CN109370377A - It is a kind of based on inorganic material-modified water-base epoxy nuclear power station protective coating and its application method - Google Patents
It is a kind of based on inorganic material-modified water-base epoxy nuclear power station protective coating and its application method Download PDFInfo
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- CN109370377A CN109370377A CN201811216113.XA CN201811216113A CN109370377A CN 109370377 A CN109370377 A CN 109370377A CN 201811216113 A CN201811216113 A CN 201811216113A CN 109370377 A CN109370377 A CN 109370377A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
- C09D1/06—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances cement
- C09D1/08—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances cement with organic additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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Abstract
The present invention relates to technical field of coatings, it provides a kind of based on inorganic material-modified water-base epoxy nuclear power station protective coating, it is grouped as by base-material and two groups of curing agent, base-material and hardener formula are distinguished as follows by weight: base material formulation includes 25-40 parts of self-emulsifying epoxy resin, 0.5-2 parts of wetting dispersing agent, 1-3 parts of anti-settling agent, 25-35 parts of aquation inorganic material, 20-30 parts of radiation hardness pigments and fillers;Hardener formula are as follows: aqueous amine additives 20-40 parts, 1-2 parts of wetting dispersing agent, 1-2 parts of anti-settling agent, 20-50 parts of radiation hardness pigments and fillers, 20-30 parts of water, 3-6 parts of coalescing agent.Coating VOC of the present invention is low, and solid part is high, meets nuclear power protection NB/T20133-2012 requirement, can be used for the nuclear leve coating of nuclear power station steel construction and concrete surface requirement of shelter, is also applied for the metal bases such as general industry carbon steel and concrete surface anti-corrosion protection.
Description
Technical field
The present invention relates to technical field of coatings more particularly to a kind of anti-based on inorganic material-modified water-base epoxy nuclear power station
Protect coating and its application method.
Background technique
Developing new energy is the inexorable trend for realizing sustainable development, and nuclear power is the important of new energy as low-carbon energy
Component part is the important foundation of China's future source of energy sustainable development.According to the Organization of Economy and Cooperation Development and International Energy Agency
Associated prediction, to the year two thousand fifty, global nuclear power generated energy will be doubled on the basis of existing, and power generation ratio will reach world's power generation total amount
17%.But ratio escheat of the current China's nuclear power in power generation total amount is lower, only accounts for 3% or so, far below being averaged for the whole world 11%
It is horizontal.But in existing electrification structure, single coal electricity just accounts for therein 74%.If electricity needs is doubled again, coal is used every year
It just will be more than 1,600,000,000 tons, so big electric consumption of coal, sulfur dioxide and smoke discharge amount increase 5,000,000 tons and 53,260,000 newly respectively every year
Ton or more, while the coal conveying of long range will aggravation environment and transport pressure.In addition, water power is limited by objective condition,
Its development difficulty is quite big.And the exploitation of the renewable energy such as solar energy, biological energy source encounters the bottleneck of core technology, use cost
It is high.Therefore, in following 30 years, these new energy do not have the condition as the main force of China energy.So to ensure
Under the premise of safety, cleaning, efficient and high-power nuclear power are at preferably.
Protective coating used in nuclear power station is more the safe operation for nuclear power station in addition to anti-corrosion purpose.It is protecting
Coating application aspect, only by just adaptable after DBA test, radiation resistance test and detergency ability test.Nuclear leve coating
It is for being related to workshop, equipment and the other structures surface radiated there are the protective coating in the place of nuclear radiation and structure.Especially
It is the containment in nuclear power station centre, there are a large amount of radioactive substance, high radiant matter, high radioactivity fission products to be stained with
It is dirty;Often place under the condition of high temperature and high humidity, is exposed in the reagent of radioactive contamination eliminating, especially in dehydration, wink
Between the intense radiation that is formed along with a large amount of radioactive substance of the high temperature and pressure that generates, while spraying high concentration of boric acid water.Therefore,
Protective coating in nuclear island safety shell cannot have it is serious peel off, flake, dusting, otherwise, a large amount of residue enters in heap
In total emergency coolant liquid, leads to pipeline, pump, nozzle and the total cooling pipe blocking of heap, reduce the function of influencing security system, it can band
Carry out serious safety accident.Nuclear power station needed regularly to carry out nuclear fuel replacement, safety inspection in phase projected life.Therefore, core
The test that must be subjected to radiation resistance test, detergency test and DBA test in power plant safety shell with protective coating, is used for concrete table
Coating materials need certain air-tightness, prevent the nuclear matter of containment from leaking and pollute.
The epoxy coating of nuclear power protection at present belongs to solvent based coating mostly, due to its VOC content height, is applied to mostly
Lower building, environment air-tight moist, the Nuclear Power Station island structure for being unfavorable for sovent diffusion pacify construction personnel's health and facility structure
It is complete that there are hidden danger;Volume solid part of general waterborne epoxy coatings is low, and single track thickness of dry film is thin when construction, influences the construction of coating
Efficiency.Research and development VOC is low, solid part is high, meets the water-base epoxy nuclear leve coating that nuclear power protection NB/T20133-2012 is required
It is of great significance to China's nuclear industry construction level and nuclear power source safety.
Summary of the invention
Therefore, for the above content, it is anti-based on inorganic material-modified water-base epoxy nuclear power station that the present invention provides a kind of
Coating and its application method are protected, VOC low is solved, solid part height, meets the aqueous of nuclear power protection NB/T20133-2012 requirement
The demand of epoxy nuclear leve coating.
In order to achieve the above objectives, the present invention is achieved by the following technical solutions:
It is a kind of based on inorganic material-modified water-base epoxy nuclear power station protective coating, by the two groups of groupings of base-material and curing agent
At base-material and hardener formula difference are as follows:
A further improvement is that: the self-emulsifying epoxy resin is self-emulsifying bisphenol A epoxide resin or self-emulsifying phenolic aldehyde ring
Oxygen resin, the self-emulsifying bisphenol A epoxide resin select the self-emulsifying bisphenol A epoxide resin of epoxide equivalent 170-200, such as WE-
8217, outer emulsifier is not added in self-emulsifying novolac epoxy resin selection, has the good emulsifying capacity degree of functionality to be in water
The self-emulsifying linear phenolic epoxy resin of 2.2-3.6, epoxide equivalent 170-200, such as Araldite PZ756, Beckpox
EP147W。
A further improvement is that: epoxy active diluent resorcinolformaldehyde resin can also be added in the base-material
Or hexanediol diglycidyl ether, additional amount parts by weight are 3-10, the resorcinolformaldehyde resin can be
XY694, the hexanediol diglycidyl ether can be XY632.
A further improvement is that: the aquation inorganic material selects portland cement or aluminate cement or the plaster of paris, or
The mixture that both any or three mixes in any proportion in the above three, preferably portland cement.
A further improvement is that: the aqueous amine additives select the modified polyamide resin for not containing organic solvent,
Active hydrogen equivalent weight 100-140 (solid values).
A further improvement is that: the wetting dispersing agent selection is non-ionic, such as Tego 740W, Tego 757W;It is described
Anti-settling agent selects organically-modified lithium montmorillonite, such as Bentone EW or organics modifications silicate, such as Garamite 7305, or
Fumed silica, such as R972;The radiation hardness pigments and fillers select titanium white, such as R706, CR510 or quartz powder, such as silica
606;The coalescing agent selects alcohol ester -12 (DOW) or DPnB (DOW) or PGDA (DOW).
The method that the coating uses is: the weight proportion of the base-material and curing agent is 1:1 when construction.
By using preceding solution, the beneficial effects of the present invention are:
1, coating of the invention is that VOC content is low, and volume solid part may be up to 90% waterborne epoxy coatings, is had excellent
Radiation-resistant property, accumulate irradiation dose up to 1 × 107Gy;Meet irradiation and DBA composite testing;Nuclear pollutant soil removal efficiency
90% or more;Corrosion Protection is excellent, the capacity of heat transmission is strong, flame propagation ratio is low, air-tightness is good and wear-resisting;To steel construction and
Concrete surface adhesive force is strong;This coating can be applied to the protection of nuclear power station steel construction and concrete surface, single track construction film thickness
Up to 100 μm, aqueous, environmental protective effectively increases the construction efficiency and environment peace of the substrate surface protective coating of nuclear power station air-tight moist
Quan Xing.
2, the good self-emulsifying novolac epoxy resin of the preferred crosslink density high-fire resistance of self-emulsifying epoxy resin of the invention, tree
Rouge is reacted with aqueous amine hardener as film forming matter, and epoxy active diluent, preferably resorcinol can also further be added
Diglycidyl ether and hexanediol diglycidyl ether, additional amount parts by weight are 3-10, that is, reduce VOC, and meet
The crosslink density and heat resistance of coating paint film.
3, aquation inorganic material of the present invention is selected any in portland cement or aluminate cement or the plaster of paris or three
The mixture of the two or three, these aquation inorganic material and water act on the gelinite to form inorganic network, while and epoxy-amine
Cured product form organic and inorganic inierpeneirating network structure, improve coating solid part, paint film intensity, coating anti-nuclear irradiation
Dosage and DBA composite testing result.
4, the weight proportion of base-material and curing agent is that 1:1 can guarantee best quality of forming film when coating application of the present invention.
Specific embodiment
Carry out the embodiment that the present invention will be described in detail below with reference to specific embodiment, how skill is applied to the present invention whereby
Art means solve technical problem, and the realization process for reaching technical effect can fully understand and implement.
Unless otherwise specified, the conventional hand that technological means employed in embodiment is well known to those skilled in the art
Section, used reagent and product are also available commercial.The source of agents useful for same, trade name and it is necessary to list it
Constituent person is indicated on the first occurrence.
Embodiment 1
It is a kind of based on inorganic material-modified water-base epoxy nuclear power station protective coating, by the two groups of groupings of base-material and curing agent
At base-material and hardener formula difference are as follows:
The self-emulsifying epoxy resin is self-emulsifying bisphenol A epoxide resin, epoxide equivalent 170-200.
The weight proportion of the base-material and curing agent is 1:1 when the coating application.
Embodiment 2
It is a kind of based on inorganic material-modified water-base epoxy nuclear power station protective coating, by the two groups of groupings of base-material and curing agent
At base-material and hardener formula difference are as follows:
The weight proportion of the base-material and curing agent is 2:1 when the coating application.
Embodiment 3
It is a kind of based on inorganic material-modified water-base epoxy nuclear power station protective coating, by the two groups of groupings of base-material and curing agent
At base-material and hardener formula difference are as follows:
The weight proportion of the base-material and curing agent is 1:2 when the coating application.
In the present invention, the self-emulsifying epoxy resin WE-8217 originates from auspicious three Chemical Industry Science Co., Ltd in Shandong, can replace
It is changed to self-emulsifying novolac epoxy resin, preferably the degree of functionality self-emulsifying novolac ring that is 2.2-3.6, epoxide equivalent 170-200
Oxygen resin, such as Araldite PZ756 of Huntsman Corporation of the U.S., the Beckpox EP147W of Zhan Xin resin Co., Ltd.
In the present invention, the aquation inorganic material can be in portland cement, aluminate cement, the plaster of paris or three
The mixture of both meanings or three's arbitrary proportion compounding.
In the present invention, the resorcinolformaldehyde resin is epoxy active diluent, and XY694 originates from Anhui and newly far changes
Work Co., Ltd, could alternatively be hexanediol diglycidyl ether, such as the XY632 of New far Chemical Industry Co., Ltd. of Anhui.
In the present invention, the aqueous amine additives select the modified polyamide resin for not containing organic solvent, active hydrogen
Equivalent 100-140 (solid values) can be waterpoxy 751 or the Huntsman Corporation of the U.S. of BASF joint-stock company
Aradur 340, aradur 435 or Zhan Xin resin Co., Ltd Beckpox EH613W, Beckpox
The WE-8115 of auspicious three Chemical Industry Science Co., Ltd of EH623W or Shandong.
In the present invention, the wetting dispersing agent selection is non-ionic, can be the Tego 740W or Tego of German Digao
757W;Anti-settling agent selects organically-modified lithium montmorillonite also to could alternatively be organic such as the Bentone EW of this company of hamming of the U.S.
It is public such as to win wound Degussa for object modified Portland, such as Garamite 7305 or fumed silica of Bi Ke chemical company of Germany
The R972 of department;The radiation hardness pigments and fillers select titanium white, such as the R706 of DuPont Corporation, Jinzhou Titanium Industry Co., Ltd.
CR510 also could alternatively be quartz powder, the silica 606 such as silicon than mining industry Co., Ltd of section;The coalescing agent is selected
The alcohol ester -12 (DOW) of Dow company is decylene glycol ester, also could alternatively be the dipropylene of Dow company
DPnB (DOW) or propylene glycol diacetate PGDA (DOW).
Coating of the present invention meets " NB/T 20133-2012 PWR nuclear power plant facilities and equipment protective coating rule by test
Model " and nuclear power station coating engineering specification performance requirement, it is specific test results in the following table:
Coating of the present invention is also applied for the metal bases such as general industry carbon steel and concrete surface anti-corrosion protection.
The foregoing descriptions are merely the embodiment using this origination techniques content, any those skilled in the art use this wound
Make done modifications and changes, all belong to the scope of the patents of this creation opinion, and is not limited to those disclosed embodiments.
Claims (7)
1. a kind of based on inorganic material-modified water-base epoxy nuclear power station protective coating, it is characterised in that: by base-material and curing agent
Two groups are grouped as, and the base-material and hardener formula difference are as follows:
2. according to claim 1 a kind of based on inorganic material-modified water-base epoxy nuclear power station protective coating, feature
Be: the self-emulsifying epoxy resin is self-emulsifying bisphenol A epoxide resin or self-emulsifying novolac epoxy resin, and the self-emulsifying is double
Phenol A epoxy resin selects the self-emulsifying bisphenol A epoxide resin of epoxide equivalent 170-200, the self-emulsifying novolac epoxy resin choosing
It is 2.2-3.6 with degree of functionality, the self-emulsifying linear phenolic epoxy resin of epoxide equivalent 170-200.
3. it is according to claim 1 or 2 a kind of based on inorganic material-modified water-base epoxy nuclear power station protective coating, it is special
Sign is: the aquation inorganic material is selected any two in portland cement or aluminate cement or the plaster of paris, or the above three
The mixture that person or three mix in any proportion.
4. according to claim 3 a kind of based on inorganic material-modified water-base epoxy nuclear power station protective coating, feature
It is: epoxy active diluent resorcinolformaldehyde resin or hexylene glycol 2-glycidyl can also be added in the base-material
Ether, additional amount parts by weight are 3-10.
5. according to claim 4 a kind of based on inorganic material-modified water-base epoxy nuclear power station protective coating, feature
Be: the aqueous amine additives select the modified polyamide resin for not containing organic solvent, and solid active hydrogen equivalent weight value is
100-140。
6. according to claim 5 a kind of based on inorganic material-modified water-base epoxy nuclear power station protective coating, feature
Be: the wetting dispersing agent is selected non-ionic;The anti-settling agent selects organically-modified lithium montmorillonite or organics modifications silicon
Hydrochlorate or fumed silica;The radiation hardness pigments and fillers select titanium white or quartz powder;The coalescing agent selects U.S.'s pottery
The alcohol ester -12 (DOW) or DPnB (DOW) or PGDA of family name company.
7. being applied according to claim 1 to a kind of protected based on inorganic material-modified water-base epoxy nuclear power station described in 6 Arbitrary Terms
The application method of material, it is characterised in that: the weight proportion of the base-material and curing agent is 1:1 when construction.
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Cited By (4)
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CN111076030A (en) * | 2019-12-20 | 2020-04-28 | 苏州热工研究院有限公司 | Corrosion control method under heat-insulating layer |
CN111662607A (en) * | 2019-03-05 | 2020-09-15 | 河北晨阳工贸集团有限公司 | Modified solvent type epoxy coating for nuclear power station and preparation method thereof |
CN112961579A (en) * | 2021-04-21 | 2021-06-15 | 大使涂料(安徽)有限公司 | Nuclear power station anti-seepage coating |
CN113549384A (en) * | 2021-07-02 | 2021-10-26 | 信和新材料(苏州)有限公司 | Epoxy resin coating and preparation method and application thereof |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111662607A (en) * | 2019-03-05 | 2020-09-15 | 河北晨阳工贸集团有限公司 | Modified solvent type epoxy coating for nuclear power station and preparation method thereof |
CN111076030A (en) * | 2019-12-20 | 2020-04-28 | 苏州热工研究院有限公司 | Corrosion control method under heat-insulating layer |
CN112961579A (en) * | 2021-04-21 | 2021-06-15 | 大使涂料(安徽)有限公司 | Nuclear power station anti-seepage coating |
CN113549384A (en) * | 2021-07-02 | 2021-10-26 | 信和新材料(苏州)有限公司 | Epoxy resin coating and preparation method and application thereof |
CN113549384B (en) * | 2021-07-02 | 2022-12-06 | 信和新材料(苏州)有限公司 | Epoxy resin coating and preparation method and application thereof |
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Application publication date: 20190222 |