CN109321929A - A kind of titanium building materials detergent and its preparation process - Google Patents
A kind of titanium building materials detergent and its preparation process Download PDFInfo
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- CN109321929A CN109321929A CN201811479434.9A CN201811479434A CN109321929A CN 109321929 A CN109321929 A CN 109321929A CN 201811479434 A CN201811479434 A CN 201811479434A CN 109321929 A CN109321929 A CN 109321929A
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/24—Cleaning or pickling metallic material with solutions or molten salts with neutral solutions
- C23G1/26—Cleaning or pickling metallic material with solutions or molten salts with neutral solutions using inhibitors
Abstract
The invention discloses a kind of titanium building materials detergent and its preparation processes, and wherein titanium building materials include that following parts by weight material is made with detergent: sodium sulfate of polyethenoxy ether of fatty alcohol 3-5 parts by weight, 2- ethylhexylsulfate sodium salt 3-5 parts by weight, alkylsulfonate 3-4 parts by weight, isomerous tridecanol polyoxyethylene ether 2-3 parts by weight, tripolyphosphate 2-3 parts by weight, adjuvant 3-5 parts by weight, fatty alcohol EO/PO polyethers 3-4 parts by weight, corrosion inhibiter 1-2 parts by weight, defoaming agent 0.03-0.1 parts by weight, essence 4-6 parts by weight, high-purity deionized water 50-63 parts by weight.The present invention has efficient dispersibility to subtle inorganic particulate or lipid spot, improves the showy ability of dirt, and material will not destroy ozone layer, the feature of environmental protection is higher.
Description
Technical field
The invention belongs to detergent technical fields, and in particular to a kind of titanium building materials detergent and its preparation process.
Background technique
Country's titanium building materials generally use solvent with cleaning agent and clean at present.Solvent cleaning mainly utilizes leaning solvent
Steam clean is carried out by equipment appropriate or is embathed.But traditional solvent-borne cleaning agent is not only expensive and has inflammable and damage skin
The shortcomings that skin, pollution is stronger, for this purpose, it is proposed that a kind of titanium building materials detergent preparation process.
Summary of the invention
The purpose of the present invention is to provide a kind of titanium building materials detergent preparation processes, to solve to mention in above-mentioned background technique
Traditional solvent-borne cleaning agent out is not only expensive and has the shortcomings that inflammable and damage skin, pollution are stronger.
To achieve the above object, the invention provides the following technical scheme: a kind of titanium building materials detergent preparation process, including
Following parts by weight material is made: sodium sulfate of polyethenoxy ether of fatty alcohol 3-5 parts by weight, 2- ethylhexylsulfate sodium salt 3-5 weight
Measure part, alkylsulfonate 3-4 parts by weight, isomerous tridecanol polyoxyethylene ether 2-3 parts by weight, tripolyphosphate 2-3 parts by weight, auxiliary
Auxiliary agent 3-5 parts by weight, fatty alcohol EO/PO polyethers 3-4 parts by weight, corrosion inhibiter 1-2 parts by weight, defoaming agent 0.03-0.1 parts by weight,
Essence 4-6 parts by weight, high-purity deionized water 50-63 parts by weight.
Further, the specific preparation process is as follows:
Step 1: by sodium sulfate of polyethenoxy ether of fatty alcohol, 2- ethylhexylsulfate sodium salt, fatty alcohol EO/PO polyethers, isomery
Tridecanol polyoxyethylene ether is sent into flask and is heated, and when heated using 3-5min as the mixing speed of border until temperature
Reach 75-85 DEG C, obtains surfactant；
Step 2: being maintained at 85-87 DEG C for the temperature of the surfactant in step 1 flask, internally be added adjuvant continue into
Row stirring work, and the heat preservation of flask inner melt is made to continue to be kept for 85-87 DEG C, so that it is reacted 4-5h；
Step 3: adjuvant, tripolyphosphate, alkylsulfonate being sequentially added and are stirred heating in round-bottomed flask, and are added
Hot temperature is incremented by with 3-5s is heated to 60-80 DEG C, to citrate, and citrate and circle are added in flask in whipping process
The proportion of melt is 1:8 in the flask of bottom；
Step 4: the solution after step 2 is reacted is added equal with 70-85 DEG C of temperature stirring after the proportioned solution of step 3
It is even, obtain dense property detergent；
Step 5: by essence, defoaming agent, corrosion inhibiter and high-purity deionized water to mix at a temperature of 25-40 DEG C, by step
Five obtained dense property detergent are added, and with 60-70 DEG C of stirring 5-8s after, hold it at 65-70 DEG C and react 3-4h；
Step 6: after the solvent that step 5 is obtained is cooling, finished product cleaning solvent is obtained in uniform tinning to packing container.
Further, in the step 5 corrosion inhibiter preparing materials are as follows: silicate and boric acid, its ratio be 1:1.
Further, the defoaming agent in the step 5 is high mercaptan or polyether-modified silicon.
Further, the preparing materials of the adjuvant in the step 2 are as follows: alkyl polyoxydivinyl ether, alkyl phenol polyoxy second
Alkene ether, trichloro ethylene or Carbon tetrachloride, and its configuration proportion are as follows: 1.5:1:1.
Further, if the detergent foam generated in the step 5 is more, defoaming agent can be added in right amount.
Compared with prior art, the beneficial effects of the present invention are: cost is relatively low, it is easy to prepare, can effectively makes molecule
The interface between water surface tension and oil and water can be effectively reduced in oil and formation unimolecule oriented attachment layer in water termination in beam
Power improves gas wetting, osmotic effect, and the detergent brokenly bubble after preparation is good, and blistering is few, rinses, substantially reduces convenient for the later period
Water resource waste has efficient dispersibility to subtle inorganic particulate or lipid spot, improves the showy ability of dirt, and material
Material will not destroy ozone layer, and the feature of environmental protection is higher, when using the present invention, will not destroy titanium building materials, it is original can to retain titanium building materials
Quality and original color.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical scheme in the embodiment of the invention is clearly and completely described,
Obviously, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based in the present invention
Embodiment, every other embodiment obtained by those of ordinary skill in the art without making creative efforts, all
Belong to the scope of protection of the invention.
Embodiment 1
A kind of titanium building materials detergent preparation process, including following parts by weight material are made: sodium sulfate of polyethenoxy ether of fatty alcohol 3
Parts by weight, 3 parts by weight of 2- ethylhexylsulfate sodium salt, 3 parts by weight of alkylsulfonate, 2 weight of isomerous tridecanol polyoxyethylene ether
Amount part, 3 parts by weight of adjuvant, 3 parts by weight of fatty alcohol EO/PO polyethers, 1 parts by weight of corrosion inhibiter, disappears at 2 parts by weight of tripolyphosphate
0.03 parts by weight of infusion, 4 parts by weight of essence, 50 parts by weight of high-purity deionized water.
Wherein, the specific preparation process is as follows:
Step 1: by sodium sulfate of polyethenoxy ether of fatty alcohol, 2- ethylhexylsulfate sodium salt, fatty alcohol EO/PO polyethers, isomery
Tridecanol polyoxyethylene ether is sent into flask and is heated, and when heated using 3min as the mixing speed of border until temperature reaches
To 75 DEG C, surfactant is obtained；
Step 2: being maintained at 85 DEG C for the temperature of the surfactant in step 1 flask, and adjuvant is internally added and continues
Work is stirred, and the heat preservation of flask inner melt is made to continue to be kept for 85 DEG C, it is made to react 4-5h；
Step 3: adjuvant, tripolyphosphate, alkylsulfonate being sequentially added and are stirred heating in round-bottomed flask, and are added
Hot temperature is incremented by with 3s is heated to 60 DEG C, and to being added citrate in flask in whipping process, and citrate and round bottom are burnt
The proportion of melt is 1:8 in bottle；
Step 4: the solution after step 2 is reacted is stirred evenly after the proportioned solution of step 3 is added with 70 DEG C of temperature,
Obtain dense property detergent；
Step 5: by essence, defoaming agent, corrosion inhibiter and high-purity deionized water to mix at a temperature of 25 DEG C, by step 5
Obtained dense property detergent is added, and with 60 DEG C of stirring 5s after, hold it at 65 DEG C and react 3h；
Step 6: after the solvent that step 5 is obtained is cooling, finished product cleaning solvent is obtained in uniform tinning to packing container.
Wherein, in the step 5 corrosion inhibiter preparing materials are as follows: silicate and boric acid, its ratio be 1:1.
Wherein, the defoaming agent in the step 5 is high mercaptan or polyether-modified silicon.
Wherein, the preparing materials of the adjuvant in the step 2 are as follows: alkyl polyoxydivinyl ether, alkylphenol-polyethenoxy
Ether, trichloro ethylene or Carbon tetrachloride, and its configuration proportion are as follows: 1.5:1:1.
Wherein, if the detergent foam generated in the step 5 is more, defoaming agent can be added in right amount.
Embodiment 2
A kind of titanium building materials detergent preparation process, including following parts by weight material are made: sodium sulfate of polyethenoxy ether of fatty alcohol 5
Parts by weight, 5 parts by weight of 2- ethylhexylsulfate sodium salt, 4 parts by weight of alkylsulfonate, 3 weight of isomerous tridecanol polyoxyethylene ether
Amount part, 5 parts by weight of adjuvant, 4 parts by weight of fatty alcohol EO/PO polyethers, 2 parts by weight of corrosion inhibiter, disappears at 3 parts by weight of tripolyphosphate
0.1 parts by weight of infusion, 6 parts by weight of essence, 63 parts by weight of high-purity deionized water.
Wherein, the specific preparation process is as follows:
Step 1: by sodium sulfate of polyethenoxy ether of fatty alcohol, 2- ethylhexylsulfate sodium salt, fatty alcohol EO/PO polyethers, isomery
Tridecanol polyoxyethylene ether is sent into flask and is heated, and when heated using 5min as the mixing speed of border until temperature reaches
To 85 DEG C, surfactant is obtained；
Step 2: being maintained at 87 DEG C for the temperature of the surfactant in step 1 flask, and adjuvant is internally added and continues
Work is stirred, and the heat preservation of flask inner melt is made to continue to be kept for 87 DEG C, it is made to react 5h.
Step 3: adjuvant, tripolyphosphate, alkylsulfonate being sequentially added and are stirred heating in round-bottomed flask,
And heating temperature is incremented by with 5s and is heated to 80 DEG C, to citrate, and citrate and circle are added in flask in whipping process
The proportion of melt is 1:8 in the flask of bottom；
Step 4: the solution after step 2 is reacted is stirred evenly after the proportioned solution of step 3 is added with 85 DEG C of temperature,
Obtain dense property detergent；
Step 5: by essence, defoaming agent, corrosion inhibiter and high-purity deionized water to mix at a temperature of 40 DEG C, by step 5
Obtained dense property detergent is added, and with 70 DEG C of stirring 8s after, hold it at 70 DEG C and react 4h；
Step 6: after the solvent that step 5 is obtained is cooling, finished product cleaning solvent is obtained in uniform tinning to packing container.
Wherein, in the step 5 corrosion inhibiter preparing materials are as follows: silicate and boric acid, its ratio be 1:1.
Wherein, the defoaming agent in the step 5 is high mercaptan or polyether-modified silicon.
Wherein, the preparing materials of the adjuvant in the step 2 are as follows: alkyl polyoxydivinyl ether, alkylphenol-polyethenoxy
Ether, trichloro ethylene or Carbon tetrachloride, and its configuration proportion are as follows: 1.5:1:1.
Wherein, if the detergent foam generated in the step 5 is more, defoaming agent can be added in right amount.
The working principle of the invention: it can effectively enable molecular beam at oil and formation unimolecule oriented attachment in water termination
The interfacial tension between water surface tension and oil and water is effectively reduced in layer, improves gas wetting, osmotic effect, and washing after preparation
It is good to wash agent brokenly bubble, blistering is few, rinses convenient for the later period, substantially reduces water resource waste, dirty to subtle inorganic particulate or lipid
Stain has efficient dispersibility, improves the showy ability of dirt, and material will not destroy ozone layer, and the feature of environmental protection is higher, uses this
When invention, titanium building materials will not be destroyed, the original quality of titanium building materials and original color can be retained.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention is defined by the appended.
Claims (6)
1. a kind of titanium building materials detergent, which is characterized in that be made including following parts by weight material: fatty alcohol polyoxyethylene ether sulphur
Sour sodium 3-5 parts by weight, 2- ethylhexylsulfate sodium salt 3-5 parts by weight, alkylsulfonate 3-4 parts by weight, isomerous tridecanol are poly-
Ethylene oxide ether 2-3 parts by weight, tripolyphosphate 2-3 parts by weight, adjuvant 3-5 parts by weight, fatty alcohol EO/PO polyethers 3-4 weight
Part, corrosion inhibiter 1-2 parts by weight, defoaming agent 0.03-0.1 parts by weight, essence 4-6 parts by weight, high-purity deionized water 50-63 weight
Part.
2. a kind of preparation process of titanium building materials detergent preparation process, which comprises the following steps:
Step 1: by sodium sulfate of polyethenoxy ether of fatty alcohol, 2- ethylhexylsulfate sodium salt, fatty alcohol EO/PO polyethers, isomery
Tridecanol polyoxyethylene ether is sent into flask and is heated, and when heated using 3-5min as the mixing speed of border until temperature
Reach 75-85 DEG C, obtains surfactant；
Step 2: being maintained at 85-87 DEG C for the temperature of the surfactant in step 1 flask, internally be added adjuvant continue into
Row stirring work, and the heat preservation of flask inner melt is made to continue to be kept for 85-87 DEG C, so that it is reacted 4-5h；
Step 3: adjuvant, tripolyphosphate, alkylsulfonate being sequentially added and are stirred heating in round-bottomed flask, and are added
Hot temperature is incremented by with 3-5s is heated to 60-80 DEG C, to citrate, and citrate and circle are added in flask in whipping process
The proportion of melt is 1:8 in the flask of bottom；
Step 4: the solution after step 2 is reacted is added equal with 70-85 DEG C of temperature stirring after the proportioned solution of step 3
It is even, obtain dense property detergent；
Step 5: by essence, defoaming agent, corrosion inhibiter and high-purity deionized water to mix at a temperature of 25-40 DEG C, by step
Five obtained dense property detergent are added, and with 60-70 DEG C of stirring 5-8s after, hold it at 65-70 DEG C and react 3-4h；
Step 6: after the solvent that step 5 is obtained is cooling, finished product cleaning solvent is obtained in uniform tinning to packing container.
3. the preparation process of titanium building materials detergent preparation process according to claim 2 a kind of, it is characterised in that: described
The preparing materials of corrosion inhibiter in step 5 are as follows: silicate and boric acid, its ratio be 1:1.
4. the preparation process of titanium building materials detergent preparation process according to claim 2 a kind of, it is characterised in that: described
Defoaming agent in step 5 is high mercaptan or polyether-modified silicon.
5. the preparation process of titanium building materials detergent preparation process according to claim 2 a kind of, it is characterised in that: described
The preparing materials of adjuvant in step 2 are as follows: alkyl polyoxydivinyl ether, alkyl phenol polyoxyethylene ether, trichloro ethylene or four oxidations
Carbon, and its configuration proportion are as follows: 1.5:1:1.
6. the preparation process of titanium building materials detergent preparation process according to claim 2 a kind of, it is characterised in that: described
If the detergent foam generated in step 5 is more, defoaming agent can be added in right amount.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811479434.9A CN109321929A (en) | 2018-12-05 | 2018-12-05 | A kind of titanium building materials detergent and its preparation process |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201811479434.9A CN109321929A (en) | 2018-12-05 | 2018-12-05 | A kind of titanium building materials detergent and its preparation process |
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| Publication Number | Publication Date |
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| CN109321929A true CN109321929A (en) | 2019-02-12 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201811479434.9A Pending CN109321929A (en) | 2018-12-05 | 2018-12-05 | A kind of titanium building materials detergent and its preparation process |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110952131A (en) * | 2019-12-03 | 2020-04-03 | 西安庄信新材料科技有限公司 | Processing method for titanium rod surface polishing treatment |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070219109A1 (en) * | 2002-12-31 | 2007-09-20 | 3M Innovative Properties Company | Degreasing compositions |
| CN101555440A (en) * | 2008-12-08 | 2009-10-14 | 东莞市松山湖微电子材料研发中心 | Method for producing cleaning agent for removing wax and oil |
| CN107541350A (en) * | 2016-06-28 | 2018-01-05 | 谢绍光 | A kind of train seat detergent |
| CN107587150A (en) * | 2016-07-07 | 2018-01-16 | 天津市澳路浦润滑科技股份有限公司 | The without phosphorus aqueous cleaning agent of normal temperature |
-
2018
- 2018-12-05 CN CN201811479434.9A patent/CN109321929A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070219109A1 (en) * | 2002-12-31 | 2007-09-20 | 3M Innovative Properties Company | Degreasing compositions |
| CN101555440A (en) * | 2008-12-08 | 2009-10-14 | 东莞市松山湖微电子材料研发中心 | Method for producing cleaning agent for removing wax and oil |
| CN107541350A (en) * | 2016-06-28 | 2018-01-05 | 谢绍光 | A kind of train seat detergent |
| CN107587150A (en) * | 2016-07-07 | 2018-01-16 | 天津市澳路浦润滑科技股份有限公司 | The without phosphorus aqueous cleaning agent of normal temperature |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110952131A (en) * | 2019-12-03 | 2020-04-03 | 西安庄信新材料科技有限公司 | Processing method for titanium rod surface polishing treatment |
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Application publication date: 20190212 |
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