CN109329284A - A kind of composition pesticide - Google Patents
A kind of composition pesticide Download PDFInfo
- Publication number
- CN109329284A CN109329284A CN201811271836.XA CN201811271836A CN109329284A CN 109329284 A CN109329284 A CN 109329284A CN 201811271836 A CN201811271836 A CN 201811271836A CN 109329284 A CN109329284 A CN 109329284A
- Authority
- CN
- China
- Prior art keywords
- composition
- benziothiazolinone
- polyglutamic acid
- agent
- pesticide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
- A01N37/46—N-acyl derivatives
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
Abstract
The invention discloses a kind of composition pesticide, effective component includes polyglutamic acid and benziothiazolinone, and the weight ratio between two components is 30~1:1~10, and the present invention also provides the Preparation method and uses of the composition.Test result show composition of the invention can good regulating crop growth, improve disease-resistant resistance, promote crop health benefit, improve crop yield.
Description
Technical field
The invention belongs to agriculture plant protection fields, more particularly to a kind of with the composition pesticide for improving performance, tool
Say to body it is to be related to a kind of composition pesticide comprising polyglutamic acid and benziothiazolinone.
Background technique
Polyglutamic acid (γ-poly-glutamic acid, abbreviation γ-PGA) is also known as natto gum, polyglutamic acid, it is
A kind of water solubility, biodegrade are free of toxicity, use boiomacromolecule made from microbe fermentation method.Polyglutamic acid is by paddy
A kind of homogeneous polyamino acid that propylhomoserin monomer is polymerized by amido bond has splendid biodegradability, superpower absorption, nothing
The advantages that malicious, is added into compound fertilizer to have and reduces fertilizer nutrient loss, it is more to improve utilization rate of fertilizer, coordinate plant growth etc.
Weight effect.Significant application effect is all had on the plants such as rice, wheat, corn, vegetables, fruit tree, flowers, can be significantly improved
Crop yield.
Benziothiazolinone (benzisothiazolinone) is a kind of novel, wide-spectrum bactericide, is mainly used for preventing and treating and treating yellow
The various bacteria of melon downy mildew, pear scab, apple scab, citrus anthracnose, grapevine anthracnose etc., fungal disease.Its
Bactericidal effect mechanism, main includes destroying germ cell nuclear structure, it is made to lose cardia and failure death and interference germ
The metabolism of cell makes its physiologic derangement, eventually leads to dead two aspects.It is black to be mainly used for prevention and treatment cucumber downy mildew, pears
Star disease, apple scab, citrus anthracnose, grapevine anthracnose etc. have special efficacy to various bacteria, fungal disease.
Actual pesticide experience have shown that, repeat and single-minded apply a kind of reactive compound to prevent and treat harmful bacteria very
It will lead to the fast selective of species strain in more situations, it is usual at present for the risk for reducing resistance species strain selectivity
Harmful bacteria is prevented and treated using the mixture of different activities compound.By will have the reactive compound of different role mechanism into
Row combination, can delaying drug resistance generate, reduce amount of application, reduce control cost.
Summary of the invention
The object of the present invention is to provide a kind of composition pesticides with synergistic effect to be prolonged with improving sterilization control efficiency
Slow resistance generates, while can adjust plant growth, improves crop yield.
It is a further object to provide exist comprising two kinds of effective component polyglutamic acids and benziothiazolinone bactericidal composition
Agriculture field prevents and treats corps diseases or promotes the application in plant growth.
The purpose of the present invention can be achieved by the following measures:
A kind of composition pesticide, the composition include two kinds of active components of polyglutamic acid and benziothiazolinone.
Weight ratio between two component of the polyglutamic acid and benziothiazolinone is 30~1:1~10, to make combination of the invention
Object effect is further promoted, and the weight ratio between two components advanced optimizes as 25~1:1~5.
Two kinds of active component weight ratios of polyglutamic acid described in one of scheme and benziothiazolinone are preferably 20~1:1.
In a kind of preferred scheme, the weight ratio between two component of polyglutamic acid and benziothiazolinone can arbitrarily match following
30:1,29:1,28:1,27:1,26:1,25:1,24:1,23:1,22:1,21:1,20:1,19 are adjusted than in the range of:
1、18:1、17:1、16:1、15:1、14:1、13:1、12:1、11:1、10:1、9:1、8:1、7:1、6:1、5:1、4:1、3:1、2:
1,1:1,1:2,1:3,1:4,1:5,1:6,1:7,1:8,1:9,1:10 can also match composed model at any of the above two
Enclose it is interior selected, these ratios can be understood as weight ratio, also may include molar ratio.
Inventor is found by experiment that composition of the invention is that crops are true, bacterial disease synergy is bright for preventing and treating
It is aobvious, it is often more important that the two compounds the growth that can preferably adjust crop, promotes the health benefit of crop, improves the production of crop
Amount.
The present invention provides the bactericidal compositions comprising component polyglutamic acid and component benziothiazolinone to prevent and treat agriculture in agriculture field
Purposes in terms of crop disease, especially use in terms of regulating crop growth in terms of wheat or fruit tree improves
On the way.
To give full play to advantageous effect of the invention, composition of the invention can also (such as fungicide be killed with other pesticides
Worm agent, herbicide, plant growth regulator), fertilizer etc. be used in mixed way, these therewith it is mixed be disclosed in the prior art often
Pesticide or fertilizer.
The dosage form allowed on pesticide can be made by active constituent and insecticides adjuvant in composition of the invention.Further,
The composition is by the active component of 1.0001~85.0001% parts by weight and the auxiliary agent group of 98.9999~14.9999% parts by weight
At the dosage form allowed on pesticide.
Above-mentioned composition specifically may include insecticides adjuvant, such as carrier, solvent, dispersing agent, wetting agent, adhesive, thickening
One or more of agent, adhesive, surfactant etc. can mix common auxiliary agent during application.
Suitable auxiliary agent can be solid or liquid, they are usually common substance during formulation, such as day
Right or regenerated minerals, solvent, dispersing agent, wetting agent, adhesive, thickener, adhesive or fertilizer.
The method of administration of the present composition includes the aerial part that composition of the invention is used for plant growth, especially
It is leaf portion or blade face.It can choose seed soaking or be applied to controlling object surface.The frequency and amount of application of application depend on pathogen
Biology and weather life condition.The growth place of plant, such as rice field can be soaked with the liquid preparation of composition, or
Composition is applied in soil by person in solid form, and such as in granular form (soil application), composition can be by soil through planting
Object root enters in plant (systemic action).
These compositions can be only administered comprising active constituent, can also be mixed together with additive (insecticides adjuvant)
It closes and uses.
Composition of the invention can be prepared into dosage form pesticide-acceptable, such as wettable powder, suspending agent, moisture
Shot agent, aqueous emulsion or microemulsion, missible oil, dispersible oil-suspending agent, suspoemulsion, oil-suspending agent or encapsulated form etc..According to this
The property and application composition purpose to be achieved and ambient conditions of a little compositions, can choose by composition with it is spraying,
Atomizing dusts, broadcasts sowing or sprinkles the method application poured or the like.
Composition of the invention can be prepared into various dosage forms by known method, it can be by effective component and auxiliary agent, such as
Solvent, solid carrier can uniformly mix together with surfactant when needing, grind, be prepared into required dosage form.
Above-mentioned solvent can be selected from aromatic hydrocarbon, preferably contain 8-12 carbon atom, such as xylene mixture or substituted benzene, phthalein
Esters of gallic acid, such as two octanoic acid of Dibutyl phthalate or phthalandione, fat hydrocarbon, such as thiacyclohexane or paraffin, the ether of pure and mild ethylene glycol and they
And ester, such as ethyl alcohol, ethylene glycol, ethylene glycol monomethyl；Ketone, such as cyclohexanone, highly polar solvent, such as N- methyl -2- pyrrolidines
Ketone, dimethyl sulfoxide or dimethylformamide and vegetable oil or vegetable oil, such as soybean oil.
Above-mentioned solid carrier, such as usually natural mineral fillers for wettable powder and dispersible agent, for example, it is sliding
Stone, kaolin, montmorillonite or atlapulgite.In order to manage the physical property of composition, can also be added polymolecularity silicic acid or
Polymolecularity adsorpting polymerization object carrier, such as granulated adsorptive carriers or non-adsorbed carrier, suitable granulated adsorptive carriers are porous
Type, such as float stone, bentonite or bentonite；Suitable non-adsorbed carrier such as calcite or sand.Further, it is possible to use a large amount of inorganic
The prefabricated material to granulate of property or organic nature is as carrier, especially dolomite.
The chemical property of effective component in composition according to the present invention, suitable surfactant are sulfomethylated lignin
Acid, naphthalene sulfonic acids, phenolsulfonic acid, alkali salt or amine salt, alkylaryl sulfonates, alkyl sulfate, alkylsulfonate, fat
Alcohol sulfate, fatty acid and sulphated fatty alcohol glycol ether, there are also the condensation product of sulfonated naphthalene and naphthalene derivatives and formaldehyde, naphthalene or
The condensation product of naphthalene sulfonic acids and phenol and formaldehyde, NONIN HS 240, ethoxylated isooctyl-phenol, octyl phenol, nonyl phenol,
Alkylaryl polyglycol ether, tributyl benzene polyglycol ether, three stearyl phenyl polyglycol ethers, alkyl aryl polyether alcohol,
Ethoxylated castor oil, polyoxyethylene alkyl ether, ethylene oxide condensation product, ethoxylation polyoxypropylene, laurel acid polyethylene glycol
Ether acetal, sorbitol ester, lignin sulfite waste liquor and methylcellulose.
Two kinds of effective components show as synergistic effect in composition of the invention, and the activity of the composition is than using individualized
The independent activity of the expected summation of activity and single compound of closing object is more significant.Synergistic effect shows as allowing amount of application
Reduction, broader antifungal control spectrum, quick, more longlasting control efficiency, by a small number of applying only once or several times more
Good control plant pest fungi and broaden the possible administration interval time.These characteristics are plant epiphyte control practices
It especially needs in the process.
Other features that composition pesticide of the present invention is shown are mainly shown as: 1, composition mixture of the invention has bright
Aobvious synergistic effect；2, since two single dose chemical structures of this composition are widely different, the mechanism of action is entirely different, is not present
Cross resistance can delay two single doses that generated resistance problem is used alone；3, composition of the invention can adjust work well
Object growth, improves disease-resistant resistance, promotes crop health benefit, improves crop yield.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, with reference to embodiments, to the present invention
It is further elaborated.It should be appreciated that described herein, specific examples are only used to explain the present invention, is not used to limit
The fixed present invention, any modifications, equivalent replacements and improvementsmade within the spirit and principles of the invention, etc. should be included in
Within protection scope of the present invention.
Percentage is weight percentage in all formulas of following embodiment.The processing work of the various preparations of the present composition
Skill is the prior art, can be varied according to different situations.
One, dosage form prepares embodiment
(1) processing and embodiment of wettable powder
Active constituent polyglutamic acid and active constituent benziothiazolinone and various auxiliary agents and filler etc. are sufficiently mixed in proportion, passed through
Wettable powder is made after ultra-fine pulverizer disintegrating.
Embodiment 1:66% polyglutamic acid benziothiazolinone wettable powder (5:1)
Polyglutamic acid 55%, benziothiazolinone 11%, alkylaryl sulfonates 4.6%, sodium bicarbonate 7.8%, bentonite
5.5%, white carbon black complements to 100%.
Embodiment 2:20% polyglutamic acid benziothiazolinone wettable powder (1:1)
Polyglutamic acid 10%, benziothiazolinone 10%, lignosulfonates 8%, sodium alkyl benzene sulfonate 5.9%, ammonium sulfate
4.1%, precipitated calcium carbonate complements to 100%.
(2) processing and embodiment of suspending agent
By active component polyglutamic acid and active component benziothiazolinone, with each components such as dispersing agent, wetting agent, thickener and water
It is mixed according to the formula uniformly, after sand milling and/or high speed shear, obtains semi-finished product, water supplement was uniformly mixed after analysis
Filter is got product.
Embodiment 3:13.2% polyglutamic acid benziothiazolinone suspending agent (10:1)
Polyglutamic acid 12%, benziothiazolinone 1.2%, lauryl sodium sulfate 6.2%, sulfonate sodium 8.8%, aluminium chloride
4.2%, hydroxymethyl cellulose 1.42%, methanol 10%, polyoxyethylene glycerol ether 0.3%, water complements to 100%.
Embodiment 4:22% polyglutamic acid benziothiazolinone suspending agent (1:10)
Polyglutamic acid 2%, benziothiazolinone 20%, ammonium sulfate 3.8%, alkyl phenol polyoxyethylene ether 7.28%, pull open powder
BX6.66%, cyclohexanone 12%, aluminium-magnesium silicate 0.8%, silicone oil 0.5%, water complements to 100%.
(3) processing and embodiment of water dispersible granules
By active constituent polyglutamic acid and active constituent benziothiazolinone, it is mixed according to the formula uniformly with auxiliary agent and filler,
Through air-flow crushing at wettable powder, a certain amount of water mixing extrusion granulation is added, water-dispersible grain is made after dry screening
Agent product.
Embodiment 5:78% polyglutamic acid benziothiazolinone water dispersion granule (25:1)
Polyglutamic acid 75%, benziothiazolinone 3%, calcium dodecyl benzene sulfonate 5.2%, bentonite 4%, kaolin complements to
100%.
Embodiment 6:52.5% polyglutamic acid benziothiazolinone water dispersion granule (20:1)
Polyglutamic acid 50%, benziothiazolinone 2.5%, alkyl phenol polyoxyethylene ether sulfate 8.52%, aluminium chloride 4.15%, silicon
Sour magnalium 2.5%, white carbon black complements to 100%.
(4) processing and embodiment of microemulsion
By active constituent polyglutamic acid and active constituent benziothiazolinone, it is mixed according to the formula uniformly with auxiliary agent and solvent,
Uniform solution is formed, water is added and is uniformly mixed, can be prepared by microemulsion product.
Embodiment 7:31% polyglutamic acid benziothiazolinone microemulsion (30:1)
Polyglutamic acid 30%, benziothiazolinone 1%, alkylbenzene naphthalene sulfonate 5%, toluene 10%, polyvinyl alcohol 6%, water is supplied
To 100%.
Embodiment 8:16% polyglutamic acid benziothiazolinone microemulsion (15:1)
Polyglutamic acid 15%, benziothiazolinone 1%, APES formaldehyde condensation products sulfat phosphate 8%, hexamethylene
Ketone 12%, dialkyl succinylsuccinate sulfonated ester 5%, water complements to 100%.
Embodiment 9:3% polyglutamic acid benziothiazolinone microemulsion (1:5)
Polyglutamic acid 0.5%, benziothiazolinone 2.5%, styrene phenol formaldehyde resin polyoxyethylene ether phosphate salt 5%, two
Toluene 10%, alkyl naphthalene formaldehyde condensate sulfonate 5%, water complements to 100%.
Two, drug effect verification test
(1) Assays Example
1, polyglutamic acid is compounded with benziothiazolinone adjusts synthesis measuring test to wheat growth
Polyglutamic acid and benziothiazolinone are diluted with acetone according to a certain concentration, cauline leaf is carried out to crop and is sprayed, is surveyed in field
Fixed influence of each concentration to plant growth, including plant height, setting percentage, seed mass of 1000 kernel, disease-resistant situation and the production to crop
It measures situation etc. and carries out overall merit.
Plant height control rate=(clear water compare plant height-treated plant height)/clear water compares plant height * 100%
Setting percentage=bear fruit grains/number of grain per ear * 100%
Preventive effect=(disease index-treated the disease index of clear water control)/clear water control disease index *
100%
Seed mass of 1000 kernel increase rate=(treated seed mass of 1000 kernel-clear water control seed mass of 1000 kernel)/clear water control
Seed mass of 1000 kernel * 100%
Per mu yield increase rate=(treated per mu yield-clear water control per mu yield)/clear water control per mu yield * 100%
Polyglutamic acid compounded with benziothiazolinone to wheat growth adjust synthesis measuring result see attached list in table 1, pass through experiment
Castering action is cooperateed with very well inventors have found that having between polyglutamic acid and benziothiazolinone, and polyglutamic acid and benziothiazolinone mixture be not
With under proportion, opposite polyglutamic acid, benziothiazolinone single dose and clear water control act on obvious, main table to the growth regulating of wheat
Present 1, wheat plant can be downgraded, effectively controls the prosperous excessive growth of wheat control, prevents Wheat lodging；2, the solid of wheat can be promoted
Rate improves yield；3, it is remarkably improved the weight of wheat seed；4, benziothiazolinone has wheat growth prevention fungal disease certain
Protective effect, and polyglutamic acid has certain disease-resistant anti-adversity ability to wheat growth, has certain association after the two mixture
Same synergistic effect；5, composition of the invention, which has the specific yield of wheat, is obviously improved effect.
(2) field efficacy verification test
(1) polyglutamic acid and benziothiazolinone mixture adjust the field compbined test of growth and disease-resistant yield-increasing to apple
Application period: apple florescence and apple phase of bearing fruit respectively are administered 1 time.
Spraying times: 2 times.It is sprayed using example of formulations of the invention, three repetitions, results are averaged.
The field Comprehensive Experiment result that polyglutamic acid and benziothiazolinone mixture adjust growth to apple see attached list in table 2, from
2 experimental data of table shows that for product of the invention in apple florescence and phase application of bearing fruit, the health that can effectively adjust apple is raw
It is long.1, the transverse diameter and vertical diameter of apple be can effectively improve, apple is increased；2, the soluble sugar and acidity of apple be can effectively improve
Content increases the sour-sweet mouthfeel degree 3 of apple, benziothiazolinone, with preferable absorbability, prevents nosomycosis to apple development to apple
Evil has certain protective effect, and polyglutamic acid has certain disease-resistant anti-adversity ability to apple development, has after the two mixture
There is certain synergistic function；4, composition of the invention, which has the specific yield of apple, is obviously improved effect.
Claims (9)
1. a kind of composition pesticide, it is characterised in that the composition includes active component polyglutamic acid and benziothiazolinone.
2. composition according to claim 1, it is characterised in that the weight ratio of the polyglutamic acid and benziothiazolinone be 30~
1:1~10.
3. composition according to claim 1 or 2, it is characterised in that the weight ratio of the polyglutamic acid and benziothiazolinone is preferred
25~1:1~5.
4. composition according to claim 1,2 or 3, it is characterised in that the weight ratio of the polyglutamic acid and benziothiazolinone is excellent
Select 20~1:1.
5. composition pesticide according to any one of claims 1 to 4, it is characterised in that the composition is by active constituent and helps
The dosage form allowed on pesticide is made in agent.
6. composition pesticide according to claim 5, it is characterised in that the composition pesticide is by 1.0001~85.0001%
The dosage form allowed on the auxiliary agent of the active component of parts by weight and 98.9999~14.9999% parts by weight composition pesticide.
7. composition pesticide according to claim 5, it is characterised in that the dosage form be microemulsion, water dispersible granules,
Suspending agent or wettable powder.
8. composition pesticide according to claim 5 or 6, it is characterised in that the auxiliary agent is selected from carrier, solvent, dispersion
One or more of agent, wetting agent, adhesive, thickener, adhesive, surfactant or fertilizer.
9. any composition pesticide in agriculture field disease resistance or promotes in plant growth in claim 1~8
Purposes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811271836.XA CN109329284A (en) | 2018-10-29 | 2018-10-29 | A kind of composition pesticide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811271836.XA CN109329284A (en) | 2018-10-29 | 2018-10-29 | A kind of composition pesticide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109329284A true CN109329284A (en) | 2019-02-15 |
Family
ID=65310911
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811271836.XA Pending CN109329284A (en) | 2018-10-29 | 2018-10-29 | A kind of composition pesticide |
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| Country | Link |
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| CN (1) | CN109329284A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101695297A (en) * | 2009-11-04 | 2010-04-21 | 陕西西大华特科技实业有限公司 | Benziothiazolinone water suspension and preparation method thereof |
| CN103619174A (en) * | 2011-05-13 | 2014-03-05 | Isp投资公司 | Aqueous solutions of 1,2-benzisothiazolin-3-one |
| CN106900722A (en) * | 2016-09-23 | 2017-06-30 | 江苏辉丰农化股份有限公司 | A kind of composition pesticide |
-
2018
- 2018-10-29 CN CN201811271836.XA patent/CN109329284A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101695297A (en) * | 2009-11-04 | 2010-04-21 | 陕西西大华特科技实业有限公司 | Benziothiazolinone water suspension and preparation method thereof |
| CN103619174A (en) * | 2011-05-13 | 2014-03-05 | Isp投资公司 | Aqueous solutions of 1,2-benzisothiazolin-3-one |
| CN106900722A (en) * | 2016-09-23 | 2017-06-30 | 江苏辉丰农化股份有限公司 | A kind of composition pesticide |
Non-Patent Citations (4)
| Title |
|---|
| 余露: ""高效广谱杀菌剂噻霉酮"", 《农药市场信息》 * |
| 王萌等: ""γ－聚谷氨酸在农业应用中的研究进展"", 《黑龙江农业科学》 * |
| 郭玉人: "《农药安全使用手册》", 30 September 2009, 上海科学技术出版社 * |
| 金青哲等: "《功能性脂质》", 31 August 2013, 中国轻工业出版社 * |
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