CN109370483A - A kind of strength is water-fast ceramic tile gum and preparation and construction method - Google Patents

A kind of strength is water-fast ceramic tile gum and preparation and construction method Download PDF

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Publication number
CN109370483A
CN109370483A CN201811244869.5A CN201811244869A CN109370483A CN 109370483 A CN109370483 A CN 109370483A CN 201811244869 A CN201811244869 A CN 201811244869A CN 109370483 A CN109370483 A CN 109370483A
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ceramic tile
water
strength
gum
fast
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CN201811244869.5A
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Inventor
童国松
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Hangzhou Gubang Building Materials Technology Co Ltd
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Hangzhou Gubang Building Materials Technology Co Ltd
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Priority to CN201811244869.5A priority Critical patent/CN109370483A/en
Publication of CN109370483A publication Critical patent/CN109370483A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J125/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Adhesives based on derivatives of such polymers
    • C09J125/02Homopolymers or copolymers of hydrocarbons
    • C09J125/04Homopolymers or copolymers of styrene
    • C09J125/08Copolymers of styrene
    • C09J125/14Copolymers of styrene with unsaturated esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/06Non-macromolecular additives organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08Macromolecular additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Finishing Walls (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The present invention relates to chemical building material technical fields, and in particular to a kind of preparation and its application method of the water-fast ceramic tile gum of strength.Concrete component includes styrene-butadiene emulsion, Nano silica sol, adhesion promoter, filler material, silicon powder, thickener, cement mortar, preservative and water.Ceramic tile gum of the invention has the ability of the anti-ceramic tile deformation of flexibility of the superpower cohesive force and one-component gum of two-component gum, while having excellent water-fast and durability, and construction is simple is quick, can apply to the paving of various construction environments, various ceramic tiles.

Description

A kind of strength is water-fast ceramic tile gum and preparation and construction method
Technical field
The invention belongs to chemical building material technical fields, more particularly to a kind of water-fast ceramic tile gum of strength and make and use Method.
Background technique
With the upgrading of consumption, Modern Family generallys use the high-end tiles such as polished bricks, vitrified tile to fit up, this Wall on the heavy brick of low water absorption, even if being glued using the dry powder ceramic tile glue of national standard JC/T547-2005 " ceramic wall and floor bricks binder " Patch, is also easy to produce hollowing, obscission.So many producers have developed ceramic tile gum or binder is used to do boundary layer, Increase the adhesive force between ceramic tile and cement mortar, falling off for ceramic tile is avoided with this.
There are mainly of two types for current existing ceramic tile gum.One is two-component ceramic tile gum, such as Chinese invention patents CN201210011156.0 discloses a kind of emulsion-type Dual-component surfactant and preparation method thereof, and main component is propylene yogurt Liquid+cement+auxiliary agent is brushed after Site, uses cement mortar paving again after solidification 24 hours.This gum advantage is Adhesion strength is high, water-tolerant, but gum poor permeability, it is difficult to generate bite force with ceramic tile, and it is comparatively laborious to construct, back Glue film is partially rigid, poor to the deformation of ceramic tile caused by expanding with heat and contract with cold adaptability.
There are also one is one-component ceramic tile gum, as Chinese invention patent CN201610620038.8 disclose it is a kind of aqueous Environment-friendly type ceramic tile gum lotion and its manufacturing method, main component are acrylate polymer emulsion, need 2-3 hours after brushing Curing time.The main function principle of this kind of gums is similar to pressure sensitive adhesive, the method pasted using physics, after being solidified by lotion The viscosity of generation, is pasted together ceramic tile and cement sand bed.This kind of gum advantage is that glass transition temperature is low, and film is partially soft Property, shear strength is very high, good impact resistance, can offset ceramic tile and expand with heat and contract with cold the stress of generation, and it is bulging and de- to reduce rising for ceramic tile It falls.But its disadvantage is also evident from, and water resistance is general, it is impossible to be used in occasion (such as toilet, pond) that is moist or having water, In addition because using simple physical bond, pull strength is relatively low, and over time, and film is easy ageing hardening Become fragile, viscous force decline, so durability is not also grown, service life is short.
Therefore, in the prior art, there is cumbersome, the deficiency of anti-ceramic tile deformability difference of constructing in two-component ceramic tile gum, single Component ceramic tile gum is there are water-fast and durability is poor, the low disadvantage of pull strength.
Summary of the invention
In order to overcome the shortcomings in the prior art, the present invention provides a kind of water-fast ceramic tile gum of strength and preparation and construction parties Method.This kind of ceramic tile gum, the ability of the anti-ceramic tile deformation of the flexibility of superpower cohesive force and one-component gum with two-component gum, There is excellent water-fast and durability simultaneously, construction is simple is quick, can apply to the paving of various construction environments, various ceramic tiles.
The present invention is realized by the following technical programs:
A kind of strength is water-fast ceramic tile gum, it is characterised in that including following components in percentage by weight: styrene-butadiene emulsion 25- 45%, Nano silica sol 4-7%, adhesion promoter 0.1-0.3%, filler material 35-50%, silicon powder 2-3%, thickener 0.2- 0.3%, cement mortar 0.2-0.4%, preservative 0.1-0.3%, remaining is water.
A kind of strength is water-fast ceramic tile gum, it is characterised in that including following components in percentage by weight: butylbenzene cream Liquid 30-40%, Nano silica sol 4.5-6.5%, adhesion promoter 0.18-0.28%, filler material 39-48%, silicon powder 2-2.5%, Thickener 0.2-0.25%, cement mortar 0.2-0.3%, preservative 0.1-0.2%, remaining is water.
A kind of strength is water-fast ceramic tile gum, it is characterised in that including following components in percentage by weight: butylbenzene cream Liquid 45%, Nano silica sol 6.5%, adhesion promoter 0.18%, filler material 39%, silicon powder 2.0%, thickener 0.2%, cement swash Agent 0.2% is sent out, preservative 0.1%, remaining is water.
The styrene-butadiene emulsion has born flexible and extremely low water absorption rate, and good with cement compatibility, even if for a long time Immersion can also provide excellent strength conservation rate in water.The SD7623 styrene-butadiene emulsion of preferred Germany's BASF production in the present invention.
The Nano silica sol, preferential partial size are 10nm, and the silica solution of pH value 8-9, this kind of silica solution permeability be strong and fourth Benzene emulsion compatibility is good, while can improve the water resistance and storage stability of lotion.
The KH-450 aqueous silane coupling agent of the adhesion promoter, preferably Nanjing energy moral new material production, in this hair It can be further improved the water resistance of styrene-butadiene emulsion in bright, and adhesive force of the ceramic tile gum on smooth basal plane can be improved.
The filler material, the preferably quartz sand of 70-100 mesh, are added in ceramic tile gum, and when use and cement mortar is solid together Change, increases contact surface area, to improve the bite force between boundary layer.
The silicon powder, the canescence silicon powder of preferably 2000 mesh, can the intergranular hole of filling concrete, while and water Change product and generate gelinite, to improve the performances such as the intensity of cement mortar, impervious, resistance to compression.
The thickener, the hydroxyethyl cellulose or hydroxypropyl methyl cellulose of preferably 50,000 viscosity.
The cement mortar, preferably triethanolamine can keep the stabilization of system pH value when producing ceramic tile gum, It can promote hydrated cementitious when construction, improve cement early strength.
The preservative, preferably Kathon CG, main component are isothiazolinone compound, can inhibit micro- life in the present invention Object growth, improves the storage stability of ceramic tile gum.
The preparation method of a kind of strength is water-fast ceramic tile gum comprising the steps of: add the thickener in proportion Entering into water, stirring and dissolving is uniform, then sequentially add styrene-butadiene emulsion, quartz sand, silicon powder, high-speed stirred half an hour, then Silane coupling agent is added dropwise while stirring, be further continued for after adding stirring curing half an hour, be eventually adding Nano silica sol, preservative and Cement mortar, after mixing evenly finished product.
A kind of construction method of the water-fast ceramic tile gum of strength of the present invention is as follows:
1) first with the dust and release agent at the scrub-brush cleaning ceramic tile back side, cleaning treatment again after being rinsed with water when necessary;
2) the water-fast ceramic tile gum of strength of the invention is brushed at the ceramic tile back side, brushing surface is not less than the 80% of ceramic tile area;
3) not dry to ceramic tile gum, the cement mortar being stirred in advance is smeared immediately, and thickness is not less than 1CM, such as uses glue for tile It then can be with plaster;
4) pressure on the wall by tile paste, is suitably rubbed, and is struck real smooth.
A kind of technical principle of the water-fast ceramic tile gum of strength of the present invention is as follows: the small molecule silicon in ceramic tile gum is molten Latex solution penetrates into the pore at the ceramic tile back side, is formed by curing the anchor point of superpower cohesive force, thus realize ceramic tile gum and Being seamless bonding between ceramic tile.On the other hand, ceramic tile gum of the present invention construct when using brush paste by the way of, gum layer not Before solid, cement mortar is spread in painting, and by the Brownian movement of the percussion of external force and molecule itself, ceramic tile gum penetrates into cement In mortar, and rapid curing under the action of cement mortar, to form the netted anchoring between ceramic tile gum, cement mortar Structure.
Compared with prior art, the invention has the following advantages:
1) the water-fast ceramic tile gum of strength of the invention has excellent water resistance, and film water absorption rate is low, can be used for humidity and have water The tile laying of environment;
2) the water-fast ceramic tile gum of strength of the invention is coupled hardness with softness, existing superpower cohesive force, and has certain flexibility, can be supported Imperial ceramic tile expands with heat and contract with cold the stress of generation, therefore pull strength and shear strength, than more prominent, it is existing that technical indicator is superior to market There is product;
3) the water-fast ceramic tile gum of strength of the invention carries out infiltration combination, and and cement bonded sand to ceramic tile using chemical bonding Pulp layer generates netted anchor structure, and durability is more preferable;
4) the water-fast ceramic tile gum construction of strength of the invention is simpler, and without waiting, directly i.e. brush pastes, and shortens the construction period;
5) the water-fast ceramic tile gum of strength of the invention belongs to green product, and organic volatile is less, and smell is lower, to environment It is more friendly.
Detailed description of the invention
Fig. 1 is the stickup schematic diagram of the water-fast ceramic tile gum of strength provided by the invention;
Fig. 2 is the stickup schematic diagram of existing one-component ceramic tile gum.
Specific embodiment
Below in conjunction with Figure of description and specific embodiment to further illustrate the technical scheme of the present invention.
Unless specific instructions, various raw materials of the invention are commercially available buys, or is prepared according to the conventional method of this field It obtains.Wherein, the adhesive theory figure of the water-fast ceramic tile gum of strength provided by the invention and one-component ceramic tile gum is shown in Fig. 1-2.
Embodiment 1
A kind of water-fast ceramic tile gum of strength, include following components in percentage by weight: styrene-butadiene emulsion 25%, Nano silica sol 4% are attached Adhesion promoter 0.25%, filler material 48%, silicon powder 2.5%, thickener 0.3%, cement mortar 0.3%, preservative 0.2%, Yu Weishui.
Wherein the styrene-butadiene emulsion is the SD7623 styrene-butadiene emulsion of German BASF production, and the Nano silica sol is Zhejiang Space reaches the TUS-1 silica solution of Chemical Manufacture, and the adhesion promoter is KH-450 aqueous silane coupling agent, and the filler material is The quartz sand of 70-100 mesh, the silicon powder are 2000 mesh powders.The thickener is the hydroxyethyl cellulose of 50,000 viscosity, institute Stating cement mortar is triethanolamine, and the preservative is Kathon CG.
The preparation method of the water-fast ceramic tile gum of a kind of strength of the present invention comprising the steps of: by the increasing in proportion Thick dose is added to the water, and stirring and dissolving is uniform, then sequentially adds styrene-butadiene emulsion, filler material, silicon powder, and high-speed stirred half is small When, adhesion promoter is then added dropwise while stirring, stirring curing half an hour is further continued for after adding, is eventually adding nano silicasol Glue, preservative and cement mortar, after mixing evenly finished product.
A kind of application method of the water-fast ceramic tile gum of strength of the present invention is as follows:
1) first with the dust and release agent at the scrub-brush cleaning ceramic tile back side, cleaning treatment again after being rinsed with water when necessary;2) exist The water-fast ceramic tile gum of strength of the invention is brushed at the ceramic tile back side, and brushing surface is not less than the 80% of ceramic tile area;3) to ceramic tile gum It is not dry, the cement mortar being stirred in advance is smeared immediately, and thickness is not less than 1CM, can be with plaster if using glue for tile;4) by porcelain Brick is pasted on the wall, and pressure is suitably rubbed, and is struck real smooth.
Embodiment 2
A kind of water-fast ceramic tile gum of strength, include following components in percentage by weight: styrene-butadiene emulsion 30%, Nano silica sol 4.5%, Adhesion promoter 0.3%, filler material 47%, silicon powder 2.5%, thickener 0.3%, cement mortar 0.3%, preservative 0.2%, Yu Weishui.
The ceramic tile gum material therefor of the present embodiment, preparation method and application method are identical with embodiment 1.
Embodiment 3
A kind of water-fast ceramic tile gum of strength, include following components in percentage by weight: styrene-butadiene emulsion 35%, Nano silica sol 5.5%, Adhesion promoter 0.28%, filler material 44%, silicon powder 2.0%, thickener 0.25%, cement mortar 0.3%, preservative 0.1%, Remaining is water.
The ceramic tile gum material therefor of the present embodiment, preparation method and application method are identical with embodiment 1.
Embodiment 4
A kind of water-fast ceramic tile gum of strength, include following components in percentage by weight: styrene-butadiene emulsion 40%, Nano silica sol 6.0%, Adhesion promoter 0.24%, filler material 42%, silicon powder 2.0%, thickener 0.2%, cement mortar 0.2%, preservative 0.1%, Remaining is water.
The ceramic tile gum material therefor of the present embodiment, preparation method and application method are identical with embodiment 1.
Embodiment 5
A kind of water-fast ceramic tile gum of strength, include following components in percentage by weight: styrene-butadiene emulsion 45%, Nano silica sol 6.5%, Adhesion promoter 0.18%, filler material 39%, silicon powder 2.0%, thickener 0.2%, cement mortar 0.2%, preservative 0.1%, Remaining is water.
The ceramic tile gum material therefor of the present embodiment, preparation method and application method are identical with embodiment 1.
The water-fast ceramic tile gum of strength made from embodiment 1-5 is tested for the property, and is carried out with commercially available brand gum Comparison, experimental result are as shown in table 1.
The performance comparison of table 1, strength water-fast ceramic tile gum and commercially available ceramic tile gum of the invention
It can be seen that the water-fast ceramic tile gum of strength of the invention, shear strength and commercially available one-component ceramic tile gum from the data of table 1 Quite, but tensile strength is much higher than one-component ceramic tile gum;Meanwhile tensile strength and shear strength are superior to two-component ceramic tile back Glue.Therefore, the water-fast ceramic tile gum of strength of the invention has the superpower cohesive force of two-component gum and the flexibility of one-component gum The ability of anti-ceramic tile deformation, while there is excellent water-fast and durability, construction is simple is quick, can apply to various construction rings The paving in border, various ceramic tiles.
The foregoing is merely presently preferred embodiments of the present invention, is not intended to limit protection scope of the present invention.It is all in this hair Within bright claim, made any modification, equivalent replacement and improvement etc., should be included in protection scope of the present invention it It is interior.

Claims (6)

1. a kind of water-fast ceramic tile gum of strength, it is characterised in that including following components in percentage by weight: styrene-butadiene emulsion 25-45%, Nano silica sol 4-7%, adhesion promoter 0.1-0.3%, filler material 35-50%, silicon powder 2-3%, thickener 0.2-0.3%, water Mud exciting agent 0.2-0.4%, preservative 0.1-0.3%, remaining is water.
2. a kind of water-fast ceramic tile gum of strength as described in claim 1, it is characterised in that the group including following weight percent Point: styrene-butadiene emulsion 30-40%, Nano silica sol 4.5-6.5%, adhesion promoter 0.18-0.28%, filler material 39-48%, silicon are micro- Powder 2-2.5%, thickener 0.2-0.25%, cement mortar 0.2-0.3%, preservative 0.1-0.2%, remaining is water.
3. a kind of water-fast ceramic tile gum of strength as described in claim 1, it is characterised in that the group including following weight percent Point: styrene-butadiene emulsion 45%, Nano silica sol 6.5%, adhesion promoter 0.18%, filler material 39%, silicon powder 2.0%, thickener 0.2%, cement mortar 0.2%, preservative 0.1%, remaining is water.
4. a kind of water-fast ceramic tile gum of strength as described in claim 1, it is characterised in that the Nano silica sol is partial size 10nm, the silica solution of pH value 8-9;The filler material is the quartz sand of 70-100 mesh;The silicon powder is the canescence of 2000 mesh Silicon powder;The thickener is the hydroxyethyl cellulose or hydroxypropyl methyl cellulose of 50,000 viscosity;The cement mortar is three Ethanol amine;The preservative is Kathon CG.
5. a kind of preparation method of the water-fast ceramic tile gum of strength described in claim 1, it is characterised in that the following steps are included: will Thickener in proportion is added to the water, and stirring and dissolving is uniform, then sequentially adds styrene-butadiene emulsion, quartz sand, silicon powder, high speed Half an hour is stirred, silane coupling agent is then added dropwise while stirring, stirring curing half an hour is further continued for after adding, is eventually adding nanometer Silica solution, preservative and cement mortar, after mixing evenly finished product.
6. a kind of construction method of the water-fast ceramic tile gum of strength described in claim 1, it is characterised in that:
1) first with the dust and release agent at the scrub-brush cleaning ceramic tile back side, cleaning treatment again after being rinsed with water when necessary;
2) the water-fast ceramic tile gum of strength of the invention is brushed at the ceramic tile back side, brushing surface is not less than the 80% of ceramic tile area;
3) not dry to ceramic tile gum, the cement mortar being stirred in advance is smeared immediately, and thickness is not less than 1CM, such as uses glue for tile It then can be with plaster;
4) pressure on the wall by tile paste, is suitably rubbed, and is struck real smooth.
CN201811244869.5A 2018-10-24 2018-10-24 A kind of strength is water-fast ceramic tile gum and preparation and construction method Pending CN109370483A (en)

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Cited By (8)

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Publication number Priority date Publication date Assignee Title
CN111500225A (en) * 2020-05-10 2020-08-07 国润新材料科技(广东)有限公司 Liquid two-component interface treating agent
CN111574940A (en) * 2020-05-10 2020-08-25 国润新材料科技(广东)有限公司 Interface treating agent
CN113533198A (en) * 2021-07-26 2021-10-22 天津市建筑材料科学研究院有限公司 Method for detecting adhesive property of back adhesive of ceramic facing brick
CN113930191A (en) * 2020-06-29 2022-01-14 苏州金螳螂建筑装饰股份有限公司 Super-strong water-resistant bonding reinforcing agent and preparation method and construction method thereof
CN114045132A (en) * 2021-11-29 2022-02-15 广东家实多集团有限公司 Tile back glue emulsion and preparation and detection method thereof
CN114605926A (en) * 2022-01-14 2022-06-10 湖北碱克新材料有限公司 Water-resistant double-component tile back glue and preparation method thereof
CN114702937A (en) * 2022-03-31 2022-07-05 华润水泥技术研发有限公司 High-strength ceramic tile gum
CN115353832A (en) * 2022-09-23 2022-11-18 西卡德高(上海)建材有限公司 Tile back glue and preparation method thereof

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111500225A (en) * 2020-05-10 2020-08-07 国润新材料科技(广东)有限公司 Liquid two-component interface treating agent
CN111574940A (en) * 2020-05-10 2020-08-25 国润新材料科技(广东)有限公司 Interface treating agent
CN113930191A (en) * 2020-06-29 2022-01-14 苏州金螳螂建筑装饰股份有限公司 Super-strong water-resistant bonding reinforcing agent and preparation method and construction method thereof
CN113930191B (en) * 2020-06-29 2022-11-01 苏州金螳螂建筑装饰股份有限公司 Super-strong water-resistant bonding reinforcing agent and preparation method and construction method thereof
CN113533198A (en) * 2021-07-26 2021-10-22 天津市建筑材料科学研究院有限公司 Method for detecting adhesive property of back adhesive of ceramic facing brick
CN114045132A (en) * 2021-11-29 2022-02-15 广东家实多集团有限公司 Tile back glue emulsion and preparation and detection method thereof
CN114605926A (en) * 2022-01-14 2022-06-10 湖北碱克新材料有限公司 Water-resistant double-component tile back glue and preparation method thereof
CN114702937A (en) * 2022-03-31 2022-07-05 华润水泥技术研发有限公司 High-strength ceramic tile gum
CN115353832A (en) * 2022-09-23 2022-11-18 西卡德高(上海)建材有限公司 Tile back glue and preparation method thereof
CN115353832B (en) * 2022-09-23 2024-03-22 西卡德高(上海)建材有限公司 Ceramic tile back adhesive and preparation method thereof

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Application publication date: 20190222