CN109370473A - A kind of papery mounting of calligraphy and painting paste-like materials and preparation method thereof - Google Patents
A kind of papery mounting of calligraphy and painting paste-like materials and preparation method thereof Download PDFInfo
- Publication number
- CN109370473A CN109370473A CN201810900280.XA CN201810900280A CN109370473A CN 109370473 A CN109370473 A CN 109370473A CN 201810900280 A CN201810900280 A CN 201810900280A CN 109370473 A CN109370473 A CN 109370473A
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- China
- Prior art keywords
- calligraphy
- materials
- painting
- papery
- mounting
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J103/00—Adhesives based on starch, amylose or amylopectin or on their derivatives or degradation products
- C09J103/02—Starch; Degradation products thereof, e.g. dextrin
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The present invention relates to a kind of papery mounting of calligraphy and painting paste-like materials and preparation method thereof, belong to Restoration of painting and calligraphy technical field.The present invention has certain mould proof ability using the carboxymethyl chitosan with bacteriostasis property as carrier, and fully dispersed with its supported nano zinc oxide, can release the Zn with oxidisability in water using nano granular of zinc oxide2+Ion works as Zn2+After the cell membrane contact of bacterium, the active protease in cell membrane can be made to lose activity, to play the role of bactericidal, chitosan polymer can carry out pre-reinforcement to papery painting and calligraphy simultaneously, form protective film, it prevents from running ink, and also contain calcium bicarbonate in paste-like materials, it can delay the acidization of paper relics, make pH value close to neutrality, the precipitation of calcium carbonate that calcium bicarbonate generates in paper relics acidization simultaneously can fill up papery painting and calligraphy surface fiber fault location, effective buffering is formed to external acidic materials, it is more caused by painting and calligraphy to reduce external acidic materials, more lasting damage.
Description
Technical field
The present invention relates to a kind of papery mounting of calligraphy and painting paste-like materials and preparation method thereof, belong to Restoration of painting and calligraphy technology neck
Domain.
Background technique
The material of painting and calligraphy is mostly papery or thin,tough silk matter, and aging, breakage easily occur for passage at any time.But in fact, conduct
Rapid wear historical relic, many ancient calligraphy and painting works can also retain so far and preservation condition is fine, this has with traditional mounting process process
Close relationship.
Paste is the bonding agent that Chinese Painting and Calligraphy mounting process uses, and is made of flour heating.The production and utilization of paste,
In occupation of highly important position in the mounting of calligraphy and painting.Paste is as essential adhesive, and the mounting of calligraphy and painting is almost per together
Process all be unable to do without it.Exactly because also in this way, paste is for mounting quality, especially for painting and calligraphy it is smooth whether, play
Very important effect.
Using paste as the reason of mounting bonding agent mainly has 3 points: first, and the raw material flour of paste is easy to get
Daily bread, cost are very low；Second, paste is nontoxic, has not significant impact after use to appearance, and strong for papery physics
Degree has certain promotion；Third and most important reason are exactly paste as bonding agent, have the invertibity of operation.Make
It can be opened again with the painting and calligraphy of paste mounting, mounting repeatedly, this, which had not only met ancient calligraphy and painting sometimes, needs the requirement of mounting again, but also
Meet the invertibity principle in historical relic's protection.But paste also has its limitation, and the main component of paste is glucose, protein,
This causes mounting that unstable material, therefore the microbial destructions such as mould one have also been introduced while playing protective effect to painting and calligraphy
It is directly that paper relics are difficult to one of harm protected.The damage to painting and calligraphy of microorganism, ancients often add in paste in order to prevent
Doping is to play the role of fungus and mildew resistance.
Although the improvement of paste additive there has been some reports, in terms of the evaluation for more resting on paste performance itself,
Paste after not continuing improvement additive is applied to the experiment on paper, and lacks the ageing properties number after use
According to.The paste study on the modification that in addition, there will be rests on antibiotic property more or the single aspect of pH value is modified, though cause method of modifying that can mention
High performance in a certain respect is but likely to result in the loss of other aspect performances.More it is worth noting that, during mounting
Race ink (also known as decoloration) problem being likely to occur using paste is never paid attention to, and running black problem is to need to consider in mounting
Major issue, modified paste can not be suitable for historical relic's protection if it can aggravate to run black problem.It can be seen that paste adds
There is still a need for further researches for the improvement and evaluation of agent.
Summary of the invention
The technical problems to be solved by the invention: for mounting of calligraphy and painting paste additive mostly by chemical reagent institute's generation
It replaces, causes the pollution to environment, the harm to personnel, or even the implicit destruction to paper relics, archives, painting and calligraphy pieces itself
Problem provides a kind of papery mounting of calligraphy and painting paste-like materials and preparation method thereof.
In order to solve the above technical problems, the technical solution adopted by the present invention is that:
A kind of papery mounting of calligraphy and painting paste-like materials, the paste-like materials are made of starch dry powder with deionized water, the starch
Dry powder is made of the component of following portions by weight:
50~60 parts of starch, 1.0~1.2 parts of carboxymethyl chitosans, 1.0~1.2 parts of nano zine oxides, 1.0~1.2 parts of bicarbonates
Calcium.
The starch dry powder and the mass ratio of deionized water are 1:3.
A kind of preparation method of papery mounting of calligraphy and painting paste-like materials, specific steps are as follows:
(1) take starch, carboxymethyl chitosan, nano zine oxide, calcium bicarbonate be added deionized water in ultrasonic disperse, stand 1~
Upper liquid is taken after 2h, upper liquid is evaporated to dryness, and obtains starch dry powder；
(2) take starch dry powder that 30~40min of heating stirring in deionized water is added, cooling one layer of preservative film of rear cover saves, and obtains paper
Matter mounting of calligraphy and painting paste-like materials.
The ultrasonic power is 300W~500W.
The evaporating temperature is 50~60 DEG C.
The heating stirring process is to stir 30~40min at 70~80 DEG C with 300~400r/min.
The storage temperature is 1~4 DEG C.
The present invention is compared with other methods, and advantageous effects are:
(1) present invention has certain mould proof ability, and receive using the carboxymethyl chitosan with bacteriostasis property as carrier with its load
Rice zinc oxide is fully dispersed, can release the Zn with oxidisability in water using nano granular of zinc oxide2+Ion works as Zn2+With
After the cell membrane contact of bacterium, the active protease in cell membrane can be made to lose activity, to play the role of bactericidal, together
When chitosan polymer can to papery painting and calligraphy carry out pre-reinforcement, formed protective film, prevent run ink；
(2) also contain calcium bicarbonate in papery mounting of calligraphy and painting paste-like materials of the present invention, the acidization of paper relics can be delayed,
Make pH value close to neutrality, while the precipitation of calcium carbonate that calcium bicarbonate generates in paper relics acidization can fill up papery painting and calligraphy
Surface fiber fault location forms effective buffering to external acidic materials, and it is more caused by painting and calligraphy, more to reduce external acidic materials
Lasting damage.
Specific embodiment
Take 50~60g starch, 1.0~1.2g carboxymethyl chitosan, 1.0~1.2g nano zine oxide, 1.0~1.2g carbonic acid
Hydrogen calcium is added in 120~150mL deionized water, disperses 20~30min with 300W~500W ultrasonic echography, after standing 1~2h
Upper liquid is taken, upper liquid is placed in drying box, is evaporated to dryness at 50~60 DEG C, starch dry powder is obtained, takes 20~30g starch dry
Powder is added in 60~90mL deionized water, stirs 30~40min, cooling rear cover one at 70~80 DEG C with 300~400r/min
Layer preservative film, is placed in 1~4 DEG C of refrigerator and saves, obtain papery mounting of calligraphy and painting paste-like materials.
Take 50g starch, 1.0g carboxymethyl chitosan, 1.0g nano zine oxide, 1.0g calcium bicarbonate, be added 120mL go from
In sub- water, 20min is dispersed with 300W ultrasonic echography, upper liquid is taken after standing 1h, upper liquid is placed in drying box, at 50 DEG C
Under be evaporated to dryness, obtain starch dry powder, take 20g starch dry powder, be added in 60mL deionized water, stirred at 70 DEG C with 300r/min
30min, cooling one layer of preservative film of rear cover, is placed in 1 DEG C of refrigerator and saves, obtain papery mounting of calligraphy and painting paste-like materials.
Take 55g starch, 1.0g carboxymethyl chitosan, 1.0g nano zine oxide, 1.0g calcium bicarbonate, be added 130mL go from
In sub- water, 25min is dispersed with 400W ultrasonic echography, upper liquid is taken after standing 1h, upper liquid is placed in drying box, at 55 DEG C
Under be evaporated to dryness, obtain starch dry powder, take 25g starch dry powder, be added in 80mL deionized water, stirred at 75 DEG C with 300r/min
35min, cooling one layer of preservative film of rear cover, is placed in 2 DEG C of refrigerators and saves, obtain papery mounting of calligraphy and painting paste-like materials.
Take 60g starch, 1.2g carboxymethyl chitosan, 1.2g nano zine oxide, 1.2g calcium bicarbonate, be added 150mL go from
In sub- water, 30min is dispersed with 500W ultrasonic echography, upper liquid is taken after standing 2h, upper liquid is placed in drying box, at 60 DEG C
Under be evaporated to dryness, obtain starch dry powder, take 30g starch dry powder, be added in 90mL deionized water, stirred at 80 DEG C with 400r/min
40min, cooling one layer of preservative film of rear cover, is placed in 4 DEG C of refrigerators and saves, obtain papery mounting of calligraphy and painting paste-like materials.
Reference examples: the paste-like materials of Shaanxi company production.
The paste-like materials of example and reference examples are detected, specific testing result such as table 1.
1 performance characterization contrast table of table
| Detection project | Example 1 | Example 2 | Example 3 | Reference examples |
| Anti-mildew performance/21 day | Without obvious mildew | Without obvious mildew | Without obvious mildew | It is slight mouldy |
| PH value | 6.58 | 6.87 | 7.56 | 5.58 |
| Mount part appearance | Without significant change | Without significant change | Without significant change | Slight change |
| Folding strength | 23 | 24 | 24 | 16 |
As shown in Table 1, the papery mounting of calligraphy and painting prepared by the present invention paste-like materials have good bacteriostasis property and repair mounting
Performance.
Claims (7)
1. a kind of papery mounting of calligraphy and painting paste-like materials, which is characterized in that the paste-like materials are by starch dry powder and deionized water
Composition, the starch dry powder are made of the component of following portions by weight:
50~60 parts of starch, 1.0~1.2 parts of carboxymethyl chitosans, 1.0~1.2 parts of nano zine oxides, 1.0~1.2 parts of bicarbonates
Calcium.
2. a kind of papery mounting of calligraphy and painting paste-like materials as described in claim 1, which is characterized in that the starch dry powder with go
The mass ratio of ionized water is 1:3.
3. a kind of preparation method of papery mounting of calligraphy and painting paste-like materials as described in claim 1~2 any one, feature
It is, specific steps are as follows:
(1) take starch, carboxymethyl chitosan, nano zine oxide, calcium bicarbonate be added deionized water in ultrasonic disperse, stand 1~
Upper liquid is taken after 2h, upper liquid is evaporated to dryness, and obtains starch dry powder；
(2) take starch dry powder that 30~40min of heating stirring in deionized water is added, cooling one layer of preservative film of rear cover saves, and obtains paper
Matter mounting of calligraphy and painting paste-like materials.
4. a kind of preparation method of papery mounting of calligraphy and painting paste-like materials as claimed in claim 3, which is characterized in that described super
Acoustical power is 300W~500W.
5. a kind of preparation method of papery mounting of calligraphy and painting paste-like materials as claimed in claim 3, which is characterized in that the steaming
Sending out temperature is 50~60 DEG C.
6. a kind of preparation method of papery mounting of calligraphy and painting paste-like materials as claimed in claim 3, which is characterized in that described to add
Thermal agitation process is to stir 30~40min at 70~80 DEG C with 300~400r/min.
7. a kind of preparation method of papery mounting of calligraphy and painting paste-like materials as claimed in claim 3, which is characterized in that the guarantor
Depositing temperature is 1~4 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810900280.XA CN109370473A (en) | 2018-08-09 | 2018-08-09 | A kind of papery mounting of calligraphy and painting paste-like materials and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810900280.XA CN109370473A (en) | 2018-08-09 | 2018-08-09 | A kind of papery mounting of calligraphy and painting paste-like materials and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109370473A true CN109370473A (en) | 2019-02-22 |
Family
ID=65404559
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810900280.XA Pending CN109370473A (en) | 2018-08-09 | 2018-08-09 | A kind of papery mounting of calligraphy and painting paste-like materials and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109370473A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01201383A (en) * | 1988-02-05 | 1989-08-14 | Koji Shimizu | Production of starch-based adhesive having substrate hiding power and for use in application of wall paper |
| CN106390175A (en) * | 2016-08-31 | 2017-02-15 | 暨南大学 | Antibacterial carboxymethyl chitosan/nano zinc oxide composite microsphere and preparation method thereof |
-
2018
- 2018-08-09 CN CN201810900280.XA patent/CN109370473A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01201383A (en) * | 1988-02-05 | 1989-08-14 | Koji Shimizu | Production of starch-based adhesive having substrate hiding power and for use in application of wall paper |
| CN106390175A (en) * | 2016-08-31 | 2017-02-15 | 暨南大学 | Antibacterial carboxymethyl chitosan/nano zinc oxide composite microsphere and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 于孟楠: "传统纸质书画装裱用浆糊材料改进研究", <中国优秀硕士学位论文全文数据库 哲学与人文科学辑> * |
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Application publication date: 20190222 |
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