CN109367091A - A kind of manufacture craft and healthy shoe of sole - Google Patents

A kind of manufacture craft and healthy shoe of sole Download PDF

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Publication number
CN109367091A
CN109367091A CN201811159800.2A CN201811159800A CN109367091A CN 109367091 A CN109367091 A CN 109367091A CN 201811159800 A CN201811159800 A CN 201811159800A CN 109367091 A CN109367091 A CN 109367091A
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CN
China
Prior art keywords
sole
magnetic sheet
surface layer
added
drug
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CN201811159800.2A
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Chinese (zh)
Inventor
沈丹
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Individual
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Individual
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Priority to CN201811159800.2A priority Critical patent/CN109367091A/en
Publication of CN109367091A publication Critical patent/CN109367091A/en
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D35/00Producing footwear
    • B29D35/12Producing parts thereof, e.g. soles, heels, uppers, by a moulding technique
    • B29D35/122Soles
    • AHUMAN NECESSITIES
    • A43FOOTWEAR
    • A43BCHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B13/00Soles; Sole-and-heel integral units
    • A43B13/02Soles; Sole-and-heel integral units characterised by the material
    • A43B13/04Plastics, rubber or vulcanised fibre
    • AHUMAN NECESSITIES
    • A43FOOTWEAR
    • A43BCHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B17/00Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined
    • A43B17/003Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined characterised by the material
    • A43B17/006Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined characterised by the material multilayered
    • AHUMAN NECESSITIES
    • A43FOOTWEAR
    • A43BCHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B17/00Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined
    • A43B17/08Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined ventilated
    • AHUMAN NECESSITIES
    • A43FOOTWEAR
    • A43BCHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B7/00Footwear with health or hygienic arrangements
    • A43B7/14Footwear with health or hygienic arrangements with foot-supporting parts
    • A43B7/1405Footwear with health or hygienic arrangements with foot-supporting parts with pads or holes on one or more locations, or having an anatomical or curved form
    • A43B7/1415Footwear with health or hygienic arrangements with foot-supporting parts with pads or holes on one or more locations, or having an anatomical or curved form characterised by the location under the foot
    • A43B7/144Footwear with health or hygienic arrangements with foot-supporting parts with pads or holes on one or more locations, or having an anatomical or curved form characterised by the location under the foot situated under the heel, i.e. the calcaneus bone
    • AHUMAN NECESSITIES
    • A43FOOTWEAR
    • A43BCHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B7/00Footwear with health or hygienic arrangements
    • A43B7/14Footwear with health or hygienic arrangements with foot-supporting parts
    • A43B7/1405Footwear with health or hygienic arrangements with foot-supporting parts with pads or holes on one or more locations, or having an anatomical or curved form
    • A43B7/1415Footwear with health or hygienic arrangements with foot-supporting parts with pads or holes on one or more locations, or having an anatomical or curved form characterised by the location under the foot
    • A43B7/1445Footwear with health or hygienic arrangements with foot-supporting parts with pads or holes on one or more locations, or having an anatomical or curved form characterised by the location under the foot situated under the midfoot, i.e. the second, third or fourth metatarsal
    • AHUMAN NECESSITIES
    • A43FOOTWEAR
    • A43BCHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B7/00Footwear with health or hygienic arrangements
    • A43B7/14Footwear with health or hygienic arrangements with foot-supporting parts
    • A43B7/1405Footwear with health or hygienic arrangements with foot-supporting parts with pads or holes on one or more locations, or having an anatomical or curved form
    • A43B7/1455Footwear with health or hygienic arrangements with foot-supporting parts with pads or holes on one or more locations, or having an anatomical or curved form with special properties
    • A43B7/146Footwear with health or hygienic arrangements with foot-supporting parts with pads or holes on one or more locations, or having an anatomical or curved form with special properties provided with acupressure points or means for foot massage

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  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Epidemiology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)

Abstract

The invention discloses a kind of manufacture crafts of sole, comprising the following steps: charging, mixing, cut-parts, moulded from foam, modulus and cooling and shaping finally obtain the product high with hole-closing structure, mechanical strength.The invention also discloses a kind of healthy shoes, including footwear body and sole, it is constituted between footwear body and sole and wears chamber for what wearer foot protruded into, it wears intracavitary equipped with health insoles, health insoles include the bottom of elastic material and the surface layer of ventilative material, Chinese traditional medicine layer is equipped between bottom and surface layer, bottom lower end surface is integrally formed with the poroid Support of regular hexagon honeycomb;The plantar reflecting region that bottom corresponds to human body is provided with multiple magnetic sheet mounting bases, and the lower end surface of magnetic sheet mounting base is equipped with opening, and the outer rim of opening extends to form limited wall into hole, and magnetic sheet is installed into the magnetic sheet mounting base by the opening activity.The present invention has the following advantages and effects: sole is made by even side injection, without the processing of chemical glue, and sole has excellent antiskid function.

Description

A kind of manufacture craft and healthy shoe of sole
Technical field
The present invention relates to technical field of shoe making, in particular to the manufacture craft and healthy shoe of a kind of sole.
Background technique
Current consumer is higher and higher to the comfort level requirement of footwear, and designer and craftsman can only be in appearance and modelings It works hard on decoration, or the Functional Designs such as breathable shoes, massage shoes is known as healthy shoe.
But traditional healthy shoe sole processing process is needed when sole to be bonded with indsole manually in insole in One layer of chemical glue is painted on bottom in advance, is dried at a temperature of certain after fitting, so that extra chemical glue volatilizees, Completion sole is bonded with indsole.Using such processing technology, not only process is relatively complicated, moreover, because what is used is mostly Irritant smell and chemical glue with certain toxicity, the glue in the sole after drying still with the presence of remaining, not only The health of user is affected, also easily the body of worker is impacted in process of production.In addition, being added using such Work technique, not only labor intensive, production efficiency are low, are unfavorable for producing in enormous quantities, but also the sole surface that processing obtains often has Trace after glue dries, appearance are comparatively coarse.
Summary of the invention
The object of the present invention is to provide a kind of manufacture craft of sole and healthy shoes, and sole, nothing is made by even side injection The processing of chemical glue is needed, and sole has excellent antiskid function.
In order to achieve the above object, the present invention provides a kind of manufacture crafts of sole, comprising the following steps:
Step S11, it feeds: being 80 DEG C~90 DEG C, after temperature reaches by the temperature setting of open mill, EVA pellet is added;
Step S12, it is kneaded: being separately added into stearic acid, zinc stearate and zinc oxide until expecting packet roller, after stirring 5-6 times, Wait expect to show uniform white, it is then added corresponding AC foaming agent and DCP crosslinking agent, after stirring 4-5 times, material shows It is uniform faint yellow, then add corresponding polyisobutene, after stirring 7-8 times, slice;
Step S13, sheet material obtained in step S12 cut-parts: is cut into die cavity size, uniform small pieces;
Step S14, moulded from foam: the small pieces cut out in step S13 are placed on compression molding instrument, are 170 in temperature DEG C~175 DEG C, molding be 10MPa under conditions of foam 850 minutes.
Step S15, it modulus: after reaching preset clamp time in step S14, is quickly opened and takes out.
Step S16, cooling and shaping: the mold taken out in step S15 is cooled to 65 DEG C or so, and is immediately fed into 120 DEG C Heating carries out second time of foaming in~170 DEG C of baking oven, finally obtains the product high with hole-closing structure, mechanical strength.
It is EVA100phr, stearic acid 0.5phr, zinc stearate that further setting, which is the material mixture ratio in the step S12, 0.7phr, zinc oxide 1.2phr, AC foaming agent 2phr, DCP crosslinking agent 1phr.
It is 1% that further setting, which is the weight ratio of addition polyisobutene in the step S12,.
Further setting is that Petropols are added, are continuously agitated after naphthenic oil to be heated to 120 DEG C, until petroleum tree Transparent sticky state is presented in rouge, and is added after being cooled to room temperature into step S12.
It includes C that further setting, which is the Petropols,5Resin, C9Resin and C5Hydrogenation resin, and weight ratio is 3%.
Compared to the prior art, it has the advantages that
Using sole made by the present invention without using chemical glue, the health of user not only can guarantee, and meet ring The production chain environment of guarantor.
The on-slip in addition, antiskid property of sole refers in people's walking process, when sole is to the road holding or sliding on ground Effect, qualified healthy shoe should have certain skid-proof function, while be an important indicators for judging footwear quality.Sole stops The quality of slip is directly related to the comfortable and safe of dress, and user puts on the bad shoes of anti-slip effect and sliding fall is be easy to cause to fall The safety accidents such as wound.In the U.S., merely because about 17% industrial accident is fallen down and caused to shoe soles slip stopping difference, every time The big appointment of this kind of accident occur 25~300,000 its, caused by loss reach 7,000,000,000 dollars, therefore many countries place hope on raising The non-skid property of sole is to reduce the generation of this kind of accident, and the on-slip coefficient of all kinds of import shoes of clear stipulaties will reach standard It can import.And maximum exported country one of of the China as footwear, the gesture under the import standard requirements that footwear are continuously improved in his country It is unfavorable to generate to the outlet of the footwear in China, therefore, how to improve the non-skid property of sole, it is ensured that the person peace of consumer It is complete imperative.
In the prior art, research staff increases non-skid property often through the pattern structure for changing sole, although energy Road holding is improved to reach antiskid effect, but after prolonged use, pattern structure, which can generate abrasion, leads to antiskid effect line Property decline.Therefore in the present invention, change the material of sole as point of penetration from the production of sole to enhance antiskid property.Due to EVA foaming product belongs to a kind of plastic material, when opposite sliding occurs for it and ground, the frictional force of generation be adhesive attraction and Lag resistance, when EVA foaming product slides on road surface, can constantly between road surface generate adherency, stretching, new adherency, This cyclic process of new stretching, to generate resistance, obstruction EVA foamed material continues to slide, and we want to improve EVA hair What the non-skid property of bubble sole was not just desirable to hinder EVA shoe bottom on road surface continues sliding, therefore, EVA again in the present invention Modified materials in right amount with adhesion characteristics are added in material, so that entire sole has certain adherency shape, to improve EVA shoe bottom Non-skid property.
Then, polyisobutene is selected in the present invention, polyisobutene is that a kind of nontoxic sticky or semisolid of colorless and odorless is poly- Object is closed, a kind of low molecular weight polyisobutene outstanding tackifier since its intrinsic viscosity becomes are frequently used to produce The winding film of the one kind such as preservative film, this film surface have certain viscoplasticity and tension, can be commodity by the two It wraps up, achievees the purpose that protect product.In view of the viscosity that polyisobutene is excellent, lasting, the excellent phase with many resins Capacitive and nontoxic, harmless application field, therefore it is applied to EVA foamed shoe sole, improve the non-skid property of sole.
On the other hand, Petropols are a kind of low acid values, the good resin of water-fast, acidproof, alkaline-resisting thermostabilization, and are had Certain tune is viscous.It is used in combination generally as promotor, regulator or modifying agent and other type resins.There are many researchers to rubber Petropols are added in glue to play the role of thickening, reinforcement, softening, therefore by C in the present invention5Resin, C9Resin and C5Add hydrogen Resin is added into EVA material and foams, and the non-skid property at EVA shoe bottom is improved using the tackifying of Petropols.
In order to achieve the above object, the present invention also provides a kind of healthy shoes, including by a kind of above-mentioned production work of sole Sole made by skill and the footwear body on the sole, composition is protruded into for wearer foot between the footwear body and sole Chamber is worn, the dress is intracavitary to be equipped with health insoles, and the health insoles include the bottom of elastic material and the table of ventilative material Layer, the bottom are bonded fixation with surface layer, Chinese traditional medicine layer are equipped between the bottom and surface layer, the lower end surface of the bottom is integrally set The Support for having regular hexagon honeycomb poroid;The plantar reflecting region that the bottom corresponds to human body is provided with multiple magnetic sheet mounting bases, The lower end surface of the magnetic sheet mounting base is equipped with opening, and the outer rim of the opening extends to form limited wall into hole, the opening Diameter is less than the diameter of magnetic sheet, and magnetic sheet is installed into the magnetic sheet mounting base by the opening activity;The surface layer corresponds to human body Plantar reflecting region be equipped with multiple massage bumps;The Chinese traditional medicine layer is paper stock or cloth containing drug, the formula of the drug It include: Radix Astragali 30g, herba taxilli 20g, wild chrysanthemum 20g, pueraria lobata 20g, radix paeoniae rubra 20g, radix cyathulae 20g, Prunella vulgaris 20g, Rhizoma Chuanxiong 15g, Cortex Eucommiae 15g, Rhizoma Gastrodiae 15g , Common St.Paulswort Herb 15g, Semen Leonuri 15g, radix rehmanniae recen 15g, Cortex Phellodendri 15g, rhizoma anemarrhenae 15g, Moschus 2g, lanceleaf anisetree root 30g, folium artemisiae argyi 20g, ramulus cinnamomi 20g, safflower 20g, asarum 20g, Radix Angelicae Sinensis 20g, caulis lonicerae 20g, Schisandra chinensis 15g, capsicum 15g, Chinese prickly ash 15g, Caulis Spatholobi 15g;The making step of the Chinese traditional medicine layer are as follows:
Step S21, by addition to Moschus drug and 250g yellow lead put into pulverizer crush re-sieving;
Step S22,500g oil is added in a reservoir and heats, the stirring of yellow lead powder is put into after low-grade fever;
Step S23, drug powder is added and is stirred continuously, until drug powder is in coke yellow, reducing internal heat is removed with iron wire sieve The dregs of a decoction extract plaster;
Step S24, plaster is put into cold water, impregnates, pulls out, dry, releasing fire-toxin;
Step S25, take cream medicine is placed in container, is melted and is stirred evenly in water-bath or mild fire, and a certain amount of plaster is taken to be coated in paper On material or cloth, Moschus powder is sprinkled, is dried;
Manufactured Chinese traditional medicine layer is sewed or is affixed between bottom and surface layer.
Further setting is that the magnetic sheet mounting base inner face is contacted with Chinese traditional medicine layer, and drug powder is added by the opening The magnetic sheet mounting base, the drug powder formula are as follows: radix aucklandiae 2g, wrinkled giant hyssop 2g, peppermint 2g, lavender 2g crushed 120 meshes.
Further setting is that the position where the magnetic sheet mounting base is corresponding with the position where the massage bumps.
Further setting is the supporting block that the surface layer corresponds to human body arch area and heel region is equipped with protrusion.
Further setting is the surface layer massage point small throughout the massage bumps, and the bottom is silica gel material, The edge of the bottom is the inclined-plane to smoothly transit, and the bottom and surface layer perforation are provided with multiple ventholes.
Compared to the prior art, it has the advantages that
1, regular hexagon honeycomb cavernous structure makes health insoles save former material under the premise of support strength with higher Material;Setting magnetic sheet mounting base and opening facilitate user to take out or place magnetic sheet, meet the needs of customer personalized, setting limit Wall is fixed magnetic sheet more in magnetic sheet mounting base;Massage bumps are set in corresponding human foot echo area, are passed through when on foot Contact of the sole with massage bumps carries out massage stimulation to plantar reflecting region;Contain alleviation hypertension, diabetes, wind by setting The Chinese traditional medicine layer of wet, headache syndromes drugs reaches the health-care effect prevented and cured diseases;Lotion is made in drug, then lotion is applied to It on paper stock or cloth, sews or affixes between bottom and surface layer, by the surface layer for material of breathing freely, the drug in Chinese traditional medicine layer is delayed It releases and.
2, drug powder such as Moschus powder is added to Chinese traditional medicine layer by the present invention, be can promote drug and is played curative effect.
3, massage bumps, magnetic sheet are arranged in identical position in the present invention, promote massage stimulation and magnetotherapy effect mutually Into playing better health-care effect.
4, the present invention in supporting block and arch of foot and followed by fitting, formed support force, meet ergonomics, make more to relax on foot It is suitable.
5, silica gel material is elastic material in the present invention, has shock absorbing effect, keeps health insoles more comfortable, simultaneously Magnetic sheet is facilitated to be installed into magnetic sheet mounting base using its elasticity.
Detailed description of the invention
Fig. 1 is the flow chart of embodiment 1;
Fig. 2 is the line chart of the weight ratio of polyisobutene and EVA shoe bottom non-skid property in embodiment 1;
Fig. 3 is the weight ratio and the hardness at EVA shoe bottom and the line chart of density of 1 polyisobutene in embodiment;
Fig. 4 is the weight ratio and the tensile strength at EVA shoe bottom and the broken line of elongation at break of polyisobutene in embodiment 1 Figure;
Fig. 5 is C in embodiment 19The weight ratio of resin and the line chart of EVA shoe bottom non-skid property;
Fig. 6 is C in embodiment 19The weight ratio and the hardness at EVA shoe bottom and the line chart of density of resin;
Fig. 7 is C in embodiment 19The weight ratio and the tensile strength at EVA shoe bottom and the line chart of elongation at break of resin;
Fig. 8 is the structural schematic diagram of embodiment 2;
Fig. 9 is the surface layer schematic diagram of health insoles in embodiment 2;
Figure 10 is the bottom schematic diagram of health insoles in embodiment 2;
Figure 11 is the cross-sectional view of health insoles in embodiment 2;
Figure 12 is enlarged diagram at A in Figure 11.
In figure: 01, footwear body;02, sole;03, chamber is worn;04, health insoles;1, surface layer;2, bottom;201, Support; 3, Chinese traditional medicine layer;4, massage bumps;5, massage point;6, magnetic sheet mounting base;601, it is open;602, limited wall;603, magnetic sheet;7, it supports Block;8, venthole.
Specific embodiment
Below in conjunction with attached drawing, invention is further described in detail.
Embodiment 1
With reference to Fig. 1, a kind of manufacture craft of sole, comprising the following steps:
Step S11, it feeds: being 80 DEG C~90 DEG C, after temperature reaches by the temperature setting of open mill, EVA pellet is added;
Step S12, it is kneaded: being separately added into stearic acid, zinc stearate and zinc oxide until expecting packet roller, after stirring 5-6 times, Wait expect to show uniform white, it is then added corresponding AC foaming agent and DCP crosslinking agent, after stirring 4-5 times, material shows It is uniform faint yellow, then add corresponding polyisobutene, after stirring 7-8 times, slice;
Step S13, sheet material obtained in step S12 cut-parts: is cut into die cavity size, uniform small pieces;
Step S14, moulded from foam: the small pieces cut out in step S13 are placed on compression molding instrument, are 170 in temperature DEG C~175 DEG C, molding be 10MPa under conditions of foam 850 minutes.
Step S15, it modulus: after reaching preset clamp time in step S14, is quickly opened and takes out.
Step S16, cooling and shaping: the mold taken out in step S15 is cooled to 65 DEG C or so, and is immediately fed into 120 DEG C Heating carries out second time of foaming in~170 DEG C of baking oven, finally obtains the product high with hole-closing structure, mechanical strength.
Further, the material mixture ratio in the step S12 is EVA100phr, stearic acid 0.5phr, zinc stearate 0.7phr, zinc oxide 1.2phr, AC foaming agent 2phr, DCP crosslinking agent 1phr.
Further, the weight ratio that polyisobutene is added in the step S12 is 1%.
Further, after naphthenic oil being heated to 120 DEG C, Petropols is added, are continuously agitated, until Petropols are in Existing transparent sticky state, and be added after being cooled to room temperature into step S12.
Further, the Petropols include C5Resin, C9Resin and C5Hydrogenation resin, and weight ratio is 3%.
Wherein, EVA is the abbreviation of ethylene-vinyl acetate copolymer, and AC foaming agent chemical name is azodicarbonamide, should AC foaming agent is one of most common foaming agent in rubber processing industry;DCP crosslinking agent is cumyl peroxide, is this field The common knowledge of technical staff.
Test repeatedly is carried out to sole 02 made of above-mentioned step to be concluded that
With reference to Fig. 2, it can be seen that it joined the trend that the non-skid property of the foaming product of polyisobutene is significantly improved, The coefficient of friction that pure EVA is measured is only 0.43, and after 1% polyisobutene is only added, coefficient of friction just increases to 0.52, antiskid property About 21% can be about improved, this is because inherently a kind of thick liquid of low molecular weight of polyisobutene, when hair is blended with EVA When bubble, whole system can be made to have certain adhesiveness.When with contact face contact, adhesive attraction increases, and causes entirely to rub The increase of resistance is wiped, thus non-skid property improves.This matches with the thinking discussed in the present invention, and it is of the invention reasonable to illustrate Property, next research can continue to consider from this angle.
With reference to Fig. 3, one of an important factor for controlling foaming material performance is density, and hardness can then indicate that material locally supports Resist hard object to be pressed into the capacity of water on its surface, the hardness of foamed material generally within the scope of 50-70, it is too hard or it is too soft all can shadow Ring the application of product.The hardness 63 of pure EVA foaming body, density 0.210g/cm3, joined the EVA foaming of 1% polyisobutene The density and hardness of body is respectively 0.203g/cm3With 61, the foaming body of 5% polyisobutene, hardness and density difference joined For 0.199g/cm3With 59, the density and hardness of foamed material can be all presented slightly with the increase of polyisobutene additional amount Downward trend, since the addition of polyisobutene can be such that the abscess aperture of foaming body slightly increases, this certainly will will cause extrudate density Reduce with hardness, and polyisobutene additional amount is bigger, cell diameter is also bigger, will also result in density and hardness reduction, still Density and hardness overall variation is not that very greatly, joined 5% polyisobutene, density is also just reduced by about 4%.Hardness is basic On be also able to maintain 94% or so of pure EVA foaming, after increasing polyisobutylene materials, for the density and hardness at EVA shoe bottom Influence equal very little.
With reference to Fig. 4, it can be seen that after polyisobutene is added, the tensile strength of foamed material can be declined on the whole, pure The tensile strength of EVA foamed material is 3MPa, and after 5% polyisobutene is added, tensile strength 2.68MPa is had dropped About 11%.Elongation at break is but as the increase of polyisobutene additional amount has the increase of highly significant.Analyzing its reason may be Because of the linear molecular structure of the saturation of polyisobutene, there is certain elasticity.After it to be blended with EVA to foaming, when by When external tensile force, crazing can be caused, so that matrix is generated shear yielding, absorb energy by crazing, shear band, to make multiple Foamed material elongation at break is closed to be improved.As can also be seen from Figure when polyisobutene additional amount is 1%, stretch light Degree be have one it is small-scale increased, this illustrates that the linear molecular chain structure of polyisobutene has certain winding effect, to body There is a reinforcing effect in system, but if continue to increase the dosage of polyisobutene, and can be because polyisobutene will increase EVA molecule The distance of interchain causes the tensile strength of composite foam material to be declined.
Therefore, in the present invention, it is preferred to which the polyisobutene that weight ratio is 1% is added.
With reference to Fig. 5, it can be seen that joined C9The coefficient of friction of the EVA composite foam material of resin significantly improves, only plus Enter 1% C9Resin can make coefficient of friction be increased to 0.55 from 0.43, but be not C9Resin adds more, and coefficient of friction is got over Greatly, it can be seen from the figure that with C9Resin amount increases, and coefficient of friction is but gradually reduced, when additional amount is respectively 3%, 5%, 7% when the coefficient of friction that measures be respectively 0.55,0.54,0.51, but than not plus C9The friction of resin Coefficient is high, this illustrates C9The non-skid property of EVA foamed shoe sole can be improved in the addition of resin.
With reference to Fig. 6, it can be seen from the figure that the density and hardness of pure EVA foaming body is 0.21g/cm respectively3With 63, when It joined 1% C9After resin, the density and hardness of EVA composite foam material has slight decline, falls below respectively 0.204g/cm3With 60.But with C9The increase of resin amount, density and hardness will continue to decline, since EVA is composite foamed The cell diameter of material is with C9Increasing for resin amount and be gradually increased, it is especially special to work as C9Resin is added to 7%, list A cell diameter increases 2 times or so compared with not adding, this inevitably results in the decline of foaming body its hardness and density, therefore Work as C9When resin is added to 7%, the hardness and density of foaming body also fall below minimum.
With reference to Fig. 7, as can be seen from the figure work as C9When resin amount is less than 5%, the stretching of EVA composite foam material is strong Degree can be because of C9Resin is added and has increase, and the elongation at break of EVA composite foam material can be with C9The increase of resin amount and protect Hold the trend of increase.But work as C9When resin amount reaches 7%, tensile strength can be obviously reduced, the increase of elongation at break Trend is obvious not as good as front.Analyzing its reason may be because of C9Contain the cyclic structures such as phenyl ring, cohesive force in molecular resin chain Greatly, certain rigidity can be presented, and since itself polarity is larger, it is preferable with EVA compatibility, it can be improved foaming body Intensity, therefore foaming body tensile strength is promoted to increase, but if C9Resin amount is too big, and it is violent to will lead to cell diameter Become larger, reduces tensile strength at this time.Work as C9When the amount of resin is added to 7%, reinforcing effect be not enough to make up abscess become larger and Caused by weaken effect, therefore final tensile strength becomes smaller.
Therefore, in the present invention, it is preferred to the C for being 3% with weight ratio9Resin, and C5Resin and C5The test of hydrogenation resin As a result with C9Resin is substantially similar, therefore in the present invention, C9Resin, C5Resin and C5The weight ratio of hydrogenation resin is all made of 3%.
In conclusion joined polyisobutene, C9Resin, C5Resin and C5The non-skid property of the foaming product of hydrogenation resin The trend being significantly improved, this matches in thinking of the invention, illustrates reasonability of the invention, but three of the above Substance is not that additional amount is more, and the raising of antiskid property effect is more obvious, coefficient of friction also can because additional amount is excessive have it is slight under The trend of drop.Therefore, it tests and realizes, polyisobutene, C repeatedly by continuous in the present invention9Resin, C5Resin and C5Add hydrogen It is reasonable and creative that the addition of resin and weight ratio content all have.
In addition, can also add thiacyclohexane dicarboxylic acid esters in sole 02 to increase non-skid property.
Embodiment 2
With reference to Fig. 8 to Figure 12, the present invention provides a kind of healthy shoe, including footwear body 01 and sole 02, the sole 02 by A kind of manufacture craft of sole described in embodiment 1 is made, and composition is protruded into for wearer foot between footwear body 01 and sole 02 Chamber 03 is worn, described wear is equipped with health insoles 04 in chamber 03, the health insoles 04 include 2 He of bottom for including elastic material The surface layer 1 of ventilative material, the bottom 2 are bonded fixation with surface layer 1, and Chinese traditional medicine layer 3 is equipped between the bottom 2 and surface layer 1.It should Chinese traditional medicine layer 3 is paper stock or cloth containing drug, and the formula of the drug includes: Radix Astragali 30g, herba taxilli 20g, wild chrysanthemum 20g, Pueraria lobata 20g, radix paeoniae rubra 20g, radix cyathulae 20g, Prunella vulgaris 20g, Rhizoma Chuanxiong 15g, Cortex Eucommiae 15g, Rhizoma Gastrodiae 15g , Common St.Paulswort Herb 15g, Semen Leonuri 15g, radix rehmanniae recen 15g, Cortex Phellodendri 15g, rhizoma anemarrhenae 15g, Moschus 2g, lanceleaf anisetree root 30g, folium artemisiae argyi 20g, ramulus cinnamomi 20g, safflower 20g, asarum 20g, Radix Angelicae Sinensis 20g, caulis lonicerae 20g, Schisandra chinensis 15g, capsicum 15g, Chinese prickly ash 15g, Caulis Spatholobi 15g.
Wherein, Radix Astragali has effects that reducing pressure and sugar, and herba taxilli has effects that nourishing liver and kidney degrading the channel, and wild chrysanthemum, which has, to be controlled The effect of dizzy and detumescence, pueraria lobata have effects that decompression is quenched one's thirst, and radix paeoniae rubra has effects that cooling and activating blood, and radix cyathulae has diuresis Treating stranguria effect, Prunella vulgaris, which has effects that relieve inflammation or internal heat, controls headache, and Rhizoma Chuanxiong has effects that promoting blood circulation and stopping pain, Cortex Eucommiae have antihypertensive diuretic The effect of, Rhizoma Gastrodiae has effects that controlling cold and headache , Common St.Paulswort Herb has effects that be depressured clearing damp, and Semen Leonuri is antipyretic with wind is controlled Effect, radix rehmanniae recen have effects that heat-clearing hypoglycemic, and Cortex Phellodendri has effects that Qinghuo Jiedu, rhizoma anemarrhenae have effects that clearing heat-fire, Moschus has effects that the powdered medicine ' Tongluosan ' stasis of blood, priming reach thoroughly, and lanceleaf anisetree root has effects that wind-dispelling dissipates the stasis of blood, and folium artemisiae argyi has eliminating cold to stop pain Effect, ramulus cinnamomi have effects that diuresis eliminating the phlegm, and safflower has effects that promoting blood circulation and stopping pain, and asarum has effects that headache is controlled in wind-dispelling, Radix Angelicae Sinensis, which has effects that enrich blood, to relieve pain, and Schisandra chinensis has effects that nourishing generate fluid, and capsicum has effects that cold dispelling helps digestion, Chinese prickly ash tool There is the effect of warm in pain, Caulis Spatholobi has effects that control rheumatism paralysis, and caulis lonicerae has effects that dispelling wind dredging collateral.To sum up institute It states, drug ingedient contained by Chinese traditional medicine layer 3 can play assisting in treating hypertension, hyperglycemia, rheumatism, the effect of headache.
The making step of the Chinese traditional medicine layer 3 are as follows:
Step S21: by addition to Moschus drug and 250g yellow lead put into pulverizer crush re-sieving;
Step S22: 500g oil is added in a reservoir and heats, the stirring of yellow lead powder is put into after low-grade fever;
Step S23: being added drug powder and be stirred continuously, until drug powder is in coke yellow, reducing internal heat is removed with iron wire sieve The dregs of a decoction extract plaster;
Step S24: being put into cold water for plaster, impregnates, pulls out, dry, releasing fire-toxin;
Step S25: take cream medicine is placed in container, is melted and is stirred evenly in water-bath or mild fire, and a certain amount of plaster is taken to be coated in paper On material or cloth, Moschus powder is sprinkled, is dried,
Preferably, drug and yellow lead are put into pulverizer in the step s 21 and are pulverized and sieved to 100 mesh, make drug and Huang It is red mix when increasing contact area more Datong District with oil it is more uniform, to keep drug effect performance more abundant;In step S23 constantly Stirring makes drug and oil mixing sufficiently be also prevented from drug and burn, and the removal dregs of a decoction keep ointment texture finer and smoother;It goes in step s 24 Except fire toxin prevents medicine irritation skin;Sprinkling Moschus powder in step s 25 promotes drug to play effect, increases fragrance, selects Non-woven fabrics uniformly smears ointment on it, while sticking layer of non-woven fabric again on ointment.
After Chinese traditional medicine layer 3 is made, Chinese traditional medicine layer 3 is affixed between bottom 2 and surface layer 1 with natural adhesive, is prevented using conjunction Plastic spun lacing, which swashs sole skin and influences drug effect, to be played, it is preferred that uses amylan.
Since ointment has been made in Chinese medicine and has been arranged under ventilative surface layer 1, health insoles 04 can be released slowly Drug effect is released, the several months is up to.
In addition, bottom 2 is silica gel material, lower end surface is integrally formed with the poroid Support 201 of regular hexagon honeycomb, the branch The Support 201 that support area 201 can be set to full sole also can be set to the Support 201 of part sole, it is preferred that by hind paw It is set as Support 201, forefoot is set as the skid-proof regions of diamond shape lines.
In addition, the plantar reflecting region of the corresponding human body of the bottom 2 is provided with multiple magnetic sheet mounting bases 6, the magnetic sheet installation The lower end surface of seat 6 is equipped with opening 601, and the outer rim of the opening 601 extends to form limited wall 602 into hole, the opening 601 Diameter is less than the diameter of magnetic sheet 603, and magnetic sheet 603 is installed into the magnetic sheet mounting base 6 by 601 activity of opening, the magnetic 6 inner face of piece mounting base is contacted with Chinese traditional medicine layer 3, and the magnetic sheet mounting base 6 can be added by the opening 601 in drug powder To make drug powder contact with Chinese traditional medicine layer 3, the drug of Chinese traditional medicine layer 3 is promoted to play curative effect, drug powder formula are as follows: radix aucklandiae 2g, Wrinkled giant hyssop 2g, peppermint 2g, lavender 2g, crushed 120 meshes, which is added in magnetic sheet mounting base 6, reinforcement pair The stimulation of plantar reflecting region.The plantar reflecting region of the corresponding human body in the surface layer 1 is equipped with multiple massage bumps 4.The surface layer 1 is corresponding Human body arch area and heel region be equipped with 7th area of supporting block of protrusion, supporting block 7 and arch of foot and followed by fitting, form support force, Meet ergonomics, makes more comfortable on foot.The edge of the bottom 2 is the inclined-plane to smoothly transit, makes health insoles 04 and shoes Bottom 02 is more bonded.The bottom 2 and the perforation of surface layer 1 are provided with multiple ventholes 8, enhance the permeability of health insoles 04.
Lung, tracheae, thyroid gland, liver, kidney, spleen, heart, stomach, small intestine, knot shown in preferred plantar reflecting region Echo area corresponding to intestines and genitals is equipped with round 603 mounting hole of magnetic sheet in bottom 2, is equipped with circle in the identical position in surface layer 1 Shape massage bumps 4 are pressed by the way that Chinese medicine Moschus, magnetic sheet 603 and massage bumps 4, drug, magnetic field and physics is arranged to plantar reflecting region The three that rubs complements each other to the effect of plantar reflecting region, more enhancing health-care effect.
In addition, having randomly selected 100 experimental subjects present inventor has performed experiment and having used guarantor manufactured according to the present invention Strong insole 04, is padded in the daily shoes walked of experimental subjects, by trimestral use, as a result 85% user reflects this guarantor The comfortable foot feeling of strong insole 04, support and massage effect is good is ventilative and do not generate unpleasant peculiar smell, by massage, magnetic therapy and in The effect of medicine sustained release, the QI invigorating that has effects that refresh oneself are prevented and cured diseases, health-care assistance.
This specific embodiment is only explanation of the invention, is not limitation of the present invention, those skilled in the art Member can according to need the modification that not creative contribution is made to the present embodiment after reading this specification, but as long as at this All by the protection of Patent Law in the scope of the claims of invention.

Claims (10)

1. a kind of manufacture craft of sole, which comprises the following steps:
Step S11, it feeds: being 80 DEG C~90 DEG C, after temperature reaches by the temperature setting of open mill, EVA pellet is added;
Step S12, it is kneaded: being separately added into stearic acid, zinc stearate and zinc oxide until expecting packet roller, after stirring 5-6 times, wait expect Uniform white is showed, is then added corresponding AC foaming agent and DCP crosslinking agent, after stirring 4-5 times, material shows uniform It is faint yellow, then add corresponding polyisobutene, after stirring 7-8 times, slice;
Step S13, sheet material obtained in step S12 cut-parts: is cut into die cavity size, uniform small pieces;
Step S14, moulded from foam: the small pieces cut out in step S13 are placed on compression molding instrument, temperature be 170 DEG C~ 175 DEG C, molding be 10MPa under conditions of foam 850 minutes;
Step S15, it modulus: after reaching preset clamp time in step S14, is quickly opened and takes out;
Step S16, cooling and shaping: the mold taken out in step S15 is cooled to 65 DEG C or so, and is immediately fed into 120 DEG C~170 DEG C baking oven in heating carry out second time of foaming, finally obtain the product high with hole-closing structure, mechanical strength.
2. a kind of manufacture craft of sole according to claim 1, it is characterised in that: the material in the step S12 is matched Than for EVA100phr, stearic acid 0.5phr, zinc stearate 0.7phr, zinc oxide 1.2phr, AC foaming agent 2phr, DCP crosslinking agent 1phr。
3. a kind of manufacture craft of sole according to claim 2, it is characterised in that: addition gathers different in the step S12 The weight ratio of butylene is 1%.
4. a kind of manufacture craft of sole according to claim 1, it is characterised in that: after naphthenic oil is heated to 120 DEG C, Petropols are added, are continuously agitated, until transparent sticky state is presented in Petropols, and are added after being cooled to room temperature Into step S12.
5. a kind of manufacture craft of sole according to claim 4, it is characterised in that: the Petropols include C5Resin, C9Resin and C5Hydrogenation resin, and weight ratio is 3%.
6. a kind of healthy shoe, it is characterised in that: the production work including a kind of sole as described in claims 1 or 2 or 3 or 4 or 5 Sole made by skill (02) and the footwear body (01) being set on the sole (02), structure between the footwear body (01) and sole (02) It is worn chamber (03) at what is protruded into for wearer foot, described wear in chamber (03) is equipped with health insoles (04), the health insoles (04) include elastic material bottom (2) and ventilative material surface layer (1), the bottom (2) is bonded fixation, institute with surface layer (1) It states and is equipped with Chinese traditional medicine layer (3) between bottom (2) and surface layer (1),
The lower end surface of the bottom (2) is integrally formed with the poroid Support of regular hexagon honeycomb (201);
The plantar reflecting region of the corresponding human body of the bottom (2) is provided with multiple magnetic sheets (603) mounting base (6), the magnetic sheet installation The lower end surface of seat (6) is equipped with opening (601), and the outer rim of the opening (601) extends to form limited wall (602) into hole, described The diameter of opening (601) is less than the diameter of magnetic sheet (603), and magnetic sheet (603) is installed into the magnetic sheet by opening (601) activity (603) in mounting base (6);
The plantar reflecting region of the corresponding human body of the surface layer (1) is equipped with multiple massage bumps (4);
The Chinese traditional medicine layer (3) is paper stock or cloth containing drug, and the formula of the drug includes: Radix Astragali 30g, herba taxilli 20g, Wild chrysanthemum 20g, pueraria lobata 20g, radix paeoniae rubra 20g, radix cyathulae 20g, Prunella vulgaris 20g, Rhizoma Chuanxiong 15g, Cortex Eucommiae 15g, Rhizoma Gastrodiae 15g , Common St.Paulswort Herb 15g, Semen Leonuri 15g, radix rehmanniae recen 15g, Cortex Phellodendri 15g, rhizoma anemarrhenae 15g, Moschus 2g, lanceleaf anisetree root 30g, folium artemisiae argyi 20g, ramulus cinnamomi 20g are red Flower 20g, asarum 20g, Radix Angelicae Sinensis 20g, caulis lonicerae 20g, Schisandra chinensis 15g, capsicum 15g, Chinese prickly ash 15g, Caulis Spatholobi 15g;
The making step of the Chinese traditional medicine layer are as follows:
Step S21, by addition to Moschus drug and 250g yellow lead put into pulverizer crush re-sieving;
Step S22,500g oil is added in a reservoir and heats, the stirring of yellow lead powder is put into after low-grade fever;
Step S23, drug powder is added and is stirred continuously, until drug powder is in coke yellow, reducing internal heat removes medicine with iron wire sieve Slag extracts plaster;
Step S24, plaster is put into cold water, impregnates, pulls out, dry, releasing fire-toxin;
Step S25, take cream medicine is placed in container, is melted and is stirred evenly in water-bath or mild fire, take a certain amount of plaster be coated in paper stock or On cloth, Moschus powder is sprinkled, is dried;
Manufactured Chinese traditional medicine layer is sewed or is affixed between bottom and surface layer.
7. a kind of healthy shoe according to claim 6, it is characterised in that: magnetic sheet mounting base (6) inner face and Chinese medicine The magnetic sheet mounting base (6), the drug powder formula is added by the opening (601) in layer (3) contact, drug powder are as follows: wood Fragrant 2g, wrinkled giant hyssop 2g, peppermint 2g, lavender 2g, crushed 120 meshes.
8. a kind of healthy shoe according to claim 6, it is characterised in that: position where the magnetic sheet mounting base (6) with Position where the massage bumps (4) is corresponding.
9. a kind of healthy shoe according to claim 6, it is characterised in that: the corresponding human body arch area of the surface layer (1) and Heel region is equipped with the supporting block (7) of protrusion.
10. a kind of healthy shoe according to claim 6, it is characterised in that: the surface layer (1) is throughout the massage bumps (4) small massage point (5), the bottom (2) are silica gel material, and the edge of the bottom (2) is the inclined-plane to smoothly transit, described Bottom (2) and surface layer (1) perforation are provided with multiple ventholes (8).
CN201811159800.2A 2018-09-30 2018-09-30 A kind of manufacture craft and healthy shoe of sole Pending CN109367091A (en)

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CN111253668A (en) * 2019-12-21 2020-06-09 温州市龙湾天龙鞋业有限公司 Anti-slip sole and preparation method thereof
CN112401403A (en) * 2020-11-13 2021-02-26 许伟强 Insole prepared by combining terahertz light waves with traditional Chinese medicines and preparation method thereof
CN116080110A (en) * 2022-12-29 2023-05-09 太仓力九和塑胶工业有限公司 Preparation process of elastic pad

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CN110338511A (en) * 2019-07-03 2019-10-18 汉中进丰鞋业有限公司 A kind of Chinese herbal medicine palm fiber shoe-pad
CN111253668A (en) * 2019-12-21 2020-06-09 温州市龙湾天龙鞋业有限公司 Anti-slip sole and preparation method thereof
CN112401403A (en) * 2020-11-13 2021-02-26 许伟强 Insole prepared by combining terahertz light waves with traditional Chinese medicines and preparation method thereof
CN116080110A (en) * 2022-12-29 2023-05-09 太仓力九和塑胶工业有限公司 Preparation process of elastic pad

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