CN109370382A - Epoxy nano anticorrosive paint - Google Patents
Epoxy nano anticorrosive paint Download PDFInfo
- Publication number
- CN109370382A CN109370382A CN201811271654.2A CN201811271654A CN109370382A CN 109370382 A CN109370382 A CN 109370382A CN 201811271654 A CN201811271654 A CN 201811271654A CN 109370382 A CN109370382 A CN 109370382A
- Authority
- CN
- China
- Prior art keywords
- parts
- nano
- epoxy
- anticorrosive paint
- oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/328—Phosphates of heavy metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention proposes a kind of epoxy nano anticorrosive paints, according to the number of parts by weight, including following components: 35~50 parts of epoxy resin, 35~45 parts of phenolic resin, modified nano zinc oxide -6~12 parts of graphene oxide composite granule, 10~16 parts of fluorinated silicate ceramics, 5~10 parts of bentonite, 10~16 parts of trbasic zinc phosphate, 2~6 parts of coalescing agent, 0.1~0.5 part of dispersing agent, 0.6~1.2 part of rilanit special, 0.1~0.5 part of defoaming agent and 35~45 parts of n-butanol；The modified nano zinc oxide-graphene oxide composite granule is mainly prepared by nano zine oxide, dodecyl sodium sulfate, graphene oxide, itaconic acid and silane coupling agent.Not only antiseptic property is good for the epoxy nano anticorrosive paint, also has good wear-resisting property.
Description
Technical field
The invention belongs to technical field of nano material, and in particular to a kind of epoxy nano anticorrosive paint.
Background technique
In recent years, the fields such as China's oil, chemical industry, new energy are quickly grown, steel as most popular substrate,
The destruction of the corrosive mediums such as dissolved oxygen, hydrogen sulfide is subjected in use process.Currently, the anti-corrosion means generallyd use both at home and abroad are
In the inside and outside wall brushing anticorrosive paint of equipment, to effectively improve the service life of metal equipment, reduce the use of equipment at
This.It shows according to investigations, the yield and sales volume of China's anticorrosive paint occupy the first in the world, and main Types are epoxies, zinc-rich
Class, polyurethanes, chlorinated rubber class, acrylic compounds etc..Wherein, it is epoxies, film forming matter master that it is maximum, which to account for the market share,
If epoxy resin, there is good cohesive force with metal surface, and cure shrinkage is low, strength of coating height, corrosion resistant after solidification
Corrosion can be strong, but its maximum deficiency is that brittleness is big, curing reaction is slow, construction efficiency is low.
In addition, anticorrosive paint is just towards high-environmental, the side of high-performance, functionalization with the continuous improvement of environmental consciousness
To development, in face of the construction environment of harsh use environment and complexity, urgent need develops more practical, constructions easily weight
Anticorrosive paint fundamentally improves aseptic technic system, extends anticorrosive paint market.The development of nanotechnology is that the above problem mentions
Possibility has been supplied, the property (such as heat resistance, insulating properties, chemical stability) that nano particle itself has is applied to prevent again
It in the preparation of rotten coating, can not only improve the synthesis mechanical property of polymer, but also can be improved the corrosion-resistant of anticorrosive paint
The basic physicochemical properties such as property, heat-resisting quantity, stretch resistance.
CN101857753A discloses a kind of anticorrosive paint, coating process and application, is suitable for heat exchanger, heatproof 600
Below degree.But due to making base-material using Silicone modified acryl's resin, easy xanthochromia under high temperature can only do silver-colored black, apply simultaneously
Material is that realize, rate melting secondary film-forming carrys out anti-corrosion under high temperature by the aluminium powder of addition up to 35%, since a large amount of aluminium powder is in high temperature
Under can soften melting, therefore the coating, without red hardness, wearability is very poor under high temperature, at the same be using special ultrasonic activation come into
Row coating, compared with common process, client uses extremely inconvenient.And the trimethylbenzene that coating also uses part toxic makees solvent,
Pole is not environmentally.CN100587017C discloses a kind of solvent type organic silicon thermostable paint and its production method, can high temperature resistant
450~500 degree, but organic resin pyrolytic still can the toxic peculiar smell of generating unit intermuscular needling nose, and can change colour.It can only do black and silver-colored
Black few color can not do light color and bright-colored.The high-temperature resistant coating of the above organic or inorganic, in scumbling, high temperature resistant
Bad anti-corrosion effect, and abrasion resistant effect is poor.
Summary of the invention
The present invention proposes a kind of epoxy nano anticorrosive paint, and not only antiseptic property is good for the epoxy nano anticorrosive paint, also has
Have good wearability energy.
The technical scheme of the present invention is realized as follows:
A kind of epoxy nano anticorrosive paint, according to the number of parts by weight, including following components:
35~50 parts of epoxy resin, 35~45 parts of phenolic resin, modified nano zinc oxide-graphene oxide composite granule 6
~12 parts, 10~16 parts of fluorinated silicate ceramics, 5~10 parts of bentonite, 10~16 parts of trbasic zinc phosphate, coalescing agent 2~6 part, point
0.1~0.5 part of powder, 0.6~1.2 part of rilanit special, 0.1~0.5 part of defoaming agent and 35~45 parts of n-butanol；The modification
Nano zine oxide-graphene oxide composite granule is mainly by nano zine oxide, dodecyl sodium sulfate, graphene oxide, clothing health
Acid is prepared with silane coupling agent.
Preferably, the modified nano zinc oxide-graphene oxide composite granule preparation method the following steps are included:
1) lauryl sodium sulfate is dissolved in 70~80 DEG C of hot n-butanols and is stirred dispersion, then add nanometer
Zinc oxide is stirred dispersion, is ultrasonically treated 0.5~1.5h, then filters drying, can be obtained modified nano zinc oxide powder；
2) modified nano zinc oxide powder and graphene oxide are added in the itaconic acid solution of 2~5wt%, are stirred for point
After dissipating 1~3 hour, 50~60 DEG C are then warming up to, adds silane coupling agent, is reacted 2~4 hours, screening is dried in filtering
?.
Preferably, the lauryl sodium sulfate and the mass ratio of the nano zine oxide are 5~7:1, the nanometer
The mass ratio of zinc oxide and the graphene oxide is 2~3:1, the quality of the nano zine oxide and the silane coupling agent
The ratio between be 15~25:1.
Preferably, the silane coupling agent is aminopropyl triethoxysilane, contracting n-butanol glycerol fan's oxygroup propyl front three
Oxysilane or methacryloxypropyl trimethoxy silane.
Preferably, the coalescing agent is alcohol ester 12 or propandiol butyl ether.
Preferably, the dispersing agent is enuatrol.
Preferably, the defoaming agent is emulsification methyl-silicone oil or non-silicone mineral oil.
The preparation method of epoxy nano anticorrosive paint of the invention, comprising the following steps:
1) first by the epoxy resin of part, the phenolic resin of part, coalescing agent and modified nano zinc oxide-graphite oxide
Ultrasonic disperse is carried out after the mixing of alkene composite granule, the ultrasonic disperse time is 20~40min, obtains dispersion liquid；
2) the dispersion liquid n-butanol bath of step 1) is warming up to 50~60 DEG C, remaining components is added, after being stirred.It is cooling
To room temperature.
The present invention is migrated to film coated surface and is hydrolyzed using ceramic composition by addition fluorinated silicate ceramic composition
It generates hydrophilic silanol group and invests film hydrophily, to reduce pollution.The addition of rilanit special can effectively improve
The sagging phenomenon generated in spraying process, while can be caused in storage due to the density variation of filler and base-material to avoid coating
The bad phenomenons such as sink to the bottom, by the compounding with other components, ceramic material ingredient migration and hydrophiling are very fast, and have
There is good cleaning stability, long-acting hydrophily is still maintained after cleaning.
Beneficial effects of the present invention:
Epoxy nano anticorrosive paint of the present invention using mainly by nano zine oxide, dodecyl sodium sulfate, graphene oxide,
Modified nano zinc oxide-graphene oxide composite granule that itaconic acid and silane coupling agent are prepared, composite granule enhancing
The affinity of nano zine oxide and graphene oxide and matrix resin, obtains with the interface binding power of epoxy resin, phenolic resin
To improve, while the formation of hard agglomeration is prevented or being mitigated, good dispersibility is easy to get, to improve the machine of coating
Tool intensity and adhesive force.In addition, since zinc oxide is coupled by silane coupling agent and graphene oxide, the powder grain of formation
Son tunic easy to form between matrix resin interface, improves the rub resistance and Corrosion Protection of coating.
Specific embodiment
Embodiment 1
Modified nano zinc oxide-graphene oxide composite granule preparation method the following steps are included:
1) lauryl sodium sulfate is dissolved in 70 DEG C of hot n-butanols and is stirred dispersion, then added nano oxidized
Zinc is stirred dispersion, is ultrasonically treated 1.5h, then filters drying, can be obtained modified nano zinc oxide powder；
2) modified nano zinc oxide powder and graphene oxide are added in the itaconic acid solution of 2wt%, are stirred for dispersion 3
After hour, 60 DEG C are then warming up to, adds aminopropyl triethoxysilane, is reacted 2 hours, screening is dried in filtering.
Lauryl sodium sulfate and the mass ratio of nano zine oxide are 7:1, and the mass ratio of nano zine oxide and graphene oxide is
The mass ratio of 2:1, nano zine oxide and aminopropyl triethoxysilane is 15:1.
Modified effect is measured by sedimentation experiment, it is compound to weigh the above-mentioned modified nano zinc oxide-graphene oxide of 1~1.5g
Powder sample is placed in the measuring graduates with ground, and first plus on a small quantity dimethylbenzene sufficiently soaks nano zine oxide-graphene oxide
Afterwards, then plus dimethylbenzene sufficiently vibrated to 20mL uniformly, stand different time under room temperature, record the quality of deposit, and will
It is converted into sedimentation index；The sedimentation index=(quality of sample pellet part/sample gross mass) * 100%
Through test it is found that about 3~5h is just completely heavy in dimethylbenzene without modified nano zine oxide-graphene oxide
Lower, and pass through modified nano zinc oxide-graphene oxide composite granule, in dimethylbenzene by for 24 hours only have 1.2~
1.8% precipitating also only has about 2.6~3.2% precipitating by 48h.Therefore, modified nano zinc oxide-graphene oxide is multiple
Closing in powder has preferable dispersion performance, and modified effect is preferable.
Embodiment 2
Modified nano zinc oxide-graphene oxide composite granule preparation method the following steps are included:
1) lauryl sodium sulfate is dissolved in 80 DEG C of hot n-butanols and is stirred dispersion, then added nano oxidized
Zinc is stirred dispersion, is ultrasonically treated 0.5h, then filters drying, can be obtained modified nano zinc oxide powder；
2) modified nano zinc oxide powder and graphene oxide are added in the itaconic acid solution of 5wt%, are stirred for dispersion 1
After hour, 50 DEG C are then warming up to, adds methacryloxypropyl trimethoxy silane, is reacted 4 hours, filtering will filter
Object drying.Lauryl sodium sulfate and the mass ratio of nano zine oxide are 5:1, nano zine oxide and graphene oxide
Mass ratio is 3:1, and the mass ratio of nano zine oxide and methacryloxypropyl trimethoxy silane is 25:1.
Through test it is found that about 3~5h is just completely heavy in dimethylbenzene without modified nano zine oxide-graphene oxide
Lower, and pass through modified nano zinc oxide-graphene oxide composite granule, in dimethylbenzene by for 24 hours only have 1.2~
1.8% precipitating also only has about 2.6~3.2% precipitating by 48h.Therefore, modified nano zinc oxide-graphene oxide is multiple
Closing in powder has preferable dispersion performance, and modified effect is preferable.
Embodiment 3
A kind of epoxy nano anticorrosive paint, according to the number of parts by weight, including following components:
43 parts of epoxy resin, 24 parts of phenolic resin, embodiment 1 modified nano zinc oxide-graphene oxide composite granule 9
Part, fluorinated silicate ceramic 13 parts, 7 parts of bentonite, 12 parts of trbasic zinc phosphate, 12 parts of alcohol ester, 0.3 part of enuatrol, rilanit special
0.9 part, 0.3 part of methyl-silicone oil of emulsification and 40 parts of n-butanol.
Embodiment 4
A kind of epoxy nano anticorrosive paint, according to the number of parts by weight, including following components:
35 parts of epoxy resin, 28 parts of phenolic resin, embodiment 2 modified nano zinc oxide-graphene oxide composite granule 6
Part, fluorinated silicate ceramic 12 parts, 5 parts of bentonite, 10 parts of trbasic zinc phosphate, 2 parts of propandiol butyl ether, 0.1 part of enuatrol, hydrogenated castor
0.8 part of oil, 0.1 part of methyl-silicone oil of emulsification and 35 parts of n-butanol.
Embodiment 5
A kind of epoxy nano anticorrosive paint, according to the number of parts by weight, including following components:
50 parts of epoxy resin, 20 parts of phenolic resin, embodiment 1 modified nano zinc oxide-graphene oxide composite granule
12 parts, 10 parts of fluorinated silicate ceramics, 10 parts of bentonite, 16 parts of trbasic zinc phosphate, 12 parts of alcohol ester, 0.5 part of enuatrol, hydrogenation castor
0.6 part of sesame oil, 0.5 part of non-silicone mineral oil and 45 parts of n-butanol.
Embodiment 6
A kind of epoxy nano anticorrosive paint, according to the number of parts by weight, including following components:
40 parts of epoxy resin, 26 parts of phenolic resin, embodiment 2 modified nano zinc oxide-graphene oxide composite granule
10 parts, 10 parts of fluorinated silicate ceramics, 8 parts of bentonite, 10 parts of trbasic zinc phosphate, 3 parts of propandiol butyl ether, 0.1 part of enuatrol, hydrogenation castor
0.6 part of sesame oil, 0.5 part of non-silicone mineral oil and 45 parts of n-butanol.
Comparative example 1
A kind of epoxy nano anticorrosive paint, according to the number of parts by weight, including following components:
50 parts of epoxy resin, 24 parts of phenolic resin, nano zine oxide -9 parts of graphene oxide composite granule, fluorinated silicate
13 parts of ceramics, 7 parts of bentonite, 12 parts of trbasic zinc phosphate, 12 parts of alcohol ester, 0.3 part of enuatrol, 0.9 part of rilanit special, emulsification first
0.3 part of base silicone oil and 40 parts of n-butanol.The mass ratio of nano zine oxide and graphene oxide is 2:1.
Test example
Every kind of sample of epoxy nano anticorrosive paint of the epoxy nano anticorrosive paint that embodiment 3~6 is obtained and comparative example 1
It is respectively coated on 4 pieces of test plate (panel)s, one of to do measuring mechanical property, remaining does chemical property test, 100 microns of film thickness, paints
After film maintains 7 days, it is tested for the property, the results are shown in Table 1:
Table 1
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention
Within mind and principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.
Claims (7)
1. a kind of epoxy nano anticorrosive paint, which is characterized in that according to the number of parts by weight, including following components:
35~50 parts of epoxy resin, 35~45 parts of phenolic resin, modified nano zinc oxide-graphene oxide composite granule 6~12
Part, 10~16 parts of fluorinated silicate ceramics, 5~10 parts of bentonite, 10~16 parts of trbasic zinc phosphate, 2~6 parts of coalescing agent, dispersing agent
0.1~0.5 part, 0.6~1.2 part of rilanit special, 0.1~0.5 part of defoaming agent and 35~45 parts of n-butanol；The modified Nano
Zinc oxide-graphene oxide composite granule mainly by nano zine oxide, dodecyl sodium sulfate, graphene oxide, itaconic acid with
Silane coupling agent is prepared.
2. epoxy nano anticorrosive paint according to claim 1, which is characterized in that the modified nano zinc oxide-oxidation
The preparation method of graphene composite powder the following steps are included:
1) lauryl sodium sulfate is dissolved in 70~80 DEG C of hot n-butanols and is stirred dispersion, then added nano oxidized
Zinc is stirred dispersion, is ultrasonically treated 0.5~1.5h, then filters drying, can be obtained modified nano zinc oxide powder；
2) modified nano zinc oxide powder and graphene oxide are added in the itaconic acid solution of 2~5wt%, are stirred for dispersion 1
After~3 hours, 50~60 DEG C are then warming up to, adds silane coupling agent, is reacted 2~4 hours, screening drying is by filtering
It can.
3. epoxy nano anticorrosive paint according to claim 2, which is characterized in that the lauryl sodium sulfate with it is described
The mass ratio of nano zine oxide is 5~7:1, and the mass ratio of the nano zine oxide and the graphene oxide is 2~3:
1, the mass ratio of the nano zine oxide and the silane coupling agent is 15~25:1.
4. epoxy nano anticorrosive paint according to claim 2, which is characterized in that the silane coupling agent is aminopropyl three
Ethoxysilane, contracting n-butanol glycerol fan's oxygroup propyl trimethoxy silicane or methacryloxypropyl trimethoxy silicon
Alkane.
5. epoxy nano anticorrosive paint according to claim 1, which is characterized in that the coalescing agent be alcohol ester 12 or
Person's propandiol butyl ether.
6. epoxy nano anticorrosive paint according to claim 1, which is characterized in that the dispersing agent is enuatrol.
7. epoxy nano anticorrosive paint according to claim 1, which is characterized in that the defoaming agent is emulsification methyl-silicone oil
Or non-silicone mineral oil.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811271654.2A CN109370382A (en) | 2018-10-29 | 2018-10-29 | Epoxy nano anticorrosive paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811271654.2A CN109370382A (en) | 2018-10-29 | 2018-10-29 | Epoxy nano anticorrosive paint |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109370382A true CN109370382A (en) | 2019-02-22 |
Family
ID=65390120
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811271654.2A Withdrawn CN109370382A (en) | 2018-10-29 | 2018-10-29 | Epoxy nano anticorrosive paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109370382A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113337184A (en) * | 2021-06-09 | 2021-09-03 | 广州飞鹿铁路涂料与涂装有限公司 | Anticorrosive paint and preparation method thereof |
| CN115404002A (en) * | 2022-07-19 | 2022-11-29 | 江西必可科技有限公司 | Silicon-carbon modified elastic anticorrosive paint and preparation method thereof |
-
2018
- 2018-10-29 CN CN201811271654.2A patent/CN109370382A/en not_active Withdrawn
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113337184A (en) * | 2021-06-09 | 2021-09-03 | 广州飞鹿铁路涂料与涂装有限公司 | Anticorrosive paint and preparation method thereof |
| CN115404002A (en) * | 2022-07-19 | 2022-11-29 | 江西必可科技有限公司 | Silicon-carbon modified elastic anticorrosive paint and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109439139A (en) | Nano-organosilicon anticorrosive paint | |
| CN105860748B (en) | Solventless epoxy anti-corrosive coating and preparation method thereof | |
| CN109280465A (en) | Nano anti-corrosive loses coating | |
| CN105219208B (en) | A kind of preparation method of epoxy novolac nano anticorrosive coating | |
| CN1325578C (en) | Mixed silicon sol water inorganic zinc enriching paint | |
| CN101892004B (en) | Ultraviolet-cured heat-resistant coating and preparation and application methods thereof | |
| CN104694001B (en) | A kind of preparation method of super-hydrophobic superparamagnetic silicone resin composite material coating | |
| CN107325686A (en) | Binary polymerization graphene nano anticorrosive paint and technology of preparing | |
| CN104212347A (en) | Boron-modified organic silicon resin high-temperature-resistant coating and preparation method thereof | |
| CN107722792A (en) | A kind of preparation method with high anticorrosive property energy epoxy coating | |
| CN104946059A (en) | Anticorrosive paint composition comprising modified ceramic waste and preparation method thereof | |
| CN101899657B (en) | Chromium-free passivating treatment agent and method for preparing same | |
| CN110616014A (en) | Water-based anticorrosive heat-dissipation coating and preparation method thereof | |
| CN108129949A (en) | A kind of preparation method of epoxy heavy-duty anticorrosive coating | |
| CN109836996A (en) | Aqueous thermally conductive anticorrosive paint of one kind and preparation method thereof | |
| CN109575753A (en) | One kind is for steel surface water-base epoxy type anticorrosive paint and preparation method thereof | |
| CN110835487A (en) | Water-based graphene high-thermal-conductivity anticorrosive coating for power battery and preparation method thereof | |
| CN109370382A (en) | Epoxy nano anticorrosive paint | |
| CN104371541A (en) | High-temperature primer for metro wheels and preparation method of high-temperature primer | |
| CN115044279B (en) | Two-dimensional polydopamine reinforced waterborne epoxy composite anticorrosive paint and preparation method and application thereof | |
| CN102796439A (en) | Solvent-free nanometer modified epoxy weather-resistant type anticorrosive paint and preparation method thereof | |
| CN109401488B (en) | High-hardness wear-resistant anti-fouling inorganic nano ceramic modified wood coating and preparation method thereof | |
| CN110305580A (en) | A kind of graphene-based hydrophobic type anticorrosive coating and its preparation method and application | |
| CN110358413A (en) | Graphene fire resistant anticorrosive conductive ethylene base ester cold coating and preparation method | |
| CN105273454A (en) | Nanometer inorganic zinc-rich composite anticorrosive coating and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20190222 |