CN109364668A - A kind of energy-saving and emission-reduction flue gas and desulfurizing and denitrifying device and device special-purpose coat - Google Patents

A kind of energy-saving and emission-reduction flue gas and desulfurizing and denitrifying device and device special-purpose coat Download PDF

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Publication number
CN109364668A
CN109364668A CN201811431943.4A CN201811431943A CN109364668A CN 109364668 A CN109364668 A CN 109364668A CN 201811431943 A CN201811431943 A CN 201811431943A CN 109364668 A CN109364668 A CN 109364668A
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China
Prior art keywords
coating
flue gas
output end
emission
saving
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CN201811431943.4A
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Chinese (zh)
Inventor
张忠其
张栩婕
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Yixing City Hai Na Genie Et Environnement
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Yixing City Hai Na Genie Et Environnement
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D50/00Combinations of methods or devices for separating particles from gases or vapours
    • B01D50/40Combinations of devices covered by groups B01D45/00 and B01D47/00
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/54Nitrogen compounds
    • B01D53/56Nitrogen oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/75Multi-step processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/76Gas phase processes, e.g. by using aerosols
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77Liquid phase processes
    • B01D53/78Liquid phase processes with gas-liquid contact
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/14Polycondensates modified by chemical after-treatment
    • C08G59/1433Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds
    • C08G59/1438Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds containing oxygen
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • C09D7/62Additives non-macromolecular inorganic modified by treatment with other compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • F23J15/02Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
    • F23J15/022Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material for removing solid particulate material from the gasflow
    • F23J15/025Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material for removing solid particulate material from the gasflow using filters
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • F23J15/02Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
    • F23J15/04Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material using washing fluids
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • F23J15/06Arrangements of devices for treating smoke or fumes of coolers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0283Flue gases
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/30Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3009Sulfides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2215/00Preventing emissions
    • F23J2215/10Nitrogen; Compounds thereof
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2215/00Preventing emissions
    • F23J2215/20Sulfur; Compounds thereof
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2217/00Intercepting solids
    • F23J2217/40Intercepting solids by cyclones
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/30Technologies for a more efficient combustion or heat usage
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency

Abstract

The invention discloses a kind of energy-saving and emission-reduction flue gas and desulfurizing and denitrifying devices, including boiler, denitrification apparatus, desulfurizer and chimney, the output end of boiler is connected by the input terminal of the first deduster and denitrification apparatus, the output end of denitrification apparatus is connected with air preheater, the output end of air preheater is connected with First Heat Exchanger, the output end of First Heat Exchanger is connect with the input terminal of the second deduster, the output end of second deduster is connected with the second heat exchanger by blower, the output end of second heat exchanger is connected with desulfurizer, the output end of desulfurizer is connected with lye absorption plant, lye absorption plant output end is connect with chimney, the apparatus structure is simple and compact, effect is obvious, good energy-saving and emission-reduction, denitration desulfurization, it is low in cost;The coating that the present invention also designs the device has good chemical reagent-resistant performance good, extends the service life of device.

Description

A kind of energy-saving and emission-reduction flue gas and desulfurizing and denitrifying device and device special-purpose coat
Technical field
The present invention relates to a kind of desulfuring and denitrifying apparatus, and in particular to a kind of energy-saving and emission-reduction flue gas and desulfurizing and denitrifying device and The special-purpose coat of the device.
Background technique
Thermal energy has many uses, it may be directly applied to live and produce in, as air conditioning, metallurgy, weaving, chemical industry, The fields such as papermaking, can also be with reconvert at the energy of other forms, such as electric energy, mechanical energy, and thermal energy will be changed by dyestuff burning Can be changed into made of vapor or flue gas, and chemical energy therein is converted into entrained by combustion product by fuel by burning Thermal energy, carrier is exactly flue gas;
I crossed average annual 30.5 hundred million tons of raw coal output or so in recent years, generated electricity 15.6 hundred million tons of raw coal, the firepower based on burning Generated energy still accounts for 80% or more of whole generated energy, and for thermal power plant, heat loss due to exhaust gas is boiler various heat losses In maximum one, generally in 5-8%, account for the 80% or higher of boiler Total heat loss, influence the principal element of heat loss due to exhaust gas It is exhaust gas temperature, the exhaust gas temperature actual motion value of many station boilers in China is all higher than about 20-50 DEG C of design value, reaches 130-150 DEG C, the economy that exhaust gas temperature drop greatlys improve station boiler is greatly lowered, calculates discovery, row by practical Smoke temperature degree reduces by 35 DEG C or so, and system powergenerationcycleefficiency improves 0.5% or more, and every degree electricity saves 1.5 grams of standard coals or more, tool There are apparent energy-saving and emission-reduction potentiality;
With social progress and environmental requirement, the flue gas after combustion heating goes out chimney in recycling heat heel row and is discharged into greatly Gas, dust burdening is big in flue gas, also will cause the pollution of air containing alkali metal, sulphur etc., therefore, research and develop it is a kind of have well subtract energy The device of emission reduction combination desulphurization denitration becomes those skilled in the art's technical problem urgently to be resolved.
Summary of the invention
The technical problem to be solved by the present invention is to the shortcomings that overcoming the prior art, it is same provide a kind of energy-saving and emission-reduction flue gas When desulfuring and denitrifying apparatus and device special-purpose coat, the apparatus structure is simple and compact, and effect is obvious, good energy-saving and emission-reduction, denitration Desulfurization, low in cost, which has good chemical reagent-resistant performance good, extends the service life of device.
In order to solve the above technical problems, the present invention provides a kind of energy-saving and emission-reduction flue gas and desulfurizing and denitrifying device, including The output end of boiler, denitrification apparatus, desulfurizer and chimney, boiler is connected by the input terminal of the first deduster and denitrification apparatus It connects, the output end of denitrification apparatus is connected with air preheater, and the output end of air preheater is connected with First Heat Exchanger, and first changes The output end of hot device is connect with the input terminal of the second deduster, and the output end of the second deduster is connected with the second heat exchange by blower Device, the output end of the second heat exchanger are connected with desulfurizer, and the output end of desulfurizer is connected with lye absorption plant, and lye is inhaled Receiving apparatus output end is connect with chimney, in which:
Lye absorption plant includes absorption tower, lye head tank and neutralization pond, the input terminal and lye head tank on absorption tower Connection, the output end on absorption tower are connect with neutralization pond, and the upper end on absorption tower is equipped with flue gas gas outlet and is connected to lye head tank Mouth spray, the lower end on absorption tower is equipped with smoke air inlet and lye export, equipped with being connected to lye head tank in absorption tower Rotation fan is also distributed on the horizontal cross-section on absorption tower for effluent column.
The technical solution that the present invention further limits is:
Further, in aforementioned energy-saving and emission-reduction flue gas and desulfurizing and denitrifying device, the first deduster by fume treatment room and Ash bucket composition is stored up, storage ash bucket is set to the lower end of fume treatment room, and the bottom for storing up ash bucket is equipped with ash-valve, and fume treatment room is by upper It is divided into the first process chamber, second processing room and third process chamber under, in which:
The upper end of first process chamber is equipped with exhaust outlet, and the side of the first process chamber is equipped with discharge outlet, and discharge outlet is equipped with row Water valve, the first indoor top level of processing are equipped with sparge pipe, and sparge pipe is connect with water pump, and sparge pipe is equipped with several through-holes, Sparge pipe parallel beneath is equipped with filter screen, and baffle plate is additionally provided in the first process chamber, and left and right is staggered between adjacent baffle, The first indoor lower end of processing, which is closed on the baffle plate of second processing room, is provided with baffle, and baffle is vertically arranged with baffle plate, if The one end for having the baffle plate of baffle to be located on deduster inner wall is connected to discharge outlet;
Second processing room side is equipped with air inlet, is separated between the first process chamber and second processing room by inclined-plane, the It is formed between two process chambers and third process chamber by a plane separation, along the descending several rotations of setting in inclined-plane in second processing room Wind separator, and the bottom end of cyclone separator both passes through plane and extends to third process chamber.
Technical effect, the first deduster commutativity of the invention is strong, and non-filling, light-weight user in the deduster Just, the second processing room of process chamber is inlet plenum, and third process chamber is dust, gas separation chamber, and dusty gas is at second Enter in third process chamber under the action of guide vane in reason room and separated, such mode can reduce dusty gas and bring dedusting The impact of device, high dust collection efficiency, dedusting time is short, save the cost, reduces the time;Sparge pipe is equipped at the top of deduster simultaneously It is dusted processing, filter screen is also assisted dust-collecting, while having baffle plate, and flue gas slowly reaches sparge pipe along baffle plate Dedusting again is carried out, the water flow of dedusting sets bottom one piece of baffle plate, and blocks the discharge outlet by the other end by the baffle of one end Discharge, does not influence the operation of the other component in deduster.
In aforementioned energy-saving and emission-reduction flue gas and desulfurizing and denitrifying device, cyclone separator includes outer sleeve, inner sleeve and whirlwind Son, inner sleeve are inserted into outer sleeve and are equipped with Whirlwind cyclone between inner sleeve and outer sleeve.
In aforementioned energy-saving and emission-reduction flue gas and desulfurizing and denitrifying device, gravitation is additionally provided between the first deduster and denitrification apparatus Blower.
In aforementioned energy-saving and emission-reduction flue gas and desulfurizing and denitrifying device, ozone generator is also connected on denitrification apparatus.
Technical effect, so that denitration effect is more complete, the denitration time is short, saves the time, improves efficiency.
In aforementioned energy-saving and emission-reduction flue gas and desulfurizing and denitrifying device, the axis for rotating fan is connected with waterproof variable-frequency motor, prevents Water variable-frequency motor in motor shaft by being fixed in tower body.
In aforementioned energy-saving and emission-reduction flue gas and desulfurizing and denitrifying device, several change is equipped in First Heat Exchanger, the second heat exchanger Heat pipe, heat exchanger tube are light pipe, finned tube or screwed pipe.
In aforementioned energy-saving and emission-reduction flue gas and desulfurizing and denitrifying device, the second deduster is bag filter.
In aforementioned energy-saving and emission-reduction flue gas and desulfurizing and denitrifying device, which includes following components according to the mass fraction:
Modifying epoxy resin by organosilicon: 15-20 parts, polyether sulphone ketone modified resin: 10-12 parts, black silicon carbide: 5-7 parts, Levelling agent: 1-2 parts, filler: 1-3 parts, plasticizer: 5-7 parts, thixotropic agent: 2-4 parts, blanc fixe: 5-7 parts, pigment: 1-3 Part, dispersing agent: 3-5 parts, curing agent: 10-13 parts, compound rare-earth: 0.01-0.03 parts;
Modifying epoxy resin by organosilicon includes following component by mass percentage: deionized water: 13-18%, two laurels Sour dibutyl tin: 10-13%, methyltriethoxysilane: 10-14%, surplus are epoxy resin, and the sum of the above components are 100%;
Plasticizer is one of dioctyl phthalate, tricresyl phosphate or dibutyl phthalate;Face Material is one of titanium dioxide, iron oxide red, carbon black, barium sulfate or chrome oxide green;Dispersing agent is sodium tripolyphosphate, four polyphosphoric acids One of sodium or calgon;Curing agent is modified polyamide class curing agent;Thixotropic agent is organo montmorillonite and gas phase two Silica;Filler is the mixture of glass flake, talcum powder and molybdenum disulfide, wherein glass flake: talcum powder: molybdenum disulfide =3:1:2, glass flake press 80 mesh glass flakes: 40 mesh glass flakes=2:1 by 80 mesh glass flakes and 40 mesh glass flakes Ratio mixing;Compound rare-earth includes following component by weight percentage: Y:23-25%, Sc:16-18%, Gd:11-13%, Sm:15-18%, Pr:9-11%, surplus La, the sum of the above components are 100%.
In aforementioned energy-saving and emission-reduction flue gas and desulfurizing and denitrifying device, the construction technology of special-purpose coat specifically:
(1) it pre-processes: the surface for needing spray-on coating device being purged with giant, remove thorn bits, the weldering on surface Slag, splash, surface and oil contaminant, oxide skin, iron rust and other sundries are purged processing;
When being purged should from top to bottom, corner angle, dead angle and except clean place can with scraper, sand paper benefit remove, Finally also want the drying on holding meanss surface;
(2) sandblasting: using efficient sandblasting machine equipment, makes the gas from air compressor machine by pressure vessel and oil water separator The compressed air for becoming dried and clean drives sand grains high speed to beat and carries out sandblasting in apparatus surface by sand-blasting machine, what sandblasting used Sand grains is shot, and the angle of partial size 0.5-1.5mm, injection direction and body structure surface normal are 10 ° -30 °;
(3) ultrasonic cleaning is put into matching purge liquid (existing cleaning in supersonic wave cleaning machine to the device after blasting treatment Liquid) it is cleaned, then time 10-13min is dried;
(4) by physical gaseous phase deposition coating method to needing the cutting part of coating to carry out coating, coating temperature control exists 150-200℃;
(5) aluminium-plated: it is aluminium-plated in apparatus surface progress, apparatus surface is implemented with high-voltage arc flush coater aluminium-plated, it is desirable that spray Painting is evenly distributed, and vertical direction at least sprays twice, controls aluminized coating with a thickness of 30-38 μm;
(6) sealing paint coating: after the completion of aluminium-plated program, Seal treatment is once done with neutral paint application;
(7) spray gun spraying above-mentioned apparatus special-purpose coat the formation of coating: is used outside to the aluminized coating for having done Seal treatment;
(8) rotating forward 20-25min is carried out to coating position using pull-type polishing machine for inactivating, inverts 20-25min.
The beneficial effects of the present invention are:
There are two deduster in the present invention, the first deduster can carry out the place of a dust as pre-duster in the past Then reason is carrying out denitration, good dedusting effect becomes apparent from, more efficient;
Lye absorption plant oil lye head tank of the invention provides the removal that lye carries out acid gas in flue gas, removal Waste water in neutralized pond and is discharged again afterwards, reduces pollution damage, protects environment, while lower end is equipped with effluent column, alkali in absorption tower Liquid thus flows out and smoke contacts, while upper end has mouth spray spray lye to mix again with flue gas, under the rotation of rotation fan, Flue gas and liquid are broken into liquid mist, are increased absorbability, are removed sour gas well, so that the flue gas being finally discharged more ring It protects;In addition, the combined process of rotation fan and upper end mouth spray lower end effluent column is simple, and it is low in cost, compared to other atomizers It is cheap etc. easily facilitating.
In the present invention use ingredient of the polyether sulphone ketone modified resin as coating, the resin with self-lubricating, wearability, The features such as good mechanical property, high temperature resistant, chemical-resistant, anti-flammability, radiation resistance, hydrolytic resistance, insulation stability.
Dispersing agent is added in the present invention, dispersing agent can increase the compatibility between base-material, and particle wadding can be prevented poly-, reduce and apply Expect viscosity, is firmly adsorbed on the surface of dispersed particle, and provide good space repulsion, fills particle under high velocity agitation After dispersion, it will not reunite because of Van der Waals force and again, adsorption layer will not be shelled when by external force from particle surface From and lead to the unstable of system, to optimize the physical and chemical properties of coating;The pigment used in the present invention mainly plays screening The effect of lid and colouration;The filler of use mainly plays enhancing, assigns property, changes rheological property, reduces the effect of cost; The plasticizer used in the present invention can be substantially reduced the glass transition temperature of film, and then enhance the flexibility of film, simultaneously also The minimum film formation temperature of emulsion coatings can be reduced, coating application performance is improved;During coating, there may be foam production It is raw, therefore proper quantity of defoaming agent is added and eliminates out foam;Auxiliary material of the invention is compound rare-earth, due to the metal of the above rare earth element Atomic radius is big and rare earth activity with higher, it is easy to the gap of storeroom is filled up, meanwhile, rare earth element is easily and oxygen, sulphur Equal element compounds generate the high compound of fusing point, and the addition of compound rare-earth improves the dispersibility for preparing coating to a certain extent And compatibility, so that product mix is uniformly also improved the anti-flammability of coating.
Deionized water is used when prepared by modifying epoxy resin by organosilicon of the present invention, the performance of coating obtained by the purity of water has one Fixed influence contains a little metal ion in tap water, can cause the polycondensation reaction between hydrolysate silanol, thus to product The performance of coating generates adverse effect, and the performance of side effects coating will not be generated using deionized water.
The present invention is not limited using thermal spraying aluminium layer method by scantling, and simple process is flexible, and arc spraying zinc aluminum Very good solution fogging problem, hot jet coating surface have certain micropore, do so reusing neutral paint to aluminized coating Seal treatment makes steel construction obtain safer anti-corrosion protection, while neutral paint is used as priming paint, it does not rise with aluminized coating anti- It answers, and can preferably be combined in aluminized coating and finishing coat;The present invention forms electrode potential in apparatus surface using arc spraying aluminium Lower than metal layer, when surface has electrolyte to constitute corrosion cell, source current flows to steel substrate from coating, as a result coating Corroded and the cathodically protected effect of matrix.
Construction technology of the invention can reduce the temperature of coating, reduce that coating temperature is excessively high to have an impact device, improve Apparatus surface quality, prolongs the service life.
Detailed description of the invention
Fig. 1 is the system schematic of the embodiment of the present invention;
Fig. 2 is the structural schematic diagram of the first deduster in the embodiment of the present invention;
Fig. 3 is the structural schematic diagram of lye absorption plant in the embodiment of the present invention;
In figure: 1- boiler, 2- denitrification apparatus, 3- desulfurizer, 4- chimney, the first deduster of 5-, 51- store up ash bucket, 52- the One process chamber, 521- exhaust outlet, 522- discharge outlet, 523- sparge pipe, 524- filter screen, 525- through-hole, 526- baffle plate, 527- Baffle, 53- second processing room, 531- air inlet, tri- process chamber of 54-, 6- First Heat Exchanger, the second deduster of 7-, 8- second are changed Hot device, 9- lye absorption plant, the absorption tower 91-, 92- lye head tank, 93- neutralization pond, 94- mouth spray, 95- effluent column, 96- Rotation fan, 97- lye export, 10- air preheater.
Specific embodiment
Embodiment 1
A kind of energy-saving and emission-reduction flue gas and desulfurizing and denitrifying device provided in this embodiment, structure as shown in Figure 1-3, include pot Furnace 1, denitrification apparatus 2, desulfurizer 3 and chimney 4, it is characterised in that: the output end of boiler 1 passes through the first deduster 5 and denitration The input terminal of device 2 connects, and the output end of denitrification apparatus 2 is connected with air preheater 10, and the output end of air preheater 10 connects Be connected to First Heat Exchanger 6, the output end of First Heat Exchanger 6 is connect with the input terminal of the second deduster 7, the second deduster 7 it is defeated Outlet is connected with the second heat exchanger 8 by blower, and the output end of the second heat exchanger 8 is connected with desulfurizer 3, desulfurizer 3 Output end is connected with lye absorption plant 9, and 9 output end of lye absorption plant is connect with chimney 4, in which:
Lye absorption plant 9 includes absorption tower 91, lye head tank 92 and neutralization pond 93, the input terminal and alkali on absorption tower 91 Liquid head tank 92 connects, and the output end on absorption tower 91 connect with neutralization pond 93, the upper end on absorption tower 91 equipped with flue gas gas outlet and The lower end of the mouth spray 94 being connected to lye head tank 92, absorption tower 91 is equipped with smoke air inlet and lye export 97, absorption tower It is equipped with the effluent column 95 being connected to lye head tank 92 in 91, rotation fan 96 is also distributed on the horizontal cross-section on absorption tower 91;
First deduster 5 is made of fume treatment room and storage ash bucket 51, and storage ash bucket 51 is set to the lower end of fume treatment room, The bottom for storing up ash bucket 51 is equipped with ash-valve, and fume treatment room is from top to bottom divided into the first process chamber 52, second processing room 53 and the Three process chambers 54, in which:
The upper end of first process chamber 52 is equipped with exhaust outlet 521, and the side of the first process chamber 52 is equipped with discharge outlet 522, draining Mouth 522 is equipped with drain valve, and the top level in the first process chamber 52 is equipped with sparge pipe 523, and sparge pipe 523 is connect with water pump, Sparge pipe 523 is equipped with several through-holes 525, and 523 parallel beneath of sparge pipe is equipped with filter screen 524, also sets in the first process chamber 52 There is baffle plate 526, it is long that the length for the baffle plate that is staggered between adjacent baffle 526 or so is greater than deduster section half Degree, guarantees that final water can be discharged by following baffle plate through discharge outlet along each baffle plate, will not damage other devices, at first Lower end in reason room 52, which is closed on the baffle plate 526 of second processing room 53, is provided with baffle 527, and baffle 527 and baffle plate 526 hang down Straight setting, one end that the baffle plate 526 equipped with baffle 527 is located on deduster inner wall is connected to discharge outlet 522;
53 side of second processing room is equipped with air inlet 531, by inclined-plane point between the first process chamber 52 and second processing room 53 Every forming, formed between second processing room 53 and third process chamber 54 by a plane separation, in second processing room 53 along inclined-plane by The small several cyclone separators 55 of setting are arrived greatly, and cyclone separator upper end is connected to inclined-plane, and the bottom end of cyclone separator 55 both passes through Plane extends to third process chamber 54.
In the present embodiment, cyclone separator 55 includes outer sleeve, inner sleeve and Whirlwind cyclone, and inner sleeve is inserted into outer sleeve It is interior and between inner sleeve and outer sleeve be equipped with Whirlwind cyclone.
First deduster is specific in use, flue gas enters in second processing room from air inlet, in the effect of guide vane Lower high speed rotation is in third process chamber into the outer sleeve of cyclone separator, and the little particle coke powder dirt in gas is in outer sleeve It is separated with gas, concentrates and enters eventually into downwards in storage ash bucket, store up and be equipped with upper and lower level-sensing device in ash bucket, when little particle coke powder is to upper In limited time, format ash-valve opens ash discharge, and when little particle coke powder arrives lower limit, ash-valve closing prevents negative pressure from entering deduster intracavitary, It is pooled to the first process chamber upwards by inner sleeve through second processing room and third process chamber purified gas, and by exhaust outlet Discharge, second processing room is inlet plenum, and third process chamber is dust, gas separation chamber, and dusty gas is in second processing room Enter in third process chamber under the action of guide vane and separated, such mode can reduce ash-laden gas and bring rushing for deduster It hits.
In the present embodiment, gravitation blower is additionally provided between the first deduster 5 and denitrification apparatus 2;Also connect on denitrification apparatus 2 It is connected to ozone generator;The axis of rotation fan 96 is connected with waterproof variable-frequency motor, and waterproof variable-frequency motor in motor shaft by fixing In tower body;Several heat exchanger tubes are equipped in First Heat Exchanger 6, the second heat exchanger 8, heat exchanger tube is light pipe, finned tube or screwed pipe; Second deduster 7 is bag filter.
When it is implemented, flue gas passes through the pre- dedusting of the first deduster by boiler export, then pass through denitrification apparatus denitration, it is smelly Oxygen Generator assists denitration, the flue gas after denitration is sent into air preheater, it is cooling that the flue gas after preheating carries out First Heat Exchanger Cooling, drops to that acid dew point is gold-plated, and the sulfuric acid vapor condensation in pre- hot fume is become acid mist, condenses on grey particle, reduces cigarette The specific resistance of flying dust in gas, then through the second deduster dedusting, then it is further decreased to through the second heat exchanger the temperature of desulfurization, into Desulfurizer desulfurization, the flue gas after desulfurization absorb sour gas by lye absorption plant, are then discharged into chimney again.
Denitrification apparatus, the desulfurizer used in this implementation is all made of usual means in the prior art.
Embodiment 2
The present embodiment provides the special-purpose coat of device in embodiment 1, the coating coating includes following according to the mass fraction Component:
Modifying epoxy resin by organosilicon: 15 parts, polyether sulphone ketone modified resin: 10 parts, black silicon carbide: 5 parts, levelling agent: 1 Part, filler: 1 part, plasticizer: 5 parts, thixotropic agent: 2 parts, blanc fixe: 5 parts, pigment: 1 part, dispersing agent: 3 parts, curing agent: 10 parts, compound rare-earth: 0.01 part;
Modifying epoxy resin by organosilicon includes following component by mass percentage: deionized water: 13%, tin dilaurate two Butyl tin: 10%, methyltriethoxysilane: 10%, surplus is epoxy resin, and the sum of the above components are 100%;
Plasticizer is dioctyl phthalate;Pigment is titanium dioxide;Dispersing agent is sodium tripolyphosphate;Curing agent is to change The polyamide-based curing agent of property;Thixotropic agent is organo montmorillonite and fumed silica;Filler is glass flake, talcum powder and two The mixture of molybdenum sulfide, wherein glass flake: talcum powder: molybdenum disulfide=3:1:2, glass flake is by 80 mesh glass flakes and 40 Mesh glass flake is in 80 mesh glass flakes: the mixing of 40 mesh glass flakes=2:1 ratio;Compound rare-earth includes by weight percentage Following component: Y:23%, Sc:16%, Gd:11%, Sm:15%, Pr:9%, surplus La, the sum of the above components are 100%.
The construction technology of above-mentioned special-purpose coat specifically:
(1) it pre-processes: the surface for needing spray-on coating device being purged with giant, remove thorn bits, the weldering on surface Slag, splash, surface and oil contaminant, oxide skin, iron rust and other sundries are purged processing;
When being purged should from top to bottom, corner angle, dead angle and except clean place can with scraper, sand paper benefit remove, Finally also want the drying on holding meanss surface;
(2) sandblasting: using efficient sandblasting machine equipment, makes the gas from air compressor machine by pressure vessel and oil water separator The compressed air for becoming dried and clean drives sand grains high speed to beat and carries out sandblasting in apparatus surface by sand-blasting machine, what sandblasting used Sand grains is shot, and the angle of partial size 0.5mm, injection direction and body structure surface normal are 10 °;
(3) ultrasonic cleaning is put into matching purge liquid (existing cleaning in supersonic wave cleaning machine to the device after blasting treatment Liquid) it is cleaned, then time 10min is dried;
(4) by physical gaseous phase deposition coating method to needing the cutting part of coating to carry out coating, coating temperature control exists 150℃;
(5) aluminium-plated: it is aluminium-plated in apparatus surface progress, apparatus surface is implemented with high-voltage arc flush coater aluminium-plated, it is desirable that spray Painting is evenly distributed, and vertical direction at least sprays twice, controls aluminized coating with a thickness of 30 μm;
(6) sealing paint coating: after the completion of aluminium-plated program, Seal treatment is once done with neutral paint application;
(7) spray gun spraying above-mentioned apparatus special-purpose coat the formation of coating: is used outside to the aluminized coating for having done Seal treatment;
(8) rotating forward 20min is carried out to coating position using pull-type polishing machine for inactivating, inverts 20min.
Embodiment 3
The present embodiment provides the special-purpose coat of device in embodiment 1, the coating coating includes following according to the mass fraction Component:
Modifying epoxy resin by organosilicon: 20 parts, polyether sulphone ketone modified resin: 12 parts, black silicon carbide: 7 parts, levelling agent: 2 Part, filler: 3 parts, plasticizer: 5-7 parts, thixotropic agent: 4 parts, blanc fixe: 7 parts, pigment: 3 parts, dispersing agent: 5 parts, solidification Agent: 13 parts, compound rare-earth: 0.03 part;
Modifying epoxy resin by organosilicon includes following component by mass percentage: deionized water: 18%, tin dilaurate two Butyl tin: 13%, methyltriethoxysilane: 14%, surplus is epoxy resin, and the sum of the above components are 100%;
Plasticizer is tricresyl phosphate;Pigment is iron oxide red;Dispersing agent is sodium tetrapolyphosphate;Curing agent is to be modified Polyamide-based curing agent;Thixotropic agent is organo montmorillonite and fumed silica;Filler is glass flake, talcum powder and two sulphur Change the mixture of molybdenum, wherein glass flake: talcum powder: molybdenum disulfide=3:1:2, glass flake is by 80 mesh glass flakes and 40 mesh Glass flake is in 80 mesh glass flakes: the mixing of 40 mesh glass flakes=2:1 ratio;Compound rare-earth include by weight percentage with Lower ingredient: Y:25%, Sc:18%, Gd:13%, Sm:18%, Pr:11%, surplus La, the sum of the above components are 100%.
The construction technology of above-mentioned special-purpose coat specifically:
(1) it pre-processes: the surface for needing spray-on coating device being purged with giant, remove thorn bits, the weldering on surface Slag, splash, surface and oil contaminant, oxide skin, iron rust and other sundries are purged processing;
When being purged should from top to bottom, corner angle, dead angle and except clean place can with scraper, sand paper benefit remove, Finally also want the drying on holding meanss surface;
(2) sandblasting: using efficient sandblasting machine equipment, makes the gas from air compressor machine by pressure vessel and oil water separator The compressed air for becoming dried and clean drives sand grains high speed to beat and carries out sandblasting in apparatus surface by sand-blasting machine, what sandblasting used Sand grains is shot, and the angle of partial size 1.5mm, injection direction and body structure surface normal are 30 °;
(3) ultrasonic cleaning is put into matching purge liquid (existing cleaning in supersonic wave cleaning machine to the device after blasting treatment Liquid) it is cleaned, then time 13min is dried;
(4) by physical gaseous phase deposition coating method to needing the cutting part of coating to carry out coating, coating temperature control exists 200℃;
(5) aluminium-plated: it is aluminium-plated in apparatus surface progress, apparatus surface is implemented with high-voltage arc flush coater aluminium-plated, it is desirable that spray Painting is evenly distributed, and vertical direction at least sprays twice, controls aluminized coating with a thickness of 38 μm;
(6) sealing paint coating: after the completion of aluminium-plated program, Seal treatment is once done with neutral paint application;
(7) spray gun spraying above-mentioned apparatus special-purpose coat the formation of coating: is used outside to the aluminized coating for having done Seal treatment;
(8) rotating forward 25min is carried out to coating position using pull-type polishing machine for inactivating, inverts 25min.
Embodiment 4
The present embodiment provides the special-purpose coat of device in embodiment 1, the coating coating includes following according to the mass fraction Component:
Modifying epoxy resin by organosilicon: 18 parts, polyether sulphone ketone modified resin: 11 parts, black silicon carbide: 6 parts, levelling agent: 1 Part, filler: 2 parts, plasticizer: 6 parts, thixotropic agent: 3 parts, blanc fixe: 6 parts, pigment: 2 parts, dispersing agent: 4 parts, curing agent: 12 parts, compound rare-earth: 0.02 part;
Modifying epoxy resin by organosilicon includes following component by mass percentage: deionized water: 15%, tin dilaurate two Butyl tin: 12%, methyltriethoxysilane: 12%, surplus is epoxy resin, and the sum of the above components are 100%;
Plasticizer is dibutyl phthalate;Pigment is carbon black;Dispersing agent is calgon;Curing agent is to be modified Polyamide-based curing agent;Thixotropic agent is organo montmorillonite and fumed silica;Filler is glass flake, talcum powder and two sulphur Change the mixture of molybdenum, wherein glass flake: talcum powder: molybdenum disulfide=3:1:2, glass flake is by 80 mesh glass flakes and 40 mesh Glass flake is in 80 mesh glass flakes: the mixing of 40 mesh glass flakes=2:1 ratio;Compound rare-earth include by weight percentage with Lower ingredient: Y:24%, Sc:17%, Gd:12%, Sm:16%, Pr:10%, surplus La, the sum of the above components are 100%.
The construction technology of above-mentioned special-purpose coat specifically:
(1) it pre-processes: the surface for needing spray-on coating device being purged with giant, remove thorn bits, the weldering on surface Slag, splash, surface and oil contaminant, oxide skin, iron rust and other sundries are purged processing;
When being purged should from top to bottom, corner angle, dead angle and except clean place can with scraper, sand paper benefit remove, Finally also want the drying on holding meanss surface;
(2) sandblasting: using efficient sandblasting machine equipment, makes the gas from air compressor machine by pressure vessel and oil water separator The compressed air for becoming dried and clean drives sand grains high speed to beat and carries out sandblasting in apparatus surface by sand-blasting machine, what sandblasting used Sand grains is shot, and the angle of partial size 0.9mm, injection direction and body structure surface normal are 20 °;
(3) ultrasonic cleaning is put into matching purge liquid (existing cleaning in supersonic wave cleaning machine to the device after blasting treatment Liquid) it is cleaned, then time 12min is dried;
(4) by physical gaseous phase deposition coating method to needing the cutting part of coating to carry out coating, coating temperature control exists 150-200℃;
(5) aluminium-plated: it is aluminium-plated in apparatus surface progress, apparatus surface is implemented with high-voltage arc flush coater aluminium-plated, it is desirable that spray Painting is evenly distributed, and vertical direction at least sprays twice, controls aluminized coating with a thickness of 35 μm;
(6) sealing paint coating: after the completion of aluminium-plated program, Seal treatment is once done with neutral paint application;
(7) spray gun spraying above-mentioned apparatus special-purpose coat the formation of coating: is used outside to the aluminized coating for having done Seal treatment;
(8) rotating forward 23min is carried out to coating position using pull-type polishing machine for inactivating, inverts 22min.
In addition to the implementation, the present invention can also have other embodiments.It is all to use equivalent substitution or equivalent transformation shape At technical solution, fall within the scope of protection required by the present invention.

Claims (10)

1. a kind of energy-saving and emission-reduction flue gas and desulfurizing and denitrifying device, including boiler (1), denitrification apparatus (2), desulfurizer (3) and Chimney (4), it is characterised in that: the output end of the boiler (1) passes through the input terminal of the first deduster (5) and denitrification apparatus (2) Connection, the output end of the denitrification apparatus (2) are connected with air preheater (10), and the output end of the air preheater (10) connects It being connected to First Heat Exchanger (6), the output end of the First Heat Exchanger (6) is connect with the input terminal of the second deduster (7), and described The output end of two dedusters (7) is connected with the second heat exchanger (8) by blower, the output end connection of second heat exchanger (8) Have desulfurizer (3), the output end of the desulfurizer (3) is connected with lye absorption plant (9), the lye absorption plant (9) output end is connect with the chimney (4), in which:
The lye absorption plant (9) includes absorption tower (91), lye head tank (92) and neutralization pond (93), the absorption tower (91) input terminal is connect with the lye head tank (92), and the output end of absorption tower (91) is connect with the neutralization pond (93), The mouth spray (94) that the upper end of the absorption tower (91) is equipped with flue gas gas outlet and is connected to lye head tank (92), the absorption The lower end of tower (91) is equipped with smoke air inlet and lye export (97), is equipped with and lye head tank (92) in the absorption tower (91) Rotation fan (96) is also distributed on the horizontal cross-section of the absorption tower (91) for the effluent column (95) of connection.
2. energy-saving and emission-reduction flue gas and desulfurizing and denitrifying device according to claim 1, it is characterised in that: first dedusting Device (5) is made of fume treatment room and storage ash bucket (51), and storage ash bucket (51) is set to the lower end of the fume treatment room, institute The bottom for stating storage ash bucket (51) is equipped with ash-valve, and the fume treatment room is from top to bottom divided into the first process chamber (52), at second Manage room (53) and third process chamber (54), in which:
The upper end of first process chamber (52) is equipped with exhaust outlet (521), and the side of the first process chamber (52) is equipped with discharge outlet (522), the discharge outlet (522) is equipped with drain valve, and the top level in first process chamber (52) is equipped with sparge pipe (523), the sparge pipe (523) connect with water pump, and the sparge pipe (523) is equipped with several through-holes (525), the sparge pipe (523) parallel beneath is equipped with filter screen (524), is additionally provided with baffle plate (526) in first process chamber (52), the adjacent folding Left and right is staggered between flowing plate (526), and the baffling of the second processing room (53) is closed in the lower end in the first process chamber (52) It is provided on plate (526) baffle (527), the baffle (527) is vertically arranged with the baffle plate (526), is equipped with baffle (527) Baffle plate (526) be located at one end on deduster inner wall and be connected to discharge outlet (522);
Second processing room (53) side is equipped with air inlet (531), first process chamber (52) and second processing room (53) Between be separated by inclined-plane, formed between the second processing room (53) and third process chamber (54) by a plane separation, institute Along the descending several cyclone separators (55) of setting in inclined-plane in the second processing room (53) stated, and the cyclone separator (55) bottom end both passes through plane and extends to third process chamber (54).
3. energy-saving and emission-reduction flue gas and desulfurizing and denitrifying device according to claim 2, it is characterised in that: the whirlwind point It include outer sleeve, inner sleeve and Whirlwind cyclone from device (55), the inner sleeve is inserted into outer sleeve and inner sleeve and outer sleeve Between be equipped with Whirlwind cyclone.
4. energy-saving and emission-reduction flue gas and desulfurizing and denitrifying device according to claim 1, it is characterised in that: first dedusting Gravitation blower is additionally provided between device (5) and denitrification apparatus (2).
5. energy-saving and emission-reduction flue gas and desulfurizing and denitrifying device according to claim 1, it is characterised in that: the denitrification apparatus (2) ozone generator is also connected on.
6. energy-saving and emission-reduction flue gas and desulfurizing and denitrifying device according to claim 1, it is characterised in that: the rotation fan (96) axis is connected with waterproof variable-frequency motor, and the waterproof variable-frequency motor in motor shaft by being fixed in tower body.
7. energy-saving and emission-reduction flue gas and desulfurizing and denitrifying device according to claim 1, it is characterised in that: first heat exchange Several heat exchanger tubes are equipped in device (6), the second heat exchanger (8), the heat exchanger tube is light pipe, finned tube or screwed pipe.
8. energy-saving and emission-reduction flue gas and desulfurizing and denitrifying device according to claim 1, it is characterised in that: second dedusting Device (7) is bag filter.
9. the special-purpose coat of energy-saving and emission-reduction flue gas and desulfurizing and denitrifying device according to claim 1, which is characterized in that should Coating includes following components according to the mass fraction:
Modifying epoxy resin by organosilicon: 15-20 parts, polyether sulphone ketone modified resin: 10-12 parts, black silicon carbide: 5-7 parts, levelling Agent: 1-2 parts, filler: 1-3 parts, plasticizer: 5-7 parts, thixotropic agent: 2-4 parts, blanc fixe: 5-7 parts, pigment: 1-3 parts, point Powder: 3-5 parts, curing agent: 10-13 parts, compound rare-earth: 0.01-0.03 parts;
The modifying epoxy resin by organosilicon includes following component by mass percentage: deionized water: 13-18%, two laurels Sour dibutyl tin: 10-13%, methyltriethoxysilane: 10-14%, surplus are epoxy resin, and the sum of the above components are 100%;
The plasticizer is one of dioctyl phthalate, tricresyl phosphate or dibutyl phthalate;Institute The pigment stated is one of titanium dioxide, iron oxide red, carbon black, barium sulfate or chrome oxide green;The dispersing agent is trimerization phosphorus One of sour sodium, sodium tetrapolyphosphate or calgon;The curing agent is modified polyamide class curing agent;The touching Become agent as organo montmorillonite and fumed silica;The filler is the mixture of glass flake, talcum powder and molybdenum disulfide, Wherein glass flake: talcum powder: molybdenum disulfide=3:1:2, the glass flake is by 80 mesh glass flakes and 40 mesh glass flakes In 80 mesh glass flakes: the mixing of 40 mesh glass flakes=2:1 ratio;The compound rare-earth includes following by weight percentage Ingredient: Y:23-25%, Sc:16-18%, Gd:11-13%, Sm:15-18%, Pr:9-11%, surplus La, the sum of the above components It is 100%.
10. the special-purpose coat of energy-saving and emission-reduction flue gas and desulfurizing and denitrifying device according to claim 9, which is characterized in that The construction technology of special-purpose coat specifically:
(1) pre-process: the surface for needing spray-on coating device being purged with giant, remove the thorn bits on surface, welding slag, Splash, surface and oil contaminant, oxide skin, iron rust and other sundries are purged processing;
It should from top to bottom, at corner angle, dead angle and not except clean place can be removed with scraper, sand paper benefit, finally when being purged Also want the drying on holding meanss surface;
(2) sandblasting: using efficient sandblasting machine equipment, becomes the gas from air compressor machine by pressure vessel and oil water separator The compressed air of dried and clean drives sand grains high speed to beat and carries out sandblasting, the sand grains that sandblasting uses in apparatus surface by sand-blasting machine It is shot, the angle of partial size 0.5-1.5mm, injection direction and body structure surface normal are 10 ° -30 °;
(3) ultrasonic cleaning is put into matching purge liquid in supersonic wave cleaning machine to the device after blasting treatment and cleans, the time For 10-13min, then dry;
(4) by physical gaseous phase deposition coating method to needing the cutting part of coating to carry out coating, coating temperature is controlled in 150- 200℃;
(5) aluminium-plated: it is aluminium-plated in apparatus surface progress, apparatus surface is implemented with high-voltage arc flush coater aluminium-plated, it is desirable that spraying point Cloth is uniform, and vertical direction at least sprays twice, controls aluminized coating with a thickness of 30-38 μm;
(6) sealing paint coating: after the completion of aluminium-plated program, Seal treatment is once done with neutral paint application;
(7) spray gun spraying above-mentioned apparatus special-purpose coat the formation of coating: is used outside to the aluminized coating for having done Seal treatment;
(8) rotating forward 20-25min is carried out to coating position using pull-type polishing machine for inactivating, inverts 20-25min.
CN201811431943.4A 2018-11-27 2018-11-27 A kind of energy-saving and emission-reduction flue gas and desulfurizing and denitrifying device and device special-purpose coat Pending CN109364668A (en)

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Publication number Priority date Publication date Assignee Title
CN110624380A (en) * 2019-09-30 2019-12-31 南通天祺环保科技发展有限公司 Synergistic desulfurization and denitrification agent and preparation and application thereof

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