CN109354320A - Complex biological filter denitrification system - Google Patents

Complex biological filter denitrification system Download PDF

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Publication number
CN109354320A
CN109354320A CN201811435624.0A CN201811435624A CN109354320A CN 109354320 A CN109354320 A CN 109354320A CN 201811435624 A CN201811435624 A CN 201811435624A CN 109354320 A CN109354320 A CN 109354320A
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CN
China
Prior art keywords
complex biological
biological filter
weight
parts
denitrification system
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201811435624.0A
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Chinese (zh)
Inventor
戴翊臣
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Xuzhou Zhonghuan Shourun Environmental Protection Technology Co Ltd
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Xuzhou Zhonghuan Shourun Environmental Protection Technology Co Ltd
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Priority to CN201811435624.0A priority Critical patent/CN109354320A/en
Publication of CN109354320A publication Critical patent/CN109354320A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/50Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/16Nitrogen compounds, e.g. ammonia
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • C02F2101/38Organic compounds containing nitrogen
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/08Multistage treatments, e.g. repetition of the same process step under different conditions
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/12Activated sludge processes
    • C02F3/1236Particular type of activated sludge installations

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)
  • Biological Treatment Of Waste Water (AREA)

Abstract

The invention discloses a kind of complex biological filter denitrification systems, including the complex biological filter, sand filter and clear water reserviors being sequentially communicated, filled with highly in the filtrate of 30 ~ 50cm in the complex biological filter, waterwater entrance is provided with below the filtrate, waste water and the carbon source of external addition enter complex biological filter together, the lower section of the filtrate is also communicated with Aeration fan and anti-gas blower, and the irrigation channel of the sand filter carries out dosing;The irrigation channel of clear water reserviors is added with disinfectant.Present system is suitable for mentioning for sewage plant and marks transformation and advanced treating, and system is to COD and NH3- N removal rate respectively reaches 89.4% and 96.8% or so.

Description

Complex biological filter denitrification system
Technical field
The present invention relates to technical field of sewage to be suitable for more particularly to a kind of complex biological filter denitrification system Sewage plant proposes mark transformation and advanced treating.
Background technique
Currently, including that coking, chemical industry, petrochemical industry, printing and dyeing, papermaking, medicine, pesticide, landfill leachate etc. are difficult to degrade nitrogenous has Machine waste water, though ammonia nitrogen and most of organic matter can be effectively removed, still contains after secondary biochemical treatment in waste water Certain density hardly degraded organic substance, nitrate nitrogen, organic nitrogen and ammonia nitrogen, secondary biochemical effluent biodegradability is very poor, needs to pass through Advanced treating can be only achieved discharge and reuse requirement.
Carrier of the biofilter material as biomembrane, the selection of filtrate are the technology success or not keys of biological aerated filter One, it determines that can waste water treatment system efficient operation.There are COD and NH for existing filtrate3- N removal rate is low, pressure resistance Spend the problems such as low.
Summary of the invention
The purpose of the present invention is to provide a kind of complex biological filter denitrification systems, to overcome deficiency in the prior art.
To achieve the above object, the invention provides the following technical scheme:
The embodiment of the present application discloses a kind of complex biological filter denitrification system, including be sequentially communicated complex biological filter, sand filtration Pond and clear water reserviors,
The filtrate highly in 30 ~ 50cm is filled in the complex biological filter,
Waterwater entrance is provided with below the filtrate, waste water and the external carbon source added enter complex biological filter together,
The lower section of the filtrate is also communicated with Aeration fan and anti-gas blower,
The irrigation channel of the sand filter carries out dosing;
The irrigation channel of clear water reserviors is added with disinfectant.
Preferably, in above-mentioned complex biological filter denitrification system, the carbon source is methanol.
Preferably, in above-mentioned complex biological filter denitrification system, the medicine that the irrigation channel of sand filter adds is sodium acetate.
Preferably, in above-mentioned complex biological filter denitrification system, the disinfectant uses calcium hypochlorite or chlorine.
Preferably, in above-mentioned complex biological filter denitrification system, the filtrate filled in complex biological filter includes:
Recessed native 38 ~ 45 parts by weight;
55 ~ 65 parts by weight of diatomite;
3 ~ 8 parts by weight of flyash;
10 ~ 20 parts by weight of pore creating material.
Preferably, in above-mentioned complex biological filter denitrification system, the pore creating material uses starch.
Preferably, in above-mentioned complex biological filter denitrification system, the filtrate includes recessed native 40 parts by weight, diatomite 58 parts by weight, 5 parts by weight of flyash, 13 parts by weight of starch.
Preferably, in above-mentioned complex biological filter denitrification system, the preparation method of filtrate includes:
(1), by recessed native 38 ~ 45 parts by weight, 55 ~ 65 parts by weight of diatomite, 3 ~ 8 parts by weight of flyash, 10 ~ 20 parts by weight of pore creating material Premixing obtains powder, and water is added and further mixes;
(2), dry pressure formed using half, diameter is obtained in the bead of 10 ~ 13mm;
(3), 1 ~ 4 hour dry under the conditions of 50 ~ 70 DEG C, it is 1 ~ 4 hour dry to then heat to 90 ~ 120 DEG C of conditions;
(4), it is sintered in chamber type electric resistance furnace, then natural cooling.
Preferably, in above-mentioned complex biological filter denitrification system, the mass ratio of powder is 90% ~ 95% in mixture; The molding pressure of half dry pressing is 10MPa or so.
Preferably, in above-mentioned complex biological filter denitrification system, sintering condition meets: being first warming up to 50 DEG C/min 400 DEG C and 10min is kept, then is warming up to 600 DEG C with 20 DEG C/min and keeps 10min, then be warming up to 1000 DEG C with 50 DEG C/min And keep 20min.
Compared with the prior art, the advantages of the present invention are as follows: present system is suitable for mentioning for sewage plant and marks transformation and depth Degree processing, system is to COD and NH3- N removal rate respectively reaches 89.4% and 96.8% or so.
Detailed description of the invention
In order to illustrate the technical solutions in the embodiments of the present application or in the prior art more clearly, to embodiment or will show below There is attached drawing needed in technical description to be briefly described, it should be apparent that, the accompanying drawings in the following description is only this The some embodiments recorded in application, for those of ordinary skill in the art, without creative efforts, It is also possible to obtain other drawings based on these drawings.
Fig. 1 show the schematic illustration of complex biological filter denitrification system in the specific embodiment of the invention.Specific implementation Mode
The present invention is described further by the following example: according to following embodiments, the present invention may be better understood.So And as it will be easily appreciated by one skilled in the art that specific material ratio, process conditions and its result described in embodiment are only used for Illustrate the present invention, without the present invention described in detail in claims should will not be limited.
As shown in connection with fig. 1, the embodiment of the application discloses a kind of complex biological filter denitrification system, including successively connects Logical complex biological filter 1, sand filter 2 and clear water reserviors 3, the interior filtrate 4 being filled with highly in 30 ~ 50cm of complex biological filter 1, It is provided with waterwater entrance 5 below filtrate, the carbon source 6 of waste water and external addition enters complex biological filter 1 together, under filtrate Side is also communicated with Aeration fan 7 and anti-gas blower 8, and the irrigation channel of sand filter 2 carries out dosing 9;The irrigation channel of clear water reserviors 3 adds Added with disinfectant 10.
In a preferred embodiment, carbon source is methanol.The medicine that the irrigation channel of sand filter 2 adds is sodium acetate.Disinfectant is adopted With calcium hypochlorite or chlorine.
In one embodiment, the raw material that filtrate 4 uses includes: recessed soil, 100 mesh;Diatomite, 100 mesh;Flyash, 100 Mesh;Starch.
The preparation of filtrate 4 includes: by recessed native 40 parts by weight, 58 parts by weight of diatomite, 5 parts by weight of flyash, 13 weight of starch It measures part premixing and obtains powder, water is added and further mixes, the mass ratio of powder is 90% in mixture.Using half dry pressing Molding, molding pressure are 10MPa or so, obtain diameter in the bead of 10mm or so;It is 2 hours dry under the conditions of 60 DEG C, so After to be warming up to 120 DEG C or so conditions 2 hours dry;It is sintered in chamber type electric resistance furnace, is first warming up to 400 DEG C with 50 DEG C/min And 10min is kept, then be warming up to 600 DEG C with 20 DEG C/min and keep 10min, then be warming up to 1000 DEG C with 50 DEG C/min and keep 20min, then natural cooling.
The compound bio filtrate of preparation is put into the system of Fig. 1, filtrate packed height is about 50cm.Waste water is injected, Activated sludge is added, sludge concentration is controlled in 1700mg/L or so.Air pump is opened, adjusting gas flow makes dissolved oxygen (DO) It is mature to filtrate surface biological film for 3mg/L or so, COD and NH3- N removal rate respectively reaches 89.4% and 96.8% left side It is right.
Here, it should also be noted that, in order to avoid having obscured the present invention because of unnecessary details, in the accompanying drawings only Show with closely related structure and/or processing step according to the solution of the present invention, and be omitted little with relationship of the present invention Other details.
Finally, it is to be noted that, the terms "include", "comprise" or its any other variant be intended to it is non-exclusive Property include so that include a series of elements process, method, article or equipment not only include those elements, but also Further include other elements that are not explicitly listed, or further include for this process, method, article or equipment it is intrinsic Element.

Claims (10)

1. a kind of complex biological filter denitrification system, which is characterized in that including be sequentially communicated complex biological filter, sand filter and Clear water reserviors;Filled with highly in the filtrate of 30 ~ 50cm in the complex biological filter;Waste water is provided with below the filtrate to enter Mouthful, the carbon source of waste water and external addition enters complex biological filter together;The lower section of the filtrate be also communicated with Aeration fan and Anti- gas blower;The irrigation channel of the sand filter carries out dosing;The irrigation channel of clear water reserviors is added with disinfectant.
2. complex biological filter denitrification system according to claim 1, which is characterized in that the carbon source is methanol.
3. complex biological filter denitrification system according to claim 1, which is characterized in that the irrigation channel of sand filter added Medicine is sodium acetate.
4. complex biological filter denitrification system according to claim 1, which is characterized in that the disinfectant uses hypochlorous acid Calcium or chlorine.
5. complex biological filter denitrification system according to claim 1, which is characterized in that filled in complex biological filter Filtrate includes:
Recessed native 38 ~ 45 parts by weight;
55 ~ 65 parts by weight of diatomite;
3 ~ 8 parts by weight of flyash;
10 ~ 20 parts by weight of pore creating material.
6. complex biological filter denitrification system according to claim 5, which is characterized in that the pore creating material uses starch.
7. complex biological filter denitrification system according to claim 5, which is characterized in that the filtrate includes recessed native 40 weight Measure part, 58 parts by weight of diatomite, 5 parts by weight of flyash, 13 parts by weight of starch.
8. complex biological filter denitrification system according to claim 5, which is characterized in that the preparation method of filtrate includes:
(1), by recessed native 38 ~ 45 parts by weight, 55 ~ 65 parts by weight of diatomite, 3 ~ 8 parts by weight of flyash, 10 ~ 20 parts by weight of pore creating material Premixing obtains powder, and water is added and further mixes;
(2), dry pressure formed using half, diameter is obtained in the bead of 10 ~ 13mm;
(3), 1 ~ 4 hour dry under the conditions of 50 ~ 70 DEG C, it is 1 ~ 4 hour dry to then heat to 90 ~ 120 DEG C of conditions;
(4), it is sintered in chamber type electric resistance furnace, then natural cooling.
9. complex biological filter denitrification system according to claim 8, which is characterized in that the mass ratio of powder in mixture It is 90% ~ 95%;The molding pressure of half dry pressing is 10MPa or so.
10. complex biological filter denitrification system according to claim 8, which is characterized in that sintering condition meets: first with 50 DEG C/min is warming up to 400 DEG C and keeps 10min, then be warming up to 600 DEG C with 20 DEG C/min and keep 10min, then with 50 DEG C/min It is warming up to 1000 DEG C and keeps 20min.
CN201811435624.0A 2018-11-28 2018-11-28 Complex biological filter denitrification system Withdrawn CN109354320A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811435624.0A CN109354320A (en) 2018-11-28 2018-11-28 Complex biological filter denitrification system

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811435624.0A CN109354320A (en) 2018-11-28 2018-11-28 Complex biological filter denitrification system

Publications (1)

Publication Number Publication Date
CN109354320A true CN109354320A (en) 2019-02-19

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11851356B2 (en) 2020-01-06 2023-12-26 The Research Foundation For The State University Of New York Bioreactor system and method for nitrification and denitrification

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11851356B2 (en) 2020-01-06 2023-12-26 The Research Foundation For The State University Of New York Bioreactor system and method for nitrification and denitrification

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Application publication date: 20190219