CN109384323A - A kind for the treatment of process of breeding wastewater - Google Patents
A kind for the treatment of process of breeding wastewater Download PDFInfo
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- CN109384323A CN109384323A CN201811339906.0A CN201811339906A CN109384323A CN 109384323 A CN109384323 A CN 109384323A CN 201811339906 A CN201811339906 A CN 201811339906A CN 109384323 A CN109384323 A CN 109384323A
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F3/00—Fertilisers from human or animal excrements, e.g. manure
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F7/00—Fertilisers from waste water, sewage sludge, sea slime, ooze or similar masses
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/001—Processes for the treatment of water whereby the filtration technique is of importance
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
- C02F1/441—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
- C02F1/444—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by ultrafiltration or microfiltration
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F2001/007—Processes including a sedimentation step
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/20—Nature of the water, waste water, sewage or sludge to be treated from animal husbandry
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2301/00—General aspects of water treatment
- C02F2301/08—Multistage treatments, e.g. repetition of the same process step under different conditions
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
- Y02A40/20—Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Hydrology & Water Resources (AREA)
- Water Supply & Treatment (AREA)
- Fertilizers (AREA)
- Treatment Of Sludge (AREA)
Abstract
The present invention discloses a kind for the treatment of process of breeding wastewater, waste water is collected storage, it is not easy to precipitate by waste water flowing by spiral agitator, waste water is uniformly successively introduced to inclined wire formula reciprocating sieve, multi-stage absorption sedimentation basin, disc type multilayer reciprocating sieve, fine filter tank, bag filter, ultrafiltration apparatus and HCNS film condensing device.The dry matter that separating dry space from moist space obtains carries out fermentation process as organic fertilizer raw material, and the clear water that film is concentrated to get can be used as recirculated water use, and another part concentrate is packaged into Liquid Fertilizer after processing.Entire process flow is easy to operate, and automatic management may be implemented in integration linkage.And clear water stable effluent quality meets national " animal husbandry pollutant emission standard " (GB18256-2001) discharge standard;In technique of the invention, all generation wastes are all focused on and resource utilization.
Description
Technical field
The present invention relates to technical field of sewage more particularly to a kind for the treatment of process of breeding wastewater.
Background technique
China's scale in recent years, intensive livestock and poultry breeding industry flourish, and modernize case type large-scale cultivation skill
Art promotes the livestock and poultry breeding industry in China city to high-quality and efficient development, and the following livestock breeding wastewater discharge amount is also presented
Increase trend year by year, causes the environmental pollutions such as serious soil, water source and air pollution to area.Since China is to pork
Preference, the quantity on pig farm and larger, Wastewater from Pig Farm discharge amount account for the half of livestock and poultry farm wastewater emission amount with
On.Wastewater from Pig Farm high organic content, CODcr are up to 4000~8000mg/L, and BOD5 is up to 1500~6000mg/L, ammonia nitrogen
At concentrations up to 800~1500mg/L, also has the characteristics that antibiotic and pathogen residual, such as handle not in time, not only pollution week
Collarette border also directly affects the health and epidemic prevention on pig farm itself, and the sound development that will restrict entire pig-breeding industry.Pig farm
If waste water treatment process using Anaerobic Microbiological Treatment Technology, its advantage is that can organic pollutant in efficient degradation water, but
It is difficult to remove the ammonia nitrogen in waste water.Denitrogenation generally comprises three ammonification, nitrification, denitrification processes, and heterotrophic bacterium handle had before this
Machine nitrogen is converted into ammoniacal nitrogen, and ammoniacal nitrogen is nitrite nitrogen nitrogen by autotrophic type oxidation by nitrobacteria, and nitrite nitrogen is nitrified by autotrophic type again
Bacterium is oxidized to nitrate nitrogen, and nitrite nitrogen and nitrate-nitrogen reduction are that gaseous nitrogen is removed from sewage by last heterotroph denitrifying bacterium.
However there are following contradictions for biological denitrification process: nitrifier is stringent aerobic bacteria, and nitration reaction needs aerobic environment, and denitrification
Bacterium is facultative anaerobic bacteria, needs to carry out under anaerobic environment.Therefore, livestock and poultry breeding industry ammonia nitrogen in waste water is difficult qualified discharge.
The prior art uses flocculation treatment usually in separating dry space from moist space, and polyacrylamide is added in aquaculture wastewater and gathers
Close the chemical flocs substances such as aluminium chloride.The sewage changed different for concentration, can not accurately control the addition of flocculant
Amount, while the residual volume of flocculant excessive inside liquid can cause fouling membrane to ultrafiltration below and reverse osmosis treatment, furthermore
There are a large amount of flocculant in organic excrement dry matter that separating dry space from moist space obtains, slow down the fermentation process of excrement, while to soil
Improvement hundred evil and none is sharp.And the polypropylene milling amine of high concentration is the agent of nerve intoxicating, is had damage to nervous system.
Summary of the invention
In view of the above-mentioned problems, the present invention provides a kind for the treatment of process of breeding wastewater, the treatment process first by waste water into
Row collect storage, by spiral agitator by waste water flowing be not easy to precipitate, by waste water uniformly successively introduce inclined wire formula reciprocating sieve,
Multi-stage absorption sedimentation basin, disc type multilayer reciprocating sieve, fine filter tank, bag filter, ultrafiltration apparatus and HCNS film concentration dress
It sets.The dry matter that wherein separating dry space from moist space obtains carries out fermentation process as organic fertilizer raw material, and the clear water that film is concentrated to get can be used as
Recirculated water uses, and another part concentrate is packaged into Liquid Fertilizer after processing.Entire process flow is easy to operate, integration connection
It is dynamic, automatic management may be implemented.And clear water stable effluent quality meets national " animal husbandry pollutant emission standard "
(GB18256-2001) discharge standard;All generation wastes all obtain centralized processing and recycling benefit in technique of the invention
With.
In order to achieve the above objectives, the specific technical proposal of the invention is: a kind for the treatment of process of breeding wastewater, including it is as follows
Step:
(1) store collected: the collection of bubble excrement is stored in former manure pit, and spiral agitator is installed in former manure pit by precipitating
Excrement slag stirs evenly;
(2) primary filter: doing primary filter for being introduced into inclined wire formula reciprocating sieve by the bubble excrement stored in step (1),
The dry matter excrement slag being obtained by filtration and filtrate, wherein as the raw material for making organic fertilizer, be used as after pretreatment has dry matter excrement slag
Machine fertilizer raw material is sent into organic ferment tank processing, and the filtrate being obtained by filtration is placed in multi-stage absorption sedimentation basin;
(3) multi-stage absorption sedimentation basin: will introduce multi-stage absorption sedimentation basin by the filtrate that step (2) primary filter obtains,
Multiple sedimentation basins with adsorbent equipment are flowed through, the supernatant liquor of sedimentation basin is introduced into transition storage pool, and lower sediment thing introduces
Inclined wire formula reciprocating sieve does primary filter again;
(4) secondary filtration: the supernatant obtained by step (3) is introduced into disc type multilayer reciprocating sieve and does second level mistake
Filter, raw material of the dry matter excrement slag being obtained by filtration as production organic fertilizer, is sent into organic hair as organic fertilizer raw material after pretreatment
Fermenting pot processing, the liquid being obtained by filtration are placed in secondary filtration filtrate storage pool;(5) three-stage filtration: step (4) will be passed through
The filtrate that secondary filtration obtains is introduced into capillary bag filtering ponds, and the filtrate being obtained by filtration is placed in three-stage filtration filtrate holding vessel,
Solid filter residue does resource utilization;
(6) bag type filtering: the filtrate obtained by step 5 three-stage filtration being introduced into bag type filtering tank and is further filtered,
The liquid being obtained by filtration is placed in bag type filtering filtrate holding vessel;
(7) ultrafiltration: the filtrate obtained by step 6 is introduced into ultrafiltration apparatus, during the filtration clear liquid being obtained by filtration is discharged into
Between store in water tank;Concentrated liquid fertilizer is packaged into after the processing of partial concentration liquid.
(8) HCNS film is concentrated: the filtration clear liquid obtained by step 7 is introduced HCNS film condensing device by intermediate water tank
In, it is reverse osmosis to obtain 3/4 circulation clear water, recycle clear water COD be less than 50mg/L, ammonia nitrogen be less than 40mg/L can qualified discharge,
It can be used in pasture as recirculated water, remaining 1/4 concentrate is packaged into concentrated liquid fertilizer after the processing such as high temperature sterilization.
Preferably, the filter bag of step (6) the bag type filtering tank is 240-1000 mesh.
Preferably, pretreated organic fertilizer raw material is sent into organic ferment tank processing, fermentation in the step (2)
Good pig manure can be used as organic fertilizer or be carbonized to obtain charcoal recycling into retort.
The present invention has the advantage that 1, bubble excrement is collected storage, by spiral agitator by breeding wastewater stream
It is dynamic to be not easy to precipitate, waste water is uniformly successively introduced inclined wire formula reciprocating sieve, multi-stage absorption sedimentation basin, disc type multilayer reciprocating sieve,
Fine filter tank, bag filter, ultrafiltration apparatus and HCNS film condensing device, the dry matter that separating dry space from moist space obtains is as organic fertilizer
Raw material carries out fermentation process, and the clear water that film is concentrated to get can be used as recirculated water use, and another part concentrate is packed after processing
At Liquid Fertilizer.Entire process flow is easy to operate, and automatic management may be implemented, and clear water effluent quality is steady in integration linkage
Surely meet national " animal husbandry pollutant emission standard " (GB18256-2001) discharge standard;2, in technique of the invention not
The chemical flocs substance such as polyacrylamide and aluminium polychloride is added, the excessive flocculant in liquid the inside simultaneously is avoided
Residual volume can cause fouling membrane to ultrafiltration below and reverse osmosis treatment, furthermore in the obtained organic excrement dry matter of separating dry space from moist space
It is additive-free, it can be used as the raw material of production organic fertilizer;3, the generation waste in technique of the invention all focused on and
Resource utilization.
Specific embodiment
Example 1: a kind for the treatment of process of breeding wastewater includes the following steps:
(1) store collected: the collection of bubble excrement is stored in former manure pit, and spiral agitator is installed in former manure pit by precipitating
Excrement slag stirs evenly;The COD of former liquid dung is 8264mg/L, ammonia nitrogen 657mg/L;
(2) primary filter: doing primary filter for being introduced into inclined wire formula reciprocating sieve by the bubble excrement stored in step (1),
The dry matter excrement slag being obtained by filtration and filtrate, wherein as the raw material for making organic fertilizer, be used as after pretreatment has dry matter excrement slag
Machine fertilizer raw material is sent into organic ferment tank processing, and the filtrate being obtained by filtration is placed in multi-stage absorption sedimentation basin;
(3) multi-stage absorption sedimentation basin: will introduce multi-stage absorption sedimentation basin by the filtrate that step (2) primary filter obtains,
Multiple sedimentation basins with adsorbent equipment are flowed through, the supernatant liquor of sedimentation basin is introduced into transition storage pool, and lower sediment thing introduces
Inclined wire formula reciprocating sieve does primary filter again;
(4) secondary filtration: the supernatant obtained by step (3) is introduced into disc type multilayer reciprocating sieve and does second level mistake
Filter, raw material of the dry matter excrement slag being obtained by filtration as production organic fertilizer, is sent into organic hair as organic fertilizer raw material after pretreatment
Fermenting pot processing, the liquid being obtained by filtration are placed in secondary filtration filtrate storage pool;
(5) three-stage filtration: the filtrate obtained by step (4) secondary filtration is introduced into capillary bag filtering ponds, is filtered
To filtrate be placed in three-stage filtration filtrate holding vessel, solid filter residue does resource utilization;
(6) bag type filtering: the filtrate obtained by step 5 three-stage filtration being introduced into bag type filtering tank and is further filtered,
The liquid being obtained by filtration is placed in bag type filtering filtrate holding vessel, and wherein the filter bag of bag type filtering tank is 640 mesh;
(7) ultrafiltration: the filtrate obtained by step 6 is introduced into ultrafiltration apparatus, during the filtration clear liquid being obtained by filtration is discharged into
Between store in water tank;Concentrated liquid fertilizer is packaged into after the processing of partial concentration liquid.
(8) HCNS film is concentrated: the cleaner liquid of crossing obtained by step 7 is introduced HCNS film condensing device by intermediate water tank
In, reverse osmosis to obtain 3/4 circulation clear water, the COD for recycling clear water is 32mg/L, ammonia nitrogen be 27mg/L can qualified discharge, can also be
It is used in pasture as recirculated water, remaining 1/4 concentrate is packaged into concentrated liquid fertilizer after the processing such as high temperature sterilization.
Waste water is collected storage first by treatment process of the present invention, is not easy to sink by waste water flowing by spiral agitator
It forms sediment, waste water is uniformly successively introduced to inclined wire formula reciprocating sieve, multi-stage absorption sedimentation basin, disc type multilayer reciprocating sieve, fine filter tank, bag
Formula filter, ultrafiltration apparatus and HCNS film condensing device.The dry matter that separating dry space from moist space obtains is sent out as organic fertilizer raw material
Ferment processing, the clear water that film is concentrated to get can be used as recirculated water use, and another part concentrate is packaged into Liquid Fertilizer after processing.It is whole
A process flow is easy to operate, and automatic management may be implemented in integration linkage.And clear water stable effluent quality meets country
" animal husbandry pollutant emission standard " (GB18256-2001) discharge standard;In technique of the invention, all generations are useless
Gurry is all focused on and resource utilization.
It is that the description of example has been carried out to the present invention above, it is clear that the implementation of the present invention is not limited by the above manner,
As long as using the various improvement that technical solution of the present invention carries out, or not improved that conception and technical scheme of the invention are direct
Applied to other occasions, all fall in the scope of protection of the present invention.
Claims (3)
1. a kind for the treatment of process of breeding wastewater, which comprises the steps of:
(1) store collected: the collection of bubble excrement is stored in former manure pit, and spiral agitator is installed in former manure pit by the excrement slag of precipitating
It stirs evenly;
(2) primary filter: primary filter is done by being introduced into inclined wire formula reciprocating sieve by the bubble excrement stored in step (1), is filtered
Obtained dry matter excrement slag and filtrate, wherein raw material of the dry matter excrement slag as production organic fertilizer, is used as organic fertilizer after pretreatment
Raw material is sent into organic ferment tank processing, and the filtrate being obtained by filtration is placed in multi-stage absorption sedimentation basin;
(3) multi-stage absorption sedimentation basin: multi-stage absorption sedimentation basin will be introduced by the filtrate that step (2) primary filter obtains, flowed through
Multiple sedimentation basins with adsorbent equipment, the supernatant liquor of sedimentation basin are introduced into transition storage pool, and lower sediment thing introduces inclined wire
Formula reciprocating sieve does primary filter again;
(4) secondary filtration: the supernatant obtained by step (3) being introduced into disc type multilayer reciprocating sieve and does secondary filtration,
Raw material of the dry matter excrement slag being obtained by filtration as production organic fertilizer, is sent into organic fermentor as organic fertilizer raw material after pretreatment
Fermentation process, the liquid being obtained by filtration are placed in secondary filtration filtrate storage pool;
(5) three-stage filtration: the filtrate obtained by step (4) secondary filtration is introduced into capillary bag filtering ponds, is obtained by filtration
Filtrate is placed in three-stage filtration filtrate holding vessel, and solid filter residue does resource utilization;
(6) bag type filtering: the filtrate obtained by step 5 three-stage filtration being introduced into bag type filtering tank and is further filtered, and is filtered
Obtained liquid is placed in bag type filtering filtrate holding vessel;
(7) ultrafiltration: the filtrate obtained by step 6 is introduced into ultrafiltration apparatus, the filtration clear liquid being obtained by filtration is discharged into intermediate water
It is stored in case, concentrated liquid fertilizer is packaged into after the processing of partial concentration liquid;
(8) HCNS film is concentrated: the filtration clear liquid obtained by step 7 being introduced into HCNS film condensing device by intermediate water tank, instead
3/4 obtained circulation clear water is permeated up to mark discharge, can also be used in pasture as recirculated water, remaining 1/4 concentrate is through height
Concentrated liquid fertilizer is packaged into after the processing such as temperature sterilization.
2. a kind for the treatment of process of breeding wastewater according to claim 1, which is characterized in that step (6) the pocket type mistake
The filter bag of filter tank is 240-1000 mesh.
3. a kind for the treatment of process of breeding wastewater according to claim 1, which is characterized in that locate in advance in the step (2)
Organic fertilizer raw material after reason is sent into organic ferment tank processing, and the pig manure fermented can be used as organic fertilizer or enter retort
Carbonization obtains charcoal recycling.
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CN201811339906.0A CN109384323A (en) | 2018-11-12 | 2018-11-12 | A kind for the treatment of process of breeding wastewater |
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CN201811339906.0A CN109384323A (en) | 2018-11-12 | 2018-11-12 | A kind for the treatment of process of breeding wastewater |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110550787A (en) * | 2019-08-20 | 2019-12-10 | 生态环境部华南环境科学研究所 | Desalting treatment equipment and method for fertilizer utilization of cow breeding wastewater |
CN112225621A (en) * | 2020-11-11 | 2021-01-15 | 中国农业科学院农业资源与农业区划研究所 | Method for treating livestock and poultry waste and utilizing fertilizer-based resources |
WO2022052356A1 (en) * | 2020-09-11 | 2022-03-17 | 山东理工职业学院 | Hepa filter applied to industrial circulating water treatment |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110550787A (en) * | 2019-08-20 | 2019-12-10 | 生态环境部华南环境科学研究所 | Desalting treatment equipment and method for fertilizer utilization of cow breeding wastewater |
WO2022052356A1 (en) * | 2020-09-11 | 2022-03-17 | 山东理工职业学院 | Hepa filter applied to industrial circulating water treatment |
CN112225621A (en) * | 2020-11-11 | 2021-01-15 | 中国农业科学院农业资源与农业区划研究所 | Method for treating livestock and poultry waste and utilizing fertilizer-based resources |
CN112225621B (en) * | 2020-11-11 | 2022-05-03 | 中国农业科学院农业资源与农业区划研究所 | Method for treating livestock and poultry waste and utilizing fertilizer-based resources |
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