CN109367060A - A kind of microwave heating curing method of pair of composite material - Google Patents
A kind of microwave heating curing method of pair of composite material Download PDFInfo
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- CN109367060A CN109367060A CN201811500937.XA CN201811500937A CN109367060A CN 109367060 A CN109367060 A CN 109367060A CN 201811500937 A CN201811500937 A CN 201811500937A CN 109367060 A CN109367060 A CN 109367060A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
- B29C70/30—Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core
- B29C70/34—Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core and shaping or impregnating by compression, i.e. combined with compressing after the lay-up operation
- B29C70/342—Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core and shaping or impregnating by compression, i.e. combined with compressing after the lay-up operation using isostatic pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
- B29C35/08—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
- B29C70/54—Component parts, details or accessories; Auxiliary operations, e.g. feeding or storage of prepregs or SMC after impregnation or during ageing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
- B29C35/08—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation
- B29C35/0805—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation
- B29C2035/0855—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation using microwave
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- Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Thermal Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Composite Materials (AREA)
- Mechanical Engineering (AREA)
- Toxicology (AREA)
- Heating, Cooling, Or Curing Plastics Or The Like In General (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
Abstract
The present invention provides the microwave heating curing method of a kind of pair of composite material, including uses a kind of composite material solidification equipment, and described device includes electrothermal piece, shake table, microwave generator, microwave cavity and vacuumizing part, and the shake table is arranged in microwave cavity；For placing composite material on shake table, the microwave generator and electrothermal piece are used to as the composite material heat supply；The shake table for the vibration of 5000Hz or less vibration frequency can be provided to the composite material and can provide 2g or more vibration acceleration vibration shake table；The method also includes one layer of strong absorbing material is first arranged at the area of its outer surface before composite material is heating and curing；The microwave generator and the strong absorbing material of setting make device that heating is pinpointed or oriented to composite material, and the electrothermal piece makes device carry out whole heating to composite material.The method of the invention can composite material solidify under atmospheric pressure to obtain the product of function admirable.
Description
Technical field
The invention belongs to composite material curing molding fields, and in particular to the microwave heating solidification side of a kind of pair of composite material
Method.
Background technique
Aerospace is formed with high performance resin based composites and mainly uses autoclave process at present, because when its solidification
Relatively high temperature and solidifying pressure are typically necessary to eliminate bubble caused by resin matrix in solidification process, such as T800
Carbon-fibre reinforced epoxy resin prepreg solidifies under conditions of 180 DEG C and 0.6MPa, to avoid dredging inside the product after solidification
Loose porous and poor mechanical property.
In conventional thermocompression tank curing process, due to the geometric dimension of composite product, material system and curing process
The difference of parameter can be different degrees of the uneven distribution for causing product internal temperature and curing degree, cause product to generate complicated
Internal stress, the shape Collaborative Manufacturing of composite product is seriously affected, especially for solidifying thick section parts, inside product
The defects of there are biggish temperature gradients, therefore the complicated internal stress generated can make product generate layering and MATRIX CRACKING, very
To being damaged product just during molding.
It, will be micro- because microwave has many advantages, such as that selectivity heating, heating speed is fast, homogeneous heating, penetrability is strong, thermal inertia is small
Wave technology is applied to composite material and solidifies field, can substantially reduce curing time, reduces production cost, obtains excellent product
Can, there is huge development potentiality.The patent right CN201610025303 that is formerly obtained such as present inventor,
CN201610027791, CN201610027866, CN201610030557 and CN201710214268 etc. are using microwave
Hot-press solidifying is carried out to composite material in conjunction with the technique of autoclave.So that the composite product of hot-press solidifying is in solidification process
In can obtain precisely required temperature field.
But the use of autoclave is all also be unable to do without in above-mentioned composite material solidification process.And autoclave forming process exists
Autoclave equipment itself is expensive, and production efficiency is low, energy consumption is high, device fabrication and operating cost are high, to molding die requirement
High some disadvantages.In addition, the operation with high pressure combination microwave in autoclave is in use, there is also some potential safety problemss.This is
The widely applied bottleneck of composite material is restricted through becoming, inexpensive non-autoclave forming technique is absurd fantastic in this background
It is raw.
Non-autoclave forming technique is a kind of inexpensive manufacture technology of composite material, main with autoclave forming process
Difference does not need to apply external pressure when being molding, abandons the autoclave to involve great expense, only with baking oven and pumped vacuum systems, therefore
The cured low production cost of composite material.This is better than autoclave forming process in terms of equipment molding and die cost.But
It is to obtain and solidify product with the composite material of autoclave forming process phase homogenous quantities, be the main mesh of non-autoclave molding technology
Mark.
However, the molding composite product porosity of non-autoclave is higher since briquetting pressure is low.General autoclave at
The porosity of type aerospace main force support structure part should be lower than 1%, and the porosity of secondary load-carrying construction part should be lower than 2%, and traditional
Material prepreg solidify according to non-autoclave forming technique, product porosity can be up to 5%~10%.Hole
An important factor for being influence composite property, therefore reduce the porosity for solidifying obtained composite product and reach
The porosity level of the composite product of solidification of hot-press tank, it has also become the top priority of non-autoclave forming technique research.
That is, with the continuous development of resin material curing process, the little non-bearing component of some stress, people
It has begun with curing process outside autoclave and makes.But for aerospace such as T800 carbon-fibre reinforced epoxy resin
The composite materials such as prepreg, only the solidifying pressure by vacuumizing is far from enough, because solidifying pressure is inadequate, after solidification inside product
The defects of gap will be generated, and then substantially reduce the mechanical property of product.So for the advanced resin base of aerospace
Carbon fibre reinforced composite can't reach requirement using curing technology outside current existing autoclave.
Therefore, for save the cost and raising safety coefficient, high-pressure curing is being carried out to composite material without using autoclave
When, if the porosity of the high-performance composite materials of aerospace can be made also to be able to achieve the similar hot-press solidifying in autoclave
Effect, this is those skilled in the art's problem to be solved.Therefore, those skilled in the art need to develop and be used for accordingly
High performance resin base carbon fibre enhances the cured device and method of composite product.
Summary of the invention
The present invention provides the microwave heating curing method of a kind of pair of composite material, including uses a kind of composite material solidification dress
It sets, described device includes electrothermal piece, shake table, microwave generator, microwave cavity and vacuumizing part, and the shake table is arranged micro-
Wave is intracavitary；For placing composite material on shake table, the microwave generator sends microwave into microwave cavity and is used to be described multiple
Condensation material heat supply, the electrothermal piece are also used for as the composite material heat supply；The vacuumizing part includes vacuum bag and vacuum
Pipe, and for extracting the gas generated in composite material solidification process out in time；The shake table is can be to the composite material
The vibration of 5000Hz or less vibration frequency is provided and the shake table of the vibration of 2g or more vibration acceleration can be provided；The method
It further include that one layer of strong absorbing material, the strong suction are first set at the area of its outer surface before composite material is heating and curing
Wave material refers to that the ability of its electromagnetic wave absorption energy is better than the material of the composite material；The microwave generator and setting
Strong absorbing material makes device be pinpointed or be oriented heating to composite material, the electrothermal piece make device to composite material into
The whole heating of row, the shake table provide the vibration acceleration of the vertical direction of 2g or more for solidifying for composite material.
In a kind of specific embodiment, electrothermal piece (222) setting is in microwave cavity (2).
In a kind of specific embodiment, the composite material is the composite material of carbon fiber and resin, the strong suction
Wave material is selected from one of di-iron trioxide and silicon carbide or a variety of.
In a kind of specific embodiment, described device further includes microwave power control module and control system, setting
Control system outside microwave cavity by automatically control microwave power control module automatically adjust microwave generator opening and closing and/
Or watt level；It is preferred that the control system is also electrically connected the opening and closing controlled for automatically adjusting electrothermal piece with the electrothermal piece
And/or heating rate.
In a kind of specific embodiment, the pressure in the composite material solidification process is 0.1~0.2MPa.
In a kind of specific embodiment, the shake table vibrates for that can provide 2000Hz or less to the composite material
The vibration of frequency and can provide 3g or more vibration acceleration vibration shake table.
In a kind of specific embodiment, the shake table vibrates frequency for that can provide 10Hz or more to the composite material
The vibration of rate and can provide 50g or less vibration acceleration vibration shake table, the preferably described shake table is can be to described multiple
Condensation material provides the vibration of 20Hz or more vibration frequency and can provide the shake table of the vibration of 30g or less vibration acceleration.
In a kind of specific embodiment, the shake table is can provide in 30~1000Hz extremely to the composite material
The vibration of small part vibration frequency and at least partly shake table of the vibration of vibration acceleration can be provided in 5~20g.
In a kind of specific embodiment, multiple vibration hammers, and each vibration hammer are connected with below the shake table (7)
It is connect with vibration hydraulic oil pipe or tracheae (71) to be provided commonly for the composite material for shake table and setting on a vibration table
The random continual vibration of acceleration vertical direction is provided, the preferably described vibration hammer is evenly distributed below shake table.
In a kind of specific embodiment, described device further includes temperature-measuring part, and the temperature-measuring part includes thermometric
Head, data collecting instrument and thermometric transmission line, the temperature measuring head are arranged in the composite, thermometric transmission line one end and thermometric
Head connection, the other end lead on the outside of the microwave cavity and connect with the data collecting instrument, and the data collecting instrument is for timely
Show the temperature that the temperature measuring head measures, and the data of acquisition are transmitted to control system (11), control system by data collecting instrument
The opening and closing and/or watt level of microwave generator are automatically adjusted by automatically controlling microwave power control module.
Preferably, the power adjustable section of the microwave generator, preferably its power linear are adjustable, and microwave generator is located at micro-
Wave top of chamber, the microwave generator include wave transparent heat-resistant board and leaky antenna.
Preferably, airfelt is additionally provided between the vacuum bag and composite material to lead for gas when vacuumizing
Stream, the vacuumizing part further includes quick union and sealant tape.
Using device and method provided by the invention, can at least bring it is following the utility model has the advantages that
1) present invention provides a kind of multi- scenarios methods such as the vibration acceleration field of electrical heat energy field, microwave energy field and vertical direction
Recombination energy field so that be heating and curing composite material when its internal temperature field and curing degree it is uniform.
2) whole heating is carried out to composite material as main heating source using electrothermal piece in device provided by the invention, and
Heating auxiliary is pinpointed or oriented using microwave, energy is provided, so that being heating and curing for composite material can be truly realized uniform throughout one
It causes.The inside and outside solidification that the internal temperature that the present invention is able to achieve composite product is uniformly distributed with product is synchronous, to subtract significantly
The probability of the various defects such as layering, deformation, cracking, residual stress occurs for the product after solidifying less, makes product because of internal temperature
Scrappage is greatly reduced caused by uneven, improves the quality of production and productivity effect of product.
3) present invention really realizes the uniform temperature fields of thick composite material and Varying-thickness large-scale composite material, inside and outside synchronization
Solidification helps to solve large-scale composite material primary load bearing product shape Collaborative Manufacturing problem.The present invention can be used for the quality of production and want
Harsh aerospace product is sought, the quality of production for improving aerospace product is had important practical significance.
4) in a kind of specific embodiment, present invention combination computer autocontrol technique, use is provided by the invention
Device can solidify the recombination energy field that composite material carries out automatically controlling.
Generally speaking, solidification equipment of the present invention and curing method can make material prepreg under atmospheric pressure
Solidify and obtains the product of function admirable.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of device of the present invention.
Wherein, 1, microwave generator, 2, microwave cavity, 5, vacuum bag, 6, airfelt, 7, shake table, 71, vibration use hydraulic oil
Pipe or tracheae, 8, vacuum tube, 222, electrothermal piece, 01, composite material.
Specific embodiment
The embodiment of the present invention is described in detail below, but the present invention can be limited and be covered according to claim
Multitude of different ways implement.
As known to those skilled in the art: shake table is also known as vibration exciter or vibration machine.It is a kind of using electric
Dynamic, electro-hydraulic pressure, piezoelectricity or other principles obtain the device of mechanical oscillation.Higher acceleration and higher is realized with lesser table top
Working frequency.Vibration test is broadly divided into sinusoidal vibration and random vibration.Shake table is suitable for auto parts and components, electronics member device
Coupled vibration is carried out to sample on the industries such as part, component, medicine, food, furniture, gift, ceramics, packaging laboratory and production line
Test.It is tested as environment receives, quality identification test, reliability compliance test, endurance test, vibration simulation analysis, material is special
Property test, fatigue test, vibration prevent improve etc..The vibration that analog equipment is subjected in manufacture, assembling, transport and use process
Rotating ring border, to evaluate resistance to vibration, reliability and the integrity of its structure.
That is, the purposes of shake table is limited to the service life of artificial post test product more at present.
And the random vibration of the vertical direction generated in the present invention using shake table, it is compound to be used for resin-based carbon fiber
In the solidification process of material, so that material prepreg is solidified into qualified composite product.Solidification in the present invention is former
Reason has references to concrete vibrating principle.Specifically, mixed and stirred with concrete agitator concreting component when, must exclude its
Phenomena such as middle bubble, is made firm by ramming, and concrete compaction is combined, and eliminates the voids and pits of concrete is guaranteed with improving its intensity
The quality of concrete component.The above-mentioned process eliminating bubble to concrete, being made firm by ramming is concrete vibrating.The vibration of low frequency formula
Dynamic frequency is 25~50HZ；Intermediate frequency formula is 83~133HZ；High frequency type is 167HZ or more.
For the present invention unlike concrete vibrating, vibration frequency of the invention first is not limited to the frequency of concrete vibrating
Rate, secondly, concrete vibrating belongs to cold curing, and the invention belongs to curing processes；In addition, being to utilize 2g or more in the present invention
The vibration vertically downward of vibration acceleration, and vibration acceleration direction is usually unordered in concrete vibrating.
Referring to the concrete secondary vibration that 1~4h or so is carried out before initial set, the present invention is subsequent can also accordingly to test two
Effect of the secondary vibration to composite material heat cure.
Present mature technology, such as " accelerating lifetime testing of commercially available acquisition can be used in shake table in the present invention
Instrument ", the shake table itself are exclusively used in the test that accelerates the failure of life of product, and are used to replace by such shake table in the present invention
High pressure in autoclave and make the solidification effect of carbon fiber resin composite material more excellent.
In addition, the direction of gravity acceleration g is always straight down, heretofore described shake table can provide 2g's or more
Vibration acceleration, i.e., the vibration acceleration that shake table provides in solidification process are 2g or more, g=9.8m/s2, when preferred consolidation shakes
Dynamic acceleration is 2~50g, more preferable 5~30g.Namely the vibration acceleration direction that shake table provides in the present invention is equally perpendicular
Histogram to.
Embodiment 1
Enhance material prepreg using device of the present invention solidification T800 resin-based carbon fiber,
First electric heating and shake table do vibration processing to composite material, and temperature is warming up to 80 DEG C by room temperature with 1.5 DEG C/min,
30min is kept the temperature later, and vibration frequency is the random vibration of 10-2000Hz, vibration acceleration 10g, g=9.8m/s2, at vibration
To composite material vacuumize process during reason, composite material local environment pressure is atmospheric pressure.
After the vibration processing that the composite material keeps the temperature 30min at 80 DEG C, stops vibration, be directly warming up to 180 DEG C by 80 DEG C
Heat cure is carried out, electric heating and the compound thermal field of microwave heating do elevated cure processing, the compound thermal of composite material to composite material
Field heating rate is 3~5 DEG C/min, this stage continues vacuumize process to composite material, and composite material local environment pressure is still
For atmospheric pressure.150min is kept the temperature after being warming up to 180 DEG C, obtains composite product after furnace cooling.Therefore, in vacuumized conditions
Under and ambient air pressure, the pressure that composite material is subject to be 0.1-0.2Mpa.
The porosity of gained composite product is 0.32~0.43%, the interlaminar shear strength of gained composite product
For 94.65~98.96Mpa.
In apparatus of the present invention, such as the vibration environment of the shake table are as follows: Triaxiality and six degrees of freedom super-Gaussian random vibration,
Peak acceleration is 75g, and vibration frequency is 10~5000Hz, and the temperature range of work is -100 DEG C~+200 DEG C.Vibration
Using external air compressor as power source, sustainable utilization pneumatic hammer provides stable vibration source for shake table, vibrates in vibration processes platform
It is transferred to composite material in the vertical direction from shake table.
Embodiment 2
Solidify T800 composite material using device of the present invention,
First electric heating and shake table do vibration processing to composite material, and temperature is warming up to 135 by room temperature with 1.5 DEG C/min
DEG C, keep the temperature 30min later, vibration frequency is the random vibration of 10-2000Hz, vibration acceleration 15g, during vibration processing
To composite material vacuumize process, composite material local environment pressure is atmospheric pressure.
After the vibration processing that the composite material keeps the temperature 20min at 135 DEG C, stops vibration, be directly warming up to 180 by 135 DEG C
DEG C carry out heat cure, electric heating and the compound thermal field of microwave heating do elevated cure processing to composite material, composite material it is compound
Thermal field heating rate is 3~5 DEG C/min, this stage continues vacuumize process, composite material local environment pressure to composite material
It is still atmospheric pressure.150min is kept the temperature after being warming up to 180 DEG C, obtains composite product after furnace cooling.
The porosity of gained composite product is 0.23~0.28%, the interlaminar shear strength of gained composite product
For 105.32~107.95Mpa.
Embodiment 3
Solidify T800 composite material using device of the present invention,
First electric heating and the compound thermal field of microwave heating do elevated cure processing to composite material, and shake table is simultaneously to composite wood
Material does vibration processing, and temperature is warming up to 180 DEG C by room temperature with 3~5 DEG C/min, keeps the temperature 10min, vibration frequency 10- later
The random vibration of 2000Hz, vibration acceleration 10g, vibration processing is in the process to composite material vacuumize process, composite material
Local environment pressure is atmospheric pressure.
After the vibration processing that the composite material keeps the temperature 10min at 180 DEG C, stops vibration, continues 180 DEG C of heat preservation 150min,
Electric heating and the compound thermal field of microwave heating solidify complex material heat preservation, this stage continues vacuumize process to composite material, multiple
Condensation material local environment pressure is still atmospheric pressure.After heat preservation, composite product is obtained after furnace cooling.
The porosity of gained composite product is 0.16~0.22%, the interlaminar shear strength of gained composite product
For 109.74~116.33Mpa.
Comparative example 1
This comparative example is that autoclave is used alone to carry out high temperature and pressure integrally curing to T800 composite material, and solidifying pressure is
0.6MPa, electric heating makes composite temperature be warming up to 180 DEG C by room temperature with 1.5 DEG C/min in autoclave, and is warming up to 180
150min is kept the temperature after DEG C, and composite product is obtained after furnace cooling, composite material is vacuumized in entire solidification process
Processing.
The porosity of gained composite product is 0.36%, and the interlaminar shear strength of gained composite product is
98.15Mpa。
Comparative example 2
This comparative example is that microwave is used alone to carry out high temperature integrally curing to T800 composite material, and solidifying pressure is environment pressure
Power, i.e. atmospheric pressure, microwave heating makes composite temperature be warming up to 180 DEG C by room temperature with 3~5 DEG C/min, and is warming up to 180
150min is kept the temperature after DEG C, and composite product is obtained after furnace cooling, composite material is vacuumized in entire solidification process
Processing.
The porosity of gained composite product is 1.45~1.56%, the interlaminar shear strength of gained composite product
For 74.63~76.97Mpa.
By the comparison result of the embodiment of the present invention 1~3 and comparative example 1 and 2 it is found that being obtained after device of the present invention solidification
To the performance of composite product can compare favourably completely with this standard cure process of solidification of hot-press tank.Even in the present invention
After optimizing vibration time, vibration outlet temperature, vibration frequency and vibration acceleration, in device and method provided by the invention
Composite material solidification effect can also be significantly better than solidification of hot-press tank.This make the present invention solution " it is desirable that do not use it is expensive and
While not safe enough autoclave equipment progress composite material solidification " problem, it is solid that unexpected composite material is also obtained
Change effect, the product properties of product after solidification are even better than this standardization program of solidification of hot-press tank.
In conclusion the present invention at least has the following characteristics that
1, the composite product haveing excellent performance is prepared in the case where vacuumizing and not impressed pressure by the present invention, drops
Low composite material curing molding pressure, and curing rate has obtained a degree of quickening, has saved equipment cost and solidification
Cost realizes composite product safety, uniform, efficient, energy conservation ground forming and hardening.
2, after the present invention can also be by optimization vibration time, vibration outlet temperature, vibration frequency and vibration acceleration, make
The performance for obtaining composite product is better than composite product made from this standardization program of solidification of hot-press tank.Reason is analyzed,
May be composite material for example 0.6MPa condition of high voltage solidification when, although pressure can be with the preimpregnation of Effective Compaction composite material
Laying is expected, to improve the quality of product, but pressure is gradually transmitted inwards from the surface of composite material, is pressurized not in table
Together, thus solidify gained product porosity it is relatively high and distribution of pores is uneven.And vibration downward in the present invention accelerates
Under degree, for composite material everywhere by uniform vibration acceleration, it equally can be with the prepreg of Effective Compaction composite material
Laying, to improve the quality of product, and solidify gained product porosity can lower and distribution of pores it is more uniform.
3, by composite heater and vibration device integrated setting in the present invention so that composite product in vibration and
It can continue to heat up or keep the temperature without cooling after heat treatment to carry out heat cure, solidify the product of resulting composite product
It can be more preferable.
4, in a kind of specific embodiment, the present invention in, will not be needed in composite product especially heat or
Cured region is covered with micro-wave screening material, does not cover micro-wave screening then to needs especially heating or cured region
Material stays one or more gap, so that the microwave shadow shield part is formed by shield microwaves area and through microwave region.Microwave
Generator generates microwave and enters and be dispersed in microwave cavity, and the region of micro-wave screening material is not pasted to composite product
(penetrating microwave region) is internally heated or solidifies.The region that micro-wave screening material has been pasted on composite product (shields micro-
Wave area) since microwave not can enter wherein, so these regions are absorbed less than microwave energy, and can only receive from electrothermal piece
222 whole heating.Therefore, it may make composite wood of the invention in such a way that the heating of microwave fixed point and electrothermal piece are integrally heated
Expect that temperature is uniform everywhere in the curing process for product.Therefore, recombination energy field heating provided by the invention is directed to microwave
The part of composite product is especially heated and is solidified, by the composite material I of certain concrete shape, material and size
After the heating parameters research of part is clear, electrothermal piece is used in combination, whole heating is carried out to workpiece, may make that heat curing process is whole
Body uniform, controllable, to obtain high performance product product.Or in the present invention before composite material is heating and curing first outside it
One layer of strong absorbing material is set at the area on surface, enhances the microwave energy absorption of portion on composite material.Equally
The effect that microwave fixed point heating is integrally heated with electrothermal piece can be played.
In addition, the present invention be series of patents or patent application CN201610025303, CN201610027791,
The improvement and innovation done on the basis of CN201610027866, CN201610030557 and CN201710214268, if this
Have in invention in the presence of not careful enough place is described, can refer to these patents or patent application is implemented.That is, the present invention also draws
Enter the content comprising these patents or patent application.
The shape of the incubator can be any moulding such as cube and cylindrical body.In the prior art for solidifying T800
The autoclave of prepreg needs pressure resistance, and tank skin is thick and solid.And the incubator in the present invention need to only provide an atmospheric pressure or be slightly above
The pressure of atmospheric pressure, so its cost is much lower.It is preferred that being provided in the incubator other than microwave cavity in the present invention for heat
The fan of gas convection current.The shake table is connected on the bottom plate of the microwave cavity using three or more helical springs, preferably extremely
Being each provided with a spring in the table top following four corners position of shake table is used to support shake table less.
The above content is combine specific preferred embodiment to the further description of the invention made, and it cannot be said that originally
The specific implementation of invention is only limited to these instructions.For those of ordinary skill in the art to which the present invention belongs, not
Under the premise of being detached from present inventive concept, several simple deductions and replacement can also be made, all shall be regarded as belonging to guarantor of the invention
Protect range.
Claims (10)
1. the microwave heating curing method of a kind of pair of composite material, including use a kind of composite material solidification equipment, described device
Including electrothermal piece (222), shake table (7), microwave generator (1), microwave cavity (2) and vacuumizing part, the shake table (7) is set
It sets in microwave cavity (2)；For placing composite material (01) on shake table, the microwave generator sends microwave into microwave cavity
For for the composite material heat supply, the electrothermal piece (222) to be also used for as the composite material heat supply；The vacuumizing part
Including vacuum bag (5) and vacuum tube (8), and for extracting the gas generated in composite material solidification process out in time；The vibration
Platform is moved as that can provide the vibration of 5000Hz or less vibration frequency to the composite material and 2g or more vibration acceleration can be provided
Vibration shake table；The method also includes being first arranged at the area of its outer surface before composite material is heating and curing
One layer of strong absorbing material, the strong absorbing material refer to that the ability of its electromagnetic wave absorption energy is better than the material of the composite material
Material；The microwave generator and the strong absorbing material of setting make device that heating is pinpointed or oriented to composite material, described
Electrothermal piece makes device carry out whole heating to composite material, and the shake table provides the perpendicular of 2g or more for solidifying for composite material
Histogram to vibration acceleration.
2. the method according to claim 1, wherein the electrothermal piece (222) setting is in microwave cavity (2).
3. the method according to claim 1, wherein the composite material is the composite wood of carbon fiber and resin
Material, the strong absorbing material are selected from one of di-iron trioxide and silicon carbide or a variety of.
4. method according to any one of claims 1 to 3, which is characterized in that described device further includes microwave power
Control module and control system, the control system being arranged in outside microwave cavity are automatic by automatically controlling microwave power control module
Adjust the opening and closing and/or watt level of microwave generator；It is used it is preferred that the control system is also electrically connected control with the electrothermal piece
In the opening and closing and/or heating rate of automatic adjustment electrothermal piece.
5. method according to any one of claims 1 to 3, which is characterized in that in the composite material solidification process
Pressure be 0.1~0.2MPa.
6. method described according to claim 1~any one of 5, which is characterized in that the composite material is T800 carbon fiber
Reinforced epoxy prepreg is tieed up, the shake table is can provide the vibration of 2000Hz or less vibration frequency to the composite material
And the shake table of the vibration of 3g or more vibration acceleration can be provided.
7. method described according to claim 1~any one of 5, which is characterized in that the shake table is can be to described multiple
Condensation material provides the vibration of 10Hz or more vibration frequency and can provide the shake table of the vibration of 50g or less vibration acceleration, excellent
The shake table is selected as that can provide the vibration of 20Hz or more vibration frequency to the composite material and 30g or less can be provided and vibrate
The shake table of the vibration of acceleration.
8. method according to any one of claims 1 to 3, which is characterized in that the shake table is can be to described multiple
Condensation material at least partly vibration of vibration frequency is provided in 30~1000Hz and can provide in 5~20g at least partly vibration plus
The shake table of the vibration of speed.
9. method described according to claim 1~any one of 5, which is characterized in that be connected with below the shake table (7)
Multiple vibration hammers, and each vibration hammer is connect with vibration hydraulic oil pipe or tracheae (71) to be provided commonly for as shake table and set
The composite material set on a vibration table provides the random continual vibration of acceleration vertical direction, and the preferably described vibration hammer is uniform
It is distributed in below shake table.
10. method described according to claim 1~any one of 6, which is characterized in that described device further includes thermometric portion
Part, and the temperature-measuring part includes temperature measuring head, data collecting instrument and thermometric transmission line, the temperature measuring head is arranged in composite material
In, thermometric transmission line one end is connect with temperature measuring head, and the other end is led on the outside of the microwave cavity and the data collecting instrument
Connection, the data collecting instrument for showing the temperature that the temperature measuring head measures in time, and data collecting instrument is by the data of acquisition
It is transmitted to control system (11), control system automatically adjusts microwave generator by automatically controlling microwave power control module
Opening and closing and/or watt level.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| WO2020114467A1 (en) * | 2018-12-07 | 2020-06-11 | 中南大学 | Curing apparatus and curing method for composite material |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1044747A (en) * | 1988-12-30 | 1990-08-15 | 莱弗布拉德高级血库系统(有限公司) | The blood, blood components that low quick-thawing low temperature is preserved and the method and apparatus of cell tissue |
| CN1873064A (en) * | 2006-06-30 | 2006-12-06 | 北京化工大学 | Directional magnetic electrical spinning Nano fibers, preparation method and equipment needed |
| CN101913854A (en) * | 2010-08-18 | 2010-12-15 | 重庆大学 | Preparation method of nanometer strontium ferrite magnetic powder |
| CN203159237U (en) * | 2013-01-29 | 2013-08-28 | 长沙隆泰微波热工有限公司 | High-purity polycrystalline silicon preparation device |
| CN103587130A (en) * | 2013-10-15 | 2014-02-19 | 南京航空航天大学 | Method and device for curing fiber-reinforced resin-based composite material component by utilizing microwaves |
| US20160067888A1 (en) * | 2014-09-09 | 2016-03-10 | The Boeing Company | Method and Apparatus for Microwave and Convection Composite Curing |
| CN108102109A (en) * | 2017-12-28 | 2018-06-01 | 南京楚卿电子科技有限公司 | Magnetic nanoparticle polymer composites and preparation method thereof |
| CN108839359A (en) * | 2018-06-20 | 2018-11-20 | 中南大学 | Composite element curing process and composite product |
-
2018
- 2018-12-10 CN CN201811500937.XA patent/CN109367060B/en active Active
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1044747A (en) * | 1988-12-30 | 1990-08-15 | 莱弗布拉德高级血库系统(有限公司) | The blood, blood components that low quick-thawing low temperature is preserved and the method and apparatus of cell tissue |
| CN1873064A (en) * | 2006-06-30 | 2006-12-06 | 北京化工大学 | Directional magnetic electrical spinning Nano fibers, preparation method and equipment needed |
| CN101913854A (en) * | 2010-08-18 | 2010-12-15 | 重庆大学 | Preparation method of nanometer strontium ferrite magnetic powder |
| CN203159237U (en) * | 2013-01-29 | 2013-08-28 | 长沙隆泰微波热工有限公司 | High-purity polycrystalline silicon preparation device |
| CN103587130A (en) * | 2013-10-15 | 2014-02-19 | 南京航空航天大学 | Method and device for curing fiber-reinforced resin-based composite material component by utilizing microwaves |
| US20160067888A1 (en) * | 2014-09-09 | 2016-03-10 | The Boeing Company | Method and Apparatus for Microwave and Convection Composite Curing |
| CN108102109A (en) * | 2017-12-28 | 2018-06-01 | 南京楚卿电子科技有限公司 | Magnetic nanoparticle polymer composites and preparation method thereof |
| CN108839359A (en) * | 2018-06-20 | 2018-11-20 | 中南大学 | Composite element curing process and composite product |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020114467A1 (en) * | 2018-12-07 | 2020-06-11 | 中南大学 | Curing apparatus and curing method for composite material |
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