CN109355028A - A kind of ageing-resistant automobile window glass patch - Google Patents
A kind of ageing-resistant automobile window glass patch Download PDFInfo
- Publication number
- CN109355028A CN109355028A CN201811270242.7A CN201811270242A CN109355028A CN 109355028 A CN109355028 A CN 109355028A CN 201811270242 A CN201811270242 A CN 201811270242A CN 109355028 A CN109355028 A CN 109355028A
- Authority
- CN
- China
- Prior art keywords
- parts
- layer
- ageing
- nano
- window glass
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000032683 aging Effects 0.000 title claims abstract description 16
- 239000005357 flat glass Substances 0.000 title claims abstract description 16
- 239000010410 layer Substances 0.000 claims abstract description 111
- 239000011521 glass Substances 0.000 claims abstract description 19
- 239000002346 layers by function Substances 0.000 claims abstract description 15
- 238000010521 absorption reaction Methods 0.000 claims abstract description 12
- 239000002245 particle Substances 0.000 claims abstract description 11
- 239000011032 tourmaline Substances 0.000 claims abstract description 11
- 229910052613 tourmaline Inorganic materials 0.000 claims abstract description 11
- 229940070527 tourmaline Drugs 0.000 claims abstract description 11
- 239000012790 adhesive layer Substances 0.000 claims abstract description 10
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 21
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 21
- -1 Methyl Hydrogen Chemical compound 0.000 claims description 19
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 16
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 claims description 16
- 239000002086 nanomaterial Substances 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 239000005062 Polybutadiene Substances 0.000 claims description 10
- 229920002857 polybutadiene Polymers 0.000 claims description 10
- 239000005083 Zinc sulfide Substances 0.000 claims description 9
- 229920001084 poly(chloroprene) Polymers 0.000 claims description 9
- 229910052984 zinc sulfide Inorganic materials 0.000 claims description 9
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 8
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 8
- ITBNYRAZMLGAJM-UHFFFAOYSA-N CCC(C)=CC(O)(O)O Chemical group CCC(C)=CC(O)(O)O ITBNYRAZMLGAJM-UHFFFAOYSA-N 0.000 claims description 8
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 8
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 229920001577 copolymer Polymers 0.000 claims description 8
- 239000003365 glass fiber Substances 0.000 claims description 8
- 229910052739 hydrogen Inorganic materials 0.000 claims description 8
- 239000001257 hydrogen Substances 0.000 claims description 8
- 239000003112 inhibitor Substances 0.000 claims description 8
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 claims description 8
- 229920005989 resin Polymers 0.000 claims description 8
- 239000011347 resin Substances 0.000 claims description 8
- 239000012745 toughening agent Substances 0.000 claims description 8
- 239000011701 zinc Substances 0.000 claims description 8
- 229910052725 zinc Inorganic materials 0.000 claims description 8
- 239000004925 Acrylic resin Substances 0.000 claims description 7
- 229920000178 Acrylic resin Polymers 0.000 claims description 7
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 6
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 6
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical class O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 5
- 239000006229 carbon black Substances 0.000 claims description 5
- 239000012530 fluid Substances 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- 229920001296 polysiloxane Polymers 0.000 claims description 4
- 229920002545 silicone oil Polymers 0.000 claims description 4
- 235000007164 Oryza sativa Nutrition 0.000 claims description 3
- 239000003610 charcoal Substances 0.000 claims description 3
- 235000009566 rice Nutrition 0.000 claims description 3
- 150000002431 hydrogen Chemical class 0.000 claims 2
- 241000790917 Dioxys <bee> Species 0.000 claims 1
- 240000007594 Oryza sativa Species 0.000 claims 1
- 229910052720 vanadium Inorganic materials 0.000 claims 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 6
- 229910021542 Vanadium(IV) oxide Inorganic materials 0.000 description 4
- 239000011159 matrix material Substances 0.000 description 4
- GRUMUEUJTSXQOI-UHFFFAOYSA-N vanadium dioxide Chemical compound O=[V]=O GRUMUEUJTSXQOI-UHFFFAOYSA-N 0.000 description 4
- 210000003041 ligament Anatomy 0.000 description 3
- 241000209094 Oryza Species 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 238000013467 fragmentation Methods 0.000 description 1
- 238000006062 fragmentation reaction Methods 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000002352 surface water Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000013022 venting Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/29—Laminated material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen
- C08L33/16—Homopolymers or copolymers of esters containing halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3009—Sulfides
- C08K2003/3036—Sulfides of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/387—Borates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
- C09J2301/12—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
- C09J2301/122—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present only on one side of the carrier, e.g. single-sided adhesive tape
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
- C09J2301/16—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the structure of the carrier layer
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Laminated Bodies (AREA)
Abstract
The present invention is a kind of ageing-resistant automobile window glass patch, including base layer, explosion-proof layer and functional layer, the base layer, explosion-proof layer and functional layer are sequentially overlapped setting from top to bottom, and by being fixed together between three by transparent adhesive layer, the functional layer includes noise reduction layer, temperature regulation layer, Tourmaline particle glue-line, ultraviolet resistant layer and anti-fog layer, the sound absorbing layer, temperature regulation layer, Tourmaline particle glue-line, ultraviolet resistant layer passes sequentially through transparent adhesive layer with anti-fog layer from inside to outside and is fixedly connected, and the sound absorbing layer is provided with sound-absorption hole, the temperature regulation layer is equipped with bloop, and the sound-absorption hole and bloop are connected；The configuration of the present invention is simple has good resistance to ag(e)ing, effectively improves the heat-insulated and uvioresistant effect of vehicle glass, so as to improve the environment in automobile, improve comfort level and safety by bus.
Description
Technical field
The present invention relates to motor vehicle interior, specifically a kind of ageing-resistant automobile window glass patch.
Background technique
It is more crucial in the effect of automobile decoration Material Field, adhering film to glass, when vehicle window posts glass film, not only may be used
It is fuzzy caused by preventing vehicle window from being scratched by foreign object, can more prevent the direct fragmentation of glass when automobile is by external force collision and to
People's bring injury, in addition, in winter, since vehicle interior temperature and the outside temperature temperature difference are larger, usually will form on vehicle window big
Fog is measured, seriously affects the judgement of driver, and existing glass patch resistance to ag(e)ing is poor, service life is short.
Summary of the invention
The technical problem to be solved by the present invention is to, the shortcomings that overcoming the prior art, provides a kind of automobile window glass patch,
With good resistance to ag(e)ing, and the heat-insulated and uvioresistant effect of vehicle glass is effectively improved, so as to improve in automobile
Environment improves comfort level and safety by bus.
The technical solution that the present invention solves the above technical problem is: a kind of ageing-resistant automobile window glass patch, including matrix
Layer, explosion-proof layer and functional layer, the base layer, explosion-proof layer and functional layer are sequentially overlapped setting from top to bottom, and pass through three
Between be fixed together by transparent adhesive layer, the functional layer include sound absorbing layer, temperature regulation layer, Tourmaline particle glue-line,
Ultraviolet resistant layer and anti-fog layer, the sound absorbing layer, temperature regulation layer, Tourmaline particle glue-line, ultraviolet resistant layer and anti-fog layer by
Interior and the sound absorbing layer is provided with sound-absorption hole to passing sequentially through transparent adhesive layer outside and be fixedly connected, in the temperature regulation layer
Equipped with bloop, and the sound-absorption hole and bloop are connected；
The base layer is mixed by component A and B component according to 3:1 in mass ratio, and wherein component A includes according to the mass fraction
Following components: perfluoroalkyl acrylate ester copolymer 60-70 points, 30-40 parts of water-based acrylic resin, silane-modified nano-zinc sulfide 15-
18 parts, 10-13 parts of Methyl Hydrogen Polysiloxane Fluid, 10-15 parts of modified glass-fiber, 20-25 parts of butadiene rubber, 20-25 parts of nano material,
3-8 parts of dibenzoyl peroxide, 10-14 parts of organobentonite, 6-8 parts of toughener, 2-3 parts of mould inhibitor, organically-modified hard charcoal
It is 13-16 parts black, 3-6 parts of silane coupling agent；
B component includes following components according to the mass fraction: 30-50 parts of polyvinyl butyral resin, trihydroxy methyl ethyl propylene
12-16 parts of base ether dicaprylate, 16-22 parts of polytetrafluoroethylene (PTFE), 15-18 parts of neoprene, 12-14 parts of nano-zinc borate, it is hollow
18-24 parts of glass microballoon, 10-15 parts of nano-aluminum hydroxide, 8-12 parts of triphenyl phosphite, cumyl peroxide alcohol 10-13
Part, 6-9 parts of curing agent.
Of the invention further limits technical solution:
Component A above-mentioned includes following components according to the mass fraction: perfluoroalkyl acrylate ester copolymer 60 divides, water-based acrylic resin 30
Part, 15 parts of silane-modified nano-zinc sulfide, 10 parts of Methyl Hydrogen Polysiloxane Fluid, 10 parts of modified glass-fiber, butadiene rubber 20 part, nanometer
20 parts of material, 3 parts of dibenzoyl peroxide, 10 parts of organobentonite, 6 parts of toughener, 2 parts of mould inhibitor, organically-modified hard charcoal
Black 13 parts, 3 parts of silane coupling agent；
B component includes following components according to the mass fraction: 30 parts of polyvinyl butyral resin, trihydroxy methyl ethyl propylene base ether
12 parts of dicaprylate, 16 parts of polytetrafluoroethylene (PTFE), 15 parts of neoprene, 12 parts of nano-zinc borate, hollow glass micropearl 18 part, nanometer
10 parts of aluminium hydroxide, 8 parts of triphenyl phosphite, 10 parts of cumyl peroxide alcohol, 6 parts of curing agent.
Component A above-mentioned includes following components according to the mass fraction: perfluoroalkyl acrylate ester copolymer 65 divides, water soluble acrylic acid tree
35 parts of rouge, 17 parts of silane-modified nano-zinc sulfide, 11 parts of Methyl Hydrogen Polysiloxane Fluid, 13 parts of modified glass-fiber, 23 parts of butadiene rubber,
22 parts of nano material, 5 parts of dibenzoyl peroxide, 12 parts of organobentonite, 7 parts of toughener, 3 parts of mould inhibitor, it is organically-modified
15 parts of white carbon black, 5 parts of silane coupling agent；
B component includes following components according to the mass fraction: 40 parts of polyvinyl butyral resin, trihydroxy methyl ethyl propylene base ether
14 parts of dicaprylate, 19 parts of polytetrafluoroethylene (PTFE), 16 parts of neoprene, 13 parts of nano-zinc borate, hollow glass micropearl 20 part, nanometer
13 portions of aluminium hydroxide, 10 parts of triphenyl phosphite, 11 parts of cumyl peroxide alcohol, 8 parts of curing agent.
Temperature regulation layer above-mentioned is vanadium dioxide film.
Anti-fog layer above-mentioned is super hydrophilic nano material film.
Matrix ligament thickness above-mentioned is 0.3-0.4mm, and explosion-proof layer is with a thickness of 0.1-0.15mm.
It is above-mentioned that PTFE film is equipped on anti-fog layer.
Above-mentioned that base layer bottom is provided with mounting layer, mounting layer is pressure-sensitive glue-line.
Beneficial effect is: the configuration of the present invention is simple, and explosion-proof layer is arranged, and reduces vehicle window and encounters large impact appearance explosion probability,
Temperature regulation layer is vanadium dioxide film, can be to the mid-infrared light selective masking in sunlight, to realize regulation room
The effect of interior temperature；By the structure of the bloop in the sound-absorption hole and temperature regulation layer on sound absorbing layer, can make an uproar to outdoor
Sound is obstructed, while bloop also has heat sinking function in temperature regulation layer；Tourmaline particle glue-line is set, can be realized anti-
The function of dazzle, at the same can also releasing negative oxygen ion, play the role of purify in-vehicle air, anti-fog layer be super hydrophilic nano material
Film, make on glass adsorb water occur dissociation form tiny droplet, when water contact film surface will complete wetting sprawl, make the table of film
The surface tension of face tension and water is completely close, and water can not just adhere on the surface of film, to achieve the purpose that antifog, guarantee vapour
The clear visual field of vehicle glass improves the safety driven, while also having the effect of Heat insulation UV-resistant line, is arranged in base layer pressure-sensitive
Property glue-line, with good Electrostatic Absorption performance and venting quality, with glass surface have it is excellent be bonded effect, install and use
It is simple and fast, and by repeatedly pasting and being still able to maintain good bonding patch performance after removing, PTFE is equipped on anti-fog layer
Film improves its anticorrosion ability, increases service life；Also there is good antistatic property simultaneously and absorb thermal insulation, with
And surface water repellency and soil resistance；
Butadiene rubber is added in the present invention, has that elasticity is high, wearability is good, cold resistance is good, heat is low, flexible resistance and dynamic
The good advantage of performance and neoprene are used cooperatively, and by the number of both control, can overcome the defect that butadiene rubber mechanical property
Difference, anti-slippery are not good defects, while improving the heat resistance and corrosion resistance of base layer；Organobentonite, hollow glass
The heat resistance and resistance to ag(e)ing of base layer are significantly improved after the cooperation of glass microballon, nano material is added, so that each group is shaped to
The cooperation of more form compact and stable and silane-modified nano-zinc sulfide guarantees material in the film evenly dispersed, improves film
Absorb ultraviolet light and ageing-resistant ability.
Detailed description of the invention
Fig. 1 is schematic structural view of the invention.
Specific embodiment
Embodiment 1
The present embodiment provides a kind of ageing-resistant automobile window glass to paste, and structure is as shown in Figure 1, include base layer 1,2 and of explosion-proof layer
Functional layer, matrix ligament thickness 0.3mm, explosion-proof layer is with a thickness of 0.1mm, and base layer, explosion-proof layer and functional layer are from top to bottom successively
It is superposed, and by being fixed together between three by transparent adhesive layer, base layer bottom is provided with mounting layer 11,
The mounting layer is pressure-sensitive glue-line, and functional layer includes sound absorbing layer 3, temperature regulation layer 4, Tourmaline particle glue-line 5, ultraviolet resistant layer
6 and anti-fog layer 7, wherein temperature regulation layer is vanadium dioxide film, and anti-fog layer is super hydrophilic nano material film, sound absorbing layer, temperature
Degree regulating course, Tourmaline particle glue-line, ultraviolet resistant layer pass sequentially through transparent adhesive layer with anti-fog layer from inside to outside and are fixedly connected,
And sound absorbing layer is provided with sound-absorption hole 8, and temperature regulation layer is equipped with bloop 9, and the sound-absorption hole and bloop are connected,
Anti-fog layer is equipped with PTFE film 10；
Base layer is mixed by component A and B component according to 3:1 in mass ratio, and wherein component A includes following according to the mass fraction
Component: perfluoroalkyl acrylate ester copolymer 60 divides, 30 parts of water-based acrylic resin, 15 parts of silane-modified nano-zinc sulfide, methyl hydrogen
10 parts of silicone oil, 10 parts of modified glass-fiber, 20 parts of butadiene rubber, 20 parts of nano material, 3 parts of dibenzoyl peroxide, organic bentonite
Moisten native 10 parts, 6 parts of toughener, 2 parts of mould inhibitor, 13 parts of organically-modified white carbon black, 3 parts of silane coupling agent；
B component includes following components according to the mass fraction: 30 parts of polyvinyl butyral resin, trihydroxy methyl ethyl propylene base ether
12 parts of dicaprylate, 16 parts of polytetrafluoroethylene (PTFE), 15 parts of neoprene, 12 parts of nano-zinc borate, 18 parts of hollow glass micropearl receives
Rice 10 parts of aluminium hydroxide, 8 parts of triphenyl phosphite, 10 parts of cumyl peroxide alcohol, 6 parts of curing agent.
Embodiment 2
The present embodiment provides a kind of ageing-resistant automobile window glass to paste, and structure is as shown in Figure 1, include base layer 1,2 and of explosion-proof layer
Functional layer, matrix ligament thickness 0.3mm, explosion-proof layer is with a thickness of 0.1mm, and base layer, explosion-proof layer and functional layer are from top to bottom successively
It is superposed, and by being fixed together between three by transparent adhesive layer, base layer bottom is provided with mounting layer 11,
The mounting layer is pressure-sensitive glue-line, and functional layer includes sound absorbing layer 3, temperature regulation layer 4, Tourmaline particle glue-line 5, ultraviolet resistant layer
6 and anti-fog layer 7, wherein temperature regulation layer is vanadium dioxide film, and anti-fog layer is super hydrophilic nano material film, sound absorbing layer, temperature
Degree regulating course, Tourmaline particle glue-line, ultraviolet resistant layer pass sequentially through transparent adhesive layer with anti-fog layer from inside to outside and are fixedly connected,
And sound absorbing layer is provided with sound-absorption hole 8, and temperature regulation layer is equipped with bloop 9, and the sound-absorption hole and bloop are connected,
Anti-fog layer is equipped with PTFE film 10；
Base layer is mixed by component A and B component according to 3:1 in mass ratio, and wherein component A includes following according to the mass fraction
Component: perfluoroalkyl acrylate ester copolymer 65 divides, 35 parts of water-based acrylic resin, 17 parts of silane-modified nano-zinc sulfide, methyl hydrogen
11 parts of silicone oil, 13 parts of modified glass-fiber, 23 parts of butadiene rubber, 22 parts of nano material, 5 parts of dibenzoyl peroxide, organic bentonite
Moisten native 12 parts, 7 parts of toughener, 3 parts of mould inhibitor, 15 parts of organically-modified white carbon black, 5 parts of silane coupling agent；
B component includes following components according to the mass fraction: 40 parts of polyvinyl butyral resin, trihydroxy methyl ethyl propylene base ether
14 parts of dicaprylate, 19 parts of polytetrafluoroethylene (PTFE), 16 parts of neoprene, 13 parts of nano-zinc borate, 20 parts of hollow glass micropearl receives
13 portions of aluminium hydroxide of rice, 10 parts of triphenyl phosphite, 11 parts of cumyl peroxide alcohol, 8 parts of curing agent.
In addition to the implementation, the present invention can also have other embodiments.It is all to use equivalent substitution or equivalent transformation shape
At technical solution, fall within the scope of protection required by the present invention.
Claims (8)
1. a kind of ageing-resistant automobile window glass patch, including base layer, explosion-proof layer and functional layer, the base layer, explosion-proof layer and
Functional layer is sequentially overlapped setting from top to bottom, and by being fixed together between three by transparent adhesive layer, feature exists
In: the functional layer includes noise reduction layer, temperature regulation layer, Tourmaline particle glue-line, ultraviolet resistant layer and anti-fog layer, the sound-absorbing
Layer, temperature regulation layer, Tourmaline particle glue-line, ultraviolet resistant layer and anti-fog layer pass sequentially through transparent adhesive layer from inside to outside and fix
Connection, and the sound absorbing layer is provided with sound-absorption hole, and the temperature regulation layer is equipped with bloop, and the sound-absorption hole and noise reduction
Hole is connected；
The base layer is mixed by component A and B component according to 3:1 in mass ratio, and wherein component A includes according to the mass fraction
Following components: perfluoroalkyl acrylate ester copolymer 60-70 points, 30-40 parts of water-based acrylic resin, silane-modified nano-zinc sulfide 15-
18 parts, 10-13 parts of Methyl Hydrogen Polysiloxane Fluid, 10-15 parts of modified glass-fiber, 20-25 parts of butadiene rubber, 20-25 parts of nano material,
3-8 parts of dibenzoyl peroxide, 10-14 parts of organobentonite, 6-8 parts of toughener, 2-3 parts of mould inhibitor, organically-modified hard charcoal
It is 13-16 parts black, 3-6 parts of silane coupling agent；
B component includes following components according to the mass fraction: 30-50 parts of polyvinyl butyral resin, trihydroxy methyl ethyl propylene
12-16 parts of base ether dicaprylate, 16-22 parts of polytetrafluoroethylene (PTFE), 15-18 parts of neoprene, 12-14 parts of nano-zinc borate, it is hollow
18-24 parts of glass microballoon, 10-15 parts of nano-aluminum hydroxide, 8-12 parts of triphenyl phosphite, cumyl peroxide alcohol 10-13
Part, 6-9 parts of curing agent.
2. ageing-resistant automobile window glass patch according to claim 1, it is characterised in that: component A is wrapped according to the mass fraction
Include following components: perfluoroalkyl acrylate ester copolymer 60 divides, 30 parts of water-based acrylic resin, 15 parts of silane-modified nano-zinc sulfide, first
10 parts of base containing hydrogen silicone oil, 10 parts of modified glass-fiber, 20 parts of butadiene rubber, 20 parts of nano material, 3 parts of dibenzoyl peroxide,
10 parts of organobentonite, 6 parts of toughener, 2 parts of mould inhibitor, 13 parts of organically-modified white carbon black, 3 parts of silane coupling agent；
B component includes following components according to the mass fraction: 30 parts of polyvinyl butyral resin, trihydroxy methyl ethyl propylene base ether
12 parts of dicaprylate, 16 parts of polytetrafluoroethylene (PTFE), 15 parts of neoprene, 12 parts of nano-zinc borate, hollow glass micropearl 18 part, nanometer
10 parts of aluminium hydroxide, 8 parts of triphenyl phosphite, 10 parts of cumyl peroxide alcohol, 6 parts of curing agent part.
3. ageing-resistant automobile window glass patch according to claim 1, it is characterised in that: component A is wrapped according to the mass fraction
Include following components: perfluoroalkyl acrylate ester copolymer 65 divides, 35 parts of water-based acrylic resin, 17 parts of silane-modified nano-zinc sulfide, first
11 parts of base containing hydrogen silicone oil, 13 parts of modified glass-fiber, 23 parts of butadiene rubber, 22 parts of nano material, 5 parts of dibenzoyl peroxide,
12 parts of organobentonite, 7 parts of toughener, 3 parts of mould inhibitor, 15 parts of organically-modified white carbon black, 5 parts of silane coupling agent；
B component includes following components according to the mass fraction: 40 parts of polyvinyl butyral resin, trihydroxy methyl ethyl propylene base ether
14 parts of dicaprylate, 19 parts of polytetrafluoroethylene (PTFE), 16 parts of neoprene, 13 parts of nano-zinc borate, hollow glass micropearl 20 part, nanometer
13 portions of aluminium hydroxide, 10 parts of triphenyl phosphite, 11 parts of cumyl peroxide alcohol, 8 parts of curing agent.
4. ageing-resistant automobile window glass patch according to claim 1, it is characterised in that: the temperature regulation layer is dioxy
Change vanadium film.
5. ageing-resistant automobile window glass patch according to claim 1, it is characterised in that: the anti-fog layer is super hydrophilic receives
Rice material film.
6. ageing-resistant automobile window glass patch according to claim 1, it is characterised in that: the base layer is with a thickness of 0.3-
0.4mm, explosion-proof layer is with a thickness of 0.1-0.15mm.
7. ageing-resistant automobile window glass patch according to claim 1, it is characterised in that: be equipped on the anti-fog layer
PTFE film.
8. ageing-resistant automobile window glass patch according to claim 1, it is characterised in that: be arranged in the base layer bottom
There is mounting layer, the mounting layer is pressure-sensitive glue-line.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811270242.7A CN109355028A (en) | 2018-10-29 | 2018-10-29 | A kind of ageing-resistant automobile window glass patch |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811270242.7A CN109355028A (en) | 2018-10-29 | 2018-10-29 | A kind of ageing-resistant automobile window glass patch |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109355028A true CN109355028A (en) | 2019-02-19 |
Family
ID=65347273
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811270242.7A Pending CN109355028A (en) | 2018-10-29 | 2018-10-29 | A kind of ageing-resistant automobile window glass patch |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109355028A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111876103A (en) * | 2020-08-20 | 2020-11-03 | 江苏君澄空间科技有限公司 | Bi-component AB adhesive applicable to liquid oxygen environment |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201289852Y (en) * | 2008-09-28 | 2009-08-12 | 泰兴市维维高分子材料有限公司 | Solar cell module backing film |
| CN105348549A (en) * | 2015-11-20 | 2016-02-24 | 福州顺升科技有限公司 | Preparation method of aging-resistant super-hydrophobic hybrid film |
| CN106281096A (en) * | 2016-09-21 | 2017-01-04 | 东莞市联洲知识产权运营管理有限公司 | A kind of environment friendly heat resistant rupture pressure disc |
| CN206256825U (en) * | 2016-11-28 | 2017-06-16 | 天津市凯斯特门窗有限公司 | A kind of complex function substrate for composite door and window structure |
| CN107160799A (en) * | 2017-04-24 | 2017-09-15 | 天津创新晶彩科技有限公司 | A kind of adhering film to glass for avoiding condensation vapor |
| CN107323018A (en) * | 2017-06-24 | 2017-11-07 | 南通伯爵新能源汽车研究院有限公司 | A kind of special sound control glass of new-energy automobile |
| CN207274057U (en) * | 2017-04-24 | 2018-04-27 | 天津创新晶彩科技有限公司 | A kind of adhering film to glass easy to clean |
| CN108437573A (en) * | 2018-02-27 | 2018-08-24 | 成都新柯力化工科技有限公司 | A kind of high-wearing feature composite plastic pad pasting and preparation method for automobile |
-
2018
- 2018-10-29 CN CN201811270242.7A patent/CN109355028A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201289852Y (en) * | 2008-09-28 | 2009-08-12 | 泰兴市维维高分子材料有限公司 | Solar cell module backing film |
| CN105348549A (en) * | 2015-11-20 | 2016-02-24 | 福州顺升科技有限公司 | Preparation method of aging-resistant super-hydrophobic hybrid film |
| CN106281096A (en) * | 2016-09-21 | 2017-01-04 | 东莞市联洲知识产权运营管理有限公司 | A kind of environment friendly heat resistant rupture pressure disc |
| CN206256825U (en) * | 2016-11-28 | 2017-06-16 | 天津市凯斯特门窗有限公司 | A kind of complex function substrate for composite door and window structure |
| CN107160799A (en) * | 2017-04-24 | 2017-09-15 | 天津创新晶彩科技有限公司 | A kind of adhering film to glass for avoiding condensation vapor |
| CN207274057U (en) * | 2017-04-24 | 2018-04-27 | 天津创新晶彩科技有限公司 | A kind of adhering film to glass easy to clean |
| CN107323018A (en) * | 2017-06-24 | 2017-11-07 | 南通伯爵新能源汽车研究院有限公司 | A kind of special sound control glass of new-energy automobile |
| CN108437573A (en) * | 2018-02-27 | 2018-08-24 | 成都新柯力化工科技有限公司 | A kind of high-wearing feature composite plastic pad pasting and preparation method for automobile |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111876103A (en) * | 2020-08-20 | 2020-11-03 | 江苏君澄空间科技有限公司 | Bi-component AB adhesive applicable to liquid oxygen environment |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103930506B (en) | A kind of Special structure film for mirror seat of rear-view mirror in automobile and preparation method thereof | |
| KR101727906B1 (en) | Glazing sheet using vehicle | |
| CN110256836B (en) | Self-repairing radiation refrigerating film | |
| CN112708369A (en) | Anti-yellowing invisible car cover protective film with self-repairing function and manufacturing process thereof | |
| CA2396256A1 (en) | Laminate of a substrate and an extruded high density polyethylene layer | |
| CN109355028A (en) | A kind of ageing-resistant automobile window glass patch | |
| CN113429901A (en) | Heat-insulating noise-reducing car clothes film | |
| CN111732932B (en) | Organic silicon material and preparation method and application thereof | |
| JP2009526872A (en) | Solar control laminate | |
| CN109370520A (en) | A kind of automobile glass anti-fog film | |
| CN208562213U (en) | One kind can be from absorption acrylic protective film | |
| CN209584089U (en) | A kind of automobile window glass patch | |
| CN103302934B (en) | A kind of antifouling light modulation thermal isolation film | |
| CN203331515U (en) | Anti-fouling light-dimming heat-insulating film | |
| CN111187000A (en) | Novel automobile antifogging glass | |
| CN212174865U (en) | Novel nano energy-saving film | |
| CN208646767U (en) | A kind of combined type automobile sealing strip of compact | |
| CN221166463U (en) | Film for automobile glass | |
| CN207416152U (en) | A kind of arrangements for automotive doors waterproof membrane | |
| CN217455162U (en) | Anti-ultraviolet radiation coated glass | |
| CN217265524U (en) | Automobile glass explosion-proof membrane capable of being externally pasted with heat insulation | |
| CN109761513A (en) | A kind of temperature induced color changing laminated glass and its processing technology | |
| CN218146451U (en) | Environment-friendly heat-insulating bulletproof explosion-proof film for glass of building and automobile | |
| CN216106743U (en) | High-temperature-resistant low-residue PU adhesive protective film | |
| CN214496165U (en) | Antifogging film |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190219 |