talcum powder is between 5 to 50 μm.
The partial size of the polyether-ether-ketone PEEK is between 5 to 50 μm.
The manufacturing process of the oiling rolls and gathering roll, includes the following steps:
Step (1): according to parts by weight, 60 parts of graphite Gr, polyimides PI or polyether-ether-ketone PEEK raw material drying: are weighed Or 30 parts of 30 parts of mixture, the talcum powder of polyimides PI and polyether-ether-ketone PEEK, then by them respectively at 120-180 DEG C 1-5h is dried, then natural cooling;
Step (2): physical blending: according to parts by weight, weighing 80 parts of fluoropolymer, then by the graphite Gr after drying 30 parts of mixture, the talcum powder 30 of 60 parts, polyimides PI or polyether-ether-ketone PEEK or polyimides PI and polyether-ether-ketone PEEK Part carries out physical blending with 80 parts of fluoropolymer in high-speed mixer, obtains mixture after mixing;
Step (3): mixture compression molding: is placed on the mold on oiling rolls moulding press or on gathering roll moulding press It is inside pressed and molded to obtain blank;
Step (4): blank sintering: is sintered to the blank sintered in sintering furnace or Muffle furnace;
Step (5): machining: the blank sintered is processed with numerically controlled lathe, then with grinding machine polish surface, So that surface roughness control is between Ra 0.2-0.6 to get oiling rolls or gathering roll.The temperature of sintering be 180-390 DEG C it Between, the time of the sintering is between 10-36h.
The oiling rolls and gathering roll of formula of the invention and manufacturing process manufacture are with wear-resistant, filoplume amount is light, size The advantages of coating rate is high, spatter property is high, re-workability, it is wear-resistant to refer to that oiling rolls or gathering roll wearability are significantly better than graphite Material oiling rolls or gathering roll, without carrying out cleaning polishing daily, service life improves 3-5 times, substantially reduces production line labor Momentum;Filoplume amount gently refers under identical working condition that the filoplume weight of oiling rolls of the invention or gathering roll only has graphite painting The half of oiling roller/or gathering roll reduces glass fibre fracture of wire risk, improves fiber product quality;Size coating rate height refers to It is the size coating efficiency height of oiling rolls or gathering roll of the invention, improves size service efficiency, reduce to a certain extent Glass fibre production cost;Spatter property height refers to that oiling rolls or gathering roll of the invention are less prone to picking in use Phenomenon, pollution of the picking to size when thoroughly changing graphite material oiling rolls or gathering roll use, and then influence glass fibre Quality;Re-workability refers to that oiling rolls or gathering roll of the invention are identical as conventional graphite oiling rolls or gathering roll, can be any Machining, polishing.
Embodiment 4:
A kind of formula of oiling rolls and gathering roll, according to parts by weight, the oiling rolls and gathering roll are composed of the following components: 20 parts of the mixture of 40 parts of graphite Gr, polyimides PI or polyether-ether-ketone PEEK or polyimides PI and polyether-ether-ketone PEEK are slided 10 parts of mountain flour, 60 parts of fluoropolymer.
Fluoropolymer of the invention is polytetrafluoroethylene PTFE, fluorinated ethylene propylene copolymer FEP, tetrafluoroethene-are complete One or more of Fluoroalkyloxy vinyl ether co-polymer PFA, i.e., fluoropolymer of the invention are (1) PTFE, (2) PTFE + FEP, (3) PTFE+FEP+PFA, (4) PTFE+PFA, (5) FEP, (6) FEP+PFA, (7) PFA.
The partial size of graphite Gr is between 15 to 45 μm.
The partial size of the polyimides PI is between 5 to 50 μm.
The partial size of the talcum powder is between 5 to 50 μm.
The partial size of the polyether-ether-ketone PEEK is between 5 to 50 μm.
The manufacturing process of the oiling rolls and gathering roll, includes the following steps:
Step (1): according to parts by weight, 40 parts of graphite Gr, polyimides PI or polyether-ether-ketone PEEK raw material drying: are weighed Or 10 parts of 20 parts of mixture, the talcum powder of polyimides PI and polyether-ether-ketone PEEK, then by them respectively at 120-180 DEG C 1-5h is dried, then natural cooling;
Step (2): physical blending: according to parts by weight, weighing 60 parts of fluoropolymer, then by the graphite Gr after drying 20 parts of mixture, the talcum powder 10 of 40 parts, polyimides PI or polyether-ether-ketone PEEK or polyimides PI and polyether-ether-ketone PEEK Part carries out physical blending with 60 parts of fluoropolymer in high-speed mixer, obtains mixture after mixing;
Step (3): mixture compression molding: is placed on the mold on oiling rolls moulding press or on gathering roll moulding press It is inside pressed and molded to obtain blank;
Step (4): blank sintering: is sintered to the blank sintered in sintering furnace or Muffle furnace;
Step (5): machining: the blank sintered is processed with numerically controlled lathe, then with grinding machine polish surface, So that surface roughness control is between Ra 0.2-0.6 to get oiling rolls or gathering roll.The temperature of sintering be 180-390 DEG C it Between, the time of the sintering is between 10-36h.
The oiling rolls and gathering roll of formula of the invention and manufacturing process manufacture are with wear-resistant, filoplume amount is light, size The advantages of coating rate is high, spatter property is high, re-workability, it is wear-resistant to refer to that oiling rolls or gathering roll wearability are significantly better than graphite Material oiling rolls or gathering roll, without carrying out cleaning polishing daily, service life improves 3-5 times, substantially reduces production line labor Momentum;Filoplume amount gently refers under identical working condition that the filoplume weight of oiling rolls of the invention or gathering roll only has graphite painting The half of oiling roller/or gathering roll reduces glass fibre fracture of wire risk, improves fiber product quality;Size coating rate height refers to It is the size coating efficiency height of oiling rolls or gathering roll of the invention, improves size service efficiency, reduce to a certain extent Glass fibre production cost;Spatter property height refers to that oiling rolls or gathering roll of the invention are less prone to picking in use Phenomenon, pollution of the picking to size when thoroughly changing graphite material oiling rolls or gathering roll use, and then influence glass fibre Quality;Re-workability refers to that oiling rolls or gathering roll of the invention are identical as conventional graphite oiling rolls or gathering roll, can be any Machining, polishing.
It should be noted that listed above is only a kind of specific embodiment of the invention.It is clear that the invention is not restricted to Upper embodiment, can also be there are many deforming, in short, those skilled in the art can directly lead from present disclosure Out or all deformations for associating, it is considered as protection scope of the present invention.

Claims (8)

1. the formula of a kind of oiling rolls and gathering roll, which is characterized in that according to parts by weight, the oiling rolls and gathering roll are by following Group is grouped as: 20-60 parts of graphite Gr, polyimides PI or polyether-ether-ketone PEEK or polyimides PI and polyether-ether-ketone PEEK's 0-30 parts of mixture, 0-30 parts of talcum powder, 20-80 parts of fluoropolymer.
2. the formula of a kind of oiling rolls and gathering roll according to claim 1, which is characterized in that the fluoropolymer is poly- In tetrafluoroethene PTFE, fluorinated ethylene propylene copolymer FEP, tetrafluoroethene-perfluorinated alkoxy vinyl ether copolymer PFA It is one or more of.
3. the formula of a kind of oiling rolls and gathering roll according to claim 1, which is characterized in that the partial size of the graphite Gr exists Between 15 to 45 μm.
4. the formula of a kind of oiling rolls and gathering roll according to claim 1, which is characterized in that the grain of the polyimides PI Diameter is between 5 to 50 μm.
5. the formula of a kind of oiling rolls and gathering roll according to claim 1, which is characterized in that the partial size of the talcum powder exists Between 5 to 50 μm.
6. the formula of a kind of oiling rolls and gathering roll according to claim 1, which is characterized in that the polyether-ether-ketone PEEK's Partial size is between 5 to 50 μm.
7. a kind of manufacturing process of oiling rolls and gathering roll according to claim 1, which comprises the steps of:
Step (1): raw material drying: according to parts by weight, weigh 20-60 parts of graphite Gr, polyimides PI or polyether-ether-ketone PEEK or 0-30 parts of 0-30 parts of mixture, the talcum powder of polyimides PI and polyether-ether-ketone PEEK, then by them respectively at 120-180 DEG C Lower dry 1-5h, then natural cooling;
Step (2): physical blending: according to parts by weight, weighing 20-80 parts of fluoropolymer, then by the graphite Gr after drying 0-30 parts of mixture, the talcum of 20-60 parts, polyimides PI or polyether-ether-ketone PEEK or polyimides PI and polyether-ether-ketone PEEK 0-30 parts of powder carry out physical blending with fluoropolymer 20-80 parts in high-speed mixer, obtain mixture after mixing;
Step (3): compression molding: by mixture be placed in the mold on oiling rolls moulding press or on gathering roll moulding press into Row compression molding obtains blank;
Step (4): blank sintering: is sintered to the blank sintered in sintering furnace or Muffle furnace;
Step (5): machining: the blank sintered is processed with numerically controlled lathe, then with grinding machine polish surface so that Surface roughness control is between Ra 0.2-0.6 to get oiling rolls or gathering roll.
8. the manufacturing process of oiling rolls and gathering roll according to claim 7, which is characterized in that the temperature of the sintering is Between 180-390 DEG C, the time of the sintering is between 10-36h.
CN201811381529.7A 2018-11-20 2018-11-20 A kind of formula and its manufacturing process of oiling rolls and gathering roll Pending CN109385090A (en)

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Cited By (2)

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Publication number Priority date Publication date Assignee Title
CN109593306A (en) * 2018-11-20 2019-04-09 浙江巨化新材料研究院有限公司 One kind being used for coated glass fiber beaming device PTFE material and preparation method
CN112429979A (en) * 2020-12-18 2021-03-02 江苏长海复合材料股份有限公司 Direct yarn process for nylon fabric

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