CN109371488A - A kind of modified superelevation strength polypropylene industrial yarn - Google Patents

A kind of modified superelevation strength polypropylene industrial yarn Download PDF

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Publication number
CN109371488A
CN109371488A CN201810977058.XA CN201810977058A CN109371488A CN 109371488 A CN109371488 A CN 109371488A CN 201810977058 A CN201810977058 A CN 201810977058A CN 109371488 A CN109371488 A CN 109371488A
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CN
China
Prior art keywords
industrial yarn
melt
plastic melt
polypropylene industrial
strength polypropylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810977058.XA
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Chinese (zh)
Inventor
罗碧莲
银将
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Shanghai Jinci Industrial Co Ltd
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Shanghai Jinci Industrial Co Ltd
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Priority to CN201810977058.XA priority Critical patent/CN109371488A/en
Publication of CN109371488A publication Critical patent/CN109371488A/en
Pending legal-status Critical Current

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    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/44Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/46Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D1/00Treatment of filament-forming or like material
    • D01D1/06Feeding liquid to the spinning head
    • D01D1/065Addition and mixing of substances to the spinning solution or to the melt; Homogenising
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/07Addition of substances to the spinning solution or to the melt for making fire- or flame-proof filaments
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Artificial Filaments (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention discloses a kind of modified superelevation strength polypropylene industrial yarns, its raw material includes: flame-proof material powder according to mass fraction, plastic melt, powdered whiting 15-25%, surface modifier 1.5-2.5%, dispersing agent 2.5-5.0%, lubricant 1.0-1.5%, linear low density polyethylene 1.0-2.0%, toughening material 10-20%, nanometer calcium carbonate 50-60%, take powdered whiting 15-25% respectively first, surface modifier 1.5-2.5%, dispersing agent 2.5-5.0%, lubricant 1.0-1.5%, linear low density polyethylene 1.0-2.0%, toughening material 10-20%, the raw materials such as nanometer calcium carbonate 50-60% are sequentially placed on weigher and weigh, weighing terminates, it is related to polypropylene industrial yarn skill Art field.The modification superelevation strength polypropylene industrial yarn, using flame-proof material powder, plastic melt, the anti-flammability for greatly strengthening master batch, the use of powdered whiting, surface modifier, dispersing agent, lubricant, linear low density polyethylene, toughening material, nanometer calcium carbonate has greatly reinforced the modification superhigh intensity of polypropylene industrial yarn.

Description

A kind of modified superelevation strength polypropylene industrial yarn
Technical field
The present invention relates to polypropylene industrial yarn technical field, specially a kind of modified superelevation strength polypropylene industrial yarn.
Background technique
The kind of polypropylene fibre have long filament (including undeformed long filament and varicosity textured filament), staple fiber, bristlelike monofilament, film-fibre, Doughnut, profiled filament, various composite fibres and bonded fabric etc..Be mainly used for production carpet (including carpet backing and Flannelette), bunting, furniture stuff, various ropes, band, fishing net, asphalt felt, building reinforcing material, packaging material and industrial Cloth, such as filter cloth, bagging.Furthermore in terms of clothing using also increasingly extensively, can with multiple fiber is blended that different type is made Blended fabric, by knitting processing after shirt, coat, sweat shirt, socks etc. can be made.It is made of polypropylene fibre doughnut Wadding quilt, light, warming, elasticity is good;Structure polypropylene fibre is on macromolecular structure without containing can chemical base in conjunction with dyestuff Group, so dyeing is relatively difficult.Melt pigmentation is generallyd use, by pigment preparation and polypropylene polymers in screw extruder In equably mix, it is very high to obtain colored fibre color fastness by melt-spun.Another method is and acrylic acid, acrylonitrile, ethylene The copolymerization such as yl pyridines or graft copolymerization make to introduce the polar group that can be combined with dyestuff on polymer macromolecule, then directly use Conventional method dyeing.Often need to be added various additives during polypropylene fibre production to improve dyeability, light resistance and resist Combustion property.
Polypropylene industrial yarn has many advantages, such as that anti-aging, percent thermal shrinkage be small and anti-impact force compared with polypropylene fibre people's industry silk, And then it can be made shirt, coat, sweat shirt, socks etc. after polypropylene industrial yarn processing, but existing polypropylene industrial yarn is still deposited It is not strong and the disadvantages of modification can not be strongly in anti-flammability, make made of clothing there are inflammable and the disadvantages of easily scratch.
Summary of the invention
(1) the technical issues of solving
In view of the deficiencies of the prior art, it the present invention provides a kind of modified superelevation strength polypropylene industrial yarn, solves existing Polypropylene industrial yarn still have the disadvantages of anti-flammability is not strong and modification can not be strongly, making clothing object, there are inflammable and easily scratch The disadvantages of the problem of.
(2) technical solution
In order to achieve the above object, the present invention is achieved by the following technical programs: a kind of modified superelevation strength polypropylene fibre work Industry silk, raw material include: flame-proof material powder, plastic melt, powdered whiting 15-25%, surface modifier according to mass fraction 1.5-2.5%, dispersing agent 2.5-5.0 %, lubricant 1.0-1.5%, linear low density polyethylene 1.0-2.0%, toughening material 10-20 %, nanometer calcium carbonate 50-60%.
The invention also provides a kind of modified superelevation strength polypropylene industrial yarn extremely preparation methods, specifically include following step It is rapid:
Step 1: taking powdered whiting 15-25%, surface modifier 1.5-2.5 %, dispersing agent 2.5- respectively first 5.0%, lubricant 1.0-1.5%, linear low density polyethylene 1.0-2.0 %, toughening material 10-20%, nanometer calcium carbonate The raw materials such as 50-60% are sequentially placed on weigher and weigh, and after weighing, material feeding high-speed mixer is mixed Conjunction processing, mixes 10-20 minutes.
Step 2: selection flame-proof material fission and plastic melt are separately added into fire retardant powder and plastic melt respectively, and open Dynamic temperature control system makes temperature value be higher by 40 DEG C -80 DEG C of fusing point of plastic melt, restarts rotating electric machine and stirring motor, And the rotation direction of rotary body is opposite with the rotation direction of the first agitating paddle.
Step 3: opening powder metering feeder and plastic melt metering feeding machine simultaneously, then fire retardant powder passes through powder Enter stir chamber after body transfer passage, and plastic melt is increased after pumping takes, then passes sequentially through melt conveying channel and orifice plate Enter stir chamber afterwards, the fire retardant powder and plastic melt into stir chamber are stirred to form mixture, and orifice plate can be molten to plastics Body carries out preliminary filtering, and melt bond is avoided to form harder pimple together.
It is stirred together with the material that step 1 is chosen Step 4: the mixture of step 3 is sent into mixing machine, in twin-screw It is kneaded these mixtures in extruder, pelleter is squeezed out and be delivered to, after stock-cutter is to the mixture pelletizing of machine extrusion is extruded Again by dehydration, it is eventually fabricated the master batch of superelevation strength.
Step 5: dewatered master batch is dried, then puts into melting in small screw and form melt, then by these Parent melt is sliced static mixer of the melt before metering pump of weaving with PP prepared by driving screw and uniformly mixes, and then will melt Mixture after melting enters in weaving component through weaving metering pump, carries out spinning using conventional high-strength filament drafting winding process Obtain polypropylene industrial yarn.
Preferably, the partial size of the nanometer calcium carbonate is 2-4 microns, and the powdered whiting partial size is 5-8 microns.
Preferably, the surface modifier is phosphate ester surfactants, and the dispersing agent is paraffin and stearic group It closes, wherein paraffin and stearic weight proportion are 1:1-1:3, and the lubricant is polyethylene wax.
Preferably, the master batch puts into melting in small screw and forms melt, and the temperature of melting is 250 DEG C -300 DEG C, when Between be 5-10 minutes.
Preferably, the dry twin master batch drying system used in the step 5, the drying temperature of the master batch It is 140 DEG C -180 DEG C, drying time is 6-8 hours.
(3) beneficial effect
The present invention provides a kind of modified superelevation strength polypropylene industrial yarns.Have following the utility model has the advantages that the modification superelevation is strong Power polypropylene industrial yarn, Step 1: taking powdered whiting 15-25%, surface modifier 1.5-2.5%, dispersing agent respectively first 2.5-5.0%, lubricant 1.0-1.5 %, linear low density polyethylene 1.0-2.0%, toughening material 10-20%, nano-calcium carbonate The raw materials such as calcium 50-60% are sequentially placed on weigher and weigh, and after weighing, material are sent into high-speed mixer and is carried out Mixed processing mixes 10-20 minutes, Step 2: selection flame-proof material fission and plastic melt are separately added into fire retardant powder respectively And plastic melt, and start-up temperature control system, so that temperature value is higher by 40 DEG C -80 DEG C of fusing point of plastic melt, restarts rotation Motor and stirring motor, and the rotation direction of the rotation direction of rotary body and the first agitating paddle on the contrary, Step 3: open simultaneously Powder metering feeder and plastic melt metering feeding machine, then fire retardant powder enters stir chamber after passing through powder conveying channel, And plastic melt is increased after pumping takes, then enters stir chamber after passing sequentially through melt conveying channel and orifice plate, into stir chamber Fire retardant powder and plastic melt be stirred to form mixture, using flame-proof material powder, plastic melt, greatly strengthen mother The anti-flammability of grain, powdered whiting, dispersing agent, lubricant, linear low density polyethylene, toughening material, are received surface modifier The use of rice calcium carbonate has greatly reinforced the modification superhigh intensity of polypropylene industrial yarn.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described reality Applying example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field Those of ordinary skill's every other embodiment obtained without making creative work, belongs to guarantor of the present invention The range of shield.
The embodiment of the present invention provides a kind of technical solution: a kind of modified superelevation strength polypropylene industrial yarn, raw material is according to matter Measuring score includes: flame-proof material powder, plastic melt, powdered whiting 15-25%, surface modifier 1.5-2.5%, dispersing agent 2.5-5.0%, lubricant 1.0-1.5 %, linear low density polyethylene 1.0-2.0%, toughening material 10-20%, nano-calcium carbonate Calcium 50-60%, the rotation direction of the rotation direction of rotary body and the first agitating paddle is on the contrary, can guarantee that stirring is more abundant, only Guarantee that rotation direction is opposite.
The invention also discloses a kind of modified superelevation strength polypropylene industrial yarn extremely preparation method, having includes following step It is rapid:
Step 1: taking powdered whiting 15-25%, surface modifier 1.5-2.5 %, dispersing agent 2.5- respectively first 5.0%, lubricant 1.0-1.5%, linear low density polyethylene 1.0-2.0 %, toughening material 10-20%, nanometer calcium carbonate The raw materials such as 50-60% are sequentially placed on weigher and weigh, and after weighing, material feeding high-speed mixer is mixed Conjunction processing, mixes 10-20 minutes.
Step 2: selection flame-proof material fission and plastic melt are separately added into fire retardant powder and plastic melt respectively, and open Dynamic temperature control system makes temperature value be higher by 40 DEG C -80 DEG C of fusing point of plastic melt, restarts rotating electric machine and stirring motor, And the rotation direction of rotary body is opposite with the rotation direction of the first agitating paddle.
Step 3: opening powder metering feeder and plastic melt metering feeding machine simultaneously, then fire retardant powder passes through powder Enter stir chamber after body transfer passage, and plastic melt is increased after pumping takes, then passes sequentially through melt conveying channel and orifice plate Enter stir chamber afterwards, the fire retardant powder and plastic melt into stir chamber are stirred to form mixture, and orifice plate can be molten to plastics Body carries out preliminary filtering, and melt bond is avoided to form harder pimple together.
It stirs together with material Step 4: the mixture of step 3 is sent into mixing machine, is kneaded in double screw extruder These mixtures, squeeze out and are delivered to pelleter, and stock-cutter is made by dehydration again to after the mixture pelletizing for being extruded machine extrusion With being eventually fabricated the master batch of superelevation strength.
Step 5: dewatered master batch is dried, then puts into melting in small screw and form melt, then by these Parent melt is sliced static mixer of the melt before metering pump of weaving with PP prepared by driving screw and uniformly mixes, and then will melt Mixture after melting enters in weaving component through weaving metering pump, carries out spinning using conventional high-strength filament drafting winding process Obtain polypropylene industrial yarn.
In the present invention, the partial size of nanometer calcium carbonate is 2-4 microns, and the powdered whiting partial size is 5-8 microns, surface Modifying agent is phosphate ester surfactants, and dispersing agent is paraffin and stearic combination, and wherein paraffin is matched with stearic weight Than for 1:1-1:3, lubricant is polyethylene wax, master batch puts into melting in small screw and forms melt, and the temperature of melting is 250 DEG C -300 DEG C, the time is 5-10 minute, the dry twin master batch drying system used in step 5, master batch it is dry warm Degree is 140 DEG C -180 DEG C, and drying time is 6-8 hours.
It should be noted that, in this document, relational terms such as first and second and the like are used merely to a reality Body or operation are distinguished with another entity or operation, without necessarily requiring or implying between these entities or operation There are any actual relationship or orders.Moreover, the terms "include", "comprise" or its any other variant are intended to Cover non-exclusive inclusion, so that the process, method, article or equipment for including a series of elements not only includes that A little elements, but also including other elements that are not explicitly listed, or further include for this process, method, article or The intrinsic element of equipment.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding And modification, the scope of the present invention is defined by the appended.

Claims (6)

1. a kind of modified superelevation strength polypropylene industrial yarn, it is characterised in that: its raw material includes: fire-retardant feed powder according to mass fraction Body, plastic melt, powdered whiting 15-25%, surface modifier 1.5-2.5%, dispersing agent 2.5-5.0%, lubricant 1.0- 1.5%, linear low density polyethylene 1.0-2.0%, toughening material 10-20%, nanometer calcium carbonate 50-60%.
2. a kind of modified superelevation strength polypropylene industrial yarn according to claim 1 and preparation method thereof, it is characterised in that: tool Body the following steps are included:
Step 1: taking powdered whiting 15-25%, surface modifier 1.5-2.5%, dispersing agent 2.5-5.0%, profit respectively first The originals such as lubrication prescription 1.0-1.5%, linear low density polyethylene 1.0-2.0%, toughening material 10-20%, nanometer calcium carbonate 50-60% Material, which is sequentially placed on weigher, weighs, and after weighing, material is sent into high-speed mixer and carries out mixed processing, mixing 10-20 minutes.
Step 2: selection flame-proof material fission and plastic melt are separately added into fire retardant powder and plastic melt respectively, and start temperature Control system is spent, temperature value is made to be higher by 40 DEG C -80 DEG C of fusing point of plastic melt, restarts rotating electric machine and stirring motor, and revolve The rotation direction of swivel is opposite with the rotation direction of the first agitating paddle.
Step 3: opening powder metering feeder and plastic melt metering feeding machine simultaneously, then fire retardant powder is defeated by powder It send and enters stir chamber behind channel, and plastic melt is increased after pumping takes, then pass sequentially through melt conveying channel and orifice plate is laggard Enter stir chamber, into stir chamber fire retardant powder and plastic melt be stirred to form mixture, orifice plate can to plastic melt into The preliminary filtering of row, avoids melt bond from forming harder pimple together.
It is stirred together with the material that step 1 is chosen Step 4: the mixture of step 3 is sent into mixing machine, in twin-screw extrusion It is kneaded these mixtures in machine, squeezes out and is delivered to pelleter, lead to again after the mixture pelletizing that stock-cutter squeezes out the machine that is extruded Dehydration is crossed, the master batch of superelevation strength is eventually fabricated.
Step 5: dewatered master batch is dried, then puts into melting in small screw and form melt, then these parents are melted Body is sliced static mixer of the melt before metering pump of weaving with PP prepared by driving screw and uniformly mixes, then will be mixed after melting It closes object to enter in polypropylene industrial yarn composite spinneret pack through weaving metering pump, be carried out using conventional high-strength filament drafting winding process Spinning obtains polypropylene industrial yarn.
3. a kind of modified superelevation strength polypropylene industrial yarn according to claim 1, it is characterised in that: the nanometer calcium carbonate Partial size be 2-4 micron, the powdered whiting partial size be 5-8 microns.
4. a kind of modified superelevation strength polypropylene industrial yarn according to claim 1, it is characterised in that: the surface modifier For phosphate ester surfactants, the dispersing agent is paraffin and stearic combination, wherein paraffin and stearic weight proportion For 1:1-1:3, the lubricant is polyethylene wax.
5. a kind of modified superelevation strength polypropylene industrial yarn according to claim 2 and preparation method thereof, it is characterised in that: institute It states master batch and puts into small screw melting and form melt, the temperature of melting is 250 DEG C -300 DEG C, and the time is 5-10 minutes.
6. a kind of modified superelevation strength polypropylene industrial yarn according to claim 2 and preparation method thereof, it is characterised in that: institute The dry twin master batch drying system used in step 5 is stated, the drying temperature of the master batch is 140 DEG C -180 DEG C, dry Time is 6-8 hours.
CN201810977058.XA 2018-08-26 2018-08-26 A kind of modified superelevation strength polypropylene industrial yarn Pending CN109371488A (en)

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CN201810977058.XA CN109371488A (en) 2018-08-26 2018-08-26 A kind of modified superelevation strength polypropylene industrial yarn

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Application Number Priority Date Filing Date Title
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CN109371488A true CN109371488A (en) 2019-02-22

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03174014A (en) * 1989-12-01 1991-07-29 Tokuyama Soda Co Ltd Flame-retardant conjugate yarn
CN101275290A (en) * 2007-10-18 2008-10-01 江苏盛虹化纤有限公司 Production process of colored and functional polypropylene industrial yarn
CN102199806A (en) * 2011-04-12 2011-09-28 射阳县恩玉化纤有限公司 Method for producing high-tenacity polypropylene fibre
CN104139467A (en) * 2014-07-22 2014-11-12 广州市合诚化学有限公司 Flame-retardant masterbatch processing device and method
CN106497123A (en) * 2016-10-26 2017-03-15 山东友谊机械有限公司 A kind of plasticizing mother particle and its processing method

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03174014A (en) * 1989-12-01 1991-07-29 Tokuyama Soda Co Ltd Flame-retardant conjugate yarn
CN101275290A (en) * 2007-10-18 2008-10-01 江苏盛虹化纤有限公司 Production process of colored and functional polypropylene industrial yarn
CN102199806A (en) * 2011-04-12 2011-09-28 射阳县恩玉化纤有限公司 Method for producing high-tenacity polypropylene fibre
CN104139467A (en) * 2014-07-22 2014-11-12 广州市合诚化学有限公司 Flame-retardant masterbatch processing device and method
CN106497123A (en) * 2016-10-26 2017-03-15 山东友谊机械有限公司 A kind of plasticizing mother particle and its processing method

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Application publication date: 20190222