CN1687515A - Expanding glue for spray coating clothing, and producing method thereof - Google Patents
Expanding glue for spray coating clothing, and producing method thereof Download PDFInfo
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- CN1687515A CN1687515A CN 200510033895 CN200510033895A CN1687515A CN 1687515 A CN1687515 A CN 1687515A CN 200510033895 CN200510033895 CN 200510033895 CN 200510033895 A CN200510033895 A CN 200510033895A CN 1687515 A CN1687515 A CN 1687515A
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Abstract
The present invention provides a kind of inflation rubber used for clothes-producing spring, which is made from mixing vulcanizing agent, oxidant, strengthen agent, accelerant, softener, auxiliary agent and defoamer into the rubber main material, and adopting densely or open refining machine mix-refine materials, then through plate vulcanizing machine in conditions of high temperature and high pressure. The preparation method is as follows: firstly, add rubber main material into open refining machine to have low temperature thinly passing plasticization, fully mix-refine all the added ingredient orderly, thinly pass several times, and stop; then have returning refining process, add vulcanizing agent, thinly pass several times, and leave pieces to make into rubber pieces; finally add carried rubber pieces into vulcanizing machine to have pressurizing vulcanization, then we can get the inflation rubber.
Description
Technical field
The present invention relates to a kind of expansion glue and production technology thereof, refer to a kind of expanding glue for spray coating clothing and production method thereof especially.
Background technology
The preparation of traditional expansion glue is many to be the rubber major ingredient with the natural emulsion, powder is ground, add ammonia solvent, and then sneak into glue and stir, park a period of time, the sizing material behind the mixing was put into the mould dipping after one hour, should expansion glue semi-finished product dry or dry, demoulding then after drying once more or drying, can obtain the glue goods that expand.This kind expansion glue is sprayed at clothing when generally being used for clothing, obtain beautiful pattern.
Owing to contain a large amount of ammoniacal liquor in powder solvent and the glue in the expansion glue of this kind prepared, powder and latex send a large amount of ammonia flavors when stirring, and waste material can not be recycled once more, not only cause severe contamination and waste in process of production, the long-term contact of staff also causes very major injury to health; Secondly, traditional expansion glue preparation technology is quite time-consuming, and it is low to produce efficient in enormous quantities; Once more, because the corrosion resistance of latex is poor, therefore easily wears out, break with the expansion glue of latex as the production of rubber major ingredient.
Therefore, provide that a kind of corrosion resistance is strong, preparation technology is simple, expanding glue for spray coating clothing and production technology thereof pollution-free, that waste recovery regeneration rate is high be real in necessary.
Summary of the invention
For overcoming the deficiencies in the prior art, the object of the invention is to provide that a kind of corrosion resistance is strong, preparation technology is simple, pollution-free, expanding glue for spray coating clothing and production technology thereof that waste recovery regeneration rate is high.
The present invention implements by the following technical programs.In the rubber major ingredient, mix batchings such as adding activating agent, softening agent, promoter, filler, reinforcing agent, age resistor, defoamer, vulcanizing agent in regular turn, wherein the rubber major ingredient can be selected natural rubber, chlorinated butyl, EPDM or chlorosulfonated polyethylene for use, and the proportioning of blend glue stuff is listed below:
With the natural rubber is major ingredient, and blend glue stuff component and proportioning are as follows:
Set of dispense composition and division in a proportion (weight portion)
100 parts of natural rubbers
4 parts in sulphur
5 parts of nano zine oxides
2 parts of altaxs
0.2 part of promoter TT
2 parts of antioxidant H S-P11
30 parts in barium sulfate
20 parts of carbon blacks
1 part of stearic acid
10 parts in machine oil
5 parts of defoamers
With the chlorinated butyl is major ingredient, and blend glue stuff component and proportioning are as follows:
Set of dispense composition and division in a proportion (weight portion)
100 parts of chlorinated butyls
1.5 parts in sulphur
7 parts of nano zine oxides
1.5 parts of captaxs
1.5 parts of promoter ZDC
0.5 part of promoter TT
1 part of antioxidant H S-P11
30 parts in barium sulfate
20 parts of carbon blacks
1 part of stearic acid
10 parts of paraffin oils
5 parts of defoamers
With chlorinated butyl and natural rubber is major ingredient, and blend glue stuff component and proportioning are as follows:
Set of dispense composition and division in a proportion (weight portion)
50 parts of chlorinated butyls
50 parts of natural rubbers
2 parts in sulphur
5 parts of nano zine oxides
1 part of captax
1 part of promoter ZDC
0.5 part of promoter TT
1 part in age resistor
30 parts in barium sulfate
20 parts of carbon blacks
0.5 part of stearic acid
10 parts of paraffin oils
3 parts of defoamers
5 parts in calcium oxide
With the EPDM is major ingredient, and blend glue stuff component and proportioning are as follows:
Set of dispense composition and division in a proportion (weight portion)
100 parts of EPDMs
1.5 parts in sulphur
10 parts in zinc oxide
3 parts of promoter EG-3
1 part of antioxidant 4010NA
50 parts in barium sulfate
20 parts of carbon blacks
0.8 part of stearic acid
25 parts of naphthenic oils
3 parts of defoamer RG
With the chlorosulfonated polyethylene is major ingredient, and blend glue stuff component and proportioning are as follows:
Set of dispense composition and division in a proportion (weight portion)
100 parts of chlorosulfonated polyethylenes
5 parts in magnesia
1.5 parts of promoter TRA
1 part of anti-aging agent RD
50 parts in barium sulfate
10 parts of carbon blacks
1 part of stearic acid
15 parts of dibutyl esters
A kind of expanding glue for spray coating clothing of the present invention adopts the vulcanizer preparation, and its production method is as follows:
At first, the rubber major ingredient is put into banbury or mill carry out the low temperature thin-pass and plasticate, it is fully mixing to add each batching in regular turn, and thin-pass is repeatedly parked;
Then, carry out back mixing and handle, add vulcanizing agent, thin-pass repeatedly, slice is made film;
At last, plant sheet and put into the vulcanizer press cure, can make expansion glue.
Compared with prior art, it is the rubber major ingredient that expanding glue for spray coating clothing of the present invention adopts natural rubber, chlorinated butyl, EPDM, chlorosulfonated polyethylene, and it is strong to make the product corrosion resistance through cooperation, is difficult for wearing out, breaking; Adopt vulcanizer to prepare this kind expansion glue, speed is fast, can reclaim after desulfurization for leftover bits and reproduce, and also can add correlative regeneration glue, reduces cost, and is pollution-free, the economic benefit height.
The specific embodiment
Below in conjunction with embodiment the present invention is done further to analyze to describe.
The prescription of expanding glue for spray coating clothing is a major ingredient with rubber, and is mixed with vulcanizing agent, activating agent, softening agent, promoter, filler, age resistor, reinforcing agent, defoamer, adopts banbury or mill mixing material after the vulcanizing press High Temperature High Pressure is made.
What can be used in this prescription that hardness regulates mainly contains reinforcing agent, softening agent, filler, by in prescription, increasing the proportioning of reinforcing agent, softening agent and filler, can improve the hardness of expanding glue for spray coating clothing, otherwise, can reduce the hardness of expanding glue for spray coating clothing, make it comparatively soft.Add suitable proportioning softening agent and can guarantee that also expanding glue for spray coating clothing has enough plasticity.Promoter being used to accelerated the reaction speed of sizing material.
In the present invention, rubber can be selected natural rubber, chlorinated butyl, EPDM, chlorosulfonated polyethylene etc. for use as major ingredient.
Vulcanizing agent is used for the sulfuration of rubber and crosslinked, can select No. 1 vulcanizing agent, No. 2 vulcanizing agents, No. 3 vulcanizing agents, DCP and sulphur etc. for use.
Activating agent can be selected zinc oxide, nano zine oxide, magnesia, lead monoxide, stearic acid, glycerine, diethylene glycol (DEG) etc. for use.
Softening agent can be selected dibutyl ester, dioctyl ester, chlorinated paraffin wax, machine oil, cycloalkanes wet goods for use.
Promoter can be selected altax, captax, promoter EG-3, promoter ZDC, promoter TRA, accelerator CBS, accelerant N A-22, promoter TT, diphenylguanidine etc. for use.
Filler can be selected calcium carbonate, brium carbonate, talcum powder, barium sulfate, calcirm-fluoride, alumina silicate etc. for use.
Reinforcing agent can be selected carbon black, high abrasion carbon black, white carbon black, magnesium carbonate etc. for use.
Age resistor can be selected antioxidant H S-P11, antioxidant 4010NA, antioxidant D, anti-aging agent RD, antioxidant 264 etc. for use.
Defoamer can be calcium oxide, defoamer RG etc.
Below be the available prescription of expanding glue for spray coating clothing of the present invention:
Set of dispense composition and division in a proportion (weight portion)
100 parts of rubber
Vulcanizing agent 1-5 part
Activating agent 2-10 part
Softening agent 5-40 part
Promoter 1-8 part
Filler 5-80 part
Reinforcing agent 5-100 part
Age resistor 0.5-5 part
Defoamer 1-10 part
According to adopting the major ingredient difference, list three kinds of prescriptions that are used to prepare expanding glue for spray coating clothing, wherein, ideal with the expansion glue effect that chlorinated butyl and chlorosulfonated polyethylene are made as the sizing compound formula of major ingredient.
Embodiment 1-is major ingredient with the natural rubber, and blend glue stuff component and proportioning are as follows:
Set of dispense composition and division in a proportion (weight portion)
100 parts of natural rubbers
4 parts in sulphur
5 parts of nano zine oxides
2 parts of altaxs
0.2 part of promoter TT
2 parts of antioxidant H S-P11
30 parts in barium sulfate
20 parts of carbon blacks
1 part of stearic acid
10 parts in machine oil
5 parts of defoamers
Embodiment 2-is major ingredient with the chlorinated butyl, and blend glue stuff component and proportioning are as follows:
Set of dispense composition and division in a proportion (weight portion)
100 parts of chlorinated butyls
1.5 parts in sulphur
7 parts of nano zine oxides
1.5 parts of captaxs
1.5 parts of promoter ZDC
0.5 part of promoter TT
1 part of antioxidant H S-P11
30 parts in barium sulfate
20 parts of carbon blacks
1 part of stearic acid
10 parts of paraffin oils
5 parts of defoamers
Embodiment 3-is a major ingredient with chlorinated butyl and natural rubber, and blend glue stuff component and proportioning are as follows:
Set of dispense composition and division in a proportion (weight portion)
50 parts of chlorinated butyls
50 parts of natural rubbers
2 parts in sulphur
5 parts of nano zine oxides
1 part of captax
1 part of promoter ZDC
0.5 part of promoter TT
1 part in age resistor
30 parts in barium sulfate
20 parts of carbon blacks
0.5 part of stearic acid
10 parts of paraffin oils
3 parts of defoamers
5 parts in calcium oxide
Embodiment 4-is major ingredient with the EPDM, and blend glue stuff component and proportioning are as follows:
Set of dispense composition and division in a proportion (weight portion)
100 parts of EPDMs
1.5 parts in sulphur
10 parts in zinc oxide
3 parts of promoter EG-3
1 part of antioxidant 4010NA
50 parts in barium sulfate
20 parts of carbon blacks
0.8 part of stearic acid
25 parts of naphthenic oils
3 parts of defoamer RG
Embodiment 5-is major ingredient with the chlorosulfonated polyethylene, and blend glue stuff component and proportioning are as follows:
Set of dispense composition and division in a proportion (weight portion)
100 parts of chlorosulfonated polyethylenes
5 parts in magnesia
1.5 parts of promoter TRA
1 part of anti-aging agent RD
50 parts in barium sulfate
10 parts of carbon blacks
1 part of stearic acid
15 parts of dibutyl esters
A kind of expanding glue for spray coating clothing production method of the present invention is as follows:
At first, will carry out weighing after the preliminary treatment of above-mentioned sizing material component materials, the rubber major ingredient is put into banbury or mill carry out the low temperature thin-pass and plasticated about 5 minutes, the roller temperature should not surpass 50 ℃, and thin-pass repeatedly; Then, add batching in the rubber after plasticating in regular turn and carry out mixingly, parked one day after mixing; Then, carry out back mixing and handle, mixing after the adding vulcanizing agent carries out the thin-pass several to the rubber after mixing, and adjust its thickness degree, slice is made film; At last, plant sheet and put into the vulcanizer press cure, can make expansion glue.
Cure time in the production technology of the present invention is fast, general only needs about 5 minutes, and the corner sizing material after the deburring can reclaim once more, carries out desulfurization through desulfurizing agent, repeat above-mentioned explained hereafter again, adopt reclaimed rubber, reach the purpose of materials recycling, reduce cost, rate of recovery height pollutes little.
Above disclosed only is the preferred embodiment of expanding glue for spray coating clothing of the present invention and production technology thereof, certainly can not limit the present invention's interest field with this, therefore the equivalent variations of being done according to the present patent application claim still belongs to the scope that the present invention is contained.
Claims (8)
1. expanding glue for spray coating clothing, in the rubber major ingredient, mix and add vulcanizing agent, oxygen agent, reinforcing agent, promoter, softening agent, filler and defoamer, adopt banbury or mill mixing material after the vulcanizing press High Temperature High Pressure is made, it is characterized in that: the component of described blend glue stuff and proportioning are:
Set of dispense composition and division in a proportion (weight portion)
100 parts of rubber
Vulcanizing agent 1-5 part
Activating agent 2-10 part
Softening agent 5-40 part
Promoter 1-8 part
Filler 5-80 part
Reinforcing agent 5-100 part
Age resistor 0.5-5 part
Defoamer 1-10 part.
2. a kind of expanding glue for spray coating clothing as claimed in claim 1 is characterized in that: described rubber can be selected any in natural rubber, chlorinated butyl, EPDM, the chlorosulfonated polyethylene for use.
3. a kind of expanding glue for spray coating clothing as claimed in claim 2 is characterized in that: the prescription that described rubber major ingredient is a natural rubber is as follows:
Set of dispense composition and division in a proportion (weight portion)
100 parts of natural rubbers
4 parts in sulphur
5 parts of nano zine oxides
2 parts of altaxs
0.2 part of promoter TT
2 parts of antioxidant H S-P11
30 parts in barium sulfate
20 parts of carbon blacks
1 part of stearic acid
10 parts in machine oil
5 parts of defoamers.
4. a kind of expanding glue for spray coating clothing as claimed in claim 2 is characterized in that: the prescription that described rubber major ingredient is a chlorinated butyl is as follows:
Set of dispense composition and division in a proportion (weight portion)
100 parts of chlorinated butyls
1.5 parts in sulphur
7 parts of nano zine oxides
1.5 parts of captaxs
1.5 parts of promoter ZDC
0.5 part of promoter TT
1 part of antioxidant H S-P11
30 parts in barium sulfate
20 parts of carbon blacks
1 part of stearic acid
10 parts of paraffin oils
5 parts of defoamers.
5. a kind of expanding glue for spray coating clothing as claimed in claim 2 is characterized in that: the prescription that described rubber major ingredient is chlorinated butyl and natural rubber is as follows:
Set of dispense composition and division in a proportion (weight portion)
50 parts of chlorinated butyls
50 parts of natural rubbers
2 parts in sulphur
5 parts of nano zine oxides
1 part of captax
1 part of promoter ZDC
0.5 part of promoter TT
1 part in age resistor
30 parts in barium sulfate
20 parts of carbon blacks
0.5 part of stearic acid
10 parts of paraffin oils
3 parts of defoamers
5 parts in calcium oxide.
6. a kind of expanding glue for spray coating clothing as claimed in claim 2 is characterized in that: the prescription that described rubber major ingredient is an EPDM is as follows:
Set of dispense composition and division in a proportion (weight portion)
100 parts of EPDMs
1.5 parts in sulphur
10 parts in zinc oxide
3 parts of promoter EG-3
1 part of antioxidant 4010NA
50 parts in barium sulfate
20 parts of carbon blacks
0.8 part of stearic acid
25 parts of naphthenic oils
3 parts of defoamer RG.
7. a kind of expanding glue for spray coating clothing as claimed in claim 2 is characterized in that: the prescription that described rubber major ingredient is a chlorosulfonated polyethylene is as follows:
Set of dispense composition and division in a proportion (weight portion)
100 parts of chlorosulfonated polyethylenes
5 parts in magnesia
1.5 parts of promoter TRA
1 part of anti-aging agent RD
50 parts in barium sulfate
10 parts of carbon blacks
1 part of stearic acid
15 parts of dibutyl esters.
8. the production method of an expanding glue for spray coating clothing is characterized in that:
At first, the rubber major ingredient is put into banbury or mill carry out the low temperature thin-pass and plasticate, it is fully mixing to add each batching in regular turn, and thin-pass is repeatedly parked;
Then, carry out back mixing and handle, add vulcanizing agent, thin-pass repeatedly, slice is made film;
At last, plant sheet and put into the vulcanizer press cure, can make expansion glue.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB200510033895XA CN100371524C (en) | 2005-04-05 | 2005-04-05 | Expanding glue for spray coating clothing, and producing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB200510033895XA CN100371524C (en) | 2005-04-05 | 2005-04-05 | Expanding glue for spray coating clothing, and producing method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1687515A true CN1687515A (en) | 2005-10-26 |
| CN100371524C CN100371524C (en) | 2008-02-27 |
Family
ID=35305557
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB200510033895XA Expired - Fee Related CN100371524C (en) | 2005-04-05 | 2005-04-05 | Expanding glue for spray coating clothing, and producing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100371524C (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102229714A (en) * | 2011-06-21 | 2011-11-02 | 中潜股份有限公司 | Knee pad rubber and preparation method and application thereof |
| CN101580015B (en) * | 2009-06-04 | 2013-01-30 | 上虞市宝来同步带有限公司 | Automobile synchronous belt and manufacturing method thereof |
| CN105196439A (en) * | 2015-10-16 | 2015-12-30 | 鞍山市宏图防腐工程有限公司 | Reverse mixing technology applied to chlorosulfonated polyethylene rubber and adopting internal mixer |
| CN108568885A (en) * | 2018-05-14 | 2018-09-25 | 湖南工业大学 | A kind of low-density coir fibre amortizing packaging material and preparation method thereof and adhesive |
| CN110330701A (en) * | 2019-07-18 | 2019-10-15 | 成都五一六隔震科技有限公司 | A kind of refining glue formula and processing technology using vulcanizing agent |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1063971A (en) * | 1991-02-08 | 1992-08-26 | 冯克伦 | Fire retardant hermetic collar |
| US6001906A (en) * | 1997-08-04 | 1999-12-14 | Golumbic; Harvey J. | Water based plasticizer free poly urethane-wax coating & repair composition & method |
| CN1237592A (en) * | 1998-05-12 | 1999-12-08 | 罗超华 | Heat-resistant fireproof and oil-resistant rubber material for irradiation cross-linked wire and cable |
-
2005
- 2005-04-05 CN CNB200510033895XA patent/CN100371524C/en not_active Expired - Fee Related
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101580015B (en) * | 2009-06-04 | 2013-01-30 | 上虞市宝来同步带有限公司 | Automobile synchronous belt and manufacturing method thereof |
| CN102229714A (en) * | 2011-06-21 | 2011-11-02 | 中潜股份有限公司 | Knee pad rubber and preparation method and application thereof |
| CN105196439A (en) * | 2015-10-16 | 2015-12-30 | 鞍山市宏图防腐工程有限公司 | Reverse mixing technology applied to chlorosulfonated polyethylene rubber and adopting internal mixer |
| CN108568885A (en) * | 2018-05-14 | 2018-09-25 | 湖南工业大学 | A kind of low-density coir fibre amortizing packaging material and preparation method thereof and adhesive |
| CN110330701A (en) * | 2019-07-18 | 2019-10-15 | 成都五一六隔震科技有限公司 | A kind of refining glue formula and processing technology using vulcanizing agent |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100371524C (en) | 2008-02-27 |
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Granted publication date: 20080227 Termination date: 20100405 |