CN1093252C - 芳酰胺微丝抗切割制品 - Google Patents

芳酰胺微丝抗切割制品 Download PDF

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CN1093252C
CN1093252C CN99810751A CN99810751A CN1093252C CN 1093252 C CN1093252 C CN 1093252C CN 99810751 A CN99810751 A CN 99810751A CN 99810751 A CN99810751 A CN 99810751A CN 1093252 C CN1093252 C CN 1093252C
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microfilament
cut product
gloves
yarn
cut
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CN1319175A (zh
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J·曼滕
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TEVORON PRODUCTS CO
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TEVORON PRODUCTS CO
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    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F41—WEAPONS
    • F41H—ARMOUR; ARMOURED TURRETS; ARMOURED OR ARMED VEHICLES; MEANS OF ATTACK OR DEFENCE, e.g. CAMOUFLAGE, IN GENERAL
    • F41H5/00—Armour; Armour plates
    • F41H5/02—Plate construction
    • F41H5/04—Plate construction composed of more than one layer
    • F41H5/0471—Layered armour containing fibre- or fabric-reinforced layers
    • F41H5/0478—Fibre- or fabric-reinforced layers in combination with plastics layers
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04—Blended or other yarns or threads containing components made from different materials
    • D02G3/047—Blended or other yarns or threads containing components made from different materials including aramid fibres
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/44—Yarns or threads characterised by the purpose for which they are designed
    • D02G3/442—Cut or abrasion resistant yarns or threads
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F41—WEAPONS
    • F41H—ARMOUR; ARMOURED TURRETS; ARMOURED OR ARMED VEHICLES; MEANS OF ATTACK OR DEFENCE, e.g. CAMOUFLAGE, IN GENERAL
    • F41H1/00—Personal protection gear
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F41—WEAPONS
    • F41H—ARMOUR; ARMOURED TURRETS; ARMOURED OR ARMED VEHICLES; MEANS OF ATTACK OR DEFENCE, e.g. CAMOUFLAGE, IN GENERAL
    • F41H1/00—Personal protection gear
    • F41H1/02—Armoured or projectile- or missile-resistant garments; Composite protection fabrics
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • D10B2331/021—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides aromatic polyamides, e.g. aramides
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2904—Staple length fiber
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2933—Coated or with bond, impregnation or core
    • Y10T428/2936—Wound or wrapped core or coating [i.e., spiral or helical]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2933—Coated or with bond, impregnation or core
    • Y10T428/2964—Artificial fiber or filament
    • Y10T428/2967—Synthetic resin or polymer
    • Y10T428/2969—Polyamide, polyimide or polyester
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/298—Physical dimension

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  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Textile Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Gloves (AREA)
  • Professional, Industrial, Or Sporting Protective Garments (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Artificial Filaments (AREA)
  • Organic Insulating Materials (AREA)
  • Materials For Medical Uses (AREA)
  • Lubricants (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Wrappers (AREA)
  • Packages (AREA)
  • Woven Fabrics (AREA)
  • Knitting Of Fabric (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Outer Garments And Coats (AREA)

Abstract

本发明涉及抗切割制品，特别是手套。该制品含有芳族聚酰胺的微丝，更优选对芳酰胺，其中微丝纤度等于或小于1.3dtex(1.3×10-4g/m)。在一优选的实施方案中，该制品由长度38-100mm的短纤维制备。

Description

芳酰胺微丝抗切割制品
                          发明领域
本发明涉及由芳族聚酰胺微丝制成的抗切割制品。
                          背景技术
已知可由芳族聚酰胺(聚芳酰胺)纤维来制成抗切割制品。DE29713824中叙述了一种防护手套，其衬里由柔性的芳酰胺纤维组成。WO 9721334中公开了抗刺透复合物，其中芳酰胺纤维纱与聚合物连续体相连接。此材料基本目的在于作为冲击粒子保护的身体防护物，但该文中还叙述了此复合物可用在手套、套袖、鞋等物品中用以抵抗尖锐物体如刀子。由聚(对苯二酸对苯二酯)纱(对芳酰胺纱)制成的手套，如以商品名Twaron安全手套，在市场上有售。
尽管这些制品，特别是手套，适合于许多情况，但是还需要进行改善。此类改善包括更好地抵抗尖锐物品如钉子、刀子等的划擦和切割，而且要提高穿戴舒适性、运动自由性，而高柔度是一直致力于改善的内容。
一种芳族聚酰胺微丝可由例如EP 241,681中得知，其中已公开了由聚芳酰胺微丝制成的制品用作冲击保护结构，这种微丝的纤度为＜1.5dtex。但是，由聚芳酰胺微丝制成的制品在抗切割和穿戴舒适性方面具有显著改善了的性能这一点并不为人所知。
                   发明内容和具体实施方式
现在已发现，与已知制品相比具有改善了的性能的抗切割制品可用芳族聚酰胺(聚芳酰胺)微丝得到。
因此本发明涉及由聚芳酰胺微丝制成的制品，特别是手套、袖套和常用的切割防护服装。纺织品、编织品或针织毛毡都可以应用。可以使用多层以改善性能，并且如果需要，可以加入另外的不同材料层，例如加入金属化材料用于额外的热保护。
芳族聚酰胺(聚芳酰胺)可以是任何芳族聚酰胺，如由一种芳族二胺和一种芳族二酸氯化物聚合而得。更优选对芳族聚酰胺，最优选聚(对苯二酸对苯二酯)(PPD-T)，它可由对苯二胺和对苯二酰氯得到。
将芳族聚酰胺用本领域已知的方法纺成微丝，该纺丝纤维可用作循环长丝纱线、牵切纱线或者，更优选，作为以短纤维为基础的细纱。本发明的细纱可用任何适当的纺丝工艺制得，其中可提及的纺丝工艺如：棉、绒布和羊毛环纺丝系统，以及自由端纺丝工艺。如果用常产纤维制造抗切割制品，优选使用长度在38-100mm之间的短纤维。
微丝的纤度为至少1.3dtex(1.3×10-4g/m)或更小，优选等于或小于1.0dtex(10-4g/m)。
本发明的抗切割制品如手套的制造，例如可用芳族聚酰胺微丝所得的纱线编织而成。
本发明的纱线比纤度在1.3dtex(1.3×10-3g/m)以上的对比标准纱线有更大的抗切割性。如果手套用这些微丝制成，则与用标准丝制成的手套相比戴起来更加舒适。用此微丝制成的手套更加柔顺，因而使用者更感舒适。因此这些手套也特别适合于从事精细的工作。
下面的实验进一步说明了本发明。
将用标准纱和微丝纱编织成的样品进行比较：
根据DIN EN 388确定抗切割性：
标准 微丝 标准 微丝 标准 微丝
丝纤度(dtex) 1.7 0.93 1.7 0.93 1.7 0.93
短纤维纤度 Nm 28/2 Nm 28/2 2×Nm50/2 2×Nm80/2 2×Nm80/2 2×Nm50/2
合股纱捻度 α120 α120 α100 α100 α100 α100
密度(水平cm-1×垂直cm-1) 7×11 7×11 7×10 7×10 7×9.5 7×9.5
最小指标 6.5 9.1 3.3 3.6 2.1 5.7
性能水准 3 3 2 2 1 3
结论：该微丝纱的最小指标比标准纱线的要大。该微丝纱线的性能一直较好。当根据DIN EN 388性能具有相同值时，标准样品在性能水准较低一端而该微丝样品在性能水准的较高一端。
另外，以微丝编成的织物比用支数为1.7dtex的标准纤维织成的可比织物更加柔软并且手感更好。
此外，对以微丝和标准纤维为基础的细纱的机械性能也已进行了研究。这些细纱根据棉环纺工艺进行生产。由下表可看出，微丝细纱的强度显著提高。我们认为微丝细纱的拉伸强度较高使得由微丝制成的织物抗切割性提高。根据DIN 53362测定柔韧性。柔韧性，表示为弯曲劲度，是手套“抓紧”和柔软性的量度。
标准 微丝 标准 微丝
丝纤度(dtex) 1.7 0.93 1.7 0.93
短纤维纤度 Nm 50/2 Nm 50/2 Nm 50/2 Nm 50/2
纱捻度 α100 α100 α120 α120
强度(N) 39.47 43.55 39.72 42.97
弯曲劲度(cN/cm2) 56.89 9.90 17.60 13.60
标准 微丝 标准 微丝
丝纤度(dtex) 1.7 0.93 1.7 0.93
短纤维纤度 Nm 80/2 Nm 80/2 Nm 80/2 Nm 80/2
纱捻度 α100 α100 α120 α120
强度(N) 20.96 21.52 19.99 21.03
弯曲劲度(cN/cm2) 12.47 5.52 12.94 4.37
结论：微丝短纤维的强度显著提高，其中所有情况下都发现用微丝制成的手套的弯曲劲度得以改善。

Claims (12)

1.一种抗切割制品，含有芳族聚酰胺微丝，这种微丝的纤度为＜1.5dtex。
2.权利要求1的抗切割制品，含有对芳酰胺微丝。
3.权利要求2的抗切割制品，含有聚(对苯二酸对苯二酯)微丝。
4.权利要求1-3中任一项的抗切割制品，其中微丝的纤度等于或小于1.3dtex(1.3×10-4g/m)。
5.权利要求1-3中任一项的抗切割制品，其中微丝为长度38-100mm的短纤维的形式。
6.权利要求4的抗切割制品，其中微丝为长度38-100mm的短纤维的形式。
7.权利要求1-3中任一项的抗切割制品，其中微丝为牵切纱线或循环长丝纱线的形式。
8.权利要求4的抗切割制品，其中微丝为牵切纱线或循环长丝纱线的形式。
9.权利要求1-3中任一项的抗切割制品，其中该制品为手套。
10.权利要求4的抗切割制品，其中该制品为手套。
11.权利要求5的抗切割制品，其中该制品为手套。
12.权利要求7的抗切割制品，其中该制品为手套。
CN99810751A 1998-08-07 1999-07-06 芳酰胺微丝抗切割制品 Expired - Fee Related CN1093252C (zh)

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NL98202659.3 1998-08-07
EP98202659 1998-08-07

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CN1093252C true CN1093252C (zh) 2002-10-23

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EP (1) EP1099088B1 (zh)
JP (1) JP2002522658A (zh)
CN (1) CN1093252C (zh)
AT (1) ATE236383T1 (zh)
AU (1) AU760746B2 (zh)
BR (1) BR9912863B1 (zh)
CA (1) CA2345048C (zh)
CZ (1) CZ2001491A3 (zh)
DE (1) DE69906535T2 (zh)
DK (1) DK1099088T3 (zh)
ES (1) ES2192065T3 (zh)
HU (1) HU223636B1 (zh)
PL (1) PL190170B1 (zh)
RS (1) RS50043B (zh)
RU (1) RU2001106648A (zh)
SI (1) SI1099088T1 (zh)
SK (1) SK1982001A3 (zh)
TR (1) TR200100619T2 (zh)
WO (1) WO2000008410A1 (zh)

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WO2009087123A1 (de) 2008-01-10 2009-07-16 Teijin Aramid Gmbh Stapelfasergarn, verfahren zur herstellung eines textilen artikels und textiler artikel
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BR9912863B1 (pt) 2008-11-18
AU5158999A (en) 2000-02-28
DE69906535T2 (de) 2003-11-20
SI1099088T1 (en) 2003-08-31
ATE236383T1 (de) 2003-04-15
CA2345048C (en) 2006-11-14
CA2345048A1 (en) 2000-02-17
HUP0103018A2 (hu) 2001-12-28
WO2000008410A1 (en) 2000-02-17
SK1982001A3 (en) 2001-11-06
DK1099088T3 (da) 2003-07-21
YU14401A (sh) 2003-07-07
ES2192065T3 (es) 2003-09-16
TR200100619T2 (tr) 2001-06-21
CZ2001491A3 (cs) 2002-05-15
EP1099088B1 (en) 2003-04-02
JP2002522658A (ja) 2002-07-23
US6829881B1 (en) 2004-12-14
PL190170B1 (pl) 2005-11-30
RU2001106648A (ru) 2003-05-20
PL345892A1 (en) 2002-01-14
AU760746B2 (en) 2003-05-22
BR9912863A (pt) 2001-05-02
CN1319175A (zh) 2001-10-24
HU223636B1 (hu) 2004-10-28
EP1099088A1 (en) 2001-05-16

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