CN109354989A - A kind of stabilized aqueous yellow car refinishing paint of high-performance and preparation method thereof - Google Patents
A kind of stabilized aqueous yellow car refinishing paint of high-performance and preparation method thereof Download PDFInfo
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- CN109354989A CN109354989A CN201810998653.1A CN201810998653A CN109354989A CN 109354989 A CN109354989 A CN 109354989A CN 201810998653 A CN201810998653 A CN 201810998653A CN 109354989 A CN109354989 A CN 109354989A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
The present invention provides a kind of stabilized aqueous yellow car refinishing paints of high-performance, are composed of the following parts by weight: 6-20 parts of resin, 3-10 parts of cosolvent, 6-30 parts, 0.2-1 parts of wetting agent A, 0.5-3 parts of thickener of slurry, 0.2-2 parts of 2-amino-2-methyl-1-propanol, 20-60 parts of deionized water;The slurry is composed of the following parts by weight: 25-60 parts of deionized water, 6-18 parts of dispersing agent, 20-30 parts of yellow uitramarine, 3-20 parts of cosolvent, 0.5-2 parts of wetting agent B, 0.2-1 parts of defoaming agent, 0.2-1 parts of anti-settling agent, 0.1 part of ionic liquid.The present invention also provides the preparation methods of the stabilized aqueous yellow car refinishing paint of the high-performance.The stabilized aqueous yellow car refinishing paint of high-performance provided by the present invention has preferable stability, mildew resistance, water resistance, lower temperature resistance.
Description
Technical field
The present invention relates to a kind of car refinishing paint, more particularly to a kind of stabilized aqueous yellow car refinishing paint of high-performance and
Preparation method.
Background technique
Car refinishing paint refers to the paint that repairing again is carried out to body of a motor car genuine paint as its name suggests, by worker's hand
Work industry, and spraying must be operated at (60 DEG C or less) of low temperature.Car refinishing paint must have two kinds of functions: defencive function and beauty
Function, both functions cannot be by single product complete independentlies.Therefore, the mending paint brand of high quality generally has series of products
It is composed, it mainly has: * putty class: for filling up metal plate defect.* priming paint class: being used for antirust, promotes between paint layer
Bonding force and increase film thickness.* finishing coat class: for improving surface quality and increasing weatherability.It cannot be through in view of vehicle complete vehicle
By high-temperature baking, general car repair factory coating condition is poor, and car refinishing paint and renovation coating mostly use self-drying type priming paint, greasy
Son, intermediate coating, self-drying type synthetic resin coating and volatile dry type nitrate paint, chlorinated polyvinyl chloride paints etc..
Application No. is the Chinese patents of CN201410489250.6 to provide a kind of efficient automobile mending paint, by following weight
The composition composition of part: 3-8 parts of dispersing agent, 7-15 parts of methyl methacrylate, 2-8 parts of butyl acrylate, 3-6 parts of blue or green blue, gather
4-7 parts of glycol monoethyl ether methacrylate, 5-9 parts of dibasic acid esters coalescents, 2-4 parts of defoaming agent, modified hydroxyl acrylic acid tree
7-11 parts of rouge, 2-5 parts of drier, 4-6 parts of organic solvent, 8-11 parts of uncle 16 carbon mercaptan, 2-6 parts of reflective glass beads.This is specially
Benefit is the problem is that its stability, mildew resistance, water resistance, lower temperature resistance are bad.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of stabilized aqueous yellow car refinishing paint of high-performance, have compared with
Stability well, mildew resistance, water resistance, lower temperature resistance.
In order to solve the above technical problems, the technical scheme is that
A kind of stabilized aqueous yellow car refinishing paint of high-performance, is composed of the following parts by weight: 6-20 parts of resin,
3-10 parts of cosolvent, 6-30 parts of slurry, 0.2-1 parts of wetting agent A, 0.5-3 parts of thickener, 2-amino-2-methyl-1-propanol 0.2-2
Part, 20-60 parts of deionized water;
The slurry is composed of the following parts by weight: 25-60 parts of deionized water, 6-18 parts of dispersing agent, and yellow uitramarine
20-30 parts, 3-20 parts of cosolvent, 0.5-2 parts of wetting agent B, 0.2-1 parts of defoaming agent, 0.2-1 parts of anti-settling agent, ionic liquid 0.1
Part.
Further, resin of the present invention is one of PUA, PUD or two kinds.
Further, cosolvent of the present invention is isopropanol, ethylene glycol monobutyl ether, n-amyl alcohol, propylene glycol monomethyl ether acetic acid
One or more of tertiary butyl ether of ester, sec-butyl alcohol, ethylene glycol.
Further, wetting agent A of the present invention is polyether siloxane copolymer.
Further, thickener of the present invention is one or more of polyacrylic acid, polyacrylamide, polyurethane.
Further, dispersing agent of the present invention is the polybasic carboxylic acid salting liquid of polynary amine amide, band pigment affinity groups
One of high molecular weight block copolymer solution.
Further, wetting agent B of the present invention is one of polyether silicone, hyperbranched polyether.
Further, defoaming agent of the present invention is one of organosilicon, mineral oil;The yellow uitramarine is oxidation
One of iron oxide yellow, transparent yellow iron oxide, benzidine yellow, lemon yellow, Yellow disazo pigment, yellow monoazo pigment;It is described
Anti-settling agent is one or more of lithium magnesium silicate, polyamide wax, fumed silica, bentonite.
Further, the preparation step of ionic liquid of the present invention are as follows:
A1., 1,3-propane sultone is dissolved in the 1,3-propane sultone solution for obtaining that concentration is 4mol/L in acetone,
1,3-propane sultone solution is put into ice water, is instilled and the equimolar 1- vinyl imidazole of 1,3-propane sultone, room temperature
Lower stirring obtains solids in 5 days, and vacuum drying after solids acetone washing 3 times is obtained intermediate product;
A2. intermediate product, initiator, lauryl sodium sulfate that step A1 is obtained are added in ethanol water, are led to
Stirred under nitrogen atmosphere 35min is simultaneously warming up to 75 DEG C, the equimolar divinylbenzene of 1,3-propane sultone is then added, after continuation of insurance
Temperature is stirred to react 10h and obtains reaction solution, is centrifuged after reaction solution is demulsified with methanol, ionic liquid is obtained after vacuum drying.
Another technical problem to be solved by the present invention is that providing the system of the stabilized aqueous yellow car refinishing paint of above-mentioned high-performance
Preparation Method.
In order to solve the above technical problems, technical solution is:
A kind of preparation method of the stabilized aqueous yellow car refinishing paint of high-performance, comprising the following steps:
B1. each component is weighed by weight, successively by deionized water, cosolvent, wetting agent B, dispersing agent, defoaming agent, anti-
Heavy agent, ionic liquid are added in oscillator, and yellow uitramarine, 1500-2000w power, 750-1000r/ is added after shaking 5-10min
The fineness for shaking 120-300min to material under min vibration frequency is starched less than 5 μm;
B2. resin, deionized water, cosolvent are added in blender under stirring condition, are stirred under 400-500r/min revolving speed
Slurry is added after mixing 1-3min, sequentially adds wetting agent A, thickener, 1000- after stirring 5-10min under 800-1200r/min revolving speed
Addition 2-amino-2-methyl-1-propanol adjusts pH as 8.0-9 after stirring 5-10min under 1200r/min revolving speed, stirs to material
Viscosity be 800-1500mPas after continue stir 4-8min obtain the stabilized aqueous yellow car refinishing paint of high-performance.
Compared with prior art, the invention has the following advantages:
1) cosolvent that the present invention selects can make viscosity after storing 30 days at 50 DEG C of slurry not change, no sedimentation, after punching silver
Form and aspect color difference≤0.2 is painted viscosity after storing 30 days at 50 DEG C and is not changed, no sedimentation, and positive side changes very little after punching silver, form and aspect
Change (hexagonal degree color difference meter) color difference≤0.2, substantially increases stability of the invention;In addition, cosolvent can also greatly improve
Mildew resistance of the invention.
2) resin that the present invention selects can greatly improve the water resistance of paint film, and 360h is not blistering at 40 ± 2 DEG C, wrinkle resistant,
It does not fall off.
3) dispersing agent selected of the present invention can effectively improve the dispersibility of each component, to further increase of the invention steady
Qualitative, mildew resistance and water resistance.
3) present invention is that ionic liquid is made in Material synthesis with 1,3- propane sultone, 1- vinyl imidazole, divinylbenzene etc.
Body can effectively improve compatibility and bond strength between each component, and the stability of itself is also very good, therefore can be into
One step, which reduces, improves stability, mildew resistance and water resistance of the invention;In addition, the ionic liquid has stronger resistance to low temperature,
Therefore lower temperature resistance of the invention can also be effectively improved.
Specific embodiment
Below in conjunction with specific embodiment, the present invention will be described in detail, herein illustrative embodiments and their description of the invention
For explaining the present invention, but it is not as a limitation of the invention.
Embodiment 1
The stabilized aqueous yellow car refinishing paint of high-performance, is composed of the following parts by weight: PUA6 parts, isopropanol 10
Part, 10 parts of slurry, 0.5 part of polyether siloxane copolymer, 1 part of polyacrylic acid, 1 part of 2-amino-2-methyl-1-propanol, deionized water
50 parts;Slurry is composed of the following parts by weight: 50 parts of deionized water, 12 parts of the polybasic carboxylic acid salting liquid of polynary amine amide,
20 parts of iron oxide yellow, 20 parts of isopropanol, 0.8 part of polyether silicone, 0.4 part of organosilicon, 0.2 part of lithium magnesium silicate, ionic liquid 0.1
Part.
The preparation method of the stabilized aqueous yellow car refinishing paint of the high-performance the following steps are included:
B1. weigh each component by weight, successively by deionized water, isopropanol, polyether silicone, polynary amine amide it is more
First carboxylic acid salt solution, organosilicon, lithium magnesium silicate, ionic liquid are added in oscillator, and iron oxide yellow is added after shaking 5min,
The fineness for shaking 200min to material under 2000w power, 800r/min vibration frequency is starched less than 5 μm;
B2. PUA, deionized water, isopropanol are added in blender under stirring condition, stir 2min under 420r/min revolving speed
Slurry is added afterwards, sequentially adds polyether siloxane copolymer, polyacrylic acid, 1100r/min after stirring 10min under 800r/min revolving speed
Addition 2-amino-2-methyl-1-propanol adjusts pH as 8.0-9 after stirring 9min under revolving speed, and stirring to the viscosity of material is 800-
Continue stirring 5min after 1500mPas and obtains the stabilized aqueous yellow car refinishing paint of high-performance.
Embodiment 2
The stabilized aqueous yellow car refinishing paint of high-performance, is composed of the following parts by weight: 20 parts of PUD, ethylene glycol
3 parts of monobutyl ether, 20 parts of slurry, 0.8 part of polyether siloxane copolymer, 1.5 parts of polyacrylamide, 2-amino-2-methyl-1-propanol
0.5 part, 40 parts of deionized water;Slurry is composed of the following parts by weight: 30 parts of deionized water, the height with pigment affinity groups
10 parts of molecular weight block copolymer, 30 parts of transparent yellow iron oxide, 3 parts of ethylene glycol monobutyl ether, 1.5 parts of hyperbranched polyether, minerals
0.6 part, 0.4 part of polyamide wax, 0.1 part of ionic liquid of oil.
The preparation method of the stabilized aqueous yellow car refinishing paint of the high-performance the following steps are included:
B1. each component is weighed by weight, successively by deionized water, ethylene glycol monobutyl ether, hyperbranched polyether, band pigment parent
It is added in oscillator with the high molecular weight block copolymer of group, mineral oil, polyamide wax, ionic liquid, after shaking 10min
Transparent yellow iron oxide is added, the fineness of concussion 250min to material is obtained less than 5 μm under 1500w power, 900r/min vibration frequency
To slurry;
B2. PUD, deionized water, ethylene glycol monobutyl ether are added in blender under stirring condition, are stirred under 440r/min revolving speed
Slurry is added after mixing 1.5min, sequentially adds polyether siloxane copolymer, polyacrylamide after stirring 5min under 1200r/min revolving speed
Amine, stirs that 2-amino-2-methyl-1-propanol to be added to adjust pH after 7min be 8.0-9, stirring to material under 1050r/min revolving speed
Viscosity be 800-1500mPas after continue stir 4min obtain the stabilized aqueous yellow car refinishing paint of high-performance.
Embodiment 3
The stabilized aqueous yellow car refinishing paint of high-performance, is composed of the following parts by weight: 10 parts of PUA, PUD, just
8 parts of amylalcohol, 6 parts are starched, 1 part of polyether siloxane copolymer, 2 parts of polyacrylamide, 1.5 parts of 2-amino-2-methyl-1-propanol, is gone
60 parts of ionized water;Slurry is composed of the following parts by weight: 25 parts of deionized water, the high molecular weight with pigment affinity groups is embedding
8 parts of copolymer 1 of section, 25 parts of benzidine yellow, 10 parts of n-amyl alcohol, 1.4 parts of hyperbranched polyether, 0.5 part of mineral oil, gas phase titanium dioxide
0.6 part of silicon, 0.1 part of ionic liquid.
The preparation method of the stabilized aqueous yellow car refinishing paint of the high-performance the following steps are included:
B1. each component is weighed by weight, successively by deionized water, n-amyl alcohol, hyperbranched polyether, band pigment affinity groups
High molecular weight block copolymer, mineral oil, fumed silica, ionic liquid be added oscillator in, shake 6min after plus
Enter benzidine yellow, the fineness that 300min to material are shaken under 1900w power, 750r/min vibration frequency is starched less than 5 μm;
B2. PUA, PUD, deionized water, n-amyl alcohol are added in blender under stirring condition, are stirred under 450r/min revolving speed
Slurry is added after 1.2min, sequentially adds polyether siloxane copolymer, polyurethane, 1000r/ after stirring 9min under 900r/min revolving speed
Addition 2-amino-2-methyl-1-propanol adjusts pH as 8.0-9 after stirring 5min under min revolving speed, and the viscosity of stirring to material is
Continue stirring 7min after 800-1500mPas and obtains the stabilized aqueous yellow car refinishing paint of high-performance.
Embodiment 4
The stabilized aqueous yellow car refinishing paint of high-performance, is composed of the following parts by weight: 15 parts of PUD, propylene glycol
6 parts of methyl ether acetate, 30 parts of slurry, 0.2 part of polyether siloxane copolymer, 0.8 part of polyurethane, 2-amino-2-methyl-1-propanol
1.8 parts, 20 parts of deionized water;Slurry is composed of the following parts by weight: 60 parts of deionized water, the height with pigment affinity groups
6 parts of molecular weight block copolymer, 21 parts of lemon yellow, 15 parts of propylene glycol methyl ether acetate, 1.8 parts of polyether silicone, organosilicon 0.8
Part, 0.8 part of bentonite, 0.1 part of ionic liquid.
The preparation method of the stabilized aqueous yellow car refinishing paint of the high-performance the following steps are included:
B1. each component is weighed by weight, successively by deionized water, propylene glycol methyl ether acetate, polyether silicone, band face
The high molecular weight block copolymer of material affinity groups, organosilicon, bentonite, ionic liquid are added in oscillator, after shaking 7min
Lemon yellow is added, the fineness that 120min to material are shaken under 1800w power, 1000r/min vibration frequency is starched less than 5 μm;
B2. PUD, deionized water, propylene glycol methyl ether acetate are added in blender under stirring condition, 480r/min revolving speed
Slurry is added after lower stirring 1.4min, sequentially adds polyether siloxane copolymer, poly- ammonia after stirring 8min under 1000r/min revolving speed
Ester, stirs that 2-amino-2-methyl-1-propanol to be added to adjust pH after 10min be 8.0-9, stirring to material under 1200r/min revolving speed
Viscosity be 800-1500mPas after continue stir 8min obtain the stabilized aqueous yellow car refinishing paint of high-performance.
Embodiment 5
The stabilized aqueous yellow car refinishing paint of high-performance, is composed of the following parts by weight: 8 parts of PUA, sec-butyl alcohol 5
Part, starch 15 parts, 0.3 part of polyether siloxane copolymer, 0.5 part of polyacrylamide, 2 parts of 2-amino-2-methyl-1-propanol, go from
30 parts of sub- water;Slurry is composed of the following parts by weight: 40 parts of deionized water, the polybasic carboxylic acid salting liquid 15 of polynary amine amide
Part, 28 parts of Yellow disazo pigment, 8 parts of sec-butyl alcohol, 0.5 part of hyperbranched polyether, 1 part of organosilicon, 1 part of bentonite, ionic liquid
0.1 part.
The preparation method of the stabilized aqueous yellow car refinishing paint of the high-performance the following steps are included:
B1. weigh each component by weight, successively by deionized water, sec-butyl alcohol, hyperbranched polyether, polynary amine amide it is more
First carboxylic acid salt solution, organosilicon, bentonite, ionic liquid are added in oscillator, and Yellow disazo pigment is added after shaking 9min,
The fineness for shaking 150min to material under 1600w power, 850r/min vibration frequency is starched less than 5 μm;
B2. PUA, deionized water, sec-butyl alcohol are added in blender under stirring condition, stir 3min under 400r/min revolving speed
Slurry is added afterwards, sequentially adds polyether siloxane copolymer, polyacrylamide, 1150r/ after stirring 6min under 1100r/min revolving speed
Addition 2-amino-2-methyl-1-propanol adjusts pH as 8.0-9 after stirring 8min under min revolving speed, and the viscosity of stirring to material is
Continue stirring 6min after 800-1500mPas and obtains the stabilized aqueous yellow car refinishing paint of high-performance.
Embodiment 6
The stabilized aqueous yellow car refinishing paint of high-performance, is composed of the following parts by weight: 14 parts of PUA, PUD, second
9 parts of the tertiary butyl ether of glycol, 25 parts of slurry, 0.6 part of polyether siloxane copolymer, 3 parts of polyacrylic acid, 2-amino-2-methyl-1-propanol
0.2 part, 45 parts of deionized water;Slurry is composed of the following parts by weight: 45 parts of deionized water, the polynary carboxylic of polynary amine amide
14 parts of acid salt solution, 27 parts of yellow monoazo pigment, 16 parts of the tertiary butyl ether of ethylene glycol, 1 part of polyether silicone, 0.2 part of mineral oil,
0.5 part of fumed silica, 0.1 part of ionic liquid.
The preparation method of the stabilized aqueous yellow car refinishing paint of the high-performance the following steps are included:
B1. each component is weighed by weight, successively by deionized water, the tertiary butyl ether of ethylene glycol, polyether silicone, polyamine acyl
Polybasic carboxylic acid salting liquid, mineral oil, fumed silica, the ionic liquid of amine are added in oscillator, are added after shaking 8min
Yellow monoazo pigment, the fineness that 180min to material are shaken under 1700w power, 950r/min vibration frequency are obtained less than 5 μm
Slurry;
B2. PUA, PUD, deionized water, the tertiary butyl ether of ethylene glycol are added in blender under stirring condition, 500r/min revolving speed
Slurry is added after lower stirring 1min, sequentially adds polyether siloxane copolymer, polypropylene after stirring 7min under 1050r/min revolving speed
Acid, stirs that 2-amino-2-methyl-1-propanol to be added to adjust pH after 6min be 8.0-9, stirring to material under 1080r/min revolving speed
Viscosity be 800-1500mPas after continue stir 4.5min obtain the stabilized aqueous yellow car refinishing paint of high-performance.
The preparation step of embodiment 1-6 intermediate ion liquid are as follows:
A1., 1,3-propane sultone is dissolved in the 1,3-propane sultone solution for obtaining that concentration is 4mol/L in acetone,
1,3-propane sultone solution is put into ice water, is instilled and the equimolar 1- vinyl imidazole of 1,3-propane sultone, room temperature
Lower stirring obtains solids in 5 days, and vacuum drying after solids acetone washing 3 times is obtained intermediate product;
A2. intermediate product, initiator, lauryl sodium sulfate that step A1 is obtained are added in ethanol water, are led to
Stirred under nitrogen atmosphere 35min is simultaneously warming up to 75 DEG C, the equimolar divinylbenzene of 1,3-propane sultone is then added, after continuation of insurance
Temperature is stirred to react 10h and obtains reaction solution, is centrifuged after reaction solution is demulsified with methanol, ionic liquid is obtained after vacuum drying.
Comparative Examples 1
It does not include co-solvent ethylene gylcol monobutyl ether, other components and preparation method are same as Example 2.
Comparative Examples 2
PUD is replaced with common polyurethane resin, other components and preparation method are same as Example 2.
Comparative Examples 3
PUA is replaced with common polyurethane resin, other components and preparation method are same as Example 5.
Comparative Examples 4
Do not include high molecular weight block copolymer of the dispersing agent with pigment affinity groups, other components and preparation method with
Embodiment 2 is identical.
Comparative Examples 5
It does not include ionic liquid, other components and preparation method are same as Example 2.
Comparative example
Comparative example is the embodiment 1 of the Chinese invention application No. is CN201410489250.6.
Experimental example one: stability test
Test the rate of change in viscosity after storing 30 days at 50 DEG C of each car refinishing paint, rate of change in viscosity=(viscosity-after test
Viscosity before testing)/preceding viscosity × 100% is tested, rate of change in viscosity is lower to show that stability is better.Test result is as shown in table 1:
Rate of change in viscosity (%) | |
Embodiment 1 | 0 |
Embodiment 2 | 0 |
Embodiment 3 | 0 |
Embodiment 4 | 0 |
Embodiment 5 | 0 |
Embodiment 6 | 0 |
Comparative Examples 1 | 3.89 |
Comparative Examples 2 | 0 |
Comparative Examples 3 | 0 |
Comparative Examples 4 | 3.21 |
Comparative Examples 5 | 3.77 |
Comparative example | 10.56 |
Table 1
By table 1 it will be evident that the rate of change in viscosity of 1-6 of the embodiment of the present invention is 0, show stability of the invention compared with
It is good.The constituent part of Comparative Examples 1-5 is different from embodiment 2,5, and wherein the rate of change in viscosity of Comparative Examples 1,4,5 has
Different degrees of raising illustrates that cosolvent, dispersing agent, ionic liquid can effectively improve stability;Comparative Examples 2,3 glue
Degree change rate is similarly 0, illustrates that the type of resin has little effect stability.
Experimental example two: mildew resistance test
By each car refinishing paint inoculated aspergillus niger bacterium, the mildew the area ratio of surface of the paint film, mildew the area ratio are tested after 20 days
=mildew area/paint film area × 100%, mildew the area ratio is smaller to show that mildew resistance is better.Test result is as shown in table 2:
Table 2
By table 2 it will be evident that the mildew the area ratio of 1-6 of the embodiment of the present invention is 0, show mildew resistance of the invention compared with
It is good.The constituent part of Comparative Examples 1-5 is different from embodiment 2,5, and wherein the mildew the area ratio of Comparative Examples 1,4,5 has
Different degrees of raising illustrates that cosolvent, dispersing agent, ionic liquid can effectively improve mildew resistance;The length of Comparative Examples 2,3
Mould the area ratio is similarly 0, illustrates that the type of resin has little effect mildew resistance.
Experimental example three: water resistance test
Each car refinishing paint is coated on steel plate, is subsequently placed in 40 ± 2 DEG C of water, paint film situation is observed after 360h,
Test result is as shown in table 3:
Table 3
By table 3 it will be evident that 1-6 of the embodiment of the present invention does not occur blistering, corrugation, obscission, show the present invention
Water resistance it is preferable.The constituent part of Comparative Examples 1-5 is different from embodiment 2,5, and wherein Comparative Examples 2-4 rises
Bubble, corrugation, obscission, illustrate that PUA, PUD, dispersing agent can effectively improve water resistance;Comparative Examples 1,5 do not rise
Bubble, corrugation, obscission, illustrate that cosolvent, ionic liquid have little effect water resistance.
Experimental example four: lower temperature resistance test
The glass transition temperature of each car refinishing paint is tested by DMA method, glass transition temperature is lower to show that lower temperature resistance is better,
Test result is as shown in table 4:
Glass transition temperature (DEG C) | |
Embodiment 1 | -50.6 |
Embodiment 2 | -50.9 |
Embodiment 3 | -50.2 |
Embodiment 4 | -50.5 |
Embodiment 5 | -50.4 |
Embodiment 6 | -50.3 |
Comparative Examples 1 | -50.7 |
Comparative Examples 2 | -45.8 |
Comparative Examples 3 | -45.5 |
Comparative Examples 4 | -50.6 |
Comparative Examples 5 | -40.1 |
Comparative example | -31.3 |
Table 4
By table 4 it will be evident that the glass transition temperature of 1-6 of the embodiment of the present invention is significantly lower than comparative example, show this hair
Bright lower temperature resistance is preferable.The constituent part of Comparative Examples 1-5 is different from embodiment 2,5, wherein Comparative Examples 2,3,5
Glass transition temperature has different degrees of rising, illustrates that PUA, PUD, ionic liquid can effectively improve lower temperature resistance;Reference is implemented
The glass transition temperature and embodiment 1-6 of example 1,4 are similar, illustrate that cosolvent, dispersing agent have little effect lower temperature resistance.
The above-described embodiments merely illustrate the principles and effects of the present invention, and is not intended to limit the present invention.It is any ripe
The personage for knowing this technology all without departing from the spirit and scope of the present invention, carries out modifications and changes to above-described embodiment.Cause
This, institute is complete without departing from the spirit and technical ideas disclosed in the present invention by those of ordinary skill in the art such as
At all equivalent modifications or change, should be covered by the claims of the present invention.
Claims (10)
1. a kind of stabilized aqueous yellow car refinishing paint of high-performance, it is characterised in that: be composed of the following parts by weight: tree
6-20 parts of rouge, 3-10 parts of cosolvent, 6-30 parts of slurry, A0.2-1 parts of wetting agent, 0.5-3 parts of thickener, 2- amino-2-methyl -1-
0.2-2 parts of propyl alcohol, 20-60 parts of deionized water;
The slurry is composed of the following parts by weight: 25-60 parts of deionized water, 6-18 parts of dispersing agent, and yellow uitramarine 20-30
Part, 3-20 parts of cosolvent, 0.5-2 parts of wetting agent B, 0.2-1 parts of defoaming agent, 0.2-1 parts of anti-settling agent, 0.1 part of ionic liquid.
2. the stabilized aqueous yellow car refinishing paint of high-performance according to claim 1, it is characterised in that: the resin is
One of PUA, PUD or two kinds.
3. the stabilized aqueous yellow car refinishing paint of high-performance according to claim 1, it is characterised in that: the cosolvent is
One of tertiary butyl ether of isopropanol, ethylene glycol monobutyl ether, n-amyl alcohol, propylene glycol methyl ether acetate, sec-butyl alcohol, ethylene glycol is several
Kind.
4. the stabilized aqueous yellow car refinishing paint of high-performance according to claim 1, it is characterised in that: the wetting agent A
For polyether siloxane copolymer.
5. the stabilized aqueous yellow car refinishing paint of high-performance according to claim 1, it is characterised in that: the thickener is
One or more of polyacrylic acid, polyacrylamide, polyurethane.
6. the stabilized aqueous yellow car refinishing paint of high-performance according to claim 1, it is characterised in that: the dispersing agent is
One of the polybasic carboxylic acid salting liquid of polynary amine amide, high molecular weight block copolymer solution with pigment affinity groups.
7. the stabilized aqueous yellow car refinishing paint of high-performance according to claim 1, it is characterised in that: the wetting agent B
For one of polyether silicone, hyperbranched polyether.
8. the stabilized aqueous yellow car refinishing paint of high-performance according to claim 1, it is characterised in that: the defoaming agent is
One of organosilicon, mineral oil;The yellow uitramarine be iron oxide yellow, transparent yellow iron oxide, benzidine yellow, lemon yellow,
One of Yellow disazo pigment, yellow monoazo pigment;The anti-settling agent is lithium magnesium silicate, polyamide wax, gas phase dioxy
One or more of SiClx, bentonite.
9. the stabilized aqueous yellow car refinishing paint of high-performance according to claim 1, it is characterised in that: the ionic liquid
Preparation step are as follows:
A1., 1,3-propane sultone is dissolved in the 1,3-propane sultone solution for obtaining that concentration is 4mol/L in acetone, by 1,
3-N-morpholinopropanesulfonic acid lactone solution is put into ice water, and instillation and the equimolar 1- vinyl imidazole of 1,3-propane sultone stir at room temperature
It mixes 5 days and obtains solids, vacuum drying after solids acetone washing 3 times is obtained into intermediate product;
A2. intermediate product, initiator, lauryl sodium sulfate that step A1 is obtained are added in ethanol water, lead to nitrogen
The lower stirring 35min of protection is simultaneously warming up to 75 DEG C, and the equimolar divinylbenzene of 1,3-propane sultone is then added, continues heat preservation and stirs
It mixes reaction 10h and obtains reaction solution, be centrifuged after reaction solution is demulsified with methanol, ionic liquid is obtained after vacuum drying.
10. the preparation method of the stabilized aqueous yellow car refinishing paint of high-performance described in any one according to claim 1~9,
It is characterized by comprising following steps:
B1. weigh each component by weight, successively by deionized water, cosolvent, wetting agent B, dispersing agent, defoaming agent, anti-settling agent,
Ionic liquid is added in oscillator, and yellow uitramarine, 1500-2000w power, 750-1000r/min shake is added after shaking 5-10min
The fineness for shaking 120-300min to material under dynamic frequency is starched less than 5 μm;
B2. resin, deionized water, cosolvent are added in blender under stirring condition, stir 1- under 400-500r/min revolving speed
Slurry is added after 3min, sequentially adds wetting agent A, thickener, 1000- after stirring 5-10min under 800-1200r/min revolving speed
Addition 2-amino-2-methyl-1-propanol adjusts pH as 8.0-9 after stirring 5-10min under 1200r/min revolving speed, stirs to material
Viscosity be 800-1500mPas after continue stir 4-8min obtain the stabilized aqueous yellow car refinishing paint of high-performance.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112552812A (en) * | 2019-09-26 | 2021-03-26 | 雅图高新材料有限公司 | Water-based single-component automobile paint containing transparent iron oxide pigment and preparation method thereof |
CN113416472A (en) * | 2021-07-30 | 2021-09-21 | 雅图高新材料股份有限公司 | Water-based bi-component epoxy primer for racing helmet and preparation method thereof |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002301422A (en) * | 2001-01-30 | 2002-10-15 | Kowa Industry Co Ltd | Powder painting method |
EP1325090A2 (en) * | 2000-09-25 | 2003-07-09 | Chemetall GmbH | Method for coating metallic surfaces and use of substrates coated in such a way or coatings produced in such a way |
CN1986665A (en) * | 2005-12-22 | 2007-06-27 | 关西油漆株式会社 | Aqueous coating composition |
CN102190952A (en) * | 2011-05-24 | 2011-09-21 | 东来涂料技术(上海)有限公司 | Environment-friendly water-based single-component metallic-effect refinish paint for automobiles and preparation method thereof |
CN102250536A (en) * | 2011-05-24 | 2011-11-23 | 东来涂料技术(上海)有限公司 | Environmentally-friendly water-based single-component solid-color automobile refinishing paint and preparation method thereof |
CN102277074A (en) * | 2011-07-25 | 2011-12-14 | 东来涂料技术(上海)有限公司 | Water-based automotive refinish paint with high hiding power and preparation method thereof |
-
2018
- 2018-08-29 CN CN201810998653.1A patent/CN109354989B/en active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1325090A2 (en) * | 2000-09-25 | 2003-07-09 | Chemetall GmbH | Method for coating metallic surfaces and use of substrates coated in such a way or coatings produced in such a way |
JP2002301422A (en) * | 2001-01-30 | 2002-10-15 | Kowa Industry Co Ltd | Powder painting method |
CN1986665A (en) * | 2005-12-22 | 2007-06-27 | 关西油漆株式会社 | Aqueous coating composition |
CN102190952A (en) * | 2011-05-24 | 2011-09-21 | 东来涂料技术(上海)有限公司 | Environment-friendly water-based single-component metallic-effect refinish paint for automobiles and preparation method thereof |
CN102250536A (en) * | 2011-05-24 | 2011-11-23 | 东来涂料技术(上海)有限公司 | Environmentally-friendly water-based single-component solid-color automobile refinishing paint and preparation method thereof |
CN102277074A (en) * | 2011-07-25 | 2011-12-14 | 东来涂料技术(上海)有限公司 | Water-based automotive refinish paint with high hiding power and preparation method thereof |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112552812A (en) * | 2019-09-26 | 2021-03-26 | 雅图高新材料有限公司 | Water-based single-component automobile paint containing transparent iron oxide pigment and preparation method thereof |
CN113416472A (en) * | 2021-07-30 | 2021-09-21 | 雅图高新材料股份有限公司 | Water-based bi-component epoxy primer for racing helmet and preparation method thereof |
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