CN109370073A - Medicinal chlorinated butyl rubber bung and its preparation process - Google Patents
Medicinal chlorinated butyl rubber bung and its preparation process Download PDFInfo
- Publication number
- CN109370073A CN109370073A CN201811220294.3A CN201811220294A CN109370073A CN 109370073 A CN109370073 A CN 109370073A CN 201811220294 A CN201811220294 A CN 201811220294A CN 109370073 A CN109370073 A CN 109370073A
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- Prior art keywords
- butyl rubber
- medicinal
- chlorinated butyl
- parts
- rubber bung
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
- C08J3/246—Intercrosslinking of at least two polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/26—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers modified by chemical after-treatment
- C08J2323/28—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers modified by chemical after-treatment by reaction with halogens or halogen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/04—Homopolymers or copolymers of ethene
- C08J2423/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/346—Clay
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
Abstract
The present invention relates to a kind of medicinal chlorinated butyl rubber bung and its preparation processes, belong to medicinal bottle stopper Material Field, are prepared by the raw material of following mass fraction: 100 parts of chlorinated scoline；1.0-2.0 parts of crosslinking agent；0.3-0.5 parts of acid absorbent；50-80 parts of calcined kaolin；5-10 parts of white carbon black；2-4 parts of polyethylene wax；2-3 parts of titanium dioxide；0.1-0.3 parts of carbon black.The present invention relates to a kind of medicinal chlorinated butyl rubber bungs and preparation method thereof.Clarity is good in chemical property detection, and when rubber plug and drug contact, there is no the risks of pollution drug；Use crosslinking agent B SH as vulcanizing agent, uses small amounts magnesium that there is good heat resistance as the vulcanizing system of medicinal chlorinated butyl rubber bung as acid absorbent.
Description
Technical field
The present invention relates to a kind of medicinal chlorinated butyl rubber bung and its preparation processes, belong to medicinal bottle stopper Material Field.
Background technique
The vulcanizing system that current the most frequently used chlorinated scoline bottle stopper uses is resin zinc oxide system, but the use of zinc is not
Conducive to the cleanliness for promoting bottle stopper, the encapsulation of the drug especially changed greatly to pH value is more unfavorable, in addition in view of oxidation
For zinc to the sensibility and incompatibility problem of some drugs, the vulcanizing system that exploitation does not need zinc oxide, which is only, solves the problems, such as this
Effective way.
Crosslinking agent B SH is a kind of double sulfydryl salt of not carbon azacyclo-, is applied to when chlorinated scoline as vulcanizing agent, no
Effectively crosslinking can be realized to chlorinated scoline by needing to be oxidized zinc, while can promote water resistant, heat resistanceheat resistant and the chemically-resistant of product
Property.In the test of the drug strong with antibiotics, especially acid-base property, compatibility is significantly better than the conduct of resin zinc oxide
The product of vulcanizing system.That is crosslinking agent B SH has better drug compatibility as the chlorinated butyl rubber bung of vulcanizing agent.
Current field has the following disadvantages in summary:
1, the chlorinated scoline piston of currently used resin curative systems production, the clarity in chemical property detection
It is bad, when being easy to cause rubber plug and drug contact, make the risk that there is pollution drug；
2, there is poor heat resistance in the chlorinated butyl rubber bung using resin zinc oxide as vulcanizing system；
3, the resin curative systems of the medicinal chlorinated butyl rubber bung of tradition need to use zinc oxide as activating agent, be unfavorable for bottle stopper
Inherent cleanliness, no zinc vulcanizing system can promote the quality of bottle stopper product.
Summary of the invention
The problem to be solved by the present invention is that overcoming the deficiencies of the prior art and provide a kind of medicinal chlorinated butyl rubber bung
And its preparation process, use crosslinking agent B SH as vulcanizing agent, uses small amounts magnesium as acid absorbent, as medicinal chlorination fourth
The vulcanizing system of base rubber stopper, obtained product clarity is good, when being easy to cause rubber plug and drug contact, makes the presence of pollution drug
Risk, be provided simultaneously with good heat resistance.
The present invention is implemented as follows:
A kind of medicinal chlorinated butyl rubber bung, is prepared by the raw material of following mass fraction；
| Chlorinated scoline | 100 |
| Crosslinking agent | 1.0-2.0 |
| Acid absorbent | 0.3-0.5 |
| Calcined kaolin | 50-80 |
| White carbon black | 5-10 |
| Polyethylene wax | 2-4 |
| Titanium dioxide | 2-3 |
| Carbon black | 0.1-0.3。 |
Described: crosslinking agent is the double sulfydryl salt (BSH) of carbon azacyclo-.
Described: acid absorbent is magnesia.
Described: the preparation process of medicinal chlorinated butyl rubber bung is as follows:
Raw material cooperation → mixing → preforming → sulfidization molding → flash trimming → cleaning → packaging；
(1) it is kneaded: into after factory's ingredient inspection qualification, after carrying out ingredient according to formula, carrying out mixing, mill to various raw materials
It is stored after being mixed, lower turn after parking 24 hours or more；
(2) preforming: rubber compound is stored after extrusion, calendering, cooling and cut-parts, parks 4 hours or more, in advance at
Type quality inspection to film length and width, wait sulfidization molding again；
(3) it sulfidization molding: is chemically crosslinked in vulcanizing equipment according to the technique of regulation, sulfidization molding；
(4) flash trimming: being punched out the film after vulcanization, forms single product；
(5) it cleans: product is cleaned, rinse, promote product cleanliness.
Described: curing temperature is 172-178 DEG C, vulcanization time 280-310s in sulfidization molding, and sulfide stress is
110-140kg/cm2。
The beneficial effects of the present invention are:
1, the present invention relates to a kind of medicinal chlorinated butyl rubber bungs and preparation method thereof.The clarity in chemical property detection
Well, when and rubber plug is with drug contact, there is no the risks of pollution drug.
2, use crosslinking agent B SH as vulcanizing agent, use small amounts magnesium as acid absorbent, as medicinal chlorinated butyl rubber
The vulcanizing system of rubber plug has good heat resistance.
3, it ensure that the inherent cleanliness of bottle stopper, no zinc vulcanizing system can promote bottle as activating agent without using zinc oxide
Fill in the quality of product.
Specific embodiment
Below with reference to embodiment, the present invention will be further described.
Embodiment 1
Medicinal chlorinated butyl rubber bung is prepared by the raw material of following mass fraction；
| Chlorinated scoline | 100 |
| Crosslinking agent | 1.0 |
| Acid absorbent | 0.3 |
| Calcined kaolin | 50 |
| White carbon black | 5 |
| Polyethylene wax | 2 |
| Titanium dioxide | 2 |
| Carbon black | 0.1。 |
Described: crosslinking agent is the double sulfydryl salt (BSH) of carbon azacyclo-.
Described: acid absorbent is magnesia.
Described: the preparation process of medicinal chlorinated butyl rubber bung is as follows:
Raw material cooperation → mixing → preforming → sulfidization molding → flash trimming → cleaning → packaging；
(1) it is kneaded: into after factory's ingredient inspection qualification, after carrying out ingredient according to formula, carrying out mixing, mill to various raw materials
It is stored after being mixed, lower turn after parking 24 hours or more；
(2) preforming: rubber compound is stored after extrusion, calendering, cooling and cut-parts, parks 4 hours or more, in advance at
Type quality inspection to film length and width, wait sulfidization molding again；
(3) it sulfidization molding: is chemically crosslinked in vulcanizing equipment according to the technique of regulation, sulfidization molding；
(4) flash trimming: being punched out the film after vulcanization, forms single product；
(5) it cleans: product is cleaned, rinse, promote product cleanliness.
Described: curing temperature is 172-178 DEG C, vulcanization time 280s, sulfide stress 110kg/ in sulfidization molding
cm2。
Embodiment 2
Medicinal chlorinated butyl rubber bung is prepared by the raw material of following mass fraction；
| Chlorinated scoline | 100 |
| Crosslinking agent | 2.0 |
| Acid absorbent | 0.5 |
| Calcined kaolin | 80 |
| White carbon black | 10 |
| Polyethylene wax | 4 |
| Titanium dioxide | 3 |
| Carbon black | 0.3。 |
Described: crosslinking agent is the double sulfydryl salt (BSH) of carbon azacyclo-.
Described: acid absorbent is magnesia.
Described: the preparation process of medicinal chlorinated butyl rubber bung is as follows:
Raw material cooperation → mixing → preforming → sulfidization molding → flash trimming → cleaning → packaging；
(1) it is kneaded: into after factory's ingredient inspection qualification, after carrying out ingredient according to formula, carrying out mixing, mill to various raw materials
It is stored after being mixed, lower turn after parking 24 hours or more；
(2) preforming: rubber compound is stored after extrusion, calendering, cooling and cut-parts, parks 4 hours or more, in advance at
Type quality inspection to film length and width, wait sulfidization molding again；
(3) it sulfidization molding: is chemically crosslinked in vulcanizing equipment according to the technique of regulation, sulfidization molding；
(4) flash trimming: being punched out the film after vulcanization, forms single product；
(5) it cleans: product is cleaned, rinse, promote product cleanliness.
Described: curing temperature is 172-178 DEG C, vulcanization time 310s, sulfide stress 140kg/ in sulfidization molding
cm2。
Embodiment 3
Medicinal chlorinated butyl rubber bung is prepared by the raw material of following mass fraction；
| Chlorinated scoline | 100 |
| Crosslinking agent | 1.5 |
| Acid absorbent | 0.4 |
| Calcined kaolin | 60 |
| White carbon black | 7 |
| Polyethylene wax | 3 |
| Titanium dioxide | 2.5 |
| Carbon black | 0.2。 |
Described: crosslinking agent is the double sulfydryl salt (BSH) of carbon azacyclo-.
Described: acid absorbent is magnesia.
Described: the preparation process of medicinal chlorinated butyl rubber bung is as follows:
Raw material cooperation → mixing → preforming → sulfidization molding → flash trimming → cleaning → packaging；
(1) it is kneaded: into after factory's ingredient inspection qualification, after carrying out ingredient according to formula, carrying out mixing, mill to various raw materials
It is stored after being mixed, lower turn after parking 24 hours or more；
(2) preforming: rubber compound is stored after extrusion, calendering, cooling and cut-parts, parks 4 hours or more, in advance at
Type quality inspection to film length and width, wait sulfidization molding again；
(3) it sulfidization molding: is chemically crosslinked in vulcanizing equipment according to the technique of regulation, sulfidization molding；
(4) flash trimming: being punched out the film after vulcanization, forms single product；
(5) it cleans: product is cleaned, rinse, promote product cleanliness.
Described: curing temperature is 172-178 DEG C, vulcanization time 300s, sulfide stress 120kg/ in sulfidization molding
cm2。
All products should meet following quality standard:
Remarks: being the chemical index that product predominantly detects above, and standard foundation is State Food and Drug Administration
YBB00052005-2015。
Claims (5)
1. a kind of medicinal chlorinated butyl rubber bung, it is characterised in that be prepared by the raw material of following mass fraction；
2. medicinal chlorinated butyl rubber bung according to claim 1, it is characterised in that described: crosslinking agent is carbon azacyclo-
Double sulfydryl salt.
3. medicinal chlorinated butyl rubber bung according to claim 1, it is characterised in that described: acid absorbent is magnesia.
4. medicinal chlorinated butyl rubber bung according to claim 1, it is characterised in that described: medicinal chlorinated scoline
The preparation process of plug is as follows:
Raw material cooperation → mixing → preforming → sulfidization molding → flash trimming → cleaning → packaging；
(1) it is kneaded: into after factory's ingredient inspection qualification, after carrying out ingredient according to formula, carrying out mixing, mill carries out various raw materials
It is stored after mixing, lower turn after parking 24 hours or more；
(2) preforming: rubber compound is stored after extrusion, calendering, cooling and cut-parts, is parked 4 hours or more, preforming matter
It examines to film length and width, wait sulfidization molding again；
(3) it sulfidization molding: is chemically crosslinked in vulcanizing equipment according to the technique of regulation, sulfidization molding；
(4) flash trimming: being punched out the film after vulcanization, forms single product；
(5) it cleans: product is cleaned, rinse, promote product cleanliness.
5. medicinal chlorinated butyl rubber bung according to claim 4, it is characterised in that described: vulcanizing temperature in sulfidization molding
Degree is 172-178 DEG C, vulcanization time 280-310s, sulfide stress 110-140kg/cm2。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811220294.3A CN109370073A (en) | 2018-10-19 | 2018-10-19 | Medicinal chlorinated butyl rubber bung and its preparation process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811220294.3A CN109370073A (en) | 2018-10-19 | 2018-10-19 | Medicinal chlorinated butyl rubber bung and its preparation process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109370073A true CN109370073A (en) | 2019-02-22 |
Family
ID=65400318
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811220294.3A Pending CN109370073A (en) | 2018-10-19 | 2018-10-19 | Medicinal chlorinated butyl rubber bung and its preparation process |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110142765A (en) * | 2019-05-17 | 2019-08-20 | 深圳市皕像科技有限公司 | A kind of method, apparatus and system of processing rubber plug |
| CN110330732A (en) * | 2019-05-20 | 2019-10-15 | 浙江贝斯特医用科技有限公司 | Without zinc hemostix butyl rubber bung and its manufacturing process |
| CN111073164A (en) * | 2019-12-23 | 2020-04-28 | 山东省药用玻璃股份有限公司 | Preparation method of rubber plug for preparing medicine bottle by using double-activator |
| CN112300505A (en) * | 2020-11-18 | 2021-02-02 | 哈尔滨展鹏医药包装有限公司 | Chlorinated butyl rubber plug for oral liquid bottle and preparation method thereof |
| CN114539684A (en) * | 2022-02-23 | 2022-05-27 | 江苏华兰药用新材料股份有限公司 | Halogenated butyl rubber material for injection medicine and preparation method thereof |
| CN114835980A (en) * | 2022-06-07 | 2022-08-02 | 安徽中马橡塑制品有限公司 | Medical antibacterial anti-puncturing rubber plug and preparation method thereof |
| CN114907650A (en) * | 2022-06-07 | 2022-08-16 | 安徽中马橡塑制品有限公司 | Special rubber plug suitable for sensitive medicine |
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| JPS5896636A (en) * | 1981-12-03 | 1983-06-08 | Japan Synthetic Rubber Co Ltd | Cocrosslinked composition consisting of halogen- containing polymer and unsaturated polymer |
| EP0841374A2 (en) * | 1996-11-07 | 1998-05-13 | Daikyo Seiko, Ltd. | Molded rubber part suitable for use in contact with medical solution |
| CN103131094A (en) * | 2011-11-25 | 2013-06-05 | 住友橡胶工业株式会社 | Thermoplastic elastomer composition and medical rubber product |
| JP2014237623A (en) * | 2013-06-07 | 2014-12-18 | 川口化学工業株式会社 | Novel crosslinking agent for rubber having excellent processing stability and low solvent extractability |
| JP2015093987A (en) * | 2013-11-08 | 2015-05-18 | 川口化学工業株式会社 | Halogenated butyl rubber composition having high crosslinking reactivity, excellent storage stability and excellent processing stability |
| CN105111602A (en) * | 2015-09-28 | 2015-12-02 | 郑州翱翔医药科技股份有限公司 | Medicinal thermoplastic elastomer and preparation method thereof |
| CN105273321A (en) * | 2014-07-16 | 2016-01-27 | 住友橡胶工业株式会社 | Medical rubber part |
| CN107446251A (en) * | 2017-09-01 | 2017-12-08 | 应城市恒天药业包装有限公司 | A kind of medicinal halogenated butyl rubber plug of environment-friendly type |
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2018
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Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS525857A (en) * | 1975-07-01 | 1977-01-17 | Nippon Zeon Co Ltd | Cross-linkable halogen-containing polymecomposition |
| JPS5896636A (en) * | 1981-12-03 | 1983-06-08 | Japan Synthetic Rubber Co Ltd | Cocrosslinked composition consisting of halogen- containing polymer and unsaturated polymer |
| EP0841374A2 (en) * | 1996-11-07 | 1998-05-13 | Daikyo Seiko, Ltd. | Molded rubber part suitable for use in contact with medical solution |
| CN103131094A (en) * | 2011-11-25 | 2013-06-05 | 住友橡胶工业株式会社 | Thermoplastic elastomer composition and medical rubber product |
| JP2014237623A (en) * | 2013-06-07 | 2014-12-18 | 川口化学工業株式会社 | Novel crosslinking agent for rubber having excellent processing stability and low solvent extractability |
| JP2015093987A (en) * | 2013-11-08 | 2015-05-18 | 川口化学工業株式会社 | Halogenated butyl rubber composition having high crosslinking reactivity, excellent storage stability and excellent processing stability |
| CN105273321A (en) * | 2014-07-16 | 2016-01-27 | 住友橡胶工业株式会社 | Medical rubber part |
| CN105111602A (en) * | 2015-09-28 | 2015-12-02 | 郑州翱翔医药科技股份有限公司 | Medicinal thermoplastic elastomer and preparation method thereof |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110142765A (en) * | 2019-05-17 | 2019-08-20 | 深圳市皕像科技有限公司 | A kind of method, apparatus and system of processing rubber plug |
| CN110330732A (en) * | 2019-05-20 | 2019-10-15 | 浙江贝斯特医用科技有限公司 | Without zinc hemostix butyl rubber bung and its manufacturing process |
| CN111073164A (en) * | 2019-12-23 | 2020-04-28 | 山东省药用玻璃股份有限公司 | Preparation method of rubber plug for preparing medicine bottle by using double-activator |
| CN112300505A (en) * | 2020-11-18 | 2021-02-02 | 哈尔滨展鹏医药包装有限公司 | Chlorinated butyl rubber plug for oral liquid bottle and preparation method thereof |
| CN114539684A (en) * | 2022-02-23 | 2022-05-27 | 江苏华兰药用新材料股份有限公司 | Halogenated butyl rubber material for injection medicine and preparation method thereof |
| CN114835980A (en) * | 2022-06-07 | 2022-08-02 | 安徽中马橡塑制品有限公司 | Medical antibacterial anti-puncturing rubber plug and preparation method thereof |
| CN114907650A (en) * | 2022-06-07 | 2022-08-16 | 安徽中马橡塑制品有限公司 | Special rubber plug suitable for sensitive medicine |
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Application publication date: 20190222 |