CN109336565A - A kind of preparation method of Zirconia reinforced alumina wear-resistant ceramic - Google Patents
A kind of preparation method of Zirconia reinforced alumina wear-resistant ceramic Download PDFInfo
- Publication number
- CN109336565A CN109336565A CN201811580397.0A CN201811580397A CN109336565A CN 109336565 A CN109336565 A CN 109336565A CN 201811580397 A CN201811580397 A CN 201811580397A CN 109336565 A CN109336565 A CN 109336565A
- Authority
- CN
- China
- Prior art keywords
- preparation
- content
- resistant ceramic
- reinforced alumina
- zirconia reinforced
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 title claims abstract description 49
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 title claims abstract description 39
- 239000000919 ceramic Substances 0.000 title claims abstract description 35
- 238000002360 preparation method Methods 0.000 title claims abstract description 21
- 238000005245 sintering Methods 0.000 claims abstract description 22
- 229910019064 Mg-Si Inorganic materials 0.000 claims abstract description 9
- 229910019406 Mg—Si Inorganic materials 0.000 claims abstract description 9
- 238000000498 ball milling Methods 0.000 claims abstract description 9
- 239000000843 powder Substances 0.000 claims abstract description 9
- 238000003825 pressing Methods 0.000 claims abstract description 8
- 239000003595 mist Substances 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- 238000005453 pelletization Methods 0.000 claims abstract description 5
- 238000000462 isostatic pressing Methods 0.000 claims abstract description 4
- 239000004576 sand Substances 0.000 claims abstract description 4
- 239000004615 ingredient Substances 0.000 claims abstract description 3
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 14
- 239000000463 material Substances 0.000 claims description 8
- 229910017970 MgO-SiO2 Inorganic materials 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 229910052727 yttrium Inorganic materials 0.000 claims description 4
- 230000002457 bidirectional effect Effects 0.000 claims description 3
- 238000009826 distribution Methods 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 238000001694 spray drying Methods 0.000 claims description 3
- 229910052681 coesite Inorganic materials 0.000 claims description 2
- 229910052906 cristobalite Inorganic materials 0.000 claims description 2
- 238000000465 moulding Methods 0.000 claims description 2
- 239000004014 plasticizer Substances 0.000 claims description 2
- 239000012744 reinforcing agent Substances 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 239000002002 slurry Substances 0.000 claims description 2
- 229910052682 stishovite Inorganic materials 0.000 claims description 2
- 229910052905 tridymite Inorganic materials 0.000 claims description 2
- 230000008901 benefit Effects 0.000 abstract description 6
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- 239000002131 composite material Substances 0.000 abstract description 3
- 238000010304 firing Methods 0.000 abstract description 3
- -1 ball milling Substances 0.000 abstract 1
- 238000003801 milling Methods 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 230000000087 stabilizing effect Effects 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 7
- 229910001928 zirconium oxide Inorganic materials 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 239000012071 phase Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 229910052573 porcelain Inorganic materials 0.000 description 4
- 230000007423 decrease Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 2
- 229910010293 ceramic material Inorganic materials 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 239000002105 nanoparticle Substances 0.000 description 2
- 238000005488 sandblasting Methods 0.000 description 2
- 229910001018 Cast iron Inorganic materials 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 241001269238 Data Species 0.000 description 1
- 241000406668 Loxodonta cyclotis Species 0.000 description 1
- 229910000617 Mangalloy Inorganic materials 0.000 description 1
- 208000037656 Respiratory Sounds Diseases 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 238000000975 co-precipitation Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000007656 fracture toughness test Methods 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 239000002114 nanocomposite Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000005036 potential barrier Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/10—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on aluminium oxide
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
- C04B2235/3206—Magnesium oxides or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
- C04B2235/3208—Calcium oxide or oxide-forming salts thereof, e.g. lime
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
- C04B2235/3232—Titanium oxides or titanates, e.g. rutile or anatase
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
- C04B2235/3244—Zirconium oxides, zirconates, hafnium oxides, hafnates, or oxide-forming salts thereof
- C04B2235/3246—Stabilised zirconias, e.g. YSZ or cerium stabilised zirconia
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3418—Silicon oxide, silicic acids or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/74—Physical characteristics
- C04B2235/77—Density
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
Abstract
The present invention relates to a kind of preparation methods of Zirconia reinforced alumina wear-resistant ceramic, it is the following steps are included: raw material preparation, ingredient, ball milling, sand milling, mist projection granulating, dry-pressing formed, isostatic pressing, firing；The present invention is to add TiO with alpha-aluminium oxide powder and 3molY stabilizing zirconia primary raw material2It with Ca-Mg-Si system sintering aid, through ball milling, is sanded to regulation fineness, mist projection granulating prepares ZTA pelletizing after mixing, the ZTA composite ceramics being prepared through dry-pressing-isostatic pressing, sintering；The present invention has the advantages that toughness is strong, wearability is high, low manufacture cost.
Description
Technical field
The present invention relates to wear-resistant ceramic technical fields, and in particular to a kind of preparation of Zirconia reinforced alumina wear-resistant ceramic
Method.
Background technique
Mining, metallurgy industry raw material transmission process in, equipment liner, feed bin, elephant trunk liner etc. to wearability require compared with
It is high.Aluminium oxide ceramics has the characteristics that density is big, hardness is high, wear-resistant, and wearability is 10 times of manganese steel, the 8 of rich chromium cast iron
Times.For these reasons, the application impetus of wear-resisting alumina ceramic is continuously increased, and is had become and is most widely used in the world
One of wear-resistant material.But in actual condition, the replacement cycle at HI high impact position is not still able to satisfy production, still restricts entire
The service life of producing line.
The hardness and fracture toughness of ceramic material are to influence the key factor of its wear rate, have high rigidity and fracture toughness
Ceramic material wear rate it is lower.Zirconium oxide mutually can be used to carry out reinforced alumina ceramic as a kind of most common toughening, make
Standby Zirconia reinforced alumina (ZTA) wear-resistant ceramic hardness and fracture toughness can have biggish promotion, so that it is resistance to improve its
Mill property.
The preparation method of ZTA ceramics is chemical coprecipitation.There are production costs excessively high, environmental pollution, complex process etc.
Disadvantage is applied obviously unrealistic in wear-resistant ceramic industry；Therefore it provides a kind of toughness is strong, wearability is high, low manufacture cost
The preparation method of Zirconia reinforced alumina wear-resistant ceramic is necessary.
Summary of the invention
The purpose of the invention is to overcome the deficiencies in the prior art, and provide that a kind of toughness is strong, wearability is high, is fabricated to
The preparation method of this low Zirconia reinforced alumina wear-resistant ceramic.
The object of the present invention is achieved like this: a kind of preparation method of Zirconia reinforced alumina wear-resistant ceramic, it is wrapped
Include following steps:
(1) nano zirconium dioxide raw material preparation: is stablized as main material, TiO using alpha-aluminium oxide powder, 3mol yttrium2And Ca-Mg-Si
Sintering aid does in system；
(2) it ingredient: by the raw material of above-mentioned preparation using water as decentralized medium, is mixed according to the ratio that solid content is 60%；
(3) ball milling: the mixture prepared, water, abrading-ball are added in ball grinder according to a certain percentage, and ball grinder is placed on ball milling
On machine, D50 is milled to less than 5 μm；
(4) it is sanded: the mixture slurry after the completion of ball milling being sanded using sand mill, be sanded to precision prescribed D97 less than 1 μ
M adds plasticizer and reinforcing agent；
(5) mist projection granulating: carrying out mist projection granulating in spray drying tower, obtains the pelletizing of normal distribution, wherein 40 mesh are to 100
80% for being granulated powder content and being greater than total amount between mesh, moisture content is less than 1%；
(6) dry-pressing formed: pelletizing obtained above progress is dry-pressing formed, it is pressurizeed using bidirectional hydraulic press, molding pressure
It is by force 30-40MPa；
(7) isostatic pressing: improving green density, under conditions of 200Mpa, continues 3-5min；
(8) be burnt into: 1500-1520 DEG C at a temperature of be burnt into, keep the temperature 2-5h.
It is 80:20, TiO that alpha-aluminium oxide powder and 3mol yttrium, which stablize the mass ratio of nano zirconium dioxide, in step (1)2Content
For 0.1-0.5wt%, the content of Ca-Mg-Si is 0.5-1wt%.
Ca-Mg-Si selects CaO-MgO-SiO2, CaO-MgO-SiO2The content of middle CaO is 18%-24%, and the content of MgO is
32%-40%, SiO2Content be 36%-45%.
Beneficial effects of the present invention: 1, crystal grain refinement, the crystalline substance of strict control matrix (aluminium oxide) and disperse phase (zirconium oxide)
Particle size, making zirconium oxide, more uniformly disperse has better toughening effect between aluminium oxide.
2, using dry-pressing-equal pressing forming technology, green volume density is improved, higher green volume density is conducive to produce
The sintering of product reduces the porosity of firing porcelain block.
3, TiO is added2And CaO-MgO-SiO2It is sintering aid, sintering temperature is effectively reduced；The present invention have toughness it is strong,
The advantages of wearability height, low manufacture cost.
Detailed description of the invention
Fig. 1 is the preparation method knot fracture toughness test figure of Zirconia reinforced alumina wear-resistant ceramic of the present invention.
Fig. 2 is the preparation method hardness test figure of Zirconia reinforced alumina wear-resistant ceramic of the present invention.
Fig. 3 is the preparation method relative density test chart of Zirconia reinforced alumina wear-resistant ceramic of the present invention.
Specific embodiment
Following further describes the present invention with reference to the drawings.
Embodiment 1
The preparation method of Zirconia reinforced alumina wear-resistant ceramic takes alpha-aluminium oxide powder and 3mol yttrium to stablize nano zirconium dioxide not
Same proportion, taking the two proportion respectively is the sample of 90:10,80:20,70:30,60:40, wherein TiO2It is done with Ca-Mg-Si system
Sintering aid, and by above-mentioned sample respectively using water as decentralized medium, it is mixed according to the ratio that solid content is 60%, and according to this hair
Bright preparation method prepares 4 kinds of different ZTA ceramics respectively, and 90:10 is denoted as A, and so on be denoted as B, C, D respectively, obtain
Its ceramic hardness of A, B, C, D4 kind ZTA arrived and toughness are as illustrated in fig. 1 and 2, and wherein the test of toughness is surveyed using single side notched beam
Method for testing, wearability are 45 ° of sandblasting test methods, and ball milling uses 5 tons of horizontal ball mills；It is sanded and uses 60L stick pin sand mill；Spray
Mist is granulated the pressure spray drying tower for using evaporation capacity 300kg/h；It is dry-pressing formed to use 200-400t bidirectional hydraulic press；Etc. quiet
Press uses cold isostatic press (maximum pressure 300MPa)；Kiln is using 1600 DEG C of electric pushed bat kilns.
By Fig. 1 and 2 it is found that when it is 90:10 that alpha-aluminium oxide powder and 3mol yttrium, which stablize nano zirconium dioxide proportion, composition
ZTA ceramics hardness it is relatively high, but since its zirconium dioxide content is less, thus the test result of its fracture toughness compared with
Difference, ductile strength are poor；It when proportion is 80:20, is obviously improved when fracture toughness is with respect to 90:10, and its hardness lowers
Degree is smaller, and the effect of the acquirement of two item datas is preferable；When proportion is 70:30 and 60:40, fracture toughness effect is preferable,
But hardness relative to 80:20 when significantly decrease, therefore composite effect is undesirable；The present invention has a kind of user
Just, security performance height, easy-operating advantage.
Embodiment 2
The relative density of tetra- kinds of different ratios of A, B, C, D, phase are tested by changing sintering temperature on the basis of the above embodiments
The performance of the various aspects of ZTA ceramics is also directly affected to the height of density.On the one hand the raising of sintering temperature can be grain
Son provides enough energy, it is enable to form ZTA ceramics across potential barrier；Another aspect temperature increases, to increase diffusion
Coefficient is conducive to the movement and mass exchange of particle, so that sintered specimen be made to densify.Therefore respectively 1300 DEG C, 1400 DEG C,
1500 DEG C, be fired under the conditions of 1600 DEG C of sintering temperature, due to joined TiO2Sintering aid is done with Ca-Mg-Si system, benefit
It will form intergranular liquid phase at high temperature with it and promote the diffusion and transmission of substance, to reduce the sintering temperature of material.
As shown in figure 3, relative density of the ZTA ceramics under different sintering temperatures.From the figure 3, it may be seen that ZTA complex phase ceramic sample
Relative density increase with the raising of sintering temperature.At 1300 DEG C, the relative density of A is 75.72%；At 1400 DEG C
Relative density reaches 88.91%；When sintering temperature rises to 1500 DEG C, relative density is up to 97.26%.In different sintering temperature
In the case where degree, with the raising of sintering temperature, grain diameter is become larger, and stomata is reduced, the increase of grain diameter and stomata
Reduction help to improve the relative density of sample.But since ZTA ceramics are compound material, 1600 are reached in temperature
DEG C when, relative density is decreased obviously.And option b can be seen that when temperature reaches 1500 DEG C or so according to Fig. 3, phase
To density highest, the case where reaching highest 98.7%, will appear decline later, this is because being the oxidation because of intergranular distribution
Zirconium particle inhibits growing up for blapharoplast, and tiny particle is then unfavorable for the densification of material.In being total to for both factors
Under same-action, under certain sintering temperature, the relative density of sample just increases that be that zirconium oxide can achieve full with temperature
And state, the case where causing first increases and then decreases.
Embodiment 3
It is higher and resistance to using the hardness and fracture toughness relative performance of ZTA ceramics made of the proportion of 80:20 in above-described embodiment
Mill property is also obviously improved, and the ZTA ceramics of 80:20 is equally prepared using method of the invention, with existing 92 aluminium oxide
Ceramics compare test, and wherein fracture toughness is single side notched beam test method, and wearability is 45 ° of sandblasting test methods；It surveys
Test result is as shown in the table:
Upper table, it is apparent that the various aspects of performance of the ceramics of ZTA made of in this way is made pottery far beyond 92 aluminium oxide
The performance of porcelain, ZTA ceramics in zirconium oxide can undergo phase transition toughening, for nano composite ceramic, since there are nano particle meetings
Nano effect is generated, to improve the mechanical property of material.Nano particle is distributed in the crystal boundary of blapharoplast, inhibits the length of particle
Greatly, small grains can hinder the extension of crackle, and improve the mechanical property of material.The ZTA composite ceramic prepared in this way
Porcelain, the crystallite dimension of strict control matrix (aluminium oxide) and disperse phase (zirconium oxide), making zirconium oxide, more uniformly disperse is aoxidizing
Between aluminium, has better toughening effect.And dry-pressing-equal pressing forming technology is used, green volume density is improved, it is higher
Green volume density is conducive to the sintering of product, reduces the porosity of firing porcelain block.Add TiO2And CaO-MgO-SiO2System's sintering
Sintering temperature is effectively reduced in auxiliary agent；The present invention has the advantages that a kind of performance easy to use, safe is high, easy-operating, present invention tool
Flexible is strong, wearability is high, low manufacture cost advantage.
Claims (3)
1. a kind of preparation method of Zirconia reinforced alumina wear-resistant ceramic, it is characterised in that: it the following steps are included:
(1) nano zirconium dioxide raw material preparation: is stablized as main material, TiO using alpha-aluminium oxide powder, 3mol yttrium2And Ca-Mg-Si
Sintering aid does in system；
(2) it ingredient: by the raw material of above-mentioned preparation using water as decentralized medium, is mixed according to the ratio that solid content is 60%；
(3) ball milling: the mixture prepared, water, abrading-ball are added in ball grinder according to a certain percentage, and ball grinder is placed on ball milling
On machine, D50 is milled to less than 5 μm；
(4) it is sanded: the mixture slurry after the completion of ball milling being sanded using sand mill, be sanded to precision prescribed D97 less than 1 μ
M adds plasticizer and reinforcing agent；
(5) mist projection granulating: carrying out mist projection granulating in spray drying tower, obtains the pelletizing of normal distribution, wherein 40 mesh are to 100
80% for being granulated powder content and being greater than total amount between mesh, moisture content is less than 1%；
(6) dry-pressing formed: pelletizing obtained above progress is dry-pressing formed, it is pressurizeed using bidirectional hydraulic press, molding pressure
It is by force 30-40MPa；
(7) isostatic pressing: improving green density, under conditions of 200Mpa, continues 3-5min；
(8) be burnt into: 1500-1520 DEG C at a temperature of be burnt into, keep the temperature 2-5h.
2. the preparation method of Zirconia reinforced alumina wear-resistant ceramic as described in claim 1, it is characterised in that: the step
(1) it is 80:20, TiO that alpha-aluminium oxide powder and 3mol yttrium, which stablize the mass ratio of nano zirconium dioxide, in2Content be 0.1-0.5wt%,
The content of Ca-Mg-Si is 0.5-1wt%.
3. the preparation method of Zirconia reinforced alumina wear-resistant ceramic as claimed in claim 2, it is characterised in that: the Ca-
Mg-Si selects CaO-MgO-SiO2, CaO-MgO-SiO2The content of middle CaO is 18%-24%, and the content of MgO is 32%-40%, SiO2
Content be 36%-45%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811580397.0A CN109336565A (en) | 2018-12-24 | 2018-12-24 | A kind of preparation method of Zirconia reinforced alumina wear-resistant ceramic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811580397.0A CN109336565A (en) | 2018-12-24 | 2018-12-24 | A kind of preparation method of Zirconia reinforced alumina wear-resistant ceramic |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109336565A true CN109336565A (en) | 2019-02-15 |
Family
ID=65297192
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811580397.0A Pending CN109336565A (en) | 2018-12-24 | 2018-12-24 | A kind of preparation method of Zirconia reinforced alumina wear-resistant ceramic |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109336565A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111517784A (en) * | 2020-05-13 | 2020-08-11 | 珠海粤博佳新材料有限公司 | Manufacturing method of wear-resistant zirconia ceramic |
| CN111848136A (en) * | 2019-04-29 | 2020-10-30 | 扬州北方三山工业陶瓷有限公司 | Preparation method of high-toughness and high-hardness alumina-based wear-resistant ceramic |
| CN112142450A (en) * | 2020-09-16 | 2020-12-29 | 南充三环电子有限公司 | Zirconia composite alumina ceramic sintered body and preparation method and application thereof |
| CN113666724A (en) * | 2020-05-15 | 2021-11-19 | 九豪精密陶瓷股份有限公司 | High-strength zirconia-alumina composite ceramic substrate for semiconductor device and method for manufacturing same |
| CN114702308A (en) * | 2022-03-30 | 2022-07-05 | 中国科学院金属研究所 | High-strength ZTA porous ceramic material and preparation method thereof |
| CN116283240A (en) * | 2023-03-28 | 2023-06-23 | 苏州芯合半导体材料有限公司 | Ruby type high-strength Cr-ZTA ceramic material and preparation method thereof |
| CN116354708A (en) * | 2021-12-28 | 2023-06-30 | 财团法人工业技术研究院 | Ceramic material and ceramic article made of same |
| CN117226958A (en) * | 2023-10-10 | 2023-12-15 | 江苏睿中轨道交通装备有限公司 | Composite ceramic anchoring piece pre-buried in concrete and preparation device thereof |
Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS54102312A (en) * | 1978-01-31 | 1979-08-11 | Hitachi Ltd | Alumina base porcelain composition |
| JPH01212272A (en) * | 1988-02-19 | 1989-08-25 | Ngk Spark Plug Co Ltd | High-alumina insulator for ignition plug |
| CN1884189A (en) * | 2006-06-21 | 2006-12-27 | 济南大学 | Fiber reinforced alumina ceramic-base composites and method for preparing same |
| CN101508562A (en) * | 2009-04-07 | 2009-08-19 | 广东东方锆业科技股份有限公司 | Aluminum oxide toughening structure ceramic material and method of producing the same |
| CN101962287A (en) * | 2010-09-14 | 2011-02-02 | 石家庄铁道大学 | Processable aluminium oxide base composite ceramic material and preparation method thereof |
| CN103641453A (en) * | 2013-11-27 | 2014-03-19 | 中国兵器工业第五二研究所烟台分所 | Toughened aluminum oxide ceramic thermal insulation piece, and preparation technology of toughened aluminum oxide ceramic thermal insulation piece, and application of toughened aluminum oxide ceramic heat piece in extruding cylinder |
| CN104193307A (en) * | 2014-08-22 | 2014-12-10 | 淄博市周村磊宝耐火材料有限公司 | Preparation method of low-cost zirconium dioxide toughened alumina ceramic granular powder |
| CN104261821A (en) * | 2014-09-12 | 2015-01-07 | 李正国 | Process for manufacturing super-wearable zirconia ceramic extrusion head |
| CN104326751A (en) * | 2014-07-01 | 2015-02-04 | 郑州大学 | Microwave sintering method of ZTA ceramic |
| CN105254283A (en) * | 2015-09-17 | 2016-01-20 | 上海应用技术学院 | Preparation method for alumina ceramic matrix material |
| CN106904950A (en) * | 2017-03-21 | 2017-06-30 | 华东理工大学 | A kind of low sintering 95 alumina ceramic material |
| CN107673757A (en) * | 2017-09-22 | 2018-02-09 | 广东百工新材料科技有限公司 | A kind of ceramic mobile phone bonnet and preparation method thereof |
-
2018
- 2018-12-24 CN CN201811580397.0A patent/CN109336565A/en active Pending
Patent Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS54102312A (en) * | 1978-01-31 | 1979-08-11 | Hitachi Ltd | Alumina base porcelain composition |
| JPH01212272A (en) * | 1988-02-19 | 1989-08-25 | Ngk Spark Plug Co Ltd | High-alumina insulator for ignition plug |
| CN1884189A (en) * | 2006-06-21 | 2006-12-27 | 济南大学 | Fiber reinforced alumina ceramic-base composites and method for preparing same |
| CN101508562A (en) * | 2009-04-07 | 2009-08-19 | 广东东方锆业科技股份有限公司 | Aluminum oxide toughening structure ceramic material and method of producing the same |
| CN101962287A (en) * | 2010-09-14 | 2011-02-02 | 石家庄铁道大学 | Processable aluminium oxide base composite ceramic material and preparation method thereof |
| CN103641453A (en) * | 2013-11-27 | 2014-03-19 | 中国兵器工业第五二研究所烟台分所 | Toughened aluminum oxide ceramic thermal insulation piece, and preparation technology of toughened aluminum oxide ceramic thermal insulation piece, and application of toughened aluminum oxide ceramic heat piece in extruding cylinder |
| CN104326751A (en) * | 2014-07-01 | 2015-02-04 | 郑州大学 | Microwave sintering method of ZTA ceramic |
| CN104193307A (en) * | 2014-08-22 | 2014-12-10 | 淄博市周村磊宝耐火材料有限公司 | Preparation method of low-cost zirconium dioxide toughened alumina ceramic granular powder |
| CN104261821A (en) * | 2014-09-12 | 2015-01-07 | 李正国 | Process for manufacturing super-wearable zirconia ceramic extrusion head |
| CN105254283A (en) * | 2015-09-17 | 2016-01-20 | 上海应用技术学院 | Preparation method for alumina ceramic matrix material |
| CN106904950A (en) * | 2017-03-21 | 2017-06-30 | 华东理工大学 | A kind of low sintering 95 alumina ceramic material |
| CN107673757A (en) * | 2017-09-22 | 2018-02-09 | 广东百工新材料科技有限公司 | A kind of ceramic mobile phone bonnet and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 史国普 等: ""低温烧结氧化铝陶瓷"", 《济南大学学报（自然科学版）》 * |
| 史国普 等: ""低温烧结氧化铝陶瓷的动力学研究"", 《硅酸盐通报》 * |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111848136A (en) * | 2019-04-29 | 2020-10-30 | 扬州北方三山工业陶瓷有限公司 | Preparation method of high-toughness and high-hardness alumina-based wear-resistant ceramic |
| CN111517784A (en) * | 2020-05-13 | 2020-08-11 | 珠海粤博佳新材料有限公司 | Manufacturing method of wear-resistant zirconia ceramic |
| CN113666724A (en) * | 2020-05-15 | 2021-11-19 | 九豪精密陶瓷股份有限公司 | High-strength zirconia-alumina composite ceramic substrate for semiconductor device and method for manufacturing same |
| CN112142450A (en) * | 2020-09-16 | 2020-12-29 | 南充三环电子有限公司 | Zirconia composite alumina ceramic sintered body and preparation method and application thereof |
| CN112142450B (en) * | 2020-09-16 | 2022-05-13 | 南充三环电子有限公司 | Zirconia composite alumina ceramic sintered body and preparation method and application thereof |
| CN116354708A (en) * | 2021-12-28 | 2023-06-30 | 财团法人工业技术研究院 | Ceramic material and ceramic article made of same |
| CN114702308A (en) * | 2022-03-30 | 2022-07-05 | 中国科学院金属研究所 | High-strength ZTA porous ceramic material and preparation method thereof |
| CN116283240A (en) * | 2023-03-28 | 2023-06-23 | 苏州芯合半导体材料有限公司 | Ruby type high-strength Cr-ZTA ceramic material and preparation method thereof |
| CN117226958A (en) * | 2023-10-10 | 2023-12-15 | 江苏睿中轨道交通装备有限公司 | Composite ceramic anchoring piece pre-buried in concrete and preparation device thereof |
| CN117226958B (en) * | 2023-10-10 | 2024-07-02 | 江苏睿中轨道交通装备有限公司 | Composite ceramic anchoring piece pre-buried in concrete and preparation device thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109336565A (en) | A kind of preparation method of Zirconia reinforced alumina wear-resistant ceramic | |
| CN108083779B (en) | Rare earth alumina ceramic composite material and preparation method thereof | |
| CN101857451B (en) | Heat-insulating integrated composite brick with alkaline structure and preparation method thereof | |
| CN107774983B (en) | A kind of rare earth modified granule reinforced steel matrix skin layer steric configuration composite material and preparation method | |
| CN102600939B (en) | Method for manufacturing nanometer zirconia ceramic reinforced wear-resisting steel ball | |
| Yin et al. | Preparation and properties of an Al2O3/Ti (C, N) micro-nano-composite ceramic tool material by microwave sintering | |
| CN101798216B (en) | Zirconium oxide-based nano ceramic tool and die material added with titanium boride and preparation method thereof | |
| CN108640672A (en) | A kind of preparation method of light-weight magnesite-alumina spinel refractories | |
| CN102659421A (en) | Production method of mullite cast steel brick | |
| CN102424584B (en) | Magnesium-hercynite-structured heat-insulating integral composite brick and preparation method thereof | |
| CN102285807A (en) | Magnesium-spinel-zirconium structure and thermal insulation integrated composite brick and preparation method thereof | |
| CN114736022B (en) | High-density, high-strength and ultrahigh-hardness boron carbide/high-entropy diboride complex phase ceramic and preparation method thereof | |
| CN105924175B (en) | A kind of fine grain boron carbide ceramics and preparation method thereof | |
| Huang et al. | Development of ZrO2–WC composites by pulsed electric current sintering | |
| CN104909774B (en) | Aluminous cement combination properties of alumina-magnesia castables and preparation method thereof | |
| CN103934453B (en) | Utilize the method for modified metal power forging gasoline engine connecting rod blank | |
| US3929498A (en) | Sintered zirconia bodies | |
| CN108298964A (en) | High-purity fine grain wear-resisting alumina liner plate and preparation method thereof | |
| CN108117381A (en) | A kind of inertia composite calcining-endure plate and preparation method thereof | |
| CN112897994A (en) | Preparation method of corundum spinel complex phase material | |
| CN108840668A (en) | A kind of wear-resistant material | |
| CN104725059A (en) | Zirconium oxide monodisperse active spinel powder and preparation method thereof | |
| CN114380606A (en) | Preparation process of machined high-strength refractory material | |
| CN102603332A (en) | Magnesium-iron-aluminum spinel three-layer composite brick and preparation method of composite brick | |
| CN102603331A (en) | Magnesium zirconium three-layer composite brick and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190215 |
|
| RJ01 | Rejection of invention patent application after publication |