CN109354896A - Insulate new material and preparation method thereof - Google Patents
Insulate new material and preparation method thereof Download PDFInfo
- Publication number
- CN109354896A CN109354896A CN201810983718.5A CN201810983718A CN109354896A CN 109354896 A CN109354896 A CN 109354896A CN 201810983718 A CN201810983718 A CN 201810983718A CN 109354896 A CN109354896 A CN 109354896A
- Authority
- CN
- China
- Prior art keywords
- new material
- insulation new
- insulation
- material according
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/04—Thermoplastic elastomer
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
Abstract
The present invention relates to a kind of insulation new materials and preparation method thereof, belong to new material technology field.The insulation new material, by the material composition of following mass fraction: 20-30 parts of thermoplastic elastomer (TPE)；A2-5 parts of fire retardant；B3-6 parts of fire retardant；8-15 parts of ceramic powders；6-15 parts of coupling agent；0-20 parts of silica 1；10-15 parts of dispersing agent；6-12 parts of binder；20-30 parts of polyacrylic resin；10-20 parts of water.The insulation new material has the characteristics such as heat-resist, abrasion-resistant is high and low in cost.Preparation method provided by the invention, it is scientific and reasonable, it is simple and easy.
Description
Technical field
The present invention relates to a kind of insulation new materials and preparation method thereof, belong to new material technology field.
Background technique
Common insulating materials is divided into three kinds: (1) inorganic insulating material: having mica, asbestos, marble, porcelain, glass
Deng；(2) organic insulating material: there are resin, rubber, paper, fiber crops, cotton yarn etc.；(3) mix insulation material: added with the above insulating materials
Work and molding name kind insulating materials.
The research of insulating materials is always an emphasis of China's scientific research project, if it is possible to research and develop a ingredient it is simple,
The prices of raw materials are cheap, and can reach the green wood material formula of good insulation effect, will be used widely in multiple fields.
Insulating materials is the non electrically conductive material in the case where allowing voltage, but is not absolute non electrically conductive material, in certain electric field strength
Under effect, the processes such as conductive, polarization, loss, breakdown can also occur, and be used for a long time it also occur that aging.But it is existing exhausted
The heat-resisting crocking resistance of edge material is poor, and expensive, is not easy to not large-scale production.
Summary of the invention
In view of the deficiencies of the prior art, the object of the present invention is to provide a kind of insulation new materials, have heat-resist, wear-resisting
Wipe the characteristics such as high and low in cost.
Meanwhile the present invention also provides preparation methods, and it is scientific and reasonable, it is simple and easy.
Insulation new material of the present invention, by the material composition of following mass fraction:
Preferably, the insulation new material, by the material composition of following mass fraction:
The thermoplastic elastomer (TPE) is one or more of G130D, G155D or G163D.
The fire retardant A is organic fire-retardant.
Preferably, the fire retardant A is organophosphorous fire retardant.
The fire retardant B is magnalium flame retardant
The coupling agent is one or both of KH-550 or KH-560.
The ceramic powders granularity is 3-6mm.
The dispersing agent is one or more of barium stearate, calcium stearate or atoleine.
Preferably, the dispersing agent is barium stearate or calcium stearate.
The binder is one of phosphate binders or cyanoacrylate-polyethylene glycol binder or two
Kind.
Preferably, the binder is phosphate binders.
The preparation method of insulation new material of the present invention, comprising the following steps:
1) at room temperature, all raw materials are proportionally added in high-speed mixer, are uniformly mixed；
2) it feeds the mixture into double screw extruder, said hot-forming twice, extrusioning mixture, spontaneously dry, obtain
To insulation new material.
In the step 1, high-speed mixer revolving speed is 700-800rpm；Set temperature is 110-130 DEG C.
Compared with prior art, the invention has the following beneficial effects:
1. insulation new material described in has the characteristic heat-resist, abrasion-resistant is high；
2. insulation new material ingredient described in is simple, from a wealth of sources to be easy to get, low in cost, is suitble to large-scale production；
Preparation method described in 3., it is scientific and reasonable, it is simple and easy.
Detailed description of the invention
Fig. 1 is preparation method flow chart of the invention.
Specific embodiment
The present invention will be further explained with reference to the examples below.
In embodiment, each substance unit is all Kg.
Embodiment 1
A kind of insulation new material, by the material composition of following mass fraction, thermoplastic elastomer (TPE) G130D 20Kg；Fire retardant
A organophosphorous fire retardant 2Kg；Fire retardant B magnalium flame retardant 3Kg；Ceramic powders 8Kg；Coupling agent KH-550 6Kg；Silica
10Kg；Dispersing agent 10Kg；Binder 6Kg；Polyacrylic resin 20Kg；Water 10Kg.
Wherein, ceramic powders granularity is 3mm；Dispersing agent is calcium stearate；Binder is phosphate binders.
It is prepared as follows:
1) at room temperature, all raw materials are proportionally added in high-speed mixer, are uniformly mixed；
2) it feeds the mixture into double screw extruder, said hot-forming twice, extrusioning mixture, spontaneously dry, obtain
To insulation new material.
In step 1, high-speed mixer revolving speed is 800rpm；Set temperature is 110 DEG C.
Embodiment 2
A kind of insulation new material, by the material composition of following mass fraction, thermoplastic elastomer (TPE) G155D 30Kg；Fire retardant
A organophosphorous fire retardant 5Kg；Fire retardant B magnalium flame retardant 6Kg；Ceramic powders 15Kg；Coupling agent KH-560 15Kg；Titanium dioxide
Silicon 20Kg；Dispersing agent 15Kg；Binder 12Kg；Polyacrylic resin 30Kg；Water 20Kg.
Wherein, ceramic powders granularity is 4mm, and dispersing agent is barium stearate, and binder is cyanoacrylate-polyethylene glycol
Binder.
It is prepared as follows:
1) at room temperature, all raw materials are proportionally added in high-speed mixer, are uniformly mixed；
2) it feeds the mixture into double screw extruder, said hot-forming twice, extrusioning mixture, spontaneously dry, obtain
To insulation new material.
In step 1, high-speed mixer revolving speed is 760rpm；Set temperature is 130 DEG C.
Embodiment 3
A kind of insulation new material, by the material composition of following quality Kg number, thermoplastic elastomer (TPE) G163D 25Kg；Fire retardant
A organophosphorous fire retardant 4Kg；Fire retardant B magnalium flame retardant 4Kg；Ceramic powders 10Kg；Coupling agent KH-560 9Kg；Titanium dioxide
Silicon 15Kg；Dispersing agent 12Kg；Binder 10Kg；25 parts of polyacrylic resin；15 parts of water.
Wherein, ceramic powders granularity is 5mm, and dispersing agent is barium stearate and calcium stearate, and binder is alpha-cyanoacrylate
Ester-polyethylene glycol binder.
It is prepared as follows:
1) at room temperature, all raw materials are proportionally added in high-speed mixer, are uniformly mixed；
2) it feeds the mixture into double screw extruder, said hot-forming twice, extrusioning mixture, spontaneously dry, obtain
To insulation new material.
In step 1, high-speed mixer revolving speed is 740rpm；Set temperature is 115 DEG C.
Embodiment 4
A kind of insulation new material, by the material composition of following quality Kg number, thermoplastic elastomer (TPE) G163D and G130D
26Kg；Fire retardant A organic silicon fibre retardant 4Kg；Fire retardant B magnalium flame retardant 5Kg；Ceramic powders 12Kg；Coupling agent KH-
55010Kg；Silica 1 6Kg；Dispersing agent 13Kg；Binder 14Kg；Polyacrylic resin 26Kg；Water 16Kg.
Wherein, ceramic powders granularity is 5mm, and dispersing agent is barium stearate and calcium stearate, and binder is alpha-cyanoacrylate
Ester-polyethylene glycol binder.
It is prepared as follows:
1) at room temperature, all raw materials are proportionally added in high-speed mixer, are uniformly mixed；
2) it feeds the mixture into double screw extruder, said hot-forming twice, extrusioning mixture, spontaneously dry, obtain
To insulation new material.
In step 1, high-speed mixer revolving speed is 780rpm；Set temperature is 120 DEG C.
Embodiment 5
A kind of insulation new material, by the material composition of following quality Kg number, thermoplastic elastomer (TPE) G130D 28Kg；Fire retardant
A organic silicon fibre retardant 5Kg；Fire retardant B magnalium flame retardant 5Kg；Ceramic powders 13Kg；Coupling agent KH-560 13Kg；Titanium dioxide
Silicon 17Kg；Dispersing agent 13Kg；Binder 11Kg；Polyacrylic resin 26Kg；Water 17Kg.
Wherein, ceramic powders granularity is 3.5mm, and dispersing agent is barium stearate and calcium stearate, and binder is cyanoacrylate
Acid esters-polyethylene glycol binder.
It is prepared as follows:
1) at room temperature, all raw materials are proportionally added in high-speed mixer, are uniformly mixed；
2) it feeds the mixture into double screw extruder, said hot-forming twice, extrusioning mixture, spontaneously dry, obtain
To insulation new material.
In step 1, high-speed mixer revolving speed is 800rpm；Set temperature is 120 DEG C.
Embodiment 6
A kind of insulation new material, by the material composition of following quality Kg number, thermoplastic elastomer (TPE) G130D and G155D
29Kg；Fire retardant A organic silicon fibre retardant 4Kg；Fire retardant B magnalium flame retardant 4Kg；Ceramic powders 14Kg；Coupling agent KH-
55012Kg；Silica 1 8Kg；Dispersing agent 19Kg；Binder 11Kg；Polyacrylic resin 27Kg；Water 19Kg.
Wherein, ceramic powders granularity is 4.5mm, and dispersing agent is barium stearate and atoleine, and binder is cyanoacrylate
Acid esters-polyethylene glycol binder.
It is prepared as follows:
1) at room temperature, all raw materials are proportionally added in high-speed mixer, are uniformly mixed；
2) it feeds the mixture into double screw extruder, said hot-forming twice, extrusioning mixture, spontaneously dry, obtain
To insulation new material.
In step 1, high-speed mixer revolving speed is 750rpm；Set temperature is 110 DEG C.
Embodiment 7
A kind of insulation new material, by the material composition of following quality Kg number, thermoplastic elastomer (TPE) G155D 24Kg；Fire retardant
A organophosphorous fire retardant 3Kg；Fire retardant B magnalium flame retardant 3Kg；Ceramic powders 9Kg；Coupling agent KG-550 and KH-560 8Kg；
Silica 1 2Kg；Dispersing agent 11Kg；Binder 8Kg；Polyacrylic resin 23Kg；Water 14Kg.
Wherein, ceramic powders granularity is 5mm, and dispersing agent is atoleine and calcium stearate, and binder is alpha-cyanoacrylate
Ester-polyethylene glycol binder and phosphate binders.
It is prepared as follows:
1) at room temperature, all raw materials are proportionally added in high-speed mixer, are uniformly mixed；
2) it feeds the mixture into double screw extruder, said hot-forming twice, extrusioning mixture, spontaneously dry, obtain
To insulation new material.
In step 1, high-speed mixer revolving speed is 800rpm；Set temperature is 130 DEG C.
Embodiment 8
A kind of insulation new material, by the material composition of following quality Kg number, thermoplastic elastomer (TPE) G155D, G130D and
G163D 22Kg；Fire retardant A organophosphorous fire retardant 3Kg；Fire retardant B magnalium flame retardant 3.5Kg；Ceramic powders 8Kg；Coupling agent
KG-5607Kg；Silica 1 3Kg；Dispersing agent 12Kg；Binder 7Kg；Polyacrylic resin 23Kg；Water 14Kg.
Wherein, ceramic powders granularity is 6mm, and dispersing agent is barium stearate and calcium stearate, and binder is phosphate bonded
Agent.
It is prepared as follows:
1) at room temperature, all raw materials are proportionally added in high-speed mixer, are uniformly mixed；
2) it feeds the mixture into double screw extruder, said hot-forming twice, extrusioning mixture, spontaneously dry, obtain
To insulation new material.
In step 1, high-speed mixer revolving speed is 700rpm；Set temperature is 110 DEG C.
Embodiment 1-8 product is tested for the property, test result is as shown in table 1.
The resistivity measurement result of 1 embodiment 1-8 product of table
Claims (10)
1. a kind of insulation new material, it is characterised in that: by the material composition of following mass fraction:
2. insulation new material according to claim 1, it is characterised in that: by the material composition of following mass fraction:
3. insulation new material according to claim 1, it is characterised in that: thermoplastic elastomer (TPE) G130D, G155D or
One or more of G163D.
4. insulation new material according to claim 1, it is characterised in that: fire retardant A is organic fire-retardant；Fire retardant B is
Magnalium flame retardant.
5. insulation new material according to claim 1, it is characterised in that: coupling agent is one of KH-550 or KH-560
Or two kinds.
6. insulation new material according to claim 1, it is characterised in that: ceramic powders granularity is 3-6mm.
7. insulation new material according to claim 1, it is characterised in that: dispersing agent is barium stearate, calcium stearate or liquid
One or more of body paraffin.
8. insulation new material according to claim 1, it is characterised in that: binder is phosphate binders or cyanoacrylate
One or both of acid esters-polyethylene glycol binder.
9. a kind of preparation method of insulation new material described in claim 1, it is characterised in that: the following steps are included:
1) at room temperature, all raw materials are proportionally added in high-speed mixer, are uniformly mixed；
2) it feeds the mixture into double screw extruder, said hot-forming twice, extrusioning mixture, spontaneously dry, obtain absolutely
Edge new material.
10. the preparation method of insulation new material according to claim 9, it is characterised in that: in step 1, high-speed mixer
Revolving speed is 700-800rpm；Set temperature is 110-130 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810983718.5A CN109354896A (en) | 2018-08-27 | 2018-08-27 | Insulate new material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810983718.5A CN109354896A (en) | 2018-08-27 | 2018-08-27 | Insulate new material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109354896A true CN109354896A (en) | 2019-02-19 |
Family
ID=65349894
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810983718.5A Pending CN109354896A (en) | 2018-08-27 | 2018-08-27 | Insulate new material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109354896A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111875359A (en) * | 2020-08-03 | 2020-11-03 | 湖南省新化县林海陶瓷有限公司 | High-voltage-resistant insulating and positioning ceramic material |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102295804A (en) * | 2010-06-24 | 2011-12-28 | 上海凯波特种电缆料厂有限公司 | Thermoplastic halogen-free inflaming retarding material for automobile wire as well as preparation and application thereof |
| CN102775740A (en) * | 2012-07-24 | 2012-11-14 | 金发科技股份有限公司 | Halogen-free flame-retardant elastomer composition |
| CN105111522A (en) * | 2015-09-16 | 2015-12-02 | 合肥海畅电气技术有限公司 | Insulating material of high voltage transmission equipment |
| CN107793727A (en) * | 2017-11-07 | 2018-03-13 | 广西小草信息产业有限责任公司 | One kind insulation new material and preparation method thereof |
| CN108192176A (en) * | 2018-02-07 | 2018-06-22 | 苏州美昱高分子材料有限公司 | Electric vehicle car high-voltage line crosslinked insulating material |
-
2018
- 2018-08-27 CN CN201810983718.5A patent/CN109354896A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102295804A (en) * | 2010-06-24 | 2011-12-28 | 上海凯波特种电缆料厂有限公司 | Thermoplastic halogen-free inflaming retarding material for automobile wire as well as preparation and application thereof |
| CN102775740A (en) * | 2012-07-24 | 2012-11-14 | 金发科技股份有限公司 | Halogen-free flame-retardant elastomer composition |
| CN105111522A (en) * | 2015-09-16 | 2015-12-02 | 合肥海畅电气技术有限公司 | Insulating material of high voltage transmission equipment |
| CN107793727A (en) * | 2017-11-07 | 2018-03-13 | 广西小草信息产业有限责任公司 | One kind insulation new material and preparation method thereof |
| CN108192176A (en) * | 2018-02-07 | 2018-06-22 | 苏州美昱高分子材料有限公司 | Electric vehicle car high-voltage line crosslinked insulating material |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111875359A (en) * | 2020-08-03 | 2020-11-03 | 湖南省新化县林海陶瓷有限公司 | High-voltage-resistant insulating and positioning ceramic material |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106633390B (en) | A kind of ground-buried high voltage power cable modified polypropene enhancing corrugate sheath pipe and preparation method thereof | |
| CN102993555A (en) | High impact halogen-free flame retardant PP/PPO (Propene Polymer/Poly Phenylene Oxide) alloy material and preparation method and application thereof | |
| CN102234401B (en) | Calcium sulfate whisker modified polystyrene composite material, and preparation method thereof. | |
| CN105199304A (en) | Polymer composite high in heat-conducting property | |
| CN105670288A (en) | High-performance flame-retardancy insulating plastic material and preparation method thereof | |
| CN109354896A (en) | Insulate new material and preparation method thereof | |
| CN104558981A (en) | PFA fluorine color masterbatch and production process thereof | |
| CN114524987B (en) | Ceramic polyolefin with high porcelain strength and preparation method thereof | |
| CN101357844A (en) | PTC thermal sensitive ceramic material and method for preparing the same | |
| CN105130274B (en) | A kind of microwave composite medium substrate of high thermal stability and preparation method thereof | |
| CN113354409A (en) | Microwave dielectric ceramic and preparation method thereof | |
| CN102040806B (en) | High temperature resistance anti-static low warpage PBT / PET alloy composite material and its manufacturing method | |
| CN102372898A (en) | Nano-ZnO filling modified polyether-ether-ketone (PEEK) film and preparation method thereof | |
| US3943217A (en) | Process for manufacturing bodies of various shapes from inorganic powders | |
| CN110698814A (en) | Anhydride cured epoxy resin-silicon micro powder composite material for processing low-voltage electrical products | |
| CN106854074A (en) | Inorganic solid carbon resistance and its manufacture method | |
| CN109517332A (en) | A kind of polyether-ether-ketone base transformer framework and preparation method thereof | |
| CN110054889A (en) | A kind of anti-flammability biology base PA56 composite material and preparation method | |
| TW357371B (en) | Low-temperature dielectric compound and the use of the cascade microdielectric ceramic components | |
| GB2093012A (en) | Refractory or heat-resistant composite articles | |
| CN108455984A (en) | A kind of nano ceramics cerul feeding and preparation method thereof | |
| CN114804835A (en) | Novel carbon composite ceramic linear resistor and preparation method thereof | |
| CN107793727A (en) | One kind insulation new material and preparation method thereof | |
| CN104788837A (en) | PPS thermal conductive insulating plastic | |
| CN105273215B (en) | A kind of heat-resisting electron membrane and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190219 |
|
| RJ01 | Rejection of invention patent application after publication |