CN103396719A - High-solid-state epoxy coating used for a plurality of nuclear reactor types - Google Patents
High-solid-state epoxy coating used for a plurality of nuclear reactor types Download PDFInfo
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Abstract
The invention relates to the technical field of chemical coatings. A high-solid-state epoxy coating used for a plurality of nuclear reactor types comprises a first component and a second component; the first component comprises: by weight, 25-40 parts of epoxy resin, 5-10 parts of an epoxy activity diluent, 30-50 parts of a radiation resistant color filler, 0-3 parts of an anti-settling agent, 1-5 parts of a wetting dispersant, 5-10 parts of a solvent and 0-5 parts of an antifoaming agent; and the second component comprises: by weight, 20-60 parts of anacardol-modified phenolic aldehyde amine, 10-20 parts of an alicyclic amine additive product, 20-50 parts of the radiation resistant color filler, 0-5 parts of the wetting dispersant, 5-10 parts of the solvent and 0-5 parts of the antifoaming agent. In the high-solid-state epoxy coating, the volume solid part reaches up to 85%, the high-solid-state epoxy coating has a strong adhesive force to steel structures and concrete surfaces, can meet irradiation and LOCA (loss of coolant accident) compound tests, and has excellent irradiation resistance; the cumulative irradiation dose can reach 1*107Gy, the decontamination rate can reach above 95%; and the high-solid-state epoxy coating has a good heat conduction capability, a low flame propagation ratio, air permeability performances and wear resistance.
Description
Technical field
The present invention relates to the chemistry painting industry technical field, particularly relate to the solid-state epoxy coating of a kind of height for multiple nuclear reactor type.
Background technology
The developing goal that the year two thousand twenty China's GDP quadruples is estimated domestic hundred million kilowatts of the capacity of installed generator 8-9 that approximately need at this point, and existing installed capacity is only 400,000,000 kilowatts.But in existing electrification structure, the coal electricity accounted for wherein 74%.If electricity needs is doubled again, every year just will be over 1,600,000,000 tons with coal, large electric consumption of coal like this, and sulfurous gas and smoke discharge amount are newly-increased more than 5,000,000 tons and 5,326 ten thousand tons respectively every year, with the coal of duration distance, carry and will aggravate environment and transport pressure.In addition, water power is subject to the restriction of objective condition, and its development difficulty is quite large.And the exploitation of the renewable energy sources such as sun power, bioenergy runs into the bottleneck of core technology, and its use cost is high.Therefore, in 30 years of future, these new forms of energy do not possess the condition that becomes China main force energy.So clean, efficient and high-power nuclear power has become preferred.
The nuclear power protective coating is important to the safe and effective operation meaning that keeps nuclear power facility.Be applied to the coating of Nuclear power plants, by it, use position, can be divided into core level and non-core level coating.Core level coating is be used to the place that has nuclear radiation and the protective coating of structure, relates to factory building, equipment and other body structure surface of radiation.The protective coating that Nuclear power plants is all, except anticorrosion purpose, is more the safe operation for Nuclear power plants.In the protective coating application facet, only have by just adaptable after LOCA test, radiation hardness and detergency ability test.Core level coating is be used to the place that has nuclear radiation and the protective coating of structure, relates to factory building, equipment and other body structure surface of radiation.Particularly, there is the contamination of a large amount of radioactive substances, high radiant matter, high radioactivity fission product in the reactor housing in Nuclear power plants centre; Particularly, there is a large amount of radioactive substances in the reactor housing in Nuclear power plants centre in the application of paint environment for use; Often be under hot and humid condition, be exposed to and remove in alpha-contamination reagent, particularly in the dehydration situation, the High Temperature High Pressure that moment produces is accompanied by the severe radiation that a large amount of radioactive substances forms, and sprays simultaneously high concentration of boric acid water.Therefore, be applied to protective coating in the nuclear island reactor housing cannot have serious peel off, flake, efflorescence.Otherwise a large amount of resistatess enters in heap in the cooling fluid of always meeting an urgent need, and reduces the function that affects security system, brings serious security incident.Therefore, the reactor housing interior finish must stand the examination of anti-irradiation test, detergency test and DBA test, and coating needs certain resistance to air loss simultaneously, prevents that the nuclear substance leakage of reactor housing from polluting.
At present nuclear power protection is the solvent based coating that hangs down solid part with epoxy coating, and nuclear industrial facility mostly is hypogee, and the airtight humidity of environment is unfavorable for the nuclear island structure of solvent diffusion.Solvent based coating uses in nuclear island, because its volatility is high, the personnel health is existed to potential safety hazard.And due to China's nuclear power developing, adopted the pattern of introduction and autonomous research, nuclear-power reactor type abundant species is various, and various heap type causes coating type and painting assembly set complexity loaded down with trivial details to the requirement difference of protective coating, application inconvenience.
Summary of the invention
In order to solve the problems of the technologies described above, technical solution of the present invention provides a kind of preferred epoxy of passing through, solidifying agent, the type of radiation hardness filler and proportioning, prepare the low VOC of high solid, meet nuclear power protection NB/T20133.X-2012 requirement, can be used for the solid-state epoxy coating of height of the requirement of shelter of multiple nuclear reactor type (for example AP1000, APR1000 and CANDU).
In order to achieve the above object, the solid-state epoxy coating of a kind of height for multiple nuclear reactor type of the present invention, be comprised of first and second liang of components, wherein,
The first component is counted by weight, fills a prescription as follows: epoxy resin 25-40 part, epoxy active diluent 5-10 part, radiation hardness color stuffing 30-50 part, anti-settling agent 0-3 part, wetting dispersing agent 1-5 part, defoamer 0-5 part, solvent 5-10 part;
The second component is solidifying agent, and it is counted by weight, fills a prescription as follows: modified by cardanol phenolic aldehyde amine 20-60 part, aliphatic cyclic amine affixture 10-20 part, radiation hardness color stuffing 20-50 part, wetting dispersing agent 0-5 part, solvent 5-10 part, defoamer 0-5 part.
Preferably, described epoxy resin is the mixture of bisphenol-A epoxy and novolac epoxy.Adopt the good novolac epoxy of cross-linking density high heat resistance, mix the bisphenol-A epoxy that adds liquid.
Preferably, described epoxy active diluent is resorcinol diglycidyl ether and/or trishydroxymethyl triglycidyl ether, adopts epoxy active diluent both to reduce VOC, has met again cross-linking density and the resistance toheat of coating.
Preferably, described radiation hardness color stuffing is selected the iron mica of Antiradiation excellent property, talcum powder, titanium dioxide, mica powder, a kind of or arbitrary combination in silicon powder and silica powder.These color stuffings not only have good Corrosion Protection, and excellent radiation resistance is also arranged, and after irradiation, do not produce new source of radiation, and cost are low.
Preferably, described anti-settling agent is selected the N monomethyl pyrrolidone solution of organobentonite, castor oil derivative, aerosil, polyolefin-wax (particulate), modified hydrogenated Viscotrol C, modification polyureas and a kind of or arbitrary combination in polyamide wax series.Due to anti-settling agent, be the rheology control agent of a class coating, it makes coating have thixotropy, and viscosity improves greatly.
Preferably, described wetting dispersing agent is selected the low dispersal agent molecule of solvent-borne type and/or solvent-borne type macromolecule dispersing agent, the low dispersal agent molecule of solvent-borne type is mainly with being mainly the oligopolymer that linear alkyl amides or branch type polycarboxylic acid or polycarboxylic acid and polyamine form, non-ionic type is in the majority, and the solvent-borne type macromolecule dispersing agent is mainly reactive derivative, polyurethanes and the grafted propylene acid copolymer of polyester backbone structure.
Preferably, described solvent is selected varsol and/or oxo solvent, and varsol is mainly the products such as aliphatic hydrocarbon, aromatic hydrocarbon, chlorinated hydrocarbon and terpene hydrocarbon, and oxo solvent is mainly the products such as alcohol, ketone, ester and alcohol ether.
Preferably, described defoamer is selected polyether modified siloxane.
The present invention, by adopting technique scheme, compared with prior art, has following advantage:
1, the solid-state epoxy coating of a kind of height for multiple nuclear reactor type of the present invention, its volume solid part are up to 85%, and spraying application VOC is less than 250g/l, and to steel construction and concrete surface strong adhesion, air-tightness is good; Excellent radiation-resistant property, the accumulation irradiation dose can reach 1 * 10
7Gy; Soil removal efficiency reaches more than 95%; The capacity of heat transmission, flame propagation ratio that air-tightness and wear resistance are good, good are low, can meet the LOCA/DBA composite testing.
2, the solid-state epoxy coating of a kind of height for multiple nuclear reactor type of the present invention, volatility is low, less on personnel health's impact, research and development VOC is low, solid part is high, meet the core level coating that nuclear power protection NB/T20133.X-2012 requires, and China's nuclear industry its construction level and nuclear power source security are significant.
Embodiment
Embodiment 1:
As a specific embodiment, the solid-state epoxy coating of a kind of height for multiple nuclear reactor type of the present invention, be comprised of first and second liang of components, wherein,
The first component is counted by weight, fills a prescription as follows:
25 parts of epoxy resin, be specially 5 parts of 20 parts of formaldehyde epoxy resins and liquid bisphenol-A epoxies,
5 parts of epoxy active diluents, be specially 5 parts of resorcinol diglycidyl ethers,
30 parts of radiation hardness color stuffings, be specially 5 parts of 10 parts of titanium dioxides, 15 parts of silicon powders and talcum powder,
1 part of wetting dispersing agent, described wetting dispersing agent can be selected the low dispersal agent molecule of solvent-borne type and/or solvent-borne type macromolecule dispersing agent, the low dispersal agent molecule of solvent-borne type is mainly with being mainly the oligopolymer that linear alkyl amides or branch type polycarboxylic acid or polycarboxylic acid and polyamine form, non-ionic type is in the majority, and the solvent-borne type macromolecule dispersing agent is mainly reactive derivative, polyurethanes and the grafted propylene acid copolymer of polyester backbone structure.
5 parts of solvents, described solvent can be selected the mixture of varsol and/or oxo solvent and/or water, and varsol is mainly the products such as aliphatic hydrocarbon, aromatic hydrocarbon, chlorinated hydrocarbon and terpene hydrocarbon, and oxo solvent is mainly the products such as alcohol, ketone, ester and alcohol ether.
The second component is solidifying agent, and it is counted by weight, fills a prescription as follows:
20 parts of modified by cardanol phenolic aldehyde amine,
10 parts of aliphatic cyclic amine affixtures,
20 parts of radiation hardness color stuffings, be specially 20 parts of talcum powder,
5 parts of solvents, described solvent can be selected the mixture of varsol and/or oxo solvent and/or water, and varsol is mainly the products such as aliphatic hydrocarbon, aromatic hydrocarbon, chlorinated hydrocarbon and terpene hydrocarbon, and oxo solvent is mainly the products such as alcohol, ketone, ester and alcohol ether.
Above-mentioned the first and second components are mixed in the 4-6:1 ratio, the thinner that adds 5-10% while using spraying, this thinner can be selected non-activated thinner, such as acetone, methylethylketone, pimelinketone, benzene,toluene,xylene, propyl carbinol etc., the VOC that calculates this coating is 150g/l, makes high solid-state epoxy coating, namely can be used for construction, this coating is conducive to apply in airtight nuclear island structure, meets the standard-required of NB/T20133.
Embodiment 2:
As a specific embodiment, the solid-state epoxy coating of a kind of height for multiple nuclear reactor type of the present invention, be comprised of first and second liang of components, wherein,
The first component is counted by weight, fills a prescription as follows:
40 parts of epoxy resin, be specially 15 parts of 25 parts of novolac epoxys and liquid bisphenol-A epoxies,
10 parts of epoxy active diluents, be specially 6 parts of 4 parts of Resorcinol 2-glycidyls and trishydroxymethyl triglycidyl ether,
50 parts of radiation hardness color stuffings, be specially 10 parts of titanium dioxides, 35 parts of 5 parts of talcum powder and silicon powders,
3 parts of anti-settling agents, described anti-settling agent are selected the N monomethyl pyrrolidone solution of organobentonite, castor oil derivative, aerosil, polyolefin-wax (particulate), modified hydrogenated Viscotrol C, modification polyureas and a kind of or arbitrary combination in polyamide wax series.Due to anti-settling agent, be the rheology control agent of a class coating, it makes coating have thixotropy, and viscosity improves greatly.
5 parts of wetting dispersing agents, described wetting dispersing agent can be selected the low dispersal agent molecule of solvent-borne type and/or solvent-borne type macromolecule dispersing agent, the low dispersal agent molecule of solvent-borne type is mainly with being mainly the oligopolymer that linear alkyl amides or branch type polycarboxylic acid or polycarboxylic acid and polyamine form, non-ionic type is in the majority, and the solvent-borne type macromolecule dispersing agent is mainly reactive derivative, polyurethanes and the grafted propylene acid copolymer of polyester backbone structure.
10 parts of solvents, described solvent can be selected the mixture of varsol and/or oxo solvent and/or water, and varsol is mainly the products such as aliphatic hydrocarbon, aromatic hydrocarbon, chlorinated hydrocarbon and terpene hydrocarbon, and oxo solvent is mainly the products such as alcohol, ketone, ester and alcohol ether.
5 parts of defoamers, described defoamer is selected polyether modified siloxane.
The second component is solidifying agent, and it is counted by weight, fills a prescription as follows:
60 parts of modified by cardanol phenolic aldehyde amine,
20 parts of aliphatic cyclic amine affixtures,
50 parts of radiation hardness color stuffings, be specially 50 parts of talcum powder,
5 parts of wetting dispersing agents, described wetting dispersing agent can be selected the low dispersal agent molecule of solvent-borne type and/or solvent-borne type macromolecule dispersing agent, the low dispersal agent molecule of solvent-borne type is mainly with being mainly the oligopolymer that linear alkyl amides or branch type polycarboxylic acid or polycarboxylic acid and polyamine form, non-ionic type is in the majority, and the solvent-borne type macromolecule dispersing agent is mainly reactive derivative, polyurethanes and the grafted propylene acid copolymer of polyester backbone structure.
10 parts of solvents, described solvent can be selected the mixture of varsol and/or oxo solvent and/or water, and varsol is mainly the products such as aliphatic hydrocarbon, aromatic hydrocarbon, chlorinated hydrocarbon and terpene hydrocarbon, and oxo solvent is mainly the products such as alcohol, ketone, ester and alcohol ether.
5 parts of defoamers, described defoamer is selected polyether modified siloxane.
Above-mentioned the first and second components are mixed in the 4-6:1 ratio, the thinner that adds 5-10% while using spraying, this thinner can be selected non-activated thinner, such as acetone, methylethylketone, pimelinketone, benzene,toluene,xylene, propyl carbinol etc., the VOC that calculates this coating is 145g/l, makes high solid-state epoxy coating, namely can be used for construction, this coating is conducive to apply in airtight nuclear island structure, meets the standard-required of NB/T20133.
Embodiment 3:
As a specific embodiment, the solid-state epoxy coating of a kind of height for multiple nuclear reactor type of the present invention, be comprised of first and second liang of components, wherein,
The first component is counted by weight, fills a prescription as follows:
35 parts of epoxy resin, be specially 20 parts of 15 parts of novolac epoxys and liquid bisphenol-A epoxies,
8 parts of epoxy active diluents, be specially 5 parts of 3 parts of Resorcinol 2-glycidyls and trishydroxymethyl triglycidyl ether,
40 parts of radiation hardness color stuffings, be specially 5 parts of titanium dioxides, 10 parts of talcum powder, and 25 parts of silica powders,
2 parts of anti-settling agents, described anti-settling agent are selected the N monomethyl pyrrolidone solution of organobentonite, castor oil derivative, aerosil, polyolefin-wax (particulate), modified hydrogenated Viscotrol C, modification polyureas and a kind of or arbitrary combination in polyamide wax series.Due to anti-settling agent, be the rheology control agent of a class coating, it makes coating have thixotropy, and viscosity improves greatly,
3 parts of wetting dispersing agents, described wetting dispersing agent can be selected the low dispersal agent molecule of solvent-borne type and/or solvent-borne type macromolecule dispersing agent, the low dispersal agent molecule of solvent-borne type is mainly with being mainly the oligopolymer that linear alkyl amides or branch type polycarboxylic acid or polycarboxylic acid and polyamine form, non-ionic type is in the majority, the solvent-borne type macromolecule dispersing agent is mainly reactive derivative, polyurethanes and the grafted propylene acid copolymer of polyester backbone structure
7 parts of solvents, described solvent can be selected the mixture of varsol and/or oxo solvent and/or water, and varsol is mainly the products such as aliphatic hydrocarbon, aromatic hydrocarbon, chlorinated hydrocarbon and terpene hydrocarbon, and oxo solvent is mainly the products such as alcohol, ketone, ester and alcohol ether.
3 parts of defoamers, described defoamer is selected polyether modified siloxane.
The second component is solidifying agent, and it is counted by weight, fills a prescription as follows:
45 parts of modified by cardanol phenolic aldehyde amine,
15 parts of aliphatic cyclic amine affixtures,
35 parts of radiation hardness color stuffings, be specially 35 parts of talcum powder,
3 parts of wetting dispersing agents, described wetting dispersing agent can be selected the low dispersal agent molecule of solvent-borne type and/or solvent-borne type macromolecule dispersing agent, the low dispersal agent molecule of solvent-borne type is mainly with being mainly the oligopolymer that linear alkyl amides or branch type polycarboxylic acid or polycarboxylic acid and polyamine form, non-ionic type is in the majority, the solvent-borne type macromolecule dispersing agent is mainly reactive derivative, polyurethanes and the grafted propylene acid copolymer of polyester backbone structure
8 parts of solvents, described solvent can be selected the mixture of varsol and/or oxo solvent and/or water, and varsol is mainly the products such as aliphatic hydrocarbon, aromatic hydrocarbon, chlorinated hydrocarbon and terpene hydrocarbon, and oxo solvent is mainly the products such as alcohol, ketone, ester and alcohol ether.
3 parts of defoamers, described defoamer is selected polyether modified siloxane.
Above-mentioned the first and second components are mixed in the 4-6:1 ratio, the thinner that adds 5-10% while using spraying, this thinner can be selected non-activated thinner, such as acetone, methylethylketone, pimelinketone, benzene,toluene,xylene, propyl carbinol etc., the VOC that calculates this coating is 145g/l, makes high solid-state epoxy coating, namely can be used for construction, this coating is conducive to apply in airtight nuclear island structure, meets the standard-required of NB/T20133.
Although specifically show and introduced the present invention in conjunction with preferred embodiment; but the those skilled in the art should be understood that; within not breaking away from the spirit and scope of the present invention that appended claims limits; can make a variety of changes the present invention in the form and details, be protection scope of the present invention.
Claims (10)
1. solid-state epoxy coating of the height for multiple nuclear reactor type, it is characterized in that: by first and second liang of components, formed, wherein, the first component is counted by weight, fills a prescription as follows: epoxy resin 25-40 part, epoxy active diluent 5-10 part, radiation hardness color stuffing 30-50 part, anti-settling agent 0-3 part, wetting dispersing agent 1-5 part, solvent 5-10 part, defoamer 0-5 part;
The second component is solidifying agent, and it is counted by weight, fills a prescription as follows: modified by cardanol phenolic aldehyde amine 20-60 part, aliphatic cyclic amine affixture 10-20 part, radiation hardness color stuffing 20-50 part, wetting dispersing agent 0-5 part, solvent 5-10 part, defoamer 0-5 part.
2. the solid-state epoxy coating of a kind of height for multiple nuclear reactor type according to claim 1, it is characterized in that: described epoxy resin is the mixture of bisphenol-A epoxy and novolac epoxy.
3. the solid-state epoxy coating of a kind of height for multiple nuclear reactor type according to claim 1, it is characterized in that: described epoxy active diluent is resorcinol diglycidyl ether and/or trishydroxymethyl triglycidyl ether.
4. the solid-state epoxy coating of a kind of height for multiple nuclear reactor type according to claim 1, it is characterized in that: described radiation hardness color stuffing is iron mica, talcum powder, titanium dioxide, mica powder, a kind of or arbitrary combination in silicon powder and silica powder.
5. the solid-state epoxy coating of a kind of height for multiple nuclear reactor type according to claim 1, it is characterized in that: described anti-settling agent is selected the N monomethyl pyrrolidone solution of organobentonite, castor oil derivative, aerosil, polyolefin-wax, modified hydrogenated Viscotrol C, modification polyureas and a kind of or arbitrary combination in polyamide wax series.
6. the solid-state epoxy coating of a kind of height for multiple nuclear reactor type according to claim 1 is characterized in that: described wetting dispersing agent is selected the low dispersal agent molecule of solvent-borne type and/or solvent-borne type macromolecule dispersing agent.
7. the solid-state epoxy coating of a kind of height for multiple nuclear reactor type according to claim 6 is characterized in that: the low dispersal agent molecule of described solvent-borne type is linear alkyl amides or branch type polycarboxylic acid or polycarboxylic acid and the oligopolymer of polyamine composition.
8. the solid-state epoxy coating of a kind of height for multiple nuclear reactor type according to claim 6, is characterized in that: the reactive derivative that described solvent-borne type macromolecule dispersing agent is the polyester backbone structure, polyurethanes and grafted propylene acid copolymer.
9. the solid-state epoxy coating of a kind of height for multiple nuclear reactor type according to claim 1, it is characterized in that: described solvent is selected varsol and/or oxo solvent, and varsol is a kind of or arbitrary combination in aliphatic hydrocarbon, aromatic hydrocarbon, chlorinated hydrocarbon and terpene hydrocarbon.
10. the solid-state epoxy coating of a kind of height for multiple nuclear reactor type according to claim 1, it is characterized in that: described defoamer is selected polyether modified siloxane.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105694677A (en) * | 2016-04-27 | 2016-06-22 | 黄河科技学院 | Novolac epoxy resin radiation protective paint and preparation method thereof |
| CN105778717A (en) * | 2016-04-01 | 2016-07-20 | 厦门大学 | Fluorine-silicone containing epoxy resin radiation-resistant coating and preparation method thereof |
| CN106243301A (en) * | 2016-08-24 | 2016-12-21 | 泰州精英化成医药科技有限公司 | The synthetic method of a kind of polyamide modified phenolic aldehyde amine epoxy resin and corresponding high tenacity low-temperature quick-dry heavy-duty antiseptic paint thereof |
| CN114773964A (en) * | 2022-05-13 | 2022-07-22 | 珠海市威旗防腐科技股份有限公司 | Irradiation-resistant polyamide novolac epoxy paint and preparation method and application thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100240811A1 (en) * | 2009-03-18 | 2010-09-23 | He Yufang | Thermosetting Resin Composition and Application Thereof |
| KR20100113764A (en) * | 2009-04-14 | 2010-10-22 | 엘지이노텍 주식회사 | Adhesive for semiconductor packaging with ion exchangers |
| CN102260425A (en) * | 2011-06-17 | 2011-11-30 | 江苏普兰纳涂料有限公司 | High-performance epoxy grout for megawatt-level wind turbine blades and preparation method thereof |
| CN102618148A (en) * | 2012-03-30 | 2012-08-01 | 北京红狮漆业有限公司 | Epoxy coating and preparation method and application thereof |
| CN102888176A (en) * | 2012-09-06 | 2013-01-23 | 上海大通涂料化工有限公司 | Heat reflection type epoxy anti-corrosion coating |
-
2013
- 2013-08-06 CN CN2013103387308A patent/CN103396719A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100240811A1 (en) * | 2009-03-18 | 2010-09-23 | He Yufang | Thermosetting Resin Composition and Application Thereof |
| KR20100113764A (en) * | 2009-04-14 | 2010-10-22 | 엘지이노텍 주식회사 | Adhesive for semiconductor packaging with ion exchangers |
| CN102260425A (en) * | 2011-06-17 | 2011-11-30 | 江苏普兰纳涂料有限公司 | High-performance epoxy grout for megawatt-level wind turbine blades and preparation method thereof |
| CN102618148A (en) * | 2012-03-30 | 2012-08-01 | 北京红狮漆业有限公司 | Epoxy coating and preparation method and application thereof |
| CN102888176A (en) * | 2012-09-06 | 2013-01-23 | 上海大通涂料化工有限公司 | Heat reflection type epoxy anti-corrosion coating |
Non-Patent Citations (4)
| Title |
|---|
| 倪玉德: "《涂料用溶剂与助剂》", 30 June 2012, article "助剂" * |
| 瞿雄伟等: "《腰果酚及腰果酚类树脂》", 31 January 2013, article "腰果酚" * |
| 肖保谦: "《涂料分析检验工》", 31 January 2006, article "触变剂" * |
| 陈国权等: "《涂料添加剂的制法、配方及开发》", 31 March 1989, article "防尘剂" * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105778717A (en) * | 2016-04-01 | 2016-07-20 | 厦门大学 | Fluorine-silicone containing epoxy resin radiation-resistant coating and preparation method thereof |
| WO2017166913A1 (en) * | 2016-04-01 | 2017-10-05 | 厦门大学 | Radiation-resistant fluorine-silicon containing epoxy-resin coating and preparation method thereof |
| CN105694677A (en) * | 2016-04-27 | 2016-06-22 | 黄河科技学院 | Novolac epoxy resin radiation protective paint and preparation method thereof |
| CN106243301A (en) * | 2016-08-24 | 2016-12-21 | 泰州精英化成医药科技有限公司 | The synthetic method of a kind of polyamide modified phenolic aldehyde amine epoxy resin and corresponding high tenacity low-temperature quick-dry heavy-duty antiseptic paint thereof |
| CN114773964A (en) * | 2022-05-13 | 2022-07-22 | 珠海市威旗防腐科技股份有限公司 | Irradiation-resistant polyamide novolac epoxy paint and preparation method and application thereof |
| CN114773964B (en) * | 2022-05-13 | 2023-05-26 | 珠海市威旗防腐科技股份有限公司 | Irradiation-resistant polyamide phenolic epoxy paint and preparation method and application thereof |
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Application publication date: 20131120 |