CN109338275A - A kind of middle-size and small-size cylinder body carburizing multistage quenching technical of 18CrNiMo7-6 steel - Google Patents

A kind of middle-size and small-size cylinder body carburizing multistage quenching technical of 18CrNiMo7-6 steel Download PDF

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Publication number
CN109338275A
CN109338275A CN201811327857.9A CN201811327857A CN109338275A CN 109338275 A CN109338275 A CN 109338275A CN 201811327857 A CN201811327857 A CN 201811327857A CN 109338275 A CN109338275 A CN 109338275A
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carburizing
cylinder body
small
18crnimo7
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张林建
施纵横
顾晓明
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Changzhou Tianshan Heavy Industry Machinery Co Ltd
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Changzhou Tianshan Heavy Industry Machinery Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/06Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
    • C23C8/08Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases only one element being applied
    • C23C8/20Carburising
    • C23C8/22Carburising of ferrous surfaces
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18Hardening; Quenching with or without subsequent tempering
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/56General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering characterised by the quenching agents
    • C21D1/607Molten salts
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/0068Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for particular articles not mentioned below
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Heat Treatment Of Articles (AREA)

Abstract

The present invention relates to heat treatment operation technical field, especially a kind of middle-size and small-size cylinder body carburizing multistage quenching technical of 18CrNiMo7-6 steel successively carries out " carburizing-high tempering-quenching-lonneal " to the middle-size and small-size cylinder body of 18CrNiMo7-6 steel;Wherein, carburizing process first uses stage heating mode, i.e. " preheating-samming-heating-samming-heating ", then seeps 30h by force, and strong carburizing potential 1.15% spreads 20h, spreads carbon potential 0.75%;Quenching process is using multistage quenching.This process optimization temperature, carbon potential and soaking time in cylinder body carburizing each stage, realizes better carburizing effect.It is quenched using multistage, possesses good thermal stability and chemical stability;Occupied area is small, high recycling rate, and pollution is small, is more suitble to big part or batch production;The deflection of workpiece can greatly be reduced, eliminate workpiece residual stress, improve plasticity and toughness and workpiece strength, strong operability provides biggish adjustment space by the regulation of hardening heat and mixing speed for quenching.

Description

A kind of middle-size and small-size cylinder body carburizing multistage quenching technical of 18CrNiMo7-6 steel
Technical field
The present invention relates to heat treatment operation technical field, specific field is a kind of cylinder body entirety carburizing and quenching work Skill.
Background technique
Currently, existing cylinder body entirety carburizing and quenching has the following problems:
(1) infiltration layer is uneven, and carburizing and quenching effect is undesirable, and cylinder body class workpiece is due to requiring whole carburizing, by itself The limitation of Workpiece structure and itself material, carburizing process poor controllability cause infiltration layer uneven, and harden ability is poor, and quenching effect is not It is ideal.
(2) easily-deformable, cylinder body class workpiece entirety carburizing and quenching is being seeped because its volume is big, density is high, workpiece thickness is different In carbon quenching process, it is easy to influence the heating and cooling rate of workpiece, deflection is caused to increase.
Summary of the invention
The purpose of the present invention is to provide a kind of middle-size and small-size cylinder body carburizing multistage quenching technicals of 18CrNiMo7-6 steel, lead to Change common cylinder body material at present is crossed, optimizes heat treatment process, solves the main problem of current cylinder body entirety carburizing and quenching: One, infiltration layer is uneven, and cylinder body class workpiece usually requires that whole carburizing and quenching, is limited to material-structure influence, carburizing and quenching effect It is not easy to control;Two, easily-deformable, cylinder body class workpiece volume itself is big, and density is high, and thickness great disparity causes uneven heating even, deflection Greatly.
To achieve the above object, the invention provides the following technical scheme:
A kind of middle-size and small-size cylinder body carburizing multistage quenching technical of 18CrNiMo7-6 steel, it is middle-size and small-size to 18CrNiMo7-6 steel Cylinder body successively carries out " carburizing-high tempering-quenching-lonneal ";Wherein, carburizing process first uses stage heating mode, That is " preheating-samming-heating-samming-heating " then seeps by force 30h, and strong carburizing potential 1.15% spreads 20h, spreads carbon potential 0.75%;Quenching process is followed successively by salt bath, air-cooled and water cooling using multistage quenching.
The middle-size and small-size cylinder body carburizing multistage quenching technical of 18CrNiMo7-6 steel of the present invention, wherein the carburizing For journey in stage heating, first time samming temperature is 650 DEG C, time 60min;Second of samming temperature is 800 DEG C, the time For 60min;Strong seep with the temperature of diffusion process is 930 DEG C.
The middle-size and small-size cylinder body carburizing multistage quenching technical of 18CrNiMo7-6 steel of the present invention, wherein first furnace after diffusion It is cooled to 820 DEG C, keeps samming 60min;Then slow cooling is come out of the stove to 350 DEG C, air-cooled.
The middle-size and small-size cylinder body carburizing multistage quenching technical of 18CrNiMo7-6 steel of the present invention, wherein when carburizing, have Effect hardened-depth is 2.8-3.2mm.
The middle-size and small-size cylinder body carburizing multistage quenching technical of 18CrNiMo7-6 steel of the present invention, wherein high tempering Temperature is 660 DEG C, send nitrogen to be tempered, flow 10m3/ h, time 180min;Then it is cooled to 400 DEG C fastly, comes out of the stove, it is air-cooled.
The middle-size and small-size cylinder body carburizing multistage quenching technical of 18CrNiMo7-6 steel of the present invention, wherein the salt bath is adopted It is 55% sodium nitrite and 45% potassium nitrate with quality accounting.
The middle-size and small-size cylinder body carburizing multistage quenching technical of 18CrNiMo7-6 steel of the present invention, wherein when quenching, first 650 DEG C, samming 120min are preheated to, then heats to 830 DEG C, keeps 240min;Then enter salt bath, 170 DEG C of salt temperature, when Between be 60min.
The middle-size and small-size cylinder body carburizing multistage quenching technical of 18CrNiMo7-6 steel of the present invention, wherein when salt bath, stir Motor play 5min up and down is mixed, 40min is stirred fastly, stirs 20min slowly;Wherein, upper and lower play is carried out simultaneously with stirring fastly.
The middle-size and small-size cylinder body carburizing multistage quenching technical of 18CrNiMo7-6 steel of the present invention, wherein go out after salt bath Furnace, air-cooled to 100 DEG C are washed to 40 DEG C of end face, upper and lower play 2min into 40 DEG C of sinks.
The middle-size and small-size cylinder body carburizing multistage quenching technical of 18CrNiMo7-6 steel of the present invention, wherein lonneal Temperature is 160 DEG C, and then time 600min comes out of the stove, air-cooled.
Compared with prior art, the beneficial effects of the present invention are:
(1) present invention employs 18CrNiMo7-6 to replace common 20CrMo cylinder block material, compared to 20CrMo, The essential element content of 18CrNiMo7-6: C:0.150-0.210%, Cr:0.155-0.180%, Ni:1.40-1.70% are A kind of Germany's production domesticization low-carbon alloy steel, has high-intensitive, high tenacity and high-hardenability.Its Ms point is 400 DEG C or so, Ac1: 740 DEG C, Ac3: 820 DEG C, when workpiece carbonization rear surface concentration of carbon reaches 0.7% or so, Ms is 120 DEG C or so, can be in 160- The transformation of core tissue is realized in salt bath quenching within the scope of 180 DEG C, realizes transformation of the overcooling austenite to martensite in the air-cooled stage, The control of retained austenite is realized in water cooling stage.
(2) present invention optimizes the temperature in cylinder body carburizing each stage, carbon potential and soaking times, realize better carburizing effect Fruit.
(3) present invention replaces common oil bath to quench using multistage quenching (salt bath+air-cooled+water cooling), compared to oil bath Quenching, multistage quenching possess good thermal stability and chemical stability, recycling rate of waterused by the combination of a variety of hardening medias Height pollutes the workpiece of small, combination diversity, the suitable biggish part of volume or mass production;Workpiece can greatly be reduced Deflection, eliminate workpiece residual stress, improve plasticity and toughness and workpiece strength, strong operability, while being situated between according to multistage quenching The difference of matter cooling characteristics provides biggish adjustment space by the regulation of hardening heat and mixing speed for quenching.
Detailed description of the invention
Fig. 1 is " carburizing-high tempering " process curve during the cylinder body carburizing and quenching of present invention process;
Fig. 2 is " quenching-lonneal " process curve during the cylinder body carburizing and quenching of present invention process;
Fig. 3 is the surface layer metallographic structure (20 μm) for the cylinder body that present invention process obtains;
Fig. 4 is the core metallographic structure (20 μm) for the cylinder body that present invention process obtains;
Fig. 5 is the hardness gradient curve for the cylinder body that present invention process obtains.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other Embodiment shall fall within the protection scope of the present invention.
The present invention provides a kind of technical solution referring to FIG. 1-2:
A kind of middle-size and small-size cylinder body carburizing multistage quenching technical of 18CrNiMo7-6 steel, it is middle-size and small-size to 18CrNiMo7-6 steel Cylinder body successively carries out " carburizing-high tempering-quenching-lonneal ".
Wherein, carburizing process first uses stage heating mode, i.e. " preheating-samming-heating-samming-heating ", for the first time Samming temperature is 650 DEG C, time 60min;Second of samming temperature is 800 DEG C, time 60min;It can using samming twice Greatly reduce workpiece deflection;And found by many experiments, if being adjusted to other samming temperature parameters, will easily cause The effect of deflection out of hand, or even increase deformation.So that workpiece heating is more uniform, be conducive to the control of deformation.Then Strong to seep 30h, strong carburizing potential 1.15% spreads 20h, spreads carbon potential 0.75%, not only can guarantee effective hardened-depth, but also can keep away Exempt from the appearance of carbide surface;Grope to find by many experiments, if improving carburizing time, carbon potential on this basis, can lead Cause layer depth beyond requirement, carbide accumulation;And reduce carburizing time, carbon potential, it will cause layer depth insufficient, reduce carburizing efficiency. Under this technological parameter, when carburizing, the Available Hardened Depth 2.8-3.2mm, strong seep with the temperature of diffusion process is 930 DEG C.
It is first furnace-cooled to 820 DEG C after diffusion, keeps samming 60min;Then slow cooling is come out of the stove to 350 DEG C, air-cooled.
Wherein, the temperature of high tempering is 660 DEG C, send nitrogen to be tempered, flow 10m3/ h, time 180min;Then It is cooled to 400 DEG C fastly, comes out of the stove, it is air-cooled.
Quenching process is followed successively by salt bath, air-cooled and water cooling using multistage quenching.Salt bath use quality accounting for 55% Asia Sodium nitrate and 45% potassium nitrate, grope to find by many experiments, if using other ratios instead, will seriously affect hardening media Cooling rate, and too fast cooling rate will lead to workpiece cracking, be unfavorable for the conversion of tissue slowly excessively.When quenching, first preheat To 650 DEG C, samming 120min, 830 DEG C are then heated to, keeps 240min;Then enter salt bath, 170 DEG C of salt temperature, the time is 60min the experiment has found that such as adjust preheating temperature on the basis of this technological parameter, the time will be unfavorable for control deformation, adjustment samming Temperature, that the time will lead to quenching process tissue austenitizing is incomplete, using the temperature of this technique salt bath, time, Ke Yishi The abundant transformation of quenching structure inside and outside existing multistage quenching control workpiece.When salt bath, play 5min, is stirred fastly above and below stirring motor 40min stirs 20min slowly;Wherein, upper and lower play is carried out simultaneously with stirring fastly.It comes out of the stove after salt bath, air-cooled to 100 DEG C, into 40 DEG C of water Slot is washed to 40 DEG C of end face, upper and lower play 2min;Multistage quenching may be implemented using different temperature gradients, control inside and outside workpiece The abundant transformation of quenching structure.By the way of multistage quenching, the cylinder body of 18CrNiMo7-6 material can be made to obtain better core And textura epidermoidea.
Wherein, the temperature of lonneal is 160 DEG C, and then time 600min comes out of the stove, air-cooled.
In entire technical process, by the analysis detection with furnace sample, to monitor the effective hardness layer hardness ladder of workpiece Distribution, surface hardness and the core hardness of degree and metallographic structure.
(1) tissue
Textura epidermoidea is that fine acicular martensite, retained austenite and granular carbide form, as shown in Figure 3.
Core set is woven to lath martensite and ferrite composition free on a small quantity, as shown in Figure 4.
Core and textura epidermoidea are all satisfied the organizational requirements of the ME grade of ISO6336-5-2016.
(2) hardness gradient
With furnace sample interval 120 ° of selections, 3 positions, sample the Available Hardened Depth is detected, three positions are corresponding effectively Hardened-depth and the distribution of corresponding hardness gradient are as shown in Figure 5:
Layer depth are as follows: 3.04mm, 3.05mm, 3.07mm meet technique the Available Hardened Depth requirement.
(3) it deforms
The single weight of cylinder body is larger, individually about 800kg, and thickness great disparity, by the rank that preheating insulation is added in process Section reduces its rate of heat addition, reduces workpiece caused by uneven heating and deforms.Cylinder body heat-treatment distortion is mainly with cylinder inner bore ellipse Spending is main monitoring point, and under different technology conditions, the comparison of cylinder inner bore ovality is as shown in table 1:
The comparison of 1 inner hole ovality of table
Technique Oil quenching is not preheated Preheat oil quenching Preheating multistage quenching of the present invention
Cylinder inner bore ovality/‰ 0.9-1.3 0.6-1.0 0.3-0.7
Never the comparison for preheating oil quenching, preheating oil quenching and preheating multistage quenching rear-bank rotor housing inner hole ovality can be seen that cylinder Body heat treated deformation be effectively improved, realize the optimization aim of technique, the deformation after reducing heat treatment of workpieces Amount.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding And modification, the scope of the present invention is defined by the appended.

Claims (10)

1. a kind of middle-size and small-size cylinder body carburizing multistage quenching technical of 18CrNiMo7-6 steel, it is characterised in that: to 18CrNiMo7-6 The middle-size and small-size cylinder body of steel successively carries out " carburizing-high tempering-quenching-lonneal ";Wherein, carburizing process first uses stage Heating mode, i.e. " preheating-samming-heating-samming-heating ", then seep by force 30h, and strong carburizing potential 1.15% spreads 20h, diffusion Carbon potential 0.75%;Quenching process is followed successively by salt bath, air-cooled and water cooling using multistage quenching.
2. the middle-size and small-size cylinder body carburizing multistage quenching technical of 18CrNiMo7-6 steel according to claim 1, feature exist In: for the carburizing process in stage heating, first time samming temperature is 650 DEG C, time 60min;Second of samming temperature Degree is 800 DEG C, time 60min;Strong seep with the temperature of diffusion process is 930 DEG C.
3. the middle-size and small-size cylinder body carburizing multistage quenching technical of 18CrNiMo7-6 steel according to claim 1, feature exist In: it is first furnace-cooled to 820 DEG C after diffusion, keeps samming 60min;Then slow cooling is come out of the stove to 350 DEG C, air-cooled.
4. the middle-size and small-size cylinder body carburizing multistage quenching technical of 18CrNiMo7-6 steel according to claim 1, feature exist In: when carburizing, the Available Hardened Depth 2.8-3.2mm.
5. the middle-size and small-size cylinder body carburizing multistage quenching technical of 18CrNiMo7-6 steel according to claim 1, feature exist In: the temperature of high tempering is 660 DEG C, send nitrogen to be tempered, flow 10m3/ h, time 180min;Then it is cooled to 400 fastly DEG C, it comes out of the stove, it is air-cooled.
6. the middle-size and small-size cylinder body carburizing multistage quenching technical of 18CrNiMo7-6 steel according to claim 1, feature exist In: the salt bath uses quality accounting for 55% sodium nitrite and 45% potassium nitrate.
7. the middle-size and small-size cylinder body carburizing multistage quenching technical of 18CrNiMo7-6 steel according to claim 1, feature exist In: when quenching, 650 DEG C, samming 120min are first preheated to, then heats to 830 DEG C, keeps 240min;Then enter salt bath, salt bath 170 DEG C of temperature, time 60min.
8. the middle-size and small-size cylinder body carburizing multistage quenching technical of 18CrNiMo7-6 steel according to claim 1, feature exist In: when salt bath, play 5min, stirs 40min fastly, stirs 20min slowly above and below stirring motor;Wherein, upper and lower play and stir fastly simultaneously into Row.
9. the middle-size and small-size cylinder body carburizing multistage quenching technical of 18CrNiMo7-6 steel according to claim 1, feature exist In: it comes out of the stove after salt bath, air-cooled to 100 DEG C, is washed to 40 DEG C of end face, upper and lower play 2min into 40 DEG C of sinks.
10. the middle-size and small-size cylinder body carburizing multistage quenching technical of 18CrNiMo7-6 steel according to claim 1, feature exist In: the temperature of lonneal is 160 DEG C, and then time 600min comes out of the stove, air-cooled.
CN201811327857.9A 2018-11-09 2018-11-09 A kind of middle-size and small-size cylinder body carburizing multistage quenching technical of 18CrNiMo7-6 steel Pending CN109338275A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110343994A (en) * 2019-08-08 2019-10-18 常州天山重工机械有限公司 A kind of micro- aberration control method of flywheel ring gear carburizing and quenching
CN110484858A (en) * 2019-08-29 2019-11-22 汉德车桥(株洲)齿轮有限公司 A method of eliminating pinion steel mixed crystal
CN113549866A (en) * 2021-07-22 2021-10-26 湖南南方宇航高精传动有限公司 Carburizing and quenching process for planet wheel of gear box roller path of wind generating set
CN114774837A (en) * 2022-04-28 2022-07-22 南京高精齿轮集团有限公司 Carburizing and quenching process

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CN102776471A (en) * 2012-07-10 2012-11-14 镇江中船设备有限公司 Carburizing quenching technology for low-carbon alloy steel parts
CN105483603A (en) * 2015-12-10 2016-04-13 常州天山重工机械有限公司 Thermal treatment process for hardness gradient of shallow deep carburized gear
CN108220578A (en) * 2017-12-22 2018-06-29 常州天山重工机械有限公司 The judgment method of large-scale 18CrNiMo7-6 gear wheel carburizations part salt bath quenching time

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102776471A (en) * 2012-07-10 2012-11-14 镇江中船设备有限公司 Carburizing quenching technology for low-carbon alloy steel parts
CN105483603A (en) * 2015-12-10 2016-04-13 常州天山重工机械有限公司 Thermal treatment process for hardness gradient of shallow deep carburized gear
CN108220578A (en) * 2017-12-22 2018-06-29 常州天山重工机械有限公司 The judgment method of large-scale 18CrNiMo7-6 gear wheel carburizations part salt bath quenching time

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110343994A (en) * 2019-08-08 2019-10-18 常州天山重工机械有限公司 A kind of micro- aberration control method of flywheel ring gear carburizing and quenching
CN110343994B (en) * 2019-08-08 2022-01-11 常州天山重工机械有限公司 Carburizing and quenching micro-distortion control method for flywheel gear ring
CN110484858A (en) * 2019-08-29 2019-11-22 汉德车桥(株洲)齿轮有限公司 A method of eliminating pinion steel mixed crystal
CN110484858B (en) * 2019-08-29 2021-08-20 汉德车桥(株洲)齿轮有限公司 Method for eliminating mixed crystal of gear steel
CN113549866A (en) * 2021-07-22 2021-10-26 湖南南方宇航高精传动有限公司 Carburizing and quenching process for planet wheel of gear box roller path of wind generating set
CN113549866B (en) * 2021-07-22 2023-04-14 湖南南方宇航高精传动有限公司 Carburizing and quenching process for planet wheel of gear box roller path of wind generating set
CN114774837A (en) * 2022-04-28 2022-07-22 南京高精齿轮集团有限公司 Carburizing and quenching process

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Application publication date: 20190215