CN109374732A - Tomography escapes the portable quick hydrogen-measuring apparatus of gas and its monitoring method - Google Patents

Tomography escapes the portable quick hydrogen-measuring apparatus of gas and its monitoring method Download PDF

Info

Publication number
CN109374732A
CN109374732A CN201810926066.1A CN201810926066A CN109374732A CN 109374732 A CN109374732 A CN 109374732A CN 201810926066 A CN201810926066 A CN 201810926066A CN 109374732 A CN109374732 A CN 109374732A
Authority
CN
China
Prior art keywords
hydrogen
gas
circuit
quartz crystal
sensitive film
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201810926066.1A
Other languages
Chinese (zh)
Other versions
CN109374732B (en
Inventor
何镧
刘佳琪
王成宇
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hangzhou Chao Ju Technology Co Ltd
Original Assignee
Hangzhou Chao Ju Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hangzhou Chao Ju Technology Co Ltd filed Critical Hangzhou Chao Ju Technology Co Ltd
Priority to CN201810926066.1A priority Critical patent/CN109374732B/en
Publication of CN109374732A publication Critical patent/CN109374732A/en
Application granted granted Critical
Publication of CN109374732B publication Critical patent/CN109374732B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N29/00Investigating or analysing materials by the use of ultrasonic, sonic or infrasonic waves; Visualisation of the interior of objects by transmitting ultrasonic or sonic waves through the object
    • G01N29/02Analysing fluids
    • G01N29/036Analysing fluids by measuring frequency or resonance of acoustic waves
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N2291/00Indexing codes associated with group G01N29/00
    • G01N2291/01Indexing codes associated with the measuring variable
    • G01N2291/014Resonance or resonant frequency
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N2291/00Indexing codes associated with group G01N29/00
    • G01N2291/02Indexing codes associated with the analysed material
    • G01N2291/021Gases

Landscapes

  • Physics & Mathematics (AREA)
  • Acoustics & Sound (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Investigating Or Analyzing Materials By The Use Of Fluid Adsorption Or Reactions (AREA)
  • Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)
  • Investigating Or Analyzing Materials By The Use Of Ultrasonic Waves (AREA)

Abstract

The present invention relates to a kind of portable quick hydrogen-measuring apparatus of tomography evolution gas and its monitoring methods.Hydrogen-measuring apparatus includes the first air inlet, the second air inlet, gas outlet, three-way magnetic valve, speed regulation air pump, quartz crystal oscillator hydrogen sensitive film sensor, oxygen carrier clarifier and control circuit;First air inlet is connected with a bite of three-way magnetic valve, and two mouthfuls of three-way magnetic valve, speed regulation air pump, quartz crystal oscillator hydrogen sensitive film sensor and gas outlet pass sequentially through pipeline and be connected;Second air inlet is connected with the import of oxygen carrier clarifier, and the outlet of oxygen carrier clarifier is connected with three mouthfuls of three-way magnetic valve, and three-way magnetic valve, speed regulation air pump and quartz crystal oscillator hydrogen sensitive film sensor are connected with control circuit respectively.The present invention is reduced the influence of interference gas, improves the accuracy of measurement by being measured based on surface acoustic wave sensing technology to density of hydrogen.Measurement gas circuit and purification gas circuit are switched over by automatically controlling, and highly shortened the measurement recovery time of device, improve observed efficiency.

Description

Tomography escapes the portable quick hydrogen-measuring apparatus of gas and its monitoring method
Technical field
The present invention relates to a kind of hydrogen detection device more particularly to a kind of tomography portable quick hydrogen-measuring apparatus of evolution gas and Its monitoring method, the field movable suitable for earthquake fault exploration and mine prospection detect.
Background technique
Density of hydrogen in the earth's crust is higher by thousands of, tens of thousands of or even hundreds of thousands times than the density of hydrogen in atmosphere.In the earth's crust Hydrogen is mainly derived from biological chemistry action and chemical action, therefore in oil-and-gas basin, tectinic mobile belt, geothermal area and volcanic rock Area can find the higher hydrogen source of concentration.Research shows that hydrogen is power actuated in close relations with the earth's crust now, especially It is stored with seismic activity, coal mine in close relations.Pass through the variation of detection density of hydrogen, especially detection tomography fluid in earth's surface The concentration for overflowing hydrogen in gas, can not only find tomography crustal motion active regions as earthquake precursor observation point, Er Qieke Using the effective means as expiloration of coal mines, oil field prospecting.
Domestic External Observation density of hydrogen mainly uses thermal conductivity detector (TCD) gas chromatograph, but its sensitivity is lower, detection Limit generally 10 × 10-6(10ppm), and the background value of hydrogen is 0.5ppm in soil, therefore, this detection device is not able to satisfy The needs of formation gas detection.The sensitivity usually with higher of the hydrogen sensor of semi-conductor type and lower detection limit, but In the quickly hydrogen of continuous measurement higher concentration, sensor is easy to appear of short duration intoxicating phenomenon, influences measurement efficiency, and mesh The preceding hydrogen meter both at home and abroad based on semi-conductor type is chiefly used in Laboratory Observation.In addition, either chromatograph or semiconductor pass Sensor, when detection, are required to through gas-chromatography post separation gas, but the use of chromatographic column need certain temperature and flow velocity and With lossy, especially when alkanes gas content is higher in detection gas, the anti-interference of the quick detection method of these hydrogen compared with Difference.Therefore, existing hydrogen meter can not be used for quickly detecting density of hydrogen in tomography evolution gas in field, be unable to satisfy field The demand of mobile detection.
Summary of the invention
In order to solve the above-mentioned technical problem the present invention, provides a kind of portable quick hydrogen-measuring apparatus of tomography evolution gas and its prison Survey method realizes continuous quick in situ measurement, and hydrogen gas sensor anti-interference used is good, and measuring range is big, and detection limit is low, from It is dynamic to complete measurement and purification, accelerate the resume speed of hydrogen gas sensor, improves measuring accuracy.
Above-mentioned technical problem of the invention is mainly to be addressed by following technical proposals: tomography evolution of the invention The portable quick hydrogen-measuring apparatus of gas, including the first air inlet, the second air inlet, gas outlet, three-way magnetic valve, speed regulation air pump, stone English crystal oscillator hydrogen sensitive film sensor, oxygen carrier clarifier and control circuit;First air inlet is connected with a bite of three-way magnetic valve, and three Two mouthfuls of three-way electromagnetic valve, speed regulation air pump, quartz crystal oscillator hydrogen sensitive film sensor and gas outlet pass sequentially through pipeline and are connected;Second into Port is connected with the import of oxygen carrier clarifier, and the outlet of oxygen carrier clarifier is connected with three mouthfuls of three-way magnetic valve, three-way magnetic valve, Speed regulation air pump and quartz crystal oscillator hydrogen sensitive film sensor are connected with the control circuit respectively.Control circuit controls threeway electromagnetism The conducting direction of valve realizes measurement gas circuit and purifies the switching of gas circuit, and control circuit controls the work of speed regulation air pump, by speed regulation gas The flow velocity of gas in pump control gas circuit.When a bite of three-way magnetic valve and two mouthfuls of conductings, the first air inlet, three-way magnetic valve, tune Fast air pump, quartz crystal oscillator hydrogen sensitive film sensor and gas outlet are linked to be measurement gas circuit;Three mouthfuls of three-way magnetic valve and two mouthfuls conductings When, the second air inlet, oxygen carrier clarifier, three-way magnetic valve, speed regulation air pump, quartz crystal oscillator hydrogen sensitive film sensor and gas outlet connect At purification gas circuit.When measurement, sample gas enters the first air inlet of device, is input to quartz-crystal through three-way magnetic valve, speed regulation air pump Shake hydrogen sensitive film sensor, and quartz crystal oscillator hydrogen sensitive film sensor is detected the density of hydrogen in sample gas and conveyed with digital signal To control circuit, control circuit is handled, and shows the density of hydrogen measured by display screen, and by storage chip store to Movable storage device, residual gas are discharged through the gas outlet of device.It is measured, to improve sensor resume speed, purified gas Road is started to work, and air is flowed into from the second air inlet of device, through oxygen carrier clarifier dehydrogenation oxygen carrier, by three-way magnetic valve, is adjusted Fast air pump is input to quartz crystal oscillator hydrogen sensitive film sensor, replaces the indoor residual gas of sensor gas, and make the oxygen in air Ion reacts the hydrogen molecule adsorbed in release film with hydrogen sensitive film, and the gas containing hydrogen molecule is discharged through the gas outlet of device. It adjusts the speed air pump and adjusts the supply voltage for adjusting air pump according to the measuring command or cleaning command of control circuit by PWM, further The gas production flow of air pump is adjusted, to meet measurement, purification demand.The technical program reduces the hardware of device using air pump is adjusted Setting, reduces the volume and power consumption of device, meets the requirement of portable, low-power consumption, small size.The technical program is using quartz Crystal oscillator hydrogen sensitive film sensor measurement hydrogen, fast response time, high sensitivity and strong interference immunity, measuring range is big, detection limit It is low.Hydrogen-measuring apparatus uses binary channels gas circuit, utilizes the absorption in purification gas circuit Rapid Cleaning quartz crystal oscillator hydrogen sensitive film sensor Hydrogen and residual hydrogen, increase substantially the resume speed of sensor, realize quickly continuous measurement and analysis.Meet field pair Density of hydrogen is used for quickly detecting, moves the demand of detection in tomography evolution gas.
Preferably, the quartz crystal oscillator hydrogen sensitive film sensor includes the cylinder housing to form cylindrical body gas chamber, The side of cylinder housing is equipped with the sensor import of the setting substantially symmetrical about its central axis of cylinder housing and sensor outlet, cylinder One end face of body shell body is equipped with quartz crystal, and the center of quartz crystal is connected with first electrode, cylinder housing Another end face is equipped with the induction resonance piece that surface is coated with hydrogen sensitive film, and the edge for incuding resonance piece is connected with second electrode, First electrode, second electrode are connected with the control circuit respectively.Quartz crystal oscillator hydrogen sensitive film sensor is according to hydrogen and its He in the velocity of sound there is this characteristic of the difference of highly significant to pass through quartz crystal using surface acoustic wave sensing technology by gas The induction resonance piece that caused oscillation causes surface to be coated with hydrogen sensitive film resonates, and resonance piece is incuded after hydrogen sensitive film adsorbed hydrogen Frequency of oscillation can change, i.e. the variation of the frequency of oscillation of induction resonance piece reflects the density of hydrogen in sample gas, pass through survey The frequency variation of amount induction resonance piece is to obtain the density of hydrogen in tested gas.Quartz crystal oscillator hydrogen sensitive film sensor uses Micro-electronic mechanical skill is prepared.The electrode of quartz crystal uses parallel field excitation, and vibration, sense are generated under voltage signal Answer resonance piece that the variation of resonance frequency is transmitted to control circuit by electrode.Caused by the technical program passes through quartz crystal Oscillation causes surface to be coated with the induction resonance piece resonance of hydrogen sensitive film, so that density of hydrogen is measured, fast response time, sensitivity Height, strong interference immunity.
Preferably, the quartz crystal, induction resonance piece are circular piezoelectric vibrator, it is plated in induction resonance piece table The hydrogen sensitive film in face is that is prepare using sol-gal process adulterate the tungstic acid microporous membrane of palladium particle, in tungstic acid micropore Supported palladium particle.
Preferably, the quartz crystal oscillator hydrogen sensitive film sensor includes signal processing circuit, signal processing circuit packet Crystal oscillating circuit and frequency detection circuit are included, the quartz crystal is connected by first electrode with crystal oscillating circuit, The induction resonance piece is connected by second electrode with frequency detection circuit, crystal oscillating circuit, frequency detection circuit difference It is connected with the governor circuit.Crystal oscillating circuit uses parallel connection type feed circuit, and DC energy is converted into required oscillation The AC energy of frequency.Resonance piece will be incuded as positive feedback unit and access frequency detection circuit, frequency detection circuit detection sense The frequency of resonance piece is answered to change, the signal measured is conveyed to control circuit.
Preferably, being equipped with temperature sensor, temperature sensor and institute in the quartz crystal oscillator hydrogen sensitive film sensor The control circuit stated is connected.The indoor temperature change of temperature sensor real-time monitoring quartz crystal oscillator hydrogen sensitive film sensor gas is surveyed The temperature value obtained is conveyed to control circuit and is handled, by control circuit that collected temperature value and the temperature-compensating prestored is electric Pressure is compared, and temperature-compensated voltage data are returned to the temperature-compensating that crystal oscillating circuit realizes frequency by calculating, are disappeared Except oscillatory drift caused by temperature.
Preferably, the oxygen carrier clarifier includes tubular shell, the both ends of tubular shell be respectively equipped with clarifier into Mouth, clarifier outlet, tubular shell is interior to be equipped with hydrophobic filter membrane, and the centre of hydrophobic filter membrane is equipped with porous composite reactive carbon fiber The inner surface load of dimension, hole has oxonium ion.
Preferably, the control circuit includes signal processing circuit, frequency differential circuit, low-pass filtering amplification electricity Road, A/D conversion circuit, microprocessor unit, driving unit and man-machine interaction unit and for entire hydrogen-measuring apparatus provide work electricity The power supply unit of pressure, the quartz crystal oscillator hydrogen sensitive film sensor are connected with signal processing circuit, signal processing circuit, frequency Difference channel, low-pass filtering amplifying circuit, A/D conversion circuit and microprocessor unit are sequentially connected, signal processing circuit, driving Unit, man-machine interaction unit are connected with microprocessor unit respectively, driving unit respectively with the three-way magnetic valve, speed regulation gas Pump is connected.Signal processing circuit can be set to belong to control circuit, may be set to be and belongs to quartz crystal oscillator hydrogen sensitive film biography Sensor.Man-machine interaction unit includes liquid crystal display and multiple keys.Staff passes through the work by key assignments hydrogen-measuring apparatus State, microprocessor unit realize measurement gas circuit by the conducting direction that driving unit controls three-way magnetic valve and purify gas circuit Switching, microprocessor unit control the work of speed regulation air pump by driving unit, by the stream of gas in speed regulation air pump control gas circuit Speed, microprocessor unit control the frequency of oscillation of crystal oscillating circuit, and frequency detection circuit obtains the oscillation frequency of induction resonance piece Rate is conveyed to frequency differential circuit, then the amplification and the conversion of A/D conversion circuit of low-pass filtered amplifying circuit, finally conveys To microprocessor unit, is handled, shown and stored by microprocessor unit.Microprocessor unit passes through spi bus or IIC Bus is communicated with other modules, the work of the entire hydrogen-measuring apparatus of coordinated control.
The monitoring method of the tomography evolution portable quick hydrogen-measuring apparatus of gas of the invention are as follows: first air inlet, three Three-way electromagnetic valve, speed regulation air pump, quartz crystal oscillator hydrogen sensitive film sensor and gas outlet are linked to be measurement gas circuit, second air inlet Mouth, oxygen carrier clarifier, three-way magnetic valve, speed regulation air pump, quartz crystal oscillator hydrogen sensitive film sensor and gas outlet are linked to be purification gas circuit; The conducting direction of the control circuit control three-way magnetic valve realizes measurement gas circuit and purifies the switching of gas circuit, control circuit control The work of system speed regulation air pump controls the flow velocity of gas in gas circuit, the output of quartz crystal oscillator hydrogen sensitive film sensor by speed regulation air pump Transducing signal be conveyed to the control circuit, handled, shown and stored by control circuit;When measurement, gas circuit is measured Work, sample gas make sample gas with fixation through the first air inlet and three-way magnetic valve flow direction speed regulation air pump under the control of speed regulation air pump Flow velocity enters quartz crystal oscillator hydrogen sensitive film sensor, then flows out through quartz crystal oscillator hydrogen sensitive film sensor from gas outlet, quartz-crystal Vibration hydrogen sensitive film sensor output reflects the hydrogen transducing signal of density of hydrogen in sample gas and hydrogen transducing signal is conveyed to institute The control circuit stated;When purification, purification gas circuit work, air flows into oxygen carrier clarifier through the second air inlet, and purified device purifies, So that oxygen-enriched few hydrogen in air, the air of oxygen-enriched few hydrogen flows to speed regulation air pump through three-way magnetic valve, under the control of speed regulation air pump Air is set to enter quartz crystal oscillator hydrogen sensitive film sensor with fixed flow rate, quartz crystal oscillator hydrogen sensitive film sensor, which quickly absorbs oxygen, to be released Hydrogen release, achievees the purpose that purification, and residual gas is flowed out through quartz crystal oscillator hydrogen sensitive film sensor from gas outlet again.The technical program Using quartz crystal oscillator hydrogen sensitive film sensor measurement hydrogen, fast response time, high sensitivity and strong interference immunity, measuring range Greatly, detection limit is low.Hydrogen-measuring apparatus uses binary channels gas circuit, utilizes purification gas circuit Rapid Cleaning quartz crystal oscillator hydrogen sensitive film sensor The hydrogen and residual hydrogen of interior absorption, increase substantially the resume speed of sensor, realize quickly continuous measurement and analysis.It is full Sufficient field is used for quickly detecting, moves the demand of detection to density of hydrogen in tomography evolution gas.
Preferably, the quartz crystal oscillator hydrogen sensitive film sensor includes the cylinder housing to form cylindrical body gas chamber, The side of cylinder housing is equipped with the sensor import of the setting substantially symmetrical about its central axis of cylinder housing and sensor outlet, cylinder One end face of body shell body is equipped with quartz crystal, and the center of quartz crystal is connected with first electrode, cylinder housing Another end face is equipped with induction resonance piece, and the edge for incuding resonance piece is connected with second electrode;The tomography evolution gas is just Taking the quick hydrogen-measuring apparatus of formula includes the signal processing circuit being made of crystal oscillating circuit and frequency detection circuit, quartz crystal It is connected by first electrode with crystal oscillating circuit, induction resonance piece is connected by second electrode with frequency detection circuit, crystal Oscillating circuit, frequency detection circuit are connected with the control circuit respectively;The monitoring method includes: by crystal oscillation electricity Road controls the frequency of oscillation of quartz crystal, and the induction resonance piece that the oscillation of quartz crystal causes surface to be coated with hydrogen sensitive film is total It shakes, the frequency of oscillation that resonance piece is incuded after hydrogen sensitive film adsorbed hydrogen can change, that is, incude the frequency of oscillation of resonance piece Variation reflects the density of hydrogen in sample gas, and the frequency of oscillation of induction resonance piece is measured by frequency detection circuit, and is conveyed to Control circuit is handled and is calculated through control circuit, obtains the density of hydrogen in sample gas.The electrode of quartz crystal uses parallel field Excitation generates vibration under voltage signal, incudes resonance piece by electrode and the variation of resonance frequency is transmitted to control circuit.This Technical solution is resonated by the induction resonance piece that oscillation caused by quartz crystal causes surface to be coated with hydrogen sensitive film, to measure Density of hydrogen out, fast response time, high sensitivity, strong interference immunity.
Preferably, being equipped with temperature sensor, temperature sensor and the control circuit in the cylinder case body It is connected;The monitoring method includes: crystal oscillating circuit using parallel connection type feed circuit, and DC energy is converted into required vibration The AC energy for swinging frequency is conveyed to quartz crystal, and frequency of oscillation is eliminated using temperature-compensation method and made an uproar caused by temperature drift Sound is gone out the temperature of quartz crystal by temperature sensor measurement, and collected temperature value is transferred to control circuit, by controlling Collected temperature value and the temperature-compensated voltage prestored are compared circuit, are returned temperature-compensated voltage data by calculating The temperature-compensating of frequency is realized back to crystal oscillating circuit.The influence for reducing temperature, improves the reliability and accuracy of measurement.
The beneficial effects of the present invention are: utilizing the velocity of sound and other gases of hydrogen by being based on surface acoustic wave sensing technology The velocity of sound differ biggish principle, density of hydrogen is measured, the influence of interference gas is reduced, improves the accuracy of measurement, Measuring range is big, and detection limit is low.With measurement gas circuit and purification gas circuit, two gas circuits are switched over by automatically controlling, operation side Just, gas phase splitter is not used, the measurement response time is improved, purification gas circuit completes cleaning function, helps hydrogen gas sensor fast Quick-recovery highly shortened the measurement recovery time of device, improve observed efficiency.Realize field to hydrogen in tomography evolution gas Concentration is used for quickly detecting, and meets the needs of field movable detection.
Detailed description of the invention
Fig. 1 is a kind of attachment structure schematic diagram of the invention.
Fig. 2 is a kind of structural schematic diagram of quartz crystal oscillator hydrogen sensitive film sensor in the present invention.
Fig. 3 is a kind of circuit theory connection block diagram of control circuit in the present invention.
1. first air inlet in figure, 2. second air inlets, 3. gas outlets, 4. three-way magnetic valves, 5. speed regulation air pumps, 6. quartz Crystal oscillator hydrogen sensitive film sensor, 7. oxygen carrier clarifiers, 8. control circuits, 9. cylinder housing, 10. signal processing circuits, 11. pass Sensor import, 12. sensor outlets, 13. quartz crystals, 14. first electrodes, 15. induction resonance pieces, 16. second electrodes, 17. temperature sensor, 18. crystal oscillating circuits, 19. frequency detection circuits, 20. frequency differential circuits, the amplification of 21. low-pass filtering Circuit, 22.A/D conversion circuit, 23. microprocessor units, 24. driving units, 25. man-machine interaction units, 26. power supply units.
Specific embodiment
Below with reference to the embodiments and with reference to the accompanying drawing the technical solutions of the present invention will be further described.
Embodiment: the tomography of the present embodiment escapes the portable quick hydrogen-measuring apparatus of gas, as shown in Figure 1, including the first air inlet The 1, second air inlet 2 of mouth, gas outlet 3, three-way magnetic valve 4, speed regulation air pump 5, quartz crystal oscillator hydrogen sensitive film sensor 6, oxygen carrier are net Change device 7 and control circuit 8.First air inlet is connected with a bite of three-way magnetic valve, two mouthfuls of three-way magnetic valve, speed regulation air pump, Quartz crystal oscillator hydrogen sensitive film sensor and gas outlet pass sequentially through pipeline and are connected;The import phase of second air inlet and oxygen carrier clarifier Even, the outlet of oxygen carrier clarifier is connected with three mouthfuls of three-way magnetic valve.When a bite of three-way magnetic valve and two mouthfuls of conductings, first into Port, three-way magnetic valve, speed regulation air pump, quartz crystal oscillator hydrogen sensitive film sensor and gas outlet are linked to be measurement gas circuit;Threeway electromagnetism When three mouthfuls of valve and two mouthfuls conductings, the second air inlet, oxygen carrier clarifier, three-way magnetic valve, speed regulation air pump, quartz crystal oscillator hydrogen are quick thin Film sensors and gas outlet are linked to be purification gas circuit.Oxygen carrier clarifier includes the tubular shell made of PA tube, caliber 12mm, Pipe range 50mm, the both ends of tubular shell are respectively clarifier import, clarifier outlet, and tubular shell is provided with hydrophobic filter membrane, dredges The centre of water filter membrane is composite reactive carbon fiber, and fibre diameter 0.5mm, the porous aperture of fiber is 5 μm, internal surface of hole activation Modified load oxonium ion.
As shown in Fig. 2, quartz crystal oscillator hydrogen sensitive film sensor 6 is prepared using MEMS technology, it is a kind of miniature hydrogen Sensor, including formed cylindrical body gas chamber cylinder housing 9 and signal processing circuit 10, cylindrical body gas chamber be diameter 15mm, The cylindrical body of length 8mm, the side of cylinder housing are provided with using the central axis of cylinder housing as the symmetrically arranged biography of symmetry axis The aperture of sensor import 11 and sensor outlet 12, sensor import and sensor outlet is 2mm.One end of cylinder housing Quartz crystal 13 is housed, the center of quartz crystal is connected with first electrode 14, and quartz crystal uses circular piezoelectric on face Oscillator, with a thickness of 0.5~0.8mm, the section AT, fundamental frequency is 30~40MHz;Surface is housed on another end face of cylinder housing It is coated with the induction resonance piece 15 of hydrogen sensitive film, the edge for incuding resonance piece is connected with second electrode 16, and induction resonance piece also uses Circular piezoelectric vibrator, substrate is identical with quartz crystal, and the hydrogen sensitive film for being plated in induction resonance piece surface is doping palladium particle Tungstic acid microporous membrane, is prepared using sol-gal process, tungstic acid partial size 10nm, micropore size 0.3nm, and tungstic acid is micro- Supported palladium particle in hole, hydrogen sensitive film diameter 10mm, with a thickness of 1500nm.Temperature sensor 17 is installed in cylinder case body. Signal processing circuit includes crystal oscillating circuit 18 and frequency detection circuit 19, and quartz crystal is shaken by first electrode and crystal It swings circuit to be connected, induction resonance piece is connected by second electrode with frequency detection circuit.
As shown in figure 3, control circuit 8 includes frequency differential circuit 20, low-pass filtering amplifying circuit 21, A/D conversion circuit 22, microprocessor unit 23, driving unit 24 and man-machine interaction unit 25 and the electricity of operating voltage is provided for entire hydrogen-measuring apparatus Source unit 26, driving unit, man-machine interaction unit are connected with microprocessor unit respectively, and man-machine interaction unit includes liquid crystal display Screen and multiple keys, driving unit are connected with three-way magnetic valve, speed regulation air pump respectively.Microprocessor unit and crystal oscillating circuit It is connected, crystal oscillating circuit, frequency detection circuit are connected with frequency differential circuit respectively, and frequency differential circuit is again and low-pass filtering Amplifying circuit is connected, and low-pass filtering amplifying circuit is connected with A/D conversion circuit again, and A/D conversion circuit is again and microprocessor unit It is connected.Temperature sensor is also connected with microprocessor unit.The electrode of quartz crystal uses parallel field excitation when measurement, in electricity It presses and generates vibration under 3~5mV of signal, incude resonance piece by electrode and the variation of resonance frequency is transmitted to signal processing. The detection sensitivity of quartz crystal oscillator hydrogen sensitive film sensor is less than 0.5ppb/Hz, response time 10s.
The monitoring method of the above-mentioned tomography evolution portable quick hydrogen-measuring apparatus of gas are as follows: staff is by surveying hydrogen by key assignments The working condition of device, microprocessor unit by driving unit control three-way magnetic valve conducting direction realize measurement gas circuit and The switching of gas circuit is purified, microprocessor unit controls the work of speed regulation air pump by driving unit, controls gas circuit by speed regulation air pump The flow velocity of middle gas, microprocessor unit control the frequency of oscillation of crystal oscillating circuit, and frequency detection circuit obtains induction resonance The frequency of oscillation of piece is conveyed to frequency differential circuit, then low-pass filtered amplifying circuit and A/D conversion circuit, is finally conveyed to Microprocessor unit is handled by microprocessor unit, shown and is stored;Microprocessor unit is total by spi bus or IIC Line is communicated with other modules, the entire hydrogen-measuring apparatus of coordinated control;
When measurement, measurement gas circuit work, sample gas is through the first air inlet and three-way magnetic valve flow direction speed regulation air pump, in speed regulation gas Sample gas is set to enter quartz crystal oscillator hydrogen sensitive film sensor with 200~230ml/min fixed flow rate under the control of pump, it is ensured that sensor Response time it is most short, crystal oscillating circuit control quartz crystal frequency of oscillation, crystal oscillating circuit using parallel connection type it is anti- The AC energy that DC energy is converted into required frequency of oscillation is conveyed to quartz crystal by current feed circuit, and frequency of oscillation is using temperature It spends compensation method and eliminates noise caused by temperature drift, the temperature of quartz crystal is gone out by temperature sensor measurement, and will acquisition To temperature value be transferred to microprocessor unit, by microprocessor unit by collected temperature value and prestore temperature-compensating electricity Pressure is compared, and temperature-compensated voltage data is returned to crystal oscillating circuit by calculating, and by crystal oscillating circuit Varactor realize that the temperature-compensating of frequency of oscillation, the oscillation of quartz crystal cause surface to be coated with the induction of hydrogen sensitive film Resonance piece resonates, and the frequency of oscillation that resonance piece is incuded after hydrogen sensitive film adsorbed hydrogen can change, that is, incudes the vibration of resonance piece The variation for swinging frequency reflects density of hydrogen in sample gas, will induction resonance piece it is electric as positive feedback unit access frequency detecting Road, by frequency detection circuit measure induction resonance piece frequency of oscillation, the frequency differential circuit being conveyed in control circuit, then Low-pass filtered amplifying circuit and A/D conversion circuit, are finally conveyed to microprocessor unit, are carried out by microprocessor unit Reason, display and storage, obtain the density of hydrogen in sample gas, and residual gas is flowed through quartz crystal oscillator hydrogen sensitive film sensor from gas outlet Out;
When purification, purification gas circuit work, air flows into oxygen carrier clarifier through the second air inlet, and purified device purifies, so that Oxonium ion increases in air, hydrogen molecule is reduced, and the air of oxygen-enriched few hydrogen flows to speed regulation air pump through three-way magnetic valve, in speed regulation gas Air is set to enter quartz crystal oscillator hydrogen sensitive film sensor with 50~60ml/min fixed flow rate under the control of pump, hydrogen sensitive film is quick Oxygen evolution hydrogen is absorbed, the gas in sensor is replaced rapidly, achievees the purpose that purification, residual gas is quick from quartz crystal oscillator hydrogen The sensor outlet of thin film sensor flows out, and finally flows out from gas outlet.
Microprocessor unit as information processing centre and monitoring center, mainly using powerful data-handling capacity and Control ability come realize system critical data processing and other modules real-time control, be mainly responsible for control instruction transmission, The receiving processing of data.Microprocessor unit uses single-chip microcontroller and field programmable gate array (FPGA) for kernel control chip reality Now to the acquisition of data and the control of each module.In device operational process, to avoid microprocessor unit from program deadlock occur Or phenomena such as flying is run, tracked by vibration frequency and output frequency of the FPGA to quartz crystal oscillator hydrogen sensitive film sensor, Adjustment is carried out, to the output of power supply unit to the flow control stability that three-way magnetic valve unlatches and closes the time and adjusts the speed air pump Voltage carries out detection and carries out adjustment to the timing and acquisition rate of man-machine interaction unit.
Man-machine interaction unit mainly includes the mobile memory interface of LCD liquid crystal display, film key and USB.The display of data And the input of human-computer interaction instruction is realized by display screen and film key, in the operation of other modules of device, first keeps in people The instruction of machine interaction, when microprocessor unit has operational requirements, then carries out data readback, is transmitted to microprocessor unit progress It executes;When microprocessor unit handles the measurement data of sensor well, chip is controlled by USB and directly sends data to shifting Dynamic storage equipment stores immediately.
According to hydrogen-measuring apparatus use environment, rechargeable type, replaceable lithium electricity of the power supply unit using high capacity small size Pond can continuously power 8 hours as power supply, lithium battery capacity 1000mAh.By integrated power supply regulated converter part, 12V DC voltage is converted into+3V ,+5V and -10V DC voltage, supplies electricity to corresponding module respectively.To guarantee hydrogen-measuring apparatus Low power capabilities, power supply unit maintains electric current using the shutdown of 20 μ A static working currents and 1 μ A, and carries out under-voltage to battery Monitoring, once cell voltage is lower than threshold voltage, microprocessor unit can monitor immediately, and battery low-electricity quantity signal is transmitted To LCD display, the prompt of battery capacity deficiency is carried out.

Claims (10)

1. a kind of tomography escapes the portable quick hydrogen-measuring apparatus of gas, it is characterised in that including the first air inlet, the second air inlet, go out Port, three-way magnetic valve, speed regulation air pump, quartz crystal oscillator hydrogen sensitive film sensor, oxygen carrier clarifier and control circuit;First air inlet Mouthful be connected with a bite of three-way magnetic valve, two mouthfuls of three-way magnetic valve, adjust the speed air pump, quartz crystal oscillator hydrogen sensitive film sensor and out Port passes sequentially through pipeline and is connected;Second air inlet is connected with the import of oxygen carrier clarifier, the outlet and threeway of oxygen carrier clarifier Three mouthfuls of solenoid valve are connected, three-way magnetic valve, speed regulation air pump and quartz crystal oscillator hydrogen sensitive film sensor respectively with the control Circuit is connected.
2. tomography according to claim 1 escapes the portable quick hydrogen-measuring apparatus of gas, it is characterised in that the quartz-crystal Vibration hydrogen sensitive film sensor includes the cylinder housing to form cylindrical body gas chamber, and the side of cylinder housing is equipped with cylinder case One end face of the sensor import of the setting substantially symmetrical about its central axis of body and sensor outlet, cylinder housing is equipped with quartz crystal oscillator Piece, the center of quartz crystal are connected with first electrode, another end face of cylinder housing is equipped with surface, and to be coated with hydrogen quick thin The induction resonance piece of film, the edge for incuding resonance piece are connected with second electrode, first electrode, second electrode respectively with the control Circuit processed is connected.
3. tomography according to claim 2 escapes the portable quick hydrogen-measuring apparatus of gas, it is characterised in that the quartz-crystal Vibration piece, induction resonance piece are circular piezoelectric vibrator, and the hydrogen sensitive film for being plated in induction resonance piece surface is using sol-gal process The tungstic acid microporous membrane of the doping palladium particle of preparation, supported palladium particle in tungstic acid micropore.
4. tomography according to claim 2 or 3 escapes the portable quick hydrogen-measuring apparatus of gas, it is characterised in that the quartz Crystal oscillator hydrogen sensitive film sensor includes signal processing circuit, and signal processing circuit includes crystal oscillating circuit and frequency detecting electricity Road, the quartz crystal are connected by first electrode with crystal oscillating circuit, and the induction resonance piece passes through the second electricity Pole is connected with frequency detection circuit, and crystal oscillating circuit, frequency detection circuit are connected with the governor circuit respectively.
5. tomography according to claim 1 or 2 or 3 escapes the portable quick hydrogen-measuring apparatus of gas, it is characterised in that described Temperature sensor is equipped in quartz crystal oscillator hydrogen sensitive film sensor, temperature sensor is connected with the control circuit.
6. tomography according to claim 1 or 2 escapes the portable quick hydrogen-measuring apparatus of gas, it is characterised in that the oxygen carrier Clarifier includes tubular shell, and the both ends of tubular shell are respectively equipped with clarifier import, clarifier outlet, are equipped in tubular shell Hydrophobic filter membrane, the centre of hydrophobic filter membrane, which is equipped with, has porous composite reactive carbon fiber, and the inner surface load in hole has oxonium ion.
7. tomography according to claim 1 or 2 or 3 escapes the portable quick hydrogen-measuring apparatus of gas, it is characterised in that described Control circuit includes signal processing circuit, frequency differential circuit, low-pass filtering amplifying circuit, A/D conversion circuit, microprocessor list Member, driving unit and man-machine interaction unit and the power supply unit of operating voltage, the quartz-crystal are provided for entire hydrogen-measuring apparatus Vibration hydrogen sensitive film sensor is connected with signal processing circuit, signal processing circuit, frequency differential circuit, low-pass filtering amplification electricity Road, A/D conversion circuit and microprocessor unit are sequentially connected, signal processing circuit, driving unit, man-machine interaction unit respectively and Microprocessor unit is connected, and driving unit is connected with the three-way magnetic valve, speed regulation air pump respectively.
8. a kind of monitoring method of the tomography evolution portable quick hydrogen-measuring apparatus of gas as described in claim 1, it is characterised in that First air inlet, three-way magnetic valve, speed regulation air pump, quartz crystal oscillator hydrogen sensitive film sensor and the gas outlet is linked to be measurement gas Road, second air inlet, three-way magnetic valve, adjust the speed air pump, quartz crystal oscillator hydrogen sensitive film sensor and go out oxygen carrier clarifier Port is linked to be purification gas circuit;The conducting direction of the control circuit control three-way magnetic valve realizes measurement gas circuit and purification gas circuit Switching, control circuit control speed regulation air pump work, pass through speed regulation air pump control gas circuit in gas flow velocity, quartz crystal oscillator hydrogen The transducing signal of sensitive film sensor output is conveyed to the control circuit, is handled, shown and is stored by control circuit; When measurement, measurement gas circuit work, sample gas is through the first air inlet and three-way magnetic valve flow direction speed regulation air pump, in the control of speed regulation air pump Under so that sample gas is entered quartz crystal oscillator hydrogen sensitive film sensor with fixed flow rate, then through quartz crystal oscillator hydrogen sensitive film sensor from outlet Mouth outflow, the output of quartz crystal oscillator hydrogen sensitive film sensor reflect the hydrogen transducing signal of density of hydrogen in sample gas and sense hydrogen Signal is conveyed to the control circuit;When purification, purification gas circuit work, air flows into oxygen carrier clarifier through the second air inlet, Purified device purification, so that oxygen-enriched few hydrogen in air, the air of oxygen-enriched few hydrogen flow to speed regulation air pump through three-way magnetic valve, adjusting the speed Air is set to enter quartz crystal oscillator hydrogen sensitive film sensor, quartz crystal oscillator hydrogen sensitive film sensor with fixed flow rate under the control of air pump Oxygen evolution hydrogen is quickly absorbed, achievees the purpose that purification, residual gas is flowed through quartz crystal oscillator hydrogen sensitive film sensor from gas outlet again Out.
9. the monitoring method of the tomography evolution portable quick hydrogen-measuring apparatus of gas according to claim 8, it is characterised in that institute The quartz crystal oscillator hydrogen sensitive film sensor stated includes the cylinder housing to form cylindrical body gas chamber, and the side of cylinder housing is equipped with With the sensor import of the setting substantially symmetrical about its central axis of cylinder housing and sensor outlet, set on an end face of cylinder housing There is quartz crystal, the center of quartz crystal is connected with first electrode, another end face of cylinder housing is equipped with induction Resonance piece, the edge for incuding resonance piece are connected with second electrode;The tomography escapes the portable quick hydrogen-measuring apparatus of gas The signal processing circuit being made of crystal oscillating circuit and frequency detection circuit, quartz crystal are shaken by first electrode and crystal It swings circuit to be connected, induction resonance piece is connected by second electrode with frequency detection circuit, crystal oscillating circuit, frequency detection circuit It is connected respectively with the control circuit;The monitoring method includes: by the vibration of crystal oscillating circuit control quartz crystal Frequency is swung, the induction resonance piece that the oscillation of quartz crystal causes surface to be coated with hydrogen sensitive film resonates, hydrogen sensitive film adsorbed hydrogen The frequency of oscillation for incuding resonance piece afterwards can change, i.e. the variation of the frequency of oscillation of induction resonance piece reflects the hydrogen in sample gas Gas concentration, the frequency of oscillation of induction resonance piece is measured by frequency detection circuit, and is conveyed to control circuit, at control circuit Reason and calculating, obtain the density of hydrogen in sample gas.
10. the monitoring method of the tomography evolution portable quick hydrogen-measuring apparatus of gas according to claim 9, it is characterised in that institute Temperature sensor is equipped in the cylinder case body stated, temperature sensor is connected with the control circuit;The monitoring method It include: crystal oscillating circuit using parallel connection type feed circuit, the AC energy that DC energy is converted into required frequency of oscillation is defeated Quartz crystal is given, frequency of oscillation is eliminated noise caused by temperature drift using temperature-compensation method, surveyed by temperature sensor The temperature of quartz crystal is measured, and collected temperature value is transferred to control circuit, by control circuit by collected temperature Angle value and the temperature-compensated voltage prestored are compared, and temperature-compensated voltage data are returned to crystal oscillating circuit by calculating Realize the temperature-compensating of frequency.
CN201810926066.1A 2018-08-14 2018-08-14 Portable rapid hydrogen measuring device for fault escape gas and monitoring method thereof Active CN109374732B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810926066.1A CN109374732B (en) 2018-08-14 2018-08-14 Portable rapid hydrogen measuring device for fault escape gas and monitoring method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810926066.1A CN109374732B (en) 2018-08-14 2018-08-14 Portable rapid hydrogen measuring device for fault escape gas and monitoring method thereof

Publications (2)

Publication Number Publication Date
CN109374732A true CN109374732A (en) 2019-02-22
CN109374732B CN109374732B (en) 2022-01-04

Family

ID=65404487

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810926066.1A Active CN109374732B (en) 2018-08-14 2018-08-14 Portable rapid hydrogen measuring device for fault escape gas and monitoring method thereof

Country Status (1)

Country Link
CN (1) CN109374732B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111398518A (en) * 2019-10-16 2020-07-10 杭州超钜科技有限公司 Gas flux continuous measurement system and measurement method thereof
CN114355433A (en) * 2022-03-18 2022-04-15 中创智科(绵阳)科技有限公司 Method for measuring response time of air tritium concentration rapid detector

Citations (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1570612A (en) * 2004-05-10 2005-01-26 西安交通大学 Multichannel rapid evaluating device for photolysis hydrogen making catalyst performance
WO2006078229A1 (en) * 2004-10-17 2006-07-27 Board Of Regents Of The University And Community College System Of Nevada Self-sensing array of microcantilevers for chemical detection
CN101539633A (en) * 2009-04-29 2009-09-23 杭州超距科技有限公司 Online automatic monitoring device for hydrogen of earthquake precursor
CN102539082A (en) * 2010-12-17 2012-07-04 阿迪森真空产品公司 Device and method for detecting leaks using hydrogen as a tracer gas
CN106342210B (en) * 2009-12-31 2013-08-28 中国船舶重工集团公司第七一八研究所 A kind of for measuring the sampling analytical system of concentration of hydrogen in containment vessel
JP5388253B1 (en) * 2013-03-26 2014-01-15 克巳 奈良▲崎▼ Odor sensor device
CN204129035U (en) * 2014-09-18 2015-01-28 中宜环科仪器江苏有限公司 A kind of portable gas-sensitive type ammonia nitrogen determination instrument
CN104655587A (en) * 2015-02-14 2015-05-27 合肥知常光电科技有限公司 Extra-high sensitive gas absorption spectrum measuring system and method based on MEMS
EP2972293A1 (en) * 2013-03-15 2016-01-20 The Government of the United States of America, as represented by the Secretary of the Navy Gas chromatographic "in column" spectroscopic analysis
CN107101951A (en) * 2017-05-07 2017-08-29 东北大学 It is a kind of to be used for the fibre optical sensor of density of hydrogen and temperature simultaneously measuring
CN107192791A (en) * 2017-05-16 2017-09-22 湖北锐意自控系统有限公司 A kind of gas analyzing apparatus and method
CN107402188A (en) * 2017-06-07 2017-11-28 杭州电子科技大学 The continuous on-line monitoring system of underground fluid carbon dioxide and monitoring method
CN107941787A (en) * 2017-11-02 2018-04-20 中山大学 Hydrogen gas sensor and preparation method thereof, the method for realizing hydrogen detection
CN108169294A (en) * 2018-02-12 2018-06-15 中国工程物理研究院总体工程研究所 Film hydrogen gas sensor with self-heating and temperature compensation function
US20180196012A1 (en) * 2016-12-13 2018-07-12 Pendar Technologies Llc Devices and methods for quartz enhanced photoacoustic spectroscopy

Patent Citations (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1570612A (en) * 2004-05-10 2005-01-26 西安交通大学 Multichannel rapid evaluating device for photolysis hydrogen making catalyst performance
WO2006078229A1 (en) * 2004-10-17 2006-07-27 Board Of Regents Of The University And Community College System Of Nevada Self-sensing array of microcantilevers for chemical detection
CN101539633A (en) * 2009-04-29 2009-09-23 杭州超距科技有限公司 Online automatic monitoring device for hydrogen of earthquake precursor
CN106342210B (en) * 2009-12-31 2013-08-28 中国船舶重工集团公司第七一八研究所 A kind of for measuring the sampling analytical system of concentration of hydrogen in containment vessel
CN102539082A (en) * 2010-12-17 2012-07-04 阿迪森真空产品公司 Device and method for detecting leaks using hydrogen as a tracer gas
EP2972293A1 (en) * 2013-03-15 2016-01-20 The Government of the United States of America, as represented by the Secretary of the Navy Gas chromatographic "in column" spectroscopic analysis
JP5388253B1 (en) * 2013-03-26 2014-01-15 克巳 奈良▲崎▼ Odor sensor device
CN204129035U (en) * 2014-09-18 2015-01-28 中宜环科仪器江苏有限公司 A kind of portable gas-sensitive type ammonia nitrogen determination instrument
CN104655587A (en) * 2015-02-14 2015-05-27 合肥知常光电科技有限公司 Extra-high sensitive gas absorption spectrum measuring system and method based on MEMS
US20180196012A1 (en) * 2016-12-13 2018-07-12 Pendar Technologies Llc Devices and methods for quartz enhanced photoacoustic spectroscopy
CN107101951A (en) * 2017-05-07 2017-08-29 东北大学 It is a kind of to be used for the fibre optical sensor of density of hydrogen and temperature simultaneously measuring
CN107192791A (en) * 2017-05-16 2017-09-22 湖北锐意自控系统有限公司 A kind of gas analyzing apparatus and method
CN107402188A (en) * 2017-06-07 2017-11-28 杭州电子科技大学 The continuous on-line monitoring system of underground fluid carbon dioxide and monitoring method
CN107941787A (en) * 2017-11-02 2018-04-20 中山大学 Hydrogen gas sensor and preparation method thereof, the method for realizing hydrogen detection
CN108169294A (en) * 2018-02-12 2018-06-15 中国工程物理研究院总体工程研究所 Film hydrogen gas sensor with self-heating and temperature compensation function

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
杨迁: "基于超声谐振腔的氢气检测系统研究与设计", 《中国优秀硕士学位论文全文数据库 信息科技辑》 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111398518A (en) * 2019-10-16 2020-07-10 杭州超钜科技有限公司 Gas flux continuous measurement system and measurement method thereof
CN114355433A (en) * 2022-03-18 2022-04-15 中创智科(绵阳)科技有限公司 Method for measuring response time of air tritium concentration rapid detector

Also Published As

Publication number Publication date
CN109374732B (en) 2022-01-04

Similar Documents

Publication Publication Date Title
CN109374732A (en) Tomography escapes the portable quick hydrogen-measuring apparatus of gas and its monitoring method
Konash et al. Piezoelectric crystals as detectors in liquid chromatography
CN100489518C (en) Portable gas chromatograph used for analyzing trace organics in environmental gas
CN107389387B (en) Portable trace mercury analyzer
CN208580064U (en) A kind of tomography evolution portable quick hydrogen-measuring apparatus of gas
CN102928257A (en) Hierarchical collection device of suspended matters of natural water body, and collection method of hierarchical collection device
CN109682861A (en) A kind of multi-parameter water-quality remotely monitors and water quality remote control medicine adding platform
CN105021493B (en) A kind of absorption analysis method and device of multicomponent gas
CN101799485B (en) Core holder and zeta electric potential measuring system and method using same
KR20170098878A (en) Acoustic perfusion devices
CN113155664B (en) High-sensitivity weak gas detection device and detection method thereof
CN109387540A (en) The continuous on-line monitoring system of helium and its monitoring method
CN212341013U (en) Automatic sample introduction device of solution cathode glow discharge spectrum detection system
CN202033263U (en) Miniature detection cell for quartz crystal microbalance
CN208399243U (en) A kind of Handheld detection device of quick detection elements mercury
CN109115871B (en) Handheld elemental mercury rapid detection equipment and detection method
CN203861692U (en) Medical infusion bottle infusion monitoring system
CN103808768B (en) The on-the-spot mercury vapour detection system of earthquake precursors and mercury vapour detection method thereof
JP2003149150A (en) Method and device for measuring methane dissolved in liquid
CN101548893B (en) Integrated device for abstracting, collecting, transporting and measuring trace tissue fluid
CN109164004A (en) Porous particle specific surface area characterization sensor and method based on BET gravimetric method
CN212722834U (en) High-precision low-power water quality online analyzer
CN205449888U (en) Hydrogen gas detection surveys system
CN103940769A (en) Flume experiment method for transporting colloid in underflow band
CN112798711A (en) Portable helium analyzer and detection method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant