CN109332611A - A kind of water-cooled steel ingot mould - Google Patents

A kind of water-cooled steel ingot mould Download PDF

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Publication number
CN109332611A
CN109332611A CN201811389741.8A CN201811389741A CN109332611A CN 109332611 A CN109332611 A CN 109332611A CN 201811389741 A CN201811389741 A CN 201811389741A CN 109332611 A CN109332611 A CN 109332611A
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CN
China
Prior art keywords
water
steel ingot
arc panel
cooled
mould
Prior art date
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Pending
Application number
CN201811389741.8A
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Chinese (zh)
Inventor
朱书成
刘庆波
许少普
李忠波
杨阳
康文举
张占杰
张涛
唐郑磊
庞百鸣
于飒
董真真
袁继恒
袁永旗
朱先兴
王英杰
符可义
薛艳生
蒋鹏
李亮
袁高俭
全微波
郑海明
陈良
陈熙
李嘎子
白艺博
王勇
杨春
赵运启
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Nanyang Hanye Special Steel Co Ltd
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Nanyang Hanye Special Steel Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Nanyang Hanye Special Steel Co Ltd filed Critical Nanyang Hanye Special Steel Co Ltd
Priority to CN201811389741.8A priority Critical patent/CN109332611A/en
Publication of CN109332611A publication Critical patent/CN109332611A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D7/00Casting ingots, e.g. from ferrous metals
    • B22D7/06Ingot moulds or their manufacture
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22CFOUNDRY MOULDING
    • B22C3/00Selection of compositions for coating the surfaces of moulds, cores, or patterns
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D15/00Electrolytic or electrophoretic production of coatings containing embedded materials, e.g. particles, whiskers, wires
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00Electroplating: Baths therefor
    • C25D3/02Electroplating: Baths therefor from solutions
    • C25D3/04Electroplating: Baths therefor from solutions of chromium
    • C25D3/06Electroplating: Baths therefor from solutions of chromium from solutions of trivalent chromium
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/10Electroplating with more than one layer of the same or of different metals
    • C25D5/12Electroplating with more than one layer of the same or of different metals at least one layer being of nickel or chromium
    • C25D5/14Electroplating with more than one layer of the same or of different metals at least one layer being of nickel or chromium two or more layers being of nickel or chromium, e.g. duplex or triplex layers

Abstract

The invention discloses a kind of water-cooled steel ingot moulds, belong to ingot steel casting equipment technical field.It includes water-cooled chassis and the mould body that is arranged in the water-cooled chassis, the mould body includes two surface plates being oppositely arranged and two arc panels being oppositely arranged, the surface plate and the arc panel edge are mutually detachably connected, coating is respectively provided on the inside of the surface plate and the arc panel, longitudinally disposed multiple water-flowing troughs inside the surface plate and the arc panel, multiple water-flowing trough lower parts are connected to water inlet manifold, the water inlet manifold is connected to water pump, and multiple water-flowing trough tops are connected to outfall sewer.Water-cooled steel ingot mould of the invention has the characteristics that steel ingot cooling efficiency is high, is convenient in demoulding, steel ingot is less prone to crackle.

Description

A kind of water-cooled steel ingot mould
Technical field
The present invention relates to ingot steel casting equipment technical field, specifically a kind of water-cooled steel ingot mould.
Background technique
With industrial development, demand and quality requirement to super-thick steel plate are stepped up, therefore the production to super-thick steel plate Equipment and process requirements also increase accordingly, the gradually improvement of operation and technology recently as water-cooled steel ingot mould equipment, life The super-thick steel plate quality of production is improved significantly, but due to the raising of intensity of cooling under water cooling condition, big width steel ingot is being poured There is the phenomenon that easily sending out longitudinal crack on wide face in process of setting, increases steel ingot cleaning workload, extend the production cycle, simultaneously It is a kind of loss to lumber recovery.
Notification number is that the patent of 104439123 B of CN discloses a kind of magnetic water-cooled steel ingot mould, which includes: steel Ingot mould inner cavity, side or rectangle cooling water pipe, Reinforced Hoop, lift water-cooled chassis, water-cooled chassis, water-cooled chassis water inlet, water cooling Chassis water outlet, water inlet manifold, outfall sewer, organizes pipe structure and pedestal at hydraulicefficiency elevation structure side by side.The saturating magnetic that the invention provides The side wall of water-cooled steel ingot mould device is formed using pipe structure welding, and water-cooled steel ingot mould production cost of material can be greatly lowered, have Conducive to water-cooled steel ingot mould processing and fabricating and maintenance.Water-cooled chassis is gone up and down to drive by the elevating mechanism of hydraulic-driven bar, it is ensured that Water-cooled chassis is steadily gone up and down.But the ingot mould of the invention is formed side by side using multiple water pipes, demoulding is difficult, be easy to cause steel Ingot damage.
Publication No. is that the patent document of 106734997 A of CN discloses a kind of round steel ingot mould, belongs to round ingot production neck Domain.Purpose is to provide a kind of round steel ingot mould for being conducive to heat dissipation, the face crack of the round ingot to reduce casting.Including mould Body is equipped with multiple stomatas in the lateral wall of die body, and multiple stomatas are located under die body at mouth, and circumferentially uniformly distributed along die body;In die body On be additionally provided with the heat dissipation channel between lateral wall and inner sidewall with stomata equivalent, the heat dissipation channel is extended by lower end surface To upper surface;The heat dissipation channel is connected with stomata one-to-one correspondence.The round steel ingot mould accelerates the intracavitary outer layer molten steel of type Radiating rate, the molten steel for being conducive to outer layer rapidly cools to form chill, and then the heat for being conducive to internal layer molten steel is quickly outside Layer molten steel transmitting, to accelerate the radiating rate of internal layer molten steel, and then improves the thickness of chill, thicker chill is more Be conducive to the static pressure for bearing to generate when pouring molten steel, to be more advantageous to the face crack for reducing steel ingot, improve steel ingot Surface quality.But the ingot mould uses air cooling way, cooling efficiency is low, wastes electric energy, and the ingot mould die body is integrated Structure, demoulding is difficult, and surface of steel ingot is not smooth enough.
Summary of the invention
In view of this, in view of the deficiencies of the prior art, the present invention provides a kind of steel ingot cooling efficiency it is high, be convenient in demoulding, Steel ingot is less prone to the water-cooled steel ingot mould of crackle.
In order to solve the above technical problems, the technical solution used in the present invention is: a kind of water-cooled steel ingot mould, including Water-cooled bottom Disk and the mould body being arranged in the water-cooled chassis, the mould body includes that two surface plates being oppositely arranged and two are oppositely arranged Arc panel, the surface plate and the arc panel edge be mutually detachably connected, on the inside of the surface plate and the arc panel It is respectively provided with coating, longitudinally disposed multiple water-flowing troughs inside the surface plate and the arc panel, multiple water-flowing trough lower parts It is connected to water inlet manifold, the water inlet manifold is connected to water pump, and multiple water-flowing trough tops are connected to outfall sewer.
Preferably, the arc panel two sides are respectively provided with raised line, and the surface plate two sides are respectively provided with groove, the raised line and institute Groove is stated to be correspondingly connected with.
Preferably, multiple Reinforced Hoops are set on the outside of the mould body.
Preferably, the arc degree α of the arc panel is 1 °~70 °.
Preferably, the water-flowing trough cross section is square or round.
Preferably, the surface plate and the arc panel are copper sheet, and the coating is metal Cr coating.
Preferably, the plating method of the coating, comprising the following steps:
(1) copper sheet inner surface is subjected to pickling and washing, activates copper sheet inner surface;
(2) electroplate liquid I is poured into electrolytic cell I, the temperature of electrolytic cell I is raised to 50 DEG C, be powered to electroplating bath starts electricity Plating, plates the chrome plating with a thickness of 20-30um in copper sheet inner surface;
(3) electroplate liquid II is poured into electrolytic cell II, the temperature of electroplate liquid II is raised to 50 DEG C, and below electroplating bath II Put a constant temperature blender with magnetic force;
(4) copper sheet by chromium plating in step (2) carries out surface clean again, is placed into electrolytic cell two and carries out second time electroplating, And constant temperature blender with magnetic force is opened, chrome layer is formed on the surface of coating.
I component of electroplate liquid and its content are Cr3+0.4-0.8mol/L、H2SO40.3-0.5mol/L、H3BO30.2- 0.4 mol /L;
II component of electroplate liquid and its content are Cr3+0.4-0.8mol/L、H2SO40.3-0.5mol/L、H3BO30.2-0.4 mol /L、C12H25SO4Na 0.005 mol/L、Si3N41-4g/L。
Preferably, the Si3N4Granularity be 10-20nm.
Preferably, the preparation method of the electroplate liquid II are as follows: the reagent of each raw material component is soluble in water, then by the First Astronautic Research Institute for Measurement and Test The Si stated3N4It is dissolved in wherein, is dispersed after mixing with ultrasonic wave, jitter time 5-6min.
Compared with prior art, beneficial effects of the present invention are as follows:
Water-cooled steel ingot mould of the invention, the arc panel that the surface plate and two that mould body is oppositely arranged by two are oppositely arranged are mutually butted, In casting process, since inner cavity is cambered design, the stress that can reduce surface of steel ingot is concentrated, in addition during solidification shrinkage Since surface is arc, deformable amount is big compared with plane steel ingot, further mitigates stress of steel ingot during solidification shrinkage and splits Line tendency.
In addition, the raised line of two surface plate two sides is docked with the groove of two arc panel two sides, flexibly tearing open for mould body can be realized It unloads, facilitates demoulding after the completion of ingot steel casting, four independent templates can be fixedly connected, protect by multiple Reinforced Hoops on the outside of mould body It holds mould body to stablize, avoids bleed-out during ingot steel casting, the arc degree of arc panel can make surface of steel ingot between 1 °~70 ° Stress is maintained at OK range, and deformable surplus during solidification shrinkage is maintained at OK range, when avoiding ingot solidification It cracks.
In addition, can be improved wear-resisting property by the way that coating is arranged on the inside of mould body, keep smooth on the inside of mould body, plating Layer is metal Cr coating, and stability is strong, long service life, and keeps steel ingot demoulding more convenient.
In addition, the coating on the inside of mould body by the way of being electroplated twice, so that the thickness of coating and hardness are guaranteed, mentions Nano-silicon nitride is added when being electroplated for second in high mould body surface abrasion resistance and corrosion resistance, can fill chromium metal grain it Between hole, and curl up and be covered on chromium metal grain surface and form stable coating, so that the surface of coating is more smooth, when demoulding It is more convenient, and not will cause steel ingot damage.
Detailed description of the invention
Fig. 1 is the top view of the embodiment of the present invention one;
Fig. 2 is the left view of the embodiment of the present invention one;
Fig. 3 is the left view of the embodiment of the present invention four;
Wherein, 1- water-cooled chassis, 2- surface plate, 3- arc panel, 4- water-flowing trough, 5- raised line, 6- fixture, 7- hydraulic press, 8- pressing plate.
Specific embodiment
For a better understanding of the present invention, the contents of the present invention, but this hair are further fairly set out below with reference to embodiment Bright protection content is not limited solely to the following examples.In the following description, give a large amount of concrete details so as to More thorough understanding of the invention is provided.It will be apparent, however, to one skilled in the art that the present invention can be with It is carried out without one or more of these details.
Embodiment one
As shown in Figure 1 and 2, a kind of water-cooled steel ingot mould, including water-cooled chassis 1 and the mould body being arranged in the water-cooled chassis 1, institute Stating mould body includes two surface plates being oppositely arranged 2 and two arc panels 3 being oppositely arranged, the surface plate 2 and the arc 3 edge of plate is mutually detachably connected, and coating, the surface plate 2 and institute are respectively provided on the inside of the surface plate 2 and the arc panel 3 State longitudinally disposed multiple water-flowing troughs 4 inside arc panel 3, multiple 4 lower parts of water-flowing trough are connected to water inlet manifold, it is described into Supply mains is connected to water pump, and multiple 4 tops of water-flowing trough are connected to outfall sewer.
Specifically, 3 two sides of arc panel are respectively provided with raised line 5,2 two sides of surface plate are respectively provided with groove, the raised line 5 It is correspondingly connected with the groove.Multiple Reinforced Hoops are set on the outside of the mould body.The arc degree α of the arc panel 3 is 60 °, arc Degree refers to the angle of cambered surface tangent line and vertical line, and 4 cross section of water-flowing trough is circle.
The water-cooled steel ingot mould of the embodiment of the present invention, the arc panel that the surface plate and two that mould body is oppositely arranged by two are oppositely arranged It is mutually butted, in casting process, since inner cavity is cambered design, the stress that can reduce surface of steel ingot is concentrated, and is in addition being solidified Since surface is arc in contraction process, deformable amount is big compared with plane steel ingot, further mitigates steel ingot in solidification shrinkage process In stress cracking tendency, coating is set on the inside of mould body, can be improved the wear-resisting property of ingot mould;The raised line of two surface plate two sides It is docked with the groove of two arc panel two sides, can be realized the flexible disassembly of mould body, ingot steel casting is facilitated to demould after the completion, outside mould body Four independent templates can be fixedly connected by multiple Reinforced Hoops of side, and mould body is kept to stablize, and avoid leaking during ingot steel casting Steel, the arc degree of arc panel can make surface of steel ingot stress be maintained at OK range, in solidification shrinkage mistake between 1 °~70 ° Deformable surplus in journey is maintained at OK range, avoids cracking when ingot solidification.
Embodiment two
As shown in Figure 1 and 2, a kind of water-cooled steel ingot mould, including water-cooled chassis 1 and the mould body being arranged in the water-cooled chassis 1, institute Stating mould body includes two surface plates being oppositely arranged 2 and two arc panels 3 being oppositely arranged, the surface plate 2 and the arc 3 edge of plate is mutually detachably connected, and coating, the surface plate 2 and institute are respectively provided on the inside of the surface plate 2 and the arc panel 3 State longitudinally disposed multiple water-flowing troughs 4 inside arc panel 3, multiple 4 lower parts of water-flowing trough are connected to water inlet manifold, it is described into Supply mains is connected to water pump, and multiple 4 tops of water-flowing trough are connected to outfall sewer.
Specifically, 3 two sides of arc panel are respectively provided with raised line 5,2 two sides of surface plate are respectively provided with groove, the raised line 5 It is correspondingly connected with the groove.Multiple Reinforced Hoops are set on the outside of the mould body.The arc degree α of the arc panel 3 is 60 °.It is described 4 cross section of water-flowing trough is square.
The water-cooled steel ingot mould of the embodiment of the present invention, with embodiment one the difference is that: the surface plate and the arc Shape plate is copper sheet, and the coating is metal Cr.
The plating method of the coating, comprising the following steps: (1) copper sheet inner surface is subjected to pickling and washing, makes copper sheet Inner surface activation;
(2) electroplate liquid I is poured into electrolytic cell I, the temperature of electrolytic cell I is raised to 50 DEG C, be powered to electroplating bath starts electricity Plating, plates the chrome plating with a thickness of 20-30um in copper sheet inner surface;
(3) electroplate liquid II is poured into electrolytic cell II, the temperature of electroplate liquid II is raised to 50 DEG C, and below electroplating bath II Put a constant temperature blender with magnetic force;
(4) copper sheet by chromium plating in step (2) carries out surface clean again, is placed into electrolytic cell two and carries out second time electroplating, And constant temperature blender with magnetic force is opened, chrome layer is formed on the surface of coating.
I component of electroplate liquid and its content are Cr3+0.4-0.8mol/L、H2SO40.3-0.5mol/L、H3BO30.2- 0.4 mol /L;
II component of electroplate liquid and its content are Cr3+0.4-0.8mol/L、H2SO40.3-0.5mol/L、H3BO30.2-0.4 mol /L、C12H25SO4Na 0.005 mol/L、Si3N41-4g/L。
The Si3N4Granularity be 10-20nm.
The preparation method of the electroplate liquid II are as follows: the reagent of each raw material component is soluble in water then metering is described Si3N4It is dissolved in wherein, is dispersed after mixing with ultrasonic wave, jitter time 5-6min.
In the embodiment of the present invention, mould body uses copper sheet, and thermal conductivity is good, and water cooling is high-efficient, and the coating on the inside of mould body uses two The mode of secondary plating improves mould body surface abrasion resistance and corrosion resistance so that the thickness of coating and hardness are guaranteed, and second When secondary plating, nano-silicon nitride is added, the hole between chromium metal grain can be filled, and curl up and be covered on chromium metal grain table Face forms stable coating, so that the surface of coating is more smooth, when demoulding is more convenient, and not will cause steel ingot damage.
Embodiment three
As shown in Figure 1 and 2, a kind of water-cooled steel ingot mould, including water-cooled chassis 1 and the mould body being arranged in the water-cooled chassis 1, institute Stating mould body includes two surface plates being oppositely arranged 2 and two arc panels 3 being oppositely arranged, the surface plate 2 and the arc 3 edge of plate is mutually detachably connected, and coating, the surface plate 2 and institute are respectively provided on the inside of the surface plate 2 and the arc panel 3 State longitudinally disposed multiple water-flowing troughs 4 inside arc panel 3, multiple 4 lower parts of water-flowing trough are connected to water inlet manifold, it is described into Supply mains is connected to water pump, and multiple 4 tops of water-flowing trough are connected to outfall sewer.
Specifically, 3 two sides of arc panel are respectively provided with raised line 5,2 two sides of surface plate are respectively provided with groove, the raised line 5 It is correspondingly connected with the groove.Multiple Reinforced Hoops are set on the outside of the mould body.The arc degree α of the arc panel 3 is 60 °.It is described 4 cross section of water-flowing trough is regular polygon.
The surface plate and the arc panel are copper sheet, the coating be metal Cr, the plating method of the coating with It is identical in embodiment two.
The production method of the water cooling steel ingot, comprising the following steps:
(1) covering slag is put at mould bottom;
(2) cooling water system is opened, checks that confirmation die body jacket outlet hydraulic pressure is greater than 0.05Mpa;
(3) it is poured, the overtemperature of molten steel is controlled at 50 ~ 80 °C, and ingot body poring rate 10-50cm/ minutes, steel ingot diameter is bigger The rate of climb is slower, and the speed of cap mouth is less than ingot body poring rate, is poured into above reinforced hole and stops casting, immediately on liquid level It is put into heat preserving agent and exothermic mixture;
(4) casting, which ends, continues water supply cooling, holds time 10~15 minutes and demoulds;
(5) upper slow cooling cover is covered after water cooling casting moulds are sloughed immediately;
(6) i.e. removing slow cooling cover removes annealing for ingot blank after confirmation is coagulated entirely.
The water cooling steel ingot prepared by the above method, it is the slag scar of surface of steel ingot, pit, dross, stomata, point, pipe, recessed The depth of the defects of convex uneven is highly less than 2mm, and surface is more smooth, flawless.
Example IV
As shown in Figure 1, Figure 3, a kind of water-cooled steel ingot mould, including water-cooled chassis 1 and the mould body that is arranged in the water-cooled chassis 1, The mould body includes two surface plates being oppositely arranged 2 and two arc panels 3 being oppositely arranged, the surface plate 2 and the arc 3 edge of shape plate is mutually detachably connected, and coating, 2 He of surface plate are respectively provided on the inside of the surface plate 2 and the arc panel 3 Longitudinally disposed multiple water-flowing troughs 4 inside the arc panel 3, multiple 4 lower parts of water-flowing trough are connected to water inlet manifold, described Water inlet manifold is connected to water pump, and multiple 4 tops of water-flowing trough are connected to outfall sewer.
Specifically, 3 two sides of arc panel are respectively provided with raised line 5,2 two sides of surface plate are respectively provided with groove, the raised line 5 It is correspondingly connected with the groove.Multiple Reinforced Hoops are set on the outside of the mould body.The arc degree α of the arc panel 3 is 60 °.It is described 4 cross section of water-flowing trough is circle.
The water-cooled steel ingot mould of the embodiment of the present invention, with embodiment one, two, three the difference is that: further include ingot stripper Structure, the demoulding mechanism include clamping device and hydraulic device, and the clamping device setting is described in the hydraulic device bottom surface Clamping device include two fixtures 6, the hydraulic device includes hydraulic press 7, the telescopic rod of the hydraulic press 7 downward, two institutes The two sides that fixture 6 is located at the telescopic rod are stated, pressing plate 8 is arranged in the telescopic rod end.
When demoulding, the Reinforced Hoop on the outside of the mould body is removed, two fixtures are clamping by two surface plates respectively, by institute It states chassis to split out, starts hydraulic press, hydraulic press telescopic rod band dynamic pressure plate moves downward, steel ingot is extruded, demoulding is completed.
Finally, it is stated that the above examples are only used to illustrate the technical scheme of the present invention and are not limiting, this field is common Other modifications or equivalent replacement that technical staff makes technical solution of the present invention, without departing from technical solution of the present invention Spirit and scope, be intended to be within the scope of the claims of the invention.

Claims (9)

1. a kind of water-cooled steel ingot mould, including water-cooled chassis and the mould body being arranged in the water-cooled chassis, it is characterised in that: described Mould body includes two surface plates being oppositely arranged and two arc panels being oppositely arranged, the surface plate and the arc panel edge It is mutually detachably connected, is respectively provided with coating on the inside of the surface plate and the arc panel, in the surface plate and the arc panel The longitudinally disposed multiple water-flowing troughs in portion, multiple water-flowing trough lower parts are connected to water inlet manifold, the water inlet manifold and water pump Connection, multiple water-flowing trough tops are connected to outfall sewer.
2. water-cooled steel ingot mould as described in claim 1, it is characterised in that: the arc panel two sides are respectively provided with raised line, described flat Panel two sides are respectively provided with groove, and the raised line is correspondingly connected with the groove.
3. water-cooled steel ingot mould as claimed in claim 2, it is characterised in that: multiple Reinforced Hoops are arranged on the outside of the mould body.
4. water-cooled steel ingot mould as claimed in claim 3, it is characterised in that: the arc degree α of the arc panel is 1 °~70 °.
5. water-cooled steel ingot mould as claimed in claim 4, it is characterised in that: the water-flowing trough cross section is square or justifies Shape.
6. water-cooled steel ingot mould as claimed in claim 1 or 5, it is characterised in that: the surface plate and the arc panel are copper Plate, the coating are metal Cr coating.
7. water-cooled steel ingot mould as claimed in claim 6, it is characterised in that: the plating method of the coating, comprising the following steps:
(1) copper sheet inner surface is subjected to pickling and washing, activates copper sheet inner surface;
(2) electroplate liquid I is poured into electrolytic cell I, the temperature of electrolytic cell I is raised to 50 DEG C, be powered to electroplating bath starts electricity Plating, plates the chrome plating with a thickness of 20-30um in copper sheet inner surface;
(3) electroplate liquid II is poured into electrolytic cell II, the temperature of electroplate liquid II is raised to 50 DEG C, and below electroplating bath II Put a constant temperature blender with magnetic force;
(4) copper sheet by chromium plating in step (2) carries out surface clean again, is placed into electrolytic cell two and carries out second time electroplating, And constant temperature blender with magnetic force is opened, chrome layer is formed on the surface of coating;
I component of electroplate liquid and its content are Cr3+0.4-0.8mol/L、H2SO40.3-0.5mol/L、H3BO30.2-0.4 mol /L;
II component of electroplate liquid and its content are Cr3+0.4-0.8mol/L、H2SO40.3-0.5mol/L、H3BO30.2-0.4 mol /L、C12H25SO4Na 0.005 mol/L、Si3N41-4g/L。
8. water-cooled steel ingot mould as claimed in claim 7, it is characterised in that: the Si3N4Granularity be 10-20nm.
9. water-cooled steel ingot mould as claimed in claim 8, it is characterised in that: the preparation method of the electroplate liquid II are as follows: Jiang Geyuan Expect that the reagent of component is soluble in water, then the Si that metering is described3N4It is dissolved in wherein, is dispersed after mixing with ultrasonic wave, when dispersion Between be 5-6min.
CN201811389741.8A 2018-11-21 2018-11-21 A kind of water-cooled steel ingot mould Pending CN109332611A (en)

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FR2249724A1 (en) * 1973-11-02 1975-05-30 Suss Benoit Fibrous sealant for ingot moulds - to prevent loss of metal on casting
US4635896A (en) * 1986-04-04 1987-01-13 Baker Edwin L Method of sealing a joint between an ingot mold and a stool and resulting assembly
CA2043506A1 (en) * 1990-05-30 1991-12-01 Toshio Negishi Width variable mold
US6167940B1 (en) * 1996-01-18 2001-01-02 Paul Wurth, S.A. Continuous casting device
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CN2885458Y (en) * 2006-03-17 2007-04-04 钢铁研究总院 Crystallizer copper plate for sheet blank continuous casting
CN101543877A (en) * 2009-05-11 2009-09-30 南阳汉冶特钢有限公司 Device using water-cooling crystallizer as ingot mold
CN201997677U (en) * 2011-03-24 2011-10-05 中冶京诚工程技术有限公司 Combined box type water-cooling casting device for ingotblank
CN104968453A (en) * 2012-11-16 2015-10-07 达涅利机械设备股份公司 Method to manufacture a crystallizer with plates for the continuous casting of slabs, and crystallizer thus obtained
EP3191240B1 (en) * 2014-09-10 2018-08-22 Ikoi S.P.A. Cooling device for ingot molds adapted to produce ingots and bars of precious metal
CN108130570A (en) * 2017-12-15 2018-06-08 北京科技大学 A kind of compound trivalent plating chromium process

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