CN109354755A - A kind of sole of shoe material and preparation method thereof - Google Patents

A kind of sole of shoe material and preparation method thereof Download PDF

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Publication number
CN109354755A
CN109354755A CN201811080653.XA CN201811080653A CN109354755A CN 109354755 A CN109354755 A CN 109354755A CN 201811080653 A CN201811080653 A CN 201811080653A CN 109354755 A CN109354755 A CN 109354755A
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Prior art keywords
parts
agent
foaming agent
sole
bridge formation
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Pending
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CN201811080653.XA
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Chinese (zh)
Inventor
黄劲煌
宋光社
黄海东
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Quanzhou Huayang Shoe Material Science And Technology Co Ltd Jinjiang Branch
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Quanzhou Huayang Shoe Material Science And Technology Co Ltd Jinjiang Branch
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Priority to CN201811080653.XA priority Critical patent/CN109354755A/en
Publication of CN109354755A publication Critical patent/CN109354755A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • AHUMAN NECESSITIES
    • A43FOOTWEAR
    • A43BCHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B13/00Soles; Sole-and-heel integral units
    • A43B13/02Soles; Sole-and-heel integral units characterised by the material
    • A43B13/04Plastics, rubber or vulcanised fibre
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0014Use of organic additives
    • C08J9/0023Use of organic additives containing oxygen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0061Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0066Use of inorganic compounding ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0095Mixtures of at least two compounding ingredients belonging to different one-dot groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04Homopolymers or copolymers of ethene
    • C08J2323/08Copolymers of ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2400/00Characterised by the use of unspecified polymers
    • C08J2400/30Polymeric waste or recycled polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/16Ethene-propene or ethene-propene-diene copolymers

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

The invention discloses a kind of sole of shoe materials, belong to shoes field, the raw material including following parts by weight meter: 30-40 parts of polyethylene vinegar ethylene, 5-15 parts of EVA particles, 6-12 parts of rubber, 15-25 parts of elastomer, EPDM5-15 parts of EPDM, 20-30 parts of recycled plastic modified materials, 2-5 parts of anti-wear agent, 2-4 parts of filler, 1-2 parts of stearic acid, 1-2 parts of bridge formation agent aid, 1-2 parts of zinc oxide, 2-4 parts of Masterbatch, 1-2 parts of bridging agent, 1-2 parts of foaming agent.There is good mechanical performance using sole made of material of the present invention, wearability is good, anti-skidding, deodorization and sole is softer, and waste and old plastics can be recycled by the present invention, environmental protection and reduces production cost.

Description

A kind of sole of shoe material and preparation method thereof
Technical field
The invention belongs to shoes field, it is related to a kind of sole of shoe material and preparation method thereof.
Background technique
Existing sole generally uses SBS main materials, is equipped with the auxiliary materials such as polystyrene, naphthenic oil, using this material The sole of production is at high cost and performance is more general.In addition, generally existing in production plastics, Rubber & Rubber Products industry The pernicious gas of association during ultimate product is formed when problem, useless defective goods cause serious pollution to the environment on periphery, mould The phenomenon that service life of glue product abandons everywhere when reaching the limit of is on the rise, and the processing of especially plastic products causes not in time Public hazards.
Summary of the invention
The needle above problem, the present invention provides a kind of sole of shoe materials and preparation method thereof.The purpose of the present invention is logical The product being mixed using waste plastic, polybag and rubber etc. is crossed, with waste plastic is main former by different products Material, configuration, production, preparation links in do not generate environmentally harmful substance, faced with the image of environment-friendly products Consumer, and the defect ware Litter for being included in waste plastic classification field can be passed through by these methods and be recycled, most The excellent product of lifelong output.
In order to solve the above technical problems, the technical scheme adopted by the invention is that: a kind of sole of shoe material, feature exist In: the raw material including following parts by weight meter: 30-40 parts of polyethylene vinegar ethylene, 5-15 parts of EVA particles, 6-12 parts of rubber, bullet 15-25 parts of body of property, EPDM5-15 parts of EPDM, 20-30 parts of recycled plastic modified materials, 2-5 parts of anti-wear agent, 2-4 parts of filler, 1-2 parts of stearic acid, 1-2 parts of bridge formation agent aid, 1-2 parts of zinc oxide, 2-4 parts of Masterbatch, 1-2 parts of bridging agent, 1-2 parts of foaming agent.
Preferably, the raw material including following parts by weight meter: 35 parts of polyethylene vinegar ethylene, 10 parts of EVA particles, rubber 6 Part, it is 20 parts of elastomer, EPDM10 parts of EPDM, 25 parts of recycled plastic modified materials, 5 parts of anti-wear agent, 3.3 parts of filler, stearic 1.6 parts, 1.0 parts of bridge formation agent aid, 1.0 parts of zinc oxide, 3.0 parts of Masterbatch, 1.5 parts of bridging agent, 1.0 parts of foaming agent of acid.
It further, further include rubber pange reclaimed materials.
Further, the mass fraction of the rubber pange reclaimed materials is 80-150.
Further, the mass fraction of the rubber pange reclaimed materials is 100.
A kind of preparation method of sole of shoe material, step include:
(1) it develops: being set and be formulated by physical property, confirmation color, physical property, multiplying power, hardness and the journey of contraction after setting Degree;
(2) foaming agent, bridge formation foaming agent, titanium dioxide, Masterbatch, bridge formation agent aid, titanium dioxide ingredient: are prepared according to formula Weighting error value is 5g, and Masterbatch weighting error value is 0.1g, and foaming agent, bridge formation foaming agent, bridge formation agent aid separately pack son, It convenient for multiple title, examines grammes per square metre whether accurate, the auxiliary material prepared is indicated into color, type body, number, date;
(3) mixing: EVA particles, filler, anti-wear agent are prepared according to formula, weighting error value ± 0.1kg moulds EVA Micelle and configured foaming agent, bridge formation foaming agent, titanium dioxide, Masterbatch, bridge formation agent aid pour into mixing slot together, carry out Pressurization production;Opening time 7-8 hours, setting air pressure reached 190-250 pa, and 92-98 DEG C of temperature, progress first time stirring simultaneously will The dust on pressurization lid periphery is removed;Air pressure reaches 290-350 pa, and at 102-108 DEG C of temperature, carrying out second of stirring simultaneously will pressurization The dust on lid periphery is removed;Air pressure reaches 390-450 pa, at 109-115 DEG C of temperature, carries out third time stirring simultaneously for pressurization lid week The dust on side is removed, while being put into bridge formation foaming agent, and at this moment pressurization lid cannot be fully pressurized the bottom of to, because foaming agent is preheated to liquid Know from experience and sprays and must dally 30 degree and can pressurize in right to the left;Stirring is primary at machine pressurization operating 60 seconds, when pressurization operates 120 seconds Carry out second of stirring, when pressurization runs to 180 seconds, temperature is at 117-123 DEG C at this time, examine material whether beating, the rear OK It can discharge.
(4) mill is granulated: first open mill is cleaned out first, sets 65-75 DEG C of open mill temperature, be granulated in trough, Air hose, cooling bucket, the full sieve of vibration are cleaned out, and sets that pelletizer, die head, expects pipe, temperature as 85-95 DEG C, debug by open mill in slot Material, is finally involved in pelletizer slot by good thin and thick, thickness setting: 5-8m/m, thin: 0.8-1m/m, by material extruding pelletization, setting Grain length is 2m/m, opens cooling water, cooling wind, fan shaking screen, particle is finally sent into agitator.
(5) be put in storage: agitator, which is cleaned up, to enter bucket for particle, finished writing designation card, weight, pack, accomplished fluently sample Test, is finally put in storage.
By the above-mentioned description of this invention it is found that compared to the prior art, the present invention has the advantage that
1, there is good mechanical performance using sole made of material of the present invention, wearability is good, anti-skidding, deodorization and sole It is softer.
2, waste and old plastics can be recycled by the present invention, environmental protection and reduction production cost.
3, the present invention will not generate pernicious gas during the manufacturing, pollute environment.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, by the following examples to the present invention It is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to Limit the present invention.
Embodiment 1
A kind of sole of shoe material, the raw material including following parts by weight meter: 35 parts of polyethylene vinegar ethylene, EVA particles 10 Part, 20 parts of elastomer, 6 parts of rubber, EPDM10 parts of EPDM, 25 parts of recycled plastic modified materials, 5 parts of anti-wear agent, filler 3.3 Part, 1.6 parts of stearic acid, 1.0 parts of bridge formation agent aid, 1.0 parts of zinc oxide, 3.0 parts of Masterbatch, 1.5 parts of bridging agent, foaming agent 1.0 Part, the mass fraction of rubber pange reclaimed materials is 100.
A kind of preparation method of sole of shoe material, step include:
(1) it develops: being set and be formulated by physical property, confirmation color, physical property, multiplying power, hardness and the journey of contraction after setting Degree;
(2) foaming agent, bridge formation foaming agent, titanium dioxide, Masterbatch, bridge formation agent aid, titanium dioxide ingredient: are prepared according to formula Electronic scale weighting error value is 5g, and Masterbatch electronic scale weighting error value is 0.1g, and foaming agent, is built bridge at bridge formation foaming agent Whether agent aid separately packs son, claim convenient for multiple, examine grammes per square metre accurate, and the auxiliary material prepared is indicated color, type body, part Number, date;
(3) mixing: EVA particles, filler, anti-wear agent are prepared according to formula, electronic scale weighting error value is 0.1kg falls EVA particles and configured foaming agent, bridge formation foaming agent, titanium dioxide, Masterbatch, bridge formation agent aid together Enter mixing slot, carries out pressurization production;Opening time 7 hours, setting air pressure reached 220 pas, 95 DEG C of temperature, carried out first time stirring And the dust on pressurization lid periphery is removed;Air pressure reaches 320 pas, at 105 DEG C of temperature, carries out second of stirring simultaneously for pressurization lid week The dust on side is removed;Air pressure reaches 420 pas, and at 112 DEG C of temperature, it is simultaneously that the dust on pressurization lid periphery is clear to carry out third time stirring It removes, while being put into bridge formation foaming agent, at this moment pressurization lid cannot be fully pressurized the bottom of to, because foaming agent is preheated to liquid and can spray palpus Right dallies 30 degree and can pressurize to the left;Stirring is primary at machine pressurization operating 60 seconds, and pressurization carries out second when operating 120 seconds Secondary stirring, pressurization is when running to 180 seconds, and temperature is at 117-123 DEG C at this time, examine material whether beating, can discharge after OK.
(4) mill is granulated: first first being cleaned out open mill, is set open mill temperature 70 C, is granulated in trough, wind Pipe, cooling bucket, the full sieve of vibration are cleaned out, and set that pelletizer, die head, expects pipe, temperature as 90 DEG C, debugged thin by open mill in slot Thickness, time thickness of standard, three times thin, one time material is finally involved in pelletizer slot by thickness, thickness setting: 5-8m/m, thin: 0.8-1m/ Material extruding pelletization is set grain length as 2m/m by m, is opened cooling water, cooling wind, fan shaking screen, is finally sent into particle and stirs Bucket.
(5) be put in storage: agitator, which is cleaned up, to enter bucket for particle, finished writing designation card, weight, packed by 25kg, beat Good sample test, last plate stack storage by 40 colors.
Embodiment 2
A kind of sole of shoe material, the raw material including following parts by weight meter: 30 parts of polyethylene vinegar ethylene, EVA particles 5 Part, 8 parts of rubber, 15 parts of elastomer, EPDM5 parts of EPDM, 20 parts of recycled plastic modified materials, 2 parts of anti-wear agent, 2 parts of filler, 1 part of stearic acid, 1.2 parts of bridge formation agent aid, 1.2 parts of zinc oxide, 2 parts of Masterbatch, 1 part of bridging agent, 1.2 parts of foaming agent, rubber hair The mass fraction for steeping reclaimed materials is 80.
A kind of preparation method of sole of shoe material, step include:
(1) it develops: being set and be formulated by physical property, confirmation color, physical property, multiplying power, hardness and the journey of contraction after setting Degree;
(2) foaming agent, bridge formation foaming agent, titanium dioxide, Masterbatch, bridge formation agent aid, titanium dioxide ingredient: are prepared according to formula Electronic scale weighting error value is 5g, and Masterbatch electronic scale weighting error value is 0.1g, and foaming agent, is built bridge at bridge formation foaming agent Whether agent aid separately packs son, claim convenient for multiple, examine grammes per square metre accurate, and the auxiliary material prepared is indicated color, type body, part Number, date;
(3) mixing: EVA particles, filler, anti-wear agent are prepared according to formula, electronic scale weighting error value is 0.1kg falls EVA particles and configured foaming agent, bridge formation foaming agent, titanium dioxide, Masterbatch, bridge formation agent aid together Enter mixing slot, carries out pressurization production;Opening time 7 hours, setting air pressure reached 220 pas, 95 DEG C of temperature, carried out first time stirring And the dust on pressurization lid periphery is removed;Air pressure reaches 320 pas, at 105 DEG C of temperature, carries out second of stirring simultaneously for pressurization lid week The dust on side is removed;Air pressure reaches 420 pas, and at 112 DEG C of temperature, it is simultaneously that the dust on pressurization lid periphery is clear to carry out third time stirring It removes, while being put into bridge formation foaming agent, at this moment pressurization lid cannot be fully pressurized the bottom of to, because foaming agent is preheated to liquid and can spray palpus Right dallies 30 degree and can pressurize to the left;Stirring is primary at machine pressurization operating 60 seconds, and pressurization carries out second when operating 120 seconds Secondary stirring, pressurization is when running to 180 seconds, and temperature is at 117-123 DEG C at this time, examine material whether beating, can discharge after OK.
(4) mill is granulated: first first being cleaned out open mill, is set open mill temperature 70 C, is granulated in trough, wind Pipe, cooling bucket, the full sieve of vibration are cleaned out, and set that pelletizer, die head, expects pipe, temperature as 90 DEG C, debugged thin by open mill in slot Thickness, time thickness of standard, three times thin, one time material is finally involved in pelletizer slot by thickness, thickness setting: 5-8m/m, thin: 0.8-1m/ Material extruding pelletization is set grain length as 2m/m by m, is opened cooling water, cooling wind, fan shaking screen, is finally sent into particle and stirs Bucket.
(5) be put in storage: agitator, which is cleaned up, to enter bucket for particle, finished writing designation card, weight, packed by 25kg, beat Good sample test, last plate stack storage by 40 colors.
Embodiment 3
A kind of sole of shoe material, the raw material including following parts by weight meter: 40 parts of polyethylene vinegar ethylene, EVA particles 15 Part, 12 parts of rubber, 25 parts of elastomer, EPDM15 parts of EPDM, 30 parts of recycled plastic modified materials, 2.5 parts of anti-wear agent, filler 4 parts, 2 parts of stearic acid, 2 parts of bridge formation agent aid, 2 parts of zinc oxide, 4 parts of Masterbatch, 2 parts of bridging agent, 2 parts of foaming agent, rubber pange The mass fraction of reclaimed materials is 150.
A kind of preparation method of sole of shoe material, step include:
(1) it develops: being set and be formulated by physical property, confirmation color, physical property, multiplying power, hardness and the journey of contraction after setting Degree;
(2) foaming agent, bridge formation foaming agent, titanium dioxide, Masterbatch, bridge formation agent aid, titanium dioxide ingredient: are prepared according to formula Electronic scale weighting error value is 5g, and Masterbatch electronic scale weighting error value is 0.1g, and foaming agent, is built bridge at bridge formation foaming agent Whether agent aid separately packs son, claim convenient for multiple, examine grammes per square metre accurate, and the auxiliary material prepared is indicated color, type body, part Number, date;
(3) mixing: EVA particles, filler, anti-wear agent are prepared according to formula, electronic scale weighting error value is 0.1kg falls EVA particles and configured foaming agent, bridge formation foaming agent, titanium dioxide, Masterbatch, bridge formation agent aid together Enter mixing slot, carries out pressurization production;Opening time 7 hours, setting air pressure reached 220 pas, 95 DEG C of temperature, carried out first time stirring And the dust on pressurization lid periphery is removed;Air pressure reaches 320 pas, at 105 DEG C of temperature, carries out second of stirring simultaneously for pressurization lid week The dust on side is removed;Air pressure reaches 420 pas, and at 112 DEG C of temperature, it is simultaneously that the dust on pressurization lid periphery is clear to carry out third time stirring It removes, while being put into bridge formation foaming agent, at this moment pressurization lid cannot be fully pressurized the bottom of to, because foaming agent is preheated to liquid and can spray palpus Right dallies 30 degree and can pressurize to the left;Stirring is primary at machine pressurization operating 60 seconds, and pressurization carries out second when operating 120 seconds Secondary stirring, pressurization is when running to 180 seconds, and temperature is at 117-123 DEG C at this time, examine material whether beating, can discharge after OK.
(4) mill is granulated: first first being cleaned out open mill, is set open mill temperature 70 C, is granulated in trough, wind Pipe, cooling bucket, the full sieve of vibration are cleaned out, and set that pelletizer, die head, expects pipe, temperature as 90 DEG C, debugged thin by open mill in slot Thickness, time thickness of standard, three times thin, one time material is finally involved in pelletizer slot by thickness, thickness setting: 5-8m/m, thin: 0.8-1m/ Material extruding pelletization is set grain length as 2m/m by m, is opened cooling water, cooling wind, fan shaking screen, is finally sent into particle and stirs Bucket.
(5) be put in storage: agitator, which is cleaned up, to enter bucket for particle, finished writing designation card, weight, packed by 25kgg, beat Good sample test, last plate stack storage by 40 colors.
The sole material of 1-3 of embodiment of the present invention preparation is tested for the property below, test result is shown in Table 1:
Project To contrasting Embodiment 1 Embodiment 2 Embodiment 3
Hardness 50 40 42 43
Wearability/mm3 140 153 148 150
Rebound degree/% 35 50 46 48
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention Made any modifications, equivalent replacements, and improvements etc., should all be included in the protection scope of the present invention within mind and principle.

Claims (6)

1. a kind of sole of shoe material, it is characterised in that: the raw material including following parts by weight meter: 30-40 parts of polyethylene vinegar ethylene, 5-15 parts of EVA particles, 6-12 parts of rubber, 15-25 parts of elastomer, EPDM5-15 parts of EPDM, recycled plastic modified materials 20- 30 parts, 2-5 parts of anti-wear agent, 2-4 parts of filler, 1-2 parts of stearic acid, 1-2 parts of bridge formation agent aid, 1-2 parts of zinc oxide, Masterbatch 2- 4 parts, 1-2 parts of bridging agent, 1-2 parts of foaming agent.
2. a kind of sole of shoe material according to claim 1, it is characterised in that: the raw material including following parts by weight meter: 35 parts of polyethylene vinegar ethylene, 10 parts of EVA particles, 6 parts of rubber, 20 parts of elastomer, EPDM10 parts of EPDM, recycled plastic changes 25 parts of material of property, 5 parts of anti-wear agent, 3.3 parts of filler, 1.6 parts of stearic acid, 1.0 parts of bridge formation agent aid, 1.0 parts of zinc oxide, Masterbatch 3.0 parts, 1.5 parts of bridging agent, 1.0 parts of foaming agent.
3. a kind of sole of shoe material according to claim 1, it is characterised in that: further include rubber pange reclaimed materials.
4. a kind of sole of shoe material according to claim 4, it is characterised in that: the quality of the rubber pange reclaimed materials Number is 80-150.
5. the shoes that a kind of sole according to claim 4 and vamp can be freely combined, it is characterised in that: the rubber hair The mass fraction for steeping reclaimed materials is 100.
6. a kind of preparation method of sole of shoe material according to claim 1, it is characterised in that: step includes:
(1) it develops: being set and be formulated by physical property, confirmation color, physical property, multiplying power, hardness and the degree of contraction after setting;
(2) foaming agent, bridge formation foaming agent, titanium dioxide, Masterbatch, bridge formation agent aid, foaming agent, frame ingredient: are prepared according to formula Whether bridge foaming agent, bridge formation agent aid separately pack son, claim convenient for multiple, examine grammes per square metre accurate, the auxiliary material prepared is indicated Color, type body, number, date;
(3) EVA particles, filler, anti-wear agent, weighting error value ± 0.1kg, by EVA particles mixing: are prepared according to formula And configured foaming agent, bridge formation foaming agent, titanium dioxide, Masterbatch, bridge formation agent aid pour into mixing slot together, pressurize Production;Opening time 7-8 hours, setting air pressure reached 190-250 pa, 92-98 DEG C of temperature, carries out first time stirring and will pressurize The dust on lid periphery is removed;Air pressure reaches 290-350 pa, at 102-108 DEG C of temperature, carries out second of stirring simultaneously for pressurization lid week The dust on side is removed;Air pressure reaches 390-450 pa, at 109-115 DEG C of temperature, carries out third time stirring and by pressurization lid periphery Dust is removed, while being put into bridge formation foaming agent, and at this moment pressurization lid cannot be fully pressurized the bottom of to, because foaming agent is preheated to liquid meeting Spraying to dally 30 degree and can pressurize in right to the left;Stirring is primary at machine pressurization operating 60 seconds, and pressurization carries out when operating 120 seconds Second of stirring, pressurization is when running to 180 seconds, and temperature is at 117-123 DEG C at this time, examine material whether beating, can go out after OK Material.
(4) mill be granulated: first open mill is cleaned out first, set 65-75 DEG C of open mill temperature, be granulated trough in, air hose, Cooling bucket, the full sieve of vibration are cleaned out, and set that pelletizer, die head, expects pipe, temperature as 85-95 DEG C, debugged thin by open mill in slot Material is finally involved in pelletizer slot by thickness, thickness setting: 5-8m/m, thin: material extruding pelletization is set grain length by 0.8-1m/m For 2m/m, cooling water, cooling wind, fan shaking screen are opened, particle is finally sent into agitator.
(5) be put in storage: agitator, which is cleaned up, to enter bucket for particle, finish writing designation card, weight, pack, accomplish fluently sample test, Finally it is put in storage.
CN201811080653.XA 2018-09-17 2018-09-17 A kind of sole of shoe material and preparation method thereof Pending CN109354755A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115141425A (en) * 2022-08-09 2022-10-04 杭州朴西生活家居有限公司 High-elasticity EVA sole material and preparation method thereof

Citations (4)

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CN102993546A (en) * 2012-08-13 2013-03-27 茂泰(福建)鞋材有限公司 High-elasticity light-weight rubber-plastic foam material with good wear resistance and preparation method of foam material
KR101512168B1 (en) * 2014-03-10 2015-04-16 주식회사 에이로 The composition for rubber sole
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