CN1093555C - Binder for ceramics and stone and its preparation method - Google Patents
Binder for ceramics and stone and its preparation method Download PDFInfo
- Publication number
- CN1093555C CN1093555C CN 97108235 CN97108235A CN1093555C CN 1093555 C CN1093555 C CN 1093555C CN 97108235 CN97108235 CN 97108235 CN 97108235 A CN97108235 A CN 97108235A CN 1093555 C CN1093555 C CN 1093555C
- Authority
- CN
- China
- Prior art keywords
- ceramics
- cement
- sepiolite
- formaldehyde
- urea
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000919 ceramic Substances 0.000 title claims abstract description 15
- 239000004575 stone Substances 0.000 title claims abstract description 15
- 238000002360 preparation method Methods 0.000 title claims description 14
- 239000011230 binding agent Substances 0.000 title claims description 9
- 239000000463 material Substances 0.000 claims abstract description 38
- 239000004568 cement Substances 0.000 claims abstract description 14
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 13
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 13
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000006004 Quartz sand Substances 0.000 claims abstract description 12
- 239000004113 Sepiolite Substances 0.000 claims abstract description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 12
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000004202 carbamide Substances 0.000 claims abstract description 12
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims abstract description 12
- 235000019353 potassium silicate Nutrition 0.000 claims abstract description 12
- 229910052624 sepiolite Inorganic materials 0.000 claims abstract description 12
- 235000019355 sepiolite Nutrition 0.000 claims abstract description 12
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 12
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims abstract description 10
- 239000000920 calcium hydroxide Substances 0.000 claims abstract description 10
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims abstract description 10
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims abstract description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 27
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 22
- 239000000843 powder Substances 0.000 claims description 14
- 238000004513 sizing Methods 0.000 claims description 14
- 238000003756 stirring Methods 0.000 claims description 7
- 239000000693 micelle Substances 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 238000001556 precipitation Methods 0.000 claims description 3
- 238000013019 agitation Methods 0.000 claims description 2
- 238000010792 warming Methods 0.000 claims description 2
- 239000000853 adhesive Substances 0.000 abstract description 4
- 239000002253 acid Substances 0.000 abstract description 3
- 238000010276 construction Methods 0.000 abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 3
- 238000003912 environmental pollution Methods 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- 235000011116 calcium hydroxide Nutrition 0.000 abstract 1
- 235000013877 carbamide Nutrition 0.000 abstract 1
- 239000011083 cement mortar Substances 0.000 abstract 1
- 230000007547 defect Effects 0.000 abstract 1
- 238000005516 engineering process Methods 0.000 abstract 1
- 239000002574 poison Substances 0.000 abstract 1
- 231100000614 poison Toxicity 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 description 5
- 238000005034 decoration Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- -1 grouan Substances 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention relates to an adhesive agent for ceramics and stones, which overcomes the existing defect that ceramics and stones are bonded by cement mortar, which is not tight. The adhesive agent is composed of polyvinyl alcohol, acrylic acid, formaldehyde, iron trichloride, urea, water glass, sepiolite, calcium hydroxide, quartz sand and cement. The adhesive agent has the advantages of strong adherence force, good water resistance, acid and alkali resistance, weatherproof performance, simple fabrication technology, no environmental pollution, non-inflammable product, no poison, low cost, easy storage and transportation, convenient construction and use, labor saving and material saving, and is suitable for the bonding of decorative surfaces of the ceramics and the stones.
Description
The present invention relates to tackiness agent of a kind of pottery and stone materials building and ornament materials and preparation method thereof.
At present, along with the progress of society, people are more and more higher to the decoration requirement of buildings, and the ceramic facing of various lithotomes and various making finenesses emerges in an endless stream.Stone material that people use always such as marble, grouan, ceramic facing such as ceramic tile, ornamental brick, mosaic or the like, and the binding of pasting these decorative fabrics mainly is to adopt sand-cement slurry, this is a kind of more traditional method, not only the total cost cost is higher for it, and break away from serious, it is very inconvenient to construct, and particularly the stickup to top board is very difficult, time-consuming especially.
The object of the present invention is to provide that a kind of construction is simple and convenient, cost is low, adherence force is strong, binder for ceramics and stone that water-fast, acid and alkali-resistance and weather change and preparation method thereof.
The present invention finishes with following mode: binder for ceramics and stone is made up of sizing material A and powder material B, wherein:
Sizing material A is by polyvinyl alcohol, and vinylformic acid, formaldehyde, iron trichloride, urea, hydrochloric acid, water glass are formed, and the weight percent of component thing is:
Polyvinyl alcohol 50-60, vinylformic acid 0.5-1, formaldehyde 20-30, iron trichloride 0.05-0.1, urea 5-10, hydrochloric acid 5-8, water glass 1-2;
Powder material B is a sepiolite, calcium hydroxide, and quartz sand, cement is formed, and the weight percent of component thing is: sepiolite 20-30, calcium hydroxide 10-15, quartz sand 20-30, cement 25-40.
The weight percent of the component thing of sizing material A is: polyvinyl alcohol 60, vinylformic acid 0.5, formaldehyde 25, iron trichloride 0.05, urea 7, hydrochloric acid 6, water glass 1.45;
The weight percent of the component thing of powder material B is: sepiolite 28, hydrochlorinate calcium 10, quartz sand 30, cement 32.
Preparation sizing material A adds polyvinyl alcohol 50-60 to be warming up to dissolving more than 92 ℃ in the entry by weight percentage, after treating to dissolve fully, under agitation evenly add vinylformic acid 0.5-1, being cooled to 80 ℃-85 ℃ adding hydrochloric acid 5-8 reacted 5-20 minute, adding formaldehyde 20-30 and iron trichloride 0.05-0.1 then reacts when white micelle precipitation occurring, be cooled to 40 ℃-70 ℃ immediately, add simultaneously after urea 5-10 is cooled to room temperature, strengthen stirring velocity, make micelle be dissolved into sol solution again, add water glass 1-2, stir;
The preparation powder material B is by weight percentage sepiolite 20-30 and quartz sand 20-30 to be pulverized, and with calcium hydroxide 10-15, cement 25-40 mixes and sieves;
Use dissolves 2 parts of powder material B by 1 part of sizing material A.
Binder for ceramics and stone of the present invention and preparation method thereof, it is simple to have manufacturing process, and non-exhaust emission can not cause environmental pollution.This adhesive product do not fire, nontoxic, with low cost, be easy to store and transportation, it is easy to use construct, labor and material saving is than the 10%-30% that can reduce cost with sand-cement slurry stickup decoration plane material.This tackiness agent just curing speed is fast, and adherence force is strong, and the performance that has good water-fast, acid and alkali-resistance and weather to change is applicable to the stickup of ceramic stone class building and ornament materials.
Embodiment one: preparation sizing material A takes by weighing the each component thing at first by weight percentage: polyvinyl alcohol 60, vinylformic acid 0.5, formaldehyde 25, iron trichloride 0.05, urea 7, hydrochloric acid 6, water glass 1.45, then, polyvinyl alcohol is dissolved in more than 92 ℃ in the hot water, the weight of water is 6-7 times of polyvinyl alcohol weight, stir and add vinylformic acid down, be cooled to 80 ℃-85 ℃, added hydrochloric acid reaction 5-20 minute, add formaldehyde and iron trichloride 0.05 then and react when white micelle precipitation occurring, be cooled to 40 ℃-70 ℃ immediately, add urea simultaneously, after reducing to room temperature, strengthen stirring velocity, make micelle be dissolved into sol solution again, add water glass 1.45, stir, i.e. cost tackiness agent sizing material A.Sizing material A stores for future use with the polyvinyl chloride plastic charging basket.
The preparation powder material B is at first by weight percentage for taking by weighing the each component thing: sepiolite 28, calcium hydroxide 10, quartz sand 30, cement 32.Then sepiolite and quartz sand are pulverized, with calcium hydroxide, cement, mixing sieves is cost binding agent powder material.Woven bag with the plastic lining bag film is packed, and puts dry place and stores for future use.
Construction using method: can paste by weight with two parts of powder material B two groups of mixing of A and B being stirred into starchiness with a sizing material A.During stickup, the starchy glue of above-mentioned furnishing being spread upon the bottom surface of pottery that need to paste or stone decoration material or smear on the wall finishing material directly will be bonding immediately and be fixed on the body of wall by being pressed on the body of wall, can not fall down.The mixed tackiness agent of A, B must use in 4 hours, influenced quality in order to avoid solidify.
Embodiment two: the preparation method is identical with embodiment one, and it adopts following component thing content: the content of each component thing is by weight percentage:
Sizing material A: polyvinyl alcohol 55, vinylformic acid 1, formaldehyde 28, iron trichloride 0.05, urea 7.95, hydrochloric acid 7, water glass 1.
Powder material B: sepiolite 25, hydrochlorinate calcium 12, quartz sand 28,, cement 35.
Using method with the tackiness agent of above-mentioned component thing content preparation is identical with embodiment one.
Claims (3)
1. a binder for ceramics and stone is characterized in that being made up of sizing material A and powder material B, wherein:
Sizing material A is made up of polyvinyl alcohol, vinylformic acid, formaldehyde, iron trichloride, urea, hydrochloric acid, water glass, and the weight percent of component thing is:
Polyvinyl alcohol 50-60, vinylformic acid 0.5-1, formaldehyde 20-30, iron trichloride 0.05-0.1, urea 5-10, hydrochloric acid 5-8, water glass 1-2;
Powder material B is by sepiolite, calcium hydroxide, and quartz sand, cement is formed, and the weight percent of component thing is: sepiolite 20-30, calcium hydroxide 10-15, quartz sand 20-30, cement 25-40.
2. according to the described binder for ceramics and stone of claim 1, it is characterized in that the weight percent of the component thing of sizing material A is: polyvinyl alcohol 60, vinylformic acid 0.5, formaldehyde 25, iron trichloride 0.05, urea 7, hydrochloric acid 6, water glass 1.45;
The weight percent of the component thing of powder material B is: sepiolite 28, calcium hydroxide 10, quartz sand 30, cement 32.
3. the preparation method of a binder for ceramics and stone is characterized in that finishing by following step:
Preparation sizing material A adds polyvinyl alcohol 50-60 to be warming up to dissolving more than 92 ℃ in the entry by weight percentage, after treating to dissolve fully, under agitation evenly add vinylformic acid 0.5-1, be cooled to 80 ℃-85 ℃ and add hydrochloric acid 5-8 reaction 5-20 minute, add formaldehyde 20-30 and iron trichloride 0.05-0.1 reaction then when white micelle precipitation occurring, be cooled to 40 ℃-70 ℃ immediately, add urea 5-10 simultaneously, after reducing to room temperature, strengthen stirring velocity, make micelle be dissolved into sol solution again, add water glass 1-2, stir;
The preparation powder material B is by weight percentage sepiolite 20-30 and quartz sand 20-30 to be pulverized, and mixes and sieves with calcium hydroxide 10-15, cement 25-40;
Use dissolves 2 parts of powder material B by 1 part of sizing material A.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 97108235 CN1093555C (en) | 1997-09-16 | 1997-09-16 | Binder for ceramics and stone and its preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 97108235 CN1093555C (en) | 1997-09-16 | 1997-09-16 | Binder for ceramics and stone and its preparation method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1211603A CN1211603A (en) | 1999-03-24 |
| CN1093555C true CN1093555C (en) | 2002-10-30 |
Family
ID=5170250
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 97108235 Expired - Fee Related CN1093555C (en) | 1997-09-16 | 1997-09-16 | Binder for ceramics and stone and its preparation method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1093555C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100445497C (en) * | 2002-12-27 | 2008-12-24 | 克里斯廷·E·沃尔纳 | Cementitious veneer and laminate material |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1329469C (en) * | 2005-08-04 | 2007-08-01 | 上海应用技术学院 | Modified urea formaldehyde binding agent and its preparation method |
| CN101280164B (en) * | 2008-03-12 | 2011-03-30 | 东莞市申隆装饰材料有限公司 | Environment-friendly glue for post-impregnated finish foil |
| CN101724364B (en) * | 2009-10-16 | 2012-01-11 | 青阳县双龙涂料有限责任公司 | Glue powder or solid glue |
| CN103374314B (en) * | 2012-04-11 | 2015-06-10 | 佛山市三水森诺建材有限公司 | Dispensing adhesive agent for connection of mosaics and production process |
| CN107418452A (en) * | 2017-09-15 | 2017-12-01 | 镇江市龙门石刻艺术工程有限公司 | A kind of curtain wall adhesive |
-
1997
- 1997-09-16 CN CN 97108235 patent/CN1093555C/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100445497C (en) * | 2002-12-27 | 2008-12-24 | 克里斯廷·E·沃尔纳 | Cementitious veneer and laminate material |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1211603A (en) | 1999-03-24 |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: XIANGTAN UNIV. Free format text: FORMER OWNER: DENG JIANCHENG Effective date: 20040203 |
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| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20040203 Address after: 411105 Hunan city of Xiangtan province donkey pond scientific research department of Xiangtan University Patentee after: Xiangtan University Address before: 411105 Hunan city of Xiangtan province donkey pond village 11 Beidou No. 106 Xiangtan University Patentee before: Deng Jiancheng |
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| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |