CN109355022A - Low viscous formula of a kind of binding dust paper roll and preparation method thereof - Google Patents
Low viscous formula of a kind of binding dust paper roll and preparation method thereof Download PDFInfo
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- CN109355022A CN109355022A CN201811081885.7A CN201811081885A CN109355022A CN 109355022 A CN109355022 A CN 109355022A CN 201811081885 A CN201811081885 A CN 201811081885A CN 109355022 A CN109355022 A CN 109355022A
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- glue
- paper roll
- binding dust
- low viscous
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
The invention discloses a kind of low viscous formulas of binding dust paper roll, the low viscous formula of the binding dust paper roll is prepared from the following raw materials: Isooctyl acrylate monomer glue 40%-50%, diluent 50%-60% and reaction additives 1%-5%, a kind of low viscous formula of binding dust paper roll provided by the invention prepares glue as raw material using acrylic acid and isooctanol, material is easy to get, industrial process is easy to control, it can be effectively reduced production cost, it is diluted simultaneously by diluent, it is effectively improved the levelability of glue surface, and cross-linking reaction is carried out by reaction additives, improve glue cohesive force, improve peeling force, reaction is mild, dosage is small, degumming can be reduced, move glue, the stability that the convenience of production and processing can be greatly improved in this way and used.
Description
Technical field
The present invention relates to binding dust paper roll technical field more particularly to a kind of low viscous formulas of binding dust paper roll.
Background technique
In present industrial production and daily life, binding dust paper roll is very widely used, by the way that viscose glue to be coated in
It is stored on paper roll, powder dust and other fine particle impurity can be glued.
But the viscose glue of existing binding dust paper roll is limited by formula and technique, can not guarantee the viscous of viscose glue well
Phenomena such as consistency, when transfer being caused to glue, glue surface planarization is poor, and the cohesive force of glue is poor, is easy to happen degumming and moves glue,
Using effect is undesirable, and the material that glue uses is not easy to obtain, and considerably increases use cost and production technology complexity.
Summary of the invention
The purpose of the present invention is to solve disadvantages existing in the prior art, and a kind of low glue of the binding dust paper roll proposed is matched
Side.
To achieve the goals above, present invention employs following technical solutions:
A kind of low viscous formula of binding dust paper roll, the low viscous formula of the binding dust paper roll are prepared from the following raw materials: Isooctyl acrylate monomer glue
Water 40%-50%, diluent 50%-60% and reaction additives 1%-5%.
Preferably, the preparation method of the low viscous formula of the binding dust paper roll includes the following steps:
S1, Isooctyl acrylate monomer glue is added in mixing drum, is heated to 15 degrees Celsius to 18 degrees Celsius.
S2, diluent is preheated to 20 degrees Celsius to 25 degrees Celsius.
S3, the diluent after preheating is added in mixing drum, Isooctyl acrylate monomer glue is diluted, reduced sticky
Degree.
S4, under 120 rpms to 150 rpms speed, uniform stirring 10 minutes to 15 minutes, it is dilute to obtain glue
Release solution.
S5, reaction additives are added in mixing drum, under 200 rpms to 800 rpms rates, are uniformly stirred
It mixes 15 minutes to 20 minutes, improves glue cohesive force, change peeling force, low viscose glue water can be obtained.
Preferably, the stirring environmental Kuznets Curves are 20 degrees Celsius to 23 degrees Celsius in temperature, humidity 40%RH-60%
RH。
Preferably, the diluent is one or more mixtures of ethyl acetate, butyl acetate and toluene.
Preferably, the reaction additives are trimethylolpropane or 2- methyl-1-aziridine propionic acid rouge.
Preferably, the Isooctyl acrylate monomer glue includes acrylic acid 35%-45%, isooctanol 35%-45%, hexamethylene
10%-15%, polymerization inhibitor 5%-8% and acidic ion liquid 1%-5%.
Preferably, the preparation method of the Isooctyl acrylate monomer glue includes the following steps:
P1, acrylic acid and isooctanol are proportionally added in reaction kettle, at 60 rpms to 70 revolutions per minute clock rates
Under rate, uniform stirring 15 minutes to 20 minutes, material solution is obtained.
P2, hexamethylene and polymerization inhibitor are added in material solution, and are heated to 100 degrees Celsius to 120 degrees Celsius, into
Row azeotropic dehydration.
P3, using acidic ion liquid as catalyst, be added in reaction kettle, carry out catalysis reaction, while is every at 180 turns
Under minute to 200 rpms of speed, uniform stirring reacts 3 hours to 5 hours, obtains reaction liquid.
P4, reaction liquid is cooled under room temperature state, stands 1 hour to 2 hours, layered shaping.
P5, the hexamethylene and catalyst for recycling lower layer, can be obtained the Isooctyl acrylate monomer glue on upper layer.
Preferably, the polymerization inhibitor is benzothiophene.
Preferably, the acidic ion liquid is cation with caprolactam, using dihydrogen phosphate as anion.
A kind of low viscous formula of binding dust paper roll provided by the invention prepares glue, material as raw material using acrylic acid and isooctanol
Material is easy to get, and industrial process is easy to control, and can be effectively reduced production cost, while being diluted by diluent, is effectively improved
The levelability of glue surface, and by reaction additives carry out cross-linking reaction, improve glue cohesive force, improve peeling force 60 to
It is 20 to 350g/25mm after 150 degrees Celsius of solidifications, reaction is mild, and dosage is small, it is possible to reduce degumming moves glue, in this way can be big
The big convenience for improving production and processing and the stability used.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, below in conjunction with specific embodiment, to this
Invention is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, not
For limiting the present invention.
A kind of low viscous formula of binding dust paper roll, the low viscous formula of the binding dust paper roll are prepared from the following raw materials: Isooctyl acrylate monomer glue
Water 40%-50%, diluent 50%-60% and reaction additives 1%-5%.
Preferably, the preparation method of the low viscous formula of the binding dust paper roll includes the following steps:
S1, Isooctyl acrylate monomer glue is added in mixing drum, is heated to 15 degrees Celsius to 18 degrees Celsius.
S2, diluent is preheated to 20 degrees Celsius to 25 degrees Celsius.
S3, the diluent after preheating is added in mixing drum, Isooctyl acrylate monomer glue is diluted, reduced sticky
Degree.
S4, under 120 rpms to 150 rpms speed, uniform stirring 10 minutes to 15 minutes, it is dilute to obtain glue
Release solution.
S5, reaction additives are added in mixing drum, under 200 rpms to 800 rpms rates, are uniformly stirred
It mixes 15 minutes to 20 minutes, improves glue cohesive force, change peeling force, low viscose glue water can be obtained.
Preferably, the stirring environmental Kuznets Curves are 20 degrees Celsius to 23 degrees Celsius in temperature, humidity 40%RH-
60%RH.
Preferably, the diluent is one or more mixtures of ethyl acetate, butyl acetate and toluene.
Preferably, the reaction additives are trimethylolpropane or 2- methyl-1-aziridine propionic acid rouge.
Preferably, the Isooctyl acrylate monomer glue includes acrylic acid 35%-45%, isooctanol 35%-45%, ring
Hexane 10%-15%, polymerization inhibitor 5%-8% and acidic ion liquid 1%-5%.
Preferably, the preparation method of the Isooctyl acrylate monomer glue includes the following steps:
P1, acrylic acid and isooctanol are proportionally added in reaction kettle, at 60 rpms to 70 revolutions per minute clock rates
Under rate, uniform stirring 15 minutes to 20 minutes, material solution is obtained.
P2, hexamethylene and polymerization inhibitor are added in material solution, and are heated to 100 degrees Celsius to 120 degrees Celsius, into
Row azeotropic dehydration.
P3, using acidic ion liquid as catalyst, be added in reaction kettle, carry out catalysis reaction, while is every at 180 turns
Under minute to 200 rpms of speed, uniform stirring reacts 3 hours to 5 hours, obtains reaction liquid.
P4, reaction liquid is cooled under room temperature state, stands 1 hour to 2 hours, layered shaping.
P5, the hexamethylene and catalyst for recycling lower layer, can be obtained the Isooctyl acrylate monomer glue on upper layer.
Preferably, the polymerization inhibitor is benzothiophene.
Preferably, the acidic ion liquid is cation with caprolactam, using dihydrogen phosphate as anion.
A kind of low viscous formula of binding dust paper roll provided by the invention prepares glue, material as raw material using acrylic acid and isooctanol
Material is easy to get, and industrial process is easy to control, and can be effectively reduced production cost, while being diluted by diluent, is effectively improved
The levelability of glue surface, and cross-linking reaction is carried out by reaction additives, glue cohesive force is improved, peeling force, reaction temperature are improved
With dosage is small, it is possible to reduce degumming, move glue, the stability that the convenience of production and processing can be greatly improved in this way and used.
Embodiment 1
A kind of low viscous formula of binding dust paper roll, the low viscous formula of the binding dust paper roll are prepared from the following raw materials: Isooctyl acrylate monomer glue
Water 41%, diluent 55% and reaction additives 4%.
Preferably, the preparation method of the low viscous formula of the binding dust paper roll includes the following steps:
S1, Isooctyl acrylate monomer glue is added in mixing drum, is heated to 15 degrees Celsius to 18 degrees Celsius.
S2, diluent is preheated to 20 degrees Celsius to 25 degrees Celsius.
S3, the diluent after preheating is added in mixing drum, Isooctyl acrylate monomer glue is diluted, reduced sticky
Degree.
S4, under 120 rpms to 150 rpms speed, uniform stirring 10 minutes to 15 minutes, it is dilute to obtain glue
Release solution.
S5, reaction additives are added in mixing drum, under 200 rpms to 800 rpms rates, are uniformly stirred
It mixes 15 minutes to 20 minutes, improves glue cohesive force, change peeling force, low viscose glue water can be obtained.
Preferably, the stirring environmental Kuznets Curves are 20 degrees Celsius to 23 degrees Celsius in temperature, humidity 40%RH-
60%RH.
Preferably, the diluent is one or more mixtures of ethyl acetate, butyl acetate and toluene.
Preferably, the reaction additives are trimethylolpropane.
Preferably, the Isooctyl acrylate monomer glue include acrylic acid 38%, isooctanol 38%, hexamethylene 14%,
Polymerization inhibitor 6% and acidic ion liquid 4%.
Preferably, the preparation method of the Isooctyl acrylate monomer glue includes the following steps:
P1, acrylic acid and isooctanol are proportionally added in reaction kettle, at 60 rpms to 70 revolutions per minute clock rates
Under rate, uniform stirring 15 minutes to 20 minutes, material solution is obtained.
P2, hexamethylene and polymerization inhibitor are added in material solution, and are heated to 100 degrees Celsius to 120 degrees Celsius, into
Row azeotropic dehydration.
P3, using acidic ion liquid as catalyst, be added in reaction kettle, carry out catalysis reaction, while is every at 180 turns
Under minute to 200 rpms of speed, uniform stirring reacts 3 hours to 5 hours, obtains reaction liquid.
P4, reaction liquid is cooled under room temperature state, stands 1 hour to 2 hours, layered shaping.
P5, the hexamethylene and catalyst for recycling lower layer, can be obtained the Isooctyl acrylate monomer glue on upper layer.
Preferably, the polymerization inhibitor is benzothiophene.
Preferably, the acidic ion liquid is cation with caprolactam, using dihydrogen phosphate as anion.
Embodiment 2
A kind of low viscous formula of binding dust paper roll, the low viscous formula of the binding dust paper roll are prepared from the following raw materials: Isooctyl acrylate monomer glue
Water 48%, diluent 50% and reaction additives 2%.
Preferably, the preparation method of the low viscous formula of the binding dust paper roll includes the following steps:
S1, Isooctyl acrylate monomer glue is added in mixing drum, is heated to 15 degrees Celsius to 18 degrees Celsius.
S2, diluent is preheated to 20 degrees Celsius to 25 degrees Celsius.
S3, the diluent after preheating is added in mixing drum, Isooctyl acrylate monomer glue is diluted, reduced sticky
Degree.
S4, under 120 rpms to 150 rpms speed, uniform stirring 10 minutes to 15 minutes, it is dilute to obtain glue
Release solution.
S5, reaction additives are added in mixing drum, under 200 rpms to 800 rpms rates, are uniformly stirred
It mixes 15 minutes to 20 minutes, improves glue cohesive force, change peeling force, low viscose glue water can be obtained.
Preferably, the stirring environmental Kuznets Curves are 20 degrees Celsius to 23 degrees Celsius in temperature, humidity 40%RH-
60%RH.
Preferably, the diluent is one or more mixtures of ethyl acetate, butyl acetate and toluene.
Preferably, the reaction additives are 2- methyl-1-aziridine propionic acid rouge.
Preferably, the Isooctyl acrylate monomer glue include acrylic acid 40%, isooctanol 40%, hexamethylene 12%,
Polymerization inhibitor 5% and acidic ion liquid 3%.
Preferably, the preparation method of the Isooctyl acrylate monomer glue includes the following steps:
P1, acrylic acid and isooctanol are proportionally added in reaction kettle, at 60 rpms to 70 revolutions per minute clock rates
Under rate, uniform stirring 15 minutes to 20 minutes, material solution is obtained.
P2, hexamethylene and polymerization inhibitor are added in material solution, and are heated to 100 degrees Celsius to 120 degrees Celsius, into
Row azeotropic dehydration.
P3, using acidic ion liquid as catalyst, be added in reaction kettle, carry out catalysis reaction, while is every at 180 turns
Under minute to 200 rpms of speed, uniform stirring reacts 3 hours to 5 hours, obtains reaction liquid.
P4, reaction liquid is cooled under room temperature state, stands 1 hour to 2 hours, layered shaping.
P5, the hexamethylene and catalyst for recycling lower layer, can be obtained the Isooctyl acrylate monomer glue on upper layer.
Preferably, the polymerization inhibitor is benzothiophene.
Preferably, the acidic ion liquid is cation with caprolactam, using dihydrogen phosphate as anion.
Embodiment 3
A kind of low viscous formula of binding dust paper roll, the low viscous formula of the binding dust paper roll are prepared from the following raw materials: Isooctyl acrylate monomer glue
Water 44%, diluent 54% and reaction additives 2%.
Preferably, the preparation method of the low viscous formula of the binding dust paper roll includes the following steps:
S1, Isooctyl acrylate monomer glue is added in mixing drum, is heated to 15 degrees Celsius to 18 degrees Celsius.
S2, diluent is preheated to 20 degrees Celsius to 25 degrees Celsius.
S3, the diluent after preheating is added in mixing drum, Isooctyl acrylate monomer glue is diluted, reduced sticky
Degree.
S4, under 120 rpms to 150 rpms speed, uniform stirring 10 minutes to 15 minutes, it is dilute to obtain glue
Release solution.
S5, reaction additives are added in mixing drum, under 200 rpms to 800 rpms rates, are uniformly stirred
It mixes 15 minutes to 20 minutes, improves glue cohesive force, change peeling force, low viscose glue water can be obtained.
Preferably, the stirring environmental Kuznets Curves are 20 degrees Celsius to 23 degrees Celsius in temperature, humidity 40%RH-
60%RH.
Preferably, the diluent is one or more mixtures of ethyl acetate, butyl acetate and toluene.
Preferably, the reaction additives are trimethylolpropane.
Preferably, the Isooctyl acrylate monomer glue include acrylic acid 39%, isooctanol 39%, hexamethylene 10%,
Polymerization inhibitor 8% and acidic ion liquid 4%.
Preferably, the preparation method of the Isooctyl acrylate monomer glue includes the following steps:
P1, acrylic acid and isooctanol are proportionally added in reaction kettle, at 60 rpms to 70 revolutions per minute clock rates
Under rate, uniform stirring 15 minutes to 20 minutes, material solution is obtained.
P2, hexamethylene and polymerization inhibitor are added in material solution, and are heated to 100 degrees Celsius to 120 degrees Celsius, into
Row azeotropic dehydration.
P3, using acidic ion liquid as catalyst, be added in reaction kettle, carry out catalysis reaction, while is every at 180 turns
Under minute to 200 rpms of speed, uniform stirring reacts 3 hours to 5 hours, obtains reaction liquid.
P4, reaction liquid is cooled under room temperature state, stands 1 hour to 2 hours, layered shaping.
P5, the hexamethylene and catalyst for recycling lower layer, can be obtained the Isooctyl acrylate monomer glue on upper layer.
Preferably, the polymerization inhibitor is benzothiophene.
Preferably, the acidic ion liquid is cation with caprolactam, using dihydrogen phosphate as anion.
Taking the above-mentioned ideal embodiment according to the present invention as inspiration, through the above description, relevant staff is complete
Various changes and amendments can be carried out without departing from the scope of the technological thought of the present invention' entirely.The technology of this invention
Property range is not limited to the contents of the specification, it is necessary to which the technical scope thereof is determined according to the scope of the claim.
Claims (8)
1. a kind of low viscous formula of binding dust paper roll, it is characterised in that: the low viscous formula of the binding dust paper roll is prepared from the following raw materials: acrylic acid
Different monooctyl ester glue 40%-50%, diluent 50%-60% and reaction additives 1%-5%.
2. a kind of preparation method of the low viscous formula of binding dust paper roll, it is characterised in that:
Include the following steps:
S1, Isooctyl acrylate monomer glue is added in mixing drum, is heated to 15 degrees Celsius to 18 degrees Celsius；
The Isooctyl acrylate monomer glue include acrylic acid 35%-45%, isooctanol 35%-45%, hexamethylene 10%-15%,
Polymerization inhibitor 5%-8% and acidic ion liquid 1%-5%；
S2, diluent is preheated to 20 degrees Celsius to 25 degrees Celsius；
S3, the diluent after preheating is added in mixing drum, Isooctyl acrylate monomer glue is diluted, reduce viscosity；
S4, under 120 rpms to 150 rpms speed, uniform stirring 10 minutes to 15 minutes, obtain glue dilution it is molten
Liquid；
S5, reaction additives are added in mixing drum, under 200 rpms to 800 rpms rates, uniform stirring 15
Minute to 20 minutes, improves glue cohesive force, changes peeling force, low viscose glue water can be obtained.
3. a kind of preparation method of the low viscous formula of binding dust paper roll according to claim 2, it is characterised in that: the mixing drum
In stirring environmental Kuznets Curves temperature be 20 degrees Celsius to 23 degrees Celsius, humidity 40%RH-60%RH.
4. a kind of preparation method of the low viscous formula of binding dust paper roll according to claim 2, it is characterised in that: the diluent
For one or more mixtures of ethyl acetate, butyl acetate and toluene.
5. a kind of preparation method of the low viscous formula of binding dust paper roll according to claim 2, it is characterised in that: the reaction adds
Adding agent is trimethylolpropane or 2- methyl-1-aziridine propionic acid rouge.
6. a kind of preparation method of the low viscous formula of binding dust paper roll according to claim 2, it is characterised in that: the acrylic acid
The preparation method of different monooctyl ester glue includes the following steps:
P1, acrylic acid and isooctanol are proportionally added in reaction kettle, under 60 rpms to 70 rpms rates,
Uniform stirring 15 minutes to 20 minutes, obtain material solution；
P2, hexamethylene and polymerization inhibitor are added in material solution, and are heated to 100 degrees Celsius to 120 degrees Celsius, be total to
Boiling dehydration；
P3, using acidic ion liquid as catalyst, be added in reaction kettle, carry out catalysis reaction, while at 180 rpms
To 200 rpms of speed, uniform stirring reacts 3 hours to 5 hours, obtains reaction liquid；
P4, reaction liquid is cooled under room temperature state, stands 1 hour to 2 hours, layered shaping；
P5, the hexamethylene and catalyst for recycling lower layer, can be obtained the Isooctyl acrylate monomer glue on upper layer.
7. a kind of preparation method of the low viscous formula of binding dust paper roll according to claim 6, it is characterised in that: the polymerization inhibitor
For benzothiophene.
8. a kind of preparation method of the low viscous formula of binding dust paper roll according to claim 6, it is characterised in that: it is described it is acid from
Sub- liquid is with caprolactam for cation, using dihydrogen phosphate as anion.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811081885.7A CN109355022A (en) | 2018-09-17 | 2018-09-17 | Low viscous formula of a kind of binding dust paper roll and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811081885.7A CN109355022A (en) | 2018-09-17 | 2018-09-17 | Low viscous formula of a kind of binding dust paper roll and preparation method thereof |
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| Publication Number | Publication Date |
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| CN109355022A true CN109355022A (en) | 2019-02-19 |
Family
ID=65350985
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
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| CN201811081885.7A Pending CN109355022A (en) | 2018-09-17 | 2018-09-17 | Low viscous formula of a kind of binding dust paper roll and preparation method thereof |
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| CN101675136A (en) * | 2007-02-22 | 2010-03-17 | 3M创新有限公司 | Pressure sensitive adhesive dispersion having high solids and low viscosity and method of making same |
| CN102533180A (en) * | 2011-12-15 | 2012-07-04 | 广东达美新材料有限公司 | Ultra-low viscosity pressure-sensitive adhesive |
| KR20150078040A (en) * | 2013-12-30 | 2015-07-08 | 코오롱인더스트리 주식회사 | Photocurable Adhesive Resin Composition And Method for Manufacturing the same |
| CN105130803A (en) * | 2015-09-10 | 2015-12-09 | 江苏国胶化学科技有限公司 | Method for preparing 2-ethylhexyl acrylate by catalysis of acidic caprolactam ionic liquid |
| CN108084329A (en) * | 2017-12-01 | 2018-05-29 | 华南协同创新研究院 | A kind of vinegar-acrylic emulsion of high-solid-content and low-viscosity and preparation method thereof |
-
2018
- 2018-09-17 CN CN201811081885.7A patent/CN109355022A/en active Pending
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| CN101675136A (en) * | 2007-02-22 | 2010-03-17 | 3M创新有限公司 | Pressure sensitive adhesive dispersion having high solids and low viscosity and method of making same |
| CN102533180A (en) * | 2011-12-15 | 2012-07-04 | 广东达美新材料有限公司 | Ultra-low viscosity pressure-sensitive adhesive |
| KR20150078040A (en) * | 2013-12-30 | 2015-07-08 | 코오롱인더스트리 주식회사 | Photocurable Adhesive Resin Composition And Method for Manufacturing the same |
| CN105130803A (en) * | 2015-09-10 | 2015-12-09 | 江苏国胶化学科技有限公司 | Method for preparing 2-ethylhexyl acrylate by catalysis of acidic caprolactam ionic liquid |
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Application publication date: 20190219 |