CN109367146A - A kind of extra-weather-proof protecting solar cell film and preparation method thereof - Google Patents
A kind of extra-weather-proof protecting solar cell film and preparation method thereof Download PDFInfo
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- CN109367146A CN109367146A CN201810998512.XA CN201810998512A CN109367146A CN 109367146 A CN109367146 A CN 109367146A CN 201810998512 A CN201810998512 A CN 201810998512A CN 109367146 A CN109367146 A CN 109367146A
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- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 239000010410 layer Substances 0.000 claims abstract description 170
- 239000011241 protective layer Substances 0.000 claims abstract description 55
- 239000012790 adhesive layer Substances 0.000 claims abstract description 53
- 229920001577 copolymer Polymers 0.000 claims abstract description 47
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 29
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 29
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 29
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 19
- 239000003607 modifier Substances 0.000 claims abstract description 18
- 239000002245 particle Substances 0.000 claims abstract description 12
- 238000000071 blow moulding Methods 0.000 claims abstract description 9
- 238000005453 pelletization Methods 0.000 claims abstract description 9
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims abstract description 8
- 229920002313 fluoropolymer Polymers 0.000 claims abstract description 7
- 239000004811 fluoropolymer Substances 0.000 claims abstract description 7
- 239000011256 inorganic filler Substances 0.000 claims abstract description 5
- 229910003475 inorganic filler Inorganic materials 0.000 claims abstract description 5
- 238000000034 method Methods 0.000 claims abstract description 5
- 238000005266 casting Methods 0.000 claims abstract description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 28
- 229920001707 polybutylene terephthalate Polymers 0.000 claims description 22
- 239000002253 acid Substances 0.000 claims description 20
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 claims description 20
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical group [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 18
- -1 polybutylene terephthalate Polymers 0.000 claims description 18
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 16
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 16
- 230000002745 absorbent Effects 0.000 claims description 15
- 239000002250 absorbent Substances 0.000 claims description 15
- 239000000463 material Substances 0.000 claims description 14
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims description 13
- 239000012745 toughening agent Substances 0.000 claims description 13
- 239000002033 PVDF binder Substances 0.000 claims description 12
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 12
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 12
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 12
- 239000004408 titanium dioxide Substances 0.000 claims description 11
- 150000002148 esters Chemical class 0.000 claims description 10
- 230000007062 hydrolysis Effects 0.000 claims description 10
- 238000006460 hydrolysis reaction Methods 0.000 claims description 10
- 229920000642 polymer Polymers 0.000 claims description 10
- 239000011787 zinc oxide Substances 0.000 claims description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 9
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical compound FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 claims description 9
- 239000005083 Zinc sulfide Substances 0.000 claims description 7
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 claims description 7
- 150000001336 alkenes Chemical group 0.000 claims description 6
- 229920001400 block copolymer Polymers 0.000 claims description 6
- 229910052731 fluorine Inorganic materials 0.000 claims description 6
- 239000011737 fluorine Substances 0.000 claims description 6
- 239000004611 light stabiliser Substances 0.000 claims description 6
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical compound FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 6
- MIZLGWKEZAPEFJ-UHFFFAOYSA-N 1,1,2-trifluoroethene Chemical group FC=C(F)F MIZLGWKEZAPEFJ-UHFFFAOYSA-N 0.000 claims description 5
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 5
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 5
- 239000012964 benzotriazole Substances 0.000 claims description 5
- UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical group FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 claims description 5
- 150000002989 phenols Chemical class 0.000 claims description 5
- 229920001897 terpolymer Polymers 0.000 claims description 5
- 150000003918 triazines Chemical class 0.000 claims description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- 230000004888 barrier function Effects 0.000 claims description 4
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical group C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 4
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 4
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 4
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical class OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 4
- VJGCZWVJDRIHNC-UHFFFAOYSA-N 1-fluoroprop-1-ene Chemical compound CC=CF VJGCZWVJDRIHNC-UHFFFAOYSA-N 0.000 claims description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 3
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims description 3
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 3
- 150000002118 epoxides Chemical class 0.000 claims description 3
- 239000010445 mica Substances 0.000 claims description 3
- 229910052618 mica group Inorganic materials 0.000 claims description 3
- QMMOXUPEWRXHJS-UHFFFAOYSA-N pent-2-ene Chemical group CCC=CC QMMOXUPEWRXHJS-UHFFFAOYSA-N 0.000 claims description 3
- 239000001632 sodium acetate Substances 0.000 claims description 3
- 235000017281 sodium acetate Nutrition 0.000 claims description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 2
- 239000000654 additive Substances 0.000 claims description 2
- 230000000996 additive effect Effects 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 claims description 2
- 239000000945 filler Substances 0.000 claims description 2
- 229960001545 hydrotalcite Drugs 0.000 claims description 2
- 229910001701 hydrotalcite Inorganic materials 0.000 claims description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 claims 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 9
- 239000001301 oxygen Substances 0.000 abstract description 9
- 229910052760 oxygen Inorganic materials 0.000 abstract description 9
- 230000032683 aging Effects 0.000 abstract description 5
- 239000010408 film Substances 0.000 description 36
- 235000010215 titanium dioxide Nutrition 0.000 description 14
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 8
- 239000012528 membrane Substances 0.000 description 8
- 229910052710 silicon Inorganic materials 0.000 description 8
- 239000010703 silicon Substances 0.000 description 8
- 239000013078 crystal Substances 0.000 description 7
- 239000002131 composite material Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 5
- 239000000843 powder Substances 0.000 description 4
- PGJHURKAWUJHLJ-UHFFFAOYSA-N 1,1,2,3-tetrafluoroprop-1-ene Chemical compound FCC(F)=C(F)F PGJHURKAWUJHLJ-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 239000000428 dust Substances 0.000 description 3
- 230000003628 erosive effect Effects 0.000 description 3
- 239000000314 lubricant Substances 0.000 description 3
- 239000010409 thin film Substances 0.000 description 3
- WROUWQQRXUBECT-UHFFFAOYSA-N 2-ethylacrylic acid Chemical compound CCC(=C)C(O)=O WROUWQQRXUBECT-UHFFFAOYSA-N 0.000 description 2
- 150000008366 benzophenones Chemical class 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000005297 material degradation process Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000010248 power generation Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 241000790917 Dioxys <bee> Species 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 229920006370 Kynar Polymers 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 229920006925 PVDF+PMMA Polymers 0.000 description 1
- 238000012356 Product development Methods 0.000 description 1
- 229910003978 SiClx Inorganic materials 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 125000005605 benzo group Chemical group 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910021421 monocrystalline silicon Inorganic materials 0.000 description 1
- 238000001579 optical reflectometry Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 150000008301 phosphite esters Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920002620 polyvinyl fluoride Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
- B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
- B32B27/322—Layered products comprising a layer of synthetic resin comprising polyolefins comprising halogenated polyolefins, e.g. PTFE
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
- H01L31/048—Encapsulation of modules
- H01L31/0481—Encapsulation of modules characterised by the composition of the encapsulation material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/71—Resistive to light or to UV
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/724—Permeability to gases, adsorption
- B32B2307/7242—Non-permeable
- B32B2307/7246—Water vapor barrier
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/73—Hydrophobic
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
Landscapes
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Electromagnetism (AREA)
- General Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Photovoltaic Devices (AREA)
- Laminated Bodies (AREA)
Abstract
The present invention provides a kind of extra-weather-proof protecting solar cell film and preparation method thereof; there are obvious excellent uvioresistant, hydrothermal aging ability; there is significant water vapor rejection ability and oxygen obstruction ability simultaneously, can more efficiently extend the service life of solar battery.Outer protective layer includes fluoropolymer, ultraviolet-resistant agent, antioxidant system, other function auxiliary agent；Middle support layer includes at least one of both Kynoar and its copolymer, modifier, inorganic filler, ultraviolet absorber, antioxidant system, other function auxiliary agent；Internal layer adhesive layer includes at least one of both Kynoar and its copolymer, modifier, compatilizer, antioxidant system, other function auxiliary agent.The particle for obtaining three layers after mixing, double-screw extruding pelletizing, baking step respectively, is finally respectively placed in the feeding funnel of three layers of extruder, and three-layer co-extruded blow molding or casting technique the preparation extra-weather-proof protecting solar cell film are passed through.
Description
Technical field
The present invention relates to a kind of extra-weather-proof protecting solar cell films and preparation method thereof.
Background technique
Solar power generation is pollution-free with its, sustainable, total amount is big, distribution is wide, using it is various informative the advantages that constitute too
Important component in positive energy energy strategy.The encouragement energetically of national governments was worldwide obtained in recent years, was won
It obtained considerable and developed by leaps and bounds.A kind of the solar battery as new energy, with conventional thermal power generation or other new
Energy such as wind-powered electricity generation, water power, nuclear power etc. is compared, and to keep its competitive advantage, then must embody its distinguished cost performance
Duration benign development can be obtained.For this purpose, the manufacturer and operator of each component part of solar battery do one's utmost
Carry out innovation research so that the cost performance of solar battery operation is continuously improved in ground.
Semiconductor solar cell --- crystal silicon solar batteries one in solar battery kind, based on element silicon
Directly in occupation of leading position.Crystal silicon solar batteries are primarily configured as being led by high transparency foreboard, encapsulating film, silver paste or aluminium paste
These materials are passed through heating by the laminated construction that the multilayered structures such as line, polycrystalline or monocrystalline silicon piece, encapsulating film and battery back-sheet are formed
The mode of lamination forms, and after sealing joint strip and frame assembling, mixing terminal box can be obtained crystal silicon solar batteries component.
Wherein, it is the key point for determining battery cost performance, and steam and oxygen that can the crystal silicon chip as " heart " efficiently run for a long time
Gas is then crystal silicon chip " fatal killer ".The main function of the backboard of one of important component as crystal silicon battery is to use
In protecting and supporting cell piece under the diversified open-air conditions such as ultraviolet light, dust storm, sleet, high/low temperature, still it is able to maintain good
Good luck row, it is necessary to have outstanding resistance ultraviolet irradiation, dust storm erosion, moisture attacks, aggressive oxygen energy.Moreover, big compression ring
Ultraviolet light irradiation, dust storm, sleet, high/low temperature in border etc. are not self-existent, therefore in common product development process
In cannot illustrate the quality of properties of product using simple independent test.It needs in a variety of conditions and deposit in the case where can expire
Sufficient requirement can more steadily guarantee properties of product.
Traditional solar energy backboard membrane is the composite membrane of " TPT ", " KPK " or " TPE " sandwich structure currently on the market,
Middle T layers be Du Pont Tedlar film, P layers be PET modifier film, K layers be Acker Ma Kynar film, E layers are that polyolefin is thin
Film.The major function of the fluorine material of outer layer is to prevent the effect of ultraviolet light, and P layers with excellent mechanical stability and good
Barrier property, T or K layers with the powerful guarantee that P layers of synergistic effect is that solar energy backboard can be used for a long time outdoors, but by
It has passed through modification in T layers or K layers, the oxygen ability that actually blocks water is well below its theoretical duty, and P layers of hydrolytic resistance ratio
It is poor, eventually lead to the service life requirement that backboard is relatively inaccessible to 25 years.
On the other hand, global climate has diversity, if one kind area in China is such as Tibet, Hainan etc., as height
Its aging speed of the conventional backing plate of molecular material composition is significantly larger than two classes, three classes area.This is because, polymer material is in purple
Outside line, high temperature wet heat condition coexist down, can rapidly occur chemical structure change, so as to cause its physical property it is quick under
Drop, the speed that structure changes are far longer than single condition.Therefore, as protective film vital in solar battery, back
Can the correctness of plate cladding material selection be the key that guarantee battery life.And judge the important technology of the Protective coatings
Index includes mainly uvioresistant ability, moisture-resistant thermal energy power, water vapor rejection ability and oxygen obstruction ability, especially at a variety of
Part coexist under integration capability.The selection of protecting solar cell film should select suitable material according to the amblent air temperature of each department
Material is only the reliability solution of high performance-price ratio.
Patent CN101932443B discloses a kind of three layers of PVDF thin film for photovoltaic cell, has A/B/C structure,
Outermost layer and innermost layer use pure PVDF or its copolymer as cortex, and middle layer uses PVDF modifier.It is using the structure
Since PVDF itself has excellent uvioresistant performance and water vapor rejection performance, it is thus possible to play one to backboard middle layer of PET
Fixed protective effect.But the transmission of ultraviolet light can not be prevented as the PVDF of cortex or its copolymer itself, with the time
Extension ultraviolet light inevitably still can damage effect to the modifier component in middle layer, cause boundary layer point
From, and ultimately cause hidden danger.
Patent CN106585010A discloses a kind of photovoltaic back PVDF thin film of double-layer coextrusion, and cortex uses PVDF
+ PMMA+TiO2+ antioxidant system+ultraviolet absorber composed structure, using the photovoltaic back PVDF of the structure and conventional monolayers
Film is not significantly improved, and since the variation of chemical structure can occur under ultraviolet irradiation for PMMA ingredient itself therein,
Further across the damp and hot experience of high temperature, it will further speed up material degradation, finally cause failure risk.
Summary of the invention
It is an object of the invention to overcome the above deficiencies in the existing technologies, and it is reasonable super resistance to provide a kind of design
Protecting solar cell film and preparation method thereof is waited, there is obvious excellent uvioresistant, hydrothermal aging ability, while being had significant
Water vapor rejection ability and oxygen obstruction ability can more efficiently extend the service life of solar battery.
Technical solution used by the present invention solves the above problems is: a kind of extra-weather-proof protecting solar cell film, by outer
To it is interior include outer protective layer, middle support layer and internal layer adhesive layer, it is characterised in that: each layer component includes: in parts by weight
Outer protective layer: 77-99 parts of fluoropolymer, 1-10 parts of ultraviolet-resistant agent, 0-2 parts of antioxidant system, other function auxiliary agent
0-1 parts；
Middle support layer: 30-80 parts of at least one of both Kynoar and its copolymer, 0-30 parts of modifier, inorganic
3-30 parts of filler, 0-3 parts of ultraviolet absorber, 0-2 parts of antioxidant system, 0-10 parts of other function auxiliary agent；
Internal layer adhesive layer: 50-99 parts of at least one of both Kynoar and its copolymer, 0-30 parts of modifier, compatible
0-5 parts of agent, 0-2 parts of antioxidant system, 0-5 parts of other function auxiliary agent.
In middle support layer of the present invention, the modifier is polymethyl methacrylate, polybutylene terephthalate
At least one kind of in ester, inorganic filler is titanium dioxide, zinc oxide, zinc sulphide, barium sulfate, talcum powder, montmorillonite, mica, carbonic acid
It is at least one kind of in calcium, silica, and Particle size requirements control, in 0.1um-10um, ultraviolet absorber is benzophenone class, benzotriazole
At least one kind of in class, triazines, other function auxiliary agent is acid absorbent, compatilizer, hydrolysis agent, at least one kind of in toughener.
In outer protective layer of the present invention, middle support layer and internal layer adhesive layer, antioxidant system is Hinered phenols, phosphite ester
It is at least one kind of in class, organic tin.
In internal layer adhesive layer of the present invention, modifier is polymethyl methacrylate, in polybutylene terephthalate (PBT)
It is at least one kind of.
In outer protective layer of the present invention, the fluoropolymer includes that polytetrafluoroethylene (PTFE), tetrafluoroethylene-perfluoro propyl are complete
At least one kind of and Kynoar and its copolymer in fluorovinyl-ether copolymer, tetrafluoraoethylene-hexafluoropropylene copolymer
At least one of the two, wherein polytetrafluoroethylene (PTFE), tetrafluoroethylene-perfluoro propyl perfluorovinylether copolymer, tetrafluoroethene-
At least one kind of shared number in hexafluoropropylene copolymer is 0.1-5 parts.
In outer protective layer of the present invention, ultraviolet-resistant agent is titanium dioxide, zinc oxide, zinc sulphide, the barium sulfate of inorganic, or
Benzophenone class, benzotriazole, the triazines of organic, various types of ultraviolet-resistant agent can be used independently or be used simultaneously；Its
His function additive is acid absorbent, flow ability modifying agent, at least one kind of in light stabilizer.
In outer protective layer of the present invention, middle support layer and internal layer adhesive layer, the polyvinylidene fluoride copolymer is inclined
The copolymer of vinyl fluoride and hexafluoropropene, the copolymer of vinylidene and chlorotrifluoroethylene, vinylidene and tetrafluoroethene and six
The terpolymer of fluoropropene, the copolymer of vinylidene and tetrafluoropropene, vinylidene and trifluoro-ethylene copolymer in
It is at least one kind of.
Acid absorbent of the present invention is MgO, nano-ZnO, hydrotalcite, sodium acetate or epoxide；It is described compatible
Agent is acrylic block copolymer, including acrylic acid or acrylic acid alkyl C1-C4 esters polymer, methacrylic acid or methyl
Two kinds in acrylic acid alkyl C1-C4 esters polymer, ethylacrylic acid or ethyl propylene dialkylaminobenzoic acid C1-C4 esters polymer or
The block copolymer of two or more formation.
In internal layer adhesive layer of the present invention, other function auxiliary agent is at least one kind of in hydrolysis agent and toughener.
The weight average molecular weight of at least one of both Kynoar of the present invention and its copolymer is 100,000-100 ten thousand.
A kind of preparation method of extra-weather-proof protecting solar cell film, it is characterised in that: outer layer is weighed according to formula respectively
The material of protective layer, middle support layer and internal layer adhesive layer obtains after mixing, double-screw extruding pelletizing, baking step respectively
The particle for obtaining outer protective layer, middle support layer, internal layer adhesive layer, is finally respectively placed in the feeding funnel of three layers of extruder
In, pass through three-layer co-extruded blow molding or casting technique the preparation extra-weather-proof protecting solar cell film.
Compared with prior art, the present invention having the following advantages that and effect:
Compared with the fluorine film that existing market is generallyd use, the present invention has more excellent uvioresistant moisture-resistant thermal energy power, has
More excellent water vapor rejection ability and oxygen obstruction ability, can make more efficiently to protect internal layer PET, further more added with
Effect ground protection crystal silicon chip, assigns the relatively reliable performance of backboard, so that solar battery is more applicable for harsh environment or more prolongs
Its long service life, has boundless market application prospect.
Specific embodiment
Below by embodiment, the present invention is described in further detail, following embodiment be explanation of the invention and
The invention is not limited to following embodiments.
A kind of extra-weather-proof protecting solar cell film includes that outer protective layer, middle support layer and internal layer are viscous from outside to inside
Layer is tied, outer protective layer and middle support layer are fixed, and middle support layer and internal layer adhesive layer are fixed, and each layer component is in parts by weight
Include:
One, outer protective layer: 77-99 parts of fluoropolymer, preferably at 85-98 parts；1-10 parts of ultraviolet-resistant agent, preferably in 4-10
Part；0-2 parts of antioxidant system, preferably at 0.5-1.5 parts；0-1 parts of other function auxiliary agent；Without containing in ultraviolet, high temperature and humidity condition
Under easily cause the PMMA and its modifier of material degradation.
Fluoropolymer includes polytetrafluoroethylene (PTFE), tetrafluoroethylene-perfluoro propyl perfluorovinylether copolymer, tetrafluoro second
At least one of at least one kind of and both Kynoar and its copolymer in alkene-hexafluoropropylene copolymer；Wherein gather
Tetrafluoroethene, tetrafluoroethylene-perfluoro propyl perfluorovinylether copolymer, at least 1 in tetrafluoraoethylene-hexafluoropropylene copolymer
Kind of shared number is 0.1-5 part, preferably 0.5-4 part, further preferably 1-3 parts, other compositions for Kynoar with
At least one of both its copolymers.Polyvinylidene fluoride copolymer is copolymer, the inclined fluorine second of vinylidene and hexafluoropropene
The terpolymer of alkene and the copolymer of chlorotrifluoroethylene, vinylidene and tetrafluoroethene and hexafluoropropene, vinylidene and four
At least one kind of in the copolymer of the copolymer of fluoropropene, vinylidene and trifluoro-ethylene, weight average molecular weight is 100,000-100 ten thousand,
Further preferably 200,000-50 ten thousand.
Ultraviolet-resistant agent is titanium dioxide, zinc oxide, zinc sulphide, barium sulfate or the benzophenone class of organic, benzo of inorganic
Triazole type, triazines preferably such as UV531, UV234, UV1577, various types of ultraviolet-resistant agent can be used independently or simultaneously
It uses.
Antioxidant system is Hinered phenols, phosphorous acid esters, at least one kind of in organic tin.
Other function auxiliary agent includes acid absorbent, flow ability modifying agent, at least one kind of in light stabilizer.
Two, middle support layer: 30-80 parts of at least one of both Kynoar and its copolymer, preferably in 50-70
Part；0-30 parts of modifier, preferably at 10-25 parts；3-30 parts of inorganic filler, preferably at 10-20 parts；0-3 parts of ultraviolet absorber；It is anti-
0-2 parts of oxygen system；0-10 parts of other function auxiliary agent；
Polyvinylidene fluoride copolymer is the copolymerization of the copolymer, vinylidene and chlorotrifluoroethylene of vinylidene and hexafluoropropene
The terpolymer of object, vinylidene and tetrafluoroethene and hexafluoropropene, the copolymer of vinylidene and tetrafluoropropene, inclined fluorine second
At least one kind of in the copolymer of alkene and trifluoro-ethylene, weight average molecular weight is 100,000-100 ten thousand, further preferably 200,000-50 ten thousand.
Modifier is polymethyl methacrylate, at least one kind of in polybutylene terephthalate (PBT).
Inorganic filler is titanium dioxide, zinc oxide, zinc sulphide, barium sulfate, talcum powder, montmorillonite, mica, calcium carbonate, dioxy
It is at least one kind of in SiClx, and Particle size requirements control is preferably controlled in 0.2um-5um in 0.1um-10um.
Ultraviolet absorber is benzophenone class, benzotriazole, at least one kind of in triazines.
Antioxidant system is Hinered phenols, phosphorous acid esters, at least one kind of in organic tin.
Other function auxiliary agent is acid absorbent, compatilizer, hydrolysis agent, at least one kind of in toughener.Acid absorbent is MgO, receives
Rice ZnO, sodium acetate or epoxide, the compatilizer are acrylic block copolymer, including acrylic acid or third
Olefin(e) acid alkyl C1-C4 esters polymer, methacrylic acid or methacrylate C1-C4 esters polymer, ethylacrylic acid
Or two or more block copolymer formed in ethyl propylene dialkylaminobenzoic acid C1-C4 esters polymer.
Three, internal layer adhesive layer: 50-99 parts of at least one of both Kynoar and its copolymer, preferably in 70-95
Part, further preferably at 85-95 parts；0-30 parts of modifier, preferably at 10-25 parts；0-5 parts of compatilizer；0-2 parts of antioxidant system,
0-5 parts of other function auxiliary agent.
Polyvinylidene fluoride copolymer is being total to for the copolymer of vinylidene and hexafluoropropene, vinylidene and chlorotrifluoroethylene
The terpolymer of polymers, vinylidene and tetrafluoroethene and hexafluoropropene, the copolymer of vinylidene and tetrafluoropropene, inclined fluorine
It is at least one kind of in the copolymer of ethylene and trifluoro-ethylene.
Modifier is polymethyl methacrylate, at least one kind of in polybutylene terephthalate (PBT).
Compatilizer is modifier of the polar functional group to polyolefin-acrylates class.
Antioxidant system is Hinered phenols, phosphorous acid esters, at least one kind of in organic tin.
Other function auxiliary agent is at least one kind of in hydrolysis agent and toughener.
Outer protective layer mainly provides barrier and resists the effect of ultraviolet light, water vapour erosion；Middle support layer mainly mentions
For mechanics strength support, the erosion of reduction ultraviolet light and water vapour, light reflectivity is further increased；Internal layer adhesive layer provide with
The effect of PET cohesive force.
The extra-weather-proof protecting solar cell film three-decker overall thickness can be adjusted arbitrarily, and general control is excellent in 5-100um
It is selected in 10-50um, further preferably in 20-35um；Wherein outer protective layer thickness is not less than 2um, further preferably in 4-
20um；Middle support layer thickness is in 2-80um, preferably in 10-90um, further preferably in 15-30um；Internal layer adhesive layer thickness
In 1-90um, preferably in 3-20um, further preferably in 5-15um.
In outer protective layer, middle support layer and internal layer adhesive layer, the specific number of each component may be set to affiliated range
Interior any integer or the number for being accurate to one decimal place.
A kind of preparation method of extra-weather-proof protecting solar cell film, it is characterised in that: outer layer is weighed according to formula respectively
The material of protective layer, middle support layer and internal layer adhesive layer obtains after mixing, double-screw extruding pelletizing, baking step respectively
The particle for obtaining outer protective layer, middle support layer, internal layer adhesive layer, is finally respectively placed in the feeding funnel of three layers of extruder
In, pass through the three-layer co-extruded blow molding process preparation extra-weather-proof protecting solar cell film.
Embodiment 1:
A kind of extra-weather-proof protecting solar cell film, from outside to inside include outer protective layer, middle support layer and internal layer adhesive layer,
Outer protective layer and middle support layer are fixed, and middle support layer and internal layer adhesive layer are fixed, wherein each layer component is in parts by weight
Include:
Outer protective layer: 90 parts of Kynoar, 6 parts of nanometer titanium dioxide, 3 parts of polytetrafluoroethylene (PTFE), 0.5 part of antioxidant system, light is steady
Determine 0.5 part of agent.
Middle support layer: 52 parts of Kynoar, 27 parts of polybutylene terephthalate (PBT), 10 parts of nano grade titanium white powder,
5 parts of toughener, 2 parts of antioxidant system, 2 parts of compatilizer, 1 part of acid absorbent, 1 part of hydrolysis agent.
Internal layer adhesive layer: 80 parts of Kynoar, 10 parts of polybutylene terephthalate (PBT), 3 parts of toughener, compatilizer 4
Part, 2 parts of antioxidant system, 1 part of hydrolysis agent.
A kind of preparation method of extra-weather-proof protecting solar cell film, steps are as follows:
The material of outer protective layer, middle support layer and internal layer adhesive layer is weighed respectively according to formula, respectively by mixing, double spiral shells
The particle that outer protective layer, middle support layer, internal layer adhesive layer are obtained after bar extruding pelletization, baking step, is finally distinguished
It is placed in the feeding funnel of three layers of extruder, extra-weather-proof protecting solar cell film is prepared by three-layer co-extruded blow molding process,
Middle outer protective layer, middle support layer, internal layer adhesive layer thickness be respectively 5um, 20um, 5um, three-layer co-extruded composite membrane it is total
Body thickness is 30 um.
Embodiment 2:
A kind of extra-weather-proof protecting solar cell film, from outside to inside include outer protective layer, middle support layer and internal layer adhesive layer,
Outer protective layer and middle support layer are fixed, and middle support layer and internal layer adhesive layer are fixed, wherein each layer component is in parts by weight
Include:
Outer protective layer: 89 parts of Kynoar, 7 parts of nanoscale zinc oxide, tetrafluoroethylene-perfluoro propyl perfluoroalkyl vinyl ether
2 parts of copolymer, 1 part of antioxidant system, 0.5 part of light stabilizer, 0.5 part of acid absorbent.
Middle support layer: 50 parts of Kynoar, 25 parts of polymethyl methacrylate, 10 parts of nano grade titanium white powder, toughening
5 parts of agent, 2 parts of antioxidant system, 2 parts of compatilizer, 2 parts of nanoscale montmorillonite, 1 part of acid absorbent, then additionally add 3 parts of ACR lubricant.
Internal layer adhesive layer: 90 parts of Kynoar, 10 parts of polymethyl methacrylate.
A kind of preparation method of extra-weather-proof protecting solar cell film, steps are as follows:
The material of outer protective layer, middle support layer, internal layer adhesive layer is weighed respectively according to formula, respectively by mixing, double spiral shells
The particle that outer protective layer, middle support layer, internal layer adhesive layer are obtained after bar extruding pelletization, baking step, is finally distinguished
It is placed in the feeding funnel of three layers of extruder, extra-weather-proof protecting solar cell film is prepared by three-layer co-extruded blow molding process,
Middle outer protective layer, middle support layer, internal layer adhesive layer thickness be respectively 8um, 17um, 5um, three-layer co-extruded composite membrane it is total
Body thickness is 30 um.
Embodiment 3:
A kind of extra-weather-proof protecting solar cell film, from outside to inside include outer protective layer, middle support layer and internal layer adhesive layer,
Outer protective layer and middle support layer are fixed, and middle support layer and internal layer adhesive layer are fixed, wherein each layer component is in parts by weight
Include:
Outer protective layer: poly- 90 parts of (biasfluoroethylene-hexafluoropropylene) copolymer, 7 parts of nano grade titanium white powder, tetrafluoroethene-hexafluoro
2 parts of propylene copolymer, 0.5 part of antioxidant system, 0.5 part of light stabilizer.
Middle support layer: 50 parts of Kynoar, 27 parts of polybutylene terephthalate (PBT) (PBT), nano grade titanium white powder
12 parts, 5 parts of toughener, 0.5 part of antioxidant system, 3 parts of compatilizer, 0.5 part of acid absorbent, 1.5 parts of hydrolysis agent.
Internal layer adhesive layer: 75 parts of Kynoar, 19 parts of polybutylene terephthalate (PBT), 2 parts of toughener, compatilizer 2
Part, 1 part of antioxidant system, 1 part of hydrolysis agent.
A kind of preparation method of extra-weather-proof protecting solar cell film, steps are as follows:
The material of outer protective layer, middle support layer, internal layer adhesive layer is weighed respectively according to formula, respectively by mixing, double spiral shells
The particle that outer protective layer, middle support layer, internal layer adhesive layer are obtained after bar extruding pelletization, baking step, is finally distinguished
It is placed in the feeding funnel of three layers of extruder, extra-weather-proof protecting solar cell film is prepared by three-layer co-extruded blow molding process,
Middle outer protective layer, middle support layer, internal layer adhesive layer thickness be respectively 10um, 15um, 5um, three-layer co-extruded composite membrane
General thickness is 30 um.
Embodiment 4:
A kind of extra-weather-proof protecting solar cell film, from outside to inside include outer protective layer, middle support layer and internal layer adhesive layer,
Outer protective layer and middle support layer are fixed, and middle support layer and internal layer adhesive layer are fixed, wherein each layer component is in parts by weight
Include:
Outer protective layer: 90 parts of Kynoar, 2 parts of polytetrafluoroethylene (PTFE), 7 parts of nanoscale zinc sulphide, 1 part of antioxidant system.
Middle support layer: 80 parts of Kynoar, 12 parts of nanometer titanium dioxide, 3 parts of toughener, 3 parts of flow ability modifying agent, antioxygen
2 parts of system.
Internal layer adhesive layer: 75 parts of Kynoar, 20 parts of polybutylene terephthalate (PBT), 2 parts of toughener, compatilizer 2
Part, 1 part of antioxidant system.
A kind of preparation method of extra-weather-proof protecting solar cell film, steps are as follows:
The material of outer protective layer, middle support layer, internal layer adhesive layer is weighed respectively according to formula, respectively by mixing, double spiral shells
The particle that outer protective layer, middle support layer, internal layer adhesive layer are obtained after bar extruding pelletization, baking step, is finally distinguished
It is placed in the feeding funnel of three layers of extruder, extra-weather-proof protecting solar cell film is prepared by three-layer co-extruded blow molding process,
Middle outer protective layer, middle support layer, internal layer adhesive layer thickness be respectively 10um, 15um, 5um, three-layer co-extruded composite membrane
General thickness is 30 um.
Comparative example (contains PMMA):
A kind of extra-weather-proof protecting solar cell film, from outside to inside include outer protective layer, middle support layer and internal layer adhesive layer,
Outer protective layer and middle support layer are fixed, and middle support layer and internal layer adhesive layer are fixed, wherein each layer component is in parts by weight
Include:
Outer protective layer: 72 parts of Kynoar, 10 parts of polymethyl methacrylate (PMMA), 10 parts of nanometer titanium dioxide, toughening
4 parts of agent, 2 parts of lubricant, 0.4 part of antioxidant system, 0.6 part of light stabilizer, 1 part of acid absorbent.
Middle support layer: 52 parts of Kynoar, 25 parts of polymethyl methacrylate, 10 parts of nanometer titanium dioxide, toughener 5
Part, 2 parts of antioxidant system, 2 parts of compatilizer, 1 part of acid absorbent, 3 parts of ACR lubricant.
Internal layer adhesive layer: Kynoar 80,10 parts of polymethyl methacrylate, 10 parts of nanometer titanium dioxide.
A kind of preparation method of extra-weather-proof protecting solar cell film, steps are as follows:
The material of outer protective layer, middle support layer, internal layer adhesive layer is weighed respectively according to formula, respectively by mixing, double spiral shells
The particle that outer protective layer, middle support layer, internal layer adhesive layer are obtained after bar extruding pelletization, baking step, is finally distinguished
It is placed in the feeding funnel of three layers of extruder, extra-weather-proof protecting solar cell film is prepared by three-layer co-extruded blow molding process,
Middle outer protective layer, middle support layer, internal layer adhesive layer thickness be respectively 8um, 17um, 5um, three-layer co-extruded composite membrane it is total
Body thickness is 30 μm.
The performance of the extra-weather-proof protecting solar cell film of the present invention and commercially available single layer polyvinylidene difluoride film and contain PMMA
When contrast test result it is as follows:
Illustrate that made membrane of the present invention has excellent resistance to UV aging, moisture-resistant heat ageing according to the performance test results above
Performance and water vapor rejection performance and oxygen barrier property.
In addition, it should be noted that, the specific embodiments described in this specification, the shape of parts and components are named
Title etc. can be different, and above content is only to structure of the invention example explanation described in this specification.It is all according to
According to equivalence changes or simple change that the invention patent design structure, feature and principle is done, it is included in this hair
In the protection scope of bright patent.Those skilled in the art can do described specific embodiment various
The mode that the modify or supplement or adopt of various kinds is similar substitutes, and without departing from structure of the invention or surmounts present claims
Range defined in book, is within the scope of protection of the invention.
Claims (10)
1. a kind of extra-weather-proof protecting solar cell film includes outer protective layer, middle support layer and internal layer bonding from outside to inside
Layer, it is characterised in that: each layer component includes: in parts by weight
Outer protective layer: 77-99 parts of fluoropolymer, 1-10 parts of ultraviolet-resistant agent, 0-2 parts of antioxidant system, other function auxiliary agent
0-1 parts；
Middle support layer: 30-80 parts of at least one of both Kynoar and its copolymer, 0-30 parts of modifier, inorganic
3-30 parts of filler, 0-3 parts of ultraviolet absorber, 0-2 parts of antioxidant system, 0-10 parts of other function auxiliary agent；
Internal layer adhesive layer: 50-99 parts of at least one of both Kynoar and its copolymer, 0-30 parts of modifier, compatible
0-5 parts of agent, 0-2 parts of antioxidant system, 0-5 parts of other function auxiliary agent.
2. extra-weather-proof protecting solar cell film according to claim 1, it is characterised in that: described in middle support layer
Modifier be polymethyl methacrylate, it is at least one kind of in polybutylene terephthalate (PBT), inorganic filler be titanium dioxide,
It is zinc oxide, zinc sulphide, barium sulfate, talcum powder, montmorillonite, mica, calcium carbonate, at least one kind of in silica, and Particle size requirements
In 0.1um-10um, ultraviolet absorber is benzophenone class, benzotriazole, at least one kind of, the other function auxiliary agent in triazines for control
It is at least one kind of in acid absorbent, compatilizer, hydrolysis agent, toughener.
3. extra-weather-proof protecting solar cell film according to claim 1, it is characterised in that: outer protective layer, intermediate branch
It supports in layer and internal layer adhesive layer, antioxidant system is Hinered phenols, phosphorous acid esters, at least one kind of in organic tin.
4. extra-weather-proof protecting solar cell film according to claim 1, it is characterised in that: modified in internal layer adhesive layer
Object is polymethyl methacrylate, at least one kind of in polybutylene terephthalate (PBT).
5. extra-weather-proof protecting solar cell film according to claim 1, it is characterised in that: described in outer protective layer
Fluoropolymer include polytetrafluoroethylene (PTFE), tetrafluoroethylene-perfluoro propyl perfluorovinylether copolymer, tetrafluoroethene-hexafluoro
At least one of at least one kind of and both Kynoar and its copolymer in propylene copolymer, wherein polytetrafluoroethyl-ne
It is alkene, tetrafluoroethylene-perfluoro propyl perfluorovinylether copolymer, at least one kind of shared in tetrafluoraoethylene-hexafluoropropylene copolymer
Number be 0.1-5 parts.
6. extra-weather-proof protecting solar cell film according to claim 1, it is characterised in that: ultraviolet in outer protective layer
Barrier is benzophenone class, benzotriazole, the triazine of the titanium dioxide of inorganic, zinc oxide, zinc sulphide, barium sulfate or organic
Class, various types of ultraviolet-resistant agent can be used independently or be used simultaneously；Other function auxiliary agent be acid absorbent, flow ability modifying agent,
It is at least one kind of in light stabilizer.
7. extra-weather-proof protecting solar cell film according to claim 5, it is characterised in that: outer protective layer, intermediate branch
It supports in layer and internal layer adhesive layer, the polyvinylidene fluoride copolymer is copolymer, the inclined fluorine second of vinylidene and hexafluoropropene
The terpolymer of alkene and the copolymer of chlorotrifluoroethylene, vinylidene and tetrafluoroethene and hexafluoropropene, vinylidene and four
It is at least one kind of in the copolymer of the copolymer of fluoropropene, vinylidene and trifluoro-ethylene.
8. extra-weather-proof protecting solar cell film according to claim 2, it is characterised in that: the acid absorbent be MgO,
Nano-ZnO, hydrotalcite, sodium acetate or epoxide；The compatilizer is acrylic block copolymer, including acrylic acid
Or acrylic acid alkyl C1-C4 esters polymer, methacrylic acid or methacrylate C1-C4 esters polymer, ethyl third
Two or more block copolymer formed in olefin(e) acid or ethyl propylene dialkylaminobenzoic acid C1-C4 esters polymer.
9. extra-weather-proof protecting solar cell film according to claim 1, it is characterised in that: in internal layer adhesive layer, other
Function additive is at least one kind of in hydrolysis agent and toughener.
10. a kind of preparation method of extra-weather-proof protecting solar cell film described in -9 any claims according to claim 1,
It is characterized by: the material of outer protective layer, middle support layer and internal layer adhesive layer is weighed respectively according to formula, respectively through overmulling
The particle of outer protective layer, middle support layer, internal layer adhesive layer is obtained after conjunction, double-screw extruding pelletizing, baking step, finally will
In its feeding funnel for being respectively placed in three layers of extruder, by three-layer co-extruded blow molding or casting technique preparation it is described it is extra-weather-proof too
Positive energy battery protection film.
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110641105A (en) * | 2019-08-02 | 2020-01-03 | 杭州福膜新材料科技股份有限公司 | Transparent UV barrier film of multilayer |
| CN110993711A (en) * | 2019-11-05 | 2020-04-10 | 乐凯胶片股份有限公司 | Polyester base film for solar back sheet and solar back sheet |
| CN111391449A (en) * | 2020-03-24 | 2020-07-10 | 吕新安 | UV (ultraviolet) blocking transparent outer bag and preparation method thereof |
| CN113147137A (en) * | 2021-05-13 | 2021-07-23 | 日氟荣高分子材料(上海)有限公司 | Multifunctional composite material and preparation method thereof |
| CN114211843A (en) * | 2021-11-15 | 2022-03-22 | 山东东岳高分子材料有限公司 | High-resistance heat-insulation fluorine sealing film for medicine packaging and preparation method thereof |
| CN114591579A (en) * | 2022-03-23 | 2022-06-07 | 临海伟星新型建材有限公司 | Weather-resistant drainage pipeline with multilayer structure and preparation method thereof |
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| CN110641105A (en) * | 2019-08-02 | 2020-01-03 | 杭州福膜新材料科技股份有限公司 | Transparent UV barrier film of multilayer |
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| CN110993711B (en) * | 2019-11-05 | 2022-03-04 | 乐凯胶片股份有限公司 | Polyester base film for solar back sheet and solar back sheet |
| CN111391449A (en) * | 2020-03-24 | 2020-07-10 | 吕新安 | UV (ultraviolet) blocking transparent outer bag and preparation method thereof |
| CN113147137A (en) * | 2021-05-13 | 2021-07-23 | 日氟荣高分子材料(上海)有限公司 | Multifunctional composite material and preparation method thereof |
| CN114211843A (en) * | 2021-11-15 | 2022-03-22 | 山东东岳高分子材料有限公司 | High-resistance heat-insulation fluorine sealing film for medicine packaging and preparation method thereof |
| CN114591579A (en) * | 2022-03-23 | 2022-06-07 | 临海伟星新型建材有限公司 | Weather-resistant drainage pipeline with multilayer structure and preparation method thereof |
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Application publication date: 20190222 |